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Arsenic and isotope concentrations in the lower Platte River valley of eastern Nebraska, early 1970s to 2023

The City of Lincoln, Nebraska, has been monitoring concentrations of arsenic in their source water and evaluating their options for treatment and removal since at least 2002. In 2022, the City of Lincoln, Nebr., with funding assistance from the Nebraska Water Sustainability Fund, began cooperating with the U.S. Geological Survey to examine arsenic concentrations in surface water and groundwater in the lower Platte River valley and the area around City of Lincoln Water System (LWS) well field. Arsenic data collected from the Platte River since 1974 were examined using the “weighted regression on time, discharge, and season” model, which compared the streamflow (also referred to as “discharge”), time of year, and season to estimate concentrations of arsenic. Annual mean arsenic concentrations modeled for more than 49 years at the Platte River at Louisville, Nebr., U.S. Geological Survey streamgage (station 06805500), indicated a significant increasing trend. Arsenic concentrations in the Platte River were seasonal, with the highest concentrations being observed during mid- to late summer. When seasonal patterns and streamflow were combined with arsenic concentrations in the Platte River during low streamflow conditions, groundwater contributions, which can have higher arsenic concentrations, make up a larger portion of the streamflow. Arsenic samples were collected from upstream rivers in 2022 and 2023 and were paired to analyze the arsenic contributions at the U.S. Geological Survey streamgage on the Platte River near Ashland, Nebr. (station 06801000), near the City of Lincoln well field. The arsenic concentrations from the streamgage on the Platte River near Ashland, Nebr., location, were higher than the U.S. Geological Survey streamgage on the Elkhorn River at Waterloo, Nebr. (station 06800500), and significantly lower than at the U.S. Geological Survey streamgage on the Platte River near Leshara, Nebr.(station 06796500), indicating that the Platte River usually contributes a higher concentration of arsenic than does the Elkhorn River as they join near Ashland, Nebr. During 1991–2023, six groundwater monitoring wells were analyzed to identify trends in arsenic concentrations. Two of the six wells had a positive trend during the 33-year period. One monitoring well did not reveal a long-term trend during this period but showed a trend during 2019–23, correlating to a period when the island in the middle of the Platte River was connected to the east bank of the river when manganese reducing conditions were present and groundwater levels were declining in the well. Across all wells the oxidation and reduction (redox) condition during the time of sampling was assessed. Mixed anoxic and (or) oxic redox condition was the most common redox process and the highest sampled arsenic concentrations in monitoring wells were observed in anoxic conditions driven by manganese reduction. Groundwater arsenic concentrations had seasonal variation around the City of Lincoln well field, with higher arsenic concentrations tending to be further south in comparison to samples collected further north. Isotope samples were collected and analyzed in surface water and groundwater around the LWS well field. The samples indicate that the proportion of surface water present in the LWS production wells can be higher in the spring and lower in the summer. With higher arsenic concentrations observed in the stream water during the summer period, the LWS source water can be affected by these elevated arsenic concentrations even though the proportion of surface water is lower.

Nebraska↗

Statistical methods in water resources

Preface This book began as class notes for a course we teach on applied statistical methods to hydrologists of the Water Resources Division, U. S. Geological Survey (USGS). It reflects our attempts to teach statistical methods which are appropriate for analysis of water resources data. As interest in this course has grown outside of the USGS, incentive grew to develop the material into a textbook. The topics covered are those we feel are of greatest usefulness to the practicing water resources scientist. Yet all topics can be directly applied to many other types of environmental data. This book is not a stand-alone text on statistics, or a text on statistical hydrology. For example, in addition to this material we use a textbook on introductory statistics in the USGS training course. As a consequence, discussions of topics such as probability theory required in a general statistics textbook will not be found here. Derivations of most equations are not presented. Important tables included in all general statistics texts, such as quantiles of the normal distribution, are not found here. Neither are details of how statistical distributions should be fitted to flood data -- these are adequately covered in numerous books on statistical hydrology. We have instead chosen to emphasize topics not always found in introductory statistics textbooks, and often not adequately covered in statistical textbooks for scientists and engineers. Tables included here, for example, are those found more often in books on nonparametric statistics than in books likely to have been used in college courses for engineers. This book points the environmental and water resources scientist to robust and nonparametric statistics, and to exploratory data analysis. We believe that the characteristics of environmental (and perhaps most other 'real') data drive analysis methods towards use of robust and nonparametric methods. Exercises are included at the end of chapters. In our course, students compute each type of analysis (t-test, regression, etc.) the first time by hand. We choose the smaller, simpler examples for hand computation. In this way the mechanics of the process are fully understood, and computer software is seen as less mysterious. We wish to acknowledge and thank several other scientists at the U. S. Geological Survey for contributing ideas to this book. In particular, we thank those who have served as the other instructors at the USGS training course. Ed Gilroy has critiqued and improved much of the material found in this book. Tim Cohn has contributed in several areas, particularly to the sections on bias correction in regression, and methods for data below the reporting limit. Richard Alexander has added to the trend analysis chapter, and Charles Crawford has contributed ideas for regression and ANOVA. Their work has undoubtedly made its way into this book without adequate recognition. Professor Ken Potter (University of Wisconsin) and Dr. Gary Tasker (USGS) reviewed the manuscript, spending long hours with no reward except the knowledge that they have improved the work of others. For that we are very grateful. We also thank Madeline Sabin, who carefully typed original drafts of the class notes on which the book is based. As always, the responsibility for all errors and slanted thinking are ours alone.

Techniques of Water-Resources Investigations↗

Shoals and valley plugs in the Hatchie River watershed

Agricultural land use and gully erosion have historically contributed more sediment to the streams of the Hatchie River watershed than those streams can carry. In 1970, the main sedimentation problem in the watershed occurred in the tributary flood plains. This problem motivated channelization projects (U.S. Department of Agriculture, 1970). By the mid-1980's, concern had shifted to sedimentation in the Hatchie River itself where channelized tributaries were understood to contribute much of the sediment. The Soil Conservation Service [Natural Resources Conservation Service (NRCS) since 1996] estimated that 640,000 tons of bedload (sand) accumulates in the Hatchie River each year and identified roughly the eastern two-thirds of the watershed, where loess is thin or absent, as the main source of sand (U.S. Department of Agriculture, 1986a). The U.S. Geological Survey (USGS), in cooperation with the West Tennessee River Basin Authority (WTRBA), conducted a study of sediment accumulation in the Hatchie River and its tributaries. This report identifies the types of tributaries and evaluates sediment, shoal formation, and valley-plug problems. The results presented here may contribute to a better understanding of similar problems in West Tennessee and the rest of the southeastern coastal plain. This information also will help the WTRBA manage sedimentation and erosion problems in the Hatchie River watershed. The source of the Mississippi section of the Hatchie River is in the sand hills southwest of Corinth, Mississippi (fig. 1). This section of the Hatchie River flows northward in an artificial drainage canal, gathering water from tributary streams that also are channelized. The drainage canal ends 2 miles south of the Tennessee State line. The Tennessee section of the Hatchie River winds north and west in a meandering natural channel to the Mississippi River. Although most of the Hatchie River tributaries are also drainage canals, the river's main stem has kept most of its natural character. The Hatchie River flows through a wide valley bottom occupied mostly by riverine wetland. Historically, the valley bottom has supported hardwood forests. Since publication of the first Hatchie River report (U.S. Department of Agriculture, 1970), the channel of the river has become shallower, and flooding has increased (U.S. Department of Agriculture 1986b). These wetter conditions inhibit growth of hardwoods and lead to premature hardwood mortality. The NRCS has predicted that despite efforts to control erosion in the uplands, most of the valley-bottom forest will die. '...swamping may be so prevalent as to change most of the Hatchie River Basin flood plain into a marsh condition, with the only remnants of the present bottomland hardwood timber remaining. (U.S. Department of Agriculture, 1986b). Loss of channel depth has been concentrated in short reaches near tributary mouths. At the mouths of Richland, Porters, Clover, and Muddy Creeks, navigation has become difficult for recreational users (Johnny Carlin, West Tennessee River Basin Authority, oral commun., 1998). As the low-gradient alluvial system of the Hatchie River accumulates sediment, another common outcome has been the formation of valley plugs, areas where 'channels are filled with sediment, and all the additional bedload brought downstream is then spread out over the flood plain until a new channel has been formed' (Happ, 1975). Valley plugs typically form where the slope of a sand-laden tributary decreases downstream, or where the tributary joins its parent stream (Happ and others, 1940; Diehl, 1994, 1997; Smith and Diehl, 2000).

Mississippi, Tennessee↗

Delineation of the Troy Bedrock Valley and particle-tracking analysis of ground-water flow underlying Belvidere, Illinois

The U.S. Geological Survey, U.S. Environmental Protection Agency, and Illinois Environmental Protection Agency began a study of the hydrogeology, flow system, and distribution of contaminants in the aquifers underlying Belvidere, Ill., and vicinity in 1992. As part of the study, the ancestral Troy Bedrock Valley, located about 1.5 miles west of Belvidere, was identified as an important part of the ground-water-flow system. In the deepest parts of the valley, the basal Glenwood confining unit may be absent; thick deposits of sand and gravel that infill part of the valley may directly overlie the sandstone St. Peter aquifer, a regionally important source of water for public supply. With few deep wells open to the St. Peter aquifer present in the valley to provide necessary geologic information, tritium and other water-chemistry data were collected from eight wells to possibly delineate areas where the confining unit may be absent; the data also provide baseline water-quality information for an area expecting changes in land use and increases in water withdrawal. Also as part of the study, particle-tracking analysis was done using an available flow model to (1) identify possible discharge locations of ground water and contaminants and (2) delineate areas contributing recharge to the Belvidere municipal wells. This report presents and interprets water-chemistry data collected during December 2000 and presents results of particle-tracking analysis. Ground water in samples from two of four wells open to the St. Peter aquifer appears to have recharged after 1954, suggesting that the Glenwood confining unit may be absent near the wells. Other hydrogeologic and water-chemistry data, however, were inconclusive or contradictory. Concentrations of iron, manganese, and lead exceeded maximum contaminant levels in five or less samples, but materials associated with the water-distribution systems appear to contribute to the elevated concentrations above natural levels. Particle-tracking analysis indicates that most ground-water flow beneath possible contaminant-source areas discharges from the glacial drift aquifer to the Kishwaukee River. Most of the source areas are in or near Belvidere and are within 1,500 feet of the river. The analysis also indicates the possibility that in parts of the study area, some ground water does not discharge to the river, but flows beneath the Kishwaukee River in the underlying carbonate Galena-Platteville aquifer. Ground water that discharges to the one municipal well open to the glacial drift aquifer is estimated to travel over 1 mile in less than 25 years. Simulated residence (travel) times of ground water from the base of the glacial drift aquifer to the six municipal wells open, in part, to the Galena-Platteville aquifer, are estimated at less than about 40 years. Because fractures in this aquifer are unaccounted for in the flow model, actual areas contributing recharge are likely larger and travel times faster than those simulated for most of the municipal wells. Tritium data indicate that, in general, travel times from the land surface to the deepest parts of the Galena-Platteville aquifer are less than 46 years. Methyl tertiary-butyl ether data indicate that travel times to the upper part of the aquifer may be less than 16 years. The water-quality-based estimates of travel time generally are consistent with the estimates from particle-tracking analysis.

Illinois↗

Streamflow and nutrient data for the Yazoo River below Steele Bayou near Long Lake, Mississippi, 1996-2000

Increased nutrient loading to the Gulf of Mexico from off-continent flux has been identified as contributing to the increase in the areal extent of the low dissolved-oxygen zone that develops annually off the Louisiana and Texas coast. The proximity of the Yazoo River Basin in northwestern Mississippi to the Gulf of Mexico, and the intensive agricultural activities in the basin have led to speculation that the Yazoo River Basin contributes a disproportionate amount of nitrogen and phosphorus to the Mississippi River and ultimately to the Gulf of Mexico. An empirical measurement of the flux of nitrogen and phosphorus from the Yazoo Basin has not been possible due to the hydrology of the lower Yazoo River Basin. Streamflow for the Yazoo River below Steele Bayou is affected by backwater from the Mississippi River. Flow at the gage is non-uniform and varying, with bi-directional and reverse flows possible. Streamflow was computed by using remote sensing and acoustic and conventional discharge and velocity measurement techniques. Streamflow from the Yazoo River for the 1996-2000 period accounted for 2.8 percent of the flow of the Mississippi River for the same period. Water samples from the Yazoo River were collected from February 1996 through December 2000 and were analyzed for total nitrogen, nitrate, total phosphorus, and orthophosphorus as part of the U.S. Geological Survey National Water-Quality Assessment Program. These data were used to compute annual loads of nitrogen and phosphorus discharged from the Yazoo River for the period 1996-2000. Annual loads of nitrogen and phosphorus were calculated by two methods. The first method used multivariate regression and the second method multiplied the mean annual concentration by the total annual flow. Load estimates based on the product of the mean annual concentration and the total annual flow were within the 95 percent confidence interval for the load calculated by multivariate regression in 10 of 20 cases. The Yazoo River loads, compared to average annual loads in the Mississippi River, indicated that the Yazoo River was contributing 1.4 percent of the total nitrogen load, 0.7 percent of the nitrate load, 3.4 percent of the total phosphorus load, and 1.6 percent of the orthophosphorus load during 1996 - 2000. The total nitrogen, nitrate, and orthophosphorus loads in the Yazoo River Basin were less than expected, whereas the total phosphorus load was slightly higher than expected based on discharge.

Water-Resources Investigations Report↗

Nitrogen and phosphorus in streams of the Great Miami River Basin, Ohio, 1998–2000

Sources and loads of nitrogen and phosphorus in streams of the Great Miami River Basin were evaluated as part of the National Water-Quality Assessment program. Water samples were collected by the U.S. Geological Survey from October 1998 through September 2000 (water years 1999 and 2000) at five locations in Ohio on a routine schedule and additionally during selected high streamflows. Stillwater River near Union, Great Miami River near Vandalia, and Mad River near Eagle City were selected to represent predominantly agricultural areas upstream from the Dayton metropolitan area. Holes Creek near Kettering is in the Dayton metropolitan area and was selected to represent an urban area in the Great Miami River Basin. Great Miami River at Hamilton is downstream from the Dayton and Hamilton-Middletown metropolitan areas and was selected to represent mixed agricultural and urban land uses of the Great Miami River Basin. Inputs of nitrogen and phosphorus to streams from point and nonpoint sources were estimated for the three agricultural basins and for the Great Miami River Basin as a whole. Nutrient inputs from point sources were computed from the facilities that discharge one-half million gallons or more per day into streams of the Great Miami River Basin. Nonpoint-source inputs estimated in this report are atmospheric deposition and commercial-fertilizer and manure applications. Loads of ammonia, nitrate, total nitrogen, orthophosphate, and total phosphorus from the five sites were computed with the ESTIMATOR program. The computations show nitrate to be the primary component of instream nitrogen loads, and particulate phosphorus to be the primary component of instream phosphorus loads. The Mad River contributed the smallest loads of total nitrogen and total phosphorus to the study area upstream from Dayton, whereas the Upper Great Miami River (upstream from Vandalia) contributed the largest loads of total nitrogen and total phosphorus to the Great Miami River Basin upstream from Dayton. An evaluation of monthly mean loads shows that nutrient loads were highest during winter 1999 and lowest during the drought of summer and autumn 1999. During the 1999 drought, point sources were the primary contributors of nitrogen and phosphorus loads to most of the study area. Nonpoint sources, however, were the primary contributors of nitrogen and phosphorus loads during months of high streamflow. Nonpoint sources were also the primary contributors of nitrogen loads to the Mad River during the 1999 drought, owing to unusually large amounts of ground-water discharge to the stream. The Stillwater River Basin had the highest nutrient yields in the study area during months of high streamflow; however, the Mad River Basin had the highest yields of all nutrients except ammonia during the months of the 1999 drought. The high wet-weather yields in the Stillwater River Basin were caused by agricultural runoff, whereas high yields in the Mad River Basin during drought resulted from the large, sustained contribution of ground water to streamflow throughout the year. In the basins upstream from Dayton, an estimated 19 to 25 percent of the nonpoint source of nitrogen and 4 to 5 percent of the nonpoint source of phosphorus that was deposited or applied to the land was transported into streams.

Ohio↗

A stream-gaging network analysis for the 7-day, 10-year annual low flow in New Hampshire streams

The 7-day, 10-year (7Q10) low-flow-frequency statistic is a widely used measure of surface-water availability in New Hampshire. Regression equations and basin-characteristic digital data sets were developed to help water-resource managers determine surface-water resources during periods of low flow in New Hampshire streams. These regression equations and data sets were developed to estimate streamflow statistics for the annual and seasonal low-flow-frequency, and period-of-record and seasonal period-of-record flow durations. generalized-least-squares (GLS) regression methods were used to develop the annual 7Q10 low-flow-frequency regression equation from 60 continuous-record stream-gaging stations in New Hampshire and in neighboring States. In the regression equation, the dependent variables were the annual 7Q10 flows at the 60 stream-gaging stations. The independent (or predictor) variables were objectively selected characteristics of the drainage basins that contribute flow to those stations. In contrast to ordinary-least-squares (OLS) regression analysis, GLS-developed estimating equations account for differences in length of record and spatial correlations among the flow-frequency statistics at the various stations. A total of 93 measurable drainage-basin characteristics were candidate independent variables. On the basis of several statistical parameters that were used to evaluate which combination of basin characteristics contribute the most to the predictive power of the equations, three drainage-basin characteristics were determined to be statistically significant predictors of the annual 7Q10: (1) total drainage area, (2) mean summer stream-gaging station precipitation from 1961 to 90, and (3) average mean annual basinwide temperature from 1961 to 1990. To evaluate the effectiveness of the stream-gaging network in providing regional streamflow data for the annual 7Q10, the computer program GLSNET (generalized-least-squares NETwork) was used to analyze the network by application of GLS regression between streamflow and the climatic and basin characteristics of the drainage basin upstream from each stream-gaging station. Improvement to the predictive ability of the regression equations developed for the network analyses is measured by the reduction in the average sampling-error variance, and can be achieved by collecting additional streamflow data at existing stations. The predictive ability of the regression equations is enhanced even further with the addition of new stations to the network. Continued data collection at unregulated stream-gaging stations with less than 14 years of record resulted in the greatest cost-weighted reduction to the average sampling-error variance of the annual 7Q10 regional regression equation. The addition of new stations in basins with underrepresented values for the independent variables of the total drainage area, average mean annual basinwide temperature, or mean summer stream-gaging station precipitation in the annual 7Q10 regression equation yielded a much greater cost-weighted reduction to the average sampling-error variance than when more data were collected at existing unregulated stations. To maximize the regional information obtained from the stream-gaging network for the annual 7Q10, ranking of the streamflow data can be used to determine whether an active station should be continued or if a new or discontinued station should be activated for streamflow data collection. Thus, this network analysis can help determine the costs and benefits of continuing the operation of a particular station or activating a new station at another location to predict the 7Q10 at ungaged stream reaches. The decision to discontinue an existing station or activate a new station, however, must also consider its contribution to other water-resource analyses such as flood management, water quality, or trends in land use or climatic change.

Water-Resources Investigations Report↗

Patterns and sources of fecal coliform bacteria in three streams in Virginia, 1999-2000

Surface-water impairment by fecal coliform bacteria is a water-quality issue of national scope and importance. In Virginia, more than 175 stream segments are on the Commonwealth's 1998 303(d) list of impaired waters because of elevated concentrations of fecal coliform bacteria. These fecal coliform-impaired stream segments require the development of total maximum daily load (TMDL) and associated implementation plans, but accurate information on the sources contributing these bacteria usually is lacking. The development of defendable fecal coliform TMDLs and management plans can benefit from reliable information on the bacteria sources that are responsible for the impairment. Bacterial source tracking (BST) recently has emerged as a powerful tool for identifying the sources of fecal coliform bacteria that impair surface waters. In a demonstration of BST technology, three watersheds on Virginia's 1998 303(d) list with diverse land-use practices (and potentially diverse bacteria sources) were studied. Accotink Creek is dominated by urban land uses, Christians Creek by agricultural land uses, and Blacks Run is affected by both urban and agricultural land uses. During the 20-month field study (March 1999?October 2000), water samples were collected from each stream during a range of flow conditions and seasons. For each sample, specific conductance, dissolved oxygen concentration, pH, turbidity, flow, and water temperature were measured. Fecal coliform concentrations of each water sample were determined using the membrane filtration technique. Next, Escherichia coli (E. coli) were isolated from the fecal coliform bacteria and their sources were identified using ribotyping (a method of 'genetic fingerprinting'). Study results provide enhanced understanding of the concentrations and sources of fecal coliform bacteria in these three watersheds. Continuum sampling (sampling along the length of the streams) indicated that elevated concentrations of fecal coliform bacteria (maximum observed concentration of 290,000 colonies/100 milliliters (col/100mL) could occur along the entire length of each stream, and that the samples collected at the downstream monitoring station of each stream were generally representative of the entire upstream reach. Seasonal patterns were observed in the base-flow fecal coliform concentrations of all streams; concentrations were typically highest in the summer and lowest in the winter. Fecal coliform concentrations were lowest during periods of base flow (typically 200?2,000 col/100mL) and increased by 3?4 orders of magnitude during storm events (as high as 700,000 col/100mL). Multiple linear regression models were developed to predict fecal coliform concentrations as a function of streamflow and other water-quality parameters. The source tracking technique provided identification of bacteria contributions from diverse sources that included (but were not limited to) humans, cattle, poultry, horses, dogs, cats, geese, ducks, raccoons, and deer. Seasonal patterns were observed in the contributions of cattle and poultry sources. There were relations between the identified sources of fecal coliform bacteria and the land-use practices within each watershed. There were only minor differences in the distribution of bacteria sources between low-flow periods and high-flow periods. A coupled approach that utilized both a large available source library and a smaller, location-specific source library provided the most success in identifying the unknown E. coli isolates. BST data should provide valuable support and guidance for producing more defendable and scientifically rigorous watershed models. Incorporation of these bacteria-source data into watershed management strategies also should result in the selection of more efficient source-reduction scenarios for improving water quality.

Water-Resources Investigations Report↗

Simulation of ground-water flow and rainfall runoff with emphasis on the effects of land cover, Whittlesey Creek, Bayfield County, Wisconsin, 1999-2001

The effects of land cover on flooding and base-flow characteristics of Whittlesey Creek, Bayfield County, Wis., were examined in a study that involved ground-water-flow and rainfall-runoff modeling. Field data were collected during 1999-2001 for synoptic base flow, streambed head and temperature, precipitation, continuous streamflow and stream stage, and other physical characteristics. Well logs provided data for potentiometric-surface altitudes and stratigraphic descriptions. Geologic, soil, hydrography, altitude, and historical land-cover data were compiled into a geographic information system and used in two ground-water-flow models (GFLOW and MODFLOW) and a rainfall-runoff model (SWAT). A deep ground-water system intersects Whittlesey Creek near the confluence with the North Fork, producing a steady base flow of 17?18 cubic feet per second. Upstream from the confluence, the creek has little or no base flow; flow is from surface runoff and a small amount of perched ground water. Most of the base flow to Whittlesey Creek originates as recharge through the permeable sands in the center of the Bayfield Peninsula to the northwest of the surface-water-contributing basin. Based on simulations, model-wide changes in recharge caused a proportional change in simulated base flow for Whittlesey Creek. Changing the simulated amount of recharge by 25 to 50 percent in only the ground-water-contributing area results in relatively small changes in base flow to Whittlesey Creek (about 2?11 percent). Simulated changes in land cover within the Whittlesey Creek surface-water-contributing basin would have minimal effects on base flow and average annual runoff, but flood peaks (based on daily mean flows on peak-flow days) could be affected. Based on the simulations, changing the basin land cover to a reforested condition results in a reduction in flood peaks of about 12 to 14 percent for up to a 100-yr flood. Changing the basin land cover to 25 percent urban land or returning basin land cover to the intensive row-crop agriculture of the 1920s results in flood peaks increasing by as much as 18 percent. The SWAT model is limited to a daily time step, which is adequate for describing the surface-water/ground-water interaction and percentage changes. It may not, however, be adequate in describing peak flow because the instantaneous peak flow in Whittlesey Creek during a flood can be more than twice the magnitude of the daily mean flow during that same flood. In addition, the storage and infiltration capacities of wetlands in the basin are not fully understood and need further study.

Wisconsin↗

Use of the Hydrological Simulation Program-FORTRAN and bacterial source tracking for development of the fecal coliform total maximum daily load (TMDL) for Accotink Creek, Fairfax County, Virginia

Impairment of surface waters by fecal coliform bacteria is a water-quality issue of national scope and importance. Section 303(d) of the Clean Water Act requires that each State identify surface waters that do not meet applicable water-quality standards. In Virginia, more than 175 stream segments are on the 1998 Section 303(d) list of impaired waters because of violations of the water-quality standard for fecal coliform bacteria. A total maximum daily load (TMDL) will need to be developed by 2006 for each of these impaired streams and rivers by the Virginia Departments of Environmental Quality and Conservation and Recreation. A TMDL is a quantitative representation of the maximum load of a given water-quality constituent, from all point and nonpoint sources, that a stream can assimilate without violating the designated water-quality standard. Accotink Creek, in Fairfax County, Virginia, is one of the stream segments listed by the State of Virginia as impaired by fecal coliform bacteria. Watershed modeling and bacterial source tracking were used to develop the technical components of the fecal coliform bacteria TMDL for Accotink Creek. The Hydrological Simulation Program-FORTRAN (HSPF) was used to simulate streamflow, fecal coliform concentrations, and source-specific fecal coliform loading in Accotink Creek. Ribotyping, a bacterial source tracking technique, was used to identify the dominant sources of fecal coliform bacteria in the Accotink Creek watershed. Ribotyping also was used to determine the relative contributions of specific sources to the observed fecal coliform load in Accotink Creek. Data from the ribotyping analysis were incorporated into the calibration of the fecal coliform model. Study results provide information regarding the calibration of the streamflow and fecal coliform bacteria models and also identify the reductions in fecal coliform loads required to meet the TMDL for Accotink Creek. The calibrated streamflow model simulated observed streamflow characteristics with respect to total annual runoff, seasonal runoff, average daily streamflow, and hourly stormflow. The calibrated fecal coliform model simulated the patterns and range of observed fecal coliform bacteria concentrations. Observed fecal coliform bacteria concentrations during low-flow periods ranged from 25 to 800 colonies per 100 milliliters, and peak concentrations during storm-flow periods ranged from 19,000 to 340,000 colonies per 100 milliliters. Simulated source-specific contributions of fecal coliform bacteria to instream load were matched to the observed contributions from the dominant sources, which were cats, deer, dogs, ducks, geese, humans, muskrats, and raccoons. According to model results, an 89-percent reduction in the current fecal coliform load delivered from the watershed to Accotink Creek would result in compliance with the designated water-quality goals and associated TMDL.

Virginia↗

Use of the Hydrological Simulation Program-FORTRAN and bacterial source tracking for development of the fecal coliform total maximum daily load (TMDL) for Blacks Run, Rockingham County, Virginia

Impairment of surface waters by fecal coliform bacteria is a water-quality issue of national scope and importance. Section 303(d) of the Clean Water Act requires that each State identify surface waters that do not meet applicable water-quality standards. In Virginia, more than 175 stream segments are on the 1998 Section 303(d) list of impaired waters because of violations of the water-quality standard for fecal coliform bacteria. A total maximum daily load (TMDL) will need to be developed by 2006 for each of these impaired streams and rivers by the Virginia Departments of Environmental Quality and Conservation and Recreation. A TMDL is a quantitative representation of the maximum load of a given water-quality constituent, from all point and nonpoint sources, that a stream can assimilate without violating the designated water-quality standard. Blacks Run, in Rockingham County, Virginia, is one of the stream segments listed by the State of Virginia as impaired by fecal coliform bacteria. Watershed modeling and bacterial source tracking were used to develop the technical components of the fecal coliform bacteria TMDL for Accotink Creek. The Hydrological Simulation Program-FORTRAN (HSPF) was used to simulate streamflow, fecal coliform concentrations, and source-specific fecal coliform loading in Blacks Run. Ribotyping, a bacterial source tracking technique, was used to identify the dominant sources of fecal coliform bacteria in the Blacks Run watershed. Ribotyping also was used to determine the relative contributions of specific sources to the observed fecal coliform load in Blacks Run. Data from the ribotyping analysis were incorporated into the calibration of the fecal coliform model. Study results provide information regarding the calibration of the streamflow and fecal coliform bacteria models and also identify the reductions in fecal coliform loads required to meet the TMDL for Blacks Run. The calibrated streamflow model simulated observed streamflow characteristics with respect to total annual runoff, seasonal runoff, average daily streamflow, and hourly stormflow. The calibrated fecal coliform model simulated the patterns and range of observed fecal coliform bacteria concentrations. Observed fecal coliform bacteria concentrations during low-flow periods ranged from 40 to 7,000 colonies per 100 milliliters, and peak concentrations during storm-flow periods ranged from 33,000 to 260,000 colonies per 100 milliliters. Simulated source-specific contributions of fecal coliform bacteria to instream load were matched to the observed contributions from the dominant sources, which were cats, cattle, deer, dogs, ducks, geese, horses, humans, muskrats, poultry, raccoons, and sheep. According to model results, a 95-percent reduction in the current fecal coliform load delivered from the watershed to Blacks Run would result in compliance with the designated water-quality goals and associated TMDL.

Virginia↗

Use of the Hydrological Simulation Program-FORTRAN and bacterial source tracking for development of the fecal coliform total maximum daily load (TMDL) for Christians Creek, Augusta County, Virginia

Impairment of surface waters by fecal coliform bacteria is a water-quality issue of national scope and importance. Section 303(d) of the Clean Water Act requires that each State identify surface waters that do not meet applicable water-quality standards. In Virginia, more than 175 stream segments are on the 1998 Section 303(d) list of impaired waters because of violations of the water-quality standard for fecal coliform bacteria. A total maximum daily load (TMDL) will need to be developed by 2006 for each of these impaired streams and rivers by the Virginia Departments of Environmental Quality and Conservation and Recreation. A TMDL is a quantitative representation of the maximum load of a given water-quality constituent, from all point and nonpoint sources, that a stream can assimilate without violating the designated water-quality standard. Christians Creek, in Augusta County, Virginia, is one of the stream segments listed by the State of Virginia as impaired by fecal coliform bacteria. Watershed modeling and bacterial source tracking were used to develop the technical components of the fecal coliform bacteria TMDL for Christians Creek. The Hydrological Simulation Program-FORTRAN (HSPF) was used to simulate streamflow, fecal coliform concentrations, and source-specific fecal coliform loading in Christians Creek. Ribotyping, a bacterial source tracking technique, was used to identify the dominant sources of fecal coliform bacteria in the Christians Creek watershed. Ribotyping also was used to determine the relative contributions of specific sources to the observed fecal coliform load in Christians Creek. Data from the ribotyping analysis were incorporated into the calibration of the fecal coliform model. Study results provide information regarding the calibration of the streamflow and fecal coliform bacteria models and also identify the reductions in fecal coliform loads required to meet the TMDL for Christians Creek. The calibrated streamflow model simulated observed streamflow characteristics with respect to total annual runoff, seasonal runoff, average daily streamflow, and hourly stormflow. The calibrated fecal coliform model simulated the patterns and range of observed fecal coliform bacteria concentrations. Observed fecal coliform bacteria concentrations during low-flow periods ranged from 40 to 2,000 colonies per 100 milliliters, and peak concentrations during stormflow periods ranged from 23,000 to 730,000 colonies per 100 milliliters. Additionally, fecal coliform bacteria concentrations were generally higher upstream and lower downstream. Simulated source-specific contributions of fecal coliform bacteria to instream load were matched to the observed contributions from the dominant sources, which were beaver, cats, cattle, deer, dogs, ducks, geese, horses, humans, muskrats, poultry, raccoons, and sheep. According to model results, a 96-percent reduction in the current fecal coliform load delivered from the watershed to Christians Creek would result in compliance with the designated water-quality goals and associated TMDL.

Virginia↗

Flood-frequency prediction methods for unregulated streams of Tennessee, 2000

Up-to-date flood-frequency prediction methods for unregulated, ungaged rivers and streams of Tennessee have been developed. Prediction methods include the regional-regression method and the newer region-of-influence method. The prediction methods were developed using stream-gage records from unregulated streams draining basins having from 1 percent to about 30 percent total impervious area. These methods, however, should not be used in heavily developed or storm-sewered basins with impervious areas greater than 10 percent. The methods can be used to estimate 2-, 5-, 10-, 25-, 50-, 100-, and 500-year recurrence-interval floods of most unregulated rural streams in Tennessee. A computer application was developed that automates the calculation of flood frequency for unregulated, ungaged rivers and streams of Tennessee. Regional-regression equations were derived by using both single-variable and multivariable regional-regression analysis. Contributing drainage area is the explanatory variable used in the single-variable equations. Contributing drainage area, main-channel slope, and a climate factor are the explanatory variables used in the multivariable equations. Deleted-residual standard error for the single-variable equations ranged from 32 to 65 percent. Deleted-residual standard error for the multivariable equations ranged from 31 to 63 percent. These equations are included in the computer application to allow easy comparison of results produced by the different methods. The region-of-influence method calculates multivariable regression equations for each ungaged site and recurrence interval using basin characteristics from 60 similar sites selected from the study area. Explanatory variables that may be used in regression equations computed by the region-of-influence method include contributing drainage area, main-channel slope, a climate factor, and a physiographic-region factor. Deleted-residual standard error for the region-of-influence method tended to be only slightly smaller than those for the regional-regression method and ranged from 27 to 62 percent.

Tennessee↗

Present and potential sediment yields in the Yampa River Basin, Colorado and Wyoming

Average annual suspended- and total-sediment loads in streamflow were determined by the flow-duration sediment-transport-curve method at 18 sites in the Yampa River basin, Colorado and Wyoming. These computations indicate that about 2.0 million tons of sediment are carried by the Yampa River at Deerlodge Park during an average year. Significant areal differences in the sediment yield from various parts of the basin also were determined. The lower Little Snake River subbasin contributes about 60 percent of the total basin sediment yield, although it represents less than 35 percent of the area and supplies less than 3 percent of the streamflow. In contrast, the upland (eastern) one-third of the basin contributes only about 14 percent of the sediment yield but 76 percent of the streamflow. Projected economic development of the basin, especially surface mining of coal, will impact the physical environment. Depending upon the amount and location of land disturbed, an estimated 10 ,000 to 30,000 tons per year of additional sediment will be contributed to the main-stem Yampa River. (Woodard-USGS)

Water-Resources Investigations Report↗

Hydrology and water quality in the Nederlo Creek Basin, Wisconsin, before construction of two water-retention structures

The Nederlo Creek basin, in the "Driftless Area" of southwest Wisconsin, is geographically and hydrologically similar to other small basins in the area. Topography is rugged, with approximately 400 feet of relief between the boundary ridge tops and the valley floor. The water-retention structures (a dry floodwater- retention structure and a 43-acre reservoir) are to provide recreation and flood protection for the basin. Streamflow, springflow, precipitation, and groundwater levels were monitored at several sites to describe the hydrologic system. Streamflow is fairly constant at base flow, but rapid changes in discharge occur during periods of snowmelt or heavy rain; recession to base-flow discharge following these events is rapid. Surface runoff is a significant contributor to Streamflow only 10 percent of the time. The mean annual hydrologic budget for water years 1968-72 shows that of the 32.5 inches of precipitation on the basin, 6.4 inches left as runoff and 25.9 inches as evapotranspiration; ground-water storage increased an average of 0.2 inches per year. The water is a hard calcium magnesium bicarbonate type. Concentrations of major constituents in ground water and streams at base flow are similar, but concentrations in the stream generally decrease during periods when surface runoff contributes to Streamflow. Dissolved-oxygen concentrations in the stream are generally lowest during the summer; nighttime lows are generally between 7 and 8 milligrams per liter and daily maximums between 11 and 12.5 milligrams per liter. Diurnal water-temperature fluctuations of several degrees are common in streams during summer; daily maximum water temperatures as high as 26°C have been measured in some areas, but temperatures this high seldom persist for more than 2 hours. Estimates of mean annual total phosphorus and total nitrogen loads during 1967-74 fall within the ranges of 0.02 to 0.07 and 0.4 to 0.8 tons per square mile, respectively; 70 to 80 percent of the total phosphorus and 35 to 55 percent of the total nitrogen are transported during periods when surface runoff contributes to Streamflow. Mean annual suspended-sediment loads during 1968-74 range from 13 to 60 tons per square mile, with 74 to 86 percent of the total transported during periods when surface water contributes to streamflow. These sediment loads are at the low end of the range previously reported for streams in the "Driftless Area".

Wisconsin↗

Effects of storm runoff on water quality in the Mill Creek drainage basin, Willingboro, New Jersey

The effect of storm runoff on the quality of water in the the Mill Creek drainage basin in west-central New Jersey is described in this report. The study area (23.7 square kilometers) consists of agricultural and undeveloped land and the residential community of Willingboro. From October 1975 to September 1976, stream discharge and 86 water-quality constituents were measured during five base flows and five storms at nine sites within the basin. Only 38 of the measured consitituents were detected in significant amounts. Insignificant amounts of pesticides, except 2,4-D and silvex, and the metals cadmium, chromium, cobalt, copper, mercury, selenium, and carbonate were measured even during heavy runoff. All other constituents showed an increase in concentration with increasing streamflow and the corresponding loads usually correlated with streamflow. Runoff from the nonresidential part of the study area in the upstream part of the drainage basin had a more significant impact on the stream quality than did the runoff from the residential area. The nonresidential area contributed more nutrients, common inorganics, sediment, and organic carbon than the residential area. The residential area contributed more calcium, nitrite, lead, iron, BOD, 2,4-D, and silvex. With the exception of suspended iron, fecal coliform bacteria, suspended lead, and suspended phosphorus, all recorded concentrations under all streamflow conditions met the recommended limits set by the U.S. Environmental Protection Agency and the New Jersey Department of Environmental Protection for domestic water supplies or streams not discharging directly into a lake or reservoir. Very short-term exceptions were recorded during peak storm runoff. Iron concentrations exceeded recommended limits of the U.S. Environmental Protection Agency. Occasional releases of suspended iron from the water-treatment plant in the lower part of the drainage basin contributed to this high concentration. However, Mill Creek and its tributaries will still have naturally occurring high suspended iron concentrations even after the water-treatment plant eliminates its sludge-holding pond. Fecal coliform bacteria affected the quality of water in the Mill Creek basin more than any other constituent measured. It exceeded recommended limits by as much as two orders of magnitude and was found in equal amounts throughout the streams in the basin. The source of the bacteria could not be identified. Runoff from the Willingboro residential area produced mean suspended lead concentrations up to three times greater than the 50 micrograms per liter criteria set for domestic water supplies. Mean concentrations of suspended phosphorus throughout the basin were 2.5 times greater than the recommended limit of 0.1 milligrams per liter. Sediment concentrations and loads increased with increasing streamflow. However, the amounts are not considered unusual for a developed area. The only sediment deposition occurred at the downstream end of the study area, which is slightly affected by tide. A significant part of the deposited material was composed of sludge material from the water-treatment plant in the lower end of the study area.

New Jersey↗

Sources and concentrations of dissolved solids and selenium in the San Joaquin River and its tributaries, California, October 1985 to March 1987

Sources and concentrations of dissolved solids and selenium in the San Joaquin River and its tributaries, California, were assessed by a mass-balance approach to determine the effects of tile-drain water and irrigation-return flows on the river. The study included low-flow periods from October 1985 to mid-February 1986 and mid-May 1986 through March 1987, and a high-flow period from mid-February to mid-May 1985. During the combined low-flow period, the dissolved-solids load from eastside tributaries and the upper San Joaquin River accounted for only 18% of the total load at Vernalis, located farthest downstream, even though they accounted for 71% of the streamflow. Salt and Mud Sloughs contributed 40% of the dissolved-solids load but only 9% of streamflow. Unmeasured sources of dissolved solids contributed about 42% of the total load during low flow. In contrast, Salt and Mud Sloughs, which receive most of the tile-drain water that enters the river, contributed almost 80% of the total selenium load to the river, and loading of selenium concentrations were highest in Salt and Mud Sloughs and decreased downstream in the San Joaquin River with dilution from eastside tributaries. A State standard for dissolved solids of 500 mg/L was exceeded 11% of the time in the San Joaquin River at Vernalis. The U.S. Environmental Protection Agency 's 4-day average aquatic-life criterion of 5 micrograms/L of selenium was exceeded in more than 60% of the samples from the sloughs and in about 20% of the samples from the San Joaquin River, just downstream of the Merced River. (USGS)

Water-Resources Investigations Report↗

Geohydrology and water quality of stratified-drift aquifers in the lower Merrimack and coastal river basins, southeastern New Hampshire

Communities in the lower Merrimack River basin and coastal river basins of southeastern New Hampshire are experiencing increased demands for water because of a rapid increase in population. The population in 1987 was 225,495 and is expected to increase by 30 percent during the next decade. As of 1987, five towns used the stratified-drift aquifers for municipal supply and withdrew an estimated 6 million gallons per day. Four towns used the bedrock aquifer for municipal supply and withdrew an average of 1 .6 million gallons per day. Stratified-drift deposits cover 78 of the 327 square miles of the study area. These deposits are generally less than 10 square miles in areal extent, and their saturated thickness ranges front less than 20 feet to as much as 100 feet. Transmissivity exceeds 4,000 square feet per day in several locations. Stratified-drift aquifers in the eastern part are predominantly small ice-contact deposits surrounded by marine sediments or till of low hydraulic conductivity. Stratified-drift aquifers in the western part consist of ice-contact and proglacial deposits that are large in areal extent and are commonly in contact with surface-water bodies. Five stratified-drift aquifers, in the towns of Derry, Windham, Kingston, North Hampton, and Greenland, have the greatest potential to supply additional amounts of water. Potential yields and contributing areas of hypothetical supply wells were estimated for an aquifer in Windham near Cobbetts Pond and for an aquifer in Kingston along the Powwow River by use of a method analogous to superposition in conjunction with a numerical ground-waterflow model. The potential yield is estimated to be 0 .6 million gallons per day for the Windham-Cobbetts Pond aquifer and 4 .0 million gallons per day for the Kingston-Powwow River aquifer. Contributing recharge area for supply wells is estimated to be 1.6 square miles in the Windham-Cobbetts Pond aquifer and 4.9 square miles in the Kingston-Powwow River aquifer. Analyses of water samples from 30 wells indicate that the water quality in the basins studied is generally suitable for drinking and other domestic purposes. Concentrations of iron and manganese exceeded the U.S. Environmental Protection Agency's (USEPA) and the New Hampshire Water Supply Engineering Bureau's secondary maximum contaminant levels for drinking water in 20 samples. With one exception, concentrations of volatile organic compounds at all wells sampled met New Hampshire Water Supply and Engineering Bureau's drinking-water standards. At one well, trichloroethylene was detected at a concentration of 5.7 micrograms per liter. Ground-water contamination has been detected at several hazardous-waste sites in the study area. Currently, 5 sites are on the USEPA's National Priority List of superfund sites, 10 sites are Resource Conservation and Recovery Act of 1976 sites, and 1 site is a Department of Defense hazardous-waste site of stratigraphic layers is a product of a material's density and the velocity at which sound travels through that material. The reflected signals return to the hydrophones at the water surface and are then filtered, amplified, and displayed graphically on the chart recorder to allow interpretation of aquifer stratigraphy and bedrock depths. Lithologic data from nearby wells and test holes were used as control points to check the interpretation of the reflection profiles. Test drilling was done at 66 locations (pls. 1-3) to determine sediment grain size, stratigraphy, depth to water table, depth to bedrock, and ground water quality. A 6-inch-diameter, hollow-stem auger was used for test drilling. Split-spoon samples of subsurface materials collected at specific depths were used to evaluate the grain-size characteristics and identify the stratigraphic sequence of materials comprising the aquifers. Thirty-eight test holes cased with a 2-inch-diameter polyvinyl-chloride (PVC) pipe and slotted screens were used to make ground-water-level measurements and collect ground-water-quality samples. Surface-water-discharge measurements were made at 16 sites during low flow when the surface water is primarily ground-water discharge. These low-flow measurements indicate quantities of ground water potentially available from aquifers. Hydraulic conductivities of aquifer materials were estimated from grain-size-distribution data from 61 samples of stratified drift. Transmissivity was estimated from well logs by assigning hydraulic conductivity to specific well-log intervals, multiplying by the saturated thickness of the interval, and summing the results. Additional transmissivity values were obtained from an analysis of specific capacity and aquifer-test data. Long-term aquifer yields and contributing areas to hypothetical supply wells were estimated by application of a method that is analogous to super position and incorporates a ground-water-flow model developed by McDonald and Harbaugh (1988). This method was applied to two aquifers judged to have the best potential for providing additional ground-water supplies. Samples of ground water from 26 test wells and 4 municipal wells were collected in March and August 1987 for analysis of common inorganic, organic, and volatile organic constituents. Methods for collecting and analyzing the samples are described by Fishman and Freidman (1989). The water-quality results from the well samples were used to characterize background water quality in the stratified-drift aquifers.

New Hampshire↗