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At least 1,171 records · Page 65Linked to original sources

Scouting craton’s edge in Paleo-Pacific Gondwana

The geology of the ice-covered interior of the East Antarctic shield is completely unknown; inferences about its composition and history are based on extrapolating scant outcrops from the coast inland. Although the shield is clearly composite in nature, a large part of its interior has been represented by a single Precambrian block, termed the Mawson block, that includes the Archean-Mesoproterozoic Gawler and Curnamona cratons of Australia. In Australia, the Mawson block is bounded on the east by Neoproterozoic sedimentary rocks and the superimposed early Paleozoic Delamerian Orogen, marked by curvilinear belts of arc plutons, and on the west by the unexposed Coompana block and Mesoproterozoic Albany-Fraser mobile belt. In Antarctica, these crustal elements are inferred to extend across Wilkes Land and south to the Miller Range region. Aero- and satellite magnetic data provide a means to see through the ice, helping to elucidate the broad composition of the shield. Rocks of the Mawson block in Australia produce distinctive magnetic anomalies; Paleoproterozoic granites and Meso- to Neoproterozoic mafic igneous rocks are associated with high-amplitude, broad-wavelength positive aero- and satellite-magnetic anomalies. The same types of magnetic anomalies can be traced to ice-covered Wilkes Land, Antarctica, and are interpreted to signify similar rocks. However, the diagnostic satellite magnetic high ends ∼800 km south of the Antarctic coast, suggesting that the Mawson block is smaller than first proposed and that the remaining East Antarctic shield is composed of several Precambrian crustal blocks of largely undetermined composition and age. Nonetheless, the coincident eastern borders of these magnetic highs and high seismic-velocity anomalies characteristic of the Precambrian shield, together define the edge of thick cratonic lithosphere. East of this boundary, magnetic lows are explained by magnetite-poor upper Neoproterozoic and lower Paleozoic sedimentary rocks, and their metamorphic equivalents, which crop out discontinuously along the Ross margin of Antarctica and in eastern Australia. These rocks are inferred to overlie a Neoproterozoic rift margin, which transects older basement provinces. The coincidence of this cratonic rift boundary with the western limit of Paleozoic and Jurassic magmatism suggests that, although tectonically modified by younger events, the composite Antarctic-Australian shield comprised thick lithosphere that was not penetrated by Paleozoic and younger convergent-margin magmas.

Book chapter↗

Tributyltin: Advancing the science on assessing endocrine disruption with an unconventional endocrine-disrupting compound

Tributyltin (TBT) has been recognized as an endocrine disrupting chemical (EDC) for several decades. However, only in the last decade, was its primary endocrine mechanism of action (MeOA) elucidated—interactions with the nuclear retinoid-X receptor (RXR), peroxisome proliferator-activated receptor γ (PPARγ), and their heterodimers. This molecular initiating event (MIE) alters a range of reproductive, developmental, and metabolic pathways at the organism level. It is noteworthy that a variety of MeOAs have been proposed over the years for the observed endocrine-type effects of TBT; however, convincing data for the MIE was provided only recently and now several researchers have confirmed and refined the information on this MeOA. One of the most important lessons learned from years of research on TBT concerns apparent species sensitivity. Several aspects such as the rates of uptake and elimination, chemical potency, and metabolic capacity are all important for identifying the most sensitive species for a given chemical, including EDCs. For TBT, much of this was discovered by trial and error, hence important relationships and important sensitive taxa were not identified until several decades after its introduction to the environment. As recognized for many years, TBT-induced responses are known to occur at very low concentrations for molluscs, a fact that has more recently also been observed in fish species. This review explores the MeOA and effects of TBT in different species (aquatic molluscs and other invertebrates, fish, amphibians, birds, and mammals) according to the OECD Conceptual Framework for Endocrine Disruptor Testing and Assessment (CFEDTA). The information gathered on biological effects that are relevant for populations of aquatic animals was used to construct Species Sensitivity Distributions (SSDs) based on No Observed Effect Concentrations (NOECs) and Lowest Observed Effect Concentrations (LOECs). Fish appear at the lower end of these distributions, showing that they are as sensitive as molluscs, and for some species, even more sensitive. Concentrations in the range of 1 ng/L for water exposure (10 ng/g for whole-body burden) have been shown to elicit endocrine-type responses, whereas mortality occurs at water concentrations ten times higher. Current screening and assessment methodologies as compiled in the OECD CFEDTA are able to identify TBT as a potent endocrine disruptor with a high environmental risk for the original use pattern. If those approaches had been available when TBT was introduced to the market, it is likely that its use would have been regulated sooner, thus avoiding the detrimental effects on marine gastropod populations and communities as documented over several decades.

Book chapter↗

Occurrence of transformation products in the environment

Historically, most environmental occurrence research has focused on the parent compounds of organic contaminants. Research, however, has documented that the environmental transport of chemicals, such as pesticides and emerging contaminants, are substantially underestimated if transformation products are not considered. Although most examples described herein were drawn from research conducted by the U.S. Geological Survey, such results are generally reflective of those found in other parts of the world. Results from a study of 51 streams in the Midwestern United States found that transformation products were seven of the ten most frequently detected pesticide compounds in late spring runoff (after application of pre-emergent herbicides), and nine of the ten most frequently detected compounds in fall season runoff (during and after harvest). In fact, 70% of the total herbicide concentration in water from the Mississippi River Basin was from transformation products. Results from a study of 86 municipal wells in Iowa found the frequency of detection increased from 17%, when pesticide parent compounds were considered, to 53%, when both parents and transformation products were considered. Transformation products were 12 of the 15 most frequently detected compounds for this groundwater study. Although studies on transformation products of synthetic organic compounds other than pesticides are not as common, wastewater treatment plant discharges have repeatedly been shown to contribute such transformation products to streams. In addition, select detergent transformation products have been commonly found in solid waste in the 1000's mg/kg. These findings and many others document that transformation products must be considered to fully assess the potential environmental occurrence of chemical contaminants and their transport and fate in various compartments of the hydrologic system. ?? 2008 Springer-Verlag Berlin Heidelberg.

The Handbook of Environmental Chemistry series↗

Geochemistry of the Amazon Estuary

The Amazon River supplies more freshwater to the ocean than any other river in the world. This enormous volume of freshwater forces the estuarine mixing out of the river channel and onto the continental shelf. On the continental shelf, the estuarine mixing occurs in a very dynamic environment unlike that of a typical estuary. The tides, the wind, and the boundary current that sweeps the continental shelf have a pronounced influence on the chemical and biological processes occurring within the estuary. The dynamic environment, along with the enormous supply of water, solutes and particles makes the Amazon estuary unique. This chapter describes the unique features of the Amazon estuary and how these features influence the processes occurring within the estuary. Examined are the supply and cycling of major and minor elements, and the use of naturally occurring radionuclides to trace processes including water movement, scavenging, sediment-water interaction, and sediment accumulation rates. The biogeochemical cycling of carbon, nitrogen, and phosphorus, and the significances of the Amazon estuary in the global mass balance of these elements are examined.

Amazon River↗

GPS: Applications for measuring tectonic and fault-related deformation

The Global Positioning System (GPS) is a space-based Global NavigationSatellite System (GNSS). Using signals transmitted by GPS satellites, the positions of ground‐based receivers can be calculated to high precision,making it possible to track the movement of points on the Earth's surface over time. Unlike older geodetic surveying methods which involved periodicallymeasuring angles, distances, or elevations between points, GPS can provide three‐component (latitude, longitude, and altitude) position informationat a range of sampling rates and on a global scale. GPS equipment is easy to use and can be set up to collect data continuously. Since itsearly geophysical applications in the mid-1980s, this versatile tool, which can be used to track displacements over time periods of seconds to decades,has become indispensable for crustal deformation studies, leading to many important insights and some surprising discoveries.

Book chapter↗

Exploring the temporal effects of seasonal water availability on the snail kite of Florida: Part III

The Florida snail kite ( Rostrhamus sociabilis ) is an endangered raptor that occurs as an isolated population, currently of about 2,000 birds, in the wetlands of southern and central Florida, USA. Its exclusive prey species, the apple snail ( Pomacea paludosa ) is strongly influenced by seasonal changes in water abundance. Droughts during the snail kite breeding season have a direct negative effect on snail kite survival and reproduction, but droughts are also needed to maintain aquatic vegetation types favorable to snail kite foraging for snails. We used a spatially explicit matrix model to explore the effects of temporal variation in water levels on the viability of the snail kite population under different temporal drought regimes in its wetland breeding habitat. We focused on three aspects of variations in water levels that were likely to affect kites: (1) drought frequency; (2) drought duration; and (3) drought timing within the year. We modeled a 31-year historical scenario using four different scenarios in which the average water level was maintained constant, but the amplitude of water level fluctuations was modified. Our results reveal the complexity of the effects of temporal variation in water levels on snail kite population dynamics. Management implications of these results are discussed. In particular, management decisions should not be based on annual mean water levels alone, but must consider the intra-annual variability.

Florida↗

Quantitative approaches to characterizing natural chemical weathering rates

Silicate minerals, constituting more than 90% of the rocks exposed at the earth’s surface, are commonly formed under temperature and pressure conditions that make them inherently unstable in surficial environments. Undoubtedly, the most significant aspect of chemical weathering resulting from this instability is the formation of soils which makes life possible on the surface of the earth. Many soil macronutrients in this “critical zone” are directly related to the rate at which primary minerals weather (Huntington, 1995; Chadwick et al., 2003). Chemical weathering also creates economically significant ore deposits, such as those for Al and U (Samma, 1986; Misra, 2000), as well as potentially releasing high concentrations of toxic trace elements such as Se and As (Frankenberger and Benson, 1994). Silicate weathering is a significant buffer to acidification caused by atmospheric deposition (Driscoll et al., 1989) and from land use practices (Farley and Werritty, 1989). Atmospheric CO 2 levels have been primarily controlled by the balance between silicate weathering and the rate of volcanic inputs from the Earth’s interior, a relationship which may explain long-term climate stability (Ruddiman, 1997)

Book chapter↗

Stochastic variation in avian survival rates: Life-history predictions, population consequences, and the potential responses to human perturbations and climate change

Stochastic variation in survival rates is expected to decrease long-term population growth rates. This expectation influences both life-history theory and the conservation of species. From this expectation, Pfister ( 1998 ) developed the important life-history prediction that natural selection will have minimized variability in those elements of the annual life cycle (such as adult survival rate) with high sensitivity. This prediction has not been rigorously evaluated for bird populations, in part due to statistical difficulties related to variance estimation. I here overcome these difficulties, and in an analysis of 62 populations, I confirm her prediction by showing a negative relationship between the proportional sensitivity (elasticity) of adult survival and the proportional variance (CV) of adult survival. However, several species deviated significantly from this expectation, with more process variance in survival than predicted. For instance, projecting the magnitude of process variance in annual survival for American redstarts ( Setophaga ruticilla ) for 25 years resulted in a 44% decline in abundance without assuming any change in mean survival rate. For most of these species with high process variance, recent changes in harvest, habitats, or changes in climate patterns are the likely sources of environmental variability causing this variability in survival. Because of climate change, environmental variability is increasing on regional and global scales, which is expected to increase stochasticity in vital rates of species. Increased stochasticity in survival will depress population growth rates, and this result will magnify the conservation challenges we face.

Book chapter↗

Non-random temporary emigration and the robust design: Conditions for bias at the end of a time series: Section VIII

Deviations from model assumptions in the application of capture–recapture models to real life situations can introduce unknown bias. Understanding the type and magnitude of bias under these conditions is important to interpreting model results. In a robust design analysis of long-term photo-documented sighting histories of the endangered Florida manatee, I found high survival rates, high rates of non-random temporary emigration, significant time-dependence, and a diversity of factors affecting temporary emigration that made it difficult to model emigration in any meaningful fashion. Examination of the time-dependent survival estimates indicated a suspicious drop in survival rates near the end of the time series that persisted when the original capture histories were truncated and reanalyzed under a shorter time frame. Given the wide swings in manatee emigration estimates from year to year, a likely source of bias in survival was the convention to resolve confounding of the last survival probability in a time-dependent model with the last emigration probabilities by setting the last unmeasurable emigration probability equal to the previous year’s probability when the equality was actually false. Results of a series of simulations demonstrated that if the unmeasurable temporary emigration probabilities in the last time period were not accurately modeled, an estimation model with significant annual variation in survival probabilities and emigration probabilities produced bias in survival estimates at the end of the study or time series being explored. Furthermore, the bias propagated back in time beyond the last two time periods and the number of years affected varied positively with survival and emigration probabilities. Truncating the data to a shorter time frame and reanalyzing demonstrated that with additional years of data surviving temporary emigrants eventually return and are detected, thus in subsequent analysis unbiased estimates are eventually realized. Knowing the extent and magnitude of the potential bias can help in making decisions as to what time frame provides the best estimates or the most reliable opportunity to model and test hypotheses about factors affecting survival probability. To assess bias, truncating the capture histories to shorter time frames and reanalyzing the data to compare time-specific estimates may help identify spurious effects. Running simulations that mimic the parameter values and movement conditions in the real situation can provide estimates of standardized bias that can be used to identify those annual estimates that are biased to the point where the 95% confidence intervals are inadequate in describing the uncertainty of the estimates.

Book chapter↗

Swallows as a sentinel species for contaminant exposure and effect studies

Tree swallows are an important model species to study the effects of contaminants in wild bird populations and have been used extensively in studies across North America. The advantages of swallows compared to other avian species are detailed. Three case histories are provided where swallows have been successfully used in Natural Resource Damage and Ecological Risk Assessments. The final two sections of this chapter are for individuals who want more in-depth information and include a summary of the chemical classes for which there are swallow data, including effect levels when known. Information provided in this section can be used to put exposure to most classes of contaminants into context with other sites across North America. Finally, commonly used endpoints, ranging from population-level down to cellular and genetic endpoints, are discussed including considerations and pitfalls, and when further work is needed to more fully understand the role of environmental and biological variation in interpreting these endpoints.

Book chapter↗

Comparative status and assessment of Limulus polyphemus with emphasis on the New England and Delaware Bay populations

Increases in harvest of the American horseshoe crab ( Limulus polyphemus ) during the 1990s, particularly for whelk bait, coupled with decreases in species that depend on their eggs has reduced horseshoe crab abundance, threatened their ecological relationships, and dictated precautionary management of the horseshoe crab resource. Accordingly, population assessments and monitoring programs have been developed throughout much of the horseshoe crab’s range. We review and discuss implications for several recent assessments of Delaware Bay and New England populations and a meta-analysis of region-specific trends. These assessments show that the western Atlantic distribution of the horseshoe crab is comprised of regional or estuarine-specific meta-populations, which exhibit distinct population dynamics and require management as separate units. Modeling of Delaware Bay and Cape Cod populations confirmed that overharvest caused declines, but indicated that some harvest levels are sustainable and consistent with population growth. Coast-wide harvest was reduced by 70% from 1998 to 2006, with the greatest reductions within Delaware Bay states. Harvest regulations in Delaware Bay starting in the late 1990s, such as harvest quotas, seasonal closures, male-only harvest, voluntary use of bait-saving devices, and establishment of the Carl N. Shuster Jr. Horseshoe Crab Reserve, were followed by stabilization and recent evidence of increase in abundance of horseshoe crabs in the region. However, decreased harvest of the Delaware Bay population has redirected harvest to outlying populations, particularly in New York and New England . While the recent Delaware Bay assessments indicate positive population growth, increased harvest elsewhere is believed to be unsustainable. Two important considerations for future assessments include (1) managing Delaware Bay horseshoe crab populations within a multi-species context, for example, to help support migratory shorebirds and (2) anticipating the potential for harvest restrictions within Delaware Bay to redirect harvest onto outlying populations that cannot sustain the increased harvest.

Book chapter↗

Organic compounds used in animal husbandry: Chapter 13

Although in general, the same drugs are used by humans as for animal husbandry, some compounds are unique to CAFOs. In raising and fattening steers, anabolic steroids are widely used in the US. In the cattle industry, large use is made of the acaricides, avermectins, and the cypermethrins as well as juvenile growth hormone inhibitor for fly and tick control that could affect soil fauna in very small quantities as they reach the environment without any modification. In poultry, the organic arsenides have been widely used for decades to control coccidiosis and increase growth. The environmental fate of the arsenic excreted in the poultry feces is therefore been an area of concern.

Book chapter↗

Multi-scale remote sensing of coral reefs

In this chapter we present how both direct and indirect remote sensing can be integrated to address two major coral reef applications - coral bleaching and assessment of biodiversity. This approach reflects the current non-linear integration of remote sensing for environmental assessment of coral reefs, resulting from a rapid increase in available sensors, processing methods and interdisciplinary collaborations (Andréfouët and Riegl, 2004). Moreover, this approach has greatly benefited from recent collaborations of once independent investigations (e.g., benthic ecology, remote sensing, and numerical modeling).

Florida↗

Gravity-driven mass flows

Gravity-driven mass flows, also known as sediment gravity flows, include a spectrum of phenomena in which more-or-less coherent mixtures of grains and intergranular fluid flow down slopes. At one end of this spectrum are dilute flows in which momentum is transferred mostly by fluid forces and sediment is largely a passive cargo that increases the effective fluid density. These dilute mass flows are part of a larger class of fluid dynamical phenomena known as gravity currents ( Simpson, 1987 ; Bonnecaze et al., 1993 ). At the other end of the spectrum are concentrated mass flows such as granular avalanches and debris flows. Forces exerted by interacting solid grains dominate momentum transfer in such flows, although fluid forces can mediate grain interactions ( Savage and Hutter, 1989 ; Iverson, 1997 ).

Book chapter↗

Heat as a ground water tracer at the Russian River RBF facility, Sonoma County, California

Temperature is routinely collected as a water quality parameter, but only recently utilized as an environmental tracer of stream exchanges with ground water (Stonestrom and Constantz, 2003). In this paper, water levels and seasonal temperatures were used to estimate streambed hydraulic conductivities and water fluxes. Temperatures and water levels were analyzed from 3 observation wells near the Russian River RBF facility, north of Forestville, Sonoma County, CA. In addition, 9 shallow piezometers were installed in 3 cross-sections across the stream near a pair of collector wells at the RBF facility. Hydraulic conductivities and fluxes were estimated by matching simulated ground-water temperatures to the observed ground-water temperatures with an inverse modeling approach. Using temperature measurements in the shallow piezometers from 0.1 to 1.0 m below the channel, estimates of infiltration indicated a distinct area of streambed clogging near one of the RBF collector wells. For the deeper observation wells, temperature probes were located at depths between 3.5 m to 7.1 m below the channel. Estimated conductivities varied over an order of magnitude, with anisotropies of 5 (horizontal to vertical hydraulic conductivity) generally providing the best fit to observed temperatures.

California↗