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At least 1,171 records · Page 65Linked to original sources
USGS1994

Effects of storm paths on precipitation chemistry, and variations of within-storm chemistry during selected storms in central Massachusetts, 1986-87

Samples of precipitation from 31 storms were collected from October 1986 through December 1987 at a site near Quabbin Reservoir in central Massachusetts and were analyzed for pH, specific conductance, and concentrations of common chemical constituent. Twenty-four storms followed a conti- nental path west of the Appalachian Mountains. The remaining seven storms followed a coastal path east of the Appalachian Mountains along the Atlantic Coast. Precipitation from the continental storms was more acidic than precipitation from the coastal storms according to a nonparametric statistical com- parison. Because the continental storms had less volume, the loads of hydrogen ions and other common chemical constituents from both groups were not statistically different. The variability of within- storm precipitation chemistry was evaluated for 8 of the 31 storms. Seven of the storms showed evidence of suspended-particulate removal at levels between the cloud layer and the land surface during their early stages. The remaining storm, also the most acidic, showed evidence of suspended- particulate removal within the cloud layer as indicated by a relatively constant pH throughout the storm. Surface-air concentrations of sulfur dioxide and nitrogen dioxide before, during, and after each of the eight storms were compared to within-storm values of pH and precipitation. Seven of the storms were accompanied by decreased atmospheric concen- trations of both sulfur dioxide and nitrogen dioxide in the early stages of the storm. For three of the storms, atmospheric concentrations of sulfur dioxide and nitrogen dioxide were higher during the 24-hour period after the storm than the 24-hour period pre- ceding the storm. Particulates in precipitation samples were analyzed for three storms. Biotite was the predominant mineral in two of the storms. Other minerals detected were garnet, quartz, gypsum, hematite, epidote, ilmenite, eggonite, halite, rutile, and organic ash.

Water-Resources Investigations Report↗
USGS1997

A comparison of drainage basin nutrient inputs with instream nutrient loads for seven rivers in Georgia and Florida, 1986-90

Instream nutrient loads of the Altamaha, Suwannee, St. Johns, Satilla, Ogeechee, Withlacoochee, and Ochlockonee River Basins were computed and compared with nutrient inputs for each basin for the period 1986-90. Nutrient constituents that were considered included nitrate, ammonia, organic nitrogen, and total phosphorus. Sources of nutrients considered for this analysis included atmospheric deposition, fertilizer, animal waste, wastewater-treatment plant discharge, and septic discharge. The mean nitrogen input ranged from 2,400 kilograms per year per square kilometer (kg/yr)km2 in the Withlacoochee River Basin to 5,470 (kg/yr)km2 in the Altamaha River Basin. The Satilla and Ochlockonee River Basins also had large amounts of nitrogen input per unit area, totaling 5,430 and 4,920 (kg/yr)km2, respectively. Fertilizer or animal waste, as sources of nitrogen, predominated in all basins. Atmospheric deposition contributed less than one-fourth of the mean total nitrogen input to all basins and was consistently the third largest input in all but the Ogeechee River Basin, where it was the second largest. The mean total phosphorus input ranged from 331 (kg/yr)km2 in the Withlacoochee River Basin to 1,380 (kg/yr)km2 in both the Altamaha and Satilla River Basins. The Ochlockonee River Basin had a phosphorus input of 1,140 (kg/yr)km2. Per unit area, the Suwannee River discharged the highest instream mean total nitrogen and phosphorus loads and also discharged higher instream nitrate loads per unit area than the other six rivers. Phosphorus loads in stream discharge were highest in the Suwannee and Ochlockonee Rivers. The ratio of nutrient outputs to inputs for the seven studied rivers ranged from 4.2 to 14.9 percent, with the St. Johns (14.9 percent) and Suwannee (12.1 percent) Rivers having significantly higher percentages than those from the other basins. The output/input percentages for mean total phosphorus ranged from 1.0 to 7.0 percent, with the St. Johns (6.2 percent) and Suwannee (7.0 percent) Rivers exporting the highest percentage of phosphorus. Although instream nutrient loads constitute only one of the various pathways nutrients may take in leaving a river basin, only a relatively small part of nutrient input to the basin leaves the basin in stream discharge for the major coastal rivers examined in this study. The actual amount of nutrient transported in a river basin depends on the ways in which nutrients are physically handled, geographically distributed, and chemically assimilated within a river basin.

Florida, Georgia↗
USGS1997

Tritium, deuterium, and oxygen-18 in water collected from unsaturated sediments near a low-level radioactive-waste burial site south of Beatty, Nevada

Pore water was extracted in March 1996 from cores collected from test holes UZB-1 and UZB-2 drilled November 1992 and September 1993, respectively, in the Amargosa Desert south of Beatty, Nevada. The test holes are part of a study to determine factors affecting water and gas movement through unsaturated sediments. The holes are about 100 meters south of the southwest corner of the fence enclosing a commercial burial area for low-level radioactive waste. Water vapor collected from test hole UZB-2 in April 1994 and July 1995 had tritium concentrations greater than would be expected from atmospheric deposition. An apparatus was built in which pore water was extracted by cryodistillation from the previously obtained core samples. The extracted core water was analyzed for the radioactive isotope tritium and for the stable isotopes deuterium (D) and oxygen-18 ( 18 O). The isotopic composition of core water was compared with that of water vapor previously collected from air ports in test hole UZB-2 and to additional samples collected during May 1996. Core water becomes increasingly depleted in D and 18 O from the land surface to a depth of 30 meters, indicating that net evaporation of water is occurring near the land surface. Below a depth of 30 meters the stable-isotopic composition of core water becomes nearly constant and roughly equal to that of ground water. The stable isotopes plot on an evaporation trend. The source of the partly evaporated water could be either ground water or past precipitation having the same average isotopic composition as ground water but not modern precipitation, based on 18 months of record. Profiles of D and 18 O in water vapor roughly parallel those in core water. The stable isotopes of core water appear to be in isotopic equilibrium with water vapor from UZB-2 when temperature-dependent fractionation is considered. The data are consistent with the hypothesis of evaporative discharge of ground water at the land surface. The concentration of tritium in core water from depths less than 50 meters was higher than that of present-day atmospheric air, indicating that elevated tritium concentrations preceded the drilling. The concentrations of tritium in core water from the deepest sample (85 meters) and in UZB-2 groundwater (110 meters) were below detection. Thus, tritium in the unsaturated zone is not being introduced through ground water. The shape of the tritium profile for core water was similar to the shape of the tritium profile for water vapor collected April 1994, except that concentrations were consistently lower in core water than in water vapor. Tritium concentrations in water vapor increased from April 1994 to May 1996. Similar to the stable isotopes, the highest tritium concentrations were measured at shallow depths. Concentrations of tritium in water vapor during core collection were estimated assuming isotopic equilibrium with core water. The computed concentrations for November 1992 and September 1993 form consistent temporal trends with subsequent tritium concentrations in water vapor collected April 1994, July 1995, and May 1996. Observations of a bimodal distribution of tritium, in which the highest concentrations are in a gravel layer at a depth of 1-2 meters, indicate lateral migration of tritium through the vicinity of UZB-2.

Nevada↗
USGS1998

Hydrology, water quality, and nutrient loads to the Bauman Park Lake, Cherry Valley, Winnebago County, Illinois, May 1996–April 1997

The Bauman Park Lake occupies a former sand and gravel quarry in the Village of Cherry Valley, Illinois. The lake is eutrophic, and nuisance growths of algae and aquatic macrophytes are supported by nutrients (nitrogen and phosphorus) that are derived primarily from ground-water inflow, the main source of water for the lake. The lake has an average depth of about 18 feet, a maximum depth of about 28 feet, and a volume of 466 acre-feet at a stage of about 717 feet above sea level. The lake also is subject to thermal stratification, and although most of the lake is well oxidized, nearly anoxic conditions were present at the lake bottom during part of the summer of 1996. About 734 pounds phosphorus and 4,575 pounds of nitrogen compounds were added to the Bauman Park Lake from May 1996 through April 1997. Phosphorus compounds were derived primarily from inflow from ground water (68.7 percent), sediments derived from shoreline erosion (15.6 percent), internal regeneration (11.7 percent), waterfowl excrement (1.6 percent), direct precipitation and overland runoff (1.2 percent), and particulate matter deposited from the atmosphere (1.2 percent). Nitrogen compounds were derived from inflow from ground water (62.1 percent), internal regeneration (19.6 percent), direct precipitation and overland runoff (10.1 percent), particulate matter deposited from the atmosphere (3.5 percent), sediments derived from shoreline erosion (4.4 percent), and waterfowl excrement (0.3 percent). About 13 pounds of phosphorus and 318 pounds of nitrogen compounds flow out of the lake to ground water. About 28 pounds of nitrogen is removed by denitrification. Algae and aquatic macrophytes utilize nitrate, nitrite, ammonia, and dissolved phosphorus. The availability of dissolved phosphorus in the lake water controls algal growth. Uptake of the nutrients, by aquatic macrophytes and algae, temporarily removes nutrients from the water column but not from the lake basin. Because the amount of nutrients entering the lake greatly exceeds the amount leaving, the nutrients are concentrated in the sediments at the lake bottom, where they can be used by the rooted aquatic macrophytes and released to the water column when the proper geochemical conditions are present.

Illinois↗
USGS1999

Selected elements and organic chemicals in bed sediment and fish tissue of the Tualatin River basin, Oregon, 1992-96

A variety of elements and organic compounds have entered the environment as a result of human activities. Such substances find their way to aquatic sediments from direct discharges to waterways, atmospheric emissions, and runoff. Some of these chemicals are known to harm fish or wildlife, either by direct toxicity, by reducing viability, or by limiting reproductive success. In aquatic systems, sediments become the eventual sink for most of these chemicals. Analyzing the sediments provides a first step in a chemical inventory that can lead to an assessment of potential biological impacts (Kennicutt and others, 1994). Many elements (iron, aluminum, calcium, and others) enter the environment from the natural weathering of rock. Additional amounts of elements have been contributed by human activities such as mining, metals production and processing, fossil fuel combustion, municipal waste incineration, and transportationrelated sources. The environmental presence of some elements, such as lead and mercury, is almost entirely due to human activity. Lead is often associated with the use of leaded gasoline and from the manufacture and disposal of lead storage batteries. Mercury was used historically in a variety of industrial processes and as a pesticide. Nriagu and Pacyna (1998) concluded that human activity is the “most important element in the global biogeochemical cycling of the trace metals.” The number of organic compounds in existence and their total production has more than tripled in the last century. Many of these compounds enter the environment directly as pesticides; others are inadvertently discharged. Some organic compounds have natural sources. Three general classes of organic compounds will be discussed: organochlorine compounds, polyaromatic hydrocarbons, and phthalates. Almost all organochlorine compounds are manmade. Many are pesticides that were used widely in the 1950s–60s (DDT and chlordanes, for example). Use of most organochlorine pesticides was restricted or banned in the United States in the 1970s–80s. Polychlorinated biphenyls (PCBs) are also organochlorine compounds; they were used for a variety of applications, but most commonly as insulators in electrical transformers and other equipment. In general, organochlorine compounds degrade very slowly in the environment and therefore, are routinely found in environmental samples, despite the fact that they are no longer used in the United States. They are hydrophobic that is they do not dissolve readily in water and, in aquatic systems, are almost exclusively associated with sediments or tissue. Because these compounds cause a variety of adverse health effects in wildlife, the U.S. Environmental Protection Agency (USEPA) has listed many as priority pollutants. Organochlorine compounds also have been implicated as endocrine disrupters— chemicals that can interfere with the normal function of hormones. Polyaromatic hydrocarbons (PAHs) are found in sediments throughout the world (Hites and others, 1980). Their presence is thought to be primarily anthropogenic. PAHs occur naturally in petroleum products and also are produced during combustion. They enter the environment from fuel spills, tar coatings, coal and other fossil fuel usage, road dust, and from the atmospheric deposition of combustion products (Prahl and others, 1984; Wakeham and others, 1980). Urban areas often have high concentrations of PAHs because of transportation-related sources (vehicle exhaust, paving materials, and releases of fuel or oil). Natural sources, such as forest fires, may contribute small amounts of PAHs. Several PAHs are known carcinogens (benzo[a]pyrene, for example); 16 are listed as USEPA priority pollutants. Phthalate compounds are often associated with urban areas. They are used in a wide variety of industrial applications and in inks, adhesives, resins, and as plasticizers (chemicals that increase the flexibility of plastics). In aquatic systems, phthalates are found mostly in sediments where they degrade very slowly. Phthalates are thought to be endocrine disrupters; Jobling and others (1995) found that some phthalates were weakly estrogenic. USEPA considers some phthalates to be possible carcinogens. This report describes the results of a reconnaissance survey of elements and organic compounds found in bed sediment and fish tissue in streams of the Tualatin River Basin. The basin is in northwestern Oregon to the west of the Portland metropolitan area (fig. 1). The Tualatin River flows for about 80 miles, draining an area of about 712 square miles, before it enters the Willamette River. Land use in the basin changes from mostly forested in the headwaters, to mixed forest and agriculture, to predominately urban. The basin supports a growing population of more than 350,000 people, most of whom live in lower parts of the basin. Water quality in the Tualatin River and its tributaries is expected to be affected by the increasing urbanization of the basin.

Oregon↗
USGS2000

Sources, instream transport, and trends of nitrogen, phosphorus, and sediment in the lower Tennessee River basin, 1980-96

In 1997, the U.S. Geological Survey (USGS) began an assessment of the lower Tennessee River Basin as part of the National Water-Quality Assessment Program. Existing nutrient and sediment data from 1980 to 1996 were compiled, screened, and interpreted to estimate watershed inputs from nutrient sources, provide a general description of the distribution and transport of nutrients and sediments in surface water, and evaluate trends in nutrient and sediment concentrations in the lower Tennessee (LTEN) River Basin. Nitrogen inputs from major sources varied widely among tributary basins in the LTEN River Basin. Point source wastewater discharges contributed between 0 and 0.61 tons per square mile per year [(tons/mi 2 )/yr]. Of the nonpoint sources of nitrogen for which inputs were estimated (atmospheric deposition, nitrogen fixation, fertilizer application, and livestock waste) livestock waste contributed the largest input in about two-thirds (7 out of 11) of the tributary basins, and fertilizer application contributed the largest input in the remaining 4 basins. Nitrogen input from fertilizer application was the most variable spatially among the nonpoint sources of nitrogen, ranging from 1.5 to 23 (tons/mi 2 )/yr. Atmospheric deposition estimates varied the least from basin to basin, ranging from 1.6 to 2.0 (tons/mi 2 )/yr. Estimates of nitrogen input from livestock waste ranged between 2.0 to 13 (tons/mi 2 )/yr. The percentage of the input from each of these nonpoint sources that entered the surface-water system is not known. Wastewater discharge contributed between 0 and 0.14 (ton/mi 2 )/yr of phosphorus to tributary basins. Livestock waste contributed most of the input in 8 out of the 11 basins, and fertilizer application contributed the most in the remaining 3 basins. Estimates of phosphorus input for fertilizer application ranged from 0.35 to 5.1 (tons/mi 2 )/yr and from 0.62 to 4.3 (tons/mi 2 )/yr from livestock waste. Reservoirs on the main stem of the Tennessee River and on the Duck and Elk Rivers affect nutrient transport because hydrodynamic conditions in the reservoirs promote assimilation by aquatic plants and deposition of particulate matter. Observed decreases in total nitrite plus nitrate and dissolved-orthophosphorus concentrations in reservoirs or at sites downstream of reservoirs during summer months were probably related to seasonality of plant growth. Nutrient and sediment data used to estimate annual instream loads and yields were compiled from various water-quality monitoring programs and represent the best available data in the LTEN River Basin, but these data have several characteristics that limit accuracy of load estimates. Many of the monitoring programs were not designed with the objective of annual load estimation, and data representing storm transport are, therefore, sparse; sampling and analytical methods varied through time and among the monitoring programs, hampering spatial and temporal comparisons. The load estimates computed from these data are useful for evaluating broad spatial patterns of instream load, and comparisons of instream load to inputs, but may not be sufficiently accurate for local-scale evaluations of water quality. Estimates of the mean annual instream load of total nitrogen entering (Chattanooga, Tenn.) and leaving (Paducah, Ky.) the LTEN River Basin were 29,000 and 60,000 tons per year (tons/yr), respectively. These estimates represent a gain of 31,000 tons/yr, on average, across the area (18,930 mi 2 ) between these inlet and outlet sites. The sum of the mean annual instream load from gaged tributaries to the main stem within the study unit was 14,000 tons/yr; however, this number cannot be directly compared with the gain between the inlet and outlet sites because (1) the gaged area represents only 30 percent of the total area and (2) the period of record at many tributary sites did not correspond with the period of record at the inlet or outlet sites. Estimates of mean annual instream load of total phosphorus at the inlet and outlet sites of the LTEN River Basin were 1,300 and 5,000 tons/yr, respectively, representing a gain of 3,700 tons/yr, on average, across the study unit. The sum of the gaged tributary load, representing only 28 percent of the area contributing to the main stem, was 4,300 tons/yr. Although this number cannot be closely compared with the gain throughout the study unit, for the same reasons given for total nitrogen, a general comparison suggests that the main stem of the Tennessee River and the tributary embayments along the main stem function as a sink for total phosphorus, removing a substantial amount from the water column through deposition or assimilation. The estimates of inputs can be compared and correlated with yields (area-normalized instream loads); significant correlations between estimates of inputs and yields might be useful as predictive tools for instream water quality where monitoring data are not available. Yields of nitrogen correlated moderately well with inputs from nonpoint sources, based on 1992 estimates. Nitrogen yield was highest [3.5 (tons/mi 2 )/yr] for Town Creek, for which the balance of nonpoint-source inputs to agricultural lands (fertilizer application plus nitrogen fixation plus livestock waste minus harvest) was also the highest [15 (tons/mi 2 )/yr]. Nitrogen yield was low [1.0 (tons/mi 2 )/yr] for the Buffalo River, for which the balance of agricultural nonpoint-source input was correspondingly low [3.2 (tons/mi 2 )/yr, the second lowest]. Correlation of wastewater discharge with yield was poor, and contrasted with the significant correlation between wastewater discharge and median nitrogen concentration during low streamflow. The poor correlation between wastewater discharge and annual yield was expected, however, as wastewater discharge is a small fraction compared with annual yield. In contrast with nitrogen, phosphorus yield did not correlate well with any estimated inputs or land-use types for the tributary basins. Phosphorus yield was highest [1.1 and 0.93 (tons/mi 2 )/yr] at two sites along the Duck River and at Elk River near Prospect [0.89 (ton/mi 2 )/yr]; however, estimates of inputs at these sites were in the middle of their respective ranges. The influence of the outcrop of phosphatic limestone formations of the brown-phosphate districts in the lower Duck and lower Elk River Basins might be responsible for the poor correlation between estimated inputs and yields of phosphorus. The outcrop pattern of these phosphatic limestones are an important factor to consider as regional boundaries are established for attainable, region-specific water-quality criteria for total phosphorus. Estimates of sediment input from cropland soil erosion in 1992 ranged from 51 to 540 (tons/mi 2 )/yr among the major hydrologic units in the LTEN River Basin. Information was not available to estimate this input for individual tributaries. Sediment yield estimates ranged from 65 to 263 (tons/mi 2 )/yr for the three tributary monitoring basins for which instream data were available, and from 17 to 26 (tons/mi 2 )/yr for the Tennessee River at South Pittsburg and at Pickwick Landing Dam, respectively. Lower sediment yields for the main stem sites compared with the tributary sites is probably due to sediment deposition in the main stem of the Tennessee River and tributary embayments along the main stem. Most of the significant trends in nutrient concentrations from about 1985 to about 1995 were decreasing trends, except for total nitrite plus nitrate, which increased at one site on the Elk River. The spatial distribution of decreasing trends of total nitrogen and total ammonia corresponds with the spatial variation among basins in wastewater loading rate. The time period of observed trends corresponds to the period of improvements in municipal treatment, thus decreases in wastewater effluent concentrations of nitrogen might be responsible for the decreasing trend in instream concentrations at these sites. Concentrations of total phosphorus did not decrease during this period at these sites, as might have been expected considering the reductions in wastewater input of phosphorus during this period.

Alabama, Georgia, Kentucky, Mississippi, Tennessee↗
USGS1999

Sources and chronology of nitrate contamination in spring waters, Suwannee River basin, Florida

A multi-tracer approach, which consisted of analyzing water samples for n aturally occurring chemical and isotopic indicators, was used to better understand sources and chronology of nitrate contamination in spring wate rs discharging to the Suwannee and Santa Fe Rivers in northern Florida. Dur ing 1997 and 1998, as part of a cooperative study between the Suwannee River Water Management District and the U.S. Geological Survey, water samples were collected and analyzed from 24 springs and two wells for major ions, nutrients, dissolved organic carbon, and selected environmental isotopes [18O/16O, D/H, 13C/12C, 15N/14N]. To better understand when nitrate entered the ground-water system, water samples were analyzed for chlorofluorocarbons (CFCs; CCl3F, CCl2F2, and C2Cl3F3) and tritium (3H); in this way, the apparent ages and residence times of spring waters and water from shallow zones in the Upper Floridan aquifer were determined. In addition to information obtained from the use of isotopic and other chemical tracers, information on changes in land-use activities in the basin during 1954-97 were used to estimate nitrogen inputs from nonpoint sources for five counties in the basin. Changes in nitrate concentrations in spring waters with time were compared with estimated nitrogen inputs for Lafayette and Suwannee Counties. Agricultural activities [cropland farming, animal farming operations (beef and dairy cows, poultry, and swine)] along with atmospheric deposition have contributed large quantities of nitrogen to ground water in the Suwannee River Basin in northern Florida. Changes in agricultural land use during the past 40 years in Alachua, Columbia, Gilchrist, Lafayette, and Suwannee Counties have contributed variable amounts of nitrogen to the ground-water system. During 1955-97, total estimated nitrogen from all nonpoint sources (fertilizers, animal wastes, atmospheric deposition, and septic tanks) increased continuously in Gilchrist and Lafayette Counties. In Suwannee, Alachua, and Columbia Counties, estimated nitrogen inputs from all nonpoint sources peaked in the late 1970's corresponding to the peak use in fertilizer during this time. Fertilizer use in Columbia, Gilchrist, Lafayette, and Suwannee Counties increased substantially during 1993-97. The heavy use of fertilizers in the basin is corroborated by nitrogen isotope data. Values of d15N of nitrate (d15N-NO3) in spring waters range from 2.7 per mil (SUW718971) to 10.6 per mil (Poe Spring) with a median of 5.4 per mil. The range of values indicates that nitrate in the sampled spring waters most likely originates from a mixture of inorganic (fertilizers) and organic (animal wastes) sources; however, higher d15N values for Poe and Lafayette Blue Springs indicate that an organic source of nitrogen probably is contributing nitrate to these spring waters. Water samples from two wells sampled in Lafayette County have high d15N-NO3 values of 11.0 and 12.1 per mil, indicating the predominance of an organic source of nitrate. These two wells are located near dairy and poultry farms, where leachate from animal wastes may contribute nitrate to ground water. Dissolved-gas data (nitrogen, argon, and oxygen) indicate that denitrification has not removed large amounts of nitrate from the ground-water system. Thus, variations in d15N-NO3 values of spring waters can be attributed to variations in d15N-NO3 values of ground-water recharge, and can be used to obtain information about source(s) of nitrate. Extending the use of age-dating techniques (CFCs and 3H) to spring waters in complex karst systems required the use of several different approaches for estimating age and residence time of ground water discharging to springs. These approaches included the use of a simple reservoir model, a piston-flow model, an exponential model, and a binary-mixing model. When age data (CFC-11, CFC-113, and 3H) are combined for all springs, models that incorporate exponential mixtures seem to provide reliable estimates of average residence times of ground water discharging to springs. Whereas, data for some individual springs fit a binary-mixing model with more than 50 percent young water (recharged within the past 5 years), data from other individual springs fit a piston-flow model with a water age of about 25 years. The young ages of several spring waters (such as SUW718971, SUW725971, and Ginnie Spring) indicate the high vulnerability of the springs to contamination. For most springs, CFCs suggest that a large fraction of the water is more than 20 years old. Springs with lower flows tend to have young ages (shallow ground-water flow systems), whereas springs with higher flows tend to have older ages (deep ground-water flow systems). The chemical composition of spring waters can be used as a qualitative indicator of age and ground-water residence time. Nitrate-nitrogen concentrations and dissolved oxygen in spring waters are inversely related to the apparent ages of spring waters and ground-water residence time in the basin. Silica concentrations increase as the age of spring waters increase. Long-term trends in nitrate concentrations in selected spring waters were compared with estimated inputs of nitrogen from various sources in Suwannee and Lafayette Counties. In both counties, trends in nitrate concentrations in spring waters closely followed the estimated contribution of nitrogen from fertilizers. Decreasing nitrate concentrations in spring waters from Suwannee County followed the decrease in estimated fertilizer use from the mid-1970's to the early 1990's. Increasing nitrate concentrations in sprin g waters from Lafayette County followed the steady increase in fertilizer use from the early 1960's to the mid-1990's The relation between the concentration of nitrate in ground water and the amount of nitrogen that is added to a ground-water contributing area for a spring is controlled by complex interactions among hydrogeologic, land-use, and climatic factors, as well as several other land-management factors. Spring waters represent mixtures of converging flow paths that contain ground water with a range of ages. Even if nitrogen inputs were reduced substantially, it may take decades for nitrate concentrations in the ground-water system to return to near background levels.

Florida↗
USGS1984

Evaluation of environmental factors affecting yields of major dissolved ions of streams in the United States

The seven major dissolved ions in streams-sodium, potassium, magnesium, calcium, chloride, sulfate, and bicarbonate and their sum dissolved solids from 56 basins in the conterminous United States and Hawaii were correlated with bedrock type, annual precipitation, population density, and average stream temperature of their respective basins through multiple linear-regression equations to predict annual yields. The study was restricted to basins underlain by limestone, sandstone, or crystalline rock. Depending on the constituent, yields ranged from about 10 to 100,000 kilograms per square kilometer. Predicted yields were within 1 order of magnitude of measured yields. The most important factor in yield prediction was annual precipitation, which accounted for 58 to 71 percent of all yields. Rock type was second in importance. Yields of magnesium, calcium, bicarbonate, and dissolved solids from limestone basins were 4 to 10 times larger than those from sandstone or crystalline basins as a result of carbonate weathering. Population density was an ineffective indicator of all constituents except sodium and chloride; it accounted for 13 percent of the annual sodium yield and 20 percent of the annual chloride yield. Average stream temperature was significant only for calcium and bicarbonate in limestone basins. Its relationship with yields was consistently negative. Either carbonate dissolution increases at low temperatures, or weathering in northern basins, which contain glacial deposits and have the lowest stream temperatures, is greater than in southern basins. Average ion contributions from atmospheric deposition accounted for 30 percent of the sodium and chloride and 60 percent of the sulfate in annual yields. The amount of sulfate derived from atmospheric contributions was higher in sandstone and crystalline basins (65 and 80 percent, respectively) than limestone basins (38 percent). This disparity is attributed to the lack of available sulfate in crystalline rock and the chemical precipitation of sulfate in the sandstone basins, most of which are in semi-arid or arid areas.

Water Supply Paper↗
USGS1987

Analysis and interpretation of water-quality trends in major U.S. rivers, 1974-81

Water-quality records from two nationwide sampling networks are now of sufficient length to permit nationally consistent analysis of long-term water-quality trends at more than 300 locations on major U.S. rivers. Observed trends in 24 water-quality measures for the period 1974--81 provide evidence of both improvement and deterioration in stream quality during a time of major changes in atmospheric and terrestrial influences on surface waters. Particularly noteworthy are widespread decreases in lead and fecal bacteria concentrations and widespread increases in nitrate, arsenic, and cadmium concentrations. Changes in municipal waste treatment, leaded-gasoline consumption, highway-salt use, and nitrogen-fertilizer application, and regionally variable trends in coal production and combustion during the period, appear to be reflected in water-quality changes. There is evidence that atmospheric deposition of a variety of substances has played a surprisingly large role in water-quality changes.

Water Supply Paper↗
USGS2018

Airborne bacteria in Earth’s lower stratosphere resemble taxa detected in the troposphere: results from a new NASA aircraft bioaerosol collector (ABC)

Airborne microorganisms in the upper troposphere and lower stratosphere remain elusive due to a lack of reliable sample collection systems. To address this problem, we designed, installed, and flight-validated a novel Aircraft Bioaerosol Collector (ABC) for NASA's C-20A that can make collections for microbiological research investigations up to altitudes of 13.7 km. Herein we report results from the first set of science flights—four consecutive missions flown over the United States (US) from 30 October to 2 November, 2017. To ascertain how the concentration of airborne bacteria changed across the tropopause, we collected air during aircraft Ascent / Descent (0.3 to 11 km), as well as sustained Cruise altitudes in the lower stratosphere (~12 km). Bioaerosols were captured on DNA-treated gelatinous filters inside a cascade air sampler, then analyzed with molecular and culture-based characterization. Several viable bacterial isolates were recovered from flight altitudes, including Bacillus sp., Micrococcus sp., Arthrobacter sp., and Staphylococcus sp. from Cruise samples and Brachybacterium sp. from Ascent/Descent samples. Using 16S V4 sequencing methods for a culture-independent analysis of bacteria, the average number of total OTUs was 305 for Cruise samples and 276 for Ascent/Descent samples. Some taxa were more abundant in the flight samples than the ground samples, including OTUs from families Lachnospiraceae, Ruminococcaceae and Erysipelotrichaceae as well as the following genera: Clostridium, Mogibacterium, Corynebacterium, Bacteroides, Prevotella, Pseudomonas , and Parabacteroides . Surprisingly, our results revealed a homogeneous distribution of bacteria in the atmosphere up to 12 km. The observation could be due to atmospheric conditions producing similar background aerosols across the western US, as suggested by modeled back trajectories and satellite measurements. However, the influence of aircraft-associated bacterial contaminants could not be fully eliminated and that background signal was reported throughout our dataset. Considering the tremendous engineering challenge of collecting biomass at extreme altitudes where contamination from flight hardware remains an ever-present issue, we note the utility of using the stratosphere as a proving ground for planned life detection missions across the solar system.

Arizona, California, Colorado, Nevada, Utah↗
USGS2022

Presence of the herbaceous marsh species Schoenoplectus americanus enhances surface elevation gain in transitional coastal wetland communities exposed to elevated CO2 and sediment deposition events

Coastal wetlands are dynamic ecosystems that exist along a landscape continuum that can range from freshwater forested wetlands to tidal marsh to mudflat communities. Climate-driven stressors, such as sea-level rise, can cause shifts among these communities, resulting in changes to ecological functions and services. While a growing body of research has characterized the landscape-scale impacts of individual climate-driven stressors, little is known about how multiple stressors and their potential interactions will affect ecological functioning of these ecosystems. How will coastal wetlands respond to discrete climate disturbances, such as hurricane sediment deposition events, under future conditions of elevated atmospheric CO 2 ? Will these responses vary among the different wetland communities? We conducted experimental greenhouse manipulations to simulate sediment deposition from a land-falling hurricane under future elevated atmospheric CO 2 concentrations (720 ppm CO 2 ). We measured responses of net primary production, decomposition, and elevation change in mesocosms representing four communities along a coastal wetland landscape gradient: freshwater forested wetland, forest/marsh mix, marsh, and mudflat. When Schoenoplectus americanus was present, above- and belowground biomass production was highest, decomposition rates were lowest, and wetland elevation gain was greatest, regardless of CO 2 and sediment deposition treatments. Sediment addition initially increased elevation capital in all communities, but post-deposition rates of elevation gain were lower than in mesocosms without added sediment. Together these results indicate that encroachment of oligohaline marshes into freshwater forested wetlands can enhance belowground biomass accumulation and resilience to sea-level rise, and these plant-mediated ecosystem services will be augmented by periodic sediment pulses from storms and restoration efforts.

Plants↗
USGS2018

Analysis ready data: Enabling analysis of the Landsat archive

Data that have been processed to allow analysis with a minimum of additional user effort are often referred to as Analysis Ready Data (ARD). The ability to perform large scale Landsat analysis relies on the ability to access observations that are geometrically and radiometrically consistent, and have had non-target features (clouds) and poor quality observations flagged so that they can be excluded. The United States Geological Survey (USGS) has processed all of the Landsat 4 and 5 Thematic Mapper (TM), Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS) archive over the conterminous United States (CONUS), Alaska, and Hawaii, into Landsat ARD. The ARD are available to significantly reduce the burden of pre-processing on users of Landsat data. Provision of pre-prepared ARD is intended to make it easier for users to produce Landsat-based maps of land cover and land-cover change and other derived geophysical and biophysical products. The ARD are provided as tiled, georegistered, top of atmosphere and atmospherically corrected products defined in a common equal area projection, accompanied by spatially explicit quality assessment information, and appropriate metadata to enable further processing while retaining traceability of data provenance.

Remote Sensing↗
USGS2021

DLR Earth Sensing Imaging Spectrometer (DESIS) level 1 product evaluation using RadCalNet measurements

The DLR Earth Sensing Imaging Spectrometer (DESIS) is the first hyperspectral imaging spectrometer installed in the Multi-User System for Earth Sensing (MUSES) on the International Space Station (ISS) for acquiring routine science grade images from orbit. It was launched on 29 June 2018 and integrated into MUSES. DESIS measures energy in the spectral range of 400 to 1000 nm with high spatial and spectral resolution: 30 m and 2.55 nm, respectively. DESIS data should be sufficiently quantitative and accurate to use it for different applications and research. This work performs a radiometric evaluation of DESIS Level 1 product (Top of Atmosphere (TOA) reflectance) by comparing it with coincident Radiometric Calibration Network (RadCalNet) measurements at Railroad Valley Playa (RVUS), Gobabeb (GONA), and La Crau (LCFR). RVUS, GONA, and LCFR offer 4, 15, and 5 coincident datasets between DESIS and RadCalNet measurements, respectively. The results show an agreement between DESIS and RadCalNet TOA reflectance within ~5% for most spectral regions. However, there is an additional ~5% disagreement across the wavelengths affected by water vapor absorption and atmospheric scattering. Among the three RadCalNet sites, RVUS and GONA show a similar measurement disagreement with DESIS of ~5%, while LCFR differs by ~10%. Agreement between DESIS and RadCalNet measurements is variable across all three sites, likely due to surface type differences. DESIS and RadCalNet agreement show a precision of ~2.5%, 4%, and 7% at RVUS, GONA, and LCFR, respectively. RVUS and GONA, which have a similar surface type, sand, have a similar level of radiometric accuracy and precision, whereas LCFR, which consists of sparse vegetation, has lower accuracy and precision. The observed precision of DESIS Level 1 products from all the sites, especially LCFR, can be improved with a better Bidirectional Reflection Distribution Function (BRDF) characterization of the RadCalNet sites.

Remote Sensing↗
USGS2021

Evaluation of SWIR crop residue bands for the Landsat Next mission

This research reports the findings of a Landsat Next expert review panel that evaluated the use of narrow shortwave infrared (SWIR) reflectance bands to measure ligno-cellulose absorption features centered near 2100 and 2300 nm, with the objective of measuring and mapping non-photosynthetic vegetation (NPV), crop residue cover, and the adoption of conservation tillage practices within agricultural landscapes. Results could also apply to detection of NPV in pasture, grazing lands, and non-agricultural settings. Currently, there are no satellite data sources that provide narrowband or hyperspectral SWIR imagery at sufficient volume to map NPV at a regional scale. The Landsat Next mission, currently under design and expected to launch in the late 2020’s, provides the opportunity for achieving increased SWIR sampling and spectral resolution with the adoption of new sensor technology. This study employed hyperspectral data collected from 916 agricultural field locations with varying fractional NPV, fractional green vegetation, and surface moisture contents. These spectra were processed to generate narrow bands with centers at 2040, 2100, 2210, 2260, and 2230 nm, at various bandwidths, that were subsequently used to derive 13 NPV spectral indices from each spectrum. For crop residues with minimal green vegetation cover, two-band indices derived from 2210 and 2260 nm bands were top performers for measuring NPV (R 2 = 0.81, RMSE = 0.13) using bandwidths of 30 to 50 nm, and the addition of a third band at 2100 nm increased resistance to atmospheric correction residuals and improved mission continuity with Landsat 8 Operational Land Imager Band 7. For prediction of NPV over a full range of green vegetation cover, the Cellulose Absorption Index, derived from 2040, 2100, and 2210 nm bands, was top performer (R 2 = 0.77, RMSE = 0.17), but required a narrow (≤20 nm) bandwidth at 2040 nm to avoid interference from atmospheric carbon dioxide absorption. In comparison, broadband NPV indices utilizing Landsat 8 bands centered at 1610 and 2200 nm performed poorly in measuring fractional NPV (R 2 = 0.44), with significantly increased interference from green vegetation.

Remote Sensing↗
USGS2024

Intercomparison of same-day remote sensing data for measuring winter cover crop biophysical traits

Winter cover crops are planted during the fall to reduce nitrogen losses and soil erosion and improve soil health. Accurate estimations of winter cover crop performance and biophysical traits including biomass and fractional vegetative groundcover support accurate assessment of environmental benefits. We examined the comparability of measurements between ground-based and spaceborne sensors as well as between processing levels (e.g., surface vs. top-of-atmosphere reflectance) in estimating cover crop biophysical traits. This research examined the relationships between SPOT 5, Landsat 7, and WorldView-2 same-day paired satellite imagery and handheld multispectral proximal sensors on two days during the 2012–2013 winter cover crop season. We compared two processing levels from three satellites with spatially aggregated proximal data for red and green spectral bands as well as the normalized difference vegetation index (NDVI). We then compared NDVI estimated fractional green cover to in-situ photographs, and we derived cover crop biomass estimates from NDVI using existing calibration equations. We used slope and intercept contrasts to test whether estimates of biomass and fractional green cover differed statistically between sensors and processing levels. Compared to top-of-atmosphere imagery, surface reflectance imagery were more closely correlated with proximal sensors, with intercepts closer to zero, regression slopes nearer to the 1:1 line, and less variance between measured values. Additionally, surface reflectance NDVI derived from satellites showed strong agreement with passive handheld multispectral proximal sensor-sensor estimated fractional green cover and biomass (adj. R 2 = 0.96 and 0.95; RMSE = 4.76% and 259 kg ha−1, respectively). Although active handheld multispectral proximal sensor-sensor derived fractional green cover and biomass estimates showed high accuracies (R 2 = 0.96 and 0.96, respectively), they also demonstrated large intercept offsets (−25.5 and 4.51, respectively). Our results suggest that many passive multispectral remote sensing platforms may be used interchangeably to assess cover crop biophysical traits whereas SPOT 5 required an adjustment in NDVI intercept. Active sensors may require separate calibrations or intercept correction prior to combination with passive sensor data. Although surface reflectance products were highly correlated with proximal sensors, the standardized cloud mask failed to completely capture cloud shadows in Landsat 7, which dampened the signal of NIR and red bands in shadowed pixels.

Maryland↗
USGS2025

Landsat surface product validation instrumentation: The BigMAC exercise

Users of Earth remotely sensed optical imagery are increasingly demanding a surface reflectance or surface temperature product instead of the top-of-atmosphere products that have been produced historically. Validating the accuracy of surface products remains a difficult task since it involves assessment across a range of atmospheric profiles, as well as many different land surface types. Thus, standard approaches from the satellite calibration community do not apply and new technologies need to be developed. The Big Multi-Agency Campaign (BigMAC) was developed to assess current technologies that might be used for validation of surface products derived from satellite imagery, with emphasis on Landsat. Conducted in August, 2021, in Brookings, SD, USA, a variety of measurement technologies were fielded and assessed for accuracy, precision, and deployability. Each technology exhibited its strengths and weaknesses. Handheld spectroradiometers are capable of surface reflectance measurements with accuracies in the 0.01 - 0.02 absolute reflectance units, but are expensive to deploy. Unmanned Aircraft System (UAS)-based radiometers have the potential of making measurements with similar accuracy, but are also difficult to deploy. Mirror-based empirical line methods showed improving accuracy potential, but deployment also remains an issue. However, there are inexpensive radiometers designed for long-term autonomous use that exhibited good accuracy and precision, as well as being easy to deploy. Thermal measurement technologies showed accuracy potential in the 1 - 2K range, and some easily deployable instruments are available. Results from BigMAC indicate there are technologies available today to begin making operational surface reflectance/temperature measurements and strong potential for improvements in the future.

Sensors↗
USGS1999

A first-order analysis of the potential role of CO2 fertilization to affect the global carbon budget: A comparison of four terrestrial biosphere models

We compared the simulated responses of net primary production, heterotrophic respiration, net ecosystem production and carbon storage in natural terrestrial ecosystems to historical (1765 to 1990) and projected (1990 to 2300) changes of atmospheric CO2 concentration of four terrestrial biosphere models: the Bern model, the Frankfurt Biosphere Model (FBM), the High-Resolution Biosphere Model (HRBM) and the Terrestrial Ecosystem Model (TEM). The results of the model intercomparison suggest that CO2 fertilization of natural terrestrial vegetation has the potential to account for a large fraction of the so-called 'missing carbon sink' of 2.0 Pg C in 1990. Estimates of this potential are reduced when the models incorporate the concept that CO2 fertilization can be limited by nutrient availability. Although the model estimates differ on the potential size (126 to 461 Pg C) of the future terrestrial sink caused by CO2 fertilization, the results of the four models suggest that natural terrestrial ecosystems will have a limited capacity to act as a sink of atmospheric CO2 in the future as a result of physiological constraints and nutrient constraints on NPP. All the spatially explicit models estimate a carbon sink in both tropical and northern temperate regions, but the strength of these sinks varies over time. Differences in the simulated response of terrestrial ecosystems to CO2 fertilization among the models in this intercomparison study reflect the fact that the models have highlighted different aspects of the effect of CO2 fertilization on carbon dynamics of natural terrestrial ecosystems including feedback mechanisms. As interactions with nitrogen fertilization, climate change and forest regrowth may play an important role in simulating the response of terrestrial ecosystems to CO2 fertilization, these factors should be included in future analyses. Improvements in spatially explicit data sets, whole-ecosystems experiments and the availability of net carbon exchange measurements across the globe will also help to improve future evaluations of the role of CO2 fertilization on terrestrial carbon storage.

Tellus, Series B: Chemical and Physical Meteorolog↗
USGS2021

Aeolian processes and landforms across the Solar System: Science and technology requirements for the next decade

Discussions of planetary atmospheric-surface interactions (including aeolian processes and phenomena and the resulting landforms) are often tied to a specific planetary body. Considering this, a series of workshops were initiated in 2008 to facilitate an interdisciplinary and interplanetary body approach to further our understanding of aeolian processes, phenomena, and landforms (Titus et al., 2008, 2010, 2012, 2015, 2017). The most recent workshop, held 12-13 May 2020, transitioned to a virtual format due to the COVID-19 pandemic, with a specific focus on the planetary aeolian community’s vision for the next decade. Discussions centered around dynamics and resulting landforms, missions and models, and facilities. Participants determined that a planetary aeolian goals-and-objectives document was needed that was inclusive of multiple planetary bodies, processes, and phenomena that all intersect where the surface meets the atmosphere. This white paper is the first iteration of that vision, with definition of Goals/Objectives that organize the broad range of existing and needed planetary aeolian studies.

Bulletin of the AAS↗