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Petrologic insights into basaltic volcanism at historically active Hawaiian volcanoes

Study of the petrology of Hawaiian volcanoes, in particular the historically active volcanoes on the Island of Hawai‘i, has long been of worldwide scientific interest. When Dr. Thomas A. Jaggar, Jr., established the Hawaiian Volcano Observatory (HVO) in 1912, detailed observations on basaltic activity at Kīlauea and Mauna Loa volcanoes increased dramatically. The period from 1912 to 1958 saw a gradual increase in the collection and analysis of samples from the historical eruptions of Kīlauea and Mauna Loa and development of the concepts needed to evaluate them. In a classic 1955 paper, Howard Powers introduced the concepts of magnesia variation diagrams, to display basaltic compositions, and olivine-control lines, to distinguish between possibly comagmatic and clearly distinct basaltic lineages. In particular, he and others recognized that Kīlauea and Mauna Loa basalts must have different sources. Subsequent years saw a great increase in petrologic data, as the development of the electron microprobe made it possible to routinely monitor glass and mineral compositions, in addition to bulk rock compositions. We now have 100 years’ worth of glass compositions for Kīlauea summit eruptions, which, together with expanding databases on prehistoric tephras, provide important constraints on the nature of Kīlauea’s summit reservoir. A series of chemically distinctive eruptions in the 1950s and 1960s facilitated evaluation of magma mixing and transport processes at Kīlauea. At Mauna Loa, lava compositions are distinctive only at the trace element level, suggesting that its summit reservoir is better mixed than Kīlauea’s. Most summit lavas at both volcanoes, however, lie on olivine control lines having the same olivine composition (Fo 86–87 ). Study of the ongoing East Rift Zone eruption at Kīlauea has further illuminated the complexity of magma storage, resupply, and mixing along this very active rift zone. Studies of active and closed-system lava lakes have been part of HVO’s efforts since Jaggar’s unique descriptions of the Halema‘uma‘u lava lake that existed before 1924. Detailed study of closed-system bodies, including the 1959 Kīlauea Iki, 1963 ‘Alae, and 1965 and prehistoric Makaopuhi lava lakes and the Uēkahuna laccolith, have allowed recognition and quantification of processes of basalt differentiation. Specific topics reviewed herein include the occurrence of segregation veins and related structures, overall cooling history, and patterns of crystallization and reequilibration of olivine in various lava lakes. In recent decades, study of the submarine slopes of the Island of Hawai‘i and of Lō‘ihi Seamount has revolutionized our understanding of the early history of Hawaiian volcanoes. Observations of Lō‘ihi lavas first established the existence of an early alkalic stage in the evolution of Hawaiian volcanoes. Stages of volcanic development from inception to tholeiitic shield building can be observed in Kīlauea’s submarine and subaerial sections. One distinctive feature of submarine volcanics at Kīlauea, Mauna Loa, and Hualālai is that picritic lavas are more abundant than in subaerial eruptions. Also, olivine compositions of submarine lavas are more magnesian, ranging from Fo 88 at Kīlauea to Fo 89 at Hualālai. The most magnesian glasses known from Kīlauea (MgO=14.7–15.0 weight percent) were found along the submarine part of Kīlauea’s East Rift Zone. Contributions to our knowledge of the nature of the mantle source(s) of Hawaiian basalts are reviewed briefly, although this is a topic where debate is ongoing. Finally, our accumulated petrologic observations impose constraints on the nature of the summit reservoirs at Kīlauea and Mauna Loa, specifically whether the summit chamber has been continuous or segmented during past decades.

Hawaii↗

Geologic map of Wupatki National Monument and vicinity, Coconino County, Northern Arizona

Introduction The geologic map of Wupatki National Monument is a cooperative effort between the U.S. Geological Survey, the National Park Service, and the Navajo Nation to provide geologic information for resource management officials of the National Park Service, U.S. Forest Service, Navajo Indian Reservation (herein the Navajo Nation), and visitor information services at Wupatki National Monument, Arizona. Funding for the map was provided in part by the Water Rights Branch of the Water Resources Division of the National Park Service. Field work on the Navajo Nation was conducted under a permit from the Navajo Nation Minerals Department. Any persons wishing to conduct geologic investigations on the Navajo Nation must first apply for, and receive, a permit from the Navajo Nation Minerals Department, P.O. Box 1910, Window Rock, Arizona 86515, telephone (928)-871-6587. Wupatki National Monument lies within the USGS 1:24,000-scale Wupatki NE, Wupatki SE, Wupatki SW, Gray Mountain, East of SP Mountain, and Campbell Francis Wash quadrangles in northern Arizona. The map is bounded approximately by longitudes 111? 16' to 111? 32' 30' W. and latitudes 35? 30' to 35? 37' 40' N. The map area is in Coconino County on the southern part of the Colorado Plateaus geologic province (herein Colorado Plateau). The map area is locally subdivided into three physiographic parts, the Coconino Plateau, the Little Colorado River Valley, and the San Francisco Volcanic Field as defined by Billingsley and others (1997) [fig. 1]. Elevations range from 4,220 ft (1,286 m) at the Little Colorado River near the northeast corner of the map area to about 6,100 ft (1,859 m) at the southwest corner of the map area. The small community of Gray Mountain is about 16 mi (26 km) northwest of Wupatki National Monument Visitor Center, and Flagstaff, Arizona, the nearest metropolitan area, is about 24 mi (38 km) southwest of the Visitor Center (fig. 1). U.S. Highway 89 provides access to the west entrance of Wupatki National Monument. A paved Coconino County road provides a loop from Wupatki National Monument south to Sunset Crater National Monument and back to U.S. Highway 89 about 10 mi (16 km) north of Flagstaff, Arizona. Access to Coconino National Forest is via dirt roads maintained by the National Forest Service. Several unimproved dirt roads on Babbitt Ranch lands provide limited access to remote areas north of Wupatki National Monument. Travel is mostly restricted to paved roads within Wupatki National Monument, and a dirt road that crosses the Little Colorado River provides access to the Navajo Nation area east and northeast of the Little Colorado River. The Little Colorado River crossing is not bridged and can be impassable when the river is flowing. Four-wheel-drive vehicles are recommended but not necessary for travel in remote parts of the Navajo Nation. Extra food and water are highly recommended for travel in this sandy area. Land ownership north of Wupatki National Monument forms a checkerboard pattern between private and State land. Coconino National Forest manages lands south of Wupatki National Monument and the National Park Service manages Wupatki National Monument. The Leupp and Tolani Lake Chapters of the Navajo Nation manage the area northeast and east of the Little Colorado River (see land management boundaries on map). The geologic map of Wupatki National Monument provides updated geologic framework information for this part of the Colorado Plateau. The geologic information supports Federal, State, and private land managers when conducting geologic, biologic, and hydrologic investigations and will support future and ongoing geologic and associated scientific investigations of all disciplines within the Wupatki National Monument area.

Arizona↗

Geologic map of the eastern quarter of the Flagstaff 30’ x 60’ quadrangle, Coconino County, northern Arizona

The eastern quarter of the Flagstaff 30′ x 60′ quadrangle includes eight USGS 1:24,000-scale quadrangles in Coconino County, northern Arizona (fig. 1, map sheet): Anderson Canyon, Babbitt Wash, Canyon Diablo, Grand Falls, Grand Falls SE, Grand Falls SW, Grand Falls NE, and Meteor Crater. The map is bounded by lat 35° to 35°30′ N. and long 111° to 111°15′ W. and is on the southern part of the Colorado Plateaus geologic province (herein Colorado Plateau). Elevations range from 4,320 ft (1,317 m) at the Little Colorado River in the northwest corner of the map area to about 6,832 ft (2,082 m) at the southwest corner of the map. This geologic map provides an updated geologic framework for the eastern quarter of the Flagstaff 30′ x 60′ quadrangle and is adjacent to two other recent geologic maps, the Cameron and Winslow 30′ x 60′ quadrangles (Billingsley and others, 2007, 2013). This geologic map is the product of a cooperative effort between the U.S. Geological Survey (USGS) and the Navajo Nation. It provides geologic information for resource management officials of the U.S. Forest Service, the Arizona Game and Fish Department, and the Navajo Nation Reservation (herein the Navajo Nation). Funding for the map was provided by the USGS geologic mapping program, Reston, Virginia. Field work on the Navajo Nation was conducted under a permit from the Navajo Nation Minerals Department. Any persons wishing to conduct geologic investigations on the Navajo Nation must first apply for, and receive, a permit from the Navajo Nation Minerals Department, P.O. Box 1910, Window Rock, Arizona 86515, telephone (928) 871-6587.

Arizona↗

Geologic map of the Kechumstuk fault zone in the Mount Veta area, Fortymile mining district, east-central Alaska

This map was developed by the U.S. Geological Survey Mineral Resources Program to depict the fundamental geologic features for the western part of the Fortymile mining district of east-central Alaska, and to delineate the location of known bedrock mineral prospects and their relationship to rock types and structural features. This geospatial map database presents a 1:63,360-scale geologic map for the Kechumstuk fault zone and surrounding area, which lies 55 km northwest of Chicken, Alaska. The Kechumstuk fault zone is a northeast-trending zone of faults that transects the crystalline basement rocks of the Yukon-Tanana Upland of the western part of the Fortymile mining district. The crystalline basement rocks include Paleozoic metasedimentary and metaigneous rocks as well as granitoid intrusions of Triassic, Jurassic, and Cretaceous age. The geologic units represented by polygons in this dataset are based on new geologic mapping and geochronological data coupled with an interpretation of regional and new geophysical data collected by the Alaska Department of Natural Resources, Division of Geological and Geophysical Surveys. The geochronological data are reported in the accompanying geologic map text and represent new U-Pb dates on zircons collected from the igneous and metaigneous units within the map area.

Alaska↗

Hydrogeology of and potential mining impacts on strippable lignite areas in the Denver Aquifer, east-central Colorado

This study describes the hydrogeology of and potential impacts of mining on strippable lignite areas in the Denver aquifer in the east-central Colorado plains. Strippable lignitic coal seams , 20 to 60 ft thick, are present in the Denver Formation. The Denver aquifer, the saturated part of the Denver Formation, is likely to be affected locally by surface mining of lignite. Transmissivity of the aquifer in the study area ranges from 145 to 1,000 mg/L to the northeast in the study area as, hydraulic head decreases from 6,600 to 5,400 ft. Distance-drawdown curves show the extent of water level drawdown near a dewatered surface mine. After reclamation of the lignite mine pit, flow through the lignite spoil pile may increase the dissolved solids concentrations in the Denver aquifer. This increase could occur, because, as water from rain and overland flow percolates through the newly-exposed rock surfaces in the spoil material, minerals from the overburden can be dissolved in the water, which then joins with water from the aquifer. This increase could locally change streams, springs, and alluvial and bedrock aquifers. (USGS)

Water-Resources Investigations Report↗

Geology and ground water of the Tualatin Valley, Oregon

The Tualatin Valley proper consists of broad valley plains, ranging in altitude from 100 to 300 feet, and the lower mountain slopes of the drainage basin of the Tualatin River, a tributary of the Willamette River in northwestern Oregon. The valley is almost entirely farmed. Its population is increasing rapidly, partly because of the expansion of metropolitan Portland. Structurally, the bedrock of the basin is a saucer-shaped syncline almost bisected lengthwise by a ridge. The bedrock basin has been partly filled by alluvium, which underlies the valley plains. Ground water occurs in the Columbia River basalt, a lava unit that forms the top several hundred feet of the bedrock, and also in the zones of fine sand in the upper part of the alluvial fill. It occurs under unconfined, confined, and perched conditions. Graphs of the observed water levels in wells show that the ground water is replenished each year by precipitation. The graphs show also that the amount and time of recharge vary in different aquifers and for different modes of ground-water occurrence. The shallower alluvial aquifers are refilled each year to a level where further infiltration recharge is retarded and water drains away as surface runoff. No occurrences of undue depletion of the ground water by pumping are known. The facts indicate that there is a great quantity of additional water available for future development. The ground water is developed for use by some spring works and by thousands of wells, most of which are of small yield. Improvements are now being made in the design of the wells in basalt and in the use of sand or gravel envelopes for wells penetrating the fine-sand aquifers. The ground water in the basalt and the valley fill is in general of good quality, only slightly or moderately hard and of low salinity. Saline and mineralized water is present in the rocks of Tertiary age below the Columbia River basalt. Under certain structural and stratigraphic conditions this water of poor quality contaminates the fresh-water aquifers. Detailed hydrologic and geologic conditions are presented in 5 tables, 7 pictures, and 17 graphic figures and plates.

Water Supply Paper↗

Constraints on the timing of Co-Cu ± Au mineralization in the Blackbird district, Idaho, using SHRIMP U-Pb ages of monazite and xenotime plus zircon ages of related Mesoproterozoic orthogneisses and metasedimentary rocks

The Blackbird district, east-central Idaho, contains the largest known Co reserves in the United States. The origin of strata-hosted Co-Cu ± Au mineralization at Blackbird has been a matter of controversy for decades. In order to differentiate among possible genetic models for the deposits, including various combinations of volcanic, sedimentary, magmatic, and metamorphic processes, we used U-Pb geochronology of xenotime, monazite, and zircon to establish time constraints for ore formation. New age data reported here were obtained using sensitive high resolution ion microprobe (SHRIMP) microanalysis of (1) detrital zircons from a sample of Mesoproterozoic siliciclastic metasedimentary country rock in the Blackbird district, (2) igneous zircons from Mesoproterozoic intrusions, and (3) xenotime and monazite from the Merle and Sunshine prospects at Blackbird. Detrital zircon from metasandstone of the biotite phyllite-schist unit has ages mostly in the range of 1900 to 1600 Ma, plus a few Neoarchean and Paleoproterozoic grains. Age data for the six youngest grains form a coherent group at 1409 ± 10 Ma, regarded as the maximum age of deposition of metasedimentary country rocks of the central structural domain. Igneous zircons from nine samples of megacrystic granite, granite augen gneiss, and granodiorite augen gneiss that crop out north and east of the Blackbird district yield ages between 1383 ± 4 and 1359 ± 7 Ma. Emplacement of the Big Deer Creek megacrystic granite (1377 ± 4 Ma), structurally juxtaposed with host rocks in the Late Cretaceous ca. 5 km north of Blackbird, may have been involved in initial deposition of rare earth elements (REE) minerals and, possibly, sulfides. In situ SHRIMP ages of xenotime and monazite in Co-rich samples from the Merle and Sunshine prospects, plus backscattered electron imagery and SHRIMP analyses of trace elements, indicate a complex sequence of Mesoproterozoic and Cretaceous events. On the basis of textural relationships observed in thin section, xeno-time and cobaltite formed during multiple episodes. The oldest age for xenotime (1370 ± 4 Ma), determined on oscillatory-zoned cores, may date the time of initial cobaltite formation, and provides a minimum age for the host metasedimentary rocks. Additional Proterozoic xenotime growth events occurred at 1315 to 1270 Ma and ca. 1050 Ma. Other xenotime grains and rims grew in conjunction with cobaltite during Cretaceous metamorphism. However, ages of these growth episodes cannot be precisely determined due to matrix effects on 206 Pb/ 238 U data for xenotime. Monazite, some of which encloses cobaltite, uniformly has Cretaceous ages that mainly are 110 ± 3 and 92 ± 5 Ma. These data indicate that xenotime, monazite, and cobaltite were extensively mobilized and precipitated during Middle to Late Cretaceous metamorphic events.

Idaho↗

Radioactive mineral spring precipitates, their analytical and statistical data and the uranium connection

Major radioactive mineral springs are probably related to deep zones of active metamorphism in areas of orogenic tectonism. The most common precipitate is travertine, a chemically precipitated rock composed chiefly of calcium carbonate, but also containing other minerals. The mineral springs are surface manifestations of hydrothermal conduit systems which extend downward many kilometers to hot source rocks. Conduits are kept open by fluid pressure exerted by carbon dioxide-charged waters rising to the surface propelled by heat and gas (CO2 and steam) pressure. On reaching the surface, the dissolved carbon dioxide is released from solution, and calcium carbonate is precipitated. Springs also contain sulfur species (for example, H2S and HS-), and radon, helium and methane as entrained or dissolved gases. The HS- ion can react to form hydrogen sulfide gas, sulfate salts, and native sulfur. Chemical salts and native sulfur precipitate at the surface. The sulfur may partly oxidize to produce detectable sulfur dioxide gas. Radioactivity is due to the presence of radium-226, radon-222, radium-228, and radon-220, and other daughter products of uranium-238 and thorium-232. Uranium and thorium are not present in economically significant amounts in most radioactive spring precipitates. Most radium is coprecipitated at the surface with barite. Barite (barium sulfate) forms in the barium-containing spring water as a product of the oxidation of sulfur species to sulfate ions. The relatively insoluble barium sulfate precipitates and removes much of the radium from solution. Radium coprecipitates to a lesser extent with manganese-barium- and iron-oxy hydroxides. R-mode factor analysis of abundances of elements suggests that 65 percent of the variance of the different elements is affected by seven factors interpreted as follows: (1) Silica and silicate contamination and precipitation; (2) Carbonate travertine precipitation; (3) Radium coprecipitation; (4) Evaporite precipitation; (5) Hydrous limonite precipitation and coprecipitated elements including uranium; (6) Rare earth elements deposited with detrital contamination (?); (7) Metal carbonate adsorption and precipitation. Economically recoverable minerals occurring at some localities in spring precipitates are ores of iron, manganese, sulfur, tungsten and barium and ornamental travertine. Continental radioactive mineral springs occur in areas of crustal thickening caused by overthrusting of crustal plates, and intrusion and metamorphism. Sedimentary rocks on the lower plate are trapped between the plates and form a zone of metamorphism. Connate waters, carbonate rocks and organic-carbon-bearing rocks react to extreme pressure and temperature to produce carbon dioxide, and steam. Fractures are forced open by gas and fluid pressures. Deep-circulating meteoric waters then come in contact with the reactive products, and a hydrothermal cell forms. When hot mineral-charged waters reach the surface they form the familiar hot mineral springs. Hot springs also occur in relation to igneous intrusive action or volcanism both of which may be products of the crustal plate overthrusting. Uranium and thorium in the sedimentary rocks undergoing metamorphism are sometimes mobilized, but mobilization is generally restricted to an acid hydrothermal environment; much is redeposited in favorable environments in the metamorphosed sediments. Radium and radon, which are highly mobile in both acid and alkaline aqueous media move upward into the hydrothermal cell and to the surface.

Open-File Report↗

Geology and genesis of the Shalipayco evaporite-related Mississippi Valley-type Zn–Pb deposit, Central Peru: 3D geological modeling and C–O–S–Sr isotope constraints

The Shalipayco Zn–Pb deposit, in central Peru, is composed of several stratabound orebodies, the largest of which are the Resurgidora and Intermedios, contained in carbonate rocks of the Upper Triassic Chambará Formation, Pucará group. Petrography suggests that a single ore-forming episode formed sphalerite and galena within vugs, open spaces, and fractures. Three-dimensional (3D) geological modeling has allowed division of the Chambará Formation into four members (Chambará I, II, III, and IV) that better define lithological controls on sulfide formation. Diagenetic replacement of evaporite minerals with the organic matter (OM) presence likely generated secondary porosity and H 2 S accumulation by bacterial sulfate reduction (BSR), providing ground preparation for the later Zn–Pb mineralizing event. The least-altered host rocks have C–O isotope compositions of 1.8 ± 0.1‰ (VPDB) and 29.9 ± 2.1‰ (VSMOW), respectively, within the Triassic marine carbonate ranges. Early dolomite contains lighter C–O composition (1.1 ± 0.9 and 23.8 ± 2.9‰, respectively) consistent with OM decomposition during burial diagenesis. Post-mineralization calcite has still lighter C–O composition (− 5.1 and 13.3‰, respectively), suggesting meteoric water that had migrated through organic-rich strata. The strontium isotopes of Mitu group basalts (0.709654–0.719669) indicate it as a possible, but not the unique source of strontium and probably of other metals. Highly negative sulfide sulfur isotope values (− 23.3 to − 6.2‰ (VCDT)) indicate a major component of the ore sulfur derived ultimately from BSR. However, multiple lines of evidence suggest that preexisting H 2 S underwent thermochemical redox cycling prior to ore formation. The influx of hot metalliferous brines to dolomitized zones containing trapped H 2 S is the preferred model for ore deposition at Shalipayco.

Mineralium Deposita↗

Antimony

Antimony is an important mineral commodity used widely in modern industrialized societies. The element imparts strength, hardness, and corrosion resistance to alloys that are used in many areas of industry, including in lead-acid storage batteries. Antimony’s leading use is as a fire retardant in safety equipment and in household goods, such as mattresses. The U.S. Government has considered antimony to be a critical mineral mainly because of its use in military applications. The great majority of the world’s antimony comes from China, and much of the remainder is shipped to China for smelting. Antimony resources are unevenly distributed around the world. China has the bulk of the world’s identified resources; other countries that have identified antimony resources include Bolivia, Canada, Mexico, Russia, South Africa, Tajikistan, and Turkey. Resources in the United States are located mainly in Alaska, Idaho, Montana, and Nevada. The most significant antimony mineral deposits occur in geologic environments with a thick sequence of siliciclastic sedimentary rocks in areas with significant fault and fracture systems. The most common antimony ore mineral is stibnite (Sb2 S3 ), but more than 100 other minerals also contain antimony. The presence of antimony in surface waters and groundwaters results primarily from rock weathering, soil runoff, and anthropogenic sources. Global emissions of antimony to the atmosphere average 6,100 metric tons per year. Empirical data suggest that the acid-generating potential of antimony mine waste is low.

Professional Paper↗

Insights into Mountain Pass carbonatite formation from in-situ sulfur isotopes and geochemistry of sulfate and sulfide minerals

The Mountain Pass carbonatite stock hosts a world-class rare earth element deposit and may be classified as a carbonate-sulfate igneous rock, as it contains on average > 50 volume percent carbonate minerals and 20 to 30 volume percent sulfate minerals. The sulfates range in composition from barite to celestine and locally occur with sparse sulfide minerals. We investigate the origin of sulfur enrichment and the occurrence of sulfur-bearing minerals in the Mountain Pass carbonatite with in-situ sulfur isotope and mineral chemistry. Barite cores with δ 34 S of 1 to 3‰ do not coexist with sulfides, whereas celestine rims with δ 34 S of > 3‰ are associated with sulfides with δ 34 S < -10‰. We propose a model in which sulfur-bearing sediments were subducted during episodes of plate convergence in the Mojave Province that preceded Mountain Pass magmatism. Metasomatism of the overlying mantle by melts derived from the subducted sediments generated an unusually carbon- and sulfur-rich source to yield carbonatite magmas. Sulfur from primary carbonatite magmas and ~ 1 to 7% sulfur from subducted sediment melts yielded a slightly enriched δ 34 S composition (relative to depleted mantle δ 34 S of -1‰) for early crystallizing barite. Celestine rims on magmatic barite cores formed at low, hydrothermal temperatures (< 350 °C) based on S isotope thermometry for equilibrium celestine-galena and celestine-pyrite pairs. The sparse sulfides in the carbonatite stock are not in equilibrium with the primary barite cores and therefore do not permit S isotope thermometry estimates of magmatic temperatures. The S/Se ratios of sulfide minerals (> 3,400) typically exceed primitive mantle values (S/Se of 3,340), also consistent with their derivation from hydrothermal fluids. Trace occurrences of sulfide and sulfate minerals in alkaline silicate stocks related to the carbonatite stock have similar δ 34 S compositions and yield similarly low formation temperatures, suggesting regionally extensive and chemically similar sulfur-bearing hydrothermal fluids that imparted lithologically diverse rocks with a consistent sulfur isotope fingerprint.

California, Nevada↗

Pyrrhotite distribution in the conterminous United States, 2020

In parts of Connecticut and Massachusetts, foundations of some homes are cracking and crumbling. Failing foundations can reduce the market value of a home and lifting a house to replace and repour a foundation is an expensive undertaking. In response, some homeowners are defaulting on their mortgages and abandoning their homes. The culprit is pyrrhotite, which occurs in construction aggregate (crushed stone) that was used as a filler in concrete. When pyrrhotite is naturally exposed to water and oxygen, it breaks down to produce sulfuric acid and secondary minerals, including gypsum, which have larger volumes than the pyrrhotite they replace. The expanded volume of the secondary minerals cracks and degrades concrete. Pyrrhotite occurs in rocks in many areas of the United States. To help assess the national risk of pyrrhotite in aggregate, the fiscal year 2019 appropriations bill for the U.S. Geological Survey’s (USGS) Mineral Resources Program allocated funds to develop a map showing the distribution of pyrrhotite across the United States. The purpose of this fact sheet is to (1) present a nationwide map that shows where pyrrhotite may occur in rocks in the United States, (2) describe and discuss the factors that control the presence and abundance of pyrrhotite in rocks, (3) provide information on geographic information system datasets that deliver more detailed information on these distributions, and (4) describe U.S. and international standards on aggregate that are designed to prevent failing concrete. While this map and fact sheet provide general information about the possible distribution of pyrrhotite in the United States, they are no substitute for site-specific characterization and quality control programs designed to ensure that aggregate used in concrete is of appropriate quality for its intended purpose.

Conterminous United States↗

Geology of the southern Elkhorn Mountains, Jefferson and Broadwater Counties, Montana

The geology of an area of about 270 square miles in the southern Elkhorn Mountains, west of Townsend in west-central Montana, is described. The mountains in the southern part of the area comprise northward-trending alternating ridges and valleys underlain principally by folded sedimentary rocks. They merge northward into the higher and more rugged main mass of the mountains, which is underlain principally by upper Cretaceous volcanic rocks. The mountaintops are 1,000 to 4,500 feet above the major valleys. The sedimentary rocks range in age from Precambrian to Tertiary and the igneous rocks from late Cretaceous to probably middle Tertiary. The oldest rocks are varicolored mudstone, shale, and sandstone of the Belt series of late Precambrian age. They are overlain with slight unconformity by a moderately thick but incomplete section of Paleozoic rocks. The basal Paleozoic formation is the Flathead quartzite of Middle Cambrian age, which is overlain by alternating units of shale and carbonate rock : the Wolsey shale, the Meagher limestone, the Park shale, the Pilgrim dolomite, and the Red Lion formation, all of Cambrian age. A slight erosional unconformity between the Red Lion formation and the Maywood formation of late Devonian age marks a long interval of crustal stability in the area. The Maywood is overlain by the Jefferson dolomite and the Three Forks shale of Late Devonian and Mississippian age, and these in turn are conformably overlain by the Lodgepole and Mission Canyon limestones, a thick carbonate sequence of Mississippian age. A slight erosional unconformity separates the Mission Canyon limestone from the Amsden formation, which probably includes beds of both Mississippian and Pennsylvanian age. The Amsden is composed of a heterogeneous assemblage of arenaceous, argillaceous, dolomitic, and calcareous rocks and grades upward into the Quadrant formation of Pennsylvanian age, an alternation of quartzitic sandstone and dolomite. At the top of the Paleozoic section is the Phosphoria formation of Permian age, a thin unit of chert and quartzitic sandstone that contains a few thin phosphate beds. The basal Mesozoic unit is the Swift formation of late Jurassic age, a thin calcareous marine sandstone that overlies the Phosphoria with slight erosional unconformity. It is overlain by nonmarine shale and sandstone of the Morrison formation of late Jurassic age and the Kootenai formation of Early Cretaceous age. The Kootenai is overlain, possibly with slight erosional unconformity, by the Colorado formation an assemblage of marine dark shale and siliceous mudstone and nonmarine quartz-chert sandstone. The Colorado formation as here used includes beds of both Early and Late Cretaceous age. The Colorado in places grades upwards into a sequence of feldspathic sandstone and tuff beds here named the Slim Sam formation. Elsewhere within the area, the Slim Sam formation is absent, probably in part owing to erosion and in part nondeposition. Where present, the Slim Sam grades upward into a thick sequence of andesitic and quartz latitic volcanic rocks, comprising tuffs, lapilli tuffs, breccias, welded tuffs and flows, that are here named the Elkhorn Mountains volclinics and are probably entirely of Cretaceous age. Where the Slim Sam formation is absent, the Elkhorn Mountains volcanics rest with angular unconformity on beds as old as the Morrison. The pre-Tertiary layered rocks, aggregating more than 15,000 feet in thickness, were folded and intruded by igneous rocks of several types, and the area was uplifted and eroded to a terrain of mature relief, similar to that of the present. During the Oligocene epoch, volcanic sediments with interbreds of nonvolcanic gravel accumulated. These beds were in turn moderately eroded, and gravel of Miocene ( ?) age was deposited in channels within them. Subsequently, probably during the Pliocene epoch, the Tertiary beds were weakly deformed locally, and a pediment was cut across the Tertiary and older rocks in the southern part of the area. Fan gravel, in part of Recent origin and in part older, blankets parts of the pediment. Glacial deposits of at least two stages of Pleistocene glaciation are present in the higher mountains in the northern part of the area. The intrusive igneous rocks, except for a few felsite dikes of uncertain age, are divisible into two groups, primarily on the basis of structural relations and secondarily on the basis of composition and fabric. The older group of dioritic and andesitic rocks were intruded in part, if not wholly, prior to the main folding and are similar in chemical and mineralogical composition to the Elkhorn Mountains volcanics. They were probably emplaced throughout the period of volcanism that commenced in late Niobrara time and continued until late Cretaceous time. The younger group consists chiefly of quartzbearing phanerites but includes rocks ranging from gabbro to alaskitic granite and aplite. These rocks were emplaced after the main episode of folding and faulting. The Boulder batholith, composed dominantly of quartz monzonite, is the principal body of this younger group. The older igneous rocks metamorphosed the invaded rocks only slightly. In contrast, the younger intrusive bodies, and especially the batholith, altered and recrystallized the country rock in moderately broad belts, changing them to various types of hornfels, calcsilicate rock, marble, and vitreous quartzite. Concomitantly magnetite, garnet, axinite, and other high-temperature replacement minerals formed locally as products of additive metamorphism. The pre-Tertiary layered rocks of the southern Elkhorn Mountains are folded into northward-trending folds and are cut by many faults. The sedimentary rocks tend to be more tightly folded than the Elkhorn Mountains volcanics, although both were involved in the major folding. The principal folds of the area from east to west are : a major dome, a complex syncline with several second-order folds, and a remnant of a northward-plunging anticline, the major part of which was engulfed by the batholith. The folded rocks are cut by many faults of small to moderate displacement and by two faults of large displacement. Most of the faults were probably formed by the same forces that produced the folds. The origin of the two major faults, however, is uncertain, and may be related to igneous activity. The batholith crosscuts the folded structure and is in turn cut by small faults. Some parts of the area were elevated along steep normal faults in late Tertiary time. The southern part of the Elkhorn Mountains has been mountainous at least since early Oligocene time, and probably began to take form during the Cretaceous. As a consequence of long continued erosion, the modern topography reflects the structure and lithologic character of the underlying rocks except in a few areas blanketed by poorly consolidated Tertiary rocks and in the higher mountains where glaciation has been prominent. Silver, lead, zinc, and gold have been produced, either singly or, more typically, as a combination of metals from a number of types of ore deposits. Replacement deposits in carbonate rocks are the most common type, but veins, contact metamorphic deposits, and pipelike bodies of breccia cemented by ore and gangue minerals also are present. The Elkhorn mining district has the largest number of mines and the greatest variety of types of deposits. In the Tizer Basin several narrow goldbearing veins cut andesitic volcanic rocks, and in the southern part of the area sporadic small veins and replacement deposits occur in carbonate rocks. The mines and prospects of the area are described, and some suggestions for future prospecting are outlined. The application of geochemical prospecting techniques may prove of value, judging from the results of reconnaissance soil sampling in the vicinity of the Elkhorn mine.

Montana↗

Silt fraction heavy-mineral distributions in a lateritic environment: The rivers and insular shelf of north-central Puerto Rico

This fraction, which is enriched in heavy minerals relative to the sand fraction, is mainly detrital but contains a strong authigenic component. The authigenic silt heavy-mineral fraction is largely a product of the lateritic weathering and dominated by iron oxides and alterites. Grains of bladed rutile and leached ilmenite are common. Spatial variability in silt-fraction mineralogy is considerable. Within the Rio Cibuco system variability is related to compositional differences in rapidly eroding source rocks. On the shelf, silt heavy-mineral abundances are greatest at the river mouths and decrease seaward. Variability in the shelf samples is controlled primarily by source rivers and shelf sorting processes.

Puerto Rico↗

Insight into the geology of the East Antarctic hinterland: a study of sediment inclusions from ice cores of the Lake Vostok borehole

The borehole at the southern part of subglacial Lake Vostok has been drilled into an ice layer that has been refrozen from the lake water. This ice layer contains random sediment inclusions, eight of which have been studied using state-of the-art analytical techniques. Six inclusions comprise soft aggregates consisting mainly of clay-mica minerals and micron-sized quartz grains while two others are solid clasts of fine-grained cemented rocks. The largest rock clast consists of poorly-rounded quartz and minor amounts of accessory minerals and is classified as quartzose siltstone. More than twenty grains of zircon and monazite have been identified in this siltstone and dated by SIMS SHRIMP-II. Two age clusters have been recognized for these detrital grains, in the ranges 0.8−1.2 Ga and 1.6−1.8 Ga. The compositions of the rock clasts suggest that the bedrock situated to the west of Lake Vostok is sedimentary. The age data on the detrital accessory minerals suggest that the provenance of these sedimentary rocks − the Gamburtsev Mountains and Vostok Subglacial Highlands, is mainly represented by Paleoproterozoic and MesoproterozoicNeoproterozoic crustal provinces

Open-File Report↗

Sierra Nevada batholith

The Sierra Nevada batholith is localized in the axial region of a complex faulted synclinorium that coincides with a downfold in the Mohorovicic discontinuity and in P-wave velocity boundaries within the crust. Observed P-wave velocities are compatible with downward increase in the proportion of diorite, quartz diorite, and calcic granodiorite relative to quartz monzonite and granite in the upper crust, with amphibolite or gabbro-basalt in the lower crust, and with periodotite in the upper mantle. The synclinorium was formed in Paleozoic and Mesozoic strata during early and middle Mesozoic time in a geosyncline marginal to the continent. Granitic magmas are believed to have formed in the lower half of the crust at depths of 25 to 45 kilometers or more, primarily as a result of high radiogenic heat production in the thickened prism of crustal rocks. Magma was generated at different times in different places as the locus of downfolding shifted. It rose into the upper crust because it was less dense than rock of the same composition or residual refractory rocks. Refractory rocks and crystals that were not melted and early crystallized mafic minerals that settled from the rising magma thickened the lower crust. Wall and roof rocks settled around, and perhaps through, the rising magma and provided space for its continued rise. Erosion followed each magmatic episode, and 10 to 12 kilometers of rock may have been eroded away since the Jurassic and 7 to 10 kilometers since the early Late Cretaceous.

California↗

Geochemical Characterization of Mine Waste, Mine Drainage, and Stream Sediments at the Pike Hill Copper Mine Superfund Site, Orange County, Vermont

The Pike Hill Copper Mine Superfund Site in the Vermont copper belt consists of the abandoned Smith, Eureka, and Union mines, all of which exploited Besshi-type massive sulfide deposits. The site was listed on the U.S. Environmental Protection Agency (USEPA) National Priorities List in 2004 due to aquatic ecosystem impacts. This study was intended to be a precursor to a formal remedial investigation by the USEPA, and it focused on the characterization of mine waste, mine drainage, and stream sediments. A related study investigated the effects of the mine drainage on downstream surface waters. The potential for mine waste and drainage to have an adverse impact on aquatic ecosystems, on drinking- water supplies, and to human health was assessed on the basis of mineralogy, chemical concentrations, acid generation, and potential for metals to be leached from mine waste and soils. The results were compared to those from analyses of other Vermont copper belt Superfund sites, the Elizabeth Mine and Ely Copper Mine, to evaluate if the waste material at the Pike Hill Copper Mine was sufficiently similar to that of the other mine sites that USEPA can streamline the evaluation of remediation technologies. Mine-waste samples consisted of oxidized and unoxidized sulfidic ore and waste rock, and flotation-mill tailings. These samples contained as much as 16 weight percent sulfides that included chalcopyrite, pyrite, pyrrhotite, and sphalerite. During oxidation, sulfides weather and may release potentially toxic trace elements and may produce acid. In addition, soluble efflorescent sulfate salts were identified at the mines; during rain events, the dissolution of these salts contributes acid and metals to receiving waters. Mine waste contained concentrations of cadmium, copper, and iron that exceeded USEPA Preliminary Remediation Goals. The concentrations of selenium in mine waste were higher than the average composition of eastern United States soils. Most mine waste was potentially acid generating because of paste-pH values of less than 4 and negative net-neutralization potentials (NNP). The processed flotation-mill tailings, however, had a near neutral paste pH, positive NNP, and a few weight percent calcite. Leachate tests indicated that elements and compounds such as Al, Cd, Cu, Fe, Mn, Se, SO4, and Zn were leached from mine waste in concentrations that exceeded aquatic ecosystem and drinking-water standards. Mine waste from the Pike Hill mines was chemically and mineralogically similar to that from the Elizabeth and Ely mines. In addition, metals were leached and acid was produced from mine waste from the Pike Hill mines in comparable concentrations to those from the Elizabeth and Ely mines, although the host rock of the Pike Hill deposits contains significant amounts of carbonate minerals and, thus, a greater acid-neutralizing capacity when compared to the host rocks of the Elizabeth and Ely deposits. Water samples collected from unimpacted parts of the Waits River watershed generally contained lower amounts of metals compared to water samples from mine drainage, were alkaline, and had a neutral pH, which was likely because of calcareous bedrock. Seeps and mine pools at the mine site had acidic to neutral pH, ranged from oxic to anoxic, and generally contained concentrations of metals, for example, aluminum, cadmium, copper, iron, and zinc, that exceeded aquatic toxicity standards or drinking-water standards, or both. Surface waters directly downstream of the Eureka and Union mines were acidic, as indicated by pH values from 3.1 to 4.2, and contained high concentrations of some elements including as much as 11,400 micrograms per liter (?g/L) Al, as much as 22.9 ?g/L Cd, as much as 6,790 ?g/L Cu, as much as 23,300 ?g/L Fe, as much as 1,400 ?g/L Mn, and as much as 3,570 ?g/L Zn. The concentrations of these elements exceeded water-quality guidelines. Generally, in surface waters, the pH increased and the concentrations of these elemen

Scientific Investigations Report↗

Geologic setting and characteristic of mineral deposits in the central Wasatch Mountains, Utah

Base- and precious-metal deposits in the central Wasatch Mountains southeast of Salt Lake City were mined for more than 100 years beginning in 1868. Deposits present in the Park City, Little Cottonwood, and Big Cottonwood mining districts include Ag-Pb-Zn ± Cu ± Au replacements and veins, a low-grade porphyry Cu-Au deposit, Cu-bearing skarns, a quartz monzonite-type (low F) porphyry Mo deposit, and high sulfidation (quartz-alunite) Au deposits. Most production came from polymetallic replacement and vein deposits in the Park City mining district, which has a recorded production of more than 1.4 million oz Au, 253 million oz Ag, 2.7 billion lbs Pb, 1.5 billion lbs Zn, and 129 million lbs Cu from 1872 to 1978. Production in the Little and Big Cottonwood districts, mostly from Pb-Ag replacement deposits, was much smaller. Most mineral deposits in the central Wasatch Mountains are genetically related to the Wasatch igneous belt, a series of high-K calc-alkaline stocks and cogenetic volcanic rocks that formed about 41(?) to 30 Ma. The mineral deposits mostly formed near the end of magmatic activity between about 36 to 31.4 Ma. A subeconomic porphyry Mo deposit in the Little Cottonwood stock is notably younger having formed about 26 to 23.5 Ma. The intrusive rocks were emplaced mostly along the westward extension of the west-trending Uinta arch during a period of NW-SE-directed extension, and much of the mineralization in the Park City district was controlled by ENE-striking normal faults. About 15 degrees of eastward tilting of the central Wasatch Mountains during Late Cenozoic Basin and Range extension has resulted in progressively deeper levels of exposure from <1 km on the east to about 11 km on the west and in profound variations in the types of mineral deposits exposed in different parts of the range. Most deposits formed at paleodepths ≤5 km, and the most productive deposits in the Park City district formed at depths of 1 to 2 km. The porphyry Mo deposit in the Little Cottonwood stock formed at greater depths of about 6 km.

Utah↗