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At least 1,153 records · Page 64Linked to original sources

USGS2015

Geologic map of Kundelan ore deposits and prospects, Zabul Province, Afghanistan; modified from the 1971 original map compilations of K.I. Litvinenko and others

This map and cross sections are redrafted modified versions of the Geological map of the Kundelan ore deposit area, scale 1:10,000 (graphical supplement no. 18) and the Geological map of the Kundelan deposits, scale 1:2,000 (graphical supplement no. 3) both contained in an unpublished Soviet report by Litvinenko and others (1971) (report no. 0540). The unpublished Soviet report was prepared in cooperation with the Ministry of Mines and Industries of the Royal Government of Afghanistan in Kabul during 1971. This redrafted map and cross sections illustrate the geology of the main Kundelan copper-gold skarn deposit, located within the Kundelan copper and gold area of interest (AOI), Zabul Province, Afghanistan. Areas of interest (AOIs) of non-fuel mineral resources within Afghanistan were first described and defined by Peters and others (2007) and later by the work of Peters and others (2011a). The location of the main Kundelan copper-gold skarn deposit (area of this map) and the Kundelan copper and gold AOI is shown on the index map provided on this map sheet. The estimated resources of the Kundelan copper-gold skarn deposit are 21,400 metric tons (t) of copper, 1.6 t of gold, and 133.4 t of molybdenum at an average grade of 1.21 weight percent (wt. %) copper (ranging from 0.66 to 4.03 wt. % copper); 0.9 grams per metric ton (g/t) gold (ranging from 0.3 to 3.1 g/t gold); 0.14 wt. % molybdenum; and as much as 10 g/t silver and 0.03 wt. % bismuth (Peters and others, 2011b). Small past production of gold and base metals is also reported by Douvgal and others (1971) from many prospects within the Kundelan copper and gold AOI. Outside the skarn areas, argillic hydrothermal alteration is present (Abdullah and others, 1977). Most copper and gold prospects in the Kundelan copper and gold AOI are reported to contain commercial-grade ores of copper and (or) gold, and many prospect areas have potential for these commodities to be discovered in commercial volumes. Future initial mine exploration and later development in many of the prospects, and specifically in the Kundelan copper-gold skarn deposit, could result in near-term small- to medium-sized gold mining operations (Peters and others, 2011b). The redrafted map and cross sections reproduce the topology of rock units, contacts, faults, and so forth, of the original Soviet map and cross sections, and they include modifications based on our examination of these documents and our observations made during a brief field visit in August of 2010. We have attempted to translate the original Russian terminology and rock classifications into modern English geologic usage as literally as possible without changing any genetic or process-oriented implications in the original descriptions. We also use the age designations from the original Soviet maps, except for the phase I and II intrusive igneous rocks. Phase I and II igneous rocks are reassigned an Early Cretaceous age (from lower Paleogene) based on a uranium-lead (U-Pb) zircon SHRIMP analysis from quartz diorite, which yielded an age of 104±1 Ma (mega-annum). The information provided in the description of map units is from both the source report by Litvinenko and others (1971) and the original 1:10,000 scale map (graphical supplement no. 18), also from Litvinenko and others (1971). Because of the poor quality of the original map, some map features could not be identified and some features may be misinterpreted. The rock unit colors used on the redrafted maps and cross sections differ from the colors shown on the original Soviet version. Colors were selected according to the color and pattern scheme of the Commission for the Geological Map of the World (CGMW) at http://www.ccgm.org. Elevations on the cross sections are derived from the original Soviet topography and may not match the Global Digital Elevation Model (GDEM) topography used on the redrafted map of this report. Most hydrography derived from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) has not been included on our redrafted version of the map because of a poor fit with alluvial deposits from the unmodified original Soviet map (graphical supplement no. 18; Litvinenko and others, 1971).

Zabul Province↗

USGS2013

Probing the deep critical zone beneath the Luquillo Experimental Forest, Puerto Rico

Recent work has suggested that weathering processes occurring in the subsurface produce the majority of silicate weathering products discharged to the world's oceans, thereby exerting a primary control on global temperature via the well-known positive feedback between silicate weathering and CO 2 . In addition, chemical and physical weathering processes deep within the critical zone create aquifers and control groundwater chemistry, watershed geometry and regolith formation rates. Despite this, most weathering studies are restricted to the shallow critical zone (e.g. soils, outcrops). Here we investigate the chemical weathering, fracturing and geomorphology of the deep critical zone in the Bisley watershed in the Luquillo Critical Zone Observatory, Puerto Rico, from two boreholes drilled to 37.2 and 27.0 m depth, from which continuous core samples were taken. Corestones exposed aboveground were also sampled. Weathered rinds developed on exposed corestones and along fracture surfaces on subsurface rocks slough off of exposed corestones once rinds attain a thickness up to ~1 cm, preventing the corestones from rounding due to diffusion limitation. Such corestones at the land surface are assumed to be what remains after exhumation of similar, fractured bedrock pieces that were observed in the drilled cores between thick layers of regolith. Some of these subsurface corestones are massive and others are highly fractured, whereas aboveground corestones are generally massive with little to no apparent fracturing. Subsurface corestones are larger and less fractured in the borehole drilled on a road where it crosses a ridge compared with the borehole drilled where the road crosses the stream channel. Both borehole profiles indicate that the weathering zone extends to well below the stream channel in this upland catchment; hence weathering depth is not controlled by the stream level within the catchment and not all of the water in the watershed is discharged to the stream

Earth Surface Processes and Landforms↗

USGS1961

Graphic and algebraic solutions of the discordant lead-uranium age problem

Uranium-bearing minerals that give lead-uranium and lead—lead ages that are essentially in agreement, i.e. concordant, generally are considered to have had a relatively simple geologic history and to have been unaltered since their deposition. The concordant ages obtained on such materials are, therefore, assumed to approach closely the actual age of the minerals. Many uranium-bearing samples, particularly uranium ores, give the following discordant age sequences; Pb 206 U 238 < Pb 207 U 235 ⪡ Pb 207 Pb 206 "> Pb 206 U 238 <Pb 207 U 235 ⪡Pb 207 Pb 206 or, less frequently, Pb 207 Pb 206 ⪡ Pb 207 U 235 < Pb 206 U 238 "> Pb 207 Pb 206 ⪡Pb 207 U 235 <Pb 206 U 238 . These discordant age sequences have been attributed most often to uncertainties in the common lead correction, selective loss of radio-active daughter products, loss or gain of lead or uranium, or contamination by an older generation of radiogenic lead. The evaluation of discordant lead isotope age data may be separated into two operations. The first operation, with which this paper is concerned, is mechanical in nature and involves the calculation of the different possible concordant ages corresponding to the various processes assumed to have produced the discordant ages. The second operation is more difficult to define and requires, in part, some personal judgement. It includes a synthesis of the possible concordant age solutions with other independent geologic and isotopic evidence. The concordant age ultimately chosen as most acceptable should be consistent not only with the known events in the geologic history of the area, the age relations of the enclosing rocks, and the mineralogic and paragenetic evidence, but also with other independent age measurements and the isotopic data obtained on the lead in related or associated non-radioactive minerals. The calculation of the possible concordant ages from discordant age data has been greatly simplified by Wetherill's graphical method of plotting the mole ratios of radiogenic Pb 206 U 238 "> Pb 206 U 238 ( N 206 N 238 "> N 206 N 238 ) vs. radiogenic Pb 207 U 235 "> Pb 207 U 235 ( N 207 N 235 "> N 207 N 235 ) after correcting for the contaminating common Pb 206 and Pb 207 . The linear relationships noted in this graphical procedure have been extended to plots of the mole ratios of total Pb 206 U 238 "> Pb 206 U 238 ( t N 206 N 238 "> t N 206 N 238 ) vs. total Pb 207 U 235 "> Pb 207 U 235 ( t N 207 N 235 "> t N 207 N 235 ). This modification permits the calculation of concordant ages for unaltered samples using only the Pb 207 Pb 206 "> Pb 207 Pb 206 ratio of the contaminating common lead. If isotopic data are available for two samples of the same age, x and y , from the same or related deposits or outcrops, graphs of the normalized difference ratios [ ( N 206 N 204 )x − ( N 206 N 204 )y ( N 238 N 204 )x −( N 238 N 204 )y ] vs. [ ( N 207 N 204 )x − ( N 207 N 204 )y ( N 235 N 204 )x −( N 235 N 204 )y ] "> [(N 206 N 204 )x − (N 206 N 204 )y(N 238 N 204 )x −(N 238 N 204 )y] vs. [(N 207 N 204 )x − (N 207 N 204 )y(N 235 N 204 )x −(N 235 N 204 )y] can give concordant ages corrected for unknown amounts of a common lead with an unknown Pb 207 / Pb 206 ratio. (If thorium is absent the difference ratios may be normalized with the more abundant index isotope, Pb 208 .) Similar plots of tho normalized, difference ratios for three genetically related samples ( x − y ) and( x − z ), will give concordant ages corrected, in addition, for either one unknown period of past alteration or initial contamination by an older generation of radiogenic lead of unknown Pb 207 /Pb 206 ratio. Practical numerical solutions for many of tho concordant age calculations are not currently available. However, the algebraic equivalents of these new graphical methods give equations which may be programmed for computing machines. For geologically probable parameters the equations of higher order have two positive real roots that rapidly converge on the exact concordant ages corrected for original radiogenic lead and for loss or gain of lead or uranium. Modifications of these general age equations expanded only to the second degree have been derived for use with desk calculators. These graphical and algebraic methods clearly suggest both the type and minimum number of samples necessary for adequate mathematical analysis of discordant lead isotope age data. This mathematical treatment also makes it clear that discordant lead isotope data alone cannot provide the basis for the choice of one of the possible concordant age solutions. The new equations, in particular, provide an incentive to improve our physical constants, analytical techniques and sampling methods in order that we may derive all of the useful geologic information that is available in a comprehensive lead isotope age study.

Geochimica et Cosmochimica Acta↗

USGS1995

The generation of oceanic rhyolites by crystal fractionation: the basalt-rhyolite association at Volcán Alcedo, Galápagos archipelago

Alcedo volcano is one of six shield volcanoes on Isabela Island in the western Galápagos Islands. Although Alcedo is dominantiy basaltic, it is unusual in that it also has erupted ∼1 km 3 of rhyolite. The rhyolitic phase marked a 10-fold decrease in the mass-eruption rate of the volcano, and the volcano has returned to erupting basalt. The basalts are tholeiitic and range from strongly to sparsely porphyritic. Olivine and plagiodase are the liquidus phases in the most primitive basalts. The MgO and Ni concentrations in the most primitive basalts indicate that they have undergone substantial differentiation since extraction from the mantle. The rhyolites contain the assemblage oligoclase-augite-titanomagnetite-fayalite-apatite and sparse xenoliths of quenched basalt and cumulate gabbros. Intermediate rocks are very rare, but some are apparently basaltrhyolite hybrids, and others resulted from differentiation of tholeiitic magma. Several modeling approaches and Sr-, Nd-, and O-isotopic data indicate that the rhyolites resulted from ∼ 90% fractionation (by weight) of plagiodase, augite, titanomagnetite, olivine, and apatite from the most primitive olivine tholeiite. The data are inconsistent with the rhyolites originating by crustal anatexis. The extreme Daly gap may be caused by the large increase in viscosity as the basaltic magma differentiates to intermediate and siliceous compositions; highly evolved magmas are eruptible only after they become saturated with volatiles by second boiling. The close association of the hybrid intermediate magmas and magmatic inclusions with the climactic plinian eruption indicates mixing between mafic and silicic magmas immediately before eruption. Rhyolite production was favored by the decrease in supply of basaltic magma as Alcedo was carried away from the focus of the Galápagos hotspot. A three-stage model for the magmatic evolution of a Galápagos volcano is proposed. In the first stage, the supply of basaltic magma is large. Basaltic magma continually intrudes the subcaldera magma chamber, buffering the magmas' compositional and thermal evolution. As the volcano is carried away from the basaltic source, the magma chamber is allowed to cool and differentiate, as exemplified by Alcedo's rhyolitic phase. Finally, the volcano receives even smaller influx of basalt, so a large magma chamber cannot be sustained, and the volcano shifts to isolated basaltic eruptions.

Galapagos Islands↗

USGS2021

Geophysical and video logs of selected wells at and near the former Naval Air Warfare Center Warminster, Bucks County, Pennsylvania, 2017-19

The U.S. Geological Survey (USGS) collected borehole geophysical and video logs in 17 open-hole wells in Northampton, Warminster, and Warwick Townships, Bucks County, Pennsylvania during 2017–19 to support detailed groundwater investigations at and near the former Naval Air Warfare Center (NAWC) Warminster, where groundwater contamination with per- and polyfluoroalkyl substances (PFAS) had become a concern since 2014. The area is underlain by the Triassic Stockton Formation, which forms a fractured-sedimentary-rock aquifer used for private, industrial, and public drinking-water supply. The geophysical and video logs were used to characterize the boreholes and identify potential water-bearing fractures for subsequent detailed investigations. Of the 17 wells that were logged, subsequent investigations were conducted by USGS in 15 wells and included hydraulic tests of discrete water-bearing zones using a straddle-packer system in 13 wells and depth-discrete point sampling in 2 wells. These 15 wells ranged in depth from about 210 to 604 feet (ft) below land surface (bls) and included six new 6-inch diameter wells drilled to initial depths of 600 ft bls on the former NAWC Warminster base property in 2018 and nine 8- to 12-inch diameter existing former production or unused test wells. Partial geophysical or video logs also were collected by USGS during 2018 in two other wells that were not included in subsequent detailed investigations. Most wells had numerous water-bearing fractures or openings throughout the depth of the open boreholes. Most of these water-bearing features appeared to be openings parallel to bedding or high-angle fractures approximately orthogonal to bedding. Casing lengths ranged from about 19 to 93 ft bls. Depth to the ambient water level at the time of logging ranged from about 1.8 ft above land surface in a flowing well to about 55 ft bls. Measured borehole flow was predominantly downward in most of the deepest wells (greater than 400 ft), which were commonly located at the highest land-surface elevations, and contained inflow from fractures at relatively shallow depths and outflow through fractures near or below depths of 500 ft bls. Borehole flow was predominantly upward in most wells less than 400 ft in depth.

Pennsylvania↗

USGS2005

New data for Late Pleistocene Pinedale alpine glaciation from southwestern Colorado

New cosmogenic surface-exposure ages of moraine-crest boulders from southwestern Colorado are compared with published surface-exposure ages of boulders from moraine complexes in north-central Colorado and in west-central (Fremont Lake basin) Wyoming. 10Be data sets from the three areas were scaled to a single 10Be production rate of 5.4 at/g/yr at sea level and high latitude (SLHL), which represents the average 10Be production rate for two high-altitude, mid-latitude sites in the western United States (US) and Austria. Multiple nuclide ages on single boulders indicate that this 10Be production rate yields ages comparable to those calculated with a commonly used 36Cl production scheme. The average age and age range of moraine-crest boulders on terminal moraines at the southwestern Colorado and Wyoming sites are similar, indicating a retreat from their positions ???16.8 36Cl ka (Cosmogenic ages in this paper are labeled 10Be or 36Cl ka or just ka when both 10Be or 36Cl ages are being discussed; radiocarbon ages are labeled 14C ka, calibrated radiocarbon are labeled cal ka, and calendar ages are labeled calendar ka. Errors (??1??) associated with ages are shown in tables. Radiocarbon ages were calibrated using the data of Hughen et al. (Science 303 (2004) 202). This suggests a near-synchronous retreat of Pinedale glaciers across a 470-km latitudinal range in the Middle and Southern Rocky Mountains. Hypothetical corrections for snow shielding and rock-surface erosion shifts the time of retreat to between 17.2 and 17.5 10Be ka at Pinedale, Wyoming, and between 16.3 and 17.3 36Cl ka at Hogback Mountain, Colorado. ?? 2004 Elsevier Ltd. All rights reserved.

Quaternary Science Reviews↗

USGS1959

Iron-ore resources of the United States including Alaska and Puerto Rico, 1955

The importance of iron ore, the basic raw material of steel, as a fundamental mineral, resource is shown by the fact that about 100 million long tons of steel is used annually in the economy of the United States, as compared with a combined total of about 5 million long tons of copper, lead, zinc, and aluminum. Satisfying this annual demand for steel requires about 110 million tons of iron ore and 70 million tons of scrap iron and steel. The average annual consumption of iron ore in the United States from 1951 to 1955, inclusive, was about 110 million long tons, which is about twice the annual average from 1900 to 1930. Production of iron ore in the United States in this 5-year period averaged approximately 100 million long tons annually, divided by regions as follows (in percent): Lake Superior, 84.1; southeastern, 6.7; western, 6.7; northeastern, 1.4; and central and gulf, 1.1. Mining of iron ore began in the American Colonies about 1619, and for 225 years it was limited to eastern United States where fuel and markets were readily available. Production of iron ore from the Lake Superior region began in 1846; the region became the leading domestic source by 1890, and the Mesabi range in Minnesota has been the world's most productive area since 1896. Proximity of raw materials, water transportation, and markets has resulted in centralization of the country's iron and steel industry in the lower Great Lakes area. Increased imports of iron ore being delivered to eastern United States as well as demands for steel in nearby markets have given impetus to expansion in the steel-making capacity in this area. The four chief iron-ore minerals - hematite, liminite, magnetite, and siderite - are widely distributed but only locally form deposits of sufficient tonnage and grade to be commercially valuable at the present time. The iron content of these minerals, of which hematite is the most important, ranges from 48 percent in siderite to 72 percent in magnetite, but as these minerals are associated with other rock-forming minerals, the iron content of marketable ore has a lower range from 30 to 67 percent. Chemical constituents other than iron also are important in determining the marketability of iron ore. Although some iron ores can be used in the blast furnace as mined, others must first be improved either chemically by reduction of undesirable constituents, or physically by aggregation. Phosphorus and sulfur particularly are common deleterious elements; excessive silica is also undesirable but within certain limits can be controlled by additional flux. Lime and magnesia are beneficial in specified amounts because of their fluxing qualities, and a small amount of alumina improves the fluidity of slag. Manganese is especially desirable as a deoxidizing and desulfurizing agent. Titanium, chromium, and nickel must also be considered in the use of ore containing these elements. The principal iron-ore deposits in the United States have been formed by three processes. Hematite-bearing bedded deposits such as those at Birmingham, Ala., are marine sedimentary rocks which, except for weathering along the outcrop, have remained practically unaltered since deposition. Deposits of the Lake Superior region, also in sedimentary strata, originally had a slightly lower iron content than those at-Birmingham, but ore bodies of hematite and limonite were formed by removal of other constituents in solution after deposition of the beds, with a relative increase of iron content in the material remaining. Limestone adjacent to igneous intrusions has been replaced by magnetite deposits at Cornwall, Pa., and by hematite-magnetite deposits near Cedar City, Utah. Magnetite deposits in New Jersey and in the Adirondack Mountains of New York are generally believed to have been formed by replacement of grains of other minerals in metamorphic rocks. Iron-ore resources are made up of reserves of iron ore, material usable under existing economic and technologic conditions; and potential ore, material likely to become usable under more favorable conditions. The tonnage and grade of material of combined reserves and potential ore in each of the deposits known or believed to contain at least 200,000 long tons of iron-ore resources are tabulated in this report, and numerous sources of additional information are given in a selected bibliography. The total domestic iron-ore resources are estimated at approximately 75,000 million long tons of crude ore. About 10,000 million tons of the resources is reserves of crude ore that will probably yield 5,500 million tons of concentrates and direct-shipping ore. About 65,000 million tons is potential ore and may yield 25,000 million tons of concentrates and some direct-shipping ore.

Bulletin↗

USGS2005

Interpretation of geophysical logs, aquifer tests, and water levels in wells in and near the North Penn Area 7 Superfund site, Upper Gwynedd Township, Montgomery County, Pennsylvania, 2000-02

Ground water in the vicinity of various industrial facilities in Upper Gwynedd Township and Lansdale Borough, Montgomery County, Pa., is contaminated with various volatile organic compounds (VOCs). The 2-square-mile area was placed on the National Priorities List as the North Penn Area 7 Superfund site by the U.S. Environmental Protection Agency (USEPA) in 1989. The U.S. Geological Survey (USGS) conducted geophysical logging, aquifer testing, water-level monitoring, and streamflow measurements in the vicinity of North Penn Area 7 beginning autumn 2000 to assist the USEPA in developing an understanding of the hydrogeologic framework in the area as part of the USEPA Remedial Investigation. The study area is underlain by Triassic and Jurassic-age sandstones, siltstones, and shales of the Lockatong Formation and the Brunswick Group. Regionally, these rocks strike northeast and dip to the northwest. The sequence of rocks form a fractured-sedimentary-rock aquifer that acts as a set of confined to partially confined layered aquifers of differing permeabilities. The aquifers are recharged by precipitation and discharge to streams and wells. The Wissahickon Creek headwaters are less than 1 mile northeast of the study area, and this stream flows southwest to bisect North Penn Area 7. Ground water is pumped in the vicinity of North Penn Area 7 for industrial use and public supply. The USGS collected geophysical logs for 16 wells that ranged in depth from 50 to 623 feet. Aquifer-interval-isolation testing was done in 9 of the 16 wells, for a total of 30 zones tested. A multiple-well aquifer test was conducted by monitoring the response of 14 wells to pumping a 600-ft deep production well in February and March 2002. In addition, water levels were monitored continuously in three wells in the area and streamflow was measured quarterly at two sites on Wissahickon Creek from December 2000 through September 2002. Geophysical logging identified water-bearing zones associated with high-angle fractures and bedding-plane openings throughout the depth of the boreholes. Heatpulse-flowmeter measurements under nonpumping, ambient conditions indicated that borehole flow, where detected, was in the upward direction in three of the eight wells and in the downward direction in three wells. In two wells, both upward and downward flow were measured. Heatpulse-flowmeter measurements under pumping conditions were used to identify the most productive intervals in wells. Correlation of natural-gamma-ray and single-point-resistance logs indicated that bedding in the area probably strikes about 40 degrees northeast and dips from 6 to 7 degrees northwest. Aquifer intervals isolated by inflatable packers in wells were pumped to test productivity and to collect samples to determine chemical quality of water produced from the interval. Interval-isolation testing confirmed the presence of vertical hydraulic gradients indicated by heatpulse-flowmeter measurements. The specific capacities of isolated intervals ranged over two orders of magnitude, from 0.02 to more than 3.6 gallons per minute per foot. Intervals adjacent to isolated pumped intervals showed little response to pumping the isolated zone. The presence of vertical hydraulic gradients and lack of adjacent-interval response to pumping in isolated intervals indicate a limited degree of vertical hydraulic connection between the aquifer intervals tested. Concentrations of most VOC contaminants generally were highest in well-water samples from the shallowest isolated intervals, with some exceptions. Trichloroethylene, cis-1,2-dichloroethylene, and toluene were the most frequently detected VOCs, with maximum concentrations of greater than 340, 680, and greater than 590 micrograms per liter, respectively. Results of the aquifer test with multiple observation wells showed that water levels in 4 of the 14 wells declined in response to pumping. The four wells that responded to pumping are either along str

Scientific Investigations Report↗

USGS2012

Physical setting and natural sources of exposure to carcinogenic trace elements and radionuclides in Lahontan Valley, Nevada

In Lahontan Valley, Nevada, arsenic, cobalt, tungsten, uranium, radon, and polonium-210 are carcinogens that occur naturally in sediments and groundwater. Arsenic and cobalt are principally derived from erosion of volcanic rocks in the local mountains and tungsten and uranium are derived from erosion of granitic rocks in headwater reaches of the Carson River. Radon and 210Po originate from radioactive decay of uranium in the sediments. Arsenic, aluminum, cobalt, iron, and manganese concentrations in household dust suggest it is derived from the local soils. Excess zinc and chromium in the dust are probably derived from the vacuum cleaner used to collect the dust, or household sources such as the furnace. Some samples have more than 5 times more cobalt in the dust than in the local soil, but whether the source of the excess cobalt is anthropogenic or natural cannot be determined with the available data. Cobalt concentrations are low in groundwater, but arsenic, uranium, radon, and 210 Po concentrations often exceed human-health standards, and sometime greatly exceed them. Exposure to radon and its decay products in drinking water can vary significantly depending on when during the day that the water is consumed. Although the data suggests there have been no long term changes in groundwater chemistry that corresponds to the Lahontan Valley leukemia cluster, the occurrence of the very unusual leukemia cluster in an area with numerous 210 Po and arsenic contaminated wells is striking, particularly in conjunction with the exceptionally high levels of urinary tungsten in Lahontan Valley residents. Additional research is needed on potential exposure pathways involving food or inhalation, and on synergistic effects of mixtures of these natural contaminants on susceptibility to development of leukemia.

Nevada↗

USGS2010

Water quality and ecological condition of urban streams in Independence, Missouri, June 2005 through December 2008

To identify the sources of selected constituents in urban streams and better understand processes affecting water quality and their effects on the ecological condition of urban streams and the Little Blue River in Independence, Missouri the U.S. Geological Survey in cooperation with the City of Independence Water Pollution Control Department initiated a study in June 2005 to characterize water quality and evaluate the ecological condition of streams within Independence. Base-flow and stormflow samples collected from five sites within Independence, from June 2005 to December 2008, were used to characterize the physical, chemical, and biologic effects of storm runoff on the water quality in Independence streams and the Little Blue River. The streams draining Independence-Rock Creek, Sugar Creek, Mill Creek, Fire Prairie Creek, and the Little Blue River-drain to the north and the Missouri River. Two small predominantly urban streams, Crackerneck Creek [12.9-square kilometer (km2) basin] and Spring Branch Creek (25.4-km2 basin), were monitored that enter into the Little Blue River between upstream and downstream monitoring sites. The Little Blue River above the upstream site is regulated by several reservoirs, but streamflow is largely uncontrolled. The Little Blue River Basin encompasses 585 km2 with about 168 km2 or 29 percent of the basin lying within the city limits of Independence. Water-quality samples also were collected for Rock Creek (24.1-km2 basin) that drains the western part of Independence. Data collection included streamflow, physical properties, dissolved oxygen, chloride, metals, nutrients, common organic micro-constituents, and fecal indicator bacteria. Benthic macroinvertebrate community surveys and habitat assessments were conducted to establish a baseline for evaluating the ecological condition and health of streams within Independence. Additional dry-weather screenings during base flow of all streams draining Independence were conducted to identify point-source discharges and other sources of potential contamination. Regression models were used to estimate continuous and annual flow-weighted concentrations, loadings, and yields for chloride, total nitrogen, total phosphorus, suspended sediment, and Escherichia coli bacteria densities. Base-flow and stormflow water-quality samples were collected at five sites within Independence. Base-flow samples for Rock Creek and two tributary streams to the Little Blue River exceeded recommended U.S. Environmental Protection Agency standards for the protection of aquatic life for total nitrogen and total phosphorus in about 90 percent of samples, whereas samples collected at two Little Blue River sites exceeded both the total nitrogen and total phosphorus standards less often, about 30 percent of the time. Dry-weather screening identified a relatively small number (14.0 percent of all analyses) of potential point-source discharges for total chlorine, phenols, and anionic surfactants. Stormflow had larger median measured concentrations of total common organic micro-constituents than base flow. The four categories of common organic micro-constituents with the most total detections in stormflow were pesticides (100 percent), polyaromatic hydrocarbons and combustion by-products (99 percent), plastics (93 percent), and stimulants (91 percent). Most detections of common organic micro-constituents were less than 2 micrograms per liter. Median instantaneous Escherichia coli densities for stormflow samples showed a 21 percent increase measured at the downstream site on the Little Blue River from the sampled upstream site. Using microbial source-tracking methods, less than 30 percent of Escherichia coli bacteria in samples were identified as having human sources. Base-flow and stormflow data were used to develop regression equations with streamflow and continuous water-quality data to estimate daily concentrations, loads, and yields of various water-quality contaminants.

Scientific Investigations Report↗

USGS2021

National Park Service Vegetation Mapping Inventory Program: Great Smoky Mountains National Park vegetation mapping project

The National Park Service (NPS) Vegetation Mapping Inventory (VMI) Program is an effort to classify, describe, and map existing vegetation communities in national park units throughout the United States. The NPS VMI Program is managed by the NPS Natural Resource Stewardship and Science Inventory and Monitoring Program and provides baseline vegetation information to natural resource managers, researchers, and ecologists. The U.S. Geological Survey Upper Midwest Environmental Sciences Center, NatureServe, and NPS Great Smoky Mountains National Park (GRSM, also referred to as the “Park”) have completed vegetation classification and mapping of GRSM, including the Foothills Parkway, for the NPS VMI Program. Mappers, ecologists, and botanists collaborated to affirm vegetation types of GRSM and to determine how best to map the vegetation types by using aerial imagery. A vegetation classification developed in 2003 by NatureServe and the NPS served as a foundation to further classify and map the vegetation types of the Park. Data from an additional 10 vegetation plots supported vegetation types either rare or not documented in the 2003 classification. Data from 203 verification sites were collected to test the field key to vegetation types and the application of vegetation types to a sample set of map polygons. Furthermore, data from 972 accuracy assessment (AA) sites were collected (of which 966 were used to test accuracy of the vegetation map layer). This GRSM vegetation mapping project identified 112 vegetation types consisting of 105 association types in the U.S. National Vegetation Classification (USNVC), 2 “park-special” types, 1 “map-special” type, and 4 cultural types in the USNVC. To map the vegetation and land cover of GRSM, 52 map classes were developed. Of these 52 map classes, 46 represent natural (including ruderal) vegetation types, most of which types are recognized in the USNVC. For the remaining 6 of the 52 map classes, 4 represent USNVC cultural types for agricultural and developed areas, and 2 represent non-USNVC types for nonvegetated open water and nonvegetated rock. Features were interpreted from viewing four-band digital aerial imagery using digital onscreen three-dimensional stereoscopic workflow systems in geographic information systems; digital aerial imagery was collected during September 23–October 30, 2015. The interpreted data were digitally and spatially referenced, thus making the spatial-database layers usable in a geographic information system. Polygon units were mapped to either a 0.5- or 0.25- hectare (ha) minimum mapping unit, depending on vegetation type. A geodatabase containing several feature-class layers and tables provides the locations and data of USNVC vegetation types (vegetation map layer), vegetation plots, verification sites, AA sites, project boundary extent, and aerial image centers and flight lines. Covering 210,875 ha, the feature-class layer and related tables for the vegetation map layer provide 34,084 polygons of detailed attribute data when special modifiers are not considered (average polygon size of 6.2 ha) and 36,589 polygons of detailed attribute data when special modifiers are considered (average polygon size of 5.8 ha). Each map polygon is assigned a map-class code and name and, when applicable, are linked to USNVC classification tables within the geodatabase. The vegetation map extent includes the administrative boundary for GRSM and the Foothills Parkway. A summary report, generated from the vegetation map layer, concludes that the 46 map classes representing natural (including ruderal) vegetation types apply to 99.2% of polygons (33,797 polygons; average size of 6.2 ha) and cover 98.6% of the Park (207,971.4 ha). Further broken down, map classes representing natural vegetation types indicate that the Park is 97.7% forest and woodland (205,882.5 ha), 0.6% shrubland (1,174.6 ha), and 0.4% herbaceous (914.3 ha). Map classes representing cultural vegetation types apply to 0.8% of polygons (259 polygons; average size of 4.9 ha) and cover 0.6% of the Park (1,277.4 ha). Map classes representing nonvegetation open and flowing water and unvegetated rock apply to 0.08% of polygons (28 polygons; average size of 58.1 ha) and cover 0.8% of the Park (1,625.9 ha). A thematic AA study was completed of map classes representing the natural (including ruderal) vegetation types of the Park. Initial AA results were discussed with NPS staff from the Park. Following input from NPS staff on how to handle map classes that fell below accuracy standards, adjustments were made to the vegetation map layer. Final results indicate an overall accuracy of 80.64% (kappa index of 79.96% for chance agreements) based on data from 966 of the 972 AA sites. Most individual map-class themes exceed the NPS VMI Program standard of 80% with a 90% confidence interval. The GRSM vegetation mapping project delivers many geospatial and vegetation data products, including an in-depth project report discussing methods and results, which includes map classification and map-class descriptions. This suite of products also includes descriptions and a field key to vegetation types; a database of vegetation plots, verification sites, and AA sites; digital images of field sites; field data sheets; digital aerial imagery; hardcopy and digital maps; a geodatabase of vegetation and land cover (map layer), field sites (vegetation plots, verification sites, and AA sites), aerial imagery index, project boundary, and metadata; and a contingency table listing AA results. Geospatial products are projected in the Universal Transverse Mercator, Zone 17 North, by using the North American Datum of 1983. Information on the NPS VMI Program and completed mapping projects are on the internet at https://www.nps.gov/im/vegetation-inventory.htm.

North Carolina, Tennessee↗

USGS1975

Building stones of our Nation's Capital

The buildings of our Nation's Capital serve as an unusual geologic display, for the city has been constructed with rocks from quarries throughout the United States and many distant lands. Each building is a unique museum that not only displays the important features of various stones and the geologic environment in which they were formed, but also serves as an historic witness to the city's growth and to the development of its architecture. This booklet describes the source and appearance of the stones used in Washington, D.C.; it includes a map and a walking guide to assist the visitor in examining them.

General Information Product↗

USGS2018

Quartz-pebble-conglomerate gold deposits

Quartz-pebble-conglomerate gold deposits represent the largest repository of gold on Earth, largely due to the deposits of the Witwatersrand Basin, which account for nearly 40 percent of the total gold produced throughout Earth’s history. This deposit type has had a controversial history in regards to genetic models. However, most researchers conclude that they are paleoplacer deposits that have been modified by metamorphism and hydrothermal fluid flow subsequent to initial sedimentation. The deposits are found exclusively within fault-bounded depositional basins. The periphery of these basins commonly consists of granite-greenstone terranes, classic hosts for lode gold that source the detrital material infilling the basin. The gold reefs are typically located along unconformities or, less commonly, at the top of sedimentary beds. Large quartz pebbles and heavy-mineral concentrates are found associated with the gold. Deposits that formed prior to the Great Oxidation Event (circa 2.4 giga-annum [Ga]) contain pyrite, whereas younger deposits contain iron oxides. Uranium minerals and hydrocarbons are also notable features of some deposits. Much of the gold in these types of deposits forms crystalline features that are the product of local remobilization. However, some gold grains preserve textures that are undoubtedly of detrital origin. Other heavy minerals, such as pyrite, contain growth banding that is truncated along broken margins, which indicates that they were transported into place as opposed to forming by in situ growth in a hydrothermal setting. The ore tailings associated with these deposits commonly contain uranium-rich minerals and sulfides. Oxidation of the sulfides releases sulfuric acid and mobilizes various metals into the environment. The neutralizing potential of the tailings is minimal, since carbonate minerals are rare. The continuity of the tabular ore bodies, such as those of the Witwatersrand Basin, has allowed these mines to be the deepest in the world. The extreme depths create engineering complications and safety issues for the miners, such as rock bursts as a result of pressure release. The richness of these deposits makes them a desirable exploration target. However, the likelihood of future discoveries is minimal. Small deposits found in the United States include those found at Nemo in the Black Hills of South Dakota and Deep Lake in the Sierra Madre of Wyoming.

Scientific Investigations Report↗

USGS2015

Lithology, hydrologic characteristics, and water quality of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas

A study to assess the potential of the Arkansas River Valley alluvial aquifer in the vicinity of Van Buren, Arkansas, as a viable source of public-supply water was conducted by the U.S. Geological Survey in cooperation with the Little Rock, District, U.S. Army Corps of Engineers. An important study component was to identify possible changes in hydrologic conditions following installation of James W. Trimble Lock and Dam 13 (December 1969) on the Arkansas River near the study area. Data were gathered for the study in regard to the lithology, hydrologic characteristics, and water quality of the aquifer. Lithologic information was obtained from drillers’ logs of wells drilled from 1957 through 1959. Water-quality samples were collected from 10 irrigation wells and analyzed for inorganic constituents and pesticides. To evaluate the potential viability of the alluvial aquifer in the Van Buren area, these data were compared to similar stratigraphic, lithologic, and groundwater-quality data from the Arkansas River Valley alluvial aquifer at Dardanelle, Ark., where the aquifer provides a proven, productive, sole-source of public-supply water. Drillers’ logs for 59 wells in the Van Buren study area revealed well depths ranging from 25 to 52 feet (ft), with a mean depth of 42 ft. The thickness of the lower sand/gravel interval serving as the water-producing zone ranged from 5 to 47 ft, with a mean thickness of 29 ft. The presence of gravel was noted in only 4 of 59 well logs available for review from the study area. Percent sand was calculated from well logs in the study area, and these sand percentages were overlain onto an orthophotograph map to examine the areal distribution of sand percentage in relation to geomorphologic features of the flood plain in the study area. The logs denoting the greatest percent sand tend to occur in areas near to the river and on the concave (point bar) side of abandoned channels, while the lower percent sand tends to occur on the convex (channel fill and backswamp deposits) side of the abandoned channels. Comparison of hydrographs from water levels collected between 1957 and 1972 to cumulative departure from mean monthly and mean annual precipitation showed overall good fit and explained the long-term decreasing water levels from the earliest period of record through October 1967, followed by a sharp rise in water levels concurrent with rises in cumulative departure from mean monthly and mean annual precipitation. Hydrographs for four wells ranging from 0.8 to 4.5 miles upstream from the dam and potentially affected by rising river stage were compared to graphs of river stage and cumulative departure from mean monthly precipitation. Water levels for these wells showed minimal discernible effect by rising river stage following dam completion. Periods of increased precipitation compared closely to increases in water level for all hydrographs, regardless of river stage, and periods of no precipitation resulted in declining water levels, although river stage continued to slowly rise during these same periods. The Arkansas River has greater salinity than local groundwater, providing a quantitative tracer for any groundwater recharge originating from the river. Comparison of predam and postdam groundwater-chloride concentrations showed no increase in chloride concentrations after dam installation, which is consistent with hydrologic data. These data suggest that the dominant source of groundwater recharge in the Arkansas River Valley alluvial aquifer is infiltration of precipitation through proximal, coarse channel deposits, with minimal influx of river water. Groundwater-quality data collected from 10 wells in the study area indicated a calcium-bicarbonate water type. No primary drinking-water standards were exceeded for any constituents, and iron and manganese were the only constituents exceeding secondary drinking-water regulations. Six of the 10 well-water samples were analyzed for the presence of pesticides, as row-crop agriculture is the dominant land use in the study area. Six herbicide compounds and one herbicide metabolite were detected at concentrations substantially below those of the Federal primary drinking-water standards and health advisories. The hydrologic and geochemical data gathered for this study provide a qualitative assessment of the potential of the Arkansas River Valley alluvial aquifer as a source of public water supply in the Van Buren area. Results indicate minimal influx of water from the Arkansas River, and recharge to the aquifer appears to be dominantly by infiltration of precipitation through overlying alluvium. If vertical wells are used as a source of public water supply, then several wells will have to be used in combination at relatively low pumping rates and placed in areas with a greater percent sand. Use of a horizontal well configuration near the river to increase production may depend on infiltration of river water to supplement water removed from storage, especially where areas of lower permeability sediments might be encountered within the surrounding alluvium. If a poor hydraulic connection exists between the river and the alluvium, as indicated by this study, then production will depend on ample precipitation and recharge throughout the year and groundwater storage sufficient to prevent declining water levels where pumping rates exceed recharge.

Arkansas↗

USGS1983

Mineral resource potential map of the Raywood Flat Roadless Areas, Riverside and San Bernardino counties, California

Geologic, geochemical, and geophysical studies within the Raywood "Flat Roadless Areas, together with an investigation of mines and prospects within the further planning area, resulted in (1) identification of nonmetallic mineral resources at a marble mine in the further planning area and (2) recognition of a small area in the recommended wilderness that has moderate potential for base-metal resources. Except for these two areas of identified and suspected resources, we did not observe indications of resource potential elsewhere in the Raywood Flat Roadless Areas. The area having nonmetallic mineral resources is in the vicinity of the Mill Creek mine near the northeastern boundary of the further planning area (B5-187); there, we identified marginal reserves of marble suitable for the production of lime and construction stone. The reserves are marginal because of their remote location and poor accessibility. Geologic mapping did not reveal any additional marble occurrences within the study area. The area having moderate potential for base-metal resources forms a small zone in the eastern part of the recommended wilderness (A5-187). Within this zone, evidence provided by stream-sediment geochemistry suggests that crystalline bedrocks in several drainages contain concentrations of metallic elements. Because the terrain is inaccessible and covered with dense brush, most of the bedrock in the specific drainages containing the geochemical anomalies could not be examined. Thus, although we infer that mineral occurrences exist in the drainage basins, we have little data on which to base an estimate of their extent and quality. Locally, the crystalline rocks probably contain hydrothermal veins or disseminated occurrences where lead, copper, molybdenum, tin, cobalt, bismuth, and arsenic have been concentrated. However, the geochemical anomalies for these metals are small, and the stream drainages also are relatively small. Therefore, the inferred occurrences of metallic minerals probably are small scale, scattered, and low grade. There is only low probability that the inferred mineral occurrences are large scale.

California↗

USGS1975

Geochemical Exploration Techniques Applicable in the Search for Copper Deposits

Geochemical exploration is an important part of copper-resource evaluation. A large number of geochemical exploration techniques, both proved and untried, are available to the geochemist to use in the search for new copper deposits. Analyses of whole-rock samples have been used in both regional and local geochemical exploration surveys in the search for copper. Analyses of mineral separates, such as biotite, magnetite, and sulfides, have also been used. Analyses of soil samples are widely used in geochemical exploration, especially for localized surveys. It is important to distinguish between residual and transported soil types. Orientation studies should always be conducted prior to a geochemical investigation in a given area in order to determine the best soil horizon and the best size of soil material for sampling in that area. Silty frost boils, caliche, and desert varnish are specialized types of soil samples that might be useful sampling media. Soil gas is a new and potentially valuable geochemical sampling medium, especially in exploring for buried mineral deposits in arid regions. Gaseous products in samples of soil may be related to base-metal deposits and include mercury vapor, sulfur dioxide, hydrogen sulfide, carbon oxysulfide, carbon dioxide, hydrogen, oxygen, nitrogen, the noble gases, the halogens, and many hydrocarbon compounds. Transported materials that have been used in geochemical sampling programs include glacial float boulders, glacial till, esker gravels, stream sediments, stream-sediment concentrates, and lake sediments. Stream-sediment sampling is probably the most widely used and most successful geochemical exploration technique. Hydrogeochemical exploration programs have utilized hot- and cold-spring waters and their precipitates as well as waters from lakes, streams, and wells. Organic gel found in lakes and at stream mouths is an unproved sampling medium. Suspended material and dissolved gases in any type of water may also be useful media. Samples of ice and snow have been used for limited geochemical surveys. Both geobotanical and biogeochemical surveys have been successful in locating copper deposits in many parts of the world. Micro-organisms, including bacteria and algae, are other unproved media that should be studied. Animals can be used in geochemical-prospecting programs. Dogs have been used quite successfully to sniff out hidden and exposed sulfide minerals. Tennite mounds are commonly composed of subsurface material, but have not as yet proved to be useful in locating buried mineral deposits. Animal tissue and waste products are essentially unproved but potentially valuable sampling media. Knowledge of the location of areas where trace-element-associated diseases in animals and man are endemic as well as a better understanding of these diseases, may aid in identifying regions that are enriched in or depleted of various elements, including copper. Results of analyses of gases in the atmosphere are proving valuable in mineral-exploration surveys. Studies involving metallic compounds exhaled by plants into the atmosphere, and of particulate matter suspended in the atmosphere are reviewed these methods may become important in the future. Remote-sensing techniques are useful for making indirect measurements of geochemical responses. Two techniques applicable to geochemical exploration are neutron-activation analysis and gamma-ray spectrometry. Aerial photography is especially useful in vegetation surveys. Radar imagery is an unproved but potentially valuable method for use in studies of vegetation in perpetually clouded regions. With the advent of modern computers, many new techniques, such as correlation analysis, regression analysis, discriminant analysis, factor analysis, cluster analysis, trend-surface analysis, and moving-average analysis can be applied to geochemical data sets. Selective use of these techniques can provide new insights into the interpretatio

Professional Paper↗

USGS2003

Influence of elk grazing on soil properties in Rocky Mountain National Park

We used three 35-year exclosures to examine the effects of high elk populations on a variety of soil properties in three vegetation types: upland sagebrush, aspen, and meadow. Grazing and hoof action by elk significantly increased bulk density (from 0.87 kg/l ungrazed to 0.94 kg/l grazed), with greater effects on soils with fewer rocks. Grazing substantially reduced extractable calcium, magnesium, potassium and phosphorus in the sagebrush type, but not in the aspen or meadow types. The only grazing effect on pH came in aspen types, where grazing prevented aspen establishment, and kept soil pH about 0.7 units higher than under aspen inside the exclosures. Grazing had no overall effect on total soil C and N across all exclosures and vegetation types. The availability of soil nitrogen, indexed by in-field resin bags and net mineralization in soil cores, showed little overall effect of grazing. Limited data on soil leaching indicated a possibility of strong increases in nitrate leaching with grazing for an aspen vegetation type at one exclosure. Although we found little effect of grazing on soil N supply, we note that N fertilization doubled the production of grasses and shrubs; if grazing eventually led to changes in soil N supply, species composition and growth would likely change. ?? 2003 Elsevier B.V. All rights reserved.

Forest Ecology and Management↗

USGS2011

Sulfur geochemistry and microbial sulfate reduction during low-temperature alteration of uplifted lower oceanic crust: Insights from ODP Hole 735B

Sulfide petrography plus whole rock contents and isotope ratios of sulfur were measured in a 1.5 km section of oceanic gabbros in order to understand the geochemistry of sulfur cycling during low-temperature seawater alteration of the lower oceanic crust, and to test whether microbial effects may be present. Most samples have low SO 4 /ΣS values (≤ 0.15), have retained igneous globules of pyrrhotite ± chalcopyrite ± pentlandite, and host secondary aggregates of pyrrhotite and pyrite laths in smectite ± iron-oxyhydroxide ± magnetite ± calcite pseudomorphs of olivine and clinopyroxene. Compared to fresh gabbro containing 100–1800 ppm sulfur our data indicate an overall addition of sulfide to the lower crust. Selection of samples altered only at temperatures ≤ 110 °C constrains microbial sulfate reduction as the only viable mechanism for the observed sulfide addition, which may have been enabled by the production of H 2 from oxidation of associated olivine and pyroxene. The wide range in δ 34 S sulfide values (− 1.5 to + 16.3‰) and variable additions of sulfide are explained by variable ε sulfate-sulfide under open system pathways, with a possible progression into closed system pathways. Some samples underwent oxidation related to seawater penetration along permeable fault horizons and have lost sulfur, have high SO 4 /ΣS (≥ 0.46) and variable δ 34 S sulfide (0.7 to 16.9‰). Negative δ 34 S sulfate –δ 34 S sulfide values for the majority of samples indicate kinetic isotope fractionation during oxidation of sulfide minerals. Depth trends in sulfide–sulfur contents and sulfide mineral assemblages indicate a late-stage downward penetration of seawater into the lower 1 km of Hole 735B. Our results show that under appropriate temperature conditions, a subsurface biosphere can persist in the lower oceanic crust and alter its geochemistry.

Chemical Geology↗