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At least 1,153 records · Page 64Linked to original sources

Contaminant distribution and accumulation in the surface sediments of Long Island Sound

The distribution of contaminants in surface sediments has been measured and mapped as part of a U.S. Geological Survey study of the sediment quality and dynamics of Long Island Sound. Surface samples from 219 stations were analyzed for trace (Ag, Ba, Cd, Cr, Cu, Hg, Ni, Pb, V, Zn and Zr) and major (Al, Fe, Mn, Ca, and Ti) elements, grain size, and Clostridium perfringens spores. Principal Components Analysis was used to identify metals that may covary as a function of common sources or geochemistry. The metallic elements generally have higher concentrations in fine-grained deposits, and their transport and depositional patterns mimic those of small particles. Fine-grained particles are remobilized and transported from areas of high bottom energy and deposited in less dynamic regions of the Sound. Metal concentrations in bottom sediments are high in the western part of the Sound and low in the bottom-scoured regions of the eastern Sound. The sediment chemistry was compared to model results (Signell et al., 1998) and maps of sedimentary environments (Knebel et al., 1999) to better understand the processes responsible for contaminant distribution across the Sound. Metal concentrations were normalized to grain-size and the resulting ratios are uniform in the depositional basins of the Sound and show residual signals in the eastern end as well as in some local areas. The preferential transport of fine-grained material from regions of high bottom stress is probably the dominant factor controlling the metal concentrations in different regions of Long Island Sound. This physical redistribution has implications for environmental management in the region.

Long Island Sound↗

Regional-scale stratigraphy of surface units in Tyrrhena and Iapygia Terrae, Mars: Insights into highland crustal evolution and alteration history

The compositional, thermophysical and geologic characteristics of surface units in Iapygia and Tyrrhena Terra (60°E–100°E, 0°–30°S) provide new insights into the compositional stratigraphy of the region. Intercrater plains are dominated by two surface units. The older unit (unit 1) is deficient in olivine and more degraded and likely consists of a mixture of impact, volcanic and sedimentary materials. The younger unit (unit 2) is enriched in olivine, exhibits a resistant morphology and higher thermal inertia, and likely represents volcanic infilling of plains. Units 1 and 2 bear a strong resemblance to those previously mapped in Mare Serpentis, a section of highlands crust located northwest of Hellas Basin. Thus, the two major intercrater plains units are even more widespread than previously thought and therefore likely constitute important components of Mars' highland stratigraphy. Many craters in the region contain high thermal inertia deposits (unit 3) that are compositionally identical to unit 2. These may have formed via volcanic infilling or may represent sedimentary materials that have been eroded from crater walls and lithified. Less common units include olivine and/or pyroxene‐rich massifs and crater central peaks. These are primarily found within Hellas Basin rim units and may represent mantle materials brought toward the surface during the Hellas impact. Putative chloride deposits are primarily associated with olivine‐deficient surfaces (unit 1) that may be heavily degraded occurrences of unit 2. The observations raise a variety of questions related to Martian crustal evolution and alteration that may have more widespread implications outside the study region.

Journal of Geophysical Research - Planets↗

A Bayesian network to predict coastal vulnerability to sea level rise

Sea level rise during the 21st century will have a wide range of effects on coastal environments, human development, and infrastructure in coastal areas. The broad range of complex factors influencing coastal systems contributes to large uncertainties in predicting long-term sea level rise impacts. Here we explore and demonstrate the capabilities of a Bayesian network (BN) to predict long-term shoreline change associated with sea level rise and make quantitative assessments of prediction uncertainty. A BN is used to define relationships between driving forces, geologic constraints, and coastal response for the U.S. Atlantic coast that include observations of local rates of relative sea level rise, wave height, tide range, geomorphic classification, coastal slope, and shoreline change rate. The BN is used to make probabilistic predictions of shoreline retreat in response to different future sea level rise rates. Results demonstrate that the probability of shoreline retreat increases with higher rates of sea level rise. Where more specific information is included, the probability of shoreline change increases in a number of cases, indicating more confident predictions. A hindcast evaluation of the BN indicates that the network correctly predicts 71% of the cases. Evaluation of the results using Brier skill and log likelihood ratio scores indicates that the network provides shoreline change predictions that are better than the prior probability. Shoreline change outcomes indicating stability (-1 < rate < 1 m/yr) or erosion (rate < -1 m/yr) tend to occur for two sets of input scenarios. Stable shoreline change rates occur mainly for low rates of relative sea level rise and occur in low-vulnerability geomorphic settings. Rates indicating erosion result for cases where the rate of relative sea level rise is high and moderate-to-high vulnerability geomorphic settings occur. In contrast, accretion (rate > 1 m/yr) was not well predicted. We find that BNs can assimilate important factors contributing to coastal change in response to sea level rise and can make quantitative, probabilistic predictions that can be applied to coastal management decisions. Copyright ?? 2011 by the American Geophysical Union.

Journal of Geophysical Research F: Earth Surface↗

Origin and properties of hydrothermal tremor at Lone Star Geyser, Yellowstone National Park, USA

Geysers are rare geologic features that intermittently discharge liquid water and steam driven by heating and decompression boiling. The cause of variability in eruptive styles and the associated seismic signals are not well understood. Data collected from five broadband seismometers at Lone Star Geyser, Yellowstone National Park are used to determine the properties, location, and temporal patterns of hydrothermal tremor. The tremor is harmonic at some stages of the eruption cycle and is caused by near‐periodic repetition of discrete seismic events. Using the polarization of ground motion, we identify the location of tremor sources throughout several eruption cycles. During preplay episodes (smaller eruptions preceding the more vigorous major eruption), tremor occurs at depths of 7–10 m and is laterally offset from the geyser's cone by ~5 m. At the onset of the main eruption, tremor sources migrate laterally and become shallower. As the eruption progresses, tremor sources migrate along the same path but in the opposite direction, ending where preplay tremor originates. The upward and then downward migration of tremor sources during eruptions are consistent with warming of the conduit followed by evacuation of water during the main eruption. We identify systematic relations among the two types of preplays, discharge, and the main eruption. A point‐source moment tensor fit to low‐frequency waveforms of an individual tremor event using half‐space velocity models indicates average V S ≳ 0.8 km/s, source depths ~4–20 m, and moment tensors with primarily positive isotropic and compensated linear vector dipole moments.

Wyoming↗

Influence of near-surface stratigraphy on coastal landslides at Sleeping Bear Dunes National Lakeshore, Lake Michigan, USA

Lake-level change and landslides are primary controls on the development of coastal environments along the coast of northeastern Lake Michigan. The late Quaternary geology of Sleeping Bear Dunes National Lakeshore was examined with high-resolution seismic reflection profiles, ground-penetrating radar (GPR), and boreholes. Based on sequence-stratigraphic principles, this study recognizes ten stratigraphic units and three major unconformities that were formed by late Pleistocene glaciation and postglacial lake-level changes. Locally high sediment supply, and reworking by two regressions and a transgression have produced a complex stratigraphy that is prone to episodic failure. In 1995, a large landslide deposited approximately 1 million m3 of sediment on the lake floor. The highly deformed landslide deposits, up to 18 m thick, extend 3-4 km offshore and unconformably overlie well-stratified glacial and lacustrine sediment. The landslide-prone bluff is underlain by channel-fill deposits that are oriented nearly perpendicular to the shoreline. The paleochannels are at least 10 m deep and 400 m wide and probably represent stream incision during a lake-level lowstand about 10.3 ka B.P. The channels filled with sediment during the subsequent transgression and lake-level highstand, which climaxed about 4.5 ka B.P. As lake level fell from the highstand, the formation of beach ridges and sand dunes sealed off the channel and isolated a small inland lake (Glen Lake), which lies 5 m above the level of Lake Michigan and may be a source of piped groundwater. Our hypothesis is that the paleochannels act as conduits for pore water flow, and thereby locally reduce soil strength and promote slope failure.

Michigan↗

Crop classification modelling using remote sensing and environmental data in the Greater Platte River Basin, USA

With an ever expanding population, potential climate variability and an increasing demand for agriculture-based alternative fuels, accurate agricultural land-cover classification for specific crops and their spatial distributions are becoming critical to researchers, policymakers, land managers and farmers. It is important to ensure the sustainability of these and other land uses and to quantify the net impacts that certain management practices have on the environment. Although other quality crop classification products are often available, temporal and spatial coverage gaps can create complications for certain regional or time-specific applications. Our goal was to develop a model capable of classifying major crops in the Greater Platte River Basin (GPRB) for the post-2000 era to supplement existing crop classification products. This study identifies annual spatial distributions and area totals of corn, soybeans, wheat and other crops across the GPRB from 2000 to 2009. We developed a regression tree classification model based on 2.5 million training data points derived from the National Agricultural Statistics Service (NASS) Cropland Data Layer (CDL) in relation to a variety of other relevant input environmental variables. The primary input variables included the weekly 250 m US Geological Survey Earth Observing System Moderate Resolution Imaging Spectroradiometer normalized differential vegetation index, average long-term growing season temperature, average long-term growing season precipitation and yearly start of growing season. An overall model accuracy rating of 78% was achieved for a test sample of roughly 215 000 independent points that were withheld from model training. Ten 250 m resolution annual crop classification maps were produced and evaluated for the GPRB region, one for each year from 2000 to 2009. In addition to the model accuracy assessment, our validation focused on spatial distribution and county-level crop area totals in comparison with the NASS CDL and county statistics from the US Department of Agriculture (USDA) Census of Agriculture. The results showed that our model produced crop classification maps that closely resembled the spatial distribution trends observed in the NASS CDL and exhibited a close linear agreement with county-by-county crop area totals from USDA census data ( R 2 = 0.90).

Greater Platte River Basin↗

Preliminary results on photometric properties of materials at the Sagan Memorial Station, Mars

Reflectance measurements of selected rocks and soils over a wide range of illumination geometries obtained by the Imager for Mars Pathfinder (IMP) camera provide constraints on interpretations of the physical and mineralogical nature of geologic materials at the landing site. The data sets consist of (1) three small “photometric spot” subframed scenes, covering phase angles from 20° to 150°; (2) two image strips composed of three subframed images each, located along the antisunrise and antisunset lines (photometric equator), covering phase angles from ∼0° to 155°; and (3) full‐image scenes of the rock “Yogi,” covering phase angles from 48° to 100°. Phase functions extracted from calibrated data exhibit a dominantly backscattering photometric function, consistent with the results from the Viking lander cameras. However, forward scattering behavior does appear at phase angles >140°, particularly for the darker gray rock surfaces. Preliminary efforts using a Hapke scattering model are useful in comparing surface properties of different rock and soil types but are not well constrained, possibly due to the incomplete phase angle availability, uncertainties related to the photometric function of the calibration targets, and/or the competing effects of diffuse and direct lighting. Preliminary interpretations of the derived Hapke parameters suggest that (1) red rocks can be modeled as a mixture of gray rocks with a coating of bright and dark soil or dust, and (2) gray rocks have macroscopically smoother surfaces composed of microscopically homogeneous, clear materials with little internal scattering, which may imply a glass‐like or varnished surface.

Journal of Geophysical Research E: Planets↗

Tectonic history of the north portion of the San Andreas fault system, California, inferred from gravity and magnetic anomalies

Geologic and geophysical data for the San Andreas fault system north of San Francisco suggest that the eastern boundary of the Pacific plate migrated eastward from its presumed original position at the base of the continental slope to its present position along the San Andreas transform fault by means of a series of eastward jumps of the Mendocino triple junction. These eastward jumps total a distance of about 150 km since 29 Ma. Correlation of right-laterally displaced gravity and magnetic anomalies that now have components at San Francisco and on the shelf north of Point Arena indicates that the presently active strand of the San Andreas fault north of the San Francisco peninsula formed recently at about 5 Ma when the triple junction jumped eastward a minimum of 100 km to its present location at the north end of the San Andreas fault. Prior to 5 Ma the triple junction was located at the north end of a proposed northwesterly extension of the Pilarcitos fault. This jump took place at what is now about latitude 38°20′N on the North American plate and may have occurred during part of the time when the relative motion between the North American and Pacific plates rotated 20° clockwise, resulting in transpression along the earlier transcurrent San Andreas fault system. The proposed 150-km eastward movement of the triple junction explains the submarine topography near Cape Mendocino where the continental shelf south of the Mendocino fault extends about 130 km farther west than does the shelf directly north of the fault.

Journal of Geophysical Research Solid Earth↗

An efficient algorithm for double-difference tomography and location in heterogeneous media, with an application to the Kilauea volcano

Improving our understanding of crustal processes requires a better knowledge of the geometry and the position of geological bodies. In this study we have designed a method based upon double-difference relocation and tomography to image, as accurately as possible, a heterogeneous medium containing seismogenic objects. Our approach consisted not only of incorporating double difference in tomography but also partly in revisiting tomographic schemes for choosing accurate and stable numerical strategies, adapted to the use of cross-spectral time delays. We used a finite difference solution to the eikonal equation for travel time computation and a Tarantola-Valette approach for both the classical and double-difference three-dimensional tomographic inversion to find accurate earthquake locations and seismic velocity estimates. We estimated efficiently the square root of the inverse model's covariance matrix in the case of a Gaussian correlation function. It allows the use of correlation length and a priori model variance criteria to determine the optimal solution. Double-difference relocation of similar earthquakes is performed in the optimal velocity model, making absolute and relative locations less biased by the velocity model. Double-difference tomography is achieved by using high-accuracy time delay measurements. These algorithms have been applied to earthquake data recorded in the vicinity of Kilauea and Mauna Loa volcanoes for imaging the volcanic structures. Stable and detailed velocity models are obtained: the regional tomography unambiguously highlights the structure of the island of Hawaii and the double-difference tomography shows a detailed image of the southern Kilauea caldera-upper east rift zone magmatic complex. Copyright 2005 by the American Geophysical Union.

Hawaii↗

Doppler weather radar observations of the 2009 eruption of Redoubt Volcano, Alaska

The U.S. Geological Survey (USGS) deployed a transportable Doppler C-band radar during the precursory stage of the 2009 eruption of Redoubt Volcano, Alaska that provided valuable information during subsequent explosive events. We describe the capabilities of this new monitoring tool and present data captured during the Redoubt eruption. The MiniMax 250-C (MM-250C) radar detected seventeen of the nineteen largest explosive events between March 23 and April 4, 2009. Sixteen of these events reached the stratosphere (above 10 km) within 2–5 min of explosion onset. High column and proximal cloud reflectivity values (50 to 60 dBZ) were observed from many of these events, and were likely due to the formation of mm-sized accretionary tephra-ice pellets. Reflectivity data suggest that these pellets formed within the first few minutes of explosion onset. Rapid sedimentation of the mm-sized pellets was observed as a decrease in maximum detection cloud height. The volcanic cloud from the April 4 explosive event showed lower reflectivity values, due to finer particle sizes (related to dome collapse and related pyroclastic flows) and lack of significant pellet formation. Eruption durations determined by the radar were within a factor of two compared to seismic and pressure-sensor derived estimates, and were not well correlated. Ash dispersion observed by the radar was primarily in the upper troposphere below 10 km, but satellite observations indicate the presence of volcanogenic clouds in the stratosphere. This study suggests that radar is a valuable complement to traditional seismic and satellite monitoring of explosive eruptions.

Alaska↗

Heat flow in the Western Arctic Ocean (Amerasian Basin)

From 1963 to 1973 the U.S. Geological Survey (USGS) measured heat flow at 356 sites in the Amerasian Basin (Western Arctic Ocean) from a drifting ice island (T-3). The resulting measurements, which are unevenly distributed on Alpha-Mendeleev Ridge (AMR) and in Canada and Nautilus basins, greatly expand available heat flow data for the Arctic Ocean. Average T-3 heat flow is ~54.7 ± 11.3 mW m-2, and Nautilus Basin, including Mendeleev Plain, is the only well-surveyed area (~13% of data) with significantly higher average heat flow (63.8 mW m-2). Heat flow and bathymetry are not correlated at a large scale, and turbiditic surficial sediments (Canada and Nautilus basins) have higher heat flow than the sediments that blanket the AMR. Thermal gradients are mostly near-linear, implying that conductive heat transport dominates and that near-seafloor sediments are in thermal equilibrium with overlying bottom waters. Combining the heat flow data with modern seismic imagery suggests that some of the observed heat flow variability may be explained by local changes in sediment thickness or lithology or the presence of basement faults that channel circulating seawater. A thermal model that incorporates thermal conductivity variations along a profile from Canada Basin (thick sediment on mostly oceanic crust) to Alpha Ridge (thin sediment over thick magmatic units associated with the High Arctic Large Igneous Province) predicts heat flow lower than that observed on Alpha Ridge. This, along with other observations, implies that circulating fluids modulate conductive heat flow and contribute to high variability in the T-3 dataset. .

Journal of Geophysical Research B: Solid Earth↗

Deep volcanic tremor and magma ascent mechanism under Kilauea, Hawaii

Deep harmonic tremor originating at depths around 40 km under Kilauea was studied using records accumulated since 1962 at the Hawaii Volcano Observatory of the U.S. Geological Survey. The deep source of the tremor was determined by onset times and confirmed by the relative amplitude across the island-wide network of seismometers. The period of tremor was conclusively shown to be determined by the source effect and not by the path or station site effect because the period would change considerably in time but maintained uniformity across the seismic net during the tremor episode. The tremor appeared to be primarily composed of P waves. We interpret the observed period and amplitude in terms of the stationary crack model of Aki et al. (1977) and find that the seismic moment rates for deep tremors are considerably larger than those for shallow-tremors suggesting more vigorous transport for the former. We propose a kinematic source model which may be more appropriate for deep tremor. According to this model, a measurable quantity called ‘reduced displacement’ is directly proportional to the rate of magma flow. A systematic search for deep tremor episodes was made for the period from 1962 through 1979, and the amplitude, period, and duration of the tremor were tabulated. We then constructed a cumulative reduced-displacement plot over the 18-year period. The result shows a generally steady process which does not seem to be significantly affected by major eruptions and large earthquakes near the surface. The total magma flow estimated from the reduced displacement is however, one order of magnitude smaller than that estimated by Swanson (1972). It may be that most channels transport magma aseismically, and only those with strong barriers generate tremor.

Hawaii↗

Changes in phosphorus concentration and flux from 2011 to 2023 in major U.S. tributaries to the Laurentian Great Lakes

Reducing phosphorus (P) flux to the Great Lakes is critical for improving water quality and controlling eutrophication. We used 13 water years (2011–2023) of U.S. Geological Survey data from 24 major U.S. tributaries (representing 47% of the U.S. Great Lakes watershed area) to evaluate temporal changes in orthophosphate (PO 4 -P) and total P (TP) using Weighted Regressions on Time, Discharge, and Season. We assessed actual and flow-normalized P concentrations and fluxes. Between 2011 and 2023, P concentrations and fluxes declined in many tributaries, although the extent and significance of these declines varied. Decreases were more common and statistically likely for TP than PO 4 -P, and several high-loading watersheds had modest or non-significant changes. Flow-normalized PO 4 -P:TP flux ratios increased in over half the tributaries, suggesting that even where P reductions occurred, reductions in the more bioavailable P fraction were proportionally smaller. Actual P fluxes were strongly correlated with streamflow, and year-to-year variability in actual fluxes was, on average, three times greater than variability related to trends in flow-normalized fluxes. This underscores the role of hydrology in modulating P export and highlights how changing precipitation and runoff patterns can obscure or counteract management progress. Spring accounted for the largest share of annual P flux in most tributaries, though many showed declining spring contributions. Our basin-wide analysis reveals that while management efforts may have yielded progress in reducing TP in many watersheds, additional strategies would be needed to address PO 4 -P reductions and account for changing hydrology, especially in high-contributing watersheds.

Journal of Great Lakes Research↗

Seismic refraction measurements within the Peninsular terrane, south central Alaska

We present an interpretation of crustal seismic refraction data from the Peninsular terrane, one of the many exotic terranes that have been accreted to the continental margin of southern Alaska in the past 200 m.y. A seismic refraction line was collected along the Glenn Highway in the Copper River Basin of south central Alaska in 1984 and 1985, as part of the U.S. Geological Survey Trans‐Alaska Crustal Transect (TACT) program. P wave velocities of 2.7–3.5 km/s and thicknesses of 1–2 km characterize post‐Lower Jurassic sedimentary rocks that underlie most of the seismic refraction line. An average crustal velocity structure includes the following five velocity divisions. Beneath the sedimentary rocks lie 1–2 km of 4.0–4.6 km/s materials, correlating with andesitic volcaniclastic sedimentary rocks and lava flows of the Lower Jurassic Talkeetna Formation. Below these rocks, seismic velocity increases rapidly, from 5.0 to 6.1 km/s, in 2–3 km. At 7–8 km depth, velocity jumps to 6.3 km/s and increments to 6.6 km/s by 10–12 km depth. Velocities increase from 6.8 to 7.0 km/s between 12 to 20 km depth. At about 22 km depth, a jump in velocity from 7.0 to 7.4 km/s is inferred but is poorly resolved. Depth to the Moho discontinuity could not be determined from our data. The absence of clear PmP reflections may indicate that Moho is deeper than 40 km. Data from two offset shotpoints northeast of the line and within the Wrangellia terrane constrain the deep structure transition between Peninsular and Wrangellia terranes. The 6.3–6.6 km/s material thickens to the northeast, toward the suture between Peninsular and Wrangellia terranes, but southwest of its mapped trace at the West Fork fault. Peninsular terrane crustal structure appears dissimilar to that of continental interiors. It is similar to velocity structures determined for accreted island arc fragments in California, such as the basement of the Great Valley and the Klamath Mountains.

Alaska↗

Use of flow-normalization to evaluate nutrient concentration and flux changes in Lake Champlain tributaries, 1990-2009

The U.S. Geological Survey evaluated 20 years of total phosphorus (P) and total nitrogen (N) concentration data for 18 Lake Champlain tributaries using a new statistical method based on weighted regressions to estimate daily concentration and flux histories based on discharge, season, and trend as explanatory variables. The use of all the streamflow discharge values for a given date in the record, in a process called "flow-normalization," removed the year-to-year variation due to streamflow and generated a smooth time series from which trends were calculated. This approach to data analysis can be of great value to evaluations of the success of restoration efforts because it filters out the large random fluctuations in the flux that are due to the temporal variability in streamflow. Results for the full 20 years of record showed a mixture of upward and downward trends for concentrations and yields of P and N. When the record was broken into two 10-year periods, for many tributaries, the more recent period showed a reversal in N from upward to downward trends and a similar reversal or reduction in magnitude of upward trends for P. Some measures of P and N concentrations and yields appear to be related to intensity of agricultural activities, point-source loads of P, or population density. Total flow-normalized P flux aggregated from the monitored tributaries showed a decrease of 30 metric tons per year from 1991 to 2009, which is about 15% of the targeted reduction established by the operational management plan for the Lake Champlain Basin.

Vermont;New York↗

Optimizing selection of training and auxiliary data for operational land cover classification for the LCMAP initiative

The U.S. Geological Survey’s Land Change Monitoring, Assessment, and Projection (LCMAP) initiative is a new end-to-end capability to continuously track and characterize changes in land cover, use, and condition to better support research and applications relevant to resource management and environmental change. Among the LCMAP product suite are annual land cover maps that will be available to the public. This paper describes an approach to optimize the selection of training and auxiliary data for deriving the thematic land cover maps based on all available clear observations from Landsats 4–8. Training data were selected from map products of the U.S. Geological Survey’s Land Cover Trends project. The Random Forest classifier was applied for different classification scenarios based on the Continuous Change Detection and Classification (CCDC) algorithm. We found that extracting training data proportionally to the occurrence of land cover classes was superior to an equal distribution of training data per class, and suggest using a total of 20,000 training pixels to classify an area about the size of a Landsat scene. The problem of unbalanced training data was alleviated by extracting a minimum of 600 training pixels and a maximum of 8000 training pixels per class. We additionally explored removing outliers contained within the training data based on their spectral and spatial criteria, but observed no significant improvement in classification results. We also tested the importance of different types of auxiliary data that were available for the conterminous United States, including: (a) five variables used by the National Land Cover Database, (b) three variables from the cloud screening ‘‘Function of mask” (Fmask) statistics, and (c) two variables from the change detection results of CCDC. We found that auxiliary variables such as a Digital Elevation Model and its derivatives (aspect, position index, and slope), potential wetland index, water probability, snow probability, and cloud probability improved the accuracy of land cover classification. Compared to the original strategy of the CCDC algorithm (500 pixels per class), the use of the optimal strategy improved the classification accuracies substantially (15-percentage point increase in overall accuracy and 4-percentage point increase in minimum accuracy).

ISPRS Journal of Photogrammetry and Remote Sensing↗

In situ benthic nutrient flux and sediment oxygen demand in Barnegat Bay, New Jersey

The U.S. Geological Survey, in cooperation with the New Jersey Department of Environmental Protection, measured sediment oxygen demand (SOD) and benthic nutrient fluxes throughout Barnegat Bay, New Jersey. SOD was determined in situ using chambers equipped with optical dissolved oxygen sensors. The benthic nutrient fluxes of ammonia (NH3), nitrite + nitrate (plus ions; here, referred to as NO32), soluble reactive phosphorous (SRP), and dissolved silica (SiO2) were measured with in situ equilibrium dialysis samplers. Measurements were made at nine stations around the periphery and at three mid-Bay locations from August 2012 to October 2013. The SOD ranged from −1.5 to −8.4 g of oxygen (O2) m−2 d−1. The SOD rates varied as a function of water temperature and followed the van't Hoff rate equation for change in reaction rate with temperature, with a temperature coefficient (Θ) that varied among sites and averaged 1.083. The highest SOD rates in the bay were measured near the mouth of the Toms River embayment. Concentrations in the upper 1 m of sediment pore water were found up to 23 mg N L−1 for NH4+ and 6.7 mg P L−1 for SRP. Maximum measured fluxes into the overlying water were 3.0 × 10−2 g NH3–N m−2 d−1, 7.0 × 10−4 g NO32–N m−2 d−1, 1.9 × 10−3 g P m−2 d−1, and 3.6 × 10−3g SiO2 m−2 d−1. Using the measured benthic N and P fluxes, daily nutrient inputs derived from sediment recycling are shown to be comparable in scale to freshwater tributary inputs to the bay.

New Jersey↗

Differentiating pedogenesis from diagenesis in early terrestrial paleoweathering surfaces formed on granitic composition parent materials

Unconformable surfaces separating Precambrian crystalline basement and overlying Proterozoic to Cambrian sedimentary rocks provide an exceptional opportunity to examine the role of primitive soil ecosystems in weathering and resultant formation of saprolite (weathered rock retaining rock structure) and regolith (weathered rock without rock structure), but many appear to have been affected by burial diagenesis and hydrothermal fluid flow, leading some researchers to discount their suitability for such studies. We examine one modern weathering profile (Cecil series), four Cambrian paleoweathering profiles from the North American craton (Squaw Creek, Franklin Mountains, Core SQ-8, and Core 4), one Neoproterozoic profile (Sheigra), and one late Paleoproterozoic profile (Baraboo), to test the hypothesis that these paleoweathering profiles do provide evidence of primitive terrestrial weathering despite their diagenetic and hydrothermal overprinting, especially additions of potassium. We employ an integrated approach using (1) detailed thin-section investigations to identify characteristic pedogenic features associated with saprolitization and formation of well-drained regoliths, (2) electron microprobe analysis to identify specific weathered and new mineral phases, and (3) geochemical mass balance techniques to characterize volume changes during weathering and elemental gains and losses of major and minor elements relative to the inferred parent materials. There is strong pedogenic evidence of paleoweathering, such as clay illuviation, sepic-plasmic fabrics, redoximorphic features, and dissolution and alteration of feldspars and mafic minerals to kaolinite, gibbsite, and Fe oxides, as well as geochemical evidence, such as whole-rock losses of Na, Ca, Mg, Si, Sr, Fe, and Mn greater than in modern profiles. Evidence of diagenesis includes net additions of K, Ba, and Rb determined through geochemical mass balance, K-feldspar overgrowths in overlying sandstone sections, and K-feldspars with reaction rims in weathered basement. The sub-Cambrian paleoweathering profiles formed on granite are remarkably similar to modern weathering profiles formed on granite, in spite of overprinting by potassium diagenesis. ?? 2007 by The University of Chicago. All rights reserved.

Journal of Geology↗