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At least 1,153 records · Page 64Linked to original sources
USGS2026

Development of a hydrologic flow model of the Zuñi Salt Lake and surrounding areas, west-central New Mexico

The terminal Zuñi Salt Lake is in a maar in west-​central New Mexico and contains hypersaline water that has long been used by Native Americans for religious purposes and the collection of salt. The U.S. Geological Survey (USGS), in cooperation with the Zuni Tribe of the Zuni Reservation, New Mexico, and Bureau of Reclamation, developed the Zuñi Salt Lake hydrologic flow model to simulate the steady-state conditions of the lake and surrounding groundwater-flow system. The model is a tool that can be used to analyze the potential hydrologic responses to resource development in the region under different water-use scenarios, which can support negotiations that could help protect future use of the lake. The USGS modular hydrologic model, MODFLOW 6, was used to simulate the hydrologic system of the lake and surrounding areas. To define the layering of the model, a three-dimensional hydrogeologic framework was constructed, which included seven informal hydrogeologic units and the locations of faults that truncate and offset the units. Calibration of the model was performed using the iterative ensemble smoother included in a parameter estimation software suite (PEST++). The iterative ensemble smoother approach resulted in a posterior parameter ensemble of model realizations with parameter and simulated values that show similar success in matching observations. Groundwater flux to the Zuñi Salt Lake simulated by using the posterior parameter distribution ranged from 26 to 730 acre-feet per year with a mean, median, and standard deviation of 530, 570, and 170 acre-feet per year, respectively. The relative contribution of groundwater discharge to the lake was simulated using a particle-tracking model for MODFLOW (MODPATH) to be from, in order of decreasing contribution, the Mesaverde, Cenozoic, Mancos, and Dakota hydrogeologic units. Simulations of future conditions using the ensemble of models can provide an empirical estimate of forecast uncertainty without substantial additional analysis.

New Mexico↗
USGS2003

Ground-water flow and ground- and surface-water interaction at McBaine Bottoms, Columbia, Missouri-2000-02

McBaine Bottoms southwest of Columbia, Missouri, is the site of 4,269 acres of the Eagle Bluffs Conservation Area operated by the Missouri Department of Conservation, about 130 acres of the city of Columbia wastewater-treat-ment wetlands, and the city of Columbia munici-pal-supply well field. The city of Columbia wastewater-treatment wetlands supply treated effluent to the Eagle Bluffs Conservation Area. The presence of a sustained ground-water high underlying the Eagle Bluffs Conservation Area has indicated that ground-water flow is toward the municipal well field that supplies drinking water to the city of Columbia. The U.S. Geological Survey, in cooperation with the Missouri Department of Conservation and the city of Columbia, measured the ground-water levels in about 88 monitoring wells and the surface-water elevation at 4 sites monthly during a 27-month period to determine the ground-water flow and the ground- and surface-water interaction at McBaine Bottoms. Lateral ground-water flow was dominated by the presence of a ground-water high that was beneath the Eagle Bluffs Conservation Area and the presence of a cone of depression in the northern part of the study area. The ground-water high was present during all months of the study. Ground-water flow was radially away from the apex of the ground-water high; west and south of the high, flow was toward the Missouri River, east of the high, flow was toward Perche Creek, and north of the high, flow was toward the north toward the city of Columbia well field. The cone of depression was centered around the city of Columbia well field. Another permanent feature on the water-level maps was a ground-water high beneath treatment wetland unit 1. Although the ground-water high beneath the Eagle Bluffs Conservation Area was present throughout the study period, the configuration of the high changed depending on hydrologic conditions. Generally in the spring, the height of the ground-water high began to decrease and hydraulic gradients around the high became more shallow than in the winter months. In early summer, the high was the least pronounced. During mid-sum-mer, the high became more pronounced, and it continued to become higher, increasing until it reached its maximum height in late fall or early winter. Fluctuations in the ground-water high were partially produced by the cycle of flooding of the Eagle Bluffs Conservation Area wetland pools in the fall and subsequent drainage so crops could be planted in many of the wetland pools. The cone of depression in the northern part of the study area generally extended from the base of the ground-water high in the northern part of the Eagle Bluffs Conservation Area throughout the rest of the study area. The depth of the cone primarily was affected by the altitude of the Missouri River and the quantity of water being pumped from the alluvial aquifer by the city of Columbia well field. Ground-water flow in the alluvial aquifer in McBaine Bottoms in the late 1960?s before the development of the city of Columbia well field and the Eagle Bluffs Conservation Area was from northwest to southeast approximately parallel to the Missouri River. The ground-water high beneath the Eagle Bluffs Conservation Area and the cone of depression around the city of Columbia well field were not present in water-level maps for 1968 and 1978. The Missouri River can be a source of recharge to the alluvial aquifer. Generally the altitude of the river in the northern part of the study area was higher than the water table in the aquifer. Ground-water flow in this area was from the river into the alluvial aquifer. In the southern part of the study area adjacent to the Eagle Bluffs Conservation Area, the Missouri River was lower than the water table in the alluvial aquifer, indicating that the river was receiving water from the alluvial aquifer beneath the Eagle Bluffs Conservation Area.

Missouri↗
USGS1983

Reconnaissance of surface-water resources in the Togiak River basin, southwestern Alaska, 1980 and 1982

Data collected during August and September 1980 and March 1982 describe hydrologic characteristics of the Togiak River and its tributaries. Surface waters are generally cold and clear, have significant wilderness recreation values, and provide outstanding salmon habitat. Late summer unit runoff ranged from 2.3 to 8.1 cubic feet per second per square mile. Stream width increased with discharge from about 20 feet on the tributaries to more than 300 feet on the Togiak River near its mouth. Mean depth increased with discharge downstream direction from about 1 to more than 4 feet. Mean velocity ranged between 1 and 4 feet per second and bore little relation to discharge. Late winter unit discharge for sites having little or no upstream lake storage was about 0.5 cubic foot per second per square mile. For the remaining sites, values ranged from 0.8 to 1.4 cubic feet per second per square mile. Unit runoff of maximum evident floods ranged from 12.9 to 50 cubic feet per second per square mile. Field measurements of water temperature, dissolved oxygen, pH, alkalinity and specific conductance indicated that water quality seems much the same throughout the basin and is influenced by the major lakes. Benthic invertebrates indicate a reasonably diverse fauna with midge larvae representing the largest percentage of all organisms found at most sites. (USGS)

Water-Resources Investigations Report↗
USGS1993

Development, calibration, and testing of ground-water flow models for the Mississippi River Valley alluvial aquifer in eastern Arkansas using one-square-mile cells

Significant water-level declines in the Mississippi River Valley alluvial aquifer prompted the need to better understand the flow system in the aquifer which, in turn, led to the development of digital groundwater flow models of the alluvial aquifer. Two models were developed in the eastern Arkansas study area with the Arkansas River dividing the study area and functioning as a hydrologic boundary to the models. Both models simulate groundwater flow in one layer with recharge entering the aquifer from head-dependent surface infiltration through the overlying confining unit and from seepage through river beds. Digital models were used to simulate flow in the aquifer during seven stress periods between 1918 and 1987. Pumpage used in the simulations ranged from 83,400,000 to 412,000,000 cu ft/d in the north model and from 12,800,000 to 58,500,000 cu ft/d in the south model. Three different spatial and temporal pumpage scenarios were tested to simulate pumpage stress in the models. The pumpage distribution used in the calibrated model was based on a combination of all three scenarios. Several criteria were used during model development to determine how well the model simulated conditions in the aquifer. Potentiometric maps of model-computed water levels were compared to measured data to check the computed water levels and direction of flow. Hydrographs of observation wells were compared to computed water levels at corresponding model cells to assess the temporal distribution of pumpage. A root-mean-square error analysis was performed during calibration by comparing observation-well and model-computed water levels for 1972. Sensitivity analyses were performed to determine the effects of changes in input parameters on computed heads (water levels). Both models were sensitive to changes in recharge and pumpage but the south model generally was less sensitive than the north model.

Water-Resources Investigations Report↗
USGS1987

GEOGRAPHIC ESTIMATION OF RUNOFF-MODEL PARAMETERS.

The U. S. Geological Survey is developing techniques to estimate and evaluate unit-hydrograph and loss-rate parameter values for rainfall-runoff models using Geographic Information System (GIS) procedures. The data base includes basin, soil, and climatological characteristics that will be stored in a GIS, and unit-hydrograph and loss-rate parameters obtained from calibration of a commonly used flood-hydrograph rainfall-runoff model for 616 storms in 98 gaged drainage basins. Development of unit-hydrograph and loss-rate parameter-estimation techniques includes statistical methods (exploratory data analysis, regression analysis, and categorical data analysis) to relate the model parameters to hydrologic characteristics. The estimation techniques are evaluated by use of error analysis of simulated hydrograph characteristics (peak discharge, flood volume, and time to peak discharge). The hydrographs will be simulated with parameters estimated by the techniques for (1) 102 storms occurring at 36 gaged basins; and (2) a large storm system (one which produced floods with a 50-to 100-year recurrence interval).

Conference Paper↗
USGS1998

Operational modeling system with dynamic-wave routing

A near real-time streamflow-simulation system utilizing continuous-simulation rainfall-runoff generation with dynamic-wave routing is being developed by the U.S. Geological Survey in cooperation with the Du Page County Department of Environmental Concerns for a 24-kilometer reach of Salt Creek in Du Page County, Illinois. This system is needed in order to more effectively manage the Elmhurst Quarry Flood Control Facility, an off-line stormwater diversion reservoir located along Salt Creek. Near real time simulation capabilities will enable the testing and evaluation of potential rainfall, diversion, and return-flow scenarios on water-surface elevations along Salt Creek before implementing diversions or return-flows. The climatological inputs for the continuous-simulation rainfall-runoff model, Hydrologic Simulation Program - FORTRAN (HSPF) are obtained by Internet access and from a network of radio-telemetered precipitation gages reporting to a base-station computer. The unit area runoff time series generated from HSPF are the input for the dynamic-wave routing model. Full Equations (FEQ). The Generation and Analysis of Model Simulation Scenarios (GENSCN) interface is used as a pre- and post-processor for managing input data and displaying and managing simulation results. The GENSCN interface includes a variety of graphical and analytical tools for evaluation and quick visualization of the results of operational scenario simulations and thereby makes it possible to obtain the full benefit of the fully distributed dynamic routing results.

Conference Paper↗
USGS2026

Salinas Valley integrated hydrologic and reservoir operations models, Monterey and San Luis Obispo Counties, California

The area surrounding the Salinas Valley groundwater basin in Monterey and San Luis Obispo Counties of California is a highly productive agricultural area, contributes substantially to the local economy, and provides a substantial portion of vegetables and other agricultural commodities to the Nation. This region of California provides about half of the Nation’s lettuce, celery, broccoli, and spinach each year. Thus, this agricultural area provides substantial volumes of agricultural products not just for California but for the United States. Changes in population and increased agricultural development, which includes a shift toward more water-intensive crops, and climate variability, have put increasing demand on both surface-water and groundwater resources in the valley. This situation has resulted in water management challenges in the Salinas Valley that generally relate to the distribution of the water supply throughout the basin. Where and when the water is present in the surface and subsurface does not coincide with where and when the water is needed. Historically, to deal with the distribution issue, water has been used conjunctively in the valley. Conjunctive use is a water management strategy that coordinates surface-water and groundwater use to maximize water availability. Groundwater is used throughout the Salinas Valley to meet water demands when surface-water supplies are insufficient. The availability of surface water is constrained by climate. Precipitation and streamflow vary seasonally and year to year. Although there are two reservoirs in the Salinas Valley to capture and store water during wet periods, the only conveyance of reservoir water to coastal agricultural areas is the Salinas River. Increasing demand for groundwater and surface-water resources throughout the Salinas Valley has resulted in undesirable effects from unsustainable water use, such as surface-water depletion, groundwater-level declines, storage depletion in the principal aquifers, and seawater intrusion. To address these escalating issues, local communities, water management agencies, and groundwater sustainability agencies are evaluating how to sustainably manage both their surface-water and groundwater resources. To meet water demands and reduce the undesirable effects of unsustainable water use, continued conjunctive management of surface water and groundwater would ideally incorporate strategies to deal with increases in demand and climate variability. To evaluate the challenging water management issues in the Salinas Valley, the U.S. Geological Survey, Monterey County Water Resources Agency, and the Salinas Valley Basin Groundwater Sustainability Agency developed a comprehensive suite of models that represent the Salinas Valley hydrogeologic system called the Salinas Valley System Model. The geologic framework is known as the Salinas Valley Geologic Framework and was developed to characterize the subsurface using various topographic and geologic data sources, including information on hydrogeologic units, their surfaces and extents, geologic structures, lithology, and elevations from borehole data and cross sections, as well as details on faults and existing models. The surface-water model is called the Salinas Valley Watershed Model and simulates the Salinas River watershed. Monthly surface-water inflows into the integrated hydrologic model domain were simulated using the Salinas Valley Watershed Model. The historical model uses historical climate data, water and land use data, and reservoir releases to simulate agricultural operations, including landscape water demands, diversions, and reclaimed wastewater. The operational model adds an embedded reservoir operations framework to the simulation of the historical model that allows specified operational rules to simulate reservoir releases and changes in reservoir storage. The operational model assumes current reservoir operations and constant land use, which differs from historical conditions. Thus, the operational model is a hypothetical baseline model that can be used by local water managers to evaluate and quantify potential benefits of water supply projects. Together, the geologic framework, watershed, historical, and operational models form a tool that can be used to simulate irrigated agriculture and associated reservoir operations of the integrated hydrologic system of the Salinas Valley.

California↗
USGS1905

Preliminary list of deep borings in the United States

The first preliminary list of deep borings in the United States was issued as Water-Supply Papers Nos. 57 and 61. The present publication includes all of the wells listed in these two papers, together with many additional borings, mostly of recent date. Messrs. M. L. Fuller and A. C. Veatch, of the eastern section of hydrology, and other geologists of the Survey have contributed many new data. Descriptions of borings published in reports issued since 1901 have been incorporated as far as practicable. All the entries are by counties. The wells and borings reported in the paper are all more than 400 feet in depth. The information concerning them has been obtained partly from replies to circular letters sent to all parts of the United States and partly from geological reports and other published sources. Owing to the difficulty of obtaining replies to the circulars, to lack of knowledge on the part of correspondents, and to the incompleteness of published records, doubtless there are borings which have not been reported. In regions of oil and gas wells, where borings are numerous, the individual wells can not be listed here, but representative wells are given. References to logs or records of the wells or extended descriptions of them are given in footnotes, and after the list of wells in each State there is added a list of the principal publications relating to deep borings in that State. The bearing of the information given in the columns of the lists probably is apparent unless, perhaps, in the one headed "Height to which the water rises." In this column an entry such as "-45" indicates that the water rises to within 45 feet of the surface; "+45" indicates that it is a flowing well and has sufficient head to raise the water 45 feet above the surface in an open pipe 45 feet or more in height. The yield in gallons per minute usually is estimated. Depths and diameters often have been reported from memory and different sources of publication sometimes give different figures. Most wells which are not stated to be "for oil," "for gas," "brine," "abandoned," etc., in the remarks column, or "not any" in the yield column, generally afford more or less water. Many of the gas and oil wells, active or abandoned, yield salt water.

Water Supply Paper↗
USGS2013

Hydrogeology and hydrologic conditions of the Northern Atlantic Coastal Plain aquifer System from Long Island, New York, to North Carolina

The seaward-dipping sedimentary wedge that underlies the Northern Atlantic Coastal Plain forms a complex groundwater system. This major source of water provides for public and domestic supply and serves as a vital source of freshwater for industrial and agricultural uses throughout the region. Population increases and land-use and climate changes, however, have led to competing demands for water. The regional response of the aquifer system to these stresses poses regional challenges for water-resources management at the State level because hydrologic effects often extend beyond State boundaries. In response to these challenges, the U.S. Geological Survey Groundwater Resources Program began a regional assessment of the groundwater availability of the Northern Atlantic Coastal Plain aquifer system in 2010. The initial phase of this investigation included a refinement of the hydrogeologic framework and an updated hydrologic budget of this aquifer system from the last regional aquifer system assessment completed by the U.S. Geological Survey in the 1980s. Refinements to the hydrogeologic framework include revision of the regional aquifer names to be more consistent with local names in New York, New Jersey, Delaware, Maryland, and Virginia, the primary States included in the study area. Other revisions to the framework include characterization of the aquifers of the regional Potomac aquifer system. The regional Potomac aquifer system is subdivided for this report into two regional aquifers. These aquifers include the single Potomac aquifer in Virginia and two aquifers in Maryland, Delaware, and New Jersey, where the Potomac aquifer system thickens within the Salisbury Embayment. The two regional aquifers making up the Potomac aquifer system include the Potomac-Patapsco aquifer and the underlying Potomac-Patuxent aquifer. The Potomac-Patuxent aquifer includes the Lower Potomac-Raritan-Magothy aquifer in southern New Jersey and the Patuxent aquifers in Delaware and Maryland. In northern New Jersey and on Long Island, New York, the PotomacPatuxent aquifer is absent, but the Late Cretaceous fluvialdeltaic aquifer that is laterally equivalent with the upper part of the Potomac Formation now is considered part of the regional Potomac-Patapsco aquifer. This aquifer includes the Middle Potomac-Raritan-Magothy aquifer in New Jersey and the Lloyd aquifer on Long Island. The name “Upper Potomac aquifer” has been removed as part of this regional framework revision. The local aquifer previously considered part of the Upper Potomac aquifer now are part of the regional Magothy aquifer. These units include the Upper Potomac-Raritan-Magothy aquifer in New Jersey, the Magothy aquifers on Long Island, Delaware, and Maryland, and the Virginia Beach aquifer in Virginia. Updates to the regional hydrologic budget include revised estimates of aquifer recharge, water use and streamflow data. Inflow to the aquifer system of about 20,000 million gallons per day (Mgal/d) includes 19,600 Mgal/d from recharge from precipitation, 200 Mgal/d of recharge from wastewater via onsite domestic septic systems, and 200 Mgal/d from the release of water from aquifer storage. Outflow from the aquifer system includes groundwater discharge to streams (11,900 Mgal/d), groundwater withdrawals (1,500 Mgal/d), and groundwater discharge to coastal waters (6,600 Mgal/d). A numerical modeling analysis is required to improve this hydrologic budget calculation and to forecast future changes in water levels and aquifer storage caused by groundwater withdrawals, land-use changes, and the effects of climate variability and change.

Delaware, Maryland, New Jersey, New York, North Ca↗
USGS2017

Field-trip guide to mafic volcanism of the Cascade Range in Central Oregon—A volcanic, tectonic, hydrologic, and geomorphic journey

The Cascade Range in central Oregon has been shaped by tectonics, volcanism, and hydrology, as well as geomorphic forces that include glaciations. As a result of the rich interplay between these forces, mafic volcanism here can have surprising manifestations, which include relatively large tephra footprints and extensive lava flows, as well as water shortages, transportation and agricultural disruption, and forest fires. Although the focus of this multidisciplinary field trip will be on mafic volcanism, we will also look at the hydrology, geomorphology, and ecology of the area, and we will examine how these elements both influence and are influenced by mafic volcanism. We will see mafic volcanic rocks at the Sand Mountain volcanic field and in the Santiam Pass area, at McKenzie Pass, and in the southern Bend region. In addition, this field trip will occur during a total solar eclipse, the first one visible in the United States in more than 25 years (and the first seen in the conterminous United States in more than 37 years). The Cascade Range is the result of subduction of the Juan de Fuca plate underneath the North American plate. This north-south-trending volcanic mountain range is immediately downwind of the Pacific Ocean, a huge source of moisture. As moisture is blown eastward from the Pacific on prevailing winds, it encounters the Cascade Range in Oregon, and the resulting orographic lift and corresponding rain shadow is one of the strongest precipitation gradients in the conterminous United States. We will see how the products of the volcanoes in the central Oregon Cascades have had a profound influence on groundwater flow and, thus, on the distribution of Pacific moisture. We will also see the influence that mafic volcanism has had on landscape evolution, vegetation development, and general hydrology.

Oregon↗
USGS2014

Report of committee on glaciers, April 1939

The Committee on Glaciers at present is constituted as follows: Harry Fielding Reid—Professor‐Emeritus of Geology, Johns Hopkins University (former member of the International Glacier Commission), 608 Cathedral Street, Baltimore, Maryland William H. Hobbs—Professor‐Emeritus of Geology, University of Michigan (until recently Vice‐ President of the International Glacier Commission, at present associate member), Ann Arbor, Michigan J. E. Church—Professor of Classics, University of Nevada (President of the International Commission of Snow, and Chairman of the Committee on Snow of the Section of Hydrology, American Geophysical Union), Reno, Nevada Colonel Lawrence Martin—Chief of the Division of Maps, Library of Congress, Washington, D. C. Wm. Osgood Field, Jr.—Explorer, 18 West Twelfth Street, New York, N.Y. Earl A. Trager—Chief of the Naturalist Division, National Park Service, Washington, D. C. Glenn L. Parker—District Engineer, Water Resources Branch, United States Geological Survey, 406 Federal Building, Tacoma, Washington Oliver Kehrlein—Chairman, Committee on Glacier Studies, Sierra Club, 1050 Mills Tower, San Francisco, California Kenneth N. Phillips—Associate Hydraulic Engineer, Water Resources Branch, United States Geological Survey, Chairman, Research Committee of the Mazamas, 606 Post‐Office Building, Portland, Oregon William S. Cooper—Professor of Botany, University of Minnesota, Minneapolis, Minnesota Gerald FitzGerald, Senior Topographic Engineer, Alaska Branch, United States Geological Survey, Washington, D.C. Laurence M. Gould, Professor of Geology, Carleton College, Northfield, Minnesota François E. Matthes, Chairman , Senior Geologist, Section of Glacial Geology, United States Geological Survey (titular member of the International Glacier Commission), Washington, D.C. In 1938, as in previous years, the Committee devoted its energies primarily to the collecting of data on the variations in length and volume of American glaciers, it being felt that the maintenance of a continuous record of these variations is of prime importance, not only to hydrology and glaciology, but, as has become increasingly evident recently, also to climatology, geomorphology, geography, ecology, history, and archaeology. As the time available for the work of the Committee is limited and does not permit covering the entire field of glaciology, it seems best to devote it before all else to this line of research which yields results of value to so many different sciences. Besides, the gathering of data on glacier‐oscillations is not a one‐man job that can be taken up or dropped at convenience from time to time, but is an organized and far‐flung enterprise whose success depends upon the faithful cooperation of many volunteer workers located in different parts of the country. Such an enterprise, once launched, must be kept running or it will disintegrate and the precious enthusiasm of the field‐workers will be lost.

Eos, Transactions, American Geophysical Union↗
USGS2007

Use of chemical analysis and assays of semipermeable membrane devices extracts to assess the response of bioavailable organic pollutants in streams to urbanization in six metropolitan areas of the United States

Studies to assess the effects of urbanization on stream ecosystems are being conducted as part of the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Program. The overall objectives of these studies are to (1) determine how hydrologic, geomorphic, water quality, habitat, and biological characteristics respond to land-use changes associated with urbanization in specific environmental settings, and (2) compare these responses across environmental settings. As part of an integrated assessment, semipermeable membrane devices (SPMDs) were deployed in streams along a gradient of urban land-use intensity in and around Atlanta, Georgia; Raleigh-Durham, North Carolina; and Denver-Fort Collins, Colorado, in 2003; and Dallas-Fort Worth, Texas; Milwaukee-Green Bay, Wisconsin; and Portland, Oregon, in 2004. Sites were selected to avoid point-source discharge and to minimize natural variability within each of the six metropolitan areas. In addition to standard chemical analysis for hydrophobic organic contaminants, three assays were used to address mixtures and potential toxicity: (1) Fluoroscan provides an estimate of the total concentration of polycyclic aromatic hydrocarbons (PAHs); (2) the P450RGS assay indicates the presence and levels of aryl hydrocarbon receptor agonists; and (3) Microtox® measures toxicological effects on photo-luminescent bacteria. Of the 140 compounds targeted or identified by gas chromatography/mass spectrometry analysis in this study, 67 were not detected. In terms of numbers and types of compounds, the following were detected: 2 wood preservatives, 6 insecticides (parent compounds), 5 herbicides, 22 polycyclic aromatic hydrocarbons, 2 dibenzofurans, 4 polychlorinated biphenyls, 7 compounds associated with fragrances or personal care products, 4 steroids associated with wastewater, 5 polydibromated diphenyl ethers (flame retardants), 3 plasticizers, 3 antimicrobials/disinfectants, and 3 detergent metabolites. Of the 73 compounds detected and three assays utilized, 29 were detected in 25 percent or more of the streams and were strongly related to increases in urban intensity (defined as having a Spearman’s rho > 0.5 with percent urban land cover) in at least one of the six metropolitan areas investigated. These 29 endpoints included 16 PAHs, a wood preservative (pentachloroanisole), 2 insecticides (chlorpyrifos and chlordane), 3 herbicides (benfluralin, trifluralin, and dacthal), a synthetic musk (hexahydrohexamethylcyclopentabenzopyran, HHCB), 2 furans (methyldibenzofuran and benzo[b]naphtho[2,3-d]furan), and a flame retardant (BDE 47). In addition, the number of compounds detected and results of the Fluoroscan and P450RGS assays were strongly related to urban intensity. Average water concentrations estimated from SPMDs were compared to screening benchmarks for the protection of human health and aquatic life; of the 14 compounds with available benchmarks, 3 compounds (anthracene, dieldrin, and diazinon) exceeded those levels in one or more streams. Both dieldrin and anthracene exceeded their respective benchmarks in seven streams, and diazinon in only one stream. There were more exceedances in Milwaukee-Green Bay and Raleigh-Durham than in the other metropolitan areas, and there were no exceedances in Dallas-Fort Worth. The six metropolitan areas studied differed in the number and types of endpoints related to urban intensity, probably from a combination of factors governing source strength, transport, and fate of hydrophobic compounds. The number of endpoints strongly related to urban intensity ranged from 3 in Dallas-Fort Worth and Portland to 21 in Raleigh-Durham. High frequencies of detection and strong correlations with urban land cover for pyrogenic PAHs (such as unsubstituted 4-ringed PAHs) in all six metropolitan areas indicate that these compounds are an important component of urbanization, regardless of location. Pentachloroanisole, dibenzofurans, and petrogenic PAHs (alkylated PAHs and heterocyclic dibenzothiophenes) were frequently detected and strongly related to urban intensity in Atlanta, Raleigh-Durham, Milwaukee-Green Bay, and Denver-Fort Collins. Two insecticides were related to urban intensity: chlorpyrifos in Atlanta, Raleigh-Durham, and Dallas-Fort Worth; and chlordane in Raleigh-Durham. Three herbicides were strongly related to urban intensity: trifluralin in Atlanta and Raleigh-Durham; benfluralin in Atlanta, and dacthal in Denver-Fort Collins. The detection frequencies for most wastewater indicator compounds were too low to establish relations with urban intensity. Of the wastewater compounds analyzed, HHCB in Raleigh-Durham and Denver-Fort Collins, and BDE 47 in Denver-Fort Collins and Dallas-Forth Worth, had the strongest relations with urban intensity. In addition to pyrogenic PAHs, levels of aryl hydrocarbon receptor agonists (as measured by the P450RGS assay) were strongly related to increasing urban intensity in all six metropolitan areas. PAHs were the only group of aryl hydrocarbon agonists consistently detected and related with urban intensity in all six metropolitan areas. It is unknown which compounds in the SPMDs caused the increased response in the P450RGS assay because the SPMDs likely contained many aryl hydrocarbon receptor agonists not quantified by chemical analysis. It is clear that bioavailable, aryl hydrocarbon receptor agonists increase in streams with increasing urban intensity in the basin. Potential toxicity mediated by this metabolic pathway should be considered in integrated assessments of the response of aquatic biota to urbanization.

Scientific Investigations Report↗
USGS2011

Hydrogeology, chemical characteristics, and water sources and pathways in the zone of contribution of a public-supply well in San Antonio, Texas

In 2001, the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey initiated a series of studies on the transport of anthropogenic and natural contaminants (TANC) to public-supply wells (PSWs). The main goal of the TANC project was to better understand the source, transport, and receptor factors that control contaminant movement to PSWs in representative aquifers of the United States. Regional- and local-scale study areas were selected from within existing NAWQA study units, including the south-central Texas Edwards aquifer. The local-scale TANC study area, nested within the regional-scale NAWQA study area, is representative of the regional Edwards aquifer. The PSW selected for study is within a well field of six production wells. Although a single PSW was initially selected, because of constraints of well-field operation, samples were collected from different wells within the well field for different components of the study. Data collected from all of the well-field wells were considered comparable because of similar well construction, hydrogeology, and geochemistry. An additional 38 PSWs (mostly completed in the confined part of the aquifer) were sampled throughout the regional aquifer to characterize water quality. Two monitoring well clusters, with wells completed at different depths, were installed to the east and west of the well field (the Zarzamora and Timberhill monitoring well clusters, respectively). One of the monitoring wells was completed in the overburden to evaluate potential hydrologic connectivity with the Edwards aquifer. Geophysical and flowmeter logs were collected from one of the well-field PSWs to determine zones of contribution to the wellbore. These contributing zones, associated with different hydrogeologic units, were used to select monitoring well completion depths and groundwater sample collection depths for depth-dependent sampling. Depth-dependent samples were collected from the PSW from three different depths and under three different pumping conditions. Additionally, selected monitoring wells and one of the well-field PSWs were sampled several times in response to a rainfall and recharge event to assess short-term (event-scale) temporal variations in water quality. For comparison purposes, groundwater samples were categorized as being from regional aquifer PSWs, from the well field (wellhead samples), from the monitoring wells (excluding the overburden well), from the overburden well, from the PSW depth-dependent sampling, and from temporal sampling. Groundwater samples were analyzed for inorganic, organic, isotopic, and age-dating tracers to characterize geochemical conditions in the aquifer and provide understanding of the mechanisms of mobilization and movement of selected constituents from source areas to a PSW. Sources, tracers, and conditions used to assess water quality and processes affecting the PSW and the aquifer system included (1) carbonate host rock composition; (2) physicochemical constituents; (3) major and trace element concentrations; (4) saturation indices with respect to minerals in aquifer rocks; (5) elemental ratios, such as magnesium to calcium ratios, that are indicative of water-rock interaction processes; (6) oxidation-reduction conditions; (7) nutrient concentrations, in particular nitrate concentrations; (8) the isotopic composition of nitrate, which can point to specific nitrate sources; (9) strontium isotopes; (10) stable isotopes of hydrogen and oxygen; (11) organic contaminant concentrations, including pesticides and volatile organic compounds; (12) age tracers, apparent-age distribution, and dissolved gas data used in age interpretations; (13) depth-dependent water chemistry collected from the PSW under different pumping conditions to assess zones of contribution; and (14) temporal variability in groundwater composition from the PSW and selected monitoring wells in response to an aquifer recharge event. Geochemical results indicate that the well-field and monitoring well samples were largely representative of groundwater in the regional confined aquifer. Constituents of concern in the Edwards aquifer for the long-term sustainability of the groundwater resource include the nutrient nitrate and anthropogenic organic contaminants. Nitrate concentrations (as nitrogen) for regional aquifer PSWs had a median value of 1.9 milligrams per liter, which is similar to previously reported values for the regional aquifer. Nitrate-isotope compositions for groundwater samples collected from the well-field PSWs and monitoring wells had a narrow range, with values indicative of natural soil organic values. A comparison with historical nitrate-isotope values, however, suggests that a component of nitrate in groundwater from biogenic sources might have increased over the last 30 years. Several organic contaminants (the pesticide atrazine, its degradate deethylatrazine, trichloromethane (chloroform; a drinking-water disinfection byproduct), and the solvent tetrachloroethene (PCE)) were widely distributed throughout the regional aquifer and in the local-scale TANC study area at low concentrations (less than 1 microgram per liter). Higher concentrations of PCE were detected in samples from the well-field PSWs and Zarzamora monitoring wells relative to the regional aquifer PSWs. The urban environment is a likely source of contaminants to the aquifer, and these results indicate that one or more local urban sources might be supplying PCE to the Zarzamora monitoring wells and the well-field wells. Samples from the well field also had high concentrations of chloroform relative to the monitoring wells and regional aquifer PSWs. For samples from the regional aquifer PSWs, the most frequently detected organic contaminants generally decreased in concentration with increasing well depth. Deeper wells might intercept longer regional flow paths with higher fractions of older water or water recharged in rural recharge areas in the western part of the aquifer that have been less affected by anthropogenic contaminants. A scenario of hypothetical contaminant loading was evaluated by using results from groundwater-flow-model particle tracking to assess the response of the aquifer to potential contamination. Results indicate that the aquifer responds quickly (less than 1 year to several years) to contaminant loading; however, it takes a relatively long time (decades) for concentrations to reach peak values. The aquifer also responds quickly (less than 1 year to several years) to the removal of contaminant loading; however, it also takes a relatively long time (decades) to reach near background concentrations. Interpretation of geochemical age tracers in this well-mixed karst system was complicated by contamination of a majority of measured tracers and complexities of extensive mixing. Age-tracer results generally indicated that groundwater samples were composed of young, recently recharged water with piston-flow model ages ranging from less than 1 to 41 years, with a median of 17 years. Although a piston-flow model is typically not valid for karst aquifers, the model ages provide a basis for comparing relative ages of different samples and a reference point for more complex hydrogeologic models for apparent-age interpretations. Young groundwater ages are consistent with particle-tracking results from hydrogeologic modeling for the local-scale TANC study area. Age-tracer results compared poorly with other geochemical indicators of groundwater residence time and anthropogenic effects on water quality, indicating that hydrogeologic conceptual models used in groundwater age interpretations might not adequately account for mixing in this karst system. Groundwater samples collected from the well field under a variety of pumping conditions were relatively homogeneous and well mixed for numerous geochemical constituents (with the notable exception of age tracers). Groundwater contributions to the PSW were dominated by well-mixed, relatively homogeneous groundwater, typical of the regional confined aquifer. Zones of preferential flow were determined for the PSW, but groundwater samples from different stratigraphic units were not geochemically distinct. Variations in chemical constituents in response to a rainfall and aquifer recharge event occurred but were relatively minor in the PSW and monitoring wells. This observation is consistent with the hypothesis that the response to individual recharge events in the confined aquifer, unless intersecting conduit flow paths, might be attenuated by mixing processes along regional flow paths. Results of this study are consistent with the existing conceptual understanding of aquifer processes in this karst system and are useful for water-resource development and management practices.

Texas↗
USGS2020

Evaluation of hydrologic impact of an irrigation curtailment program in the Upper Klamath Lake Basin using Landsat satellite data

Upper Klamath Lake (UKL) is the source of the Klamath river that flows through southern Oregon and northern California. The UKL basin is home to two endangered species and provides water for 81,000+ ha (200,000+ acres) of irrigation on the United States Bureau of Reclamation (USBR) Klamath Project located downstream of the UKL basin. Irrigated agriculture also occurs along the tributaries to UKL. During 2013–2016, water right calls resulted in various levels of curtailment of irrigation diversions from the tributaries to UKL. However, information on the extent of curtailment, how much irrigation water was saved, and its impact on the UKL is unknown. In this study, we combined Landsat-based actual evapotranspiration (ETa) data obtained from the Operational Simplified Surface Energy Balance (SSEBop) model with gridded precipitation and USGS station discharge data to evaluate the hydrologic impact of the curtailment program. Analysis was performed for five base years (2004, 2006, 2008-2010) and four target years (2013-2016) over irrigated areas above UKL. Our results indicated that the impact of the curtailment program over the June to September time-period was highest during 2013 and declined in each of the following years. The total on-field water savings were approximately 60 hm3 in 2013 and 2014, 44 hm3 in 2015, and 32 hm3 in 2016. The instream water flow change or extra water available (EWA) were found at 92, 68, 45, and 26 hm3 respectively for 2013, 2014, 2015 and 2016. Most water savings came from pasture and wetlands. Alfalfa showed the most decline in water use among grain crops. The resulting EWA from the curtailment contributed to a maximum of 19% of the lake inflows and 50% of the lake volume. This study presents the use of Landsat-based ETa and other remote sensing datasets for evaluating water-related impacts of the irrigation curtailment program.

Upper Klamath Lake Basin↗
USGS2024

An intercomparison of DOC estimated from fDOM sensors in wildfire affected streams of the western United States

Wildfires in the western United States (US) have been demonstrated to affect water quality, including dissolved organic carbon (DOC), in streams. Elevated post-wildfire DOC concentration poses a potential risk to drinking water treatment systems. In-stream measurements of fluorescent dissolved organic matter (fDOM), a proxy for DOC, have shown potential to detect dynamic changes in DOC. High frequency monitoring of water temperature, turbidity, and fDOM was used in conjunction with discrete sampling during targeted storm events and at fixed intervals to estimate DOC in five western US streams following wildfires in 2020 and 2021 with the objective to characterise and compare responses to wildfire among sites. The elevated turbidity conditions typical after wildfire presented a challenge to fDOM measurements and there was a need to identify appropriate turbidity corrections at burned sites. A combination of established and novel methods corrected fDOM concentrations for turbidity effects up to 800 Formazin nephelometric units (FNU). Pre-wildfire high frequency water quality data in adjacent burned and unburned watersheds allowed for separation of climate effects on DOC at one of the sites. Hydrology, climate and landcover were more important drivers of post-wildfire DOC yield than wildfire characteristics. Seasonal patterns of DOC were unchanged by wildfire in snowmelt-driven watersheds. Large, transient spikes in DOC concentration following frontal and convective storms were observed post-wildfire at all burned sites, but not at the unburned site. These spikes often exceeded operational thresholds for drinking water treatment. This study highlights the ability to develop high frequency DOC estimates in surface waters up to 800 FNU using fDOM sensors and targeted storm sampling and emphasises the value of high frequency pre-wildfire data in adjacent burned and unburned watersheds for separating climate and wildfire effects.

California, Colorado, Montana, Oregon↗
USGS2017

Geospatial tools effectively estimate nonexceedance probabilities of daily streamflow at ungauged and intermittently gauged locations in Ohio

Study region The state of Ohio in the United States, a humid, continental climate. Study focus The estimation of nonexceedance probabilities of daily streamflows as an alternative means of establishing the relative magnitudes of streamflows associated with hydrologic and water-quality observations. New hydrological insights for the region Several methods for estimating nonexceedance probabilities of daily mean streamflows are explored, including single-index methodologies (nearest-neighboring index) and geospatial tools (kriging and topological kriging). These methods were evaluated by conducting leave-one-out cross-validations based on analyses of nearly 7 years of daily streamflow data from 79 unregulated streamgages in Ohio and neighboring states. The pooled, ordinary kriging model, with a median Nash–Sutcliffe performance of 0.87, was superior to the single-site index methods, though there was some bias in the tails of the probability distribution. Incorporating network structure through topological kriging did not improve performance. The pooled, ordinary kriging model was applied to 118 locations without systematic streamgaging across Ohio where instantaneous streamflow measurements had been made concurrent with water-quality sampling on at least 3 separate days. Spearman rank correlations between estimated nonexceedance probabilities and measured streamflows were high, with a median value of 0.76. In consideration of application, the degree of regulation in a set of sample sites helped to specify the streamgages required to implement kriging approaches successfully.

Ohio↗
USGS2015

The role of precipitation type, intensity, and spatial distribution in source water quality after wildfire

Storms following wildfires are known to impair drinking water supplies in the southwestern United States, yet our understanding of the role of precipitation in post-wildfire water quality is far from complete. We quantitatively assessed water-quality impacts of different hydrologic events in the Colorado Front Range and found that for a three-year period, substantial hydrologic and geochemical responses downstream of a burned area were primarily driven by convective storms with a 30 min rainfall intensity >10 mm h −1 . These storms, which typically occur several times each year in July–September, are often small in area, short-lived, and highly variable in intensity and geographic distribution. Thus, a rain gage network with high temporal resolution and spatial density, together with high-resolution stream sampling, are required to adequately characterize post-wildfire responses. We measured total suspended sediment, dissolved organic carbon (DOC), nitrate, and manganese concentrations that were 10–156 times higher downstream of a burned area compared to upstream during relatively common (50% annual exceedance probability) rainstorms, and water quality was sufficiently impaired to pose water-treatment concerns. Short-term water-quality impairment was driven primarily by increased surface runoff during higher intensity convective storms that caused erosion in the burned area and transport of sediment and chemical constituents to streams. Annual sediment yields downstream of the burned area were controlled by storm events and subsequent remobilization, whereas DOC yields were closely linked to annual runoff and thus were more dependent on interannual variation in spring runoff. Nitrate yields were highest in the third year post-wildfire. Results from this study quantitatively demonstrate that water quality can be altered for several years after wildfire. Because the southwestern US is prone to wildfires and high-intensity rain storms, the role of storms in post-wildfire water-quality impacts must be considered when assessing water-quality vulnerability.

Arizona, Colorado, New Mexico, Utah↗
USGS2011

Impacts of agricultural land use on biological integrity: A causal analysis

Agricultural land use has often been linked to nutrient enrichment, habitat degradation, hydrologic alteration, and loss of biotic integrity in streams. The U.S. Geological Survey's National Water Quality Assessment Program sampled 226 stream sites located in eight agriculture‐dominated study units across the United States to investigate the geographic variability and causes of agricultural impacts on stream biotic integrity. In this analysis we used structural equation modeling (SEM) to develop a national and set of regional causal models linking agricultural land use to measured instream conditions. We then examined the direct, indirect, and total effects of agriculture on biotic integrity as it acted through multiple water quality and habitat pathways. In our nation‐wide model, cropland affected benthic communities by both altering structural habitats and by imposing water quality‐related stresses. Region‐specific modeling demonstrated that geographic context altered the relative importance of causal pathways through which agricultural activities affected stream biotic integrity. Cropland had strong negative total effects on the invertebrate community in the national, Midwest, and Western models, but a very weak effect in the Eastern Coastal Plain model. In the Western Arid and Eastern Coastal Plain study regions, cropland impacts were transmitted primarily through dissolved water quality contaminants, but in the Midwestern region, they were transmitted primarily through particulate components of water quality. Habitat effects were important in the Western Arid model, but negligible in the Midwest and Eastern Coastal Plain models. The relative effects of riparian forested wetlands also varied regionally, having positive effects on biotic integrity in the Eastern Coastal Plain and Western Arid region models, but no statistically significant effect in the Midwest. These differences in response to cropland and riparian cover suggest that best management practices and planning for the mitigation of agricultural land use impacts on stream ecosystems should be regionally focused.

Ecological Applications↗