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Sources and sinks of filtered total mercury and concentrations of total mercury of solids and of filtered methylmercury, Sinclair Inlet, Kitsap County, Washington, 2007-10

The majority of filtered total mercury in the marine water of Sinclair Inlet originates from salt water flowing from Puget Sound. About 420 grams of filtered total mercury are added to Sinclair Inlet each year from atmospheric, terrestrial, and sedimentary sources, which has increased filtered total mercury concentrations in Sinclair Inlet (0.33 nanograms per liter) to concentrations greater than those of the Puget Sound (0.2 nanograms per liter). The category with the largest loading of filtered total mercury to Sinclair Inlet included diffusion of porewaters from marine sediment to the water column of Sinclair Inlet and discharge through the largest stormwater drain on the Bremerton naval complex, Bremerton, Washington. However, few data are available to estimate porewater and stormwater releases with any certainty. The release from the stormwater drain does not originate from overland flow of stormwater. Rather total mercury on soils is extracted by the chloride ions in seawater as the stormwater is drained and adjacent soils are flushed with seawater by tidal pumping. Filtered total mercury released by an unknown freshwater mechanism also was observed in the stormwater flowing through this drain. Direct atmospheric deposition on the Sinclair Inlet, freshwater discharge from creek and stormwater basins draining into Sinclair Inlet, and saline discharges from the dry dock sumps of the naval complex are included in the next largest loading category of sources of filtered total mercury. Individual discharges from a municipal wastewater treatment plant and from the industrial steam plant of the naval complex constituted the loading category with the third largest loadings. Stormwater discharge from the shipyard portion of the naval complex and groundwater discharge from the base are included in the loading category with the smallest loading of filtered total mercury. Presently, the origins of the solids depositing to the sediment of Sinclair Inlet are uncertain, and consequently, concentrations of sediments can be qualitatively compared only to total mercury concentrations of solids suspended in the water column. Concentrations of total mercury of suspended solids from creeks, stormwater, and even wastewater effluent discharging into greater Sinclair Inlet were comparable to concentrations of solids suspended in the water column of Sinclair Inlet. Concentrations of total mercury of suspended solids were significantly lower than those of marine bed sediment of Sinclair Inlet; these suspended solids have been shown to settle in Sinclair Inlet. The settling of suspended solids in the greater Sinclair Inlet and in Operable Unit B Marine of the naval complex likely will result in lower concentrations of total mercury in sediments. Such a decrease in total mercury concentrations was observed in the sediment of Operable Unit B Marine in 2010. However, total mercury concentrations of solids discharged from several sources from the Bremerton naval complex were higher than concentrations in sediment collected from Operable Unit B Marine. The combined loading of solids from these sources is small compared to the amount of solids depositing in OU B Marine. However, total mercury concentration in sediment collected at a monitoring station just offshore one of these sources, the largest stormwater drain on the Bremerton naval complex, increased considerably in 2010. Low methylmercury concentrations were detected in groundwater, stormwater, and effluents discharged from the Bremerton naval complex. The highest methylmercury concentrations were measured in the porewaters of highly reducing marine sediment in greater Sinclair Inlet. The marine sediment collected off the largest stormwater drain contained low concentrations of methylmercury in porewater because these sediments were not highly reducing.

Washington↗

Iron mineralogy and bioaccessibility of dust generated from soils as determined by reflectance spectroscopy and magnetic and chemical properties--Nellis Dunes recreational area, Nevada

Atmospheric mineral dust exerts many important effects on the Earth system, such as atmospheric temperatures, marine productivity, and melting of snow and ice. Mineral dust also can have detrimental effects on human health through respiration of very small particles and the leaching of metals in various organs. These effects can be better understood through characterization of the physical and chemical properties of dust, including certain iron oxide minerals, for their extraordinary radiative properties and possible effects on lung inflammation. Studies of dust from the Nellis Dunes recreation area near Las Vegas, Nevada, focus on characteristics of radiative properties (capacity of dust to absorb solar radiation), iron oxide mineral type and size, chemistry, and bioaccessibility of metals in fluids that simulate human gastric, lung, and phagolysosomal fluids. In samples of dust from the Nellis Dunes recreation area with median grain sizes of 2.4, 3.1, and 4.3 micrometers, the ferric oxide minerals goethite and hematite, at least some of it nanosized, were identified. In one sample, in vitro bioaccessibility experiments revealed high bioaccessibility of arsenic in all three biofluids and higher leachate concentration and bioaccessibility for copper, uranium, and vanadium in the simulated lung fluid than in the phagolysosomal fluid. The combination of methods used here to characterize mineral dust at the Nellis Dunes recreation area can be applied to global dust and broad issues of public health.

Nevada↗

Chloride concentrations, loads, and yields in four watersheds along Interstate 95, southeastern Connecticut, 2008-11: factors that affect peak chloride concentrations during winter storms

Chloride (Cl - ) concentrations and loads and other water chemistry characteristics were assessed to evaluate potential effects of road-deicer applications on streamwater quality in four watersheds along Interstate 95 (I–95) in southeastern Connecticut from November 1, 2008, through September 30, 2011. Streamflow and water quality were studied in the Four Mile River, Oil Mill Brook, Stony Brook, and Jordan Brook watersheds, where developed land ranged from 9 to 32 percent. Water-quality samples were collected and specific conductance was measured continuously at paired water-quality monitoring sites, upstream and downstream from I–95. Specific conductance values were related to Cl - concentrations to assist in determining the effects of road-deicing operations on the levels of Cl - in the streams. Streamflow and water-quality data were compared with weather data and with the timing, amount, and composition of deicers applied to State highways. Grab samples were collected during winter stormwater-runoff events, such as winter storms or periods of rain or warm temperatures in which melting takes place. Grab samples were also collected periodically during the spring and summer and during base-flow conditions. The estimated Cl - concentrations at the eight water-quality monitoring sites during winter storms peaked as high as 270 milligrams per liter (mg/L) and were well below the U.S. Environmental Protection Agency (EPA) recommended acute chloride toxicity criterion of 860 mg/L and the chronic 4-day average toxicity criterion of 230 mg/L. Cl - concentrations in streams, particularly at sites downstream from I–95, peaked during increased streamflow in the winter and early spring as a result of deicers applied to roads and washed off by stormwater or meltwater. Cl - concentrations during most of the nonwinter seasons decreased during increases in streamflow because storm runoff was more dilute than base flow. However, peaks in specific conductance and estimated chloride concentrations at streams in more urbanized watersheds corresponded to peaks in streamflow well after winter snow or ice events; these delayed peaks in Cl - concentration likely resulted from deicer residue that remained in melting snow piles and on roadsides and (or) that were flushed from soils and shallow groundwater, then discharged downstream. Estimated peak Cl - concentrations varied with the type of winter storm event and were highest during or after winter storms of frozen precipitation and rain, in which the rain or meltwater effectively washed off the deicers. Estimated peak Cl - concentrations correlated positively with the duration of deicer application but generally not with streamflow. Estimated peak Cl - concentrations during the winter season were highest during low streamflow at most sites. Chloride concentrations varied considerably in shallow groundwater as a result of land-use differences. Cl - concentrations were very high (as high as 800 mg/L) in shallow groundwater downstream from I–95 at the Four Mile River site. Chloride/bromide mass concentration ratios and the proximity of a former landfill and sewage lagoon upstream indicate a likely source of Cl - is landfill leachate and possibly sewage leachate. Cl - loads in streams generally were highest in the winter and early spring. The estimated daily Cl - yield for the four monitoring sites downstream from I–95 ranged from 0.0004 ton per day per square mile for one of the least developed watersheds to 0.052 ton per day per square mile for the watershed with the highest percentage of urban development and impervious area. The estimated median contribution of Cl - load from atmospheric deposition was small and ranged from 0.07 percent of Cl - load at the Jordan Brook watershed to 0.57 percent at the Oil Mill Brook watershed. The Cl - loads in streams (outputs) were compared with Cl - load inputs, which include atmospheric deposition and deicer applications; Cl - load inputs were slightly larger than the Cl - load outputs at most of the sites during most years but do not account for the Cl - load in groundwater leaving the watersheds. A multiple linear regression model was developed to describe the variability of the natural log of peak specific conductance, as well as estimated Cl - concentrations. Five significant variables best explained the variability in the natural log of the peak specific conductance after deicing events: (1) snow on ground before deicing event; (2) winter precipitation with rain; (3) specific conductance in base flow; (4) State-operated road lane miles divided by watershed area; and (5) amount of Cl - from deicers applied to State-operated roads per lane mile. In this report, winter precipitation is defined as any type of precipitation, including frozen precipitation and rain, that occurs during the active deicing season, typically November through March. Frozen precipitation is defined here as snow, sleet, freezing rain, or any winter precipitation except rain. The addition of a lane mile in both directions on I–95 would result in an estimate of approximately 2 to 11 percent increase in Cl - input from deicers applied to I–95 and other roads maintained by Connecticut Department of Transportation. The largest estimated increase in Cl - load was in the watersheds with the greatest number miles of I–95 corridor relative to the total lane miles maintained by Connecticut Department of Transportation. On the basis of these estimates and the estimated peak Cl - concentrations during the study period, it is unlikely that the increased use of deicers on the additional lanes would lead to Cl - concentrations that exceed the aquatic habitat criteria.

Connecticut↗

Water quality and hydrology of Silver Lake, Oceana County, Michigan, with emphasis on lake response to nutrient loading

Executive Summary Silver Lake is a 672-acre inland lake located in Oceana County, Michigan, and is a major tourist destination due to its proximity to Lake Michigan and the surrounding outdoor recreational opportunities. In recent years, Silver Lake exhibited patterns of high phosphorus concentrations, elevated chlorophyll a concentrations, and nuisance algal blooms. The U.S. Geological Survey (USGS), in cooperation with the Silver Lake Improvement Board and in collaboration with the Annis Water Resources Institute (AWRI) of Grand Valley State University, designed a study to assess the hydrologic and nutrient inputs to Silver Lake in order to identify the events and conditions that affect the nutrient chemistry and production of algal blooms in the lake. This information can inform water-resource managers in developing various management strategies to prevent or reduce the occurrence of future algal blooms. USGS and AWRI scientists collected data from November 2012 to December 2014 to provide information for future management decisions for Silver Lake. Silver Lake can be classified as a polymictic lake and has a residence time of approximately 223 days. Based on the mean lake Secchi depth, total phosphorus, and total nitrogen concentrations, Silver Lake is classified as a eutrophic lake. In-situ bioassay results indicate that algal growth in Silver Lake is colimited by both nitrogen and phosphorus. The nutrient budget for Silver Lake was calculated using the BATHTUB model based on 2 years of water-quality data collection. The BATHTUB model, developed by the U.S. Army Corps of Engineers, treats the lake as a well-mixed system with multiple inputs and outlets for both water and dissolved constituents, such as nutrients. Based on results of the BATHTUB model, which were conditioned on observed concentrations and flows, the mean annual input of phosphorus to Silver Lake was approximately 1,342 pounds (lb); the mean annual input of nitrogen to Silver Lake was approximately 51,998 lb. The major measured sources of phosphorus loading to Silver Lake were groundwater and Hunter Creek, whereas the major measured sources of nitrogen to Silver Lake were Hunter Creek, groundwater, and atmospheric deposition. The largest loading of phosphorus and nitrogen to Silver Lake occurred during the spring. Minimal phosphorus deposition (if any) occurred in the lakebed sediment; however, of the nitrogen that entered Silver Lake, approximately 42.2 percent was deposited in the lakebed sediment as simulated by the BATHTUB model. In addition to measured sources, a septic load model was used to estimate the likely range of septic contribution to groundwater and adjacent surface waters. The likely septic loading scenario estimates that septic systems contribute 47.8 percent of the phosphorus to groundwater and 22.3 percent of phosphorus to Hunter Creek. These results indicate that septic systems are a major source of phosphorus loading to Silver Lake. The likely septic loading scenario indicated that septic systems account for 0.95 percent of the nitrogen load to Hunter Creek and 1.1 percent of the contribution of nitrogen to groundwater. The BATHTUB model was used to estimate future nutrient loading and eutrophication scenarios based on water-quality data collected from Silver Lake, groundwater, major tributaries, and atmospheric deposition. A separate septic load model was used to estimate the septic contribution to groundwater or directly to surface water, and the nutrient load estimates were modeled using the BATHTUB model to determine subsequent water-quality changes to Silver Lake. BATHTUB model scenarios based on measured data: The first BATHTUB scenario evaluated the condition of Silver Lake and the change to lake water quality (trophic status) as a result of changes in nutrient loading from different sources. Based on BATHTUB model simulations, if groundwater loading of phosphorus and nitrogen only were decreased by 75 percent, and all of the other nutrient inputs stayed the same, the future condition of Silver Lake would most likely remain highly mesotrophic to eutrophic (the current [2014] condition of Silver Lake). If nutrient loading continued to increase in groundwater, the lake would continue to remain eutrophic with more frequent algal blooms. If nutrient loading from Hunter Creek only decreased by 50–75 percent, and all of the other nutrient inputs stayed the same as the baseline dataset, Silver Lake would remain eutrophic to highly mesotrophic. By reducing the input of manageable nutrient sources (Hunter Creek, groundwater, and lawn runoff) by 75 percent, the BATHTUB model simulation indicates that Silver Lake would be classified as mesotrophic, which is indicative of improved water quality, water clarity, and reduced algal bloom frequency. Simulations also were run using the BATHTUB model to evaluate the number of days Silver Lake could experience algal blooms (algal blooms are defined as modeled chlorophyll a in excess of 10 micrograms per liter [µg/L]) as a result of an increase/decrease in phosphorus and nitrogen loading from groundwater, Hunter Creek, and (or) a combination of sources. If the phosphorus and nitrogen loading from Hunter Creek is decreased (and all other sources are not altered), Silver Lake will continue to experience algal blooms, but less frequently than what is currently experienced. The same scenario holds true if the nutrient loading from groundwater is decreased. Another scenario was simulated using a combination of sources, which includes increases and decreases in phosphorus and nitrogen loading from sources that are the most likely to be managed, and includes groundwater (as a result of conversion of household septic to sewers), Hunter Creek (conversion of household septic to sewers), and lawn runoff. Results of the BATHTUB model indicated that a 50-percent reduction of phosphorus and nitrogen from these sources would result in a considerable decrease in algal bloom frequency (from 231 to 132 days) and severity, and a 75-percent reduction would greatly reduce algal bloom occurrence on Silver Lake (from 231 to 57 days). BATHTUB model scenarios based on septic load model: A scenario also was conducted using the BATHTUB model to simulate the conversion of septic to sewer and included a low, high, and medium (likely) scenario of nutrient loading to Silver Lake. Simulations of the BATHTUB model indicated that, under the likely scenario, the conversion of all onsite septic treatment to sewers would result in an overall change in lake trophic status from eutrophic to mesotrophic, thereby reducing the frequency of algal blooms and algal bloom intensity on Silver Lake (chlorophyll a >10 µg/L, from 231 to 184 days per year, or chlorophyll a >20 µg/L, from 80 to 49 days per year).

Michigan↗

Response of Green Lake, Wisconsin, to changes in phosphorus loading, with special emphasis on near-surface total phosphorus concentrations and metalimnetic dissolved oxygen minima

Green Lake is the deepest natural inland lake in Wisconsin, with a maximum depth of about 72 meters. In the early 1900s, the lake was believed to have very good water quality (low nutrient concentrations and good water clarity) with low dissolved oxygen (DO) concentrations occurring in only the deepest part of the lake. Because of increased phosphorus (P) inputs from anthropogenic activities in its watershed, total phosphorus (TP) concentrations in the lake have increased; these changes have led to increased algal production and low DO concentrations not only in the deepest areas but also in the middle of the water column (metalimnion). The U.S. Geological Survey has routinely monitored the lake since 2004 and its tributaries since 1988. Results from this monitoring led the Wisconsin Department of Natural Resources (WDNR) to list the lake as impaired because of low DO concentrations in the metalimnion, and they identified elevated TP concentrations as the cause of impairment. As part of this study by the U.S. Geological Survey, in cooperation with the Green Lake Sanitary District, the lake and its tributaries were comprehensively sampled in 2017–18 to augment ongoing monitoring that would further describe the low DO concentrations in the lake (especially in the metalimnion). Empirical and process-driven water-quality models were then used to determine the causes of the low DO concentrations and the magnitudes of P-load reductions needed to improve the water quality of the lake enough to meet multiple water-quality goals, including the WDNR’s criteria for TP and DO. Data from previous studies showed that DO concentrations in the metalimnion decreased slightly as summer progressed in the early 1900s but, since the late 1970s, have typically dropped below 5 milligrams per liter (mg/L), which is the WDNR criterion for impairment. During 2014–18 (the baseline period for this study), the near-surface geometric mean TP concentration during June–September in the east side of the lake was 0.020 mg/L and in the west side was 0.016 mg/L (both were above the 0.015-mg/L WDNR criterion for the lake), and the metalimnetic DO minimum concentrations (MOMs) measured in August ranged from 1.0 to 4.7 mg/L. The degradation in water quality was assumed to have been caused by excessive P inputs to the lake; therefore, the TP inputs to the lake were estimated. The mean annual external P load during 2014–18 was estimated to be 8,980 kilograms per year (kg/yr), of which monitored and unmonitored tributary inputs contributed 84 percent, atmospheric inputs contributed 8 percent, waterfowl contributed 7 percent, and septic systems contributed 1 percent. During fall turnover, internal sediment recycling contributed an additional 7,040 kilograms that increased TP concentrations in shallow areas of the lake by about 0.020 mg/L. The elevated TP concentrations then persisted until the following spring. On an annual basis, however, there was a net deposition of P to the bottom sediments. Empirical models were used to describe how the near-surface water quality of Green Lake would be expected to respond to changes in external P loading. Predictions from the models showed a relatively linear response between P loading and TP and chlorophyll- a (Chl- a ) concentrations in the lake, with the changes in TP and Chl- a concentrations being less on a percentage basis (50–60 percent for TP and 30–70 percent for Chl- a ) than the changes in P loading. Mean summer water clarity, quantified by Secchi disk depths, had a greater response to decreases in P loading than to increases in P loading. Based on these relations, external P loading to the lake would need to be decreased from 8,980 kg/yr to about 5,460 kg/yr for the geometric mean June–September TP concentration in the east side of the lake, with higher TP concentrations than in the west side, to reach the WDNR criterion of 0.015 mg/L. This reduction of 3,520 kg/yr is equivalent to a 46-percent reduction in the potentially controllable external P sources (all external sources except for precipitation, atmospheric deposition, and waterfowl) from those measured during water years 2014–18. The total external P loading would need to decrease to 7,680 kg/yr (a 17-percent reduction in potentially controllable external P sources) for near-surface June–September TP concentrations in the west side of the lake to reach 0.015 mg/L. Total external P loading would need to decrease to 3,870–5,320 kg/yr for the lake to be classified as oligotrophic, with a near-surface June–September TP concentration of 0.012 mg/L. Results from the hydrodynamic water-quality model GLM–AED (General Lake Model coupled to the Aquatic Ecodynamics modeling library) indicated that MOMs are driven by external P loading and internal sediment recycling that lead to high TP concentrations during spring and early summer, which in turn lead to high phytoplankton production, high metabolism and respiration, and ultimately DO consumption in the upper, warmer areas of the metalimnion. GLM–AED results indicated that settling of organic material during summer might be slowed by the colder, denser, and more viscous water in the metalimnion and thus increase DO consumption. Based on empirical evidence from a comparison of MOMs with various meteorological, hydrologic, water quality, and in-lake physical factors, MOMs were lower during summers, when metalimnetic water temperatures were warmer, near-surface Chl- a and TP concentrations were higher, and Secchi depths were lower. GLM–AED results indicated that the external P load would need to be reduced to about 4,060 kg/yr, a 57-percent reduction from that measured in 2014–18, to eliminate the occurrence of MOMs less than 5 mg/L during more than 75 percent of the years (the target provided by the WDNR). Large reductions in external P loading are expected to have an immediate effect on the near-surface TP concentrations and metalimnetic DO concentrations in Green Lake; however, it may take several years for the full effects of the external-load reduction to be observed because internal sediment recycling is an important source of P for the following spring.

Wisconsin↗

Simulated mean monthly groundwater-transported nitrogen loads in watersheds on the north shore of Long Island Sound, 1993–2022

Elevated nitrogen loads are pervasive in the Long Island Sound, an estuary that receives freshwater and nutrients from both surface-water and groundwater discharge. Surface-water nitrogen loads to the Long Island Sound are relatively well characterized, but less is known about groundwater-transported nitrogen loads. Prior work on the northern shore of Long Island Sound (Connecticut and areas of New York and Rhode Island) suggested that groundwater travel times are relatively short (median less than 2 years) and that decade-long nutrient legacies are not widespread. Because the travel times are short, groundwater flow and nutrient loads likely vary substantially between months. In the current study, the U.S. Geological Survey, in cooperation with the U.S. Environmental Protection Agency’s Long Island Sound Study and the Connecticut Department of Energy and Environmental Protection, developed a set of models to better characterize spatial and temporal patterns of groundwater-transported nitrogen loading from atmospheric deposition, septic systems, and fertilizers within the study area. The models provide an estimate, with uncertainty, of groundwater-transported nitrogen loads in the study area, filling a key gap in the nitrogen budget for Long Island Sound. The models also highlight the spatial and temporal variation in nitrogen loading throughout the study area. The modeling workflow involved four models. (1) A soil-water-balance model was developed by using the Soil-Water-Balance software to simulate groundwater recharge across the study area for water years 2005 through 2022. The simulated mean monthly recharge from the soil-water-balance model was used as input into a groundwater-flow model. (2) The groundwater-flow model was developed by using the MODFLOW 6 software and data for water years 1993 through 2022 and simulates average monthly hydrologic conditions. The groundwater-flow model was calibrated by using the Iterative Ensemble Smoother method within the PEST++ software. The Iterative Ensemble Smoother method generates an ensemble of sets of parameter values, with each set producing reasonable simulated hydrologic parameter values. (3) An ensemble of MODPATH particle-tracking simulations were run to generate particle flow paths and travel times, with each simulation using a different set of the flow model parameters. (4) A nitrogen load model uses the MODPATH simulation outputs to track nitrogen from the land surface through multiple attenuation zones until it discharges into fresh or saline surface water. As with the groundwater-flow model, the nitrogen model simulated average monthly groundwater-transported nitrogen loads for water years 1993 through 2022. One novel aspect of the nitrogen load model is that the nitrogen attenuation parameters were calibrated to observed nitrogen loads. Across the ensemble of simulated nitrogen loads, the median study-area-wide monthly simulated nitrogen loads from the aquifer to Long Island Sound throughout the year ranged from 900 to 18,600 kilograms of nitrogen per day, with a median load of 5,100 kilograms of nitrogen per day. The simulated loads were based on average monthly conditions for water years 1993 through 2022. Loads were highest during the winter and early spring and lowest during the late summer. However, simulated travel times for groundwater and nitrogen loads discharged to Long Island Sound during summer were longer than travel times for groundwater and loads discharged during the winter, indicating that, on average, groundwater discharged during summer traveled along different, and longer, flow paths, than groundwater discharged during winter. This indicates that summer loads would respond more slowly to changes in nitrogen inputs at the water table than winter loads. Over the entire study area, approximately 15 percent of the simulated load is from atmospheric deposition sources, 30 to 40 percent is from fertilizer, and 50 to 60 percent is from septic systems. The final analysis of the study involved simulating the change in groundwater-transported nitrogen load in response to upgrading septic systems or reducing fertilizing inputs to areas of turf grass. Both management interventions reduced the groundwater-transported nitrogen load, and reductions were greater in areas with greater loads from septic systems or turf-grass fertilizers. The delay between management actions and substantial reductions in groundwater-transported nitrogen loads varied seasonally; loads during the late summer months remained elevated longer than the winter loads.

Connecticut, Rhode Island↗

Assessing the potential for evaluation of wildland fire models using remotely sensed data—Summary proceedings from a U.S. Geological Survey workshop in 2024

On September 19, 2024, the U.S. Geological Survey (USGS) held a virtual workshop titled “Potential for Evaluation of Fire Models with Remote Sensing Data Workshop” to assess the feasibility of using remotely sensed datasets to evaluate next-generation wildland fire behavior models. Remote sensing and fire modelling experts gathered to: (1) assess the suitability of a variety of classified, commercial, and publicly available remotely sensed datasets for advancing fire model evaluation; (2) develop ideas on how to integrate remotely sensed data products with fire model inputs and outputs; and (3) identify any barriers and limitations to performing an evaluation of next-generation fire models. The USGS National Civil Applications Center, USGS Earth Resources Observation and Science Center, and USGS Fort Collins Ecosystem Science Center presented information on remote sensing datasets for three Arizona wildfire case studies. The development teams of the Fire Dynamics Simulator and QUIC-Fire fire behavior models presented their models and current evaluation methodologies. Interspersed with these presentations were discussions regarding how to expand current wildfire remote sensing data collection efforts beyond operational needs to assist in future fire modeling. Workshop participants agreed that several of the remote sensing datasets have potential for wildfire model evaluation. However, participants also identified several barriers and complications to performing a model evaluation including key gaps in wildfire datasets; uncertainties related to model fire-atmosphere reinitiation; lack of ground truthing and atmospheric correction of remotely sensed datasets; and differences in spatial, geolocation, radiometric, and temporal resolutions between the datasets and models. Further, the absence of standardized methodologies for image interpretation, poor understanding of sensor capabilities and limitations, and a lack of automation also hinder model evaluation efforts. Based on feedback from this workshop, USGS fire modelers are considering a project to address the uncertainties related to fire model reinitiation and encouraging fire practitioners to collaborate with remote sensing experts on wildland fires to improve data collection for a broader community of practice. Additionally, multiagency efforts are in development for a comprehensive cross-sensor validation and ground-truth campaign to test spatial, spectral, and geolocation sensor capabilities, determine limitations, and identify observational gaps for future sensor development and acquisition.

Arizona↗

Some limitations on the possible composition of the ore-forming fluid

The activity rations of various important anions (S, CO 3 , SO 4 , OH, F, and Cl) in hydrothermal solutions at the time of deposition are evaluated using a simple thermodynamic technique. The rations are interpreted in the light of the mineralogy of ore deposits and limites are placed on the variability of each ratio in hydrothermal solutions. All of the calculations are made for 25°C and cautious extrapolation to higher temperatures seems justified; however, additional data for elevated temperatures and pressures are needed before more than approximate values may be assigned to these ratios in the ore-forming fluid. The calculated partial pressure of CO 2 in the ore fluid is generally less than one atmosphere, which suggests that a dense CO 2 phase cannot be considered an importatn ore fluid for most deposits. The partial pressure of H 2 S is usually less than 10 -4 atmospheres which makes it extremely difficult to defend the heory that metals (other than the easily complexible mercury, arsenic, antimony, and perhaps fols and silver) are transported in quantity as complex sulfide and hydrosulfides. The sulfate to sulfide ration is such that the oxidation potential at the time of deposition is defined by the following equation: Eh (in volts) = 0.22 ± 0.04 - 0.059 pH.

Trace Elements Investigations↗

One-Water Hydrologic Flow Model: A MODFLOW based conjunctive-use simulation software

The U.S. Geological Survey’s (USGS) Modular Ground-Water Flow Model (MODFLOW-2005) is a computer program that simulates groundwater flow by using finite differences. The MODFLOW-2005 framework uses a modular design that allows for the easy development and incorporation of new features called processes and packages that work with or modify inputs to the groundwater-flow equation. A process solves a flow equation or set of equations. For example, the central part of MODFLOW is the groundwater-flow process that solves the groundwater-flow equation; the surface-water routing process is an additional process that solves the surface-water flow equation. Packages are code related to the groundwater-flow process. For example, the subsidence package modifies the groundwater-flow process by including aquifer compaction effects on flow. With the development of new packages and processes, the MODFLOW-2005 base framework diverged into multiple independent versions designed for specific simulation needs. This divergence limited each independent MODFLOW release to its specific purpose, so that there was no longer a single, comprehensive, general-purpose hydraulic-simulation framework. The MODFLOW One-Water Hydrologic Flow Model (MF-OWHM, also informally known as OneWater) is an integrated hydrologic flow model that combines multiple MODFLOW-2005 variants in one cohesive simulation software; changes were made to enable multiple capabilities in one code. This fusion of the MODFLOW-2005 versions resulted in a simulation software that can be used to address and analyze a wide class of conjunctive-use, water-management, water-food-security, and climate-crop-water scenarios. As a second core version of MODFLOW-2005, MF-OWHM maintains backward compatibility with existing MODFLOW-2005 versions, with features that include the following: Process-based simulation. Saturated groundwater flow (three-dimensional). Surface-water flow (one- and two-dimensional). Stream and river flow. Lake and reservoir storage. Landscape simulation and irrigated agriculture. Land-use and crop simulation. Root uptake of groundwater. Actual evapotranspiration. Estimated irrigation demand. Reservoir operations. Aquifer compaction and subsidence by vertical model-grid deformation. Seawater intrusion by a sharp-interface assumption. Karst-aquifer and fractured-bedrock flow. Turbulent and laminar-pipe network flow. Unsaturated groundwater flow (one-dimensional). Internal linkages among the processes that couple hydraulic head, flow, and deformation. Redesigned code for faster simulation, increased user-input options, easier model updates, and more robust error reporting than in previous models. MF-OWHM is a MODFLOW-2005 based integrated hydrologic model that can simulate and analyze varying environmental conditions to allow for the evaluation of management options from many components of human and natural water movement through a physically based, supply and demand framework. The term “integrated,” in the context of this report, refers to the tight coupling of groundwater flow, surface-water flow, landscape processes, aquifer compaction and subsidence, reservoir operations, and conduit (karst) flow. Another benefit of this integrated hydrologic model is that models developed to run by MODFLOW-2005, MODFLOW-NWT, MODFLOW-CFP, or MODFLOW-FMP can also be simulated with MF-OWHM. At the time of this report’s publication, MF-OWHM version 2 (MF-OWHM2) does not include a direct internal simulation of snowmelt, advanced mountainous watershed rainfall-runoff simulation, detailed shallow soil-moisture accounting, or atmospheric moisture content. Atmospheric moisture may be accounted for indirectly by, optionally, specifying a pan-evaporation rate, reference evapotranspiration, and precipitation. These features are not included to ensure that simulation runtime remains short enough to enable the use of automated methods of calibrating model parameters to field observations, which typically require many simulation model runs. The MF-OWHM approach is to include as much detail as possible to simulate hydrological processes, providing the simulation runtimes remain reasonable enough to allow for robust parameter estimation and model calibration. To represent both natural and human-influenced flow, MF-OWHM integrates physically based flow processes derived from MODFLOW-2005 in a supply and demand framework. From this integration, the physically based movement of groundwater, surface water, imported water, and precipitation serve as supply to meet consumptive demands associated with irrigated and non-irrigated agriculture, natural vegetation, and urban water uses. Water consumption is determined by balancing the available water supply with water demand, leading to the concept of a demand-driven, supply-constrained simulation. The MF-OWHM Supply-and-Demand Framework is especially useful for the analysis of agricultural water use, where there are often few data available to describe changes in land-use through time, such as crop type and distribution, and the associated changes in groundwater pumpage. This framework attempts to satisfy each land-use water demand with available water supplies—that is, groundwater uptake, precipitation, and irrigation. An option provided in MF-OWHM2 is to automatically increase groundwater pumping for irrigation, which often is unknown, by the calculated residual between demand and the other available sources of supply. From large- to small-scale applications, the physically based supply and demand framework provides key capabilities for simulating and analyzing historical, current, and future conjunctive-use of surface water and groundwater. To achieve the physically based supply and demand framework, the MODFLOW-2005 standard of no inter-package and -process communication was relaxed for MF-OWHM2. Traditional MODFLOW simulation models required that all packages and processes interact through the groundwater-flow equation or by removing the water flow from the simulation domain. For example, the MODFLOW-2005 representation of a groundwater well extracts water from the groundwater-flow equation (by subtraction) and removes it from the simulation domain. This feature is available in the MF-OWHM framework, but options have been added to allow the specification of a use or destination of pumped groundwater within the model domain, for example, it can be used for irrigation, managed aquifer recharge, or return-flow to streams.

Techniques and Methods↗

Controls of stream chemistry and fish populations in the Neversink watershed, Catskill Mountains, New York

The Neversink Watershed Study was initiated in 1991 to develop an understanding of the key natural processes that control water quality within the forested, 166 km 2 (64 mi 2 ), Neversink River watershed; part of the New York City drinking water supply system, in the Catskill Mountain region of New York. The study entailed (1) hydrological investigations of water movement from the atmosphere to streams, (2) biogeochemical investigations of nitrogen and calcium, important nutrients in forest and aquatic ecosystems whose availability has been altered by acidic deposition, (3) an investigation of elevational patterns in atmospheric deposition, and (4) fisheries investigations to determine the relative importance of physical habitat and acidic deposition in controlling the abundance and diversity of fish species in the watershed. This report summarizes the results of these investigations, which have also been presented, in detail, in peer-reviewed technical articles and reports that are cited throughout the text.

New York↗

Hydrology, water quality, and nutrient loads to Lake Catherine and Channel Lake, near Antioch, Lake County, Illinois

From April 21, 1998, through April 30, 1999, the U.S. Geological Survey, in cooperation with the Fox Waterway Agency, conducted an investigation designed to characterize the hydrology, water quality, hydrologic budget, sediment budget, and nutrient budget of Lake Catherine and Channel Lake, Lake County, Illinois. These lakes are the northernmost lakes of the Fox Chain of Lakes. Lake Catherine and Channel Lake are divided into two basins by a submerged ridge but are continuous at the surface. The lakes are marginally to moderately eutrophic. Lake Catherine and Channel Lake have a combined volume of 7,098 acre-feet at a stage of about 736.5 feet above sea level. Lake Catherine and Channel Lake are subject to thermal stratification. Although most of the water in the lakes is well oxidized, nearly anoxic conditions were present at the bottom of Lake Catherine and Channel Lake during part of the summer in 1998. Water enters Lake Catherine and Channel Lake as inflow from surface water in the watershed (61.9 percent), inflow through the State Highway 173 bridge openings (20.7 percent), direct precipitation (8.2 percent), inflow from storm drains (7.2 percent), and inflow of ground water (2.0 percent). Water exits Lake Catherine and Channel Lake as outflow through the State Highway 173 bridge openings (87.8 percent), evaporation (7.2 percent), and as outflow to ground water (5.0 percent). About 5,200 pounds of phosphorus and 107,200 pounds of nitrogen compounds were added to the lakes during the period of investigation. Phosphorus compounds were derived from primarily internal regeneration (40.2 percent), inflow from surface water in the watershed (30.9 percent), inflow from storm drains (12.5 percent), and inflow through the State Highway 173 bridge openings (9.8 percent). Inflowing ground water, waterfowl excrement, precipitation, and atmospheric deposition of particulate matter account for 6.6 percent of the phosphorus load. Nitrogen was derived from inflow of surface water from within the watershed (52.9 percent), internal regeneration (19.5 percent), inflow through the State Highway 173 bridge openings (10.7 percent), precipitation (7 percent), and inflow from storm drains (6.5 percent). Inflowing ground water, waterfowl excrement, and atmospheric deposition of particulate matter account for about 3.4 percent of the nitrogen load. About 2,220 pounds of phosphorus and 52,300 pounds of nitrogen compounds are removed from the lakes, primarily through the openings at State Highway 173. Nitrate, nitrite, ammonia, and dissolved phosphorus are utilized by algae and aquatic macrophytes. Uptake of these nutrients by aquatic macrophytes and algae temporarily removes them from the water column but not from the lake basin. Because the amount of nutrients entering the lake greatly exceeds the amount leaving, the nutrients are concentrated in the sediments at the lake bottom, where the nutrients can be used by the rooted aquatic macrophytes (rooted aquatic plant large enough to be visible to the unaided eye) and released to the water column during reducing conditions. The buildup of nitrogen and phosphorus compounds in the lakes has the potential over time to stimulate algal and plant growth to nuisance levels that have the potential to affect the fishery and detract from the aesthetic quality of these lakes.

Water-Resources Investigations Report↗

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida↗

Water budget for and nitrogen loads to Northeast Creek, Bar Harbor, Maine

The potential for nutrient enrichment to coastal estuaries on Mt. Desert Island, Maine, may affect the health of these important ecosystems at Acadia National Park. Inputs of water and nitrogen entering one of these coastal estuaries, Northeast Creek, and adjacent wetlands on Mt. Desert Island were quantified in a recent study conducted by the U.S. Geological Survey, in cooperation with the National Park Service. Streamflow and concentra-tions of nitrogen species in the four perennial streams entering the wetland/estuary system were measured monthly for 18 months to estimate loads and develop a water budget. Old Mill Brook was instrumented with a continuous-recording stream-flow gage; the MOVE.1 record-extension technique was used with this and several other nearby continuous gages to estimate daily surface-water inflow to the wetland. Inflow from ungaged basins was estimated from the unit-area yield calculated from data obtained from the gaged basins. Precipitation data collected at the National Atmospheric Deposition Program (NADP) site at Acadia National Park Headquarters and the Acadia National Park weather station were used to calculate atmospheric inputs. Evapotranspiration from the wetland was calculated using Fennessey and Vogel?s regionalized multivariate regression model of Penman-Montieth evapotranspiration. Geologic data collected in the field and taken from published geologic maps indicate that ground water probably does not contribute significantly to the water budget of this wetland system. Surface-water outflow from the wetland was not calculated because of the tidal nature of the outlet of the wetland and the difficulties associated with measuring flow in a tidal stream.

Water-Resources Investigations Report↗

Estimates of ground-water recharge from precipitation to glacial-deposit and bedrock aquifers on Lopez, San Juan, Orcas, and Shaw islands, San Juan County, Washington

An important source of fresh water on Lopez, San Juan, Orcas, and Shaw Islands in San Juan County off the northwestern coast of Washington is glacial-deposit and bedrock aquifers. Two methods were used to estimate recharge from precipitation to the water tables on the islands. A daily near-surface water-balance method, the Deep Percolation Model (DPM), was used to simulate water budgets for the period October 1, 1996, through September 30, 1998 (water years 1997-98) for six small drainage basins?three on Lopez Island and one each on San Juan, Orcas, and Shaw Islands. The calibrated soil and subsoil parameters from the DPM for each small basin were then used in island-wide applications of the DPM where the direct runoff component (which is not available on an island-wide basis) was simulated, rather than input, and calibration was not required. A spatial distribution of annual recharge was simulated for each island, with island averages of: Lopez Island, 2.49 inches per year; San Juan Island, 1.99 inches per year; Orcas Island, 1.46 inches per year; and Shaw Island, 1.44 inches per year.A chloride mass-balance method that requires measurements of atmospheric chloride deposition, precipitation, streamflow, and chloride concentrations in ground water was used to estimate recharge to the glacial-deposit aquifers of Lopez Island. Only average recharge could be estimated using this method rather than area-specific recharge. Average recharge for Lopez Island estimated by this method was only 0.63 inch per year. The range of chloride concentrations in ground-water samples from selected wells indicates that the average recharge in areas of glacial deposits is between 0.29 and 1.95 inches per year. Recharge simulated using the DPM for two drainage basins on Lopez Island overlain by glacial deposits are 2.76 and 2.64 inches per year. Sources of chloride in ground water other than from the atmosphere would cause the recharge estimated by the chloride mass-balance method to be less than the actual recharge, therefore these estimates may represent lower limits which are, at least, consistent with the higher simulated recharge from the DPM. The average island-wide recharge is most closely related to the amount of area overlain by glacial deposits. Thus, even though Lopez Island receives the least precipitation, it has the most recharge per square mile because it proportionally has the largest area overlain by glacial deposits. Recharge simulated by the DPM for areas of shallow to outcropping bedrock generally were less than 1.5 inches per year, but recharge simulated in areas of glacial deposits ranged from less than 0.5 to 3 inches per year, with recharge as high as 9 inches per year in some small areas.

Water-Resources Investigations Report↗

Nutrient, trace-element, and ecological history of Musky Bay, Lac Courte Oreilles, Wisconsin, as inferred from sediment cores

Sediment cores were collected from Musky Bay, Lac Courte Oreilles, and from surrounding areas in 1999 and 2001 to determine whether the water quality of Musky Bay has declined during the last 100 years or more as a result of human activity, specifically cottage development and cranberry farming. Selected cores were analyzed for sedimentation rates, nutrients, minor and trace elements, biogenic silica, diatom assemblages, and pollen over the past several decades. Two cranberry bogs constructed along Musky Bay in 1939 and the early 1950s were substantially expanded between 1950?62 and between 1980?98. Cottage development on Musky Bay has occurred at a steady rate since about 1930, although currently housing density on Musky Bay is one-third to one-half the housing density surrounding three other Lac Courte Oreilles bays. Sedimentation rates were reconstructed for a core from Musky Bay by use of three lead radioisotope models and the cesium-137 profile. The historical average mass and linear sedimentation rates for Musky Bay are 0.023 grams per square centimeter per year and 0.84 centimeters per year, respectively, for the period of about 1936?90. There is also limited evidence that sedimentation rates may have increased after the mid-1990s. Historical changes in input of organic carbon, nitrogen, phosphorus, and sulfur to Musky Bay could not be directly identified from concentration profiles of these elements because of the potential for postdepositional migration and recycling. Minor- and trace-element profiles from the Musky Bay core possibly reflect historical changes in the input of clastic material over time, as well as potential changes in atmospheric deposition inputs. The input of clastic material to the bay increased slightly after European settlement and possibly in the 1930s through 1950s. Concentrations of copper in the Musky Bay core increased steadily through the early to mid-1900s until about 1980 and appear to reflect inputs from atmospheric deposition. Aluminum- normalized concentrations of calcium, copper, nickel, and zinc increased in the Musky Bay core in the mid-1990s. However, concentrations of these elements in surficial sediment from Musky Bay were similar to concentrations in other Lac Courte Oreilles bays, nearby lakes, and soils and were below probable effects concentrations for aquatic life. Biogenic-silica, diatom-community, and pollen profiles indicate that Musky Bay has become more eutrophic since about 1940 with the onset of cottage development and cranberry farming. The water quality of the bay has especially degraded during the last 25 years with increased growth of aquatic plants and the onset of a floating algal mat during the last decade. Biogenic silica data indicate that diatom production has consistently increased since the 1930s. Diatom assemblage profiles indicate a shift from low-nutrient species to higher-nutrient species during the 1940s and that aquatic plants reached their present density and/or composition during the 1970s. The diatom Fragilaria capucina (indicative of algal mat) greatly increased during the mid-1990s. Pollen data indicate that milfoil, which often becomes more common with elevated nutrients, became more widespread after 1920. The pollen data also indicate that wild rice was present in the eastern end of Musky Bay during the late 1800s and the early 1900s but disappeared after about 1920, probably because of water-level changes more so than eutrophication.

Wisconsin↗

Measuring and computing natural ground-water recharge at sites in south-central Kansas

To measure the natural groundwater recharge process, two sites in south-central Kansas were instrumented with sensors and data microloggers. The atmospheric-boundary layer and the unsaturated and saturated soil zones were monitored as a single regime. Direct observations also were used to evaluate the measurements. Atmospheric sensors included an anemometer, a tipping-bucket rain gage, an air-temperature thermistor, a relative-humidity probe, a net radiometer, and a barometric-pressure transducer. Sensors in the unsaturated zone consisted of soil-temperature thermocouples, tensiometers coupled with pressure transducers and dial gages, gypsum blocks, and a neutron-moisture probe. The saturated-zone sensors consisted of a water-level pressure transducer, a conventional float gage connected to a variable potentiometer, soil thermocouples, and a number of multiple-depth piezometers. Evaluation of the operation of these sensors and recorders indicates that certain types of equipment, such as pressure transducers, are very sensitive to environmental conditions. A number of suggestions aimed at improving instrumentation of recharge investigations are outlined. Precipitation and evapotranspiration data, taken together with soil moisture profiles and storage changes, water fluxes in the unsaturated zone and hydraulic gradients in the saturated zone at various depths, soil temperature, water table hydrographs, and water level changes in nearby wells, describe the recharge process. Although the two instrumented sites are located in sand-dune environments in area characterized by a shallow water table and a sub-humid continental climate, a significant difference was observed in the estimated total recharge. The estimates ranged from less than 2.5 mm at the Zenith site to approximately 154 mm at the Burrton site from February to June 1983. The principal reasons that the Burrton site had more recharge than the Zenith site were more precipitation, less evapotranspiration, and a shallower depth to the water table. Effective recharge took place only during late winter and spring. No summer or fall recharge was observed at either site during the observation period of this study. (Author 's abstract)

Water-Resources Investigations Report↗

Sediment transport and accretion and the hydrologic environment of Grove Creek near Kenansville, North Carolina

The Grove Creek basin includes an area of about 42 square miles in Duplin County, southeastern North Carolina. This report evaluates sediment transport and sediment-accretion rates in the lowermost 9-mile reach of Grove Creek by using hydrologic, dendrologic, and radioisotopic data collected at seven sites along the study reach. Hydrologic data indicate two discharge frequencies. In the swampiest reaches downstream of site 5, inundation occurs 35 percent of the time; above this site, inundation occurs about 15 percent of the time. For the period from October 1982 through September 1987, overbank flows at site 4 occurred 82 times and lasted a total of 632 days with a maximum duration of 3 months. Distribution of tree species indicates that water-tolerant bald cypress have developed along the lowermost 7 miles of Grove Creek where the flood plain is inundated 35 percent of the time. These swampy conditions have been in existence across limited parts of the flood plain for the last 80 to 150 years. In contrast, the upstream sites have been comparatively dry for the same period. The sediment that is transported in Grove Creek is predominately silt and clay. Measured suspended-sediment concentrations at discharges less than 100 cubic foot per second are less than 15 milligrams per liter; concentrations at higher discharges did not exceed 67 milligrams per liter. Calculated suspended-sediment loads ranged from 75 to 444 tons per year at the various data-collection sites on Grove Creek. Sediment-accretion rates estimated from dendrologic data ranged from 0.03 foot per year to 0.06 foot per year. The highest accretion rates occur in the downstream swampy reaches and are due to channel braiding, low channel gradients and flow velocities, and high frequency and duration percentages of overbank flow, which result in the deposition of clay and silt over wide areas of the flood plain. Sediment-accretion rates along Grove Creek were also estimated by radioisotope methods. Sediment cores from the flood plain showed detectable levels of cesium-137, lead-210, and radium-226. Cesium-137 was not present in the sediment cores below a depth of 10 inches; this indicates a maximum accretion rate of about 0.024 foot per year for the period 1952-87. Lead-210 and radium-226 data from these same sediment cores indicate an average accretion rate of 0.026 foot per year to a depth of about 2 feet. The maximum age of the flood-plain sediment at the 2-foot level is about 80 years. The atmosphere was confirmed as the source of excess lead-210 in flood-plain sediments by nearly matching calculated values of the lead-210 flux at each site with the measured value for atmospheric deposition.

North Carolina↗

Nonpoint and Point Sources of Nitrogen in Major Watersheds of the United States

Estimates of nonpoint and point sources of nitrogen were made for 107 watersheds located in the U.S. Geological Survey's National Water-Quality Assessment Program study units throughout the conterminous United States. The proportions of nitrogen originating from fertilizer, manure, atmospheric deposition, sewage, and industrial sources were found to vary with climate, hydrologic conditions, land use, population, and physiography. Fertilizer sources of nitrogen are proportionally greater in agricultural areas of the West and the Midwest than in other parts of the Nation. Animal manure contributes large proportions of nitrogen in the South and parts of the Northeast. Atmospheric deposition of nitrogen is generally greatest in areas of greatest precipitation, such as the Northeast. Point sources (sewage and industrial) generally are predominant in watersheds near cities, where they may account for large proportions of the nitrogen in streams. The transport of nitrogen in streams increases as amounts of precipitation and runoff increase and is greatest in the Northeastern United States. Because no single nonpoint nitrogen source is dominant everywhere, approaches to control nitrogen must vary throughout the Nation. Watershed-based approaches to understanding nonpoint and point sources of contamination, as used by the National Water-Quality Assessment Program, will aid water-quality and environmental managers to devise methods to reduce nitrogen pollution.

Water-Resources Investigations Report↗