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Atmospheric deposition: Sample handling, storage, and analytical procedures for chemical characterization of event-based samples in North Dakota

The North Dakota atmospheric-deposition network uses HASL-type collectors to sample wet and dry deposition on an event basis for analysis of 8 principal mineral, 3 nutrient, and 15 trace constituents. Comparison of the compositions of wet deposition collected in adjacent collectors sampled on weekly and event bases indicates that weekly sampling leads to significant contamination of wet deposition samples with dry deposition. Elevation of the collectors 10 feet above ground surface may decrease wind-blown soil contamination significantly. This manual presents a summary of the research procedures adopted by the North Dakota District of the U.S. Geological Survey to investigate the consequences of increased fossil-fuel combustion on the quality of atmospheric deposition. The manual has been tested by field operatives for 3 years and shown to be an effective field guide and management tool.

North Dakota↗

Flow and chloride transport in the tidal Hudson River, NY

A one-dimensional dynamic-flow model and a one-dimensional solute-transport model were used to evaluate the effects of hypothetical public-supply water withdrawals on saltwater intrusion in a 133-mile reach of the tidal Hudson River between Green Island dam, near Troy, N.Y., and Hastings-on-Hudson, N.Y. Regression techniques were used in analyses of current and extreme historical conditions, and numerical models were used to investigate the effect of various water withdrawals. Of four withdrawal scenarios investigated, simulations of a 27-day period during which discharges at Green Island dam averaged 7,090 ft3/s indicate that increasing the present Chelsea pumping-station withdrawal rate of 100 Mgal/d (million gallons per day) to 300 Mgal/d would have the least effect on upstream saltwater movement. A 90-day simulation, during which discharges at Green Island dam averaged 25,200 ft3/s, indicates that withdrawals of 1,940 Mgal/d at Chelsea would not measurably increase chloride concentrations at Chelsea under normal tidal and meteorological conditions, but withdrawals of twice that rate (3,880 Mgal/d) could increase the chloride concentration at Chelsea to 250 mg/L.

Conference Paper↗

Geohydrologic data from the Jemez Mountains and vicinity, north-central New Mexico

The Jemez Mountains volcanic region, on the west margin of the Rio Grande rift in north-central New Mexico, is the site of studies for power development from geothermal heat. This report summarizes geohydrologic data to provide background information relative to the geothermal exploration and to investigate the usefulness of hydrology in assessment of the geothermal resource. Eleven tables present chemical, temperature, discharge , and other data for springs, wells, and streams. Accompanying figures show locations of the data points and present temperature profiles and geophysical logs for selected wells. (Woodard-USGS)

Water-Resources Investigations Report↗

Interactions of metallic substances and acidic ground water in the New Jersey Coastal Plan

Four ancillary studies were undertaken in support of an investigation into the extent and distribution of corrosive ground water in the Kirkwood- Cohansey aquifer system of southern New Jersey.The ancillary studies were (1) analysis of tap-water samples for metals and the acquisition of metal data from a county study, (2) leaching experiments in which copper pipe with various types of solder were exposed to a variety of ground-water types, (3) analysis of pipe-scale deposits on plumbing from houses with wells that tap the Kirkwood-Cohansey aquifer system, and (4) measurement of corrosion rates for carbon steel and copper exposed to shallow ground water from the Kirkwood-Cohansey aquifer system. The results studies indicate that substantial concentrations of lead, copper, and zinc can leach from plumbing materials exposed to corrosive water from the Kirkwood-Cohansey aquifer system, and that leaching appears more pronounced during the summer than during the winter. The leaching experiments indicate that the corrosiveness of water, as estimated by the calculation of a corrosion index (the Aggressive Index), is related to the concentration of trace metals in the leachate.Further, although the leaching of lead-bearing solders produced lead concentrations in leachate above the Primary Drinking Water Criterion in effect at the time of the study (50 micrograms per liter), no potentially toxic levels of metals were leached from lead-free solders, although copper concentrations in some leachate samples were in excess of the Secondary Drinking Water Criterion of 1,000 micrograms per liter. Analyses of pipe-scale deposits indicate the formation of iron oxide coatings on some copper-pipe interiors exposed to untreated well water. Treated water from a public-supply system precipitated copper carbonate and copper chloride minerals. Corrosion rates measured for copper exposed to corrosive water from the Kirkwood-Cohansey aquifer system were slow (less than 0.0254 millimeters per year). Carbon-steel corrosion rates were faster; the fastest rate (0.229 millimeters per year) was measured in oxygen-saturated water.

Water-Resources Investigations Report↗

Nonpoint-source pollutant discharges of the three major tributaries to Reelfoot Lake, west Tennessee, October 1987-September 1989

An investigation of the concentration and loads of nitrogen, phosphorus, and suspended sediment in storm runoff to Reelfoot Lake, in western Tennessee, was conducted from October 1987 through September 1989. Concentrations of selected herbicides also were defined. Reelfoot Lake, with a surface area of about 15,500 acres, is the largest natural lake in Tennessee and an important recreation and fisheries resource. Previous studies showed that the lake is hypereutrophic, a condition caused by high concentrations of nutrients in water and sediments discharged from the three principal tributaries (South Reelfoot Creek, North Reelfoot Creek, and Running Slough) to the lake. Pesticides, including herbicides, have been detected in the lake's bottom sediments. Storm runoff contributed about 87percent of the total water discharge of the three main tributaries to Reelfoot Lake. South Reelfoot Creek contributed about 4.7 tons per acre per year of suspended sediment, while North Reelfoot Creek contributed about 1.9 tons per acre per year. Running Slough contributed only about 0.31 ton per acre per year of suspended sediment. Most of the suspended sediment was transported by storm runoff between October and March. About 80 percent of the annual streamflow of the three tributaries occurs during these months. The North Reelfoot Creek basin contributed 8.2 pounds per acre per year of total nitrogen and 2.4 pounds per acre per year of total phosphorus. South Reelfoot Creek basin contributed about 6.5 and 1.3 pounds per acre per year of total nitrogen and phosphorus, respectively, while Running Slough basin contributions were 3.4 and 0.86 pounds per acre per year, respectively. The differences in nutrient yields appear to result from more row-crop agriculture and the relatively steeply sloping agricultural land in the North Reelfoot Creek basin. Ninety-one percent of the total nitrogen load and 95 percent of the total phosphorus load in the three streams was transported by storm runoff. Significant differences in the mean concentrations of nutrients in runoff were defined between the active agricultural months (April through September) and the inactive months (October through March). Storm-runoff samples were analyzed for II selected triazine herbicides. Alachlor and atrazine were the most commonly detected herbicides. Thirty-two percent of the samples contained detectable levels of alachlor and 93 percent of the samples contained detectable levels of atrazine. Ninety percent of the samples collected during the active agricultural months contained detectable leveki of alachlor and all 29 samples contained detectable levels of atrazine. Sixteen samples exceeded lifetime health-advisory levels for atrazine in drinking water (3 micrograms per liter); two samples collected from the April IS, 1988, storm at North Reelfoot Creek and South Reelfoot Creek contained 42 and 57 micrograms per liter of atrazine, respectively. Concentrations of the other nine triazine herbicides were generally less than the level of detection (0.1 microgram per liter).

Tennessee↗

Areal extent, hydrogeologic characteristics, and possible origins of the carbonate rock Newburg Zone (Middle-Upper Silurian) in Ohio

The zone occurs in carbonate rocks of Middle to Late Silurian age across much of Ohio. Known also to well drillers as the "Second Water' in the "Big Lime' carbonate sequence, the Newburg zone is a source of hydrocarbons in northeast Ohio, brines in southeast Ohio, and a widespread source of water over much of west-central Ohio. Close to recharge areas, the quality of the water is comparable to that of the overlying carbonate rocks; thus, the Newburg zone warrants further investigation as a source of water for domestic use. Theories for the porosity and permeabilty of the Newburg zone include: 1) deposition of carbonate or quartz sand along an erosional surface and later lithified to porous and permeable sandstone; 2) dissolution of fossils within Silurian reef complexes; 3) fracture-induced porosity along thrust faults developed during the Alleghenian orogeny; and 4) a combination of these processes. -from Authors

Ohio Journal of Science↗

Impact of warming and suspended terrigenous sediment on the Hawaiian reef coral Montipora capitata

Coral reefs near high human population areas suffer from sedimentation and increased turbidity due to coastal development. However, there is limited research on how key species respond to turbidity caused by terrigenous sediment and how this response may change with increased water temperatures. This study investigated the effects of ambient and elevated turbidity (+ 26 NTU) in combination with ambient (27.1 °C) and elevated temperature (+ 4.1 °C; 31.2 °C) on the dominant Hawaiian reef coral Montipora capitata , collected from two Kāneʻohe Bay watersheds with distinct environmental histories. Using intermittent flow respirometry, we found that acute (12 h) exposure to elevated turbidity and temperature impacted algal symbionts ( Symbiodinium spp. ) but not the coral host, suggesting a potential delayed host physiological response. Corals from south Kāneʻohe Bay, where restricted water circulation and urbanization have degraded water quality, were more sensitive to stressors than those from the less-impacted northern sites, indicating that physiological responses vary by location and may be influenced by watershed conditions. The findings suggest that while short-term turbidity and warming impact Symbiodinium spp. immediately, prolonged exposure may lead to cascading effects on the coral host. Understanding these species-specific and location-dependent responses enhances our ability to guide restoration and conservation efforts for coral ecosystems facing both local (turbidity) and global (warming) stressors.

Hawaii↗

Hydrogeology of the upper Floridan Aquifer in the vicinity of the Marine Corps Logistics Base near Albany, Georgia

In 1995, the U.S. Navy requested that the U.S. Geological Survey conduct an investigation to describe the hydrogeology of the Upper Floridan aquifer in the vicinity of the Marine Corps Logistics Base, southeast and adjacent to Albany, Georgia. The study area encompasses about 90 square miles in the Dougherty Plain District of the Coastal Plain physiographic province, in Dougherty and Worth Counties-the Marine Corps Logistics Base encompasses about 3,600 acres in the central part of the study area. The Upper Floridan aquifer is the shallowest, most widely used source of drinking water for domestic use in the Albany area. The hydrogeologic framework of this aquifer was delineated by description of the geologic and hydrogeologic units that compose the aquifer; evaluation of the lithologic and hydrologic heterogeneity of the aquifer; comparison of the geologic and hydrogeologic setting beneath the base with those of the surrounding area; and determination of ground-water-flow directions, and vertical hydraulic conductivities and gradients in the aquifer. The Upper Floridan aquifer is composed of the Suwannee Limestone and Ocala Limestone and is divided into an upper and lower water-bearing zone. The aquifer is confined below by the Lisbon Formation and is semi-confined above by a low-permeability clay layer in the undifferentiated overburden. The thickness of the aquifer ranges from about 165 feet in the northeastern part of the study area, to about 325 feet in the southeastern part of the study area. Based on slug tests conducted by a U.S. Navy contractor, the upper water-bearing zone has low horizontal hydraulic conductivity (0.0224 to 2.07 feet per day) and a low vertical hydraulic conductivity (0.0000227 to 0.510 feet per day); the lower water-bearing zone has a horizontal hydraulic conductivity that ranges from 0.0134 to 2.95 feet per day. Water-level hydrographs of continuously monitored wells on the Marine Corps Logistics Base show excellent correlation between ground-water level and stage of the Flint River. Ground-water-flow direction in the southwestern part of the base generally is southeast to northwest; whereas, in the northeastern part of the base, flow directions generally are east to west, as well as from west to east, thus creating a ground-water low. Ground-water flow in the larger study area generally is east to west towards the Flint River, with a major ground-water-flow path existing from the Pelham Escarpment to the Flint River and a seasonal cone of depression the size of which is dependent upon the magnitude of irrigation pumping during the summer months. Calculated vertical hydraulic gradients (based upon data from 11 well-cluster sites on the Marine Corps Logistics Base) range from 0.0016 to 0.1770 foot per foot, and generally are highest in the central and eastern parts of the base. The vertical gradient is downward at all well-cluster sites.

Georgia↗

Simulation of ground-water flow and evaluation of water-management alternatives in the Assabet River Basin, Eastern Massachusetts

Water-supply withdrawals and wastewater disposal in the Assabet River Basin in eastern Massachusetts alter the flow and water quality in the basin. Wastewater discharges and stream-flow depletion from ground-water withdrawals adversely affect water quality in the Assabet River, especially during low-flow months (late summer) and in headwater areas. Streamflow depletion also contributes to loss of aquatic habitat in tributaries to the river. In 19972001, water-supply withdrawals averaged 9.9 million gallons per day (Mgal/d). Wastewater discharges to the Assabet River averaged 11 Mgal/d and included about 5.4 Mgal/d that originated from sources outside of the basin. The effects of current (2004) and future withdrawals and discharges on water resources in the basin were investigated in this study. Steady-state and transient ground-water-flow models were developed, by using MODFLOW-2000, to simulate flow in the surficial glacial deposits and underlying crystalline bedrock in the basin. The transient model simulated the average annual cycle at dynamic equilibrium in monthly intervals. The models were calibrated to 19972001 conditions of water withdrawals, wastewater discharges, water levels, and nonstorm streamflow (base flow plus wastewater discharges). Total flow through the simulated hydrologic system averaged 195 Mgal/d annually. Recharge from precipitation and ground-water discharge to streams were the dominant inflow and outflow, respectively. Evapotranspiration of ground water from wetlands and non-wetland areas also were important losses from the hydrologic system. Water-supply withdrawals and infiltration to sewers averaged 5 and 1.3 percent, respectively, of total annual out-flows and were larger components (12 percent in September) of the hydrologic system during low-flow months. Water budgets for individual tributary and main stem subbasins identified areas, such as the Fort Meadow Brook and the Assabet Main Stem Upper subbasins, where flows resulting from anthropo-genic activities were relatively large percentages, compared to other subbasins, (more than 20 percent in September) of total out-flows. Wastewater flows in the Assabet River accounted for 55, 32, and 20 percent of total nonstorm streamflow (base flow plus wastewater discharge) out of the Assabet Main Stem Upper, Middle, and Lower subbasins, respectively, in an average September. The ground-water-flow models were used to evaluate water-management alternatives by simulating hypothetical scenarios of altered withdrawals and discharges. A scenario that included no water management quantified nonstorm stream-flows that would result without withdrawals, discharges, septic-system return flow, or consumptive use. Tributary flows in this scenario increased in most subbasins by 2 to 44 percent relative to 19972001 conditions. The increases resulted mostly from variable combinations of decreased withdrawals and decreased infiltration to sewers. Average annual nonstorm streamflow in the Assabet River decreased slightly in this scenario, by 2 to 3 percent annually, because gains in ground-water discharge were offset by the elimination of wastewater discharges. A second scenario quantified the effects of increasing withdrawals and discharges to currently permitted levels. In this simulation, average annual tributary flows decreased in most subbasins, by less than 1 to 10 percent relative to 19972001 conditions. In the Assabet River, flows increased slightly, 1 to 5 percent annually, and the percentage of wastewater in the river increased to 69, 42, and 27 percent of total nonstorm streamflow out of the Assabet Main Stem Upper, Middle, and Lower subbasins, respectively, in an average September. A third set of scenarios quantified the effects of ground-water discharge of wastewater at four hypothetical sites, while maintaining 19972000 wastewater discharges to the Assabet River. Wastewater, discharged at a constant rate that varied among sites from 0.3 to 1

Scientific Investigations Report↗

Methods and guidelines for effective model calibration; with application to UCODE, a computer code for universal inverse modeling, and MODFLOWP, a computer code for inverse modeling with MODFLOW

This report documents methods and guidelines for model calibration using inverse modeling. The inverse modeling and statistical methods discussed are broadly applicable, but are presented as implemented in the computer programs UCODE, a universal inverse code that can be used with any application model, and MODFLOWP, an inverse code limited to one application model. UCODE and MODFLOWP perform inverse modeling, posed as a parameter-estimation problem, by calculating parameter values that minimize a weighted least-squares objective function using nonlinear regression. Minimization is accomplished using a modified Gauss-Newton method, and prior, or direct, information on estimated parameters can be included in the regression. Inverse modeling in many fields is plagued by problems of instability and nonuniqueness, and obtaining useful results depends on (1) defining a tractable inverse problem using simplifications appropriate to the system under investigation and (2) wise use of statistics generated using calculated sensitivities and the match between observed and simulated values, and associated graphical analyses. Fourteen guidelines presented in this work suggest ways of constructing and calibrating models of complex systems such that the resulting model is as accurate and useful as possible.

Water-Resources Investigations Report↗

Geology, ground-water flow, and dissolved-solids concentrations in ground water along hydrogeologic sections through Wisconsin aquifers

A cooperative project between the U.S. Geological Survey (USGS) and the Wisconsin Department of Natural Resources (DNR) was begun with the objectives of describing water quality and its relation to the hydrology of Wisconsin's principal aquifers and summarizing instances of ground-water contamination and quality problems from information available in DNR files. The first objective was met by a hydrologic investigation done by the USGS, and the second, by preparation of a report by the DNR, for their internal use, that describes the State's water resources and known ground-water quality and contamination problems and makes policy recommendations for ground-water management. The USGS investigation was divided into two phases. The first phase consisted of compiling available water-quality and hydrogeologic data and collecting new data to describe general regional water-quality and hydrogeologic relations within and between Wisconsin aquifers. The second phase began concurrently with the later part of the first phase and consisted of an areal description of water quality and flow in the State's shallow aquifer system (Kammerer, 1995). The overall purpose of this investigation was to provide a regional framework that could serve as a basis for intensive local and site specific ground-water investigations by State and local government agencies. This report presents the results of the first phase of the USGS investigation. Regional hydrogeologic and water-quality relations within and between aquifers are shown along 15 hydrogeologic sections that traverse the State. Maps are used to show surficial geology of bedrock and unconsolidated deposits and horizontal direction of ground-water flow. Interpretations on the maps and hydrogeologic sections are based on data from a variety of sources and provide the basis for the areal appraisal of water quality in the State's shallow aquifer system in the second phase of the investigation.

Wisconsin↗

Probability of detecting perchlorate under natural conditions in deep groundwater in California and the Southwestern United States

We use data from 1626 groundwater samples collected in California, primarily from public drinking water supply wells, to investigate the distribution of perchlorate in deep groundwater under natural conditions. The wells were sampled for the California Groundwater Ambient Monitoring and Assessment Priority Basin Project. We develop a logistic regression model for predicting probabilities of detecting perchlorate at concentrations greater than multiple threshold concentrations as a function of climate (represented by an aridity index) and potential anthropogenic contributions of perchlorate (quantified as an anthropogenic score, AS). AS is a composite categorical variable including terms for nitrate, pesticides, and volatile organic compounds. Incorporating water-quality parameters in AS permits identification of perturbation of natural occurrence patterns by flushing of natural perchlorate salts from unsaturated zones by irrigation recharge as well as addition of perchlorate from industrial and agricultural sources. The data and model results indicate low concentrations (0.1-0.5 &mu;g/L) of perchlorate occur under natural conditions in groundwater across a wide range of climates, beyond the arid to semiarid climates in which they mostly have been previously reported. The probability of detecting perchlorate at concentrations greater than 0.1 &mu;g/L under natural conditions ranges from 50-70% in semiarid to arid regions of California and the Southwestern United States to 5-15% in the wettest regions sampled (the Northern California coast). The probability of concentrations above 1 &mu;g/L under natural conditions is low (generally <3%).

California↗

Geology, hydrology, and water quality in the vicinity of a Brownfield redevelopment site in East Moline, Illinois

An investigation of the geology, hydrology, and water quality in the vicinity of a Brownfield redevelopment site in East Moline, Illinois, was designed to determine if metals and organic compounds detected in the fill deposits in this area posed a threat to the water resources. The hydrologic features of concern at the site are surface water at a pond and surrounding wetland, the Mississippi River, and an unnamed stream and ground water in the shallow aquifer. The shallow aquifer is composed of saturated fill, sand and gravel, and weathered bedrock. The overall direction of surface- and ground-water flow in the study area is toward the Mississippi River. In the eastern part of the pond and wetland, ground water discharges to surface water. In the western part of the pond and wetland, surface water recharges to ground water. Everyday during the period for which water-level data were available, between 4.7 ' 10-4 and 1.4 ' 10-1 cubic feet of water flowed across a 1 square foot area of aquifer. Variations in values for oxidation-reduction potential and specific conductance may be affected by heterogeneity in the chemical composition of the fill and unconsolidated deposits and the bedrock units. Chemical and biological processes are altering the chemistry of the water in the pond relative to its ground-water source. Concentrations of iron and manganese in water samples appear to be affected by the local geochemical environment in the aquifer. The data do not indicate that contaminants in the fill material are having a substantial adverse affect on surface- or ground-water quality in the study area.

Illinois↗

Assessment of ground-water withdrawals at municipal industrial parks in Puerto Rico, 2000

An assessment of ground-water withdrawals at municipal industrial parks throughout Puerto Rico was conducted to investigate the effect of ground-water usage on nearby surface- and ground-water resources. Water-bearing strata were divided into four generalized hydrogeologic units: (1) fissured aquifers (including karst and non-karst limestone); (2) intergranular aquifers; (3) intergranular aquifers overlying fissured rock units; and (4) strata with local or limited ground-water resources. Approximately 49 percent of the municipal industrial parks are located in areas with local or limited ground-water resources, 29 percent overlie intergranular aquifers, 13 percent overlie fissured aquifers, and 9 percent overlie intergranular units that overlie fissured rock units. Hydrogeologic data for the generalized hydrogeologic units were compiled from published U.S. Geological Survey reports. Depths to ground water near industrial parks range from approximately 20 to 400 feet in the fissured aquifers, 6 to 65 feet in coastal intergranular aquifers, 3 to 30 feet in intergranular aquifers overlying fissured rock units, and 1 to 100 feet in strata with local or limited ground-water resources. Aquifer transmissivities near industrial parks range from approximately 100,000 feet squared per day in the fissured aquifers to less than 100 feet squared per day in the strata with local or limited ground-water resources. Well construction data were compiled from published U.S. Geological Survey reports, drillers? logs, and unpublished reports. Specific capacity for wells near industrial parks ranges from approximately 100 gallons per minute per foot of drawdown in the fissured aquifer at Manati to approximately 0.1 gallon per minute per foot of drawdown in strata with local and limited ground-water resources at Bayamon. Reported well yields near industrial parks ranges from 2,800 gallons per minute in the intergranular aquifer at Santa Isabel to approximately 3 gallons per minute in strata with local and limited ground-water resources at Adjuntas. Historical ground-water-level data from U.S. Geological Survey observation wells were used to define ground-water levels trends in the vicinity of industrial parks. Areas showing ground-water level declines, and therefore possible aquifer over-development, are located in Barceloneta and Guayama. Rising ground-water levels were noted in the vicinity of industrial parks at Florida, Ponce, and Yauco. Ground-water withdrawal data were compiled from site visits to the industrial facilities and from information provided by Puerto Rico Department of Natural and Environmental Resources. Total ground-water withdrawal at the municipal industrial parks was estimated to be 1.6 million gallons per day. Most withdrawals were from intergranular coastal aquifers, which accounted for about two thirds of the ground-water withdrawals. Municipal industrial parks with substantial ground-water withdrawals are located in Bayamon, Caguas, Humacao, and Ponce.

Scientific Investigations Report↗

Hydrologic and Hydraulic Analyses of Selected Streams in Lorain County, Ohio, 2003

Hydrologic and hydraulic analyses were done for selected reaches of nine streams in Lorain County Ohio. To assess the alternatives for flood-damage mitigation, the Lorain County Engineer and the U.S. Geological Survey (USGS) initiated a cooperative study to investigate aspects of the hydrology and hydraulics of the nine streams. Historical streamflow data and regional regression equations were used to estimate instantaneous peak discharges for floods having recurrence intervals of 2, 5, 10, 25, 50, and 100 years. Explanatory variables used in the regression equations were drainage area, main-channel slope, and storage area. Drainage areas of the nine stream reaches studied ranged from 1.80 to 19.3 square miles. The step-backwater model HEC-RAS was used to determine water-surface-elevation profiles for the 10-year-recurrence-interval (10-year) flood along a selected reach of each stream. The water-surface pro-file information was used then to generate digital mapping of flood-plain boundaries. The analyses indicate that at the 10-year flood elevation, road overflow results at numerous hydraulic structures along the nine streams.

Water-Resources Investigations Report↗

Mesocosm experiments to assess factors affecting phosphorus retention and release in an extended Wisconsin wetland

Phosphorus retention by wetland sediments and vegetation was investigated in Jackson Creek wetland, an extension of an existing prairie marsh in southeastern Wisconsin. The extended wetland construction was undertaken in 1992-93 to help reduce the phosphorus loading to a downstream eutrophic lake. Two approaches were used to study potential and actual phosphorus retention in the system. Mesocosm experiments of 20-40 days duration indicated that retention of total and dissolved reactive phosphorus in mesocosm cells containing macrophytes and/or sediments was reduced by factors of 2-20 relative to cells containing only water or a copper algicide to suppress metabolic activity. In contrast to the nutrient trapping function, these results show a potential for net phosphorus release that can be associated with increased biological richness. Measurements of water flow and nutrient loads at the wetland's inflow and outflow points demonstrated 9-39% net uptake of phosphorus on an annual scale but frequent occurrences of net phosphorus release over shorter (one-month) time scales. These episodes of release are most likely during the summer months. Thus, the wetland role in phosphorus cycling is not one of a true source or sink, although the annual budget data alone suggest substantial net retention. Effective management of the wetland for its nutrient trapping potential can be hindered by this oversimplification. The system is instead subject to relatively short-term alternation between net import and export. The periodic phosphorus export, although representing a small fraction of net annual import, could be critical for growth of macrophyte and algal communities downstream.

Wisconsin↗

Application of digital profile modeling techniques to ground-water solute transport at Barstow, California

This study investigated the use of a two-dimensional profile-oriented water-quality model for the simulation of head and water-quality changes through the saturated thickness of an aquifer. The profile model is able to simulate confined or unconfined aquifers with nonhomogeneous anisotropic hydraulic conductivity, nonhomogeneous specific storage and porosity, and nonuniform saturated thickness. An aquifer may be simulated under either steady or nonsteady flow conditions provided that the ground-water flow path along which the longitudinal axis of the model is oriented does not move in the aquifer during the simulation time period. The profile model parameters are more difficult to quantify than are the corresponding parameters for an areal-oriented water-fluality model. However, the sensitivity of the profile model to the parameters may be such that the normal error of parameter estimation will not preclude obtaining acceptable model results. Although the profile model has the advantage of being able to simulate vertical flow and water-quality changes in a single- or multiple-aquifer system, the types of problems to which it can be applied is limited by the requirements that (1) the ground-water flow path remain oriented along the longitudinal axis of the model and (2) any subsequent hydrologic factors to be evaluated using the model must be located along the land-surface trace of the model. Simulation of hypothetical ground-water management practices indicates that the profile model is applicable to problem-oriented studies and can provide quantitative results applicable to a variety of management practices. In particular, simulations of the movement and dissolved-solids concentration of a zone of degraded ground-water quality near Barstow, Calif., indicate that halting subsurface disposal of treated sewage effluent in conjunction with pumping a line of fully penetrating wells would be an effective means of controlling the movement of degraded ground water.

Water Supply Paper↗

Lakes Marion-Moultrie stream system investigation, South Carolina : Part II-Simulation Studies

A stream-reservoir model was developed to simulate the operation of the Lakes Marion-Moultrie, South Carolina, reservoir system. The reservoir system is operated under the assumption of a 3-day prior knowledge of inflows. This information is attainable from the ooperational reservoir-inflow forecasting model developed in the Part I report. The model, developed for this part of the study, incorporates an inflow component, a diversion-canal component, and a reservoir system component and is capable of evaluating the performance of the reservoir systemem for a variety of operating rule conditions. All model components were verified using observed reservoir input and output data for a 6-year (1967-72 water years) period. In addition, a long-term 31-year simulation under present rule of operation was performed and the results summarized statistically. The model may be used for simulating other rule curves of operation for planning studies of reservoir system performance. (See also W75-05646) (Woodard-USGS)

South Carolina↗