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USGS2013

Sequential Gaussian co-simulation of rate decline parameters of longwall gob gas ventholes

Gob gas ventholes (GGVs) are used to control methane inflows into a longwall mining operation by capturing the gas within the overlying fractured strata before it enters the work environment. Using geostatistical co-simulation techniques, this paper maps the parameters of their rate decline behaviors across the study area, a longwall mine in the Northern Appalachian basin. Geostatistical gas-in-place (GIP) simulations were performed, using data from 64 exploration boreholes, and GIP data were mapped within the fractured zone of the study area. In addition, methane flowrates monitored from 10 GGVs were analyzed using decline curve analyses (DCA) techniques to determine parameters of decline rates. Surface elevation showed the most influence on methane production from GGVs and thus was used to investigate its relation with DCA parameters using correlation techniques on normal-scored data. Geostatistical analysis was pursued using sequential Gaussian co-simulation with surface elevation as the secondary variable and with DCA parameters as the primary variables. The primary DCA variables were effective percentage decline rate, rate at production start, rate at the beginning of forecast period, and production end duration. Co-simulation results were presented to visualize decline parameters at an area-wide scale. Wells located at lower elevations, i.e., at the bottom of valleys, tend to perform better in terms of their rate declines compared to those at higher elevations. These results were used to calculate drainage radii of GGVs using GIP realizations. The calculated drainage radii are close to ones predicted by pressure transient tests.

Pennsylvania↗

USGS1941

Geologic structure and occurrence of gas in part of southwestern New York

The area covered by this report is in southwestern New York and includes a little more than 3,000 square miles in Steuben and Yates counties and parts of the six adjacent counties. This area has been mapped to determine the structural attitude of the exposed rocks, so as to aid those interested in prospecting for natural gas in the Oriskany sandstone of Lower Devonian age. Because of the gentle regional dip toward the southwest, the youngest beds are exposed in the southwest corner of the area, and progressively older beds crop out northeastward in successive bands that strike generally northwest. All the exposed rocks are of Upper Devonian age except those in a narrow belt at the extreme north edge of the area, where a small thickness of Middle Devonian rocks crops out. The maximum thickness of beds so exposed is nearly 4,000 feet, of which the lower part is predominantly soft dark shale and the upper part predominantly fine-grained sandstone and gray shale. All the beds are marine except a few tongues of continental deposits—red shale and sandstone and gray mudstone—in the youngest beds. All the beds thicken southeastward, so that there is a northwestward convergence between any two lithologic units in the series. More than 30 key horizons that are persistent and distinctive were mapped, and altitudes on these key horizons served as a basis for constructing the structure contour map. Many of the key horizons are formation or member boundaries, but others are the tops or bottoms of limestone or sandstone beds within formations. All the stratigraphic units mapped are purely lithologic. (See pl. 2.) The Tully limestone, which crops out along the northern border of the area, is an easily recognizable and therefore valuable key bed for subsurface correlations in this part of the State. Below the Tully limestone is a thick body of Middle Devonian shales of the Hamilton group which rests on another valuable key bed, the hard, cherty Onondaga limestone, also of Middle Devonian age. Below the Onondaga limestone is the Lower Devonian Oriskany sandstone, which is the gas-producing bed. Unlike the Onondaga, the Oriskany is locally thin or absent. The structure of most of the area is shown by contour lines at 25-foot intervals, but, where key horizons are lacking the structure is indicated by dip symbols. Upon the regional south and southwest dip are superposed numerous gentle folds whose axes trend approximately northeastward in the greater part of the area but more nearly eastward in the eastern part. The folds generally tend to become narrower and steeper, and therefore more closely spaced, southwestward. Many of the anticlines fork southwestward, whereas the synclines tend to fork northeastward. All the folds have a westward or southwestward plunge. Throughout the area the rocks are jointed in two dominant sets—one that trends northwest and the other east or northeast. No evident relation between these joints, which were measured only in the hard, relatively brittle beds, and the individual folds or domes was discernible. The faults are concentrated in the northeastern and southwestern parts of the area and trend either northeastward or northwestward. Some are nearly vertical normal faults ; others are steep reverse faults. Subsurface data show that most of the faults increase in throw downward and also that many subsurface faults do not reach the surface. A group of faults in the northwestern part of the Greenwood quadrangle and the southwestern part of the Hornell quadrangle were active during Upper Devonian time, while the Gowanda shale and overlying beds were being deposited. At this stratigraphic horizon the beds in a zone a few hundred feet thick are highly deformed in a wide belt on both sides of the faults. Sandstone layers are thinned out into long stringers or swollen into thick masses and in places are bent acutely without fracture. Thin layers of shale, coquina, and sand have flowed together into intricately plicated zones that lack cleavage and joints. These features show that the sediments were deformed while wet and plastic and buried only a little way below the sea floor. The beds that were laid down over these disturbed zones were not involved in this deformation. Many of the sharper flexures and most of the faults are not evident in the beds several hundred feet stratigraphically higher. Accordingly, broad, gentle folds in these higher beds in parts of the area south and west of the northwest corner of the Greenwood quadrangle may conceal, at considerable depths below them, narrow folds separated by abrupt flexures or faults. Several of the larger streams and rivers occupy strike valleys, and their courses swing to follow the changing strike of the rocks where they cross successive folds. But, with few exceptions, the small streams are not adjusted to the bedrock structure. Domes likely to serve as traps for natural gas are concentrated in the northeastern and southwestern parts of the area. The Wayne-Dundee gas field is in the northeastern part. All the other potentially valuable domes in this part of the area have been drilled and found valueless except one small structural feature in the southern part of the Ovid quadrangle, which, if the Oriskany is present, may trap a small quantity of gas. In the Greenwood quadrangle in the southwestern part of the area there is one gas field and four well-defined domes, all of which may be productive if the Oriskany sandstone is present. In the northwest corner of the quadrangle the dips indicate at least two domes that can be adequately defined and evaluated only by geophysical prospecting. The State Line gas field is in the Wellsville quadrangle. In the southeast corner of this quadrangle there are three other domes of comparable size that may also be productive if underlain by the Oriskany sandstone. At other places in the Wellsville quadrangle the dips suggest several anticlinal axes on which analogous productive domes may be found. The structural features in this quadrangle, however, are defined by contours only in the southeastern part. In the Woodhull quadrangle a large dome east of Jasper may be productive, and the western top of the large Wood-hull dome in the southwestern part of the quadrangle seems to warrant drilling, despite the absence of the Oriskany in a well on the eastern top. Two wells drilled in 1936 and 1937 a little northeast of a broad, nearly flat-topped dome in the Hornell quadrangle, a few miles east of Hornell, struck small flows of gas, suggesting that wells drilled higher on this dome may be productive. In much of the southwestern part of the area seismograph surveys should be of great value in determining the structure at the Tully and Onondaga horizons. Without abundant subsurface control of this sort, the danger of drilling into subsurface faults can hardly be overemphasized. Three closed or nearly closed synclines in the Greenwood and Wellsville quadrangles appear to be favorable places to drill for oil in the shallow sands— presumably parts of the Dunkirk sandstone.

New York↗

USGS1941

Geologic structure and occurrence of gas in part of southwestern New York. Part 1, Structure and gas possibilities of the Oriskany sandstone in Steuben, Yates, and parts of the adjacent counties

The area covered by this report is in southwestern New York and includes a little more than 3,000 square miles in Steuben and Yates counties and parts of the six adjacent counties. This area has been mapped to determine the structural attitude of the exposed rocks, so as to aid those interested in prospecting for natural gas in the Oriskany sandstone of Lower Devonian age. Because of the gentle regional dip toward the southwest, the youngest beds are exposed in the southwest corner of the area, and progressively older beds crop out northeastward in successive bands that strike generally northwest. All the exposed rocks are of Upper Devonian age except those in a narrow belt at the extreme north edge of the area, where a small thickness of Middle Devonian rocks crops out. The maximum thickness of beds so exposed is nearly 4,000 feet, of which the lower part is predominantly soft dark shale and the upper part predominantly fine-grained sandstone and gray shale. All the beds are marine except a few tongues of continental deposits red shale and sandstone and gray mudstone in the youngest beds. All the beds thicken southeastward, so that there is a northwestward convergence between any two lithologic units in the series. More than 30 key horizons that are persistent and distinctive were mapped, and altitudes on these key horizons served as a basis for constructing the structure contour map. Many of the key horizons are formation or member boundaries, but others are the tops or bottoms of limestone or sandstone beds within formations. All the stratigraphic units mapped are purely lithologic. (See pi. 2.) The Tully limestone, which crops out along the northern border of the area, is an easily recognizable and therefore valuable key bed for subsurface correlations in this part of the State. Below the Tully limestone is a thick body of Middle Devonian shales of the Hamilton group which rests on another valuable key bed, the hard, cherty Onondaga limestone, also of Middle Devonian age. Below the Onondaga limestone is the Lower Devonian Oriskany sandstone, which is the gas-producing bed. Unlike the Onondaga, the Oriskany is locally thin or absent. The structure of most of the area is shown by contour lines at 25-foot intervals, but where key horizons are lacking the structure is indicated by dip symbols. Upon the regional south and southwest dip are superposed numerous gentle folds whose axes trend approximately northeastward in the greater part of the area but more nearly eastward in the eastern part. The folds generally tend to become narrower and steeper, and therefore more closely spaced, southwestward. Many of the anticlines fork southwestward, whereas the synclines. tend to fork northeastward. All the folds have a westward or southwestward plunge. Throughout the area the rocks are jointed in two dominant sets one that trends northwest and the other east or northeast. No evident relation .between these joints, which were measured only in the hard, relatively brittle beds, and the individual folds or domes was discernible. The faults are concentrated in the northeastern and southwestern parts of the area and trend either northeastward or northwestward. Some are nearly vertical normal faults; others are steep reverse faults. Subsurface data show that most of the faults increase in throw downward and also that many subsurface faults do not reach the surface. A group of faults in the northwestern part of the Greenwood quadrangle and the southwestern part of the Hornell quadrangle were active during Upper Devonian time, while the Gowanda shale and overlying beds were being deposited. At this stratigraphic horizon the beds in a zone a few hundred feet thick are highly deformed in a wide belt on both sides of the faults. Sandstone layers are thinned out into long stringers or swollen into thick masses and in places are bent acutely without fracture. Thin layers of shale, coquina, and sand have flowed together into intricately plicated zones that lack cleavage and joints. These features show that the sediments were deformed while wet and plastic and buried only a little way below the sea floor. The beds that were laid down over these disturbed zones were not involved in this deformation. Many of the sharper flexures and most of the faults are not evident in the beds several hundred feet stratigraphically higher. Accordingly, broad, gentle folds in these higher beds in parts of the area south and west of the northwest corner of the Greenwood quadrangle may conceal, at considerable depths below them, narrow folds separated by abrupt flexures or faults. Several of the larger streams and rivers occupy strike valleys, and their j courses swing to follow the changing strike of the rocks where they cross ( successive folds. But, with few exceptions, the small streams are not adjusted to the bedrock structure. Domes likely to serve as traps for natural gas are concentrated in the northeastern and southwestern parts of the area. The Wayne-Dundee gas field is in the northeastern part. All the other potentially valuable domes in this part of the area have been drilled and found valueless except one small structural feature in the southern part of the Ovid quadrangle, which, if the Oriskany is present, may trap a small quantity of gas. In the Greenwood quadrangle in the southwestern part of the area there is one gas field and four well-defined domes, all of which may be productive if the Oriskany sandstone is present. In the northwest corner of the quadrangle the dips indicate at least two domes that can be adequately defined and evaluated only by geophysical prospecting. The State Line gas field is in tbe Wellsville quadrangle. In the southeast corner of this quadrangle there are three other domes of comparable size that may also be productive if underlain by the Oriskany sandstone. At other places in the Wellsville quadrangle the dips suggest several anticlinal axes on which analogous productive domes maybe found. The structural features in this quadrangle, however, are defined by contours only in the southeastern part. In the Woodhull quadrangle a large dome east of Jasper may be productive, and the western top of the large Woodhull dome in the southwestern part of the quadrangle seems to warrant drilling, despite the absence of the Oriskany in a well on the eastern top. Two wells drilled in 1936 and 1937 a little northeast of a broad, nearly flat-topped dome in the Hornell quadrangle, a few miles east of Hornell,, struck small flows of gas, suggesting that wells drilled higher on this dome may be productive. In much of the southwestern part of the area seismograph surveys should be of great value in determining the structure at the Tully and Onondaga horizons. Without abundant subsurface control of this sort, the danger of drilling into subsurface faults can hardly be overemphasized. Three closed or nearly closed synclines in the Greenwood and Wellsville quadrangles appear to be favorable places to drill for oil in the shallow sands presumably parts of the Dunkirk sandstone.

New York↗

USGS2011

Mg-spinel lithology: A new rock type on the lunar farside

High-resolution compositional data from Moon Mineralogy Mapper (M 3) for the Moscoviense region on the lunar farside reveal three unusual, but distinctive, rock types along the inner basin ring. These are designated "OOS" since they are dominated by high concentrations of orthopyroxene, olivine, and Mg-rich spinel, respectively. The OOS occur as small areas, each a few kilometers in size, that are widely separated within the highly feldspathic setting of the basin rim. Although the abundance of plagioclase is not well constrained within the OOS, the mafic mineral content is exceptionally high, and two of the rock types could approach pyroxenite and harzburgite in composition. The third is a new rock type identified on the Moon that is dominated by Mg-rich spinel with no other mafic minerals detectable (<5% pyroxene, olivine). All OOS surfaces are old and undisturbed since basin formation. They are effectively invisible in image data and are only recognized by their distinctive composition identified spectroscopically. The origin of these unusual lithologies appears to be linked to one or more magmatic intrusions into the lower crust, perhaps near the crust-mantle interface. Processes such as fractional crystallization and gravity settling within such intrusions may provide a mechanism for concentrating the mafic components within zones several kilometers in dimension. The OOS are embedded within highly anorthositic material from the lunar crust; they may thus be near contemporaneous with crustal products from the cooling magma ocean. Copyright ?? 2011 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

USGS1990

Chapter 22: Changing patterns of extensional tectonics; Overprinting of the basin of the middle and upper Miocene Esmeralda Formation in western Nevada by younger structural basins

The middle and upper Miocene Esmeralda Formation of western Nevada was deposited in a continental basin that crops out over an area of about 2,000 km 2 . The formation consists of thin, westerly derived sedimentary rocks in the western three-quarters of the outcrop area and of thick (3+ km) easterly derived sedimentary rocks in the eastern quarter. Megabreccias along the eastern margin of the basin are interpreted as landslide deposits derived from fault scarps. The basin was probably a half-graben with a major fault or faults on the east side. The position of the basin, its size, and the inferred major syndepositional faults on its east side are all unrelated to present-day topography and the distribution of major faults in the area and indicate a change in paleogeography and structural pattern since the late Miocene. In the eastern part of the basin, this change was accompanied by deformation that includes low-angle-fault detachment of the Esmeralda Formation from underlying amphibolite-grade Late Proterozoic and lower Paleozoic rocks in the Mineral Ridge-Weepah Hills area and uplift, folding, faulting, tilting, and surface exposure of the entire 3+ km thickness of the formation. Middle and upper Miocene basins in the northern part of the Basin and Range province commonly have been attributed to the onset of basin-range tectonism. The tectonic history of the Esmeralda Formation, however, indicates that some of these basins do not occupy the same area, nor are they related to the same syndepositional faults, as present basins. The extensional basin of the Esmeralda Formation can be viewed either as an early structure in an evolving, but kinematically related, extensional terrane in which the distribution of basins and faults changed gradually with time, or as the product of an extensional event kinematically different from that which produced present structures in the same area. The latter hypothesis is favored because of the marked contrasts in the paleogeography and structures associated with the Esmeralda basin compared with modern basins.

Nevada↗

USGS2006

Explosive eruptive record in the Katmai region, Alaska Peninsula: An overview

At least 15 explosive eruptions from the Katmai cluster of volcanoes and another nine from other volcanoes on the Alaska Peninsula are preserved as tephra layers in syn- and post-glacial (Last Glacial Maximum) loess and soil sections in Katmai National Park, AK. About 400 tephra samples from 150 measured sections have been collected between Kaguyak volcano and Mount Martin and from Shelikof Strait to Bristol Bay (∼8,500 km 2 ). Five tephra layers are distinctive and widespread enough to be used as marker horizons in the Valley of Ten Thousand Smokes area, and 140 radiocarbon dates on enclosing soils have established a time framework for entire soil–tephra sections to 10 ka; the white rhyolitic ash from the 1912 plinian eruption of Novarupta caps almost all sections. Stratigraphy, distribution and tephra characteristics have been combined with microprobe analyses of glass and Fe–Ti oxide minerals to correlate ash layers with their source vents. Microprobe analyses (typically 20–50 analyses per glass or oxide sample) commonly show oxide compositions to be more definitive than glass in distinguishing one tephra from another; oxides from the Kaguyak caldera-forming event are so compositionally coherent that they have been used as internal standards throughout this study. Other than the Novarupta and Trident eruptions of the last century, the youngest locally derived tephra is associated with emplacement of the Snowy Mountain summit dome (<250 14 C years B.P.). East Mageik has erupted most frequently during Holocene time with seven explosive events (9,400 to 2,400 14 C years B.P.) preserved as tephra layers. Mount Martin erupted entirely during the Holocene, with lava coulees (>6 ka), two tephras (∼3,700 and ∼2,700 14 C years B.P.), and a summit scoria cone with a crater still steaming today. Mount Katmai has three times produced very large explosive plinian to sub-plinian events (in 1912; 12–16 ka; and 23 ka) and many smaller pyroclastic deposits show that explosive activity has long been common there. Mount Griggs, fumarolically active and moderately productive during postglacial time (mostly andesitic lavas), has three nested summit craters, two of which are on top of a Holocene central cone. Only one ash has been found that is (tentatively) correlated with the most recent eruptive activity on Griggs (<3,460 14 C years B.P.). Eruptions from other volcanoes NE and SW beyond the Katmai cluster represented in this area include: (1) coignimbrite ash from Kaguyak’s caldera-forming event (5,800 14 C years B.P.); (2) the climactic event from Fisher caldera (∼9,100 14 C years B.P.—tentatively correlated); (3) at least three eruptions most likely from Mount Peulik (∼700, ∼7,700 and ∼8,500 14 C years B.P.); and (4) a phreatic fallout most likely from the Gas Rocks (∼2,300 14 C years B.P.). Most of the radiocarbon dating has been done on loess, soil and peat enclosing this tephra. Ash correlations supported by stratigraphy and microprobe data are combined with radiocarbon dating to show that variably organics-bearing substrates can provide reliable limiting ages for ash layers, especially when data for several sites is available.

Alaska↗

USGS1989

The Relief Canyon gold deposit, Nevada: A mineralized solution breccia

The Relief Canyon gold deposit in the Humboldt Range of western Nevada is a low-grade, high-tonnage orebody of Tertiary or younger age. The host rocks include limestones of the Triassic Cane Spring Formation, which are overlain by shales of the Triassic Grass Valley Formation. The rocks were folded and metamorphosed to greenschist grade during Jurassic and Cretaceous regional tectonic activity. Mesozoic thrusting may have occurred along the shale-limestone contact, but evidence has been obscured by later hydrothermal activity. The sedimentary rocks were nominally offset along several Late Tertiary normal faults related to uplift of the range.The upper part of the Cane Spring Formation is composed of a poorly sorted breccia composed of limestone clasts with a clay matrix. Irregular pockets within this zone are filled with clay- to pebble-sized fragments derived from the Grass Valley shale. The enclosing limestone beds were tilted moderately to the southwest during Mesozoic deformation, whereas bedding within these pockets is generally horizontal, indicating post-tilting deposition of the sediments. The sediments show graded bedding and other sedimentary features that indicate deposition from flowing water. Thermally mature carbon derived from the limestone is also concentrated in small pockets in the matrix. The breccia unit is likely the product of low-temperature solution brecciation. Ground water dissolved much of the limestone directly beneath the shales, progressively creating irregular cavities and the breccia. Sediments derived from the overlying Grass Valley shale were fiuvially deposited as a matrix to the developing solution breccia.Episodic pulses of hydrothermal fluids were introduced along faults and possibly mixed with the ground water in the breccia zone. Initially, jasperoids formed along the faults, but later hydrothermal pulses introduced gold, silica, and fluorine into both the early jasperoids and the unconsolidated cave-fill sediments to form the orebody. Continued solution-related brecciation chaotically disrupted the gold deposit.Gold, fluorite, pyrite, silver, calcite, and fine-grained silica are the principal hydrothermal minerals in the deposit. Gold was deposited as micron-sized flakes of native gold and rarely as electrum during a relatively late stage of silicification of the jasperoids, the carbon-rich zones, and the clay-rich matrix of the breccia. Fluorite was deposited with and later than the gold in the jasperoids, and it in part replaced the clay-rich breccia matrix. Antimony, arsenic, mercury, and thallium are directly associated with gold in the orebody.The deposit formed at a relatively shallow depth. On the basis of fluid inclusion data, late-stage hydrothermal fluids related to gold and fluorite deposition were extremely dilute and had temperatures near 200 degrees C. The fluid inclusions in fluorite show no evidence for boiling, but porous crackle breccias in the jasperoids suggest that hydrobrecciation took place.

Economic Geology↗

USGS2019

Rare earth element mineral deposits in the United States

Because of their unique special chemical properties, many of the metals in the group of rare earth elements (REEs) have essential applications in 21st century technologies. Examples of products that use REEs are cell phones, computers, fluorescent and light-emitting-diode lights, flat-screen television and computer monitors, and in high-strength magnets used by clean energy technologies such as the generators of wind turbines and batteries of hybrid and electric vehicles. REEs are used in many defense applications, such as in components of jet engines, missile guidance systems, antimissile defense systems, satellites, and communication systems. The rare earth elements have become vital to manufacturing numerous high-tech products, which has been accompanied by a large increase in their demand. At the same time, there has been concern by the United States and many other Nations about the near-monopoly of mining, processing, and supply of REEs from one Nation, China. Between 2011 and 2017, China produced approximately 84 percent of the world’s REEs, and during this time the United States only produced REEs between 2012 and 2015. The U.S. production came entirely from the Mountain Pass mine in California, providing only about 4 percent of the world REE supply. Because REEs are essential for technological applications and are primarily supplied by one Nation, there has been an increased concern in identifying new sources of REEs, including economic REE deposits. In response to these concerns, since 2009, the U.S. Geological Survey (USGS) has conducted numerous studies focused on the distribution, geology, and potential resources for the REE-bearing mineral deposits in the United States. The basic characteristics of mineral deposit types that host REE enrichments in the United Sates are summarized in this report, with selected examples. Several types of REE-enriched mineral deposits are reviewed, including deposits in carbonatites, alkaline igneous rocks, sedimentary phosphate-rich rocks (phosphorite), regions containing REE-rich veins, iron oxide deposits containing REE-bearing apatite, monazite-xenotime-bearing placer deposits (heavy-mineral sands), and ion-adsorption clay deposits (REE in granite-derived regolith). A better understanding of these mineral deposits will assist in identifying domestic resources to help alleviate the dependence on imported REEs. The economic development of REE mineral deposits is affected by many factors beyond mining, such as commodity prices and mineral processing costs. Most of the REEs are hosted by minerals that have complex chemical formulas; this presents more challenges to process and extract the REEs. Continued advancements and refinements in mineral processing techniques may allow REE deposits with complex mineralogy to be economically developed in the future.

Circular↗

USGS2008

Radionuclide Data and Calculations and Loss-On-Ignition, X-Ray Fluorescence, and ICP-AES Data from Cores in Catchments of the Animas River, Colorado

The U.S. Departments of Agriculture and Interior Abandoned Mine Lands (AML) Initiative is focused on the evaluation of the effect of past mining practices on the water quality and the riparian and aquatic habitats of impacted stream reaches downstream from historical mining districts located primarily on Federal lands. This problem is manifest in the eleven western states (west of longitude 102 degrees) where the majority of hardrock mines that had past production are located on Federal lands. In areas of temperate climate and moderate to heavy precipitation, the effects of rapid chemical and physical weathering of sulfides exposed on mine-waste dumps and acidic drainage from mines have resulted in elevated metal concentrations in the stream water and stream-bed sediment. The result of these mineral weathering processes has an unquantified impact on the quality of the water and the aquatic and riparian habitats that may limit their recreational resource value. One of the confounding factors in these studies is the determination of the component of metals derived from hydrothermally altered but unmined portions of these drainage basins. Several watersheds have been studied to evaluate the effects of acid mine drainage and acid rock drainage on the near-surface environment. The Animas River watershed in southwestern Colorado contains a large number of past-producing metal mines that have affected the watershed. Beginning in October 1996, the U.S. Geological Survey (USGS) began a collaborative study of these effects under the USGS-AML Initiative. In this report, we present the radionuclide and geochemical analytical results of sediment coring during 1997-1999 from two cores from oxbow lakes 0.5 mi. upstream from the 32nd Street Bridge near Durango, Colo., and from three cores from beaver ponds within the Mineral Creek drainage basin near Silverton, Colo.

Data Series↗

USGS2004

Quality of water in the Trinity and Edwards aquifers, south-central Texas, 1996-98

During 1996–98, the U.S. Geological Survey studied surface- and ground-water quality in south-central Texas. The ground-water components included the upper and middle zones (undifferentiated) of the Trinity aquifer in the Hill Country and the unconfined part (recharge zone) and confined part (artesian zone) of the Edwards aquifer in the Balcones fault zone of the San Antonio region. The study was supplemented by information compiled from four ground-water-quality studies done during 1996–98. Trinity aquifer waters are more mineralized and contain larger dissolved solids, sulfate, and chloride concentrations compared to Edwards aquifer waters. Greater variability in water chemistry in the Trinity aquifer likely reflects the more variable lithology of the host rock. Trace elements were widely detected, mostly at small concentrations. Median total nitrogen was larger in the Edwards aquifer than in the Trinity aquifer. Ammonia nitrogen was detected more frequently and at larger concentrations in the Trinity aquifer than in the Edwards aquifer. Although some nitrate nitrogen concentrations in the Edwards aquifer exceeded a U.S. Geological Survey national background threshold concentration, no concentrations exceeded the U.S. Environmental Protection Agency public drinking-water standard. Synthetic organic compounds, such as pesticides and volatile organic compounds, were detected in the Edwards aquifer and less frequently in the Trinity aquifer, mostly at very small concentrations (less than 1 microgram per liter). These compounds were detected most frequently in urban unconfined Edwards aquifer samples. Atrazine and its breakdown product deethylatrazine were the most frequently detected pesticides, and trihalomethanes were the most frequently detected volatile organic compounds. Widespread detections of these compounds, although at small concentrations, indicate that anthropogenic activities affect ground-water quality. Radon gas was detected throughout the Trinity aquifer but not throughout the Edwards aquifer. Fourteen samples from the Trinity aquifer and 10 samples from the Edwards aquifer exceeded a proposed U.S. Environmental Protection Agency public drinking-water standard. Sources of radon in the study area might be granitic sediments underlying the Trinity aquifer and igneous intrusions in and below the Edwards aquifer. The presence of tritium in nearly all Edwards aquifer samples indicates that some component of sampled water is young (less than about 50 years), even for long flow paths in the confined zone. About one-half of the Trinity aquifer samples contained tritium, indicating that only part of the aquifer contains young water. Hydrogen and oxygen isotopes of water provide indicators of recharge sources to the Trinity and Edwards aquifers. Most ground-water samples have a meteorological isotopic signature indicating recharge as direct infiltration of water with little residence time on the land surface. Isotopic data from some samples collected from the unconfined Edwards aquifer indicate the water has undergone evaporation. At the time that ground-water samples were collected (during a drought), nearby streams were the likely sources of recharge to these wells.

Texas↗

USGS2007

Response of roseate tern to a shoreline protection project on Falkner Island, Connecticut

Construction was initiated following the 2000 tern breeding season for Phase 1 of a planned two-phase "Shoreline Protection and Erosion Control Project" at the Falkner Island Unit of the USFWS Stewart B. McKinney National Wildlife Refuge located in Long Island Sound off the coast of Guilford, CT. When the Common Tern ( Sterna hirundo ) and federally endangered Roseate Tern ( S. dougallii ) arrived in spring 2001, they encountered several major habitat changes from what had existed in previous years. These changes included: a rock revetment covering most of the former nesting habitat on the beach from the northwestern section around the northern tip and covering about 60% of the eastern side; an elevated 60- x 4-m shelf covering the beach and lower bank of the southwestern section; and about 2,000 sq m of devegetated areas on top of the island on the northeast side above the revetment, and about one-third of the southern half of the island. The southwest shelf was created by bulldozing and compacting extra construction fill and in situ materials. This shelf differed in internal structure from the main revetment on the north and eastern sections of the island because it lacked the deep internal crevices of the revetment. The deep internal crevices were created from the large stones and boulders (up to 2 tons) used in the construction of the main revetment. Small rock and gravel was used to fill the crevices to within 3 feet (0.9 m) of the surface of the revetment. Because half-buried tires and nest boxes for the six Roseate Tern ( Sterna dougallii ) sub-colony areas were deployed in similar patterns on the remaining beach, and nest boxes were placed on the newly elevated shelf areas several meters above previous locations on the now-covered beach areas, the distribution of Roseate Tern nests did not change much from 2000 to 2001. However, the movements of Roseate Tern chicks - in many cases led by their parents towards traditional hiding places - into the labyrinth of subterranean channels, especially in the main revetment area, made it difficult to measure chick growth and productivity as had been done for more than 12 years prior to construction. Also, observations of color-banded adults that were unable to locate and feed their young inside the main revetment, and of adults returning to courtship behavior and renesting after having hatched chicks from their initial clutches, indicated that a minimum of 20% of the chicks (mostly first hatched A-chicks, which usually have high rates of survival to fledging) that entered the main revetment died after doing so in 2001. The mortality rate of Roseate Tern chicks that entered the secondary revetment on the southwest shelf, however, was not unusually high in 2001. In an attempt to reduce the likelihood of nesting and chick losses in these sub-colonies, a research team led by the USGS in 2002-2003 did not put nest boxes on the northeast and east shelf areas where previous losses had been high. However, losses of tern eggs and young chicks to predatory Black-crowned Night Herons ( Nycticorax nycticorax ) were so great in 2002-2003 that few Roseate Tern chicks survived long enough to move into the main revetment area and little comparative survival data were collected. The USFWS continues to remove predatory night herons, to monitor the location and success of nesting Roseate Terns and to fill in some of problem areas near the tern nests in the main revetment. The extensive chick-searching fieldwork and observational procedures used by the USGS-led research team to determine the growth and survival of the Roseate Tern chicks at Falkner Island were not used in 2004-2005. The number of chicks lost in the revetment during these years is not known. Without additional fill, loss of chicks of this endangered species in the main revetment may rise again even though the night heron predation problem has been reduced.

Connecticut↗

USGS2008

The Geologic Time Spiral - A Path to the Past

The Earth is very old - 4.5 billion years or more according to scientific estimates. Most of the evidence for an ancient Earth is contained in the rocks that form the Earth's crust. The rock layers themselves - like pages in a long and complicated history - record the events of the past, and buried within them are the remains of life - the plants and animals that evolved from organic structures that existed 3 billion years ago. Also contained in rocks once molten are radioactive elements whose isotopes provide Earth with an atomic clock. Within these rocks, 'parent' isotopes decay at a predictable rate to form 'daughter' isotopes. By determining the relative amounts of parent and daughter isotopes, the age of these rocks can be calculated. Thus, the scientific evidence from rock layers, from fossils, and from the ages of rocks as measured by atomic clocks attests to a very old Earth. See USGS Fact Sheet 2007-3015 at http://pubs.usgs.gov/fs/2007/3015/ for ages of geologic time periods. Ages in the spiral have been rounded from the age estimates in the Fact Sheet. B.Y., billion years; M.Y., million years. For more information, see the booklet on Geologic Time at http://pubs.usgs.gov/gip/geotime/. The Geologic Time Spiral poster is available for purchase from the USGS Store.

General Information Product↗

USGS2017

Restricted gene flow between resident Oncorhynchus mykiss and an admixed population of anadromous steelhead

The species Oncorhynchus mykiss is characterized by a complex life history that presents a significant challenge for population monitoring and conservation management. Many factors contribute to genetic variation in O. mykiss populations, including sympatry among migratory phenotypes, habitat heterogeneity, hatchery introgression, and immigration (stray) rates. The relative influences of these and other factors are contingent on characteristics of the local environment. The Rock Creek subbasin in the middle Columbia River has no history of hatchery supplementation and no dams or artificial barriers. Limited intervention and minimal management have led to a dearth of information regarding the genetic distinctiveness of the extant O. mykiss population in Rock Creek and its tributaries. We used 192 SNP markers and collections sampled over a 5‐year period to evaluate the temporal and spatial genetic structures of O. mykiss between upper and lower watersheds of the Rock Creek subbasin. We investigated potential limits to gene flow within the lower watershed where the stream is fragmented by seasonally dry stretches of streambed, and between upper and lower watershed regions. We found minor genetic differentiation within the lower watershed occupied by anadromous steelhead ( F ST = 0.004), and evidence that immigrant influences were prevalent and ubiquitous. Populations in the upper watershed above partial natural barriers were highly distinct ( F ST = 0.093) and minimally impacted by apparent introgression. Genetic structure between watersheds paralleled differences in local demographics (e.g., variation in size), migratory restrictions, and habitat discontinuity. The evidence of restricted gene flow between putative remnant resident populations in the upper watershed and the admixed anadromous population in the lower watershed has implications for local steelhead productivity and regional conservation.

Washington↗

USGS2006

Proterozoic evolution of the western margin of the Wyoming craton: Implications for the tectonic and magmatic evolution of the northern Rocky Mountains

Defining the extent and age of basement provinces west of the exposed western margin of the Archean Wyoming craton has been elusive because of thick sedimentary cover and voluminous Cretaceous-Tertiary magmatism. U-Pb zircon geochronological data from small exposures of pre-Belt supergroup basement along the western side of the Wyoming craton, in southwestern Montana, reveal crystallization ages ranging from ???2.4 to ???1.8 Ga. Rock-forming events in the area as young as ???1.6 Ga are also indicated by isotopic (Nd, Pb, Sr) signatures and xenocrystic zircon populations in Cretaceous-Eocene granitoids. Most of this lithosphere is primitive, gives ages ???1.7-1.86 Ga, and occurs in a zone that extends west to the Neoproterozoic rifted margin of Laurentia. These data suggest that the basement west of the exposed Archean Wyoming craton contains accreted juvenile Paleoproterozoic arc-like terranes, along with a possible mafic underplate of similar age. This area is largely under the Mesoproterozoic Belt basin and intruded by the Idaho batholith. We refer to this Paleoproterozoic crust herein as the Selway terrane. The Selway terrane has been more easily reactivated and much more fertile for magma production and mineralization than the thick lithosphere of the Wyoming craton, and is of prime importance for evaluating Neoproterozoic continental reconstructions. ?? 2006 NRC Canada.

Canadian Journal of Earth Sciences↗

USGS1949

Index of surface-water records, part 12, Pacific slope basins in Washington and upper Columbia River basin, to September 30, 1948

The groundwater resources of Wood County, Wisconsin, are described. Groundwater is pumped only from wells drilled in Precambrian rock in the northern two-thirds of the county. The generally low permeability of this rock limits the availability of groundwater in this area. Saturated deposits of sand and gravel yield more than 500 gal/min to wells in the southern part of the county. Background groundwater quality and indicators of groundwater-quality problems, such as elevated concentrations of nitrate, chloride, hardness, and iron, are compared by aquifer for the entire county. An elevated concentration of iron is the major water quality problem in the county. Results of water quality analysis from observation wells drilled next to abandoned landfills throughout the county indicate that groundwater in the immediate vicinity of these landfills has been affected by leachate. The report includes maps of the thickness and saturated thickness of unconsolidated deposits, a water-table map, and tables of aquifer-production and well-production data from about 1,500 drillers ' well-construction reports. (USGS)

Circular↗

USGS2017

Zirconium and hafnium

Zirconium and hafnium are corrosion-resistant metals that are widely used in the chemical and nuclear industries. Most zirconium is consumed in the form of the main ore mineral zircon (ZrSiO 4 , or as zirconium oxide or other zirconium chemicals. Zirconium and hafnium are both refractory lithophile elements that have nearly identical charge, ionic radii, and ionic potentials. As a result, their geochemical behavior is generally similar. Both elements are classified as incompatible because they have physical and crystallochemical properties that exclude them from the crystal lattices of most rock-forming minerals. Zircon and another, less common, ore mineral, baddeleyite (ZrO 2 ), form primarily as accessory minerals in igneous rocks. The presence and abundance of these ore minerals in igneous rocks are largely controlled by the element concentrations in the magma source and by the processes of melt generation and evolution. The world’s largest primary deposits of zirconium and hafnium are associated with alkaline igneous rocks, and, in one locality on the Kola Peninsula of Murmanskaya Oblast, Russia, baddeleyite is recovered as a byproduct of apatite and magnetite mining. Otherwise, there are few primary igneous deposits of zirconium- and hafnium-bearing minerals with economic value at present. The main ore deposits worldwide are heavy-mineral sands produced by the weathering and erosion of preexisting rocks and the concentration of zircon and other economically important heavy minerals, such as ilmenite and rutile (for titanium), chromite (for chromium), and monazite (for rare-earth elements) in sedimentary systems, particularly in coastal environments. In coastal deposits, heavy-mineral enrichment occurs where sediment is repeatedly reworked by wind, waves, currents, and tidal processes. The resulting heavy-mineral-sand deposits, called placers or paleoplacers, preferentially form at relatively low latitudes on passive continental margins and supply 100 percent of the world’s zircon. Zircon makes up a relatively small percentage of the economic heavy minerals in most deposits and is produced primarily as a byproduct of heavy-mineral-sand mining for titanium minerals. From 2003 to 2012, world zirconium mineral concentrates production increased by more than 40 percent, and Australia and South Africa were the leading producers. Global consumption of zirconium mineral concentrates generally increased during the same time period, largely as a result of increased demand in developing economies in Asia and the Middle East. Global demand weakened in 2012, causing a decrease in world production of zirconium mineral concentrates and delaying the development of several new mining projects. Global consumption is expected to increase in the future, however, as demand from the ceramics, chemicals, and metals industries increases (driven by renewed growth in developing economies) and demand for zirconium and hafnium metal increases (driven by the construction and operation of new nuclear powerplants). The behaviors of zirconium and hafnium in the environment are very similar to one another in that most zirconium- and hafnium-bearing minerals have limited solubility and reactivity. Anthropogenic sources of zirconium, and likely hafnium, are from industrial zirconium-containing byproducts and emissions from the processing of sponge zirconium, and exposure to the general population from these sources is small. Zirconium and hafnium are likely not essential to human health and generally are considered to be of low toxicity to humans. The main exposure risks are associated with industrial inhalation and dermal exposure. Because of the low solubility of zirconium and hafnium, ecological health concerns in the aquatic environment and in soils are minimal. Heavy-mineral-sand mining may lead to increased erosion rates when the mining is managed improperly. In addition, surface mining requires removal of the overlying organic soil layer and produces waste material that includes tailings and slimes. The soil removal and mining activity disturbs the surrounding ecosystem and alters the character of the landscape. Dry mineral separation processes create high amounts of airborne dust, whereas wet mineral separation processes do not. In operations that restore the landscape to pre-mining conditions, the volume of waste and the impact on the landscape may be relatively temporary.

Professional Paper↗

USGS2011

Reconnaissance geologic map of the Dubakella Mountain 15’ quadrangle, Trinity, Shasta, and Tehama Counties, California

The Dubakella Mountain 15' quadrangle is located just south of the Hayfork quadrangle and just east of the Pickett Peak quadrangle. It spans a sequence of four northwest-trending tectonostratigraphic terranes of the Klamath Mountains geologic province that includes, from east to west, the Eastern Hayfork, Western Hayfork, Rattlesnake Creek, and Western Jurassic terranes, as well as, in the southwest corner of the quadrangle, part of a fifth terrane, the Pickett Peak terrane of the Coast Ranges geologic province. The Eastern Hayfork terrane is a broken formation and melange of volcanic and sedimentary rocks that include blocks of limestone and chert. The limestone contains late Permian microfossils of Tethyan faunal affinity. The chert contains radiolarians of Mesozoic age, mostly Triassic, but none clearly Jurassic. The Western Hayfork terrane is an andesitic volcanic arc that consists mainly of agglomerate, tuff, argillite, and chert, and includes the Wildwood pluton. That pluton is related to the Middle Jurassic (about 170 Ma) Ironside Mountain batholith that is widely exposed farther north beyond the Dubakella Mountain quadrangle. The Rattlesnake Creek terrane is a highly disrupted ophiolitic melange of probable Late Triassic or Early Jurassic age. Although mainly ophiolitic, the melange includes blocks of plutonic rocks (about 200 Ma) of uncertain genetic relation. Some scattered areas of well-bedded mildly slaty detrital rocks of the melange appear similar to Galice Formation (unit Jg) and may be inliers of the nearby Western Jurassic terrane. The Western Jurassic terrane consists mainly of slaty to phyllitic argillite, graywacke, and stretched-pebble conglomerate and is correlative with the Late Jurassic Galice Formation of southwestern Oregon. The Pickett Peak terrane, the most westerly of the succession of terranes of the Dubakella Mountain quadrangle, is mostly fine-grained schist that includes the blueschist facies mineral lawsonite and is of Early Cretaceous (about 120 Ma) metamorphic age. Remnants of the Great Valley sequence of dominantly Cretaceous marine sedimentary strata, which once covered much of the southern fringe of the Klamath Mountains, are present at three places in the Dubakella Mountain quadrangle. Mineral production in the quadrangle has included small amounts of gold, chromite, and manganese. This map of the Dubakella Mountain 15' quadrangle is a digital rendition of U.S. Geological Survey Miscellaneous Field Studies Map MF-1808, with various improvements and additions.

California↗

USGS2014

Differentiation of pre-existing trapped methane from thermogenic methane in an igneous-intruded coal by hydrous pyrolysis

So as to better understand how the gas generation potential of coal changes with increasing rank, same-seam samples of bituminous coal from the Illinois Basin that were naturally matured to varying degrees by the intrusion of an igneous dike were subjected to hydrous pyrolysis (HP) conditions of 360 °C for 72 h. The accumulated methane in the reactor headspace was analyzed for δ 13 C and δ2H, and mol percent composition. Maximum methane production (9.7 mg/g TOC) occurred in the most immature samples (0.5 %R o ), waning to minimal methane values at 2.44 %Ro (0.67 mg/g TOC), and rebounding to 3.6 mg/g TOC methane in the most mature sample (6.76 %R o ). Methane from coal with the highest initial thermal maturity (6.76 %R o ) shows no isotopic dependence on the reactor water and has a microbial δ 13 C value of −61‰. However, methane from coal of minimal initial thermal maturity (0.5 %R o ) shows hydrogen isotopic dependence on the reaction water and has a δ 13 C value of −37‰. The gas released from coals under hydrous pyrolysis conditions represents a quantifiable mixture of ancient (270 Ma) methane (likely microbial) that was generated in situ and trapped within the rock during the rapid heating by the dike, and modern (laboratory) thermogenic methane that was generated from the indigenous organic matter due to thermal maturation induced by hydrous pyrolysis conditions. These findings provide an analytical framework for better assessment of natural gas sources and for differentiating generated gas from pre-existing trapped gas in coals of various ranks.

Organic Geochemistry↗