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At least 1,135 records · Page 63Linked to original sources

The stability of sulfate and hydrated sulfate minerals near ambient conditions and their significance in environmental and planetary sciences

Sulfate and hydrated sulfate minerals are abundant and ubiquitous on the surface of the Earth and also on other planets and their satellites. The humidity-buffer technique has been applied to study the stability of some of these minerals at 0.1 MPa in terms of temperature-relative humidity space on the basis of hydration-dehydration reversal experiments. Updated phase relations in the binary system MgSO 4 -H 2 O are presented, as an example, to show how reliable thermodynamic data for these minerals could be obtained based on these experimental results and thermodynamic principles. This approach has been applied to sulfate and hydrated sulfate minerals of other metals, including Fe (both ferrous and ferric), Zn, Ni, Co, Cd, and Cu. Metal-sulfate salts play important roles in the cycling of metals and sulfate in terrestrial systems, and the number of phases extends well beyond the simple sulfate salts that have thus far been investigated experimentally. The oxidation of sulfide minerals, particularly pyrite, is a common process that initiates the formation of efflorescent metal-sulfate minerals. Also, the overall abundance of iron-bearing sulfate salts in nature reflects the fact that the weathering of pyrite or pyrrhotite is the ultimate source for many of these phases. Many aspects of their environmental significance are reviewed, particularly in acute effects to aquatic ecosystems related to the dissolution of sulfate salts during rain storms or snow-melt events. Hydrous Mg, Ca, and Fe sulfates were identified on Mars, with wide distribution and very large quantities at many locations, on the basis of spectroscopic observations from orbital remote sensing and surface explorations by rovers. However, many of these findings do not reveal the detailed information on the degree of hydration that is essential for rigorous interpretation of the hydrologic history of Mars. Laboratory experiments on stability fields, reactions pathways, and reaction rates of hydrous sulfates likely to be found on Mars enhance our understanding of the degrees of hydration of various sulfates that should currently exist on Mars at various seasons and locations and during various atmospheric pressure and obliquity periods. Two sets of systematic experiments were described; one on hydrous Mg sulfates and the other on hydrous Fe 3+ sulfates. Also, their implications to Mars sulfates mineralogy were discussed.

Journal of Asian Earth Sciences↗

Molecular and isotopic gas composition of the Devonian Berea Sandstone and implications for gas evolution, eastern Kentucky

Since 2011, the Devonian Berea Sandstone in northeastern Kentucky has produced oil where thermal maturity studies indicate that likely source rocks, namely, the Devonian Ohio Shale and Mississippian Sunbury Shale, are thermally immature. Downdip, where source rocks are mature for oil, the Berea Sandstone and Ohio Shale primarily produce gas. To investigate this thermal maturity discordancy, the molecular and isotopic composition of gases from the Berea Sandstone (oil associated) and Ohio Shale (nonassociated) were analyzed to understand the gas generation and migration history. Collected along a northwest-southeast transect in eastern Kentucky, samples range from 1079 to 4602 ft, respectively. All are wet gases with a thermogenic origin (δ 13 C-CH 4 = −53.5‰ to −46.1‰). This is mostly consistent with a reevaluation of thermal maturity in a companion study that expands the area mature for oil. Gas migration is required, however, in updip parts of the Berea play where vitrinite reflectance ( VR o ) values are less than 0.6%. Southeast regional dip exerts a first-order influence on thermal maturity as gases become drier and isotopically heavier downdip. Correlation of δ 13 C values for heavier hydrocarbon gases in a natural gas plot with VR o contour spacing demonstrates the influence of nearby source rock thermal maturity on gas composition. Downdip, migration of oil and the attendant increase in permeability relative to gas may account for the dominance of gas production in the Ohio Shale. Migration along with basin uplift after the Alleghany orogeny may have contributed to development of a gas phase that exsolved from oil.

Kentucky↗

Native amphibian toxin reduces invasive crayfish feeding with potential benefits to stream biodiversity

Background Biodiversity is generally reduced when non-native species invade an ecosystem. Invasive crayfish, Procambarus clarkii , populate California freshwater streams, and in the Santa Monica Mountains (Los Angeles, USA), their introduction has led to trophic cascades due to omnivorous feeding behavior and a rapid rate of population growth. The native California newt, Taricha torosa , possesses a neurotoxin, tetrodotoxin (TTX), that affects freshwater animal behavior. Given P. clarkii has a limited evolutionary history with TTX, we hypothesized that TTX may affect crayfish feeding behaviors. To determine if TTX affects P. clarkii behavior, we measured cumulative movement and various feeding behaviors of P. clarkii exposed to (i) waterborne, ecologically realistic concentrations of TTX (~ 3.0 × 10 − 8 moles/L), (ii) an anuran chemical cue to account for intraguild cues, or (iii) a T. torosa chemical cue with quantitated TTX in it (~ 6.2 × 10 − 8 moles/L). Results We found that the presence of TTX in any form significantly reduced crayfish movement and decreased the amount of food consumed over time. Crayfish responses to the anuran treatment did not significantly differ from controls. Conclusion Our laboratory results show that naturally occurring neurotoxin from native California newts limits invasive crayfish foraging and feeding rates, which may play a role in preserving local stream ecosystems by limiting invasive crayfish behaviors that are detrimental to biodiversity.

California↗

Landscapes to riverscapes: bridging the gap between research and conservation of stream fishes

Rivers and streams, by their very nature long ribbons of aquatic habitat, are inherently difficult to study. Approaching the banks of a flowing-water (lotic) system, one can see only a short fragment of the entire stream, from one bend to another, and can gain little appreciation for important features that lie beyond view. Moreover, materials transported downstream by the flow, and organisms traveling up or down the hydraulic highway, are soon gone from the reach and the opportunity to study them is often lost. Lakes present their own challenges for study, but by contrast to streams, one can usually see large expanses from shore that encompass all major habitats needed for aquatic organisms to complete their life history, such as gravel shoals, beds of aquatic vegetation, and open water habitats

BioScience↗

Sediment transport, terrace incision, and sediment chemistry in subbasins of differing land use, Stinking Water Creek Basin near Rangely, Colorado

In many areas of western Colorado, Late Cretaceous Mancos Shale is a source of sediment, salinity, and selenium to surface water. Natural weathering processes and human activity can expose and move sediments from the Mancos Shale, leading to increased salinity and selenium concentrations in surface water. The U.S. Geological Survey, in cooperation with the Bureau of Land Management, studied four subbasins of Stinking Water Creek near Rangely, Colorado, to provide information regarding landscapes on Mancos Shale that have undergone land-use change. Rangeland grazing is present in all four subbasins. Subbasins A1 and A2 have land use related to energy development and subbasins B1 and B2 do not. Aerial photographs, sediment chemistry, optically stimulated luminescence (OSL) ages, cross-section surveys, and Watershed Erosion Prediction Project (WEPP) modeling were used to characterize the history of land-use change by estimating stream channel incision rates and sediment, salinity, and selenium loads. All subbasins had upper and lower terraces and a modern streambed channel, and these surfaces were dated using OSL. In subbasins A1, A2, and B1, the streambed age was older than the terraces, indicating the channels are incising and widening into the older alluvium. In subbasin B2, however, the streambed age was much younger than the terraces, indicating aggradation is the main process. Differences in channel morphology were not always related to land use but to the subbasin position (upstream compared to downstream). Channels in subbasins A1 and A2 were generally wider and shallower than channels in subbasins B1 and B2. Landscape disturbances related to energy development in subbasins A1 and A2 could have caused channel evolution to progress from incision to widening processes.

Colorado↗

Preliminary examination of lunar samples: Part A: a petrographic and chemical description of samples from the lunar highlands

More than four-fifths of the surface of the Moon consists of a profoundly cratered irregular surface designated terra or highlands by analogy with the terrestrial continents. These terra regions have much higher albedos than the physiographically lower and much smoother mare regions. The difference in albedo can now be ascribed to a fundamental difference in the chemical and mineralogical character of these two regions. Lunar samples from landing sites in the mare regions and high-resolution photographs taken from lunar orbit have shown that the lunar maria are underlain by extensive lava flows. Isotopic dating of samples from four mare regions (refs. 7-1 to 7-4) indicate that mare volcanism covered a time span of 600 million years, beginning approximately 3.7 billion years ago. The intensely cratered character of terra regions is due to both the greater antiquity of these parts of the Moon and the higher flux of incoming objects that hit the Moon during very early lunar history (ref. 7-5). In contrast with the mare region, the origin of the underlying material of the terra is not easily inferred from physiographic criteria. The surface manifestations of early plutonic or extrusive igneous activity — if indeed they ever existed — were erased from the terra regions by the intense early bombardment of the lunar surface. Some portions of the highlands may be exceptions to this generalization; in particular, large craters such as Ptolemaeus, Hipparchus, Albategnius, and Alphonsus. The regions bounded by these craters are much smoother than the typical densely cratered highlands. These regions are generally assumed to be physiographic lows that have, in some way, been filled by younger material. The nature of the material and the mechanism by which it was introduced into the basins are not well understood. On the basis of rather detailed studies of the physiographic and albedo characteristics of the basin material, it has been suggested (ref. 7-6) that the filling of the highland basins was a result of volcanic processes similar to those which filled the large mare basins. Some highland basins also contain hilly, hummocky regions that bear no relation to large crater rims or crater ejecta. These regions have been interpreted as extrusive igneous features formed by viscous, silicic, igneous liquids (ref. 7-6).

Book chapter↗

Role of large- and fine-scale variables in predicting catch rates of larval Pacific lamprey in the Willamette Basin, Oregon

Pacific lamprey Entosphenus tridentatus is an anadromous fish native to the Pacific Northwest of the USA. That has declined substantially over the last 40 years. Effective conservation of this species will require an understanding of the habitat requirements for each life history stage. Because its life cycle contains extended freshwater rearing (3–8 years), the larval stage may be a critical factor limiting abundance of Pacific lamprey. The objective of our study was to estimate the influence of barriers and habitat characteristics on the catch-per-unit-effort (CPUE) of larval Pacific lamprey in the Willamette River Basin, Oregon, USA. We sampled lampreys at multiple locations in wadeable streams throughout the basin in 2011–13 and used an information theoretic approach to examine the relative influence of fine- and large-scale predictors of CPUE. Pacific lamprey was observed across the basin, but its relative abundance appeared to be limited by the presence of natural and artificial barriers in some sub-basins. Lower velocity habitats such as off-channel areas and pools contained higher densities of larval lamprey; mean Pacific lamprey CPUE in off-channel habitats was 4 and 32 times greater than in pools and riffles respectively. Restoration and conservation strategies that improve fish passage, enhance natural hydrologic and depositional processes and increase habitat heterogeneity will likely benefit larval Pacific lamprey.

Oregon↗

U.S. Geological Survey Energy and Minerals science strategy: A resource lifecycle approach

Executive Summary The economy, national security, and standard of living of the United States depend heavily on adequate and reliable supplies of energy and mineral resources. Based on population and consumption trends, the Nation’s use of energy and minerals can be expected to grow, driving the demand for ever broader scientific understanding of resource formation, location, and availability. In addition, the increasing importance of environmental stewardship, human health, and sustainable growth places further emphasis on energy and mineral resources research and understanding. Collectively, these trends in resource demand and the interconnectedness among resources will lead to new challenges and, in turn, require cutting-edge science for the next generation of societal decisions. The long and continuing history of U.S. Geological Survey contributions to energy and mineral resources science provide a solid foundation of core capabilities upon which new research directions can grow. This science strategy provides a framework for the coming decade that capitalizes on the growth of core capabilities and leverages their application toward new or emerging challenges in energy and mineral resources research, as reflected in five interrelated goals. Goal 1.—Understand fundamental Earth processes that form energy and mineral resources Goal 2.—Understand the environmental behavior of energy and mineral resources and their waste products Goal 3.—Provide inventories and assessments of energy and mineral resources Goal 4.—Understand the effects of energy and mineral development on natural resources and society Goal 5.—Understand the reliability and availability of energy and mineral supplies Within each goal, multiple actions are identified. The level of specificity and complexity of these actions varies, consistent with the reality that even a modest refocus can yield large payoffs in the near term whereas more ambitious plans may take years to reach fruition. As such, implementation of these actions is largely dependent on available resources and the sequencing of prerequisite steps. This science strategy places an emphasis on interdisciplinary collaboration and leveraging of expertise across the U.S. Geological Survey and with external partners.

Circular↗

The McKinley Sequence of granitic rocks: A key element in the accretionary history of southern Alaska

The McKinley sequence of granitic rocks consists of several discrete plutons in the central Alaska Range. Most of these plutons crop out south of the Denali fault system (DFS) in the Talkeetna quadrangle. Plutons of the McKinley sequence largely intrude deformed upper Meszoic flysch between the DFS and the northern edges of Wrangellia and the Peninsular terrane, which jointly make up the Talkeetna superterrane. The average K-Ar age of biotite from nine granites of the McKinley sequence is 57.3 Ma; Rb-Sr data for whole rock samples indicate that the McKinley sequence cannot be older than 60 Ma. A selected suite of 20 samples of granite and granodiorite range in SiO 2 from 65.9 to 77.6%. All 20 samples are corundum normative, and 18 are moderately peraluminous. Initial 87 Sr/ 86 Sr ratios range from 0.7054 to 0.7085. The σ 18 O values range from +11.2 to +14.6‰. These high and variable Sr isotopic ratios, peraluminous nature, rare earth element patterns, and high σ 18 O values suggest that granitic rocks of the McKinley sequence crystallized from hybrid magmas produced by assimilation of sedimentary rocks by a mantle-derived melt. Mesozoic flysch is the likely source of the crustal component of the hybrid magmas. Geologic evidence suggests that the Talkeetna superterrane collided with stable Alaska after Early Cretaceous time. The flysch basin, lying south of stable Alaska, was closed by northward movement of the Talkeetna superterrane; maximum age for basin closure and terrane accretion is middle Cretaceous (Cenomanian). Paleomagnetic evidence indicates that all terranes north of the DFS have been part of stable Alaska since the Paleocene and that northward movement of Wrangellia was completed by 50 Ma. Granitic rocks of the McKinley sequence may be products of terrane accretion; the granitic rocks crystallized from hybrid magmas produced during terrane collision and deformation of the flysch basin. Isotopic ages of the McKinley sequence establish the time of final accretion of the Talkeetna superterrane as Paleocene.

Journal of Geophysical Research Solid Earth↗

Introducing disciplinary perspectives and interdisciplinary possibilities for studying recreational fishers and fisheries

Individuals from many disciplines conduct research to understand the social dimension of recreational fisheries. This diverse inquiry has produced a comprehensive understanding of the behaviours of recreational fishers, the outcomes from fishing, and the relationships among fishers, others, and the natural and human environment. The associated body of research, however, is largely disconnected across disciplines. Our goals here are to help readers understand the similarities and differences among disciplines and to identify opportunities for interdisciplinary-based research on recreational fishers. Before addressing these goals, we begin by answering basic questions: What is a discipline? What are the primary disciplines used to study recreational fishers? And what is the genealogy of research on recreational fishers? Seven key disciplines are then classified by multi-criteria related to both focus and epistemological and methodological approaches. This classification reveals clear connections among: (i) ecological science and resource economics, and to a lesser extent historical ecology; (ii) environmental history and political ecology; and (iii) behavioural economics and social psychology. We next describe and provide possible remedies for barriers that inhibit interdisciplinary research, including different epistemologies, nomenclature, and reward bias. Finally, we highlight opportunities to conduct interdisciplinary research by describing the types of benefits that each discipline can provide when conducting interdisciplinary research on recreational fisheries.

Book chapter↗

The proliferation of induced seismicity in the Permian Basin, Texas

The Permian Basin has a long history of induced earthquakes, but the seismicity rates have increased dramatically over the past two decades and included a M W 5.0 likely induced by wastewater disposal (WD) in March 2020. A detailed characterization of the proliferation of seismicity in the Permian Basin throughout this time period is needed for improving the scientific understanding of the mechanisms responsible and for mitigating future seismic hazard. Due to a sparse regional seismic network before the advent of Texas Seismological Network in 2017, we characterize seismicity using the 10-station TXAR array that is 100s of km away from most of the seismicity, with the objective of improving upon the substantial contributions from previous work. By exploiting the nature of waveform similarity, we detect events with template matching, performing a quantitative analysis of spatially varying detection capabilities throughout the study area. From an initial catalog of 10,753 events, we identify 45,009 earthquakes and 10,208 quarry blasts. Using our catalog of earthquakes, we improve epicentral locations, compare relative magnitude techniques, and associate earthquakes to WD or hydraulic stimulations. We further use our earthquake catalog to investigate the relationship between seismicity and human activities near the city of Pecos, Texas. Through a comparison of our earthquake catalog with industrial records, we determine that the vast majority seismicity near Pecos, Texas, since 2000 is likely induced by an increase of WD at wells injecting at depths greater than 1.5 km.

Texas↗

Competitive Interactions of Garlic Mustard ( Alliaria petiolata ) and Damesrocket ( Hesperis matronalis )

Competitive interactions between native plants and nonnative, invasive plant species have been extensively studied; however, within degraded landscapes, the effect of interspecific interactions among invasive plants is less explored. We investigated a competitive interaction between two sympatric, invasive mustard species that have similar life history strategies and growth forms: garlic mustard and damesrocket. Greenhouse experiments using a full range of reciprocal density ratios were conducted to investigate interspecific competition. Garlic mustard had a negative effect on the final biomass, number of leaves, and relative growth rate in height of damesrocket. Survival of damesrocket was not negatively affected by interspecific competition with garlic mustard; however, garlic mustard showed higher mortality because of intraspecific competition. These results indicated that although garlic mustard has been observed to be the dominant species in this landscape, it may not completely outcompete damesrocket in all situations. Studies of invasive species in competition are important in degraded landscapes because this is the common situation in many natural areas.

Invasive Plant Science and Management↗

The potential roles of biological soil crusts in dryland hydrologic cycles

Biological soil crusts (BSCs) are the dominant living cover in many drylands of the world. They possess many features that can influence different aspects of local hydrologic cycles, including soil porosity, absorptivity, roughness, aggregate stability, texture, pore formation, and water retention. The influence of biological soil crusts on these factors depends on their internal and external structure, which varies with climate, soil, and disturbance history. This paper presents the different types of biological soil crusts, discusses how crust type likely influences various aspects of the hydrologic cycle, and reviews what is known and not known about the influence of biological crusts on sediment production and water infiltration versus runoff in various drylands around the world. Most studies examining the effect of biological soil crusts on local hydrology are done by comparing undisturbed sites with those recently disturbed by the researchers. Unfortunately, this greatly complicates interpretation of the results. Applied disturbances alter many soil features such as soil texture, roughness, aggregate stability, physical crusting, porosity, and bulk density in ways that would not necessarily be the same if crusts were not naturally present. Combined, these studies show little agreement on how biological crusts affect water infiltration or runoff. However, when studies are separated by biological crust type and utilize naturally occurring differences among these types, results indicate that biological crusts in hyperarid regions reduce infiltration and increase runoff, have mixed effects in and regions, and increase infiltration and reduce runoff in semiarid cool and cold drylands. However, more studies are needed before broad generalizations can be made on how biological crusts affect infiltration and runoff. We especially need studies that control for sub-surface soil features such as bulk density, micro- and macropores, and biological crust structure. Unlike the mixed effects of biological crusts on infiltration and runoff among regions, almost all studies show that biological crusts reduce sediment production, regardless of crust or dryland type.

Hydrological Processes↗

Forming Ganymede’s grooves at smaller strain: Toward a self-consistent local and global strain history for Ganymede

The ubiquity of tectonic features formed in extension, and the apparent absence of ones formed in contraction, has led to the hypothesis that Ganymede has undergone global expansion in its past. Determining the magnitude of such expansion is challenging however, and extrapolation of locally or regionally inferred strains to global scales often results in strain estimates that exceed those based on global constraints. Here we use numerical simulations of groove terrain formation to develop a strain history for Ganymede that is generally consistent at local, regional, and global scales. These simulations reproduce groove-like amplitudes, wavelengths, and average slopes at modest regional extensions (10–15%). The modest strains are more consistent with global constraints on Ganymede’s expansion. Yet locally, we also find that surface strains can be much larger (30–60%) in the same simulations, consistent with observations of highly-extended impact craters. Thus our simulations satisfy both the smallest-scale and largest-scale inferences of strain on Ganymede. The growth rate of the topography is consistent with (or exceeds) predictions of analytical models, and results from the use of a non-associated plastic rheology that naturally permits localization of brittle failure (plastic strain) into linear fault-like shear zones. These fault-like zones are organized into periodically-spaced graben-like structures with stepped, steeply-dipping faults. As in previous work, groove amplitudes and wavelengths depend on both the imposed heat flux and surface temperature, but because our brittle strength increases with depth, we find (for the parameters explored) that the growth rate of topography is initially faster for lower heat flows. We observe a transition to narrow rifting for higher heat flows and larger strains, which is a potential pathway for breakaway margin or band formation.

Icarus↗

Population genetic structure in Atlantic and Pacific Ocean common murres ( Uria aalge ): Natural replicate tests of post-Pleistocene evolution

Understanding the factors that influence population differentiation in temperate taxa can be difficult because the signatures of both historic and contemporary demographics are often reflected in population genetic patterns. Fortunately, analyses based on coalescent theory can help untangle the relative influence of these historic and contemporary factors. Common murres ( Uria aalge ) are vagile seabirds that breed in the boreal and low arctic waters of the Northern Hemisphere. Previous analyses revealed that Atlantic and Pacific populations are genetically distinct; however, less is known about population genetic structure within ocean basins. We employed the mitochondrial control region, four microsatellite loci and four intron loci to investigate population genetic structure throughout the range of common murres. As in previous studies, we found that Atlantic and Pacific populations diverged during the Pleistocene and do not currently exchange migrants. Therefore, Atlantic and Pacific murre populations can be used as natural replicates to test mechanisms of population differentiation. While we found little population genetic structure within the Pacific, we detected significant east-west structuring among Atlantic colonies. The degree that population genetic structure reflected contemporary population demographics also differed between ocean basins. Specifically, while the low levels of population differentiation in the Pacific are at least partially due to high levels of contemporary gene flow, the east-west structuring of populations within the Atlantic appears to be the result of historic fragmentation of populations rather than restricted contemporary gene flow. The contrasting results in the Atlantic and Pacific Oceans highlight the necessity of carefully considering multilocus nonequilibrium population genetic approaches when reconstructing the demographic history of temperate Northern Hemisphere taxa. ?? 2008 The Authors.

Molecular Ecology↗

Leafy spurge (Euphorbia esula) affects vegetation more than seed banks in mixed-grass prairies of the Northern Great Plains

Exotic plants have the ability to modify soil seed banks in habitats they invade, but little is known about the legacy of invasion on seed banks once an exotic plant has successfully been controlled. Natural areas previously invaded by leafy spurge in the northern Great Plains typically have one of two fates following its removal: a return of native plants, or a secondary invasion of other exotic plants. It is unknown, however, if this difference in plant communities following leafy spurge control is due to seed bank differences. To answer this question, we monitored seed banks and standing vegetation for 2 yr in mixed-grass prairies that were previously invaded by leafy spurge but controlled within 5 yr of our study. We found that native plant seed banks were largely intact in areas previously invaded by leafy spurge, regardless of the current living plant community, and leafy spurge invasion history had a larger impact on cover and diversity of the vegetation than on the seed banks. Differences in plant communities following leafy spurge control do not appear to be related to the seed banks, and soil conditions may be more important in determining trajectories of these postinvasion communities.

North Dakota↗

Using DNA barcoding to evaluate freshwater mussel and fish-host relationships in the Flint River (Georgia, USA)

Freshwater mussels have a unique life history in which larval mussels (glochidia) act as obligate parasites to fish hosts. Host selectivity may be species specific, and identification of host fish is a critical step in conservation planning for individual mussel species. The Flint River harbors ~23% of the freshwater mussel (order Unionida) diversity in the state of Georgia, USA. Nine species in the basin are state or federally listed, and local diversity is threatened by shifting hydrologic conditions, increasing habitat loss, and sedimentation. However, knowledge on host species is lacking for nearly 40% of mussel species in the Flint River, limiting the efforts of conservation managers. In this study, we assessed the use of host fish by mussels by identifying the species of naturally encysted mussel larvae and transformed juveniles found on wild-caught fishes. Infested fishes were collected in the summers of 2021 and 2022 and held in laboratory conditions. Glochidia and juvenile mussels were collected as they excised from live hosts and were identified by DNA barcoding with the cytochrome oxidase c subunit I locus. Twenty-eight unique mussel–host relationships were identified, 27 of which were considered novel when cross-referenced to the existing mussel–host databases and peer-reviewed literature. Our data build upon knowledge of host use in unionids and further demonstrate the importance of understanding patterns in wild host use.

Georgia↗

Thermal maturity patterns (CAI and %Ro) in the Ordovician and Devonian rocks of the Appalachian basin in New York State

The objective of this study is to enhance existing thermal maturity maps in New York State by establishing: 1) new subsurface CAI data points for the Ordovician and Devonian and 2) new %Ro and Rock Eval subsurface data points for Middle and Upper Devonian black shale units. The thermal maturity of the Ordovician and Devonian rocks is of major interest because they contain the source for most of the unconventional natural gas resources in the basin. Thermal maturity patterns of the Middle Ordovician Trenton Group are evaluated here because they closely approximate those of the overlying Ordovician Utica Shale that is believed to be the source rock for the regional oil and gas accumulation in Lower Silurian sandstones (Jenden and others, 1993; Ryder and others, 1998). Improved CAI-based thermal maturity maps of the Ordovician are important to identify areas of optimum gas generation from the Utica Shale and to provide constraints for interpreting the origin of oil and gas in the Lower Silurian regional accumulation, in particular, its basin-centered part (Ryder, 1998). Thermal maturity maps of the Devonian will better constrain burial history-petroleum generation models of the Utica Shale, as well as place limitations on the origin of regional oil and gas accumulation in Upper Devonian sandstone and Middle to Upper Devonian black shale.

New York↗