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At least 1,135 records · Page 63Linked to original sources
USGS2025

Multiscale framework for assessing land cover change on barrier islands from extreme storms and restoration

Often found along the estuarine-marine interface, barrier islands and mainland coastal zones are shaped by tides, currents, extreme storms, and relative sea-level rise. These systems provide ecosystem services such as storm surge and wave attenuation, erosion protection to inland areas, habitat for fish and wildlife, recreation, and tourism. Given the importance of these ecosystems coupled with their dynamic nature, information on how these coastal systems are changing can help to inform natural resource management. Remote sensing advancements have led to an abundance of data for monitoring change in coastal settings. This study developed a multiscale framework that can provide trajectory information from screening-level analyses by using existing or custom moderate spatial resolution land cover maps. Using the north-central Gulf Coast as a case study, the trajectory of land cover area for barrier islands and mainland coastal zones was assessed using several geospatial data sets, including: (1) long-term moderate-resolution remote sensing products with an annual (or more frequent) temporal frequency; (2) a restoration database ( e.g. , beach/dune restoration, sediment placement, and dune enhancement); and (3) a tropical storm database. Due to the coarser spatial resolution of data sets used for screening-level analyses, detailed or application-specific analyses are often needed to reduce uncertainty in smaller changes that may not be captured. These may include land cover change analyses ( i.e. this study), periodic land cover maps with higher spatial resolution and more detailed land cover classes, or elevation-related analyses ( e.g. , dune change or inundation change). Using this framework, abrupt changes in land cover on Dauphin Island, Alabama, resulting from extreme storms were detected using moderate spatial resolution screening-level data, while restoration impact analyses may require higher resolution data. Further, land cover change analyses that incorporate change allocation provide robust information for understanding land cover change in dynamic coastal settings.

Alabama, Florida↗
USGS2004

Ad Duwayhi, Saudi Arabia: Geology and geochronology of a neoproterozoic intrusion-related gold system in the Arabian shield

The Ad Duwayhi gold deposit, located in the east-central part of the Arabian shield, is the newest gold discovery in Saudi Arabia. Exploration to date has identified a gold resource of greater than 1 million ounces (oz) with significant potential for expansion. Gold mineralization was closely associated, in time and space, with emplacement of a late- to postorogenic, intracrustal, northwest-oriented granite body (659 ± 7 Ma) and comagmatic square quartz porphyry (646 ± 11 Ma), a hypabyssal and perhaps younger phase of the granite. Mineralization was largely confined to northeast-striking, southeast-dipping fault zones. Hydrothermal alteration consisted of early biotitic alteration overprinted by sericitic alteration. Sericitic alteration was coincident with gold mineralization and produced a quartz-sericite-carbonate-pyrite-rutile mineral assemblage, found both as vein fill and wall-rock alteration products. Mineralization styles, in the following general paragenetic sequence, include (1) quartz-molybdenite veins in and near the granite stock, (2) low-grade gold-bearing quartz vein breccia in and along the margins of the granite stock, (3) gold-bearing stockwork and sheeted quartz veins, and (4) massive to banded gold-rich tabular quartz veins. The gold-bearing stockwork, sheeted, and tabular veins are generally spatially associated with square quartz porphyry dikes and more distal to the granite stock. Mineralized zones at Ad Duwayhi are characterized by low sulfide and base metal content and gold/silver ratios of approximately 6/1. Gold shows no significant correlation with other metals, except lead, and moderate correlation with silver. Re-Os dating of molybdenite from a quartz-molybdenite vein and a tabular quartz vein with cogenetic gold produced robust ages of 655.6 ± 2.7 and 649.9 ± 2.3 Ma, respectively, documenting that gold mineralization and crystallization of granite and square quartz porphyry were, within uncertainty, coeval events. This age correlation combined with granite textural features, the presence of unidirectional solidification textures in granite and square quartz porphyry, and the nature and time-space distribution of mineralization styles, all indicate that mineralization evolved in and near the interface between a crystallizing magma and the surrounding rocks and, thus, is consistent with an intrusion-related genesis. In light of our findings at Ad Duwayhi, a reassessment of similar intrusion-hosted deposits in the Arabian shield is warranted, and areas of late- to postorogenic plutonism, particularly in the Afif composite terrane, should be considered prospective for intrusion-related gold systems.

Economic Geology↗
USGS2005

Foliation development and reaction softening by dissolution and precipitation in the transformation of granodiorite to orthogneiss, Glastonbury Complex, Connecticut, U.S.A

Textures, microstructures, and patterns of chemical zoning in minerals in a granodioritic orthogneiss in the Glastonbury Complex, Connecticut, lead to the interpretation that foliation development was facilitated by retrograde hydration reactions in the presence of an aqueous fluid. Incomplete replacement of the metastable magmatic minerals K-feldspar + hastingsite + magnetite produced foliation-defining biotite + epidote + quartz. These reaction products did not replace K-feldspar – hastingsite interfaces; rather, either biotite or epidote replaced the amphibole, and plagioclase replaced K-feldspar. Biotite and epidote precipitated syntectonically in discrete layers that define the foliation in the orthogneiss, whereas quartz precipitated primarily in ribbons, further enhancing the fabric. Metastable REE-rich igneous titanite also dissolved, and was incompletely replaced by REE-poor, Al-bearing metamorphic titanite. The similar concentrations of the REE in epidote and titanite show that the REE released by titanite dissolution were precipitated locally as the allanite component in adjacent grains of epidote. The entire process was syntectonic, with most grains showing multiple overgrowths in the direction of extension as defined by stretched xenoliths. Sufficient U was present in the titanite overgrowths to allow SHRIMP dating of cores, mantles, and rims. These results suggest at least three retrograde Alleghanian events of growth in a span of ~30 m.y. Thus the dissolution – transportation –precipitation process not only describes the reaction mechanism but also leads to the redistribution of reaction products into nearly monomineralic layers, thus contributing to metamorphic differentiation and to the development of the foliation. The resulting orthogneiss was much weaker that the granodiorite protolith, owing to this reaction and textural softening.

Connecticut↗
USGS1962

The origin of jasperoid in limestone

The name jasperoid has been applied to rocks that consist mainly of silica and that have formed by replacement. This paper considers only those jasperoids formed by replacement of limestone . Major problems involved in the origin of such jasperoid include: source of the silica; nature of solutions that dissolve, transport, and precipitate silica; and the mechanism of replacement of limestone by silica. The answers to these problems are of practical as well as scientific interest because many jasperoid bodies are closely related to mineralization. Silica may be derived from: juvenile silica of magmatic origin ; silica leached from underlying rocks by hydrothermal solutions; silica locally derived from enclosing rocks by circulating solutions; and silica carried downward in ground water from the weathering of overlying rocks. The nature and the concentration of other substances in solutions influence, in a complex manner, the ability of these solutions to dissolve, transport, and precipitate silica. Nevertheless, the following generalizations can be made. The solubility and rate of solution of silica in water at moderate pressure increase slowly with temperature up to 200 degrees C.; from 200 degrees to 360 degrees C. they increase rapidly; above 360 degrees C. solubility is pressure dependent, increasing steadily at high pressure and decreasing slightly at moderate pressure due to the formation of a vapor phase. The pH has slight effect on the ionic solubility of silica in the range from pH 1 to ph 9 at low temperature. The effect of other components on the solubility of silica is probably subordinate to that of temperature above 200 degrees C., but becomes increasingly important as the temperature falls below that point. Most jasperoid bodies form by both replacement and silica deposition in voids, with replacement dominant during the early phase, and precipitation dominant during later phases. Replacement of limestone by silica is favored by relatively low temperature acid solutions, and the presence of CO 2 . As limestone dissolves, Ca ions are released to promote the precipitation of colloidal silica. Acid solutions then diffuse through this gelatinous film to continue dissolving limestone behind it; the Ca ions diffusing outward cause the precipitation of more colloidal silica at the solution-gel interface. As the gel mass ages, it shrinks, hardens, and ruptures. More silica is then deposited in the fractures. Eventually the gel crystallizes to a dense mass of aphanitic quartz and chalcedony, with shrinkage cracks and vugs filled or coated with younger coarse-grained quartz and other minerals that have been deposited directly from solution. The theory that relatively low temperature favors the formation of jasperoid replacement bodies in carbonate rocks, and high temperature inhibits their formation, offers an explanation for the gap that is observed in some districts between contact metasomatic lime silicates and siliceous replacement of limestone . This gap is characterized by the lack of any reaction between limestone and silica-bearing solutions moving through it.

Economic Geology↗
USGS1978

Origin of a South Texas roll-type uranium deposit; I, Alteration of iron-titanium oxide minerals

The detrital Fe-Ti oxide minerals and their authigenic alteration products in samples from cores spanning 1.7 km across a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, south Texas, record important information on host-rock preparation and on development of the altered tongue of the deposit. In reduced rock, in front of and enveloping the altered tongue, iron disulfide minerals (pyrite and marcasite) have partially to completely replaced titanomagnetite and, to a lesser extent, titanohematite. Subsequent oxidation of these sulfidized Fe-Ti oxides, by processes that formed the altered tongue and uranium roll, produced ferric oxide and hydroxide phases (limonite) pseudomorphous after the sulfides. Fe-Ti oxides 1.0 km updip from the roll front were never sulfidized; titanomagnetite (partly replaced by hematite) and martite constitute nearly half of the heavy mineral fraction and limonite is absent. Oxidized rocks 210 m and closer to the nose of the roll front, however, are nearly devoid of titanomagnetite and contain abundant limonite. The redox interface that bounds the altered tongue, therefore, moved more than 210 m but less than 1.0 km. Detrital Fe-Ti oxide minerals are increasingly sulfidized in the downdip direction indicating that initial sulfidizaton was more intense in that direction. Organic carbon content is uniformly very low throughout the host sandstone, which implies that heterotrophic sulfate-reducing bacteria were not involved in the generation of sulfide. The H 2 S for the initial sulfidization may have been derived from oil and gas in formations that underlie the Catahoula Tuff. The H 2 S probably invaded the Catahoula along a fault that is 1.5 km downdip from the present roll front.

Texas↗
USGS1989

A reinterpretation of the δD H 2 O of inclusion fluids in contemporaneous quartz and sphalerite, Creede mining district, Colorodo: a generic problem for shallow orebodies?

Water extracted from fluid inclusions in quartz from shallow epithermal ore deposits often has a hydrogen isotope composition (δD) different from that of water extracted from inclusions in associated minerals. This difference is usually attributed to the involvement of primary fluids from multiple sources. Isotopic and homogenization and freezing temperature determinations on fluid inclusions from contemporaneous quartz and sphalerite from the epithermal, silver and base metal orebodies of the OH vein, Creede district, Colorado, suggest an alternative explanation. In near-surface deposits, differences between δD H 2 O of inclusion fluids in ore minerals and quartz may result, instead, from contamination during extraction of the fluids contained in primary inclusions by shallow ground water trapped in pseudosecondary inclusions in quartz. Quartz from the OH vein contains two principal petrographically distinct populations of fluid inclusions: primary and pseudosecondary. The primary inclusions have salinities ranging from 5 to 10 equiv wt percent NaCl, and the salinities of pseudosecondary inclusions cluster between 0 and 1 percent. Primary inclusions in quartz from one locality have a measured δD H 2 O value of -69 per mil, while pseudosecondary inclusions at the same locality have a δD H 2 O value of -102 per mil. Both salinity and isotopic values for primary inclusions in quartz are similar to those for primary inclusions in contemporaneous sphalerite. Homogenization temperatures for primary and pseudosecondary inclusions in quartz range from 191° to 280° C and from 199° to 278° C, respectively. The δD H 2 O value measured on fluid inclusions from bulk crystals ranges between -97 and -85 per mil and represents a mixture of fluids from both primary and pseudosecondary inclusions. We interpret the data to indicate that one or more episodes of abrupt incursion of cooler, overlying ground water into the ore zone caused thermal cracking of the quartz crystals during the time interval of mineralization. Subsequent healing of the fractures trapped heated, low-salinity ground water in pseudosecondary inclusions. The abrupt incursions of overlying ground water are speculated to have resulted from either collapse of a transient vapor-dominated region of the ore zone, or catastrophic venting of the system through hydrothermal eruption(s). The unusually high contrast between the salinities of the ore-depositing fluids and the ground water overlying the ore zone allowed recognition of this phenomenon at Creede. It is likely, however, that Creede is not unique. Similar phenomena may be common in shallow ore zones where rapid fluctuation of an interface between a deep, high-temperature thermal plume and an overlying, cooler ground water may be expected to occur. Careful study of the origins of fluid inclusions, particularly in quartz, is essential to characterize the primary ore fluids and to assess the role of ground water in the hydrology of shallow ore deposits.

Colorado↗
USGS1993

Origin and significance of tourmaline-rich rocks in the Broken Hill district, Australia

Tourmaline-rich rocks are widespread minor lithologies within the Early Proterozoic Willyama Supergroup in the Broken Hill district, Australia. Tourmaline concentrations occur in strata-bound and local stratiform tourmalinites, clastic metasedimentary rocks, quartz-gahnite lode rocks, stratiform Pb-Zn-Ag sulfide ores, garnet quartzites, strata-bound scheelite deposits, quartz-tourmaline nodules, discordant quartz veins, and granitic pegmatites. Most of the tourmaline-rich rocks are within the Broken Hill Group that hosts the main Pb-Zn-Ag ores.At the Globe mine along the northeast end of the main lodes, tourmalinites are closely associated with Pb-Zn-Ag mineralization and in places are interbedded with Mn-rich garnet quartzites. Galena and other ore minerals occur locally in the cores of recrystallized tourmaline grains in these tourmalinites, indicating that tourmaline and sulfides were present together prior to deformation and high-grade metamorphism. Electron microprobe analyses of tourmalines intergrown with Fe sulfides at the Globe mine show Mg-rich compositions relative to tourmalines in sulfide-free assemblages from the same area, suggesting early (premetamorphic) introduction of boron and Mg enrichment of tourmaline by sulfide-silicate reactions during metamorphism.Combined field and geochemical data indicate that the district tourmalinites represent normal clastic sediments that were metasomatically altered by boron-rich hydrothermal fluids at or below the sediment-water interface. Whole-rock chemical analyses of 33 tourmaline-rich rocks show linear trends of data for major and trace elements that closely resemble the trends observed for unmineralized elastic metasedimentary rocks of the district. Average Fe/Al, Mg/Al, Na/Al, and Ti/Al molar ratios of the tourmaline-rich rocks and clastic metasediments are very similar; the average K/Al molar ratio of the tourmaline-rich rocks is significantly lower than that of the clastic metasediments, reflecting the loss of K during tourmalinite formation. Chondrite-normalized patterns of rare earth elements (REE) in the quartz-rich tourmalinites are generally similar to those of the clastic metasediments, except for minor depletions of light REE; local positive and negative Ce anomalies suggest tourmalinite formation in the presence of seawater or a seawater-derived pore fluid. The geochemical data imply relative immobility of Al, Ti, Cr, and heavy REE during hydrothermal alteration and later metamorphism. Boron isotope analyses of 52 tourmaline separates show a total range of delta 11 B values from -26.8 to -17.0 per mil. Fine-grained, euhedral, nonpoikilitic tourmalines from tourmalinites in the andalusite-muscovite zone in the northern part of the district (e.g., Black Prince mine) have delta 11 B values from -21 to -17 per mil, whereas coarse granoblastic and poikilo-blastic tourmalines from the sillimanite and two-pyroxene granulite zones in the southern part of the district (e.g., Globe mine) have delta 11 B values of-24 to -19 per mil. Tourmalines in strongly retrogressed tourmalinites have delta 11 B values from about -27 to -20 per mil. The observed variations in delta 11 B are consistent with prograde and retrograde metamorphic fractionation of boron isotopes, in which the fluid phase is preferentially enriched in the heavier isotope ( 11 B). Premetamorphic hydrothermal fluids that deposited the Black Prince tourmalinites had delta 11 B values of-8 to -5 per mil at 200 degrees to 300 degrees C, suggesting a boron source from nonmarine evaporite borates.Tourmalinites in the Broken Hill district apparently formed by the same submarine hydrothermal processes as the main Pb-Zn-Ag lodes and the siliceous ferromanganese protoliths of the garnet quartzites. In our model, the hydrothermal system(s) acquired abundant boron by leaching evaporitic borates within the Thackaringa Group, the stratigraphic sequence that underlies the Broken Hill Group and most of the tourmaline concentrations. We suggest that evaporites of the Thackaringa Group provided a source of readily extractable boron for formation of the tourmalinites and also the source of the fluoride, sulfur, and perhaps the carbonate in the main lodes; such evaporites may have been critical for increased metal chloride complexing and transport necessary for deposition of the high-grade Pb-Zn-Ag ores. The Broken Hill deposit may have formed contemporaneously with the Mount Isa and McArthur River Pb-Zn-Ag deposits in similar evaporite-bearing sequences during widespread Early Proterozoic continental rifting.

Economic Geology↗
USGS1996

Significance of tourmaline-rich rocks in the North Range group of the Cuyuna iron range, east-central Minnesota

Concentrations of tourmaline in Early Proterozoic metasedimentary rocks of the Cuyuna iron range, east-central Minnesota, provide a basis for redefinition of the evolutionary history of the area. Manganiferous iron ore forms beds within the Early Proterozoic Trommald Formation, between thick-bedded granular iron-formation having shallow-water alepositional attributes and thin-bedded, nongranular iron-formation having deeper water attributes. These manganese-rich units were previously assumed to be sedimentary in origin. However, a reevaluation of drill core and mine samples from the Cuyuna North range has identified strata-bound tourmaline and tourmalinite, which has led to a rethinking of genetic models for the geology of the North range. We interpret the tourmaline-rich rocks of the area to be a product of submarine-hydrothermal solutions flowing along and beneath the sediment-seawater interface. This model for the depositional environment of the tourmaline is supported by previously reported mineral assemblages within the Trommald Formation that comprise aegirine; barium feldspar; manganese silicates, carbonates, and oxides; and Sr-rich barite veins.In many places, tourmaline-rich metasedimentary rocks and tourmalinites are associated locally with strata-bound sulfide deposits. At those localities, the tourmaline-rich strata are thought to be lateral equivalents of exhalative sulfide zones or genetically related subsea-floor replacements. On the basis of the occurrence of the tourmaline-rich rocks and tourmalinites, and on the associated minerals, we suggest that there is a previously unrecognized potential for sediment-hosted sulfide deposits in the Cuyuna North range.

Economic Geology↗
USGS1997

Environment of ore deposition in the creede mining district, San Juan Mountains, Colorado: Part V. Epithermal mineralization from fluid mixing in the OH vein

Detailed fluid inclusion studies on coarse-grained sphalerite from the OH vein, Creede, Colorado, have shown that the abrupt color changes between growth zones correspond to abrupt changes in the nature of the ore fluids. Within each growth zone, however, the composition of the fluids remained constant. The base of a distinctive orange-brown growth zone marks a sharp increase in both temperature and salinity relative to the preceding yellow-white zone. The orange-brown growth zone can be correlated along much of the vein and is believed to represent a time-stratigraphic interval. Along the vein, temperatures and salinities of fluid inclusions within this interval show a systematic decrease from about 285??C and 11.5 wt percent NaCl equiv near the base of the vein to about 250??C and 8 wt percent NaCl equiv, respectively, near the top of the vein. The iron concentration of this sphalerite growth zone shows a similar pattern, decreasing from about 2.8 to 1.2 mole percent FeS. When plotted on an enthalpy-salinity diagram, the fluid inclusion data define a spatial trend indicating the progressive mixing of deeply circulating hydrothermal brines with overlying, dilute ground waters. The hydrothermal brines entered the OH vein from below at a temperature, salinity, and density of approximately 285??C, 11.5 wt percent NaCl equiv, and 860 kg/m3, respectively, whereas the overlying ground waters appear to have been preheated to roughly 150??C and had an assumed salinity of 0 wt percent and a density of 920 kg/m3. The greater density of the heated ground water promoted mixing with the hydrothermal brine within the open fractures, causing sphalerite deposition. Although there were also episodes of boiling during vein mineralization, boiling appears unimportant for this sphalerite. Isotopic evidence and geochemical modeling studies also indicate that mixing was the depositional mechanism for sphalerite. An important aspect of the mixing hydrology of the Creede system involves an aquitard overlying the OH vein. This low permeability zone restricted the flow of ground water into the vein from above and forced the upwelling hydrothermal fluids to flow laterally along the vein. The mixing environment thus occurred along the interface between a deeply circulating hydrothermal convection cell and a topographically driven shallow ground-water system.

Economic Geology↗
USGS1997

Element distribution patterns in the ordovician Galena group, Southeastern Minnesota: Indicators of fluid flow and provenance of terrigenous material

As part of a regional geochemical investigation of lower Paleozoic strata in the Hollandale embayment of southeastern Minnesota, elemental concentrations in acid-insoluble residues were determined for carbonate rock in the Middle Ordovician Galena Group. Elemental distribution patterns within the insoluble residues, particularly those of Ti, Al, and Zr, show that the Wisconsin dome and the Wisconsin arch, which contributed sediment to the embayment prior to Galena time, continued as weak sources of sediment during this period. In contrast, trace metals commonly associated with Mississippi Valley-type lead-zinc mineralization, including Pb, Zn, Cu, Ag, Ni, Co, As, and Mo, show dispersal patterns that are independent of those associated with primary depositional phenomena. These trace metals are concentrated in southern Minnesota in carbonate rocks near the interface between limestone- and dolostone-dominated strata. Dispersal patterns imply that the metals were carried by a north-flowing regional ground-water system. The results show that the geochemical attributes of insoluble residues can be used to distinguish provenance and transport directions of primary sediments within a depositional basin from effects of subsequent regional ground-water flow systems.

Economic Geology↗
USGS2007

Crossing disciplines and scales to understand the critical zone

The Critical Zone (CZ) is the system of coupled chemical, biological, physical, and geological processes operating together to support life at the Earth's surface. While our understanding of this zone has increased over the last hundred years, further advance requires scientists to cross disciplines and scales to integrate understanding of processes in the CZ, ranging in scale from the mineral-water interface to the globe. Despite the extreme heterogeneities manifest in the CZ, patterns are observed at all scales. Explanations require the use of new computational and analytical tools, inventive interdisciplinary approaches, and growing networks of sites and people.

Elements↗
USGS2016

Where is the hot rock and where is the ground water— Using CSAMT to map beneath and around Mount St. Helens

We have observed several new features in recent controlled-source audio-frequency magnetotelluric (CSAMT) soundings on and around Mount St. Helens, Washington State, USA. We have identified the approximate location of a strong electrical conductor at the edges of and beneath the 2004–08 dome. We interpret this conductor to be hot brine at the hot-intrusive-cold-rock interface. This contact can be found within 50 meters of the receiver station on Spine 5, which extruded between April and July of 2005. We have also mapped separate regional and glacier-dome aquifers, which lie one atop the other, out to considerable distances from the volcano.

Washington↗
USGS1969

Flow of a disperse emulsion of crude oil in water in porous media

It has been suggested that oil migrates through reservoir sands in the form of a fine, disperse emulsion of oil in water, and that oil accumulations occur where the stream enters finer-grained rock such as silt or shale. In order to investigate the possible mechanisms, stable emulsions of oil in water were prepared without the use of wetting agents. They consisted of droplets 1/2 to 1-1/2 microns in diameter, in a concentration of 20 to 40 parts of oil per million of water. These emulsions passed freely through filter paper and ordinary passed freely through filter paper and ordinary sand. A plastic tube containing glass beads of 200-microns diameter included a bed 1/2-cm thick of crushed beads 37 to 88 microns in diameter. When the emulsion was passed through this tube, up to 80 percent of the oil was screened out at the coarse-fine interface. The amount removed depended on the contrast in grain size, the nature and the preferential wettability of the media. Similar results occurred when quartz sand was used as the coarse, and crushed sand as the fine medium. This screening did not occur as a result of capillary effects., because the pores were many times the diameter of the droplets. The oil collected as a result of flocculation of the droplets into strings and clusters., and the oil saturation in the pores consisted of masses of droplets with very little coalescence. Possibly electrostatic forces are more important Possibly electrostatic forces are more important than capillary in the behavior of fine, disperse, oil-in-water emulsions. our current ideas on multiphase flow in porous media may not apply to disperse emulsions.

Conference Paper↗
USGS1997

Kansas geological survey's Digital Petroleum Atlas (DPA) project

The Kansas Digital Petroleum Atlas (DPA) is a new approach to generating and publishing petroleum reservoir, field, play and basin studies. Atlas products are available anywhere in the world using a standard point-and-click World-Wide-Web interface. All information and technology in the DPA can be accessed, manipulated and downloaded in order to provide efficient transfer of the technology for client-defined solutions. The DPA design provides a dynamic product that is constantly evolving through new information structures, the latest research results, and incorporation of additional data. Through complete and flexible user access to both interpretative products and underlying reservoir and well data, the DPA significantly alters the relationship between research results, data access, and the transfer of technology.

Proceedings - SPE Annual Technical Conference and ↗
USGS2008

Determination of dominant biogeochemical processes in a contaminated aquifer-wetland system using multivariate statistical analysis

Determining the processes governing aqueous biogeochemistry in a wetland hydrologically linked to an underlying contaminated aquifer is challenging due to the complex exchange between the systems and their distinct responses to changes in precipitation, recharge, and biological activities. To evaluate temporal and spatial processes in the wetland-aquifer system, water samples were collected using cm-scale multi-chambered passive diffusion samplers (peepers) to span the wetland-aquifer interface over a period of 3 yr. Samples were analyzed for major cations and anions, methane, and a suite of organic acids resulting in a large dataset of over 8000 points, which was evaluated using multivariate statistics. Principal component analysis (PCA) was chosen with the purpose of exploring the sources of variation in the dataset to expose related variables and provide insight into the biogeochemical processes that control the water chemistry of the system. Factor scores computed from PCA were mapped by date and depth. Patterns observed suggest that (i) fermentation is the process controlling the greatest variability in the dataset and it peaks in May; (ii) iron and sulfate reduction were the dominant terminal electron-accepting processes in the system and were associated with fermentation but had more complex seasonal variability than fermentation; (iii) methanogenesis was also important and associated with bacterial utilization of minerals as a source of electron acceptors (e.g., barite BaSO 4 ); and (iv) seasonal hydrological patterns (wet and dry periods) control the availability of electron acceptors through the reoxidation of reduced iron-sulfur species enhancing iron and sulfate reduction.

Journal of Environmental Quality↗
USGS2015

Importance of the colmation layer in the transport and removal of cyanobacteria, viruses, and dissolved organic carbon during natural lake-bank filtration

This study focused on the importance of the colmation layer in the removal of cyanobacteria, viruses, and dissolved organic carbon (DOC) during natural bank filtration. Injection-and-recovery studies were performed at two shallow (0.5 m deep), sandy, near-shore sites at the southern end of Ashumet Pond, a waste-impacted, kettle pond on Cape Cod, MA, that is subject to periodic blooms of cyanobacteria and continuously recharges a sole-source drinking-water aquifer. The experiment involved assessing the transport behaviors of bromide (conservative tracer), Synechococcus sp. IU625 (cyanobacterium, 2.6 ± 0.2 µm), AS-1 (tailed cyanophage, 110 nm long), MS2 (coliphage, 26 nm diameter), and carboxylate-modified microspheres (1.7 µm diameter) introduced to the colmation layer using a bag-and-barrel (Lee-type) seepage meter. The injectate constituents were tracked as they were advected across the pond water–groundwater interface and through the underlying aquifer sediments under natural-gradient conditions past push-point samplers placed at ∼30-cm intervals along a 1.2-m-long, diagonally downward flow path. More than 99% of the microspheres, IU625, MS2, AS-1, and ∼44% of the pond DOC were removed in the colmation layer (upper 25 cm of poorly sorted bottom sediments) at two test locations characterized by dissimilar seepage rates (1.7 vs. 0.26 m d −1 ). Retention profiles in recovered core material indicated that >82% of the attached IU625 were in the top 3 cm of bottom sediments. The colmation layer was also responsible for rapid changes in the character of the DOC and was more effective (by three orders of magnitude) at removing microspheres than was the underlying 20-cm-thick segment of sediment.

Massachusetts↗
USGS1985

Geophysical techniques for reconnaissance investigations of soils and surficial deposits in mountainous terrain

Two techniques were assessed for their capabilities in reconnaissance studies of soil characteristics: depth to the water table and depth to bedrock beneath surficial deposits in mountainous terrain. Ground-penetrating radar had the best near-surface resolution in the upper 2 m of the profile and provided continuous interpretable imagery of soil profiles and bedrock surfaces. Where thick colluvium blankets side slopes, the GPR could not consistently define the bedrock interface. In areas with clayey or shaley sediments, the GPR is also more limited in defining depth and is less reliable. Seismic refraction proved useful in determining the elevation of the water table and depth to bedrock, regardless of thickness of overlying material, but could not distinguish soil-profile characteristics.

Soil Science Society of America Journal↗
USGS2008

Measuring the electrical properties of soil using a calibrated ground-coupled GPR system

Traditional methods for estimating vadose zone soil properties using ground penetrating radar (GPR) include measuring travel time, fitting diffraction hyperbolae, and other methods exploiting geometry. Additional processing techniques for estimating soil properties are possible with properly calibrated GPR systems. Such calibration using ground-coupled antennas must account for the effects of the shallow soil on the antenna's response, because changing soil properties result in a changing antenna response. A prototype GPR system using ground-coupled antennas was calibrated using laboratory measurements and numerical simulations of the GPR components. Two methods for estimating subsurface properties that utilize the calibrated response were developed. First, a new nonlinear inversion algorithm to estimate shallow soil properties under ground-coupled antennas was evaluated. Tests with synthetic data showed that the inversion algorithm is well behaved across the allowed range of soil properties. A preliminary field test gave encouraging results, with estimated soil property uncertainties (????) of ??1.9 and ??4.4 mS/m for the relative dielectric permittivity and the electrical conductivity, respectively. Next, a deconvolution method for estimating the properties of subsurface reflectors with known shapes (e.g., pipes or planar interfaces) was developed. This method uses scattering matrices to account for the response of subsurface reflectors. The deconvolution method was evaluated for use with noisy data using synthetic data. Results indicate that the deconvolution method requires reflected waves with a signal/noise ratio of about 10:1 or greater. When applied to field data with a signal/noise ratio of 2:1, the method was able to estimate the reflection coefficient and relative permittivity, but the large uncertainty in this estimate precluded inversion for conductivity. ?? Soil Science Society of America.

Conference Paper↗