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At least 1,117 records · Page 62Linked to original sources

Hydrogeology and simulated groundwater availability in reaches 3 and 4 of the Washita River aquifer, southern Oklahoma, 1980–2017

The 1973 Oklahoma Groundwater Law (Oklahoma Statutes §82–1020.5) requires that the Oklahoma Water Resources Board conduct hydrologic investigations of the State’s aquifers to determine the maximum annual yield for each groundwater basin. Because more than 20 years have elapsed since the final order was issued, the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, conducted an updated hydrologic investigation and evaluated the effects of potential groundwater withdrawals on groundwater flow and availability in reaches 3 and 4 of the Washita River aquifer in southern Oklahoma for a study period spanning 1980–2017. A hydrogeologic framework and conceptual model were developed to guide the construction and calibration of a numerical model of the Washita River aquifer. The numerical model was calibrated to water-table-altitude observations at selected wells, base-flow observations at selected U.S. Geological Survey streamgages, and the conceptual-model recharge. Three types of groundwater-availability scenarios were run using the calibrated numerical model. These scenarios were used to (1) estimate equal-proportionate-share pumping rates, (2) quantify the potential effects of projected well withdrawals on groundwater storage over a 50-year period, and (3) simulate the potential effects of a hypothetical 10-year drought. With Washita River main-stem inflows, the 20-, 40-, and 50-year equal-proportionate-share pumping rates under normal recharge conditions were about 3.08 acre-feet per acre per year for reach 3 and about 3.80 acre-feet per acre per year for reach 4. Projected 50-year pumping scenarios were used to simulate the effects of modified well withdrawal rates. Because well withdrawals were less than 1 percent of the calibrated numerical-model water budget, changes to the well pumping rates had little effect on Washita River base flows and groundwater storage in the Washita River aquifer. A hypothetical 10-year drought scenario was used to simulate the potential effects of a prolonged period of reduced recharge on groundwater storage. Groundwater storage at the end of the drought period was 4.6 percent less than the groundwater storage of the calibrated numerical model at the end of the drought period.

Oklahoma↗

DDT and related compounds in pore water of shallow sediments on the Palos Verdes Shelf, California, USA

For nearly two and a half decades following World War II, production wastes from the world's largest manufacturer of technical DDT (1-chloro-4-[2,2,2-trichloro-1-(4-chlorophenyl)ethyl]benzene) were discharged into sewers of Los Angeles County. Following treatment, the wastes were released via a submarine outfall system to nearshore coastal waters where a portion accumulated in shallow sediments of the Palos Verdes Shelf (PVS). An investigation of the pore-water geochemistry of DDT-related compounds (DDX) was undertaken in an effort to understand factors controlling the rate of reductive dechlorination (RDC) of the major DDT degradate, 4,4′-DDE (1-chloro-4-[2,2-dichloro-1-(4-chlorophenyl)ethenyl]benzene). Equilibrium matrix-solid phase microextraction (matrix-SPMEeq) combined with automated thermal desorption-gas chromatography/mass spectrometry (TDGC/MS) was used to determine freely dissolved concentrations of ten DDX analytes in sediment cores collected from three locations on the PVS (stations 3C, 6C, 8C, which are 7 km, 2 km, and 0 km, respectively, downcurrent from the outfall system). Pore-water concentrations (pM) of the principal DDX compounds involved in RDC were: 3C-DDE: 6.0–24, DDMU (1-chloro-4-[2-chloro-1-(4-chlorophenyl)ethenyl]benzene): 11–160, DDNU (1-chloro-4-[1-(4-chlorophenyl)ethenyl]benzene): 1.8–68; 6C-DDE: 5.6–170, DDMU: 5.6–177, DDNU: 1.7–87; 8CDDE: 27–212, DDMU: 31–403, DDNU: 5.5–89. Variations in the spatial distribution of DDX analytes in pore water reflect several factors including proximity to the outfalls, RDC reaction rates, and natural variability in sedimentation and post-depositional transport processes. A comparison of pore-water data produced using matrix-SPME eq /TD-GC/MS and whole-core squeezing/solvent extraction/liquid injection-GC/MS indicates that the majority of the DDE in the upper sediment column (≤about 10 cm) is associated with dissolved/colloidal organic matter. Below that depth, freely-dissolved DDE predominates. The principal organic geochemical phase controlling sorption of DDE in PVS sediments are residual hydrocarbons, the vast majority of which originated from petroleum refinery wastes. Organic carbon-normalized sediment-water distribution coefficients (KOC) were calculated from solid-phase and pore-water concentrations of DDX and organic carbon. Log K OC values (L/kg) were relatively invariant across the shelf and with depth in the sediment column. Shelf-wide compound-specific coefficients (log K OC ) were: DDE: 7.5 ± 0.11, DDMU: 6.92 ± 0.13, DDNU: 6.37 ± 0.19. The spatial uniformity of K OC means that biological exposure and availability of the DDX compounds can, in principle, be estimated from solid-phase chemical measurements.

California↗

A method for nitrate collection for δ 15 N and δ 18 O analysis from waters with low nitrate concentrations

Recently, methods have been developed to analyze NO3- for δ15N and δ18O, improving our ability to identify NO3- sources and transformations. However, none of the existing methods are suited for waters with low NO3- concentrations (0.7-10 µM). We describe an improved method for collecting and recovering NO3- on exchange columns. To overcome the lengthy collection loading times imposed by the large sample volumes (7-70 L), the sample was prefiltered (0.45 µm) with a large surface area filter. Switching to AG2X anion resin and using a coarser mesh size (100-200) than previous methods also enhanced sample flow. Placement of a cation column in front of the anion column minimized clogging of the anion column by dissolved organic carbon (DOC) accumulation. This also served to minimize transfer of unwanted oxygen atoms from DOC to the 18O portion of the NO3- sample, thereby contaminating the sample and shifting δ18O. The cat-AG2X method is suited for on-site sample collection, making it possible to collect and recover NO3- from low ionic strength waters with modest DOC concentrations (80-800 µM), relieves the investigator of transporting large volumes of water back to the laboratory, and offers a means of sampling rain, snow, snowmelt, and stream samples from access-limited sites.

Canadian Journal of Fisheries and Aquatic Sciences↗

Hydrologic drought of water year 2011 compared to four major drought periods of the 20th century in Oklahoma

Water year 2011 (October 1, 2010, through September 30, 2011) was a year of hydrologic drought (based on streamflow) in Oklahoma and the second-driest year to date (based on precipitation) since 1925. Drought conditions worsened substantially in the summer, with the highest monthly average temperature record for all States being broken by Oklahoma in July (89.1 degrees Fahrenheit), June being the second hottest and August being the hottest on record for those months for the State since 1895. Drought conditions continued into the fall, with all of the State continuing to be in severe to exceptional drought through the end of September. In addition to effects on streamflow and reservoirs, the 2011 drought increased damage from wildfires, led to declarations of states of emergency, water-use restrictions, and outdoor burning bans; caused at least $2 billion of losses in the agricultural sector and higher prices for food and other agricultural products; caused losses of tourism and wildlife; reduced hydropower generation; and lowered groundwater levels in State aquifers. The U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, conducted an investigation to compare the severity of the 2011 drought with four previous major hydrologic drought periods during the 20th century – water years 1929–41, 1952–56, 1961–72, and 1976–81. The period of water years 1925–2011 was selected as the period of record because few continuous record streamflow-gaging stations existed before 1925, and gaps in time existed where no streamflow-gaging stations were operated before 1925. In water year 2011, statewide annual precipitation was the 2d lowest, statewide annual streamflow was 16th lowest, and statewide annual runoff was 42d lowest of those 87 years of record. Annual area-averaged precipitation totals by the nine National Weather Service climate divisions from water year 2011 were compared to those during four previous major hydrologic drought periods to show how precipitation deficits in Oklahoma varied by region. The nine climate divisions in Oklahoma had precipitation in water year 2011 ranging from 43 to 76 percent of normal annual precipitation, with the Northeast Climate Division having the closest to normal precipitation and the Southwest Climate Division having the greatest percentage of annual deficit. Based on precipitation amounts, water year 2011 ranked as the second driest of the 1925–2011 period, being exceeded only in one year of the 1952 to 1956 drought period. Regional streamflow patterns for water year 2011 indicate that streamflow in the Arkansas-White-Red water resources region, which includes all of Oklahoma, was relatively large, being only the 26th lowest since 1930, primarily because of normal or above-normal streamflow in the northern part of the region. Twelve long-term streamflow-gaging stations with periods of record ranging from 67 to 83 years were selected to show how streamflow deficits varied by region in Oklahoma. Statewide, streamflow in water year 2011 was greater than streamflows measured in years during the drought periods of 1929–41, 1952–56, 1961–72, and 1976–81. The hydrologic drought worsened going from the northeast toward the southwest in Oklahoma, ranging from 140 percent (above normal streamflow) in the northeast, to 13 percent of normal streamflow in southwestern Oklahoma. The relatively low streamflow in 2011 resulted in 83.3 percent of the statewide conservation storage being available at the end of the water year in major reservoirs, similar to conservation storage in the preceding severe drought year of 2006. The ranking of streamflow as the 16th smallest for the 1925–2011 period, despite precipitation being ranked the 2d smallest, may have been caused, in part, by the relatively large streamflow in northeastern Oklahoma during water year 2011.

Oklahoma↗

Flow-frequency characteristics of Vermont streams

The safe and economical design of infrastructure in and near waterways and the effective management of flood-hazard areas require information on streamflow that may not be readily available. This report provides estimates of flow-frequency characteristics for gaged streams in Vermont and describes methods for estimating flow-frequency characteristics for ungaged streams. The flow-frequency characteristics investigated are the magnitude of peak discharges at recurrence intervals of 2, 5, 10, 25, 50, 100, and 500 years, and the magnitude of daily-mean discharges exceeded 25, 50, and 75 percent of the time. Peak-flow frequency characteristics for gaged streams were computed following the guidelines in Bulletin 17B of the U.S. Interagency Advisory Committee on Water Data. To determine the peak-flow exceedance probabilities at stream-gaging stations in Vermont, a new generalized skew coefficient map for the State was developed. This new map has greater resolution and more current data than the existing National map. The standard error of the new map is 0.269. Two methods of extending streamflow record were applied to improve estimates of peak-flow frequency for streams with short flow records (10 to 15 years) in small drainage areas (sites less than 15 square miles). In the first method, a two-station comparison, data from a long-record site was used to adjust the frequency characteristics at the short-record site. This method was applied to 31 crest-stage gages--stations at which only instantaneous peak discharges are determined--in Vermont. The second method used rainfall-runoff modeling. Precipitation and evapotranspiration data from 1948 to 1999 for numerous climate data-collection sites were used as input to a model to simulate flows at 10 stream-gaging stations in Vermont. Also, methods are described to estimate flow-frequency characteristics for ungaged and unregulated rural streams in Vermont. The peak-flow estimating methods were developed by generalized-least-squares regression procedures with data from 138 U.S. Geological Survey stream-gaging stations in Vermont and in adjacent areas of New York, New Hampshire, Massachusetts, and Quebec. The flow-duration (daily flow exceeded a given percentage of the time) estimating methods were developed by ordinary-least-squares regression procedures with data from 81 stream-gaging stations in Vermont and adjacent states.

Vermont↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 1 (Part A)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 2 (Part B)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 3 (Part C)

This report contains papers presented at the seventh Technical Meeting of the U.S. Geological Survey (USGS), Toxic Substances Hydrology (Toxics) Program. The meeting was held March 8-12, 1999, in Charleston, South Carolina. Toxics Program Technical Meetings are held periodically to provide a forum for presentation and discussion of results of recent research activities. The objectives of these meetings are to: Present recent research results to essential stakeholders, Encourage synthesis and integrated interpretations among scientists with different expertise who are working on a contamination issue, and Promote exchange of ideas among scientists working on different projects and issues within the Toxics Program. The Proceedings is published in three volumes. Volume 1 contains papers that report on results of research on contamination from hard-rock mining. Results include research on contamination from hard rock mining in arid southwest alluvial basins, research on hard rock mining in mountainous terrain, and progress from the USGS Abandoned Mine Lands Initiative. This Initiative is designed to develop a watershed-based approach to characterize and remediate contamination from abandoned mine lands and transfer technologies to Federal land management agencies and stakeholders. Volume 2 contains papers on contamination of hydrologic systems and related ecosystems. The papers discuss research on the response of estuarine ecosystems to contamination from human activities. They include research on San Francisco Bay; mercury contamination of aquatic ecosystems; and investigation of the occurrence, distribution, and fate of agricultural chemicals in the Mississippi River Basin. This volume also contains results on development and reconnaissance testing of new methods to detect emerging contaminants in environmental samples. Volume 3 contains papers on subsurface contamination from point sources. The papers discuss research on: hydrocarbons and fuel oxygenates at gasoline release sites; ground-water contamination by crude oil; complex contaminant mixtures from treated wastewater discharges; waste disposal and subsurface transport of contaminants in arid environments; ground water and surface water affected by municipal landfill leachate; natural attenuation of chlorinated solvents; and characterizing flow and transport in fractured rock aquifers. In all, the more than 175 papers contained in this proceedings reflect the contributions of more than 350 scientists who are co-authors. These scientists are from across the USGS, as well as from universities, other Federal and State agencies, and industry.

Water-Resources Investigations Report↗

Hydrology of Yucca Mountain and vicinity, Nevada-California — Investigative results through mid-1983

Yucca Mountain, Nevada, is one of several sites under consideration for construction of the first repository for high-level nuclear waste. The climate is arid; few perennial streams are present in the region. Flash floods occasionally occur. The site is underlain by at least 1,800 meters of volcanic tuffs of Tertiary age; limestones and dolomites of Paleozoic age underlie much of the surrounding region, and, together with alluvial deposits, comprise the major aquifers. Yucca Mountain is in the Alkali Flat-Furnace Creek Ranch ground-water subbasin, which is part of the Death Valley ground-water basin. Discharge occurs at Alkali Flat almost entirely by evapotranspiration, and at Furnace Creek Ranch from small springs and seeps. Beneath Yucca Mountain, depth to water ranges from about 460 to 700 meters; the rock under consideration for construction of the repository is in the unsaturated zone. Rate of recharge at Yucca Mountain is small, perhaps much less than 5 millimeters per year. Within the saturated zone, water movement is principally along fractures. The hydraulic gradient is small east (downgradient) of Yucca Mountain, and increases to the north and west. Lack of effective-porosity data presently precludes accurate calculation of flow velocity and travel times.

California, Nevada↗

The environmental occurrence of herbicides: The importance of degradates in ground water

Numerous studies are being conducted to investigate the occurrence, fate, and effects on human health and the environment from the extensive worldwide use of herbicides to control weeds. Few studies, however, are considering the degradates of these herbicides in their investigations. Our study of herbicides in aquifers across Iowa found herbicide degradates to be prevalent in ground water, being detected in about 75% of the wells sampled. With the exception of atrazine, the frequencies of detection in ground water for a given herbicide increased multifold when its degradates were considered. Furthermore, a majority of the measured concentration for a given herbicide was in the form of its degradates—even for a relatively persistent compound such as atrazine. For this study, degradates comprised from 60 to over 99% of a herbicide's measured concentration. Because herbicide degradates can have similar acute and chronic toxicity as their parent compounds, these compounds have environmental significance as well as providing a more complete understanding of the fate and transport of a given herbicide. Thus, it is essential that degradates are included in any type of herbicide investigation.

Iowa↗

Stream water temperature limits occupancy of salamanders in mid-Atlantic protected areas

Stream ecosystems are particularly sensitive to urbanization, and tolerance of water-quality parameters is likely important to population persistence of stream salamanders. Forecasted climate and landscape changes may lead to significant changes in stream flow, chemical composition, and temperatures in coming decades. Protected areas where landscape alterations are minimized will therefore become increasingly important for salamander populations. We surveyed 29 streams at three national parks in the highly urbanized greater metropolitan area of Washington, DC. We investigated relationships among water-quality variables and occupancy of three species of stream salamanders ( Desmognathus fuscus , Eurycea bislineata , and Pseudotriton ruber ). With the use of a set of site-occupancy models, and accounting for imperfect detection, we found that stream-water temperature limits salamander occupancy. There was substantial uncertainty about the effects of the other water-quality variables, although both specific conductance (SC) and pH were included in competitive models. Our estimates of occupancy suggest that temperature, SC, and pH have some importance in structuring stream salamander distribution.

Maryland, Virginia, West Virginia↗

Determination of hydraulic properties in the vicinity of a landfill near Antioch, Illinois

A hydrogeologic investigation was conducted in and around a landfill near Antioch, Illinois, in December 1987. The investigation consisted, in part, of an aquifer test that was designed to determine the hydraulic connection between the hydrogeologic units in the area. The hydrogeologic units consist of a shallow, unconfined, sand and gravel aquifer of variable thickness that overlies an intermediate confining unit of variable thickness composed predominantly of till. Underlying the till is a deep, confined, sand and gravel aquifer that serves as the water supply for the village of Antioch. The aquifer test was conducted in the confined aquifer. Aquifer-test data were analyzed using the Hantush and Jacob method for a leaky confined aquifer with no storage in the confining unit. Calculated transmissivity of the confined aquifer ranged from 1.96x10^4 to 2.52x10^4 foot squared per day and storativity ranged from 2.10x10^-4 to 8.71x10^-4. Leakage through the confining unit ranged from 1.29x10^-4 to 7.84x10^-4 foot per day per foot, and hydraulic conductivity of the confining unit ranged from 3.22x10^-3 to 1.96x10^-2 foot per day. The Hantush method for analysis of a leaky confined aquifer with storage in the confining unit also was used to estimate aquifer and confining-unit properties. Transmissivity and storativity values calculated using the Hantush method are in good agreement with the values calculated from the Hantush and Jacob method. Properties of the confining unit were estimated using the ratio method of Neuman and Witherspoon. The estimated diffusivity of the confining unit ranged from 50.36 to 68.13 feet squared per day, A value for the vertical hydraulic conductivity of the confining unit calculated from data obtained using both the Hantush and the Neuman and Witherspoon methods was within the range of values calculated by the Hantush and Jacob method. The aquifer-test data clearly showed that the confining unit is hydraulically connected to the confined aquifer. The aquifer-test data also indicated that the unconfined aquifer becomes hydraulically connected to the deep sand and gravel aquifer within 24 hours after the start of pumping in the confined aquifer.

Water-Resources Investigations Report↗

Hydrogeology of the surficial aquifer system, Dade County, Florida

An investigation of the surficial aquifer system in Dade County, begun in 1983, is part of a regional study of the aquifer system in southeastern Florida. Test drilling for lithologic samples, flow measurements during drilling, aquifer testing, and analyses of earlier data permitted delineation of the hydraulic conductivity distribution (on hydrogeologic sections), the aquifers in the system, the generalized transmissivity distribution, and interpretation of the ground-water flow system. The surficial aquifer system, in which an unconfined ground-water flow system exists, is composed of the sediments from land surface downward to the top of a regionally extensive zone of sediments of low permeability called the intermediate confining unit. The aquifer system units, which vary in composition from clay-size sediments to cavernous limestone, are hydro stratigraphically divided into the Biscayne aquifer at the top; an intervening semiconfining unit that consists principally of clayey sand; a predominantly gray limestone aquifer in the Tamiami Formation in western and west-central Dade County; and sand or clayey sand near the base of the surficial aquifer system. The base of the surficial aquifer system ranges from a depth of about 175 to 210 feet below land surface in westernmost Dade County to greater than 270 feet in northeastern Dade County. Test drilling and aquifer-test data indicate a complex hydraulic conductivity distribution. Hydraulic conductivities of the very highly permeable zone of the Biscayne aquifer commonly exceed 10,000 feet per day; in the gray limestone aquifer, they range from 210 to 780 feet per day. Transmissivities of the surficial aquifer system vary locally but have a recognizable areal trend. Estimated values generally are about 300,000 feet squared per day or greater in nearly all of central and eastern Dade County. Transmissivity is lower to the west, decreasing to less than 75,000 feet squared per day in western Dade County. High transmissivity usually is associated with thick sections of the Fort Thompson Formation within the Biscayne aquifer. The gray limestone aquifer of the Tamiami Formation has transmissivities that range from 5,800 to 39,000 feet squared per day in western Dade County. The transition from high transmissivity to relatively low transmissivity is often only a few miles wide and coincides with the decrease in thickness of the very highly permeable Fort Thompson Formation, which marks the western boundary of the Biscayne aquifer. More effective drainage as a result of extensive canal systems and large-scale pumping from municipal well fields has greatly altered the predevelopment flow system in eastern Dade County by: (1) eliminating or greatly reducing a seasonal and coastal ground-water ridge; (2) reducing deep circulation; (3) reducing or eliminating seasonal westward movement of ground water; (4) causing accelerated stormwater runoff and short ground-water flow paths; and (5) generally lowering the water table and inducing saltwater intrusion. Under predevelopment conditions in western Dade County, water entered the gray limestone aquifer by lateral movement from Broward and Collier Counties, and by downward seepage from The Everglades and the Biscayne aquifer, and moved southward and southeastward into Dade County to coastal discharge areas. Circulation in the Biscayne aquifer inland also was primarily to the south and southeast. In eastern Dade County, the seasonal ground-water ridge that formed under predevelopment conditions supported both easterly and westerly ground-water flow away from the ridge axis. This seasonal flow created a zone of lower dissolved solids.

Florida↗

Evaluation of pier-scour measurement methods and pier-scour predictions with observed scour measurements at selected bridge sites in New Hampshire, 1995-98

In a previous study, 44 of 48 bridge sites examined in New Hampshire were categorized as scour critical. In this study, the U.S. Geological Survey (USGS) evaluated pier-scour measurement methods and predictions at many of these sites. This evaluation included measurement of pier-scour depths at 20 bridge sites using Ground- Penetrating Radar (GPR) surveys. Pier scour was also measured during floods by teams at 5 of these 20 sites. At 4 of the 20 sites, fixed instruments were installed to monitor scour. At only one bridge site investigated by a team was any pier scour measurable during a flood event. A scour depth of 0.7 foot (0.21 m) was measured at a pier in the channel at the State Route 18 bridge over the Connecticut River in Littleton. Measurements made using GPR and (or) fixed instruments indicated pier scour for six sites. The GPR surveys indicated scour along the side of a pier and further upstream from the nose of a pier that was not detected by flood-team measurements at two sites. Most pier-scour equations selected for this examination were reviewed and published in previous scour investigations. Graphical comparison of residual pier-scour depths indicate that the Shen equation yielded pier-scour depth predictions closest to those measured, without underestimating. Measured depths of scour, however, were zero feet for 14 of the 20 sites. For the Blench-Inglis II equation and the Simplified Chinese equation, most differences between measured and predicted scour depths were within 5 feet. These two equations underpredicted scour for one of six sites with measurable scour. The underprediction, however, was within the resolution of the depth measurements. The Simplified Chinese equation is less sensitive than other equations to velocity and depth input variables, and is one of the few empirical equations to integrate the influence of flow competence, or a measure of the maximum streambed particle size that a stream is capable of transporting, in the computation of pier scour. Absence of a flow-competence component could explain some of the overprediction by other equations, but was not investigated in this study. Measurements of scour during large floods at additional sites are necessary to strengthen and substantiate the application of alternatives to the HEC-18 equation to estimate pier scour at waterway crossings in New Hampshire.

Water-Resources Investigations Report↗

Water-resources activities of the U.S. Geological Survey in Montana, October 1991 through September 1993

Water-resources programs and activities of the U.S. Geological Survey in Montana consist principally of hydrologic-data collection and investigative studies that address water-resource issues. The work is supported by direct Federal funding, by transfer of funds from other Federal agencies, and by joint funding agreements with State or local agencies. The Montana District of the Geological Survey's Water Resources Division conducts its hydrologic work through a District Office in Helena, and Field Headquarters in Helena, Billings, Fort Peck, and Kalispell. Twenty-seven projects are being con- ducted. As outlined in this report, these projects are operated under the general categories of data- collection programs and investigative studies. This report describes the projects funded for fiscal years 1992 and 1993. hi addition, it describes the operations of the Montana District, hydrologic conditions during water year 1992, activities in addition to regular programs, and sources of publications and information. It also lists reports published or released during the preceding 5 years.

Open-File Report↗

Variability in stream chemistry in relation to urban development and biological condition in seven metropolitan areas of the United States, 1999-2004

Beginning in 1999, the U.S. Geological Survey National Water Quality Assessment Program investigated the effects of urban development on stream ecosystems in nine metropolitan study areas across the United States. In seven of these study areas, stream-chemistry samples were collected every other month for 1 year at 6 to 10 sites. Within a study area, the sites collectively represented a gradient of urban development from minimally to highly developed watersheds, based on the percentage of urban land cover; depending on study area, the land cover before urban development was either forested or agricultural. The stream-chemistry factors measured in the samples were total nitrogen, total phosphorus, chloride, and pesticide toxicity. These data were used to characterize the stream-chemistry factors in four ways (hereafter referred to as characterizations)—seasonal high-flow value, seasonal low-flow value, the median value (representing a single integrated value of the factor over the year), and the standard deviation of values (representing the variation of the factor over the year). Aquatic macroinvertebrate communities were sampled at each site to infer the biological condition of the stream based on the relative sensitivity of the community to environmental stressors. A Spearman correlation analysis was used to evaluate relations between (1) urban development and each characterization of the stream-chemistry factors and (2) the biological condition of a stream and the different characterizations of chloride and pesticide toxicity. Overall, the study areas where the land cover before urban development was primarily forested had a greater number of moderate and strong relations compared with the study areas where the land cover before urban development was primarily agriculture; this was true when urban development was correlated with the stream-chemistry factors (except chloride) and when chloride and pesticide toxicity was correlated with the biological condition. Except for primarily phosphorus in two study areas, stream-chemistry factors generally increased with urban development, and among the different characterizations, the median value typically indicated the strongest relations. The variation in stream-chemistry factors throughout the year generally increased with urban development, indicating that water quality became less consistent as watersheds were developed. In study areas with high annual snow fall, the variation in chloride concentrations throughout the year was particularly strongly related to urban development, likely a result of road salt applications during the winter. The relations of the biological condition to chloride and pesticide toxicity were calculated irrespective of urban development, but the overall results indicated that the relations were still stronger in the study areas that had been forested before urban development. The weaker relations in the study areas that had been agricultural before urban development were likely the results of biological communities having been degraded from agricultural practices in the watersheds. Collectively, these results indicated that, compared with sampling a stream at a single point in time, sampling at regular intervals during a year may provide a more representative measure of water quality, especially in the areas of high urban development where water quality fluctuated more widely between samples. Furthermore, the use of "integrated" values of stream chemistry factors may be more appropriate when assessing relations to the biological condition of a stream because the taxa composition of a biological community typically reflects the water-quality conditions over time.

Scientific Investigations Report↗

Sequence stratigraphic framework of upper pliocene to holocene sediments of the Los Angeles Basin, California: Implications for aquifer architecture

Executive Summary Groundwater provides more than one-third of the municipal water supply for the coastal Los Angeles Basin and defining the aquifer architecture is a high priority for ground-water managers. Sequence stratigraphy, the state-of-the-art method for delineating reservoir geometry and continuity in the petroleum industry, is now being incorporated into ground water resource assessments and environmental investigations. By evaluating subsurface data using sequence stratigraphy, the geometry and distribution of aquifer and aquitard sediments are linked to the original depositional processes that formed the sediments. Skyline Ridge, Inc., the U.S. Geological Survey (USGS), in cooperation with Los Angeles County Department of Public Works (LACDPW) and the Water Replenishment District of Southern California (WRDSC) completed an investigation of the Wilmington – Long Beach area by integrating data from new exploratory research boreholes, marine reflection seismic, vintage land reflection seismic, and high-resolution gravity measurements. Sequence stratigraphy is shown to define pathways for saltwater intrusion into freshwater coastal aquifers by integrating preexisting data with (1) the new borehole observations and (2) structural and physical properties data derived from the geophysical measurements. By constructing a series of seismic reflection and well log cross sections (presented as sheets), this investigation further defines and delineates ten sequences of Late Pliocene to Holocene age in the Wilmington – Long Beach area of the Los Angeles Basin. These sequences were first described by Ponti and others (2007), and the implications for sea water intrusion was discussed by Edwards and others (2009a). In addition, this investigation presents regional seismic facies – environment of deposition maps for the five youngest sequences: 1) the Dominquez Sequence; 2) the Mesa Sequence; 3) the Pacific Sequence; the Harbor Sequence; and 4) the Bent Spring Sequence. The stratigraphic framework established in the Wilmington – Long Beach area is extended into the Central Basin of the greater Los Angeles area by utilizing 1980s and older vintage petroleum exploration land seismic reflection data. Tying this data to the available groundwater monitoring well network in the Central and West Coast Basins demonstrate aquifer correlation problems, and may provide insights into establishing a more robust groundwater model for the greater Los Angeles Basin area.

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Ground-water flow to Death Valley, as inferred from the chemistry and geohydrology of selected springs in Death Valley National Park, California and Nevada

Death Valley lies downgradient from adjacent valleys to the north, south, east, and west in California and Nevada, and is the site of substantial ground-water discharge. The sources of the discharging waters have been discussed by several investigators in the past and are of heightened concern because of the potential disposal of high-level radioactive waste at Yucca Mountain, Nevada, and because of ground-water withdrawals attendant to commercial mining in the northwestern Amargosa Valley region. This report describes high- and low-discharge springs in and along the Amargosa Range that were sampled to augment the level of understanding of the extent and distribution of westward ground-water flow through the range. The Black Mountains do not seem to be part of a significant path of ground-water flow from the Amargosa region. This is attributed to the complex lithology and geologic history of the Black Mountains structural block and to the presence of the intervening Furnace Creek fault zone. The only ground-water discharge associated with the Black Mountains where water chemistry reflects an external source or sources is Saratoga Spring, for which δ 2 H and δ 18 O data indicate recharge in the Spring Mountains to the east. The southern part of the Funeral Mountains transmits a large volume of water through faulted and fractured rocks of Cambrian age that lie at or along the distal part of the northeast -oriented Spotted Range-Mine Mountain structural zone. Waters discharging from springs in the Furnace Creek Ranch vicinity (Travertine and Nevares) both compositionally and isotopically resemble waters from the Ash Meadows spring group in the Amargosa Desert. The Ash Meadows springs and water in the Amargosa Valley alluvium likely are chemically representative of ground water entering the southern Funeral Mountains. Much less ground water flows through the central and northern Funeral Mountains than flows through the southern part, as indicated by the geologic setting and chemistry of Keane Wonder Spring. The northern one-half of the mountains comprises early-to-middle Proterozoic metamorphic rocks that are the core of the Funeral Mountains anticlinorium. The core is largely unfaulted, plunges to the northeast and southwest, and is truncated to some extent on the east by the shallow-dipping Boundary Canyon fault. This structural setting and the paucity of springs in the northern one-half of the Funeral Mountains indicate a long traveltime from the Amargosa region to the western margin of the northern and central parts of the mountains. The Grapevine Mountains include the highest elevations in the Amargosa Range. Substantial precipitation and recharge above about 2,000 meters are evinced by numerous small springs and seeps along the east and west margins. The local nature of the recharge is reflected in δ 2 H and δ 18 O values and in the spring chemistries that indicate control by Tertiary volcanic rocks. The highest spring discharges associated with the Grapevine Mountains are near the north end of the mountains in the Grapevine Ranch area. The springs in this area are similar chemically and isotopically, except for one or two order-of-magnitude differences in calcium, magnesium, and strontium concentrations and a 1.2 per mil difference in δ 13 C values. These differences can be attributed to differences in the distal parts of the respective flow paths. The springs also lie at the end of a northeast -oriented structural zone in the Walker Lane Belt, and their δ 2 H, δ 13 C, and δ 18 O values indicate a recharge area likely to the northeast, outside of the Grapevine Mountains.

California;Nevada↗