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Global Data Toolset (GDT)

According to the United Nations Environment Programme World Conservation Monitoring Centre (UNEP-WCMC) approximately 60 percent of the data contained in the World Database on Protected Areas (WDPA) has missing or incomplete boundary information. As a result, global analyses based on the WDPA can be inaccurate, and professionals responsible for natural resource planning and priority setting must rely on incomplete geospatial data sets. To begin to address this problem the World Data Center for Biodiversity and Ecology, in cooperation with the U. S. Geological Survey (USGS) Rocky Mountain Geographic Science Center (RMGSC), the National Biological Information Infrastructure (NBII), the Global Earth Observation System, and the Inter-American Biodiversity Information Network (IABIN) sponsored a Protected Area (PA) workshop in Asuncion, Paraguay, in November 2007. The primary goal of this workshop was to train representatives from eight South American countries on the use of the Global Data Toolset (GDT) for reviewing and editing PA data. Use of the GDT will allow PA experts to compare their national data to other data sets, including non-governmental organization (NGO) and WCMC data, in order to highlight inaccuracies or gaps in the data, and then to apply any needed edits, especially in the delineation of the PA boundaries. In addition, familiarizing the participants with the web-enabled GDT will allow them to maintain and improve their data after the workshop. Once data edits have been completed the GDT will also allow the country authorities to perform any required review and validation processing. Once validated, the data can be used to update the global WDPA and IABIN databases, which will enhance analysis on global and regional levels.

Fact Sheet↗

Water Resources Division training bulletin, October 1981 through September 1982

This bulletin is designed to inform interested personnel about training available through the Water Resources Division of the U.S. Geological Survey during the period October 1981 through September 1982. The information in this bulletin also can assist supervisors and training officers in developing a coordinated, efficient training program for the personnel for whom they are responsible. The objective of the Water Resources Division training program is to provide specialized training in many phases of hydrology and other subjects related to water-resources investigations. The courses featured in this bulletin are on specialized subjects that are not generally available elsewhere, including the latest developments in applications of ground-water, surface-water, and water-quality hydrologic methods in the field and in the laboratory. The training described herein provides: (1) rapid application of new research results to increase the skills of personnel, and (2) provides newly recruited personnel with special training skills and methods required in water-resources investigations. These courses will assist personnel in learning, reviewing, and expanding their knowledge of technical operations involved in various phases of hydrology and related subjects, and also will develop an overall insight into the broad field of water-resources work.

Open-File Report↗

Evaluation and review of best management practices for the reduction of polychlorinated biphenyls to the Chesapeake Bay

Polychlorinated biphenyls (PCBs) continue to impact the environment due to historic and ongoing anthropogenic sources (for example, industrial and agricultural), despite their ban. Contaminated stormwater has been identified as a vector for PCB transport to many estuaries impaired by PCBs. Management of these regulated discharges is typically achieved by best management practices (BMPs). This review focuses on PCB reduction practices and BMPs to assist management decision making and provide information on the current state of the science. Studies have quantitatively demonstrated the efficacy of green infrastructure BMPs and gray infrastructure improvements to reduce PCB loads, and other studies have demonstrated qualitative reductions for other BMP types. This review also highlights the disconnect between PCB load reduction and PCB bioavailability when selecting a remediation strategy. Additionally, the review evaluates modeling approaches to assess PCB load reduction to inform management decisions and suggests why there are still significant barriers to implementation.

Chesapeake Bay watershed↗

Investing in citizen science can improve natural resource management and environmental protection

Citizen science has made substantive contributions to science for hundreds of years. More recently, it has contributed to many articles in peer-reviewed scientific journals and has influenced natural resource management and environmental protection decisions and policies across the nation. Over the last 10 years, citizen science—participation by the public in a scientific project—has seen explosive growth in the United States, particularly in ecology, the environmental sciences, and related fields of inquiry. In this report, we explore the current use of citizen science in natural resource and environmental science and decision making in the United States and describe the investments organizations might make to benefit from citizen science.

Issues in Ecology↗

Florida manatee now resident in the Bahamas

In January 2000, both the Bahamas National Trust and the Save the Manatee Club received reports of a manatee at Bullocks Harbor, Great Harbour Cay, Bahamas. Under permit with the Bahamas’ Department of Fisheries, I visited Great Harbour Cay from 25 to 27 February 2000 to make a field assessment of the manatee, interview local residents, and provide management recommendations. Detailed below are findings from this trip and a review of this individual’s interesting history.

Sirenews↗

Avian Species Inventory at Manzanar National Historic Site, California - Final Report to the National Park Service

We conducted a baseline inventory for avian species at Manzanar National Historic Site, Inyo County, Calif., from 2002 to 2005. Under the guidelines of the Mojave Network Biological Inventory Program, the primary objectives for this study were to (1) inventory and document the occurrence of avian species at Manzanar, with the goal of documenting at least 90 percent of the species present; (2) provide a geographic information system (GIS)-referenced list of sensitive species occurring at Manzanar that are rare, on Federal or State lists, or otherwise worthy of special consideration; and (3) enter all species data into the National Park Service NPSpecies database. Survey methods included general area searches, variable circular plot point-count censusing, nocturnal surveys, and nest searching. During 13 year-round survey sessions, we documented the occurrence of 132 bird species at Manzanar and confirmed breeding by 19 of these. Based on our findings, as well as review of the literature and searches for records of species occurrence, we estimate inventory completeness for regularly occurring bird species at Manzanar to be near 90 percent. No sensitive species on Federal or State lists were found. The distribution and relative abundance of common bird species at this site is now well enough known to begin development of a monitoring protocol for this group.

Open-File Report↗

Hydrologic evaluation of a hypothetical coal-mining site near Chrisney, Spencer County, Indiana

Protecting the water resources of the Nation is a major emphasis of the Surface Mining Control and Reclamation Act, PL 95-87. Permanent regulations established for this Act by the Office of Surface Mining (OSM) require the issuance of a permit before mining begins. An application for a mining permit must include an assessment of the hydrologic characteristics of the mining site and adjacent area, and a projection of the potential impacts of mining activities on surface water and ground water. OSM's permanent regulations and guidelines provide little insight on the "how to" aspect of making the required hydrologic assessment. This investigation was completed to improve the understanding of the kinds of information needed to make such assessments by: (a) reviewing the regulations to determine what hydrologic information is required; (b) preparing an example hydrologic assessment based on the regulations; and (c) using the experience gained in (a) and (b) to identify areas lacking or needing additional data to make the required assessment. Hydrologic data for the study area were obtained from published and unpublished reports, maps, aerial photographs, personal interviews with residents in the area of the hypothetical mine site, and discussions with experts in the field. Where data were unavailable, "synthetic" data were generated by extrapolation from proximate or similar watersheds and (or) by assumptions based on experience or theory. Some field data were collected to corroborate and augment information originating from all these sources.

Indiana↗

Gaining, losing, and dry stream reaches at Bear Creek Valley, Oak Ridge, Tennessee, March and September 1994

A study was conducted to delineate stream reaches that were gaining flow, losing flow, or that were dry in the upper reaches of Bear Creek Valley near the Y-12 Plant in Oak Ridge, Tennessee. The study included a review of maps and discharge data from a seepage investigation conducted at Bear Creek Valley; preparation of tables showing site identification and discharge and stream reaches that were gaining flow, losing flow, or that were dry; and preparation of maps showing measurement site locations and discharge measurements, and gaining, losing, and dry stream reaches. This report will aid in developing a better understanding of ground-water and surface-water interactions in the upper reaches of Bear Creek.

Tennessee↗

An evaluation and review of water-use estimates and flow data for the Lower Klamath and Tule Lake National Wildlife Refuges, Oregon and California

The Lower Klamath and Tule Lake National Wildlife Refuges, located in the upper Klamath Basin of Oregon and California, encompass approximately 46,700 and 39,100 acres, respectively. Demand for water in the semiarid upper Klamath Basin has increased in recent years, resulting in the need to better quantify water availability and use in the refuges. This report presents an evaluation of water-use estimates for both refuges derived on the basis of two approaches. One approach used evaporation and evapotranspiration estimates and the other used measured inflow and outflow data. The quality of the inflow and outflow data also was assessed. Annual water use in the refuges, using evapotranspiration estimates, was computed with the use of different rates for each of four land-use categories. Annual water-use rates for grain fields, seasonal wetlands, permanently flooded wetlands with emergent vegetation, and open-water bodies were 2.5, 2.9, 2.63, and 4.07 feet per year, respectively. Total water use was estimated as the sum of the products of each rate and the number of acres in its associated land-use category. Mean annual (2003-2005) water use for the Lower Klamath and Tule Lake refuges was approximately 124,000 and 95,900 acre-feet, respectively. To estimate water deliveries needed for each refuge, first, annual precipitation for 2003-2005 was subtracted from the annual water use for those years. Then, an adjusted total was obtained by adding 20 percent to the difference to account for salinity flushing. Resulting estimated mean annual adjusted needed water deliveries in 2003-2005 for the Lower Klamath and Tule Lake refuges were 107,000 and 82,800 acre-feet, respectively. Mean annual net inflow to the refuges for 2003-2005 was computed by subtracting estimated and measured surface-water outflows from inflows. Mean annual net inflow during the 3-year period for the Lower Klamath refuge, calculated for a subsection of the refuge, was approximately 73,700 acre-feet. The adjusted needed water delivery for this section of the refuge, calculated from evapotranspiration estimates, was approximately 77,600 acre-feet. For the Tule Lake refuge, mean annual net inflow during the 3-year period was approximately 76,100 acre-feet, which is comparable to the estimated annual needed water delivery for the refuge of 82,800 acre-feet. For 1962-2005, mean annual net inflow to the Lower Klamath refuge was approximately 49,800 acre-feet, about 23,900 acre-feet less than for 2003-2005. Although mean April-September net inflows for 1962-2005 and 2003-2005 have remained fairly constant, annual net inflow has increased for October-March, which accounts for the difference. Consistently higher autumn and winter flow deliveries since the mid-1980s reflect a significant change in refuge management. More sections of the refuge are currently managed as seasonal wetlands than were in the 1960s and 1970s. Flow records for the Ady Canal at State Line Road, Klamath Straits Drain at State Line Road, and D Pumping Plant were evaluated for their data quality. On the basis of USGS flow-record criteria, all three flow records were rated as 'poor.' By definition, 95 percent of the daily flows in a record having this rating could be in error by more than 15 percent.

Scientific Investigations Report↗

Critical mineral resources of the United States—An introduction

Many changes have taken place in the mineral resource sector since the publication by the U.S. Geological Survey of Professional Paper 820, “United States Mineral Resources,” which is a review of the long-term United States resource position for 65 mineral commodities or commodity groups. For example, since 1973, the United States has continued to become increasingly dependent on imports to meet its demands for an increasing number of mineral commodities. The global demand for mineral commodities is at an alltime high and is expected to continue to increase, and the development of new technologies and products has led to the use of a greater number of mineral commodities in increasing quantities to the point that, today, essentially all naturally occurring elements have several significant industrial uses. Although most mineral commodities are present in sufficient amounts in the earth to provide adequate supplies for many years to come, their availability can be affected by such factors as social constraints, politics, laws, environmental regulations, land-use restrictions, economics, and infrastructure. This volume presents updated reviews of 23 mineral commodities and commodity groups viewed as critical to a broad range of existing and emerging technologies, renewable energy, and national security. The commodities or commodity groups included are antimony, barite, beryllium, cobalt, fluorine, gallium, germanium, graphite, hafnium, indium, lithium, manganese, niobium, platinum-group elements, rare-earth elements, rhenium, selenium, tantalum, tellurium, tin, titanium, vanadium, and zirconium. All these commodities have been listed as critical and (or) strategic in one or more of the recent studies based on assessed likelihood of supply interruption and the possible cost of such a disruption to the assessor. For some of the minerals, current production is limited to only one or a few countries. For many, the United States currently has no mine production or any significant identified resources and is largely dependent on imports to meet its needs. As a result, the emphasis in this volume is on the global distribution and availability of each mineral commodity. The environmental issues related to production of each mineral commodity, including current mitigation and remediation approaches to deal with these challenges, are also addressed. This introductory chapter provides an overview of the mineral resource classifications, terms, and definitions used in this volume. A review of the history of the use and meaning of the term “critical” minerals (or materials) is included as an appendix to the chapter.

Professional Paper↗

Pinyon-juniper woodlands

Pinyon-juniper woodlands are one of the largest ecosystems in the Southwest and in the Middle Rio Grande Basin (Fig. 1). The woodlands have been important to the region's inhabitants since prehistoric times for a variety of natural resources and amenities. The ecosystems have not been static; their distributions, stand characteristics, and site conditions have been altered by changes in climatic patterns and human use and, often, abuse. Management of these lands since European settlement has varied from light exploitation and benign neglect, to attempts to remove the trees in favor of forage for livestock, and then to a realization that these lands contain useful resources and should be managed accordingly. Land management agencies are committed to ecosystem management. While there are several definitions of ecosystem management, the goal is to use ecological approaches to create and maintain diverse, productive, and healthy ecosystems (Kaufmann et al. 1994). Ecosystem management recognizes that people are an integral part of the system and that their needs must be considered. Ecological approaches are central to the concept, but our understanding of basic woodland ecology is incomplete, and there are different opinions and interpretations of existing information (Gottfried and Severson 1993). There are many questions concerning proper ecosystem management of the pinyon-juniper woodlands and how managers can achieve these goals (Gottfried and Severson 1993). While the broad concept of ecosystem management generally is accepted, the USDA Forest Service, other public land management agencies, American Indian tribes, and private landowners may have differing definitions of what constitutes desired conditions. Key questions about the pinyon-juniper ecosystems remain unanswered. Some concern the basic dynamics of biological and physical components of the pinyon-juniper ecosystems. Others concern the distribution of woodlands prior to European settlement and changes since the introduction of livestock and fire control. This relates to whether tree densities have been increasing or whether trees are invading grasslands and, to a lesser extent, drier ponderosa pine (Pinus ponderosa) forests. In areas where woodlands were heavily used by American Indians for fuelwood prior to European contact, the advance of pinyon and juniper could represent the slow recovery from intensive use (Samuels and Betancourt 1982). There are numerous questions regarding declines in watershed condition related to changes in pinyon-juniper tree stand densities and to the density and composition of understory vegetation. There are different opinions about proper management of woodland ecosystems. Should these lands be managed for a single resource, such as forage for livestock production, or managed for sustained production of multiple resource products and amenities? Depending on site and stand conditions, the woodlands can produce variable quantities of fuelwood, pinyon nuts, wildlife habitat, forage for livestock, and cover for watershed protection. Management must also consider increasing recreational demands, threatened and endangered species, and protection of archeological sites. Many pinyon-juniper woodland watersheds in New Mexico have unsatisfactory soil and watershed conditions (USDA Forest Service 1993); managers must develop restoration procedures that recognize the value of woodland ecosystems. The concerns, questions, and conflicts surrounding management of pinyon-juniper lands, as well as the ecological foundations of ecosystem management, require that all interested parties reevaluate attitudes toward the woodlands. Ecosystem management goals and concepts recognize diversity. Pinyonjuniper woodlands are diverse, and stand characteristics and site productivities vary. Management objectives and prescriptions must evaluate the potential of each site, and decisions must be based on sound scientific information. This information is often unavailable. Therefore, this paper describes what we do know about the characteristics, distribution, and ecology of pinyon-juniper woodlands, including the effects of natural and human factors, within the southwestern United States and particularly the Middle Rio Grande Basin. It also reviews some past and present management options in this widespread and important vegetation type. The review draws on research and management information from the Rio Grande Basin and from similar areas in the Southwest and adjacent regions. It does not attempt to review all of the relevant literature; additional sources can be found within the articles cited in the References.

General Technical Report↗

Crocodylus acutus (American crocodile). Diet

Reported prey items of Crocodylus acutus include insects, crustaceans, fish, and large reptiles (Medem 1981. Los Crocodylia de Sur America. Volumen I. Los Crocodylia de Colombia. Colciencias. Bogota, Colombia. 398 pp.; Platt et al. 2002. Herpetol. Rev. 33:202–203; Platt et al. 2013. J. Herpetol. 47:1–10; Balaguera-Reina et al. 2018. Ecosphere 9:e02393). Recently, new potential prey items such as Ligia spp. (isopod), Python molurus bivittatus (Burmese Python), and Arius felis (Hardhead catfish) have also been documented in Florida, USA (Farris et al. 2015. Herpetol. Rev. 46:85–86; Godfrey et al. 2021. Herpetol. Rev. 52:641–642; Godfrey et al. 2022. Herpetol. Rev. 53:315–316). However, to our knowledge the toxic Sphoeroides spengleri (Bandtail Pufferfish) has not been reported in the diet of C. acutus; herein we report on the possibly lethal effects of a C. acutus from consumption of a pufferfish in south Florida.

Herpetological Review↗

The sterile-male-release technique in Great Lakes sea lamprey management

The parasitic sea lamprey (Petromyzon marinus) has been a serious pest since its introduction into the Great Lakes, where it contributed to severe imbalances in the fish communities by selectively removing large predators (Smith 1968; Christie 1974; Schneider et al.1996). Since the 1950s, restoration and maintenance of predator-prey balance has depended on the Great Lakes Fishery Commission (GLFC) sea lamprey management program. Initially, management relied primarily on stream treatments with a selective lampricide to kill larvae, on barriers to migration, and on trapping to remove potential spawners (Smith and Tibbles 1980). By the late 1970s, however, it was clear that the future of sea lamprey management lay in development of a larger array of control strategies, including more alternatives to lampricide applications (Sawyer 1980). Since then the only new alternative to chemical control to reach operational status is the release of sterilized male sea lampreys. Research on the concept began at the USGS, Hammond Bay Biological Station in Millersburg, MI (HBBS) during the 1970s (Hanson and Manion 1980). Development and evaluation continued through the 1980s, leading to the release of sterilized males in Great Lakes tributaries since 1991 (Twohey et al. 2003a). The objectives of this paper are 1) to review the implementation and evaluations of sterile-male-release technique (SMRT) as it is being applied against sea lampreys in the Great Lakes, 2) to review our current understanding of its efficacy, and 3) to identify additional research areas and topics that would increase either the efficacy of SMRT or expand its geographic potential for application.

Report↗

Leaping lopsided: a review of the current hypotheses regarding etiologies of limb malformations in frogs

Recent progress in the investigation of limb malformations in free-living frogs has underlined the wide range in the types of limb malformations and the apparent spatiotemporal clustering of their occurrence. Here, we review the current understanding of normal and abnormal vertebrate limb development and regeneration and discuss some of the molecular events that may bring about limb malformation. Consideration of the differences between limb development and regeneration in amphibians has led us to the hypothesis that some of the observed limb malformations come about through misdirected regeneration. We report the results of a pilot study that supports this hypothesis. In this study, the distal aspect of the right hindlimb buds of X. laevis tadpoles was amputated at the pre-foot paddle stage. The tadpoles were raised in water from a pond in Minnesota at which 7% of surveyed newly metamorphosed feral frogs had malformations. Six percent (6 of 100) of the right limbs of the tadpoles raised in pond water developed abnormally. One truncated right limb was the only malformation in the control group, which was raised in dechlorinated municipal water. All unamputated limbs developed normally in both groups. Three major factors under consideration for effecting the limb malformations are discussed. These factors include environmental chemicals (primarily agrichemicals), encysted larvae (metacercariae) of trematode parasites, and increased levels of ultraviolet light. Emphasis is placed on the necessary intersection of environmental stressors and developmental events to bring about the specific malformations that are observed in free-living frog populations.

California, Maine, Minnesota, Quebec, Vermont↗

Sarcoptic mange: An emerging panzootic in wildlife

Sarcoptic mange, a skin infestation caused by the mite Sarcoptes scabiei , is an emerging disease for some species of wildlife, potentially jeopardizing their welfare and conservation. Sarcoptes scabiei has a near-global distribution facilitated by its forms of transmission and use of a large diversity of host species (many of those with broad geographic distribution). In this review, we synthesize the current knowledge concerning the geographic and host taxonomic distribution of mange in wildlife, the epidemiological connections between species, and the potential threat of sarcoptic mange for wildlife conservation. Recent sarcoptic mange outbreaks in wildlife appear to demonstrate ongoing geographic spread, increase in the number of hosts and increased virulence. Sarcoptic mange has been reported in at least 12 orders, 39 families and 148 species of domestic and wild mammals, making it one of the most generalist ectoparasites of mammals. Taxonomically, the orders with most species found infested so far include Perissodactyla (67% species from the entire order), Artiodactyla (47%), and Diprotodontia (67% from this order). This suggests that new species from these mammal orders are likely to suffer cross-species transmission and be reported positive to sarcoptic mange as surveillance improves. We propose a new agenda for the study of sarcoptic mange in wildlife, including the study of the global phylogeography of S. scabiei , linkages between ecological host traits and sarcoptic mange susceptibility, immunology of individuals and species, development of control strategies in wildlife outbreaks and the effects of global environmental change in the sarcoptic mange system. The ongoing transmission globally and sustained spread among areas and wildlife species make sarcoptic mange an emerging panzootic in wildlife. A better understanding of sarcoptic mange could illuminate the aspects of ecological and evolutionary drivers in cross-species transmission for many emerging diseases.

Transboundary and Emerging Diseases↗

History of U.S. Geological Survey scientific peer review and approval, 1879–2019

The U.S. Geological Survey (USGS), a bureau within the U.S. Department of the Interior, has valued and used a scientific peer review and approval process since its creation in 1879. Bureau approval, formerly called Director’s approval, has been described in several USGS documents since 1900, and peer review has been codified in policy since 1959. Peer review of USGS manuscripts is intended to ensure the accuracy of data, the scientific validity of interpretations, and the consideration of alternative interpretations. This rigorous quality assurance process is considered deliberative because of the iterative exchange of ideas and opinions among the involved parties. Peer review practices differed between USGS organizational units until implementation of USGS Fundamental Science Practices (FSP) in 2006, which formalized Bureau-wide science practices, including peer review and approval, for all Bureau scientific information products released to the public or other Federal agencies. FSP policies also address review and approval requirements pertaining to the release of USGS-funded data and software and endorse quality-control standards for USGS laboratories. Bureau approval signifies the scientific excellence of information products, validates and ensures that all necessary reviews have been conducted, and confirms that information products meet USGS science quality standards and have the full backing of the Bureau. The extent, scope, and history of the peer review and approval process within the USGS are documented herein, so future USGS scientists and the public understand how consistent approaches in developing, reviewing, and publishing USGS scientific information have been and continue to be essential in maintaining the reputation of the Bureau for reliable and impartial Earth science research and data collection.

Fact Sheet↗

Review of revised Klamath River Total Maximum Daily Load models from Link River Dam to Keno Dam, Oregon

Flow and water-quality models are being used to support the development of Total Maximum Daily Load (TMDL) plans for the Klamath River downstream of Upper Klamath Lake (UKL) in south-central Oregon. For riverine reaches, the RMA-2 and RMA-11 models were used, whereas the CE-QUAL-W2 model was used to simulate pooled reaches. The U.S. Geological Survey (USGS) was asked to review the most upstream of these models, from Link River Dam at the outlet of UKL downstream through the first pooled reach of the Klamath River from Lake Ewauna to Keno Dam. Previous versions of these models were reviewed in 2009 by USGS. Since that time, important revisions were made to correct several problems and address other issues. This review documents an assessment of the revised models, with emphasis on the model revisions and any remaining issues. The primary focus of this review is the 19.7-mile Lake Ewauna to Keno Dam reach of the Klamath River that was simulated with the CE-QUAL-W2 model. Water spends far more time in the Lake Ewauna to Keno Dam reach than in the 1-mile Link River reach that connects UKL to the Klamath River, and most of the critical reactions affecting water quality upstream of Keno Dam occur in that pooled reach. This model review includes assessments of years 2000 and 2002 current conditions scenarios, which were used to calibrate the model, as well as a natural conditions scenario that was used as the reference condition for the TMDL and was based on the 2000 flow conditions. The natural conditions scenario included the removal of Keno Dam, restoration of the Keno reef (a shallow spot that was removed when the dam was built), removal of all point-source inputs, and derivation of upstream boundary water-quality inputs from a previously developed UKL TMDL model. This review examined the details of the models, including model algorithms, parameter values, and boundary conditions; the review did not assess the draft Klamath River TMDL or the TMDL allocations. Attention to the details of a model is one of the best ways to identify potential problems, correct them if possible, and begin to assess the magnitude of potential model errors and uncertainty. Model users need to determine the level of acceptable uncertainty associated with their objectives, identify all sources of potential uncertainty (model uncertainty, data uncertainty, etc.), and assess their approach and results accordingly. In the draft Klamath River TMDL, the Oregon Department of Environmental Quality identified the upstream boundary conditions as the largest source of uncertainty for both the current and natural conditions scenarios, not the model algorithms or choice of model parameters. We agree that the upstream boundary conditions are one of the largest, if not the largest, source of model uncertainty; therefore, the derivation of upstream boundary conditions may be more important to the TMDL than some other model-related issues identified in this review. The revised models contain a number of changes, some of which were done to solve small problems and are largely inconsequential to model results, but others of which are important and affect model predictions of instream concentrations. A consistent version of the model is now applied to all scenarios, and an error in the source code was corrected that had inadvertently discarded 20 percent of the incoming solar radiation in the original model. The baseline light-extinction coefficient for water was decreased and set to a consistent and defensible value across all models of reservoir reaches. Inconsistencies among the values of certain parameters in the original models, such as the ammonia nitrification rate and the decomposition rates of organic matter, have been eliminated, although the reasoning behind the final selections was not documented. The dependence of the rate of sediment oxygen demand (SOD) on temperature was modified such that the SOD rate was substantially decreased at temperatures less than 20°C, causing the model to predict higher dissolved oxygen (DO) concentrations in spring, autumn, and winter. Although that change to the temperature dependence function was done to make the function more similar to the model’s default, this change was not accompanied by any documentation of recalibration or sensitivity exercises. The maximum SOD rate for the 2002 current conditions scenario was decreased from 3.0 grams per square meter per day (g/m 2 /d) in the original model to 2.0 g/m 2 /d in the revised model, a considerable adjustment that appears to have been needed to offset effects of a change to another variable (O2LIM) that would have resulted in a substantial increase in the effective SOD rate for 2002. A 50-percent decrease in the SOD rate over a 2-year period, however, is not likely to be mirrored by field measurements, so this change may be compensating for some process that is not represented correctly in the DO budget for the current conditions scenarios. Several important changes were made to the natural conditions scenario. First, the elevation of the Keno reef was corrected; the elevation specified in the original model was 1 foot too high, which affected the volume of the pooled reach and the travel time through it. The most important changes to this scenario were to the upstream boundary inputs of organic matter and algae, which affect incoming fluxes of nitrogen and phosphorus. Algal biomass inputs were increased by approximately 60 percent during summer because of a change in the way those inputs were derived from results of the UKL TMDL model. Non-algal organic matter inputs were decreased, particularly in summer to correct a problem attributed to double-counting of phosphorus in the original inputs. The distribution of non-algal organic matter was changed from 20 percent dissolved in the original model to 90 percent dissolved in the revised model in response to review comments and published data. The overall sum of algal biomass and non-living organic matter was decreased, which resulted in lower inputs of total phosphorus and nitrogen. Total phosphorus inputs were less than 0.03 mg/L, and although the inputs were derived from selected results of the UKL TMDL model, these concentrations seem too low to be representative of a historically eutrophic system surrounded by extensive wetlands, peat soils, and a groundwater system high in phosphorus. The draft TMDL states that the upstream boundary conditions are the greatest source of uncertainty, greater than any uncertainty associated with the models. Efforts to improve existing models of algal growth and nutrient cycling in UKL, therefore, would provide a substantial benefit to downstream modeling efforts on the Klamath River. Although many improvements were made in revising the Klamath River TMDL models, some issues and uncertainties remain. Several errors in the model source code remain, but do not affect model results for this application as long as certain options and rates are not changed; future users of these models should be aware of these issues. Although the distribution of dissolved and particulate organic matter was modified for the natural conditions scenario, that distribution was not changed for the current conditions scenarios. Recent data on that distribution and the likely rates of organic matter decomposition could be used to improve these models in the future. Nitrate predictions at Keno (Highway 66) still are too high for the current conditions scenarios; future efforts should re-evaluate the model’s denitrification rates and the release rate of ammonia from anoxic sediments. Possibly the most important of the remaining issues are tied to the two-state (healthy/unhealthy) hypothesis for the algae population that was coded into the model. Some of the rates and conversion functions could be refined to make them more acceptable; currently, the published literature does not support the concept of moderately low dissolved-oxygen concentrations as a stressor of algae in the ranges used by the model. More research is needed before these algorithms can be truly tested. The algorithms currently appear to help the model fit the patterns in the available data, and that is useful and perhaps sufficient for some purposes, but those algorithms are not truly predictive or reliable for certain purposes until they can be tested through well-designed experiments and research. In summary, the TMDL models used to simulate Link and Klamath Rivers from Link River Dam to Keno Dam were revised to fix several problems and address various issues. The resulting models are an improvement over those that were reviewed by USGS in 2009, and represent a useful advance in the simulation of a complex system that is difficult to model. However, several issues remain that cause increased uncertainty in the model results. Depending on the objectives of the modeling, now or in the future, these remaining issues could be more or less important. For the Klamath River TMDL, the upstream boundary conditions may be a larger source of uncertainty than the concerns with model algorithms and model parameters identified in this review. Efforts to re-evaluate the available models of algal growth and nutrient cycling in UKL would be highly beneficial to downstream modeling efforts in the Klamath River.

Oregon;California↗

Diel cycling of trace elements in streams draining mineralized areas: a review

Many trace elements exhibit persistent diel, or 24-h, concentration cycles in streams draining mineralized areas. These cycles can be caused by various physical and biogeochemical mechanisms including streamflow variation, photosynthesis and respiration, as well as reactions involving photochemistry, adsorption and desorption, mineral precipitation and dissolution, and plant assimilation. Iron is the primary trace element that exhibits diel cycling in acidic streams. In contrast, many cationic and anionic trace elements exhibit diel cycling in near-neutral and alkaline streams. Maximum reported changes in concentration for these diel cycles have been as much as a factor of 10 (988% change in Zn concentration over a 24-h period). Thus, monitoring and scientific studies must account for diel trace-element cycling to ensure that water-quality data collected in streams appropriately represent the conditions intended to be studied.

Applied Geochemistry↗