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At least 1,117 records · Page 62Linked to original sources
USGS2024

Importance of a lake-wetland complex for a resilient Walleye fishery

Wetlands serve as unique habitats that can support high biodiversity. Large-scale loss of wetland habitats can threaten important linkages between lake and wetland habitats that could affect diversity and growth of aquatic organisms. In this study, we compare prey diversity and abundance as well as Walleye ( Sander vitreus ) diets and condition in a large glacial lake (Lake Kampeska, South Dakota) with a connected wetland to better understand seasonal changes in the benefits provided by each habitat. We examined seasonal differences (spring, summer, and fall) through two years (summer 2021 through fall 2022) between the habitats using prey fish catch per unit effort, richness, Shannon diversity, and Bray–Curtis dissimilarity as well as Walleye relative weight, percent of empty stomachs, diet weight, stomach fullness, diet energy, and diet taxa importance. The prey fish community was more diverse and abundant in the wetland, and Walleye consumed more prey (by weight) in the wetland during all seasons except spring. Wetland reconnection can be a tool for managers to improve water quality while providing seasonal habitat needs for fish. Additionally, the diversity of prey resources provided by wetlands, many of which are unique, support resilience in the face of ecological change. Protection of wetlands may be critical for maintaining healthy and resilient fisheries into the future.

South Dakota↗
USGS2018

Rare earth element and rare metal inventory of central Asia

Rare earth elements (REE), with their unique physical and chemical properties, are an essential part of modern living. REE have enabled development and manufacture of high-performance materials, processes, and electronic technologies commonly used today in computing and communications, clean energy and transportation, medical treatment and health care, glass and ceramics, aerospace and defense, and metallurgy and chemical refining. Central Asia is an emerging REE and rare metals (RM) producing region. A newly compiled inventory of REE-RM-bearing mineral occurrences and delineation of areas-of-interest indicate this region may have considerable undiscovered resources.

Fact Sheet↗
USGS1978

Preliminary stratigraphic cross section showing radioactive zones in the Devonian dark shales in the eastern part of the Appalachian Basin

The U.S. Geological Survey (USGS), in a cooperative agreement with the U.S. Department of Energy (DOE), is participating in the Eastern Gas Shales Project. The purpose of the DOE project is to increase the production of natural gas from eastern United States shales in petroliferous basins through improved exploration and extraction techniques. The USGS participation includes stratigraphic studies which will contribute to the characterization and appraisal of the natural gas resources of Devonian shale in the Appalachian basin. This cross section differs from others in this series partly because many of the shales in the eastern part of the basin are less radioactive than those farther west and because in this area shales that may be gas-productive are not necessarily highly radioactive and black.

Delaware, Maryland, New Jersey, New York, Pennsylv↗
USGS2024

An ensemble mean method for remote sensing of actual evapotranspiration to estimate water budget response across a restoration landscape

Estimates of actual evapotranspiration (ETa) are valuable for effective monitoring and management of water resources. In areas that lack ground-based monitoring networks, remote sensing allows for accurate and consistent estimates of ETa across a broad scale—though each algorithm has limitations (i.e., ground-based validation, temporal consistency, spatial resolution). We developed an ensemble mean ETa (EMET) product to incorporate advancements and reduce uncertainty among algorithms (e.g., energy-balance, optical-only), which we use to estimate vegetative water use in response to restoration practices being implemented on the ground using management interventions (i.e., fencing pastures, erosion control structures) on a private ranch in Baja California Sur, Mexico. This paper describes the development of a monthly EMET product, the assessment of changes using EMET over time and across multiple land use/land cover types, and the evaluation of differences in vegetation and water distribution between watersheds treated by restoration and their controls. We found that in the absence of a ground-based monitoring network, the EMET product is more robust than using a single ETa data product and can augment the efficacy of ETa-based studies. We then found increased ETa within the restored watershed when compared to the control sites, which we attribute to increased plant water availability.

Baja California Sur↗
USGS1940

Ground-water resources of Kansas

Introduction: Water is a necessity of life. Accordingly, every person is deeply interested in the subject of water supply. He knows that he must have water to drink. He depends indirectly on water for all his food and clothing. He may want water in which to wash. Civilized man has learned also that water serves admirably for a large and ever enlarging list of uses that depend on its easy convertibility from a liquid to a solid or gaseous state and its adaptability as a chemical solvent, a medium for transfer of matter or energy, and a regulator of temperature. The average consumption of water in towns and cities of the United States amounts to about 100 gallons per person per day. Because of long familiarity with never-failing supplies of water provided by nature, or equally, because of unthinking dependence on others, many individuals are probably unaware of their interest in water, but let water become difficult or impossible to obtain, or let the quality of water be greatly changed, and there is immediate concern. Many Kansas persons — without doubt too many — give little thought to the subject of water when rainfall is normal and when ponds and streams are full, but not too full. Kansas has a smaller natural water supply than many other regions, but we are used to these conditions, and it is strongly marked departures from what we regard as normal that cause anxiety. Periods of excessive heat and drought such as have recurred in Kansas, especially during the last half-dozen years, bring hardships to very many persons, particularly dwellers on the farm. Alarm is felt when field crops and pasture shrivel from lack of moisture and from heat, when there is insufficient water for the stock, when wells go dry, and when even some towns and cities must haul water in tank cars. Everyone is then water-conscious, as is true also under reverse conditions, when overabundance of rainfall produces disastrous floods. It is obvious, however, that the subject of water supply should not be given attention only in times of deficiency or overabundance. All citizens of Kansas should have enduring interest in quests of water control and conservation that will make for equable supply. No individual or government agency can increase or diminish the annual rainfall, nor safeguard wholly against floods. It is possible, on the other hand, largely to avoid the distress due to severe shortage of water in recent years. This statement calls attention to the subject of water in the ground, or as commonly known, ground water. I have been asked to discuss the underground water resources of Kansas. I am asked to give answers to such questions as: In what places and under what conditions may water that is suitable for domestic and stock use be obtained from wells? Why are some water wells in Kansas never-failing large producers of excellent waters, whereas other yield only small amounts of poor water and readily go dry? What improvements are possible in methods of finding and utilizing the ground-water resources that exist in Kansas? What provisions can be made to safeguard best against effects of prolonged drought? These questions call for a discussion of some general principles that apply to accumulation and movement of water beneath the surface of in Kansas, and especially to the various geologic conditions that are fundamental factors in controlling variation in water supply from the below ground. It will be desirable also to consider the characteristics of various districts in Kansas that may be differentiated as natural ground-water provinces, pointing out the distinguishing features of these districts. The basis for these distinctions is a difference in water-supply conditions that depends mainly on variation in underground rock structure. Importance of ground-water resources. — The importance of Kansas' ground-water resources may be emphasized from various viewpoints and in different ways. More than three-fourths of the public water supplies of Kansas are obtained from wells. In 1939, only 60 out of 375 municipal water supplies in Kansas, which is 16 percent, utilized surface waters. If the water wells of the cities and those located on all privately owned land in the state were suddenly destroyed, making it necessary to go to streams, springs, lakes (which are almost all artificial), and ponds for water supply domestic, stock, and industrial use, there would be almost incalculable difficulty and expense. If one could not go to springs, or dig new wells, or use any surface water derived from underground flow, much of Kansas would become uninhabitable. These suggested conditions seem absurd, but they emphasize our dependence on ground-water resources. Fromm a quantitative standpoint, ground-water supplies existent in Kansas far outweigh surface waters that are present in the state at any one time. No exact figures for such comparison can be given, but, taking 384 square miles as the total surface water area of the state and estimating an average water depth of five feet, the computed volume of surface waters is found to be 1/100th of that of the conservatively estimated ground-water storage in Kansas. The latter takes account only of potable fresh water and is based on an assumed mean thickness of ten feet of reservoir having an effective porosity of twenty percent. It is to be remembered, however, that most of the surface water is run-off, which soon leaves the state, stream valleys being replenished from rainfall and flow from ground-water reservoirs. Most of the ground-water supplies, on the other hand, have existed for many years with almost no appreciable movement--in fact, it is reasonably certain that some well water drawn from beneath the surface of Kansas in 1940 represents rainfall in this region at time before the first white man entered Kansas, even before the visit of Coronado in the 16th century. Most ground water is to be regarded as water in storage rather than water in transit.

Kansas↗
USGS2011

Global climate change implications for coastal and offshore oil and gas development

The discussion and debate about climate change and oil and gas resource development has generally focused on how fossil fuel use affects the Earth's climate. This paper explores how the changing climate is likely to affect oil and gas operations in low-lying coastal areas and the outer continental shelf. Oil and gas production in these regions comprises a large sector of the economies of many energy producing nations. Six key climate change drivers in coastal and marine regions are characterized with respect to oil and gas development: changes in carbon dioxide levels and ocean acidity, air and water temperature, precipitation patterns, the rate of sea level rise, storm intensity, and wave regime. These key drivers have the potential to independently and cumulatively affect coastal and offshore oil and gas exploration, production, and transportation, and several impacts of climate change have already been observed in North America.

Energy Policy↗
USGS2016

Lake Ontario benthic prey fish assessment, 2015

Benthic prey fishes are a critical component of the Lake Ontario food web, serving as energy vectors from benthic invertebrates to native and introduced piscivores. Since the late 1970’s, Lake Ontario benthic prey fish status was primarily assessed using bottom trawl observations confined to the lake’s south shore, in waters from 8 – 150 m (26 – 492 ft). In 2015, the Benthic Prey Fish Survey was cooperatively adjusted and expanded to address resource management information needs including lake-wide benthic prey fish population dynamics. Effort increased from 55 bottom trawl sites to 135 trawl sites collected in depths from 8 - 225m (26 – 738 ft). The spatial coverage of sampling was also expanded and occurred in all major lake basins. The resulting distribution of tow depths more closely matched the available lake depth distribution. The additional effort illustrated how previous surveys were underestimating lake-wide Deepwater Sculpin, Myoxocephalus thompsonii , abundance by not sampling in areas of highest density. We also found species richness was greater in the new sampling sites relative to the historic sites with 11 new fish species caught in the new sites including juvenile Round Whitefish, P rosopium cylindraceum , and Mottled sculpin, Cottus bairdii . Species-specific assessments found Slimy Sculpin, Cottus cognatus abundance increased slightly in 2015 relative to 2014, while Deepwater Sculpin and Round Goby, Neogobius melanostomus, dramatically increased in 2015, relative to 2014. The cooperative, lake-wide Benthic Prey Fish Survey expanded our understanding of benthic fish population dynamics and habitat use in Lake Ontario. This survey’s data and interpretations influence international resource management decision making, such as informing the Deepwater Sculpin conservation status and assessing the balance between sport fish consumption and prey fish populations. Additionally a significant Lake Ontario event occurred in May 2015 when a single juvenile Bloater Coregonus hoyi , was captured during the spring bottom trawl survey at 95m (312 ft) near Oswego, NY. This native, deep-water prey fish, last captured in Lake Ontario survey trawls in 1983, is part of an international, collaborative coregonid restoration effort in the Great Lakes.

Lake Ontario↗
USGS2017

Selenium

Selenium (Se) was discovered in 1817 in pyrite from copper mines in Sweden. It is a trace element in Earth’s crust, with an abundance of three to seven orders of magnitude less than the major rock-forming elements. Commercial use of selenium began in the United States in 1910, when it was used as a pigment for paints, ceramic glazes, and red glass. Since that time, it has had many other economic uses—notably, in the 1930s and 1940s, when it was used in rectifiers (which change alternating current to direct current), and in the 1960s, when it began to be used in the liner of photocopier drums. In the 21st century, other compounds have replaced selenium in these older products; modern uses for selenium include energy-efficient windows that limit heat transfer and thin-film photovoltaic cells that convert solar energy into electricity. In Earth’s crust, selenium is found as selenide minerals, selenate and selenite salts, and as substitution for sulfur in sulfide minerals. It is the sulfide minerals, most commonly those in porphyry copper deposits, that provide the bulk of the selenium produced for the international commodity market. Selenium is obtained as a byproduct of copper refining and recovered from the anode slimes generated in electrolytic production of copper. Because of this, the countries that have the largest resources and (or) reserves of copper also have the largest resources and (or) reserves of selenium. Because selenium occurs naturally in Earth’s crust, its presence in air, water, and soil results from both geologic reactions and human activity. Selenium is found concentrated naturally in soils that overlie bedrock with high selenium concentrations. Selenium mining, processing, use in industrial and agricultural applications, and disposal may all contribute selenium to the environment. A well-known case of selenium contamination from agricultural practices was discovered in 1983 in the Kesterson National Wildlife Refuge in California. There, waters draining from agricultural fields created wetlands with high concentrations of dissolved selenium in the water. The selenium was taken up by aquatic wildlife and caused massive numbers of embryonic deformities and deaths. Regulatory agencies have since worked to safeguard ecological and human health by creating environmental exposure guidelines based upon selenium concentrations in water and in fish tissue. Any attempt to regulate selenium concentrations requires a delicate balance because selenium occurs naturally and is also a vital nutrient for the health of wildlife, domestic stock, and humans. Selenium is commonly added as a vitamin to animal feed, and in some regions of the United States and the world, it is added as an amendment to soils for uptake by agricultural crops. The important role of selenium in economic products, energy supply, agriculture, and health will continue for well into the future. The challenge to society is to balance the benefits of selenium use with the environmental consequences of its extraction. Increased understanding of the elemental cycle of selenium in the earth may lead to new (or unconventional) sources of selenium, the discovery of new methods of extraction, and new technologies for minimizing the transfer of selenium from rock to biota, so to protect environmental and human health.

Professional Paper↗
USGS2013

Ecosystem stressors in southern Nevada

Southern Nevada ecosystems and their associated resources are subject to a number of global and regional/local stressors that are affecting the sustainability of the region. Global stressors include elevated carbon dioxide (CO 2 ) concentrations and associated changes in temperature and precipitation patterns and amount, solar radiation, and nutrient cycles (Smith and others 2009b). Global stressors are ubiquitous in nature and interact both directly and indirectly with regional or local stressors. Regional/local stressors in southern Nevada include: population growth and urbanization and associated increases in nitrogen deposition, energy development, water development, and recreation; increased effects of insects and disease; ongoing effects of livestock, wild horse and burro grazing; new and expanding invasive species; and altered fire regimes. This chapter provides background information on the stressors affecting southern Nevada's ecosystems that is needed to address Goal 1.0 in the SNAP Science Research Strategy, which is to restore, sustain, and enhance southern Nevada's ecosystems (Turner and others 2009). Human population growth and changes in land use strongly affect the type and magnitude of local/regional stressors. From 1960 to 2010, Nevada's growth rate was the highest in the nation (www.census.gov/prod/cen2010/briefs/c2010br-01.pdf). Clark County has experienced particularly high growth, with a population increase of greater than 40 percent since the 2000 census. Factors like land ownership, historic and current land use, proximity to human and energy developments, and desirability for recreation all influence the level of human-caused stress. The strong elevation/climate gradients and large difference in the environmental characteristics of southern Nevada ecosystems (fig. 1.2; Chapter 1) have a major influence on both patterns of land use and the dominant stressors for different ecosystem types. Shifts in land use related to population growth, urbanization, and energy development and largely focused in lower elevation ecosystems including sagebursh, blackbrush and shadscale, and Mojave Desert scrub. Water divisions influence riparian/aquatic ecosystems and springs, while groundwater pumping also has the potential to affect ecosystems that characterize lower valleys including Mojave Desert scrub. Recreational uses influence all ecosystems, and wild horse and burro use and livestock grazing affect all but alpine and subalpine ecosystems. Insects and disease, as well as invasive species are widespread stressors. Fire is limited to ecosystems with sufficient fuels to carry fire and is strongly influence by invasive species in lower elevation Mojave Desert scrub, blackbrush and shadscale, and sagebursh ecosystems. This chapter address aspects of several of the Goals and Sub-goals listed in the SNAP Science Research Strategy (table 1.3; Turner and others 2009). Altered fire regimes, invasive species, land use practices, and management actions are addressed in Goal 1 -- Sustain, Restore, and Enhance Southern Nevada's Ecosystems. The effects of these stressors on sensitive species and habitat are specifically addressed in Sub-goal 1.4 -- Sustain and Enhance Southern Nevada's Biotic Communities, to Preserve Biodiversity and Maintain Populations. Anthropogenic factors, such a recreation and urbanization, are referred to in Goal 2-- Provide for Responsible Use of Southern Nevada;s Lands in a Manner that Preserve Heritage Resources and Promotes an Understanding of Human Interaction with the Landscape.

Nevada↗
USGS1981

Stream-temperature patterns of the Muddy Creek basin, Anne Arundel County, Maryland

Using a water-balance equation based on a 4.25-year gaging-station record on North Fork Muddy Creek, the following mean annual values were obtained for the Muddy Creek basin: precipitation, 49.0 inches; evapotranspiration, 28.0 inches; runoff, 18.5 inches; and underflow, 2.5 inches. Average freshwater outflow from the Muddy Creek basin to the Rhode River estuary was 12.2 cfs during the period October 1, 1971, to December 31, 1975. Harmonic equations were used to describe seasonal maximum and minimum stream-temperature patterns at 12 sites in the basin. These equations were fitted to continuous water-temperature data obtained periodically at each site between November 1970 and June 1978. The harmonic equations explain at least 78 percent of the variance in maximum stream temperatures and 81 percent of the variance in minimum temperatures. Standard errors of estimate averaged 2.3C (Celsius) for daily maximum water temperatures and 2.1C for daily minimum temperatures. Mean annual water temperatures developed for a 5.4-year base period ranged from 11.9C at Muddy Creek to 13.1C at Many Fork Branch. The largest variations in stream temperatures were detected at thermograph sites below ponded reaches and where forest coverage was sparse or missing. At most sites the largest variations in daily water temperatures were recorded in April whereas the smallest were in September and October. The low thermal inertia of streams in the Muddy Creek basin tends to amplify the impact of surface energy-exchange processes on short-period stream-temperature patterns. Thus, in response to meteorologic events, wide ranging stream-temperature perturbations of as much as 6C have been documented in the basin. (USGS)

Water-Resources Investigations Report↗
USGS2016

Purgeable organic compounds at or near the Idaho Nuclear Technology and Engineering Center, Idaho National Laboratory, Idaho, 2015

During 2015, the U.S. Geological Survey, in cooperation with the U.S. Department of Energy, collected groundwater samples from 31 wells at or near the Idaho Nuclear Technology and Engineering Center (INTEC) at the Idaho National Laboratory for purgeable organic compounds (POCs). The samples were collected and analyzed for the purpose of evaluating whether purge water from wells located inside an areal polygon established downgradient of the INTEC must be treated as a Resource Conservation and Recovery Act listed waste. POC concentrations in water samples from 29 of 31 wells completed in the eastern Snake River Plain aquifer were greater than their detection limit, determined from detection and quantitation calculation software, for at least one to four POCs. Of the 29 wells with concentrations greater than their detection limits, only 20 had concentrations greater than the laboratory reporting limit as calculated with detection and quantitation calculation software. None of the concentrations exceeded any maximum contaminant levels established for public drinking water supplies. Most commonly detected compounds were 1,1,1-trichoroethane, 1,1-dichloroethene, and trichloroethene.

Idaho↗
USGS2012

Estimation of evaporation from open water - A review of selected studies, summary of U.S. Army Corps of Engineers data collection and methods, and evaluation of two methods for estimation of evaporation from five reservoirs in Texas

Organizations responsible for the management of water resources, such as the U.S. Army Corps of Engineers (USACE), are tasked with estimation of evaporation for water-budgeting and planning purposes. The USACE has historically used Class A pan evaporation data (pan data) to estimate evaporation from reservoirs but many USACE Districts have been experimenting with other techniques for an alternative to collecting pan data. The energy-budget method generally is considered the preferred method for accurate estimation of open-water evaporation from lakes and reservoirs. Complex equations to estimate evaporation, such as the Penman, DeBruin-Keijman, and Priestley-Taylor, perform well when compared with energy-budget method estimates when all of the important energy terms are included in the equations and ideal data are collected. However, sometimes nonideal data are collected and energy terms, such as the change in the amount of stored energy and advected energy, are not included in the equations. When this is done, the corresponding errors in evaporation estimates are not quantifiable. Much simpler methods, such as the Hamon method and a method developed by the U.S. Weather Bureau (USWB) (renamed the National Weather Service in 1970), have been shown to provide reasonable estimates of evaporation when compared to energy-budget method estimates. Data requirements for the Hamon and USWB methods are minimal and sometimes perform well with remotely collected data. The Hamon method requires average daily air temperature, and the USWB method requires daily averages of air temperature, relative humidity, wind speed, and solar radiation. Estimates of annual lake evaporation from pan data are frequently within 20 percent of energy-budget method estimates. Results of evaporation estimates from the Hamon method and the USWB method were compared against historical pan data at five selected reservoirs in Texas (Benbrook Lake, Canyon Lake, Granger Lake, Hords Creek Lake, and Sam Rayburn Lake) to evaluate their performance and to develop coefficients to minimize bias for the purpose of estimating reservoir evaporation with accuracies similar to estimates of evaporation obtained from pan data. The modified Hamon method estimates of reservoir evaporation were similar to estimates of reservoir evaporation from pan data for daily, monthly, and annual time periods. The modified Hamon method estimates of annual reservoir evaporation were always within 20 percent of annual reservoir evaporation from pan data. Unmodified and modified USWB method estimates of annual reservoir evaporation were within 20 percent of annual reservoir evaporation from pan data for about 91 percent of the years compared. Average daily differences between modified USWB method estimates and estimates from pan data as a percentage of the average amount of daily evaporation from pan data were within 20 percent for 98 percent of the months. Without any modification to the USWB method, average daily differences as a percentage of the average amount of daily evaporation from pan data were within 20 percent for 73 percent of the months. Use of the unmodified USWB method is appealing because it means estimates of average daily reservoir evaporation can be made from air temperature, relative humidity, wind speed, and solar radiation data collected from remote weather stations without the need to develop site-specific coefficients from historical pan data. Site-specific coefficients would need to be developed for the modified version of the Hamon method.

Texas↗
USGS2015

Mining for metals in society's waste

Metals are crucial to society and enable our modern standard of living. Look around and you can't help but see products made of metals. For instance, a typical gasoline-powered automobile contains over a ton of iron and steel, 240 pounds of aluminum, 42 pounds of copper, 41 pounds of silicon, 22 pounds of zinc and more than 30 other mineral commodities including titanium, platinum and gold. Metals and minerals are natural resources that human beings have been mining for thousands of years. Contemporary metal mining is dominated by iron ore, copper and gold, with 2 billion tons of iron ore, nearly 20 million tons of copper and 2,000 tons of gold produced every year. Tens to hundreds of tons of other metals that are essential components for electronics, green energy production, and high-technology products are produced annually.

The Conversation↗
USGS2008

Global daily reference evapotranspiration modeling and evaluation

Accurate and reliable evapotranspiration (ET) datasets are crucial in regional water and energy balance studies. Due to the complex instrumentation requirements, actual ET values are generally estimated from reference ET values by adjustment factors using coefficients for water stress and vegetation conditions, commonly referred to as crop coefficients. Until recently, the modeling of reference ET has been solely based on important weather variables collected from weather stations that are generally located in selected agro-climatic locations. Since 2001, the National Oceanic and Atmospheric Administration’s Global Data Assimilation System (GDAS) has been producing six-hourly climate parameter datasets that are used to calculate daily reference ET for the whole globe at 1-degree spatial resolution. The U.S. Geological Survey Center for Earth Resources Observation and Science has been producing daily reference ET (ETo) since 2001, and it has been used on a variety of operational hydrological models for drought and streamflow monitoring all over the world. With the increasing availability of local station-based reference ET estimates, we evaluated the GDAS-based reference ET estimates using data from the California Irrigation Management Information System (CIMIS). Daily CIMIS reference ET estimates from 85 stations were compared with GDAS-based reference ET at different spatial and temporal scales using five-year daily data from 2002 through 2006. Despite the large difference in spatial scale (point vs . ∼100 km grid cell) between the two datasets, the correlations between station-based ET and GDAS-ET were very high, exceeding 0.97 on a daily basis to more than 0.99 on time scales of more than 10 days. Both the temporal and spatial correspondences in trend/pattern and magnitudes between the two datasets were satisfactory, suggesting the reliability of using GDAS parameter-based reference ET for regional water and energy balance studies in many parts of the world. While the study revealed the potential of GDAS ETo for large-scale hydrological applications, site-specific use of GDAS ETo in complex hydro-climatic regions such as coastal areas and rugged terrain may require the application of bias correction and/or disaggregation of the GDAS ETo using downscaling techniques.

Journal of the American Water Resources Associatio↗
USGS2023

A novel non-destructive workflow for examining germanium and co-substituents in ZnS

A suite of complementary techniques was used to examine germanium (Ge), a byproduct critical element, and co-substituent trace elements in ZnS and mine wastes from four mineral districts where germanium is, or has been, produced within the United States. This contribution establishes a comprehensive workflow for characterizing Ge and other trace elements, which captures the full heterogeneity of samples through extensive pre-characterization. This process proceeded from optical microscopy, to scanning electron microscopy and cathodoluminescence (CL) imaging, to electron microprobe analysis, prior to synchrotron-based investigations. Utilizing non-destructive techniques enabled reanalysis, which proved essential for verifying observations and validating unexpected results. In cases where the Fe content was <0.3 wt% in ZnS, cathodoluminescence imaging proved to be an efficient means to qualitatively identify trace element zonation that could then be further explored by other micro-focused techniques. Micro-focused X-ray diffraction was used to map the distribution of the non-cubic ZnS polymorph, whereas micro-focused X-ray fluorescence (μ-XRF) phase mapping distinguished between Ge 4+ hosted in primary ZnS and a weathering product, hemimorphite [Zn 4 Si 2 O 7 (OH) 2 ·H 2 O]. Microprobe data and μ-XRF maps identified spatial relationships among trace elements in ZnS and implied substitutional mechanisms, which were further explored using Ge and copper (Cu) X-ray absorption near-edge spectroscopy (XANES). Both oxidation states of Ge (4+ and 2+) were identified in ZnS along with, almost exclusively, monovalent Cu. However, the relative abundance of Ge oxidation states varied among mineral districts and, sometimes, within samples. Further, bulk XANES measurements typically agreed with micro-focused XANES (μ-XANES) spectra, but unique micro-environments were detected, highlighting the importance of complementary bulk and micro-focused measurements. Some Ge μ-XANES utilized a high energy resolution fluorescence detector, which improved spectral resolution and spectral signal-to-noise ratio. This detector opens new opportunities for exploring byproduct critical elements in complex matrices. Overall, the non-destructive workflow employed here can be extended to other byproduct critical elements to more fully understand fundamental ore enrichment processes, which have practical implications for critical element exploration, resource quantification, and extraction.

Frontiers in Earth Science↗
USGS2001

Effects of exotic species on Yellowstone's grizzly bears

Humans have affected grizzly bears ( Ursus arctos horribilis ) by direct mortality, competition for space and resources, and introduction of exotic species. Exotic organisms that have affected grizzly bears in the Greater Yellowstone Area include common dandelion ( Taraxacum officinale ), nonnative clovers ( Trifolium spp.), domesticated livestock, bovine brucellosis ( Brucella abortus ), lake trout ( Salvelinus namaycush ), and white pine blister rust ( Cronartium ribicola ). Some bears consume substantial amounts of dandelion and clover. However, these exotic foods provide little digested energy compared to higher-quality bear foods. Domestic livestock are of greater energetic value, but use of this food by bears often leads to conflicts with humans and subsequent increases in bear mortality. Lake trout, blister rust, and brucellosis diminish grizzly bears foods. Lake trout prey on native cutthroat trout ( Oncorhynchus clarkii ) in Yellowstone Lake; white pine blister rust has the potential to destroy native whitebark pine ( Pinus albicaulis ) stands; and management response to bovine brucellosis, a disease found in the Yellowstone bison (Bison bison) and elk ( Cervus elaphus ), could reduce populations of these 2 species. Exotic species will likely cause more harm than good for Yellowstone grizzly bears. Managers have few options to mitigate or contain the impacts of exotics on Yellowstone's grizzly bears. Moreover, their potential negative impacts have only begun to unfold. Exotic species may lead to the loss of substantial highquality grizzly bear foods, including much of the bison, trout, and pine seeds that Yellowstone grizzly bears currently depend upon.

Wyoming↗
USGS2016

The chemistry and isotopic composition of waters in the low-enthalpy geothermal system of Cimino-Vico Volcanic District, Italy

Geothermal energy exploration is based in part on interpretation of the chemistry, temperature, and discharge rate of thermal springs. Here we present the major element chemistry and the δD, δ 18 O, 87 Sr/ 86 Sr and δ 11 B isotopic ratio of groundwater from the low-enthalpy geothermal system near the city of Viterbo in the Cimino-Vico volcanic district of west-Central Italy. The geothermal system hosts many thermal springs and gas vents, but the resource is still unexploited. Water chemistry is controlled by mixing between low salinity,HCO 3 -rich fresh waters (<24.2°C) flowing in shallow volcanic rocks and SO 4 -rich thermal waters (25.3°C to 62.2°C) ascending from deep, high permeability Mesozoic limestones. The (equivalent) SO 4 /Cl (0.01–0.02), Na/Cl (2.82–5.83) and B/Cl ratios (0.02–0.38) of thermal waters differs from the ratios in other geothermal systems from Central Italy, probably implying a lack of hydraulic continuity across the region. The δ 18 O (−6.6‰ to −5.9‰) and δD (−40.60‰ to −36.30‰) isotopic composition of spring water suggest that the recharge area for the geothermal system is the summit region of Mount Cimino. The strontium isotope ratios ( 87 Sr/ 86 Sr) of thermal waters (0.70797–0.70805) are consistent with dissolution of the Mesozoic evaporite-carbonate units that constitute the reservoir, and the ratios of cold fresh waters mainly reflect shallow circulation through the volcanic cover and some minor admixture (<10%) of thermal water as well. The boron isotopic composition (δ 11 B) of fresh waters (−5.00 and 6.12‰) is similar to that of the volcanic cover, but the δ 11 B of thermal waters (−8.37‰ to −4.12‰) is a mismatch for the Mesozoic reservoir rocks and instead reflects dissolution of secondary boron minerals during fluid ascent through flysch units that overlie the reservoir. A slow and tortuous ascent enhances extraction of boron but also promotes conductive cooling, partially masking the heat present in the reservoir. Overall data from this study is consistent with previous studies that concluded that the geothermal system has a large energy potential.

Journal of Volcanology and Geothermal Research↗