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At least 1,117 records · Page 62Linked to original sources

USGS2008

Reconnaissance study of water quality in the mining-affected Aries River Basin, Romania

The Aries River basin of western Romania has been subject to mining activities as far back as Roman times. Present mining activities are associated with the extraction and processing of various metals including Au, Cu, Pb, and Zn. To understand the effects of these mining activities on the environment, this study focused on three objectives: (1) establish a baseline set of physical parameters, and water- and sediment-associated concentrations of metals in river-valley floors and floodplains; (2) establish a baseline set of physical and chemical measurements of pore water and sediment in tailings; and (3) provide training in sediment and water sampling to personnel in the National Agency for Mineral Resources and the Rosia Poieni Mine. This report summarizes basin findings of physical parameters and chemistry (sediment and water), and ancillary data collected during the low-flow synoptic sampling of May 2006.

Aries River Basin↗

USGS2003

Analysis of tests of subsurface injection, storage, and recovery of freshwater in Lancaster, Antelope Valley, California

Ground-water levels in Lancaster, California, declined more than 200 feet during the 20th century, resulting in reduced ground-water supplies and more than 6 feet of land subsidence. Facing continuing population growth, water managers are seeking solutions to these problems. Injection of imported, treated fresh water into the aquifer system when it is most available and least expensive, for later use during high-demand periods, is being evaluated as part of a management solution. The U.S. Geological Survey, in cooperation with the Los Angeles County Department of Public Works and the Antelope Valley-East Kern Water Agency, monitored a pilot injection program, analyzed the hydraulic and subsidence-related effects of injection, and developed a simulation/optimization model to help evaluate the effectiveness of using existing and proposed wells in an injection program for halting the decline of ground-water levels and avoiding future land subsidence while meeting increasing ground-water demand. A variety of methods were used to measure aquifer-system response to injection. Water levels were measured continuously in nested (multi-depth) piezometers and monitoring wells and periodically in other wells that were within several miles of the injection site. Microgravity surveys were done to estimate changes in the elevation of the water table in the absence of wells and to estimate specific yield. Aquifer-system deformation was measured directly and continuously using a dual borehole extensometer and indirectly using continuous Global Positioning System (GPS), first-order spirit leveling, and an array of tiltmeters. The injected water and extracted water were sampled periodically and analyzed for constituents, including chloride and trihalomethanes. Measured injection rates of about 750 gallons per minute (gal/min) per well at the injection site during a 5-month period showed that injection at or above the average extraction rates at that site (about 800 gal/min) was hydraulically feasible. Analyses of these data took many forms. Coupled measurements of gravity and water-level change were used to estimate the specific yield near the injection wells, which, in turn, was used to estimate areal water-table changes from distributed measurements of gravity change. Values of the skeletal components of aquifer-system storage, which are key subsidence-related characteristics of the system, were derived from continuous measurements of water levels and aquifer-system deformation. A numerical model of ground-water flow was developed for the area surrounding Lancaster and used to estimate horizontal and vertical hydraulic conductivities. A chemical mass balance was done to estimate the recovery of injected water. The ground-water-flow model was used to project changes in ground-water levels for 10 years into the future, assuming no injection, no change in pumping distribution, and forecasted increases in ground-water demand. Simulated ground-water levels decreased throughout the Lancaster area, suggesting that land subsidence would continue as would the depletion of ground-water supplies and an associated loss of well production capacity. A simulation/optimization model was developed to help identify optimal injection and extraction rates for 16 existing and 13 proposed wells to avoid future land subsidence and to minimize loss of well production capacity while meeting increasing ground-water demands. Results of model simulations suggest that these objectives can be met with phased installation of the proposed wells during the 10-year period. Water quality was not considered in the optimization, but chemical-mass-balance results indicate that a sustained injection program likely would have residual effects on the chemistry of ground water.

Califronia↗

USGS1996

Geologic history and hydrogeologic units of intermontane basins of the northern Rocky Mountains, Montana and Idaho

The Regional Aquifer-System Analysis (RASA) program is a series of studies by the U.S. Geological Survey (USGS) to analyze regional ground-water systems that compose a major portion of the Nation’s water supply (Sun, 1986). The Northern Rocky Mountains Intermontane Basins is one of the study regions in this national program. The main objectives of the RASA studies are to: (1) describe the ground-water systems as they exist today, (2) analyze the known changes that have led to the system's present condition, (3) combine results of previous studies in a regional analysis, where possible, and (4) provide means by which effects of future ground-water development can be estimated. The purpose of this study, which began in 1990, was to increase understanding of the hydrogeology of the intermontane basins of the Northern Rocky Mountains area. This report is Chapter Cofa three-part series and describes the quality of ground-water and surface water in the study area. Chapter A (Tück and others, 1996) describes the geologic history and generalized hydrogeologic units. Chapter B (Briar and others, 1996) describes the general distribution of ground-watcrlcwels in basin-fill deposits, Water-quality data illustrated in this report represent the distribution of concentrations and composition of dissolved solids in ground-water and surface water in the intermontane areas. The chemistry of ground and surface water in the intermontane areas is influenced by the chemical and physical nature of the rocks in the basin deposits of the valleys and surrounding bedrock in the mountains.

Hydrologic Atlas↗

USGS1996

Quality of ground water and surface water in intermontane basins of the northern Rocky Mountains, Montana and Idaho

The Regional Aquifer-System Analysis (RASA) program is a series of studies by the U.S. Geological Survey (USGS) to analyze regional ground-water systems that compose a major portion of the Nations water supply (Sun, 1986). The Northern Rocky Mountains Intermontane Basins is one of the study regions in this national program. The main objectives of the RASA studies are to: (1) describe the ground-water systems as they exist today, (2) analyze the known changes that have led to the system's present condition, (3) combine results of previous studies in a regional analysis, where possible, and (4) provide means by which effects of future ground-water development can be estimated. The purpose of this study, which began in 1990, was to increase understanding of the hydrogeology of the intermontane basins of the Northern Rocky Mountains area. This report is Chapter C of a three-part series and describes the quality of ground water and surface water in the study area. Chapter A (Tuck and others, 1996) describes the geologic history and generalized hydrogeologic units. Chapter B (Briar and others, 1996) describes the general distribution of ground-water levels in basin-fill deposits. Water-quality data illustrated in this report represent the distribution of concentrations and composition of dissolved solids in ground water and surface water in the intermontane areas. The chemistry of ground and surface water in the intermontane areas is influenced by the chemical and physical nature of the rocks in the basin deposits of the valleys and surrounding bedrock in the mountains.

Hydrologic Atlas↗

USGS2021

An assessment of uranium in groundwater in the Grand Canyon region

The Grand Canyon region in northern Arizona is a home or sacred place of origin for many Native Americans and is visited by over 6 million tourists each year. Most communities in the area depend upon groundwater for all water uses. Some of the highest-grade uranium ore in the United States also is found in the Grand Canyon region. A withdrawal of over 1 million acres of Federal land in the Grand Canyon region from new uranium mining activities for 20 years was instituted in 2012, owing in part to a lack of scientific data on potential effects from uranium mining on water resources in the area. The USGS collects groundwater chemistry samples in the Grand Canyon region to understand the current state of groundwater quality, to monitor for changes in groundwater quality that may be the result of mining activities, and to identify "hot spots" with elevated metal concentrations and investigate the causes. This manuscript presents results for the assessment of uranium in groundwater in the Grand Canyon region. Analytical results for uranium in groundwater in the Grand Canyon region were available for 573 samples collected from 180 spring sites and 26 wells from September 1, 1981 to October 7, 2020. Samples were collected from springs issuing from stratigraphic units above, within, and below the Permian strata that hosts uranium ore in breccia pipes in the area. Maximum uranium concentrations at groundwater sites in the region ranged from less than 1 µg/L at 23 sites (11%) to 100 µg/L or more at 4 sites (2%). Of the 206 groundwater sites sampled, 195 sites (95%) had maximum observed uranium concentrations less than the USEPA Maximum Contaminant Level of 30 µg/L and 177 sites (86%) had uranium concentrations less than the 15 µg/L Canadian benchmark for protection of aquatic life in freshwater. The establishment of baseline groundwater quality is an important first step in monitoring for change in water chemistry throughout mining lifecycles and beyond to ensure the health of these critical groundwater resources.

Arizona↗

USGS1983

Preliminary appraisal of the hydrology of the Rock Island area, Le Flore County, Oklahoma

Bed rock in the Rock Island area of northeastern Le Flore County in southeastern Oklahoma consists of shale, siltstone, and sandstone of the McAlester, Hartshorne, and Atoka Formations of Pennsylvanian age. The area is on the south flank of the Backbone anticline; the rocks dip to the south at 5o-45o. Alluvium along James Fork consists of sandy and clayey silt and may be as much as 30 feet thick. Water in bedrock is under artesian conditions. The depth to water in most wells is less than 20 feet below the surface; a few wells flow. Yields of most wells probably are less than 5 gallons per minute. Water from nine wells was a sodium carbonate or sodium mixed anion type; dissolved-solids concentrations ranged from 294 to 1,250 milligrams per liter. No relationship between variations in chemistry of ground water and well depth, geographic distribution, or geologic formation is apparent. James Fork has flow most of the time and discharge exceeds 25 cubic feet per second about one-half the time. The mean dissolved-solids concentration in James Fork water ranged from 224 milligrams per liter near Williams, Oklahoma, to 332 milligrams per liter near Hackett, Arkansas. Water in James Fork is a calcium magnesium sulfate type about 75 percent of the time. Maximum suspended sediment discharge was 2,720 tons per day. Silt-clay particles (diameters less than 0.062 millimeter) are the dominant sediment size. Potential hydrologic effects of surface mining for coal include: (1) Creation of additional water storage in surface-mine ponds, (2) changes in rock permeability and ground-water storage, (3) changes in runoff and streamflow characteristics, (4) changes in drainage patterns, and (5) changes in the chemical quality and sediment load of James Fork. Although mining may increase the quantities of sediment and dissolved minerals added to James Fork, detection of these increases would be difficult because the potentially mineable area is very small in proportion to the total area of the basin.

Water-Resources Investigations Report↗

USGS1988

Ground-water geochemistry of the Albuquerque-Belen Basin, central New Mexico

The purpose of this study was to define the areal distribution of different water types, use the distribution to help define the groundwater flow system, and identify processes resulting in differences in groundwater quality in the Albuquerque-Belen Basin in central New Mexico. The chemistry of surface water inflow from adjacent areas, which infiltrates and recharges the aquifer along the basin margin, affects the groundwater quality in the eastern and southeastern areas of the basin. Groundwater in the eastern area generally has a specific conductance less than 400 microsiemens, and calcium and bicarbonate are the dominant ions. Mixing of recharge, groundwater inflow, and surface inflow from adjacent areas, which have different chemical compositions, is the major process affecting groundwater quality in the southwestern, western, and northern areas of the basin. In these areas, there is a large range in specific conductance and distribution of dissolved ions. Groundwater quality in the Rio Grande valley is affected by the infiltration of excess irrigation water. The excess irrigation water generally has a larger specific conductance than other groundwater in the valley, so mixing of these waters results in shallow groundwater generally having larger specific conductance than the deeper groundwater. (USGS)

New Mexico↗

USGS2014

Preliminary geochemical assessment of water in selected streams, springs, and caves in the Upper Baker and Snake Creek drainages in Great Basin National Park, Nevada, 2009

Water in caves, discharging from springs, and flowing in streams in the upper Baker and Snake Creek drainages are important natural resources in Great Basin National Park, Nevada. Water and rock samples were collected from 15 sites during February 2009 as part of a series of investigations evaluating the potential for water resource depletion in the park resulting from the current and proposed groundwater withdrawals. This report summarizes general geochemical characteristics of water samples collected from the upper Baker and Snake Creek drainages for eventual use in evaluating possible hydrologic connections between the streams and selected caves and springs discharging in limestone terrain within each watershed. Generally, water discharging from selected springs in the upper Baker and Snake Creek watersheds is relatively young and, in some cases, has similar chemical characteristics to water collected from associated streams. In the upper Baker Creek drainage, geochemical data suggest possible hydrologic connections between Baker Creek and selected springs and caves along it. The analytical results for water samples collected from Wheelers Deep and Model Caves show characteristics similar to those from Baker Creek, suggesting a hydrologic connection between the creek and caves, a finding previously documented by other researchers. Generally, geochemical evidence does not support a connection between water flowing in Pole Canyon Creek to that in Model Cave, at least not to any appreciable extent. The water sample collected from Rosethorn Spring had relatively high concentrations of many of the constituents sampled as part of this study. This finding was expected as the water from the spring travelled through alluvium prior to being discharged at the surface and, as a result, was provided the opportunity to interact with soil minerals with which it came into contact. Isotopic evidence does not preclude a connection between Baker Creek and the water discharging from Rosethorn Spring. The residence time of water discharging into the caves and from selected springs sampled as part of this study ranged from 10 to 25 years. Within the upper Snake Creek drainage, the results of this study show geochemical similarities between Snake Creek and Outhouse Spring, Spring Creek Spring, and Squirrel Spring Cave. The strontium isotope ratio ( 87 Sr/ 86 Sr) for intrusive rock samples representative of the Snake Creek drainage were similar to carbonate rock samples. The water sample collected from Snake Creek at the pipeline discharge point had lower strontium concentrations than the sample downstream and a similar 87 Sr/ 86 Sr value as the carbonate and intrusive rocks. The chemistry of the water sample was considered representative of upstream conditions in Snake Creek and indicates minimal influence of rock dissolution. The results of this study suggest that water discharging from Outlet Spring is not hydrologically connected to Snake Creek but rather is recharged at high altitude(s) within the Snake Creek drainage. These findings for Outlet Spring largely stem from the relatively high specific conductance and chloride concentration, the lightest deuterium (δD) and oxygen-18 (δ 18 O) values, and the longest calculated residence time (60 to 90 years) relative to any other sample collected as part of this study. With the exception of water sampled from Outlet Spring, the residence time of water discharging into Squirrel Spring Cave and selected springs in the upper Snake Creek drainage was less than 30 years.

Nevada↗

USGS2015

Hydrology of the middle San Pedro area, southeastern Arizona

In the middle San Pedro Watershed in southeastern Arizona, groundwater is the primary source of water supply for municipal, domestic, industrial, and agricultural use. The watershed comprises two smaller subareas, the Benson subarea and the Narrows-Redington subarea. Early 21st century projections for heavy population growth in the watershed have not yet become a reality, but increased groundwater withdrawals could have undesired consequences - such as decreased base flow to the San Pedro River, and groundwater-level declines - that would lead to the need to deepen existing wells. This report describes the hydrology, hydrochemistry, water quality, and development of a groundwater budget for the middle San Pedro Watershed, focusing primarily on the elements of groundwater movement that could be most useful for the development of a groundwater model Precipitation data from Tombstone, Arizona, and base flow at the stream-gaging station on the San Pedro River at Charleston both show relatively dry periods during the 1960s through the mid-1980s and in the mid-1990s to 2009, and wetter periods from the mid-1980s through the mid-1990s. Water levels in four out of five wells near the mountain fronts show cyclical patterns of recharge, with rates of recharge greatest in the early 1980s through the mid-1990s. Three wells near the San Pedro River recorded their lowest levels during the 1950s to the mid-1960s. The water-level record from one well, completed in the confined part of the coarse-grained lower basin fill, showed a decline of approximately 21 meters. Annual flow of the San Pedro River, measured at the Charleston and Redington gages, has decreased since the 1940s. The median annual streamflow and base flow at the gaging station on the river near Tombstone has decreased by 50 percent between the periods 1968–1986 and 1997–2009. Estimates of streamflow infiltration along the San Pedro River during 1914–2009 have decreased 44 percent, with the largest decreases in the months June–October in the Benson subarea. In the Narrows-Redington subarea, streamflow infiltration has decreased about 65 percent during 1914–2009. The average annual outflow (27.6 hm 3 /year [cubic hectometers per year]) from the Benson subarea aquifer for water years 2001 through 2009 exceeded the inflows (20.0 hm 3 / yr) by 7.60 hm 3 /yr. In the Narrows-Redington subarea for the same period, the average annual outflow (15.7 hm 3 /yr) from the aquifer system exceeded the inflows (13.8 hm 3 /yr) by nearly 2 hm 3 /yr. The largest withdrawals of groundwater in both subareas are for irrigation; these withdrawals peaked in 1973 and have been steadily decreasing since then. Recharge from streamflow infiltration exceeded recharge from the mountain-front and from ephemeral channels in the Benson subarea. In the Narrows-Redington subarea, however, recharge from mountain-front and ephemeral channel recharge exceeded recharge from streamflow infiltration. Evapotranspiration by phreatophytes accounts for the largest outflow of groundwater for both subareas—78 percent of the outflow in the Narrows-Redington subarea and 62 percent of the outflow in the Benson subarea. Precipitation, surface-water, and groundwater chemistry and isotope data indicated the relative age and residence time of groundwater, the amount of interaction between geologic sources and groundwater, and how recharge elevation and season were related to the presence of modern water. The bedrock aquifer receives modern recharge (

Arizona↗

USGS1972

Interstitial water studies on small core samples, leg XI

The sediments cored at Sites 98, 99 and 100 are predominantly biogenic; those cored at Sites 101 through 106 are composed mainly of terrigenous material. As reported previously, most constituents in pore waters from the biogenic oozes exhibit minor changes in chemistry relative to sea water. In the terrigenous-hemipelagic sediments interstitial solutions initially of sea water composition have undergone considerable reaction. These reactions have produced large changes in the concentrations of calcium (Ca), magnesium (Mg), sulfate (SO 4 ) and HCO 3 relative to sea water. In addition, this set of samples documents significant diagenetic alteration of sodium (Na) and chloride (Cl). Potassium exhibits little change in most samples, but in a few instances is depleted at depth. The analytical techniques employed are identical to those described in earlier volumes of the Initial Reports of the Deep Sea Drilling Project. In an effort to identify alteration of sample composition during storage, salinity determinations 2 are made on the pore solution immediately upon their recovery from the sediments. The same measurement is made in the laboratory when the sample containers are opened for analysis. Occasionally evidence of evaporation is found as in Sample 104-2-5; the shipboard salinity was 32%o, while the laboratory measurement yielded 38%o. Changes of 3 to 4 per cent were also noted in several other samples as noted in the tables. Adjustment of the analytically determined concentrations has been made and the corrected values presented in Tables 1 and 2. A large part of the work involved in the analyses of these samples has been done by Irene Uhlitzsch; we are indebted to her for the invaluable assistance she has rendered.

Initial reports of the Deep Sea Drilling Project↗

USGS1988

General hydrogeology of the aquifers of Mesozoic age, Upper Colorado River Basin - excluding the San Juan Basin - Colorado, Utah, Wyoming, and Arizona

The objective of the Upper Colorado Regional Aquifer Systems Analyses (RASA) project is to assess quantitatively the occurrence, movement, and availability of water stored in rock formations underlying the basin. This is one of a series of preliminary reports that describe what is currently known (1984) about the geometry and hydrologic properties of the aquifer systems, and the chemistry of the water in known or potential aquifers. This report provides the foundation needed for the assessment of the ground-water resources of the region. The report describes only part of the hydrologic system; that is, formations of Mesozoic age. Younger and older formations significant to the hydrologic system are described in other reports.

Arizona, Colorado, Utah, Wyoming↗

USGS2000

Regional ground-water flow and geochemistry in the midwestern Basins and Arches aquifer system in parts of Indiana, Ohio, Michigan, and Illinois

This report synthesizes information on the regional ground-water flow and geochemistry in the Midwestern Basins and Arches aquifer system in parts of Indiana, Ohio, Michigan, and Illinois. Aquifers that compose this water-table aquifer system include glacial aquifers and an underlying, areally extensive carbonate-rock aquifer. Water within the aquifers is most commonly a Ca-Mg-HCO 3 type or a Ca-Mg-SO 4 type. In general, the distribution of hydrochemical facies within the aquifer system is controlled by the mineralogy of the aquifer material, rather than by a chemical evolution of water along general directions of regional ground-water flow. Some ground-water flow systems within the aquifer system provide base flow to streams in response to ground-water recharge events. Other (often deeper) ground-water flow systems respond minimally to variations in ground-water recharge from precipitation and provide a fairly constant supply of water to streams. Streamflow hydrographs and base-flow duration curves were used to estimate such components of base flow in selected streams for long-term steady-state conditions in the aquifer system. Mean sustained ground-water discharge (discharge from fairly stable ground-water flow systems) ranges from 3 to 50 percent of mean ground-water discharge (discharge from all ground-water flow systems) to the selected stream reaches. These percentages indicate that 50 to 97 percent of base flow in the streams within the study area can be attributed to transient ground-water flow systems, which typically have a major component of local-scale flow. Because ground-water flow across the external boundaries of the aquifer system is minimal, such percentages indicate that most ground-water flow in the aquifer system is associated with seasonally transient local flow systems. Results of a ground-water flow model that was calibrated by use of regression methods and that simulates regional flow systems within the aquifer system (approximately 10 percent of total ground-water flow in the aquifer system) indicate that most water (99 percent) in simulated regional flow systems is from recharge at the water table. Most water (78 percent) discharges from simulated regional flow systems to the principal streams. Less than 3 percent of water in simulated regional flow systems discharges to the Ohio River, Lake Erie, or downdip areas in the Illinois (structural) Basin. Simulations also indicate that most of the Midwestern Basins and Arches aquifer system is characterized by alternating regional recharge and discharge areas at intervals of less than every 10 miles along the dominant regional trends of the potentiometric surfaces in the aquifers. Such alternating regional recharge and discharge areas result in the absence of long flow paths from the very highest regional potentiometric levels to the very lowest regional potentiometric levels. The presence of tritiated ground water (less than 50 years old) across most of the aquifer system also indicates that the aquifer system receives recharge across most of the study area. The northeastern part of the aquifer system near Lake Erie differs from the rest of the system with respect to regional ground-water flow and chemistry. Specifically, part of the northeastern part of the aquifer system can be characterized as a broad area (tens of miles) of weak regional discharge (less than 0.5 inch per year). Results of the regional ground-water flow model indicate that regional flow systems have a limited ability to carry ground water away from this area; thus precipitation is prevented from recharging the regional flow systems in this part of the aquifer system. Some ground water recharged during Pleistocene glaciation was found in this area.

Illinois, Indiana, Michigan, Ohio↗

USGS2007

River Chemistry and Solute Flux in Yellowstone National Park

Introduction The Yellowstone Volcano Observatory (YVO) was established to 'To strengthen the long-term monitoring of volcanic and earthquake unrest in the Yellowstone National Park region'. Yellowstone National Park is underlain by a voluminous magmatic system overlain by the most active hydrothermal system on Earth. Tracking changes in water and gas chemistry is of great importance because anomalous fluxes might signal one of the earliest warnings of volcanic unrest. Because of the tremendous number, chemical diversity, and large aerial coverage of Yellowstone's thermal features, it remains daunting to monitor individual features that might serve as proxies for anomalous activity in the hydrothermal system. Sampling rivers provides some advantages, because they integrate chemical fluxes over a very large area and therefore, river fluxes may reveal large-scale spatial patterns (Hurwitz et al., 2007). In addition, based on the application of the chloride-enthalpy method (Fournier, 1979), quantifying chloride flux in rivers provides an estimate of the total heat discharge from the Yellowstone volcanic system (Norton and Friedman 1985; Fournier, 1989; Friedman and Norton, in press). Intermittent sampling of the large rivers draining Yellowstone National Park began in the 1960's (Fournier et al., 1976) and continuous sampling has been carried out since water year (1 October - 30 September) 1983 excluding water years 1995 and 1996 (Norton and Friedman, 1985, 1991; Friedman and Norton, 1990, 2000, 2007). Between 1983 and 2001 only Cl concentrations and fluxes were determined. Starting in water year 2002, the concentrations and fluxes of other anions of possible magmatic origin (F-, Br-, HCO3- , and SO42-) were also determined, and several new sampling sites were established (Hurwitz et al., 2007). The ongoing sampling and analysis of river solute flux is a key component in the current monitoring program of YVO, and it is a collaboration between the U.S. Geological Survey and Yellowstone National Park.

Data Series↗

USGS1997

Geochemistry and microbiology of iron-related well-screen encrustation and aquifer biofouling in Suffolk County, Long Island, New York

Iron-related well-screen encrustation and aquifer biofouling has decreased the specific capacity of several production wells in Suffolk County, N.Y., and has forced the Suffolk County Water Authority to adopt a costly well-reconditioning and replacement program. The specific-capacity declines are the result of the precipitation of iron oxyhydroxides and the growth of iron bacteria on the well screens and in the pore spaces of the surrounding formation. Mineralogic and chemical analyses indicate that the inorganic part of the encrusting material consists primarily of amorphous ferric hydroxide (Fe(OH)3 ); minor components of the material include goethite (FeOOH), hematite (Fe2 O 3 ), and quartz (SiO 2 ). The weight percent of ferric hydroxide in the material ranged from 32.3 to 98.6 percent and averaged 64.3 percent. Equilibrium modeling indicated that during pumping the well waters were supersaturated with respect to goethite, hematite, magnetite, and quartz and were under-saturated with respect to ferric hydroxide. Theoretical Eh values computed for the ferrous/ferric-iron redox couple and the oxygen/water redox couple averaged 390 millivolts and 810 millivolts, respectively, indicating that the waters were in a state of redox disequilibrium. The disequilibrium condition arises from the mixing of ground water with a low dissolved-oxygen concentration with oxygenated ground water during operation of the well. The low pH of the ground water contributes to the disequilibrium condition by slowing the rate of iron oxidation after the introduction of oxygen. Chemical and mineralogical data indicate that most of the encrusting material in the wells was deposited while the wells were shut down, probably in response to the use of treated water of higher pH to keep pump turbines wet while the wells were not in operation; the increased pH of water in the static water column increases the rate of ferrous-iron oxidation and causes the well water to become increasingly saturated with respect to ferric hydroxide. The median half-time of oxidation in samples of untreated ground water (pH 4-5) was 4.19 days, whereas the average half-time of oxidation in treated water (pH 7-8) was 11.9 minutes Equilibrium modeling indicated that treated waters generally were supersaturated with respect to ferric hydroxide, whereas untreated well waters were not. Field and laboratory data indicate that iron bacteria play an important role in the encrustation and biofouling process in Suffolk County. Filamentous iron bacteria were common in the affected wells. The most common species was Gallionella ferruginea, an effective biofouling agent that prefers water with low, but detectable, dissolved-oxygen concentrations and high dissolved-iron concentrations; this species was more common in biofilm samples from the Magothy aquifer than in those from the upper glacial aquifer. Iron bacteria also were found in sediment cores from several locations in the aquifer and in drilling water. Lignite could act as a carbon source for heterotrophic iron bacteria, which could accelerate the formation of iron-bacteria biofilms in wells screened in some parts of the Magothy aquifer. Iron-bacteria biofilms alter the chemistry of well water by removing iron, manganese, and sulfate from solution and by increasing the pH. Sulfur-reducing bacteria and iron-sulfide mineral phases were observed in some samples of encrusting material, indicating that these bacteria could contribute to well-screen encrustation in some geochemical environments.

Water-Resources Investigations Report↗

USGS2006

U.S. Geological Survey and Bureau of Land Management Cooperative Coalbed Methane Project in the Powder River Basin, Wyoming

The Bureau of Land Management (BLM) Wyoming Reservoir Management Group and the U.S. Geological Survey (USGS) began a cooperative project in 1999 to collect technical and analytical data on coalbed methane (CBM) resources and quality of the water produced from coalbeds in the Wyoming part of the Powder River Basin. The agencies have complementary but divergent goals and these kinds of data are essential to accomplish their respective resource evaluation and management tasks. The project also addresses the general public need for information pertaining to Powder River Basin CBM resources and development. BLM needs, which relate primarily to the management of CBM resources, include improved gas content and gas in-place estimates for reservoir characterization and resource/reserve assessment, evaluation, and utilization. USGS goals include a basinwide assessment of CBM resources, an improved understanding of the nature and origin of coalbed gases and formation waters, and the development of predictive models for the assessment of CBM resources that can be used for such purposes in other basins in the United States (for example, the Bighorn, Greater Green River, and Williston Basins) and in other countries throughout the world (for example, Indonesia, New Zealand, and the Philippines). Samples of coal, produced water, and gas from coalbed methane drill holes throughout the Powder River Basin, many of which are adjacent to several active mine areas (figs. 1, 2), have been collected by personnel in the USGS, BLM Reservoir Management Group, and Casper and Buffalo BLM Field Offices. Sampling was done under confidentiality agreements with 29 participating CBM companies and operators. Analyses run on the samples include coal permeability, coal quality and chemistry, coal petrography and petrology, methane desorption and adsorption, produced-water chemistry, and gas composition and isotopes. The USGS has supplied results to the BLM Reservoir Management Group for their resource management needs, and data are released when the terms of the confidentiality agreements are completed and consent is obtained.

Fact Sheet↗

USGS2008

In situ arsenic removal in an alkaline clastic aquifer

In situ removal of As from ground water used for water supply has been accomplished elsewhere in circum-neutral ground water containing high dissolved Fe(II) concentrations. The objective of this study was to evaluate in situ As ground-water treatment approaches in alkaline ground-water (pH > 8) that contains low dissolved Fe (<a few tens of μg/L). The low dissolved Fe content limits development of significant Fe-oxide and the high-pH limits As adsorption onto Fe-oxide. The chemistries of ground water in the two aquifers studied are similar except for the inorganic As species. Although total inorganic As concentrations were similar, one aquifer has dominantly aqueous As(III) and the other has mostly As(V). Dissolved O 2 , Fe(II), and HCl were added to water and injected into the two aquifers to form Fe-oxide and lower the pH to remove As. Cycles of injection and withdrawal involved varying Fe(II) concentrations in the injectate. The As concentrations in water withdrawn from the two aquifers were as low as 1 and 6 μg/L, with greater As removal from the aquifer containing As(V). However, Fe and Mn concentrations increased to levels greater than US drinking water standards during some of the withdrawal periods. A balance between As removal and maintenance of low Fe and Mn concentrations may be a design consideration if this approach is used for public-supply systems. The ability to lower As concentrations in situ in high-pH ground water should have broad applicability because similar high-As ground water is present in many parts of the world.

Applied Geochemistry↗

USGS2023

Groundwater chemistry and hexavalent chromium

Water samples collected by the U.S. Geological Survey from more than 100 wells between March 2015 and November 2017 in Hinkley and Water Valleys, in the Mojave Desert 80 miles northeast of Los Angeles, California, were analyzed for field parameters, major ions, nutrients, and selected trace elements, including hexavalent chromium, Cr(VI). Water from most wells was alkaline and oxic. The pH ranged from 6.9 in water-table wells near recharge areas along the Mojave River to 9.4 in deeper wells farther downgradient in the northern subarea. Hexavalent chromium concentrations measured by ion chromatography using U.S. Environmental Protection Agency Method 218.6 and a version of that method used for detection of Cr(VI) concentrations as low as 0.06 micrograms per liter (μg/L), produced results comparable to field speciation with subsequent analyses by graphite furnace atomic absorption spectroscopy (coefficient of determination, R 2 , of 0.97). Hexavalent chromium concentrations ranged from less than the study reporting level of 0.10 to 2,500 μg/L. The highest concentrations were within the October–December 2015 (Q4 2015) regulatory Cr(VI) plume downgradient from the Hinkley compressor station. Hexavalent chromium concentrations outside the Q4 2015 regulatory Cr(VI) plume were as high as 11 μg/L. Hexavalent chromium concentrations in water from most wells were distributed in a narrow redox potential and pH band within the overlapping chromate ion, CrO 4 2− (aqueous) , and manganese-3, Mn(III) (solid) , stability fields. The redox potential of water from some wells completed in carbonate-rich mudflat/playa deposits approached the more oxic manganese-4, Mn(IV) (solid) , stability field. However, Cr(VI) concentrations in porewater pressure-extracted from Mn(IV)-containing deposits in the eastern subarea did not exceed 3.3 μg/L, and porewater does not appear to be a source of Cr(VI) concentrations greater than this concentration in water from wells in the eastern subarea. On the basis of comparison with California-wide data, Cr(VI) concentrations at the measured pH were higher than expected for uncontaminated water from wells (1) within the Q4 2015 regulatory Cr(VI) plume, (2) within the eastern subarea nominally crossgradient from the Hinkley compressor station and upgradient from the Q4 2015 regulatory Cr(VI) plume, and (3) from shallow wells in the northern subarea downgradient from the leading edge of the Q4 2015 regulatory Cr(VI) plume. Hexavalent chromium concentrations in alkaline water from wells in the northern subarea of Hinkley Valley and in Water Valley were within ranges expected for uncontaminated water elsewhere in California given their pH and trace-element composition. Hexavalent chromium concentrations were higher than expected on the basis of selected trace-element concentrations that co-occur with Cr(VI) in water from wells within the Q4 2015 regulatory Cr(VI) plume and from wells in the eastern and northern subareas near the plume margins. Hexavalent chromium concentrations did not exceed 4 μg/L in water from domestic wells sampled in Hinkley and Water Valleys and were generally within ranges expected for uncontaminated groundwater given their pH and trace-element composition. Interpretations derived from Cr(VI) and pH, and from Cr(VI) and selected trace-element concentrations collected between March 2015 and November 2017 were used within a summative-scale analysis to determine the Cr(VI) plume extent (chapter G). However, Cr(VI) background concentrations (chapter G) were calculated from regulatory data collected from selected wells between April 2017 and January 2018.

California↗

USGS2005

Managing vegetation in surface-flow wastewater-treatment wetlands for optimal treatment performance

Constructed wetlands that mimic natural marshes have been used as low-cost alternatives to conventional secondary or tertiary wastewater treatment in the U.S. for at least 30 years. However, the general level of understanding of internal treatment processes and their relation to vegetation and habitat quality has not grown in proportion to the popularity of these systems. We have studied internal processes in surface-flow constructed wastewater-treatment wetlands throughout the southwestern U.S. since 1990. At any given time, the water quality, hydraulics, water temperature, soil chemistry, available oxygen, microbial communities, macroinvertebrates, and vegetation each greatly affect the treatment capabilities of the wetland. Inside the wetland, each of these components plays a functional role and the treatment outcome depends upon how the various components interact. Vegetation plays a uniquely important role in water treatment due to the large number of functions it supports, particularly with regard to nitrogen transformations. However, it has been our experience that vegetation management is critical for achieving and sustaining optimal treatment function. Effective water treatment function and good wildlife quality within a surface-flow constructed wetland depend upon the health and sustainability of the vegetation. We suggest that an effective tool to manage and sustain healthy vegetation is the use of hummocks, which are shallow emergent plant beds within the wetland, positioned perpendicular to the water flow path and surrounded by water sufficiently deep to limit further emergent vegetation expansion. In this paper, we describe the use of a hummock configuration, in conjunction with seasonal water level fluctuations, to manage the vegetation and maintain the treatment function of wastewater-treatment wetlands on a sustainable basis.

Ecological Engineering↗