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At least 1,099 records · Page 61Linked to original sources

Dynamics within geyser conduits, and sensitivity to environmental perturbations: insights from a periodic geyser in the El Tatio Geyser Field, Atacama Desert, Chile

Despite more than 200 years of scientific study, the internal dynamics of geyser systems remain poorly characterized. As a consequence, there remain fundamental questions about what processes initiate and terminate eruptions, and where eruptions begin. Over a one-week period in October 2012, we collected down-hole measurements of pressure and temperature in the conduit of an exceptionally regular geyser (132 s/cycle) located in the Chilean desert. We identified four stages in the geyser cycle: (1) recharge of water into the conduit after an eruption, driven by the pressure difference between water in the conduit and in a deeper reservoir; (2) a pre-eruptive stage that follows the recharge and is dominated by addition of steam from below; (3) the eruption, which occurs by rapid boiling of a large mass of water at the top of the water column, and decompression that propagates boiling conditions downward; (4) a relaxation stage during which pressure and temperature decrease until conditions preceding the recharge stage are restored. Eruptions are triggered by the episodic addition of steam coming from depth, suggesting that the dynamics of the eruptions are dominated by geometrical and thermodynamic complexities in the conduit and reservoir. Further evidence favoring the dominance of internal processes in controlling periodicity is also provided by the absence of responses of the geyser to environmental perturbations (air pressure, temperature and probably also Earth tides).

Atacama Desert↗

Experimental investigation of changes in methane adsorption of bitumen-free Woodford Shale with thermal maturation induced by hydrous pyrolysis

This study quantifies the effects of organic-matter (OM) thermal maturity on methane (CH 4 ) sorption, on the basis of five samples that were artificially matured through hydrous pyrolysis achieved by heating samples of immature Woodford Shale under five different time–temperature conditions. CH 4 -sorption isotherms at 35 °C, 50 °C, and 65 °C, and pressures up to 14 MPa on dry, solvent-extracted samples of the artificially matured Woodford Shale were measured. The results showed that CH 4 -sorption capacity, normalized to TOC, varied with thermal maturity, following the trend: maximum oil (367 °C) > oil cracking (400 °C) > maximum bitumen/early oil (333 °C) > early bitumen (300 °C) > immature stage (130 °C). The Langmuir constants for the samples at maximum-oil and oil-cracking stages are larger than the values for the bitumen-forming stages. The total pore volume, determined by N 2 physisorption at 77 K, increases with increased maturation: mesopores, 2–50 nm in width, were created during the thermal conversion of organic-matter and a dramatic increase in porosity appeared when maximum-bitumen and maximum-oil generation stages were reached. A linear relationship between thermal maturity and Brunauer–Emmett–Teller (BET) surface area suggests that the observed increase in CH 4 -sorption capacity may be the result of mesopores produced during OM conversion. No obvious difference is observed in pore-size distribution and pore volume for samples with pores <2.0 nm with the increase of thermal maturity based on CO 2 physisorption at 273 K. The isosteric heat of adsorption and the standard entropy for artificially matured samples ranged from 17.9 kJ mol −1 to 21.9 kJ mol −1 and from −85.4 J mol −1 K −1 to −101.8 J mol −1 K −1 , respectively. These values are similar to the values of immature Woodford kerogen concentrate previously observed, but are larger than naturally matured organic-rich shales. High-temperature hydrous pyrolysis might have induced Lewis acid sites on both organic and mineral surfaces, resulting to some extent, in chemical interactions between the adsorption site and the methane C–H bonds. The formation of abundant mesopores (2–50 nm) within organic matter during organic-matter thermal maturation makes a great contribution to the increase in both BET surface area and pore volume, and a significant increase in 2–6 nm pores occurs at maximum-oil-generation and oil-cracking to gas, ultimately controlling the methane-adsorption capacity. Therefore, consideration of pore-size effects and thermal maturity is very important for gas in place (GIP) prediction in organic-rich shales.

Marine and Petroleum Geology↗

Transcriptome signatures of wastewater effluent exposure in larval zebrafish vary with seasonal mixture composition in an effluent-dominated stream

Wastewater treatment plant (WWTP) effluent-dominated streams provide critical habitat for aquatic and terrestrial organisms but also continually expose them to complex mixtures of pharmaceuticals that can potentially impair growth, behavior, and reproduction. Currently, few biomarkers are available that relate to pharmaceutical-specific mechanisms of action. In the experiment reported in this paper, zebrafish ( Danio rerio ) embryos at two developmental stages were exposed to water samples from three sampling sites (0.1 km upstream of the outfall, at the effluent outfall, and 0.1 km below the outfall) during base-flow conditions from two months (January and May) of a temperate-region effluent-dominated stream containing a complex mixture of pharmaceuticals and other contaminants of emerging concern. RNA-sequencing identified potential biological impacts and biomarkers of WWTP effluent exposure that extend past traditional markers of endocrine disruption. Transcriptomics revealed changes to a wide range of biological functions and pathways including cardiac, neurological, visual, metabolic, and signaling pathways. These transcriptomic changes varied by developmental stage and displayed sensitivity to variable chemical composition and concentration of effluent, thus indicating a need for stage-specific biomarkers. Some transcripts are known to be associated with genes related to pharmaceuticals that were present in the collected samples. Although traditional biomarkers of endocrine disruption were not enriched in either month, a high estrogenicity signal was detected upstream in May and implicates the presence of unidentified chemical inputs not captured by the targeted chemical analysis. This work reveals associations between bioeffects of exposure, stage of development, and the composition of chemical mixtures in effluent-dominated surface water. The work underscores the importance of measuring effects beyond the endocrine system when assessing the impact of bioactive chemicals in WWTP effluent and identifies a need for non-targeted chemical analysis when bioeffects are not explained by the targeted analysis.

Iowa↗

Low estradiol production of non-laying whooping cranes (Grus americana) is associated with the failure of small follicles to enter follicular hierarchy

For endangered species managed ex situ , production of offspring is a key factor to ensure healthy and self-sustaining populations. However, current breeding goals for the whooping crane ( Grus americana ) are impeded by poor reproduction. Our study sought to better understand mechanisms regulating ovarian function in ex situ managed whooping cranes and the regulatory function of the hypothalamic-pituitary-gonadal (HPG) axis in relation to follicle formation and egg laying. To characterize hormonal regulation of follicular development and ovulation, we collected weekly blood samples from six female whooping cranes during two breeding seasons, for a total of 11 reproductive cycles. The plasma samples were assessed for follicle stimulating hormone, luteinizing hormone, estradiol, and progesterone and the yolk precursors vitellogenin and very low-density lipoprotein. Ultrasonographic examination of the ovary was conducted at the time of blood collection. Preovulatory follicles (>12 mm) were present in laying cycles (n = 6) but absent in non-laying cycles (n = 5). The patterns of plasma hormone and yolk precursor concentrations corresponded to the stage of follicle development. Specifically, gonadotropin and yolk precursors concentrations increased as follicles transitioned from the non-yolky to yolky stage but did not increase further as the follicle advanced to preovulatory and ovulatory stages. Estrogen and progesterone concentrations increased as follicle size increased and reached peak concentrations (P < 0.05) when follicles developed to ovulatory and preovulatory stages, respectively. While overall mean circulating gonadotropin, progesterone, and yolk precursor concentrations did not differ for laying versus non-laying cycles, mean plasma estradiol in laying cycles was significantly higher than that in non-laying cycles. In summary, the findings suggested that disruption of mechanisms regulating follicle recruitment is likely responsible for the oviposition failure of the captive female whooping crane.

General and Comparative Endocrinology↗

Embryonic developmental progression in lake trout ( Salvelinus namaycush ) (Walbaum, 1792) and its relation to lake temperature

Developmental progression of lake trout ( Salvelinus namaycush ) embryos was examined with light and scanning electron microscopy. From this examination, key developmental stages were described in detail. The key developmental stages were then applied to individual lake trout egg lots incubated in constant temperatures of 2, 4, 6, 8, and 10&deg;C. We used Belehradek's, Thermodynamic, and Power models, and also developed the Zero model to determine stage specific developmental rates of lake trout eggs for each background temperature. From the models, hatch dates and staging were predicted for temperature regimes from Lake Superior (1990&ndash;91) and Lake Huron (1996&ndash;97). Based on the existing lake temperature data and the observed spawning dates, the Zero and the Power models predict that post peak spawning may contribute significantly to overall recruitment success for these years.

Journal of Great Lakes Research↗

The morphology, processes, and evolution of Monterey Fan: a revisit

Long-range (GLORIA) and mid-range (TOBI) sidescan imagery and seismic-reflection profiles have revealed the surface morphology and architecture of the complete Monterey Fan. The fan has not developed a classic wedge shape because it has been blocked for much of its history by Morro Fracture Zone. The barrier has caused the fan to develop an upper-fan and lower-fan sequence that are distinctly different from one another. The upper-fan sequence is characterized by Monterey and Ascension Channels and associated Monterey Channel-levee system. The lower-fan sequence is characterized by depositional lobes of the Ascension, Monterey, and Sur-Parkington-Lucia systems, with the Monterey depositional lobe being the youngest. Presently, the Monterey depositional lobe is being downcut because the system has reached a new, lower base level in the Murray Fracture Zone. A five-step evolution of Monterey Fan is presented, starting with initial fan deposition in the Late Miocene, about 5.5 Ma. This first stage was one of filling bathymetric lows in the oceanic basement in what was to become the upper-fan segment. The second stage involved filling the bathymetric low on the north side of Morro Fracture Zone, and probably not much sediment was transported beyond the fracture zone. The third stage witnessed sediment being transported around both ends of Morro Fracture Zone and initial sedimentation on the lower-fan segment. During the fourth stage Ascension Channel was diverted into Monterey Channel, thereby cutting off sedimentation to the Ascension depositional lobe.

California↗

Sensitivity of mayfly Neocloeon triangulifer to a reference toxicant is significantly impacted by the age of the diatom feed species Navicula pelliculosa

The development of standardized toxicity tests is critical for assessing pollutants in aquatic ecosystems. The mayfly Neocloeon triangulifer offers advantages as a test species due to its asexual reproduction, short life cycle, and high sensitivity to pollutants. However, we identified variability in response sensitivity to pollutants, which may stem from the nutritional composition and growth stage of its primary food source, Navicula spp. diatoms. This study aimed to evaluate the repeatability and reproducibility of 96 h toxicity tests to sodium chloride with N. triangulifer fed diatoms of varying ages (target concentrations: 329, 494, 741, 1111, 1666, and 2500 mg/L). We tracked Navicula spp. growth stages under controlled conditions and characterized fatty acid and lipid contents at each stage to assess how these factors influence N. triangulifer sensitivity to sodium chloride, a common reference toxicant. Sensitivity increased significantly as the diatom feed aged, highlighting the need for standardized culturing methods to improve test reliability. This study is the first to simultaneously characterize the growth stages and fatty acid profiles of Navicula spp. diatoms as feed species for N. triangulifer . This work contributes valuable insights to the optimization of standardized toxicity testing with this sensitive aquatic insect.

Ecotoxicology and Public Health↗

Time-fractional flow equations (t-FFEs) to upscale transient groundwater flow characterized by temporally non-darcian flow due to medium heterogeneity

Upscaling groundwater flow is a fundamental challenge in hydrogeology. This study proposed time-fractional flow equations (t-FFEs) for upscaling long-term, transient groundwater flow and propagation of pressure heads in heterogeneous media. Monte Carlo simulations showed that, with increasing variance and correlation of the hydraulic conductivity ( K ), flow dynamics gradually deviated from Darcian flow and exhibit sub-diffusive, time-dependent evolution which can be separated into three major stages. At the early stage, the interconnected high- K zones dominated flow, while at intermediate times, the transverse flow due to mixed high- and low- K zones caused delayed rise of the piezometric head. At late times when flow in the relatively high- K domains reached stability, cells with very low- K continued to block the entry of water and generate “islands” with low piezometric head, significantly extending the temporal evolution of the piezometric head. The elongated water breakthrough curve cannot be quantified by the flow equation with an effective K , the space-fractional flow equation, or the multi-rate mass transfer (MRMT) flow model with a few rates, motivating the development of t-FFEs assuming temporally non-Darcian flow. Model applications showed that both the early and intermediate stages of flow dynamics can be captured by a single-index t-FFE (whose index is the exponent of the power-law probability density function of the random operational time for water parcels), but the overall evolution of flow dynamics, especially the enhanced retention of flow at later times, required a distributed-order t-FFE with variable indexes for different flow phases that can dominate flow dynamics at different stages. Therefore, transient groundwater flow in aquifers with spatially stationary heterogeneity can be temporally non-Darcian and non-stationary, due to the time-sensitive, combined effects of interconnected high- K channels and isolated low- K deposits on flow dynamics (which is the hydrogeological mechanism for the temporally non-Darcian flow and sub-diffusive pressure propagation), whose long-term behavior can be quantified by multi-index stochastic models.

Water Resources Research↗

Hydrologic connectivity and residence time affect the sediment trapping efficiency and dissolved oxygen concentrations of the Atchafalaya River Basin

Little is known about water movement, volume, or residence time (RT), and how those characteristics affect sediment trapping efficiency (TE) and dissolved oxygen concentrations (DO) in the United States' largest remaining bottomland hardwood swamp, the Atchafalaya River Basin. To better understand these dynamics, this study used bathymetry, lidar, and stage records to determine volumes in the Basin's hydrologically distinct water management units (WMUs). Discharge measurements determined flow distribution and RT. Residence time was compared with DO to identify conditions that coincided with DO increases or decreases. Suspended sediment concentrations (SSC) were used to determine TE relative to calculated and measured discharge and RT. Discharge through units (85–2,200 m 3 /s) and RT (0.37–231 d) depended on connectivity and river stage. At high stages, with water temperatures >20°C, DO in the largest WMU declined by −0.21 mg/l/day. DO trends indicated less well-connected areas of the WMU contributed hypoxic waters as the flood wave lengthened and stages fell. In the two WMUs examined for TE, TE (−266% to 99% and up to 38 Gg/day) correlated with hydrologic connectivity, SSC, RT, water volume, and, in one WMU, discharge losses. Long RT and high TE indicated a high potential to process nutrients. These relationships varied among WMUs. Large volumes of sediment-laden water moving over the floodplain combined with long RT, high TE, and hypoxia indicate that this ecosystem has continental-scale importance in reducing nutrient loads to the northern Gulf of Mexico. Reports from other systems suggest similar processes may be operating on other large river floodplains globally.

Louisiana↗

The measurement and computation of flood‐discharge

The Geological Survey has been engaged for more than 50 years in measuring and publishing the discharge of streams of the United States. Measured discharges have ranged in quantity from a small fraction of a second‐foot measured volumetrically to more than 2,000,000 second‐feet measured by use of the current‐meter equipment recently developed by the Survey and described by the writer in the April 1938 issue of Civil Engineering . In this work, systematic and generally complete records of discharge are being obtained at about 3700 gaging‐stations maintained and operated by the United States Geological Survey. A typical structure at which records of river‐stages are obtained is shown in Figure 1. A discharge‐record at a gaging‐station is usually derived from a record of stage by means of a curve or table showing the stage‐discharge relation as determined by measurements of discharge distributed over the range of stage.

Eos, Transactions, American Geophysical Union↗

Study of natural glasses through their behaviour as membrane electrodes

THE low-temperature chemical alteration of natural glass occurs in two stages: an initial stage in which it remains glassy but absorbs as much as 6 per cent water 1 , and a final stage in which devitrification to clay minerals, with release of silica, occurs 2,3 . During the first stage the composition of the glass may change, with gain of K 2 O and water and loss of Na 2 O (Smith, R. L., personal communication). This change is due to ion exchange.

Nature↗

On the formation of calderas during ignimbrite eruptions

Many large calderas result from the eruption of substantial volumes (tens or hundreds of km3) of silicic pyroclastics. Such events often begin with an airfall phase and progress to the generation of voluminous ignimbrites1-3. We propose here that many such eruptions involve two well-defined stages, based on a simple analysis of magma chamber pressure variations during an eruption. The first stage begins when an overpressured magma chamber fractures the country rock and forms a conduit to the surface. The chamber pressure decreases rapidly to values less than lithostatic pressure. We show that only small to moderate volumes of magma, representing a small fraction of the total chamber, can be erupted during this stage. In the second stage, caldera collapse results from a further decrease in magma pressure, which causes the chamber roof to fracture catastrophically and deform. Subsidence of the roof attempts to re-establish lithostatic pressures within the chamber and can drive substantial volumes of magma to the surface. Geological relationships in pyroclastic deposits associated with large caldera eruptions provide independent evidence for this model. ?? 1984 Nature Publishing Group.

Nature↗

Quantifying the importance of ontogeny and prey type in modeling top-down and bottom-up effects of an ectothermic predator

Dietary decisions by predators can affect prey abundance and overall food web dynamics. Many predators do not forage on the same prey at the same frequency throughout their lives. Ontogenetic shifts in prey preference are not, however, often accounted for when modeling food web relationships, despite growing literature that suggests that stage specific dietary relationships may be an important consideration when modeling trophic interactions. We investigated the importance of considering size-structure of a predator population with ontogenetic diet shifts in evaluating relationships with prey response using a manipulative experiment with the brown treesnake ( Boiga irregularis ) in Guam. After removing ~ 40% of the snake population via toxic mammal carrion, we measured the strength of the relationship between snake density and the response of two types of prey (lizards and mammals). We evaluated these relationships based on total population size or division of the population into stage specific size categories based on diet preference predictions. We hypothesized that the density of juvenile snakes would correlate more strongly with lizard detections, while adult snakes would better correlate to rodent detections. We also measured reproductive output following changes in rates of prey detection. As expected by known ontogenetic shifts in dietary preference, explicit stage-based models better predicted shifts in rates of observed prey items than did total predator density for both lizards and mammals. Additionally, rodent detections were predictive of one reproductive pulse from snakes, while lizard detections were not predictive or correlated. Our findings support that consideration of predatory species stage-based dietary preference can be meaningful for understanding food web dynamics, particularly when a predator has a broad diet or one that changes through time.

Guam↗

Use of a seismic air gun to reduce survival of nonnative lake trout embryos: A tool for conservation?

The detrimental impacts of nonnative lake trout Salvelinus namaycush in the western USA have prompted natural resource management agencies in several states to implement lake trout suppression programs. Currently, these programs rely on mechanical removal methods (i.e., gill nets, trap nets, and angling) to capture subadult and adult lake trout. We conducted a study to explore the potential for using high-intensity sound from a relatively small (655.5 cm 3 [40 in 3 ]) seismic air gun to reduce survival of lake trout embryos. Lake trout embryos at multiple stages of development were exposed to a single discharge of the seismic air gun at two depths (5 and 15 m) and at two distances from the air gun (0.1 and 2.7 m). Control groups for each developmental stage, distance, and depth were treated identically except that the air gun was not discharged. Mortality in lake trout embryos treated at 0.1 m from the air gun was 100% at 74 daily temperature units in degrees Celsius (TU&deg;C) at both depths. Median mortality in lake trout embryos treated at 0.1 m from the air gun at 207 TU&deg;C (93%) and 267 &deg;C (78%) appeared to be higher than that of controls (49% and 48%, respectively) at 15-m depth. Among the four lake trout developmental stages, exposure to the air gun at 0.1 m resulted in acute mortality up to 60% greater than that of controls. Mortality at a distance of 2.7 m did not appear to differ from that of controls at any developmental stage or at either depth. Our results indicate that seismic air guns have potential as an alternative tool for controlling nonnative lake trout, but further investigation is warranted.

North American Journal of Fisheries Management↗

Effects of depleted uranium on survival, growth, and metamorphosis in the african clawed frog (Xenopus laevis)

Embryos (stage 8-47, Nieuwkoop and Faber) of the African clawed frog (Xenopus laevis) were subjected to water-borne depleted uranium (DU) concentrations that ranged from 4.8 to 77.7 mg/Lusing an acute 96-h frog embryo teratogenesis assay-Xenopus (FETAX). In a chronic 64-d assay, X. laevis (from embryo through metamorphosis; stages 8-66) were subjected to concentrations of DU that ranged from 6.2 to 54.3 mg/L Our results indicate DU is a non teratogenic metal. No effects on mortality, malformations, or growth were observed in the 96-h FETAX with concentrations of DU that ranged from 4.8 to 77.7 mg/L From stage 8 to stage 47, X. laevis tadpoles do not actively feed and the gills are not well developed. Thus, uptake of DU was reduced despite exposure to elevated concentrations. The 64-d assay resulted in no concentration response for either mortality or malformations; however, a delay in metamorphosis was observed in tadpoles subjected to elevated DU concentrations (from 13.1 to 54.3 mg/L) compared to tadpoles in both the well-water control and reference. The delay in metamorphosis was likely due to increasing body burden of DU that ranged from 0.98 to 2.82 mg/kg. Copyright?? Taylor & Francis Inc.

Conference Paper↗

Effects of the herbicide atrazine on Ambystoma tigrinum metamorphosis: duration, larval growth, and hormonal response

We exposed larval tiger salamanders (Ambystoma tigrinum) reared in the laboratory from eggs collected from a prairie wetland in North Dakota to three concentrations of atrazine (0, 75, and 250 i??g/L) in a static renewal test to determine the pesticide's effect on (1) plasma corticosterone and thyroxine concentrations, (2) larval size, and (3) days-to-stage at stages 2 and 4 of metamorphic climax. We found significant effects of atrazine on each of these response variables. Plasma thyroxine was elevated in both atrazine-exposed groups compared to the control group; plasma corticosterone was depressed in the 75 i??g/L treatment compared with both the control and 250 i??g/L treatment. Larvae exposed to 75 i??g/L atrazine reached stage 4 later, but at a size and weight comparable to the control group. By contrast, larvae in the 250 i??g/L treatment progressed to stage 4 at the same time but at a smaller size and lower weight than larvae in the control group. These results indicate that the herbicide has the potential to influence tiger salamander life history. We present a model consistent with our results, whereby corticosterone and thyroxine interact to regulate metamorphosis of tiger salamanders based on nutrient assimilation and adult fitness

Physiological Zoology↗

Postnatal growth rates covary weakly with embryonic development rates and do not explain adult mortality probability among songbirds on four continents

Growth and development rates may result from genetic programming of intrinsic processes that yield correlated rates between life stages. These intrinsic rates are thought to affect adult mortality probability and longevity. However, if proximate extrinsic factors (e.g., temperature, food) influence development rates differently between stages and yield low covariance between stages, then development rates may not explain adult mortality probability. We examined these issues based on study of 90 songbird species on four continents to capture the diverse life-history strategies observed across geographic space. The length of the embryonic period explained little variation (ca. 13%) in nestling periods and growth rates among species. This low covariance suggests that the relative importance of intrinsic and extrinsic influences on growth and development rates differs between stages. Consequently, nestling period durations and nestling growth rates were not related to annual adult mortality probability among diverse songbird species within or among sites. The absence of a clear effect of faster growth on adult mortality when examined in an evolutionary framework across species may indicate that species that evolve faster growth also evolve physiological mechanisms for ameliorating costs on adult mortality. Instead, adult mortality rates of species in the wild may be determined more strongly by extrinsic environmental causes.

American Naturalist↗

Macroinvertebrate oviposition habitat selectivity and egg-mass desiccation tolerances: Implications for population dynamics in large regulated rivers

Aquatic insects exhibit complex life cycles that include egg, larval, adult, and, in some instances, pupal stages. Disturbances at any of these life stages can affect overall population dynamics. Yet, efforts to understand the effects of disturbances, such as hydrologic alterations, overwhelmingly focus on the larval life stage of aquatic insects. We evaluated the potential for load-following flows associated with hydroelectric power production to act as a population bottleneck for aquatic insects via reductions in the availability and temporal persistence of optimal oviposition habitats. Specifically, we quantified the oviposition habitat selectivity of Baetis spp. (Baetidae), Brachycentrus occidentalis (Brachycentridae), Chironomidae (Diptera), and Hydropsyche occidentalis (Hydropsychidae) downstream of Flaming Gorge Dam, Utah, USA. We found that all taxa except H. occidentalis preferentially laid eggs on large emergent substrates located along the river edge. Peak discharge associated with load-following flows substantially reduced the number of emergent substrates available for oviposition, and daily low flows exposed eggs in these habitats to desiccation and drying. When subjected to experimental drying, both Baetis and H. occidentalis eggs experienced nearly 100% mortality after 2 h, whereas most B. occidentalis remained viable after 8 h. Our paired field and experimental results are consistent with the hypothesis that load-following flows from hydroelectric dams produce a population bottleneck for aquatic insects by short circuiting recruitment processes. Environmental flows that seek to improve the health of tailwater aquatic insect populations would benefit from consideration of habitat requirements for all life stages of aquatic insects.

Utah↗