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Assessment of streamflow and water quality in the Upper Yampa River Basin, Colorado, 1992–2018

The Upper Yampa River Basin drains approximately 2,100 square miles west of the Continental Divide in north-western Colorado. There is a growing need to understand potential changes in the quantity and quality of water resources as the basin is undergoing increasing land and water development to support growing municipal, industrial, and recreational needs. The U.S. Geological Survey, in cooperation with stakeholders in the Upper Yampa River Basin water community, began a study to characterize and identify changes in streamflow and selected water-quality constituents, including suspended sediment, Kjeldahl nitrogen, total nitrogen, total phosphorus, and orthophosphate, in the basin. This study used streamflow and water-quality data from selected U.S. Geological Survey sites to provide a better understanding of how major factors, including land use, climate change, and geological features, may influence streamflow and water quality. Analysis of long-term (1910–2018) and short-term (1992–2018) records of streamflow at main-stem Yampa River and tributary sites indicate downward trends in one or more streamflow statistics, including 1-day maximum, mean, and 7-day minimum. Long-term downward trends in daily mean streamflow in April (22 percent overall) at Yampa River at Steamboat Springs, Colorado, correspond to observed changes in streamflow documented across western North America and the Colorado River Basin that are predominately associated with changes in snowmelt runoff and temperatures. During the short-term period of analysis, decreases in streamflow at main-stem Yampa River and some tributary sites are likely related to changes in consumptive use and reservoir management or, at sites with no upstream flow impoundments, changes in irrigation diversions and climate. Concentrations of water-quality constituents were typically highest in spring (March, April, and May) during the early snowmelt runoff period as material that is washed off the land surface drains into streams. Highest concentrations occurred slightly later, in May, June, and July, at Yampa River above Stagecoach Reservoir, Colo., and slightly earlier, in February and March at Yampa River at Milner, Colo., indicating that these sites may have different or additional sources of phosphorus from upstream inputs. Yampa River at Milner, Colo., and Yampa River above Elkhead Creek, Colo., had the highest net yields of suspended sediment, Kjeldahl nitrogen, and total phosphorus, and are likely influenced by land use and erosion as the basins of both of these sites are underlain by highly erodible Cretaceous shales. Upward trends in estimated Kjeldahl nitrogen and total phosphorus concentrations and loads were found at Yampa River at Steamboat Springs, Colo. From 1999 to 2018, the Kjeldahl nitrogen concentration increased by 10 percent or 0.035 milligram per liter, and load increased by 22 percent or 26 tons. Total phosphorus concentration increased by 20 percent or 0.0081 milligram per liter, and loads increased by 41 percent or 6.2 tons. Decreases in streamflow and changes in land use may contribute to these trends. During multiple summer sampling events at Stagecoach Reservoir, the physical and chemical factors indicated conditions conducive to cyanobacterial blooms, including surface-water temperatures greater than 20 degrees Celsius and total phosphorus and total nitrogen concentrations in exceedance of Colorado Department of Public Health and Environment interim concentrations for water-quality standards. Local geological features (predominately sandstones and shales) and additional inputs from upstream land use likely contribute to the elevated nutrient conditions in Stagecoach Reservoir.

Colorado↗

Leaching and sorption of neonicotinoid insecticides and fungicides from seed coatings

Seed coatings are a treatment used on a variety of crops to improve production and offer protection against pests and fungal outbreaks. The leaching of the active ingredients associated with the seed coatings and the sorption to soil was evaluated under laboratory conditions using commercially available corn and soybean seeds to study the fate and transport of these pesticides under controlled conditions. The active ingredients (AI) included one neonicotinoid insecticide (thiamethoxam) and five fungicides (azoxystrobin, fludioxonil, metalaxyl, sedaxane thiabendazole). An aqueous leaching experiment was conducted with treated corn and soybean seeds. Leaching potential was a function of solubility and seed type. The leaching of fludioxonil, was dependent on seed type with a shorter time to equilibrium on the corn compared to the soybean seeds. Sorption experiments with the treated seeds and a solution of the AIs were conducted using three different soil types. Sorption behavior was a function of soil organic matter as well as seed type. For most AIs, a negative relationship was observed between the aqueous concentration and the log K oc . Sorption to all soils tested was limited for the hydrophilic pesticides thiamethoxam and metalaxyl. However, partitioning for the more hydrophobic fungicides was dependent on both seed type and soil properties. The mobility of fludioxonil in the sorption experiment varied by seed type indicating that the adjuvants associated with the seed coating could potentially play a role in the environmental fate of fludioxonil. This is the first study to assess, under laboratory conditions, the fate of pesticides associated with seed coatings using commercially available treated seeds. This information can be used to understand how alterations in agricultural practices (e.g., increasing use of seed treatments) can impact the exposure (concentration and duration) and potential effects of these chemicals to aquatic and terrestrial organisms.

Journal of Environmental Science and Health - Part↗

Chemical quality of water, sediment, and fish in Mountain Creek Lake, Dallas, Texas, 1994-97

The occurrence, trends, and sources of numerous inorganic and organic contaminants were evaluated in Mountain Creek Lake, a reservoir in Dallas, Texas. The study, done in cooperation with the Southern Division Naval Facilities Engineering Command, was prompted by the Navy’s concern for potential off-site migration of contaminants from two facilities on the shore of Mountain Creek Lake, the Naval Air Station Dallas and the Naval Weapons Industrial Reserve Plant. Sampling of stormwater (including suspended sediment), lake water, bottom sediment (including streambed sediment), and fish was primarily in Mountain Creek Lake but also was in stormwater outfalls from the Navy facilities, nearby urban streams, and small streams draining the Air Station. Volatile organic compounds, predominantly solvents from the Reserve Plant and fuel-related compounds from the Air Station, were detected in stormwater from both Navy facilities. Fuel-related compounds also were detected in Mountain Creek Lake at two locations, one near the Air Station inlet where stormwater from a part of the Air Station enters the lake and one at the center of the lake. Concentrations of volatile organic compounds at the two lake sites were small, all less than 5 micrograms per liter. Elevated concentrations of cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc, from 2 to 4 times concentrations at background sites and urban reference sites, were detected in surficial bottom sediments in Cottonwood Bay, near stormwater outfalls from the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls, compared to background and urban reference sites, were detected in surficial sediments in Cottonwood Bay. Elevated concentrations of polycyclic aromatic hydrocarbons, indicative of urban sources, also were detected in Cottonwood Creek, which drains an urbanized area apart from the Navy facilities. Elevated concentrations of polychlorinated biphenyls were detected in two inlets near the Air Station shoreline. Polycyclic aromatic hydrocarbon and heavy metal concentrations near the Air Station shoreline were not elevated compared to urban reference sites. Much larger concentrations of selected heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls were detected in deeper, older sediments than in surficial sediments in Cottonwood Bay. The decreases in concentrations coincide with changes in wastewater discharge practices at the Reserve Plant. Elevated concentrations of polycyclic aromatic hydrocarbons and polychlorinated biphenyls also were detected in older sediments in the Air Station inlet. On the basis of dated sediment cores and contaminant discharge histories, contaminant accumulation rates in Cottonwood Bay were much greater historically than recently. Most heavy metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls that accumulated in the central and eastern parts of Cottonwood Bay appear to have come from the west lagoon on the Reserve Plant. Treated sewage and industrial-process wastewater were discharged to the west lagoon from about 1941 to 1974. Estimated annual contaminant accumulation rates in Cottonwood Bay decreased by from 1 to 2 orders of magnitude after 1974, when most point-source discharges to the west lagoon ceased. Polychlorinated biphenyls were detected in 61 of 62 individual fish-tissue samples. The largest average concentrations were in eviscerated channel catfish and the smallest were in largemouth bass fillets. Polychlorinated biphenyl and selenium concentrations from analyses of this study were large enough to prompt the Texas State Department of Health to issue a fish-possession ban for Mountain Creek Lake in 1996. Suspended sediments in stormwater at the lagoon outfalls and at sites on Cottonwood Creek were sampled and analyzed for major and trace elements, polycyclic aromatic hydrocarbons, organochlorine pesticides, and polychlorinated biphenyls. The suspended sediments from the outfalls contained about the same mixture of heavy metals and organic compounds, in elevated concentrations compared to reference sites, as bottom sediments from the lagoons and surficial bottom sediments in Cottonwood Bay. Diagnostic ratios of polycyclic aromatic hydrocarbons indicate that uncombusted fuel sources contribute to older sediments and that pyrogenic sources of polycyclic aromatic hydrocarbons dominate recently deposited sediments in Cottonwood Bay and along the Air Station shoreline.

Texas↗

Fluvial sediment dynamics in the Shoshone River and tributaries around Willwood Dam, Park County, Wyoming

Sedimentation affects many of the aging reservoirs in the United States. Dams and water diversions from rivers have been central elements of infrastructure supporting agricultural irrigation in the arid and semiarid regions of the Western United States for more than a century. The Willwood Irrigation District diversion dam (hereafter referred to as “Willwood Dam”) in Park County, Wyoming, is approximately 12 miles northeast of Cody, Wyo.; has a structural height of 70 feet; and impounds the Shoshone River for diversion into the Willwood Canal. Willwood Dam is part of a larger irrigation scheme supported by water storage in the much larger Buffalo Bill Dam, which is approximately 20 miles upstream. In October 2016, renovation construction activities at Willwood Dam and the Willwood Canal caused an unplanned evacuation of nearly 96,000 cubic yards of fine sediment. The fine sediment release in 2016 raised concerns that ongoing sediment management at Willwood Dam could impose limits on the long-term health of the aquatic ecosystem and fish populations. The U.S. Geological Survey, in cooperation with Wyoming Department of Environmental Quality and Willwood Work Groups 2 and 3, initiated an investigation of the dynamics of sediment transport in the Shoshone River and selected tributaries between Buffalo Bill Dam and Willwood Dam. The goal of the study was to quantify sediment transport into and out of Willwood Dam on an annual, seasonal, and event basis to better understand the relative quantities of sediment coming from natural sources and human activities on the landscape. The study ran from March 2019 through October 2021 and used observations of streamflow, turbidity, and acoustic backscatter collected at streamgages upstream and downstream from Willwood Dam to quantify suspended-sediment loads into and out of the dam during irrigation and fallow seasons, precipitation-runoff events, and deliberate sediment releases. Each tributary’s relative contribution to the sediment load upstream from Willwood Dam was examined using discrete measurements of suspended-sediment concentration and bedload during irrigation and fallow seasons, precipitation events, and stable conditions. Analysis of daily precipitation and temperature data indicated that conditions in the study area during the 2019 agricultural year were wetter and colder than period of record normal, and drier and near normal temperatures for the 2020 and 2021 agricultural years. Not all sediment load records between 2019 and 2021 are complete because of rejected observations (outliers), instrument failures or fouling, and instrument removal for calibrations. Statistical modeling of suspended-sediment concentration using paired values of turbidity and acoustic backscatter produced four models that, after refinement, had coefficients of determination indicating that more than 84 percent of the variance was explained by either turbidity or acoustic backscatter. A system of rules was developed to select the model predictions based on the seasonal operations of Willwood Dam, assumptions about the grain sizes mobilized during these operations, and assumed accuracy of the models at the downstream streamgage (Shoshone River below Willwood Dam, near Ralston, Wyo. [streamgage 06284010]) under different operational conditions. The sediment budget between upstream and downstream estimates of loads was interpreted using the mean predicted values bound by their respective model prediction intervals. When mean predicted loads of one streamgage were contained in the prediction intervals of the other streamgage, and vice-versa, difference in the sediment budget were interpreted as “indeterminate.” Modeled sediment load balances demonstrated the depositional and erosional behaviors expected from the conceptual model of dam operations whereby sediment tends to accumulate during irrigation seasons when the dam is spilling over the top, and sediment tends to evacuate during the fallow seasons when it is flowing through the sluice gates at the base of the dam. The sediment load calculations using the rules-based model criteria indicated that between 14,200 and 380,000 tons of suspended sediment moved through the Shoshone River around Willwood Dam during the irrigation seasons of 2019, 2020, and 2021; 380,000 tons of suspended sediment were transported during the cool, wet year of 2019, and 14,200 tons of suspended sediment were transported in 2020, which was relatively dry. During fallow seasons 2019, 2020, and 2021, which had fewer complete records, between 1,140 and 106,000 tons of suspended sediment was estimated to have moved through the river. For all seasons except fallow season 2022, the models estimated that more sediment was released from the dam than entered the dam, but the modeled mean loads at each streamgage were nearly always within the prediction intervals of each other, making the sediment balance indeterminant. Examination of suspended-sediment loads during irrigation seasons indicated that between 65 and 85 percent of fine sediment was transported during annual high flows and storm events, with the remainder transported during steady, lower streamflows. Examination of suspended loads during fallow seasons indicated that deliberate sediment releases through Willwood Dam accounted for between 39 and 67 percent of the total sediment moved during the fallow seasons. Deliberate sediment releases from Willwood Dam had estimated net exports of between 1,360 and 22,400 tons. Between August 2017 and July 2023, suspended-sediment concentration and bedload sediment samples were collected from 9 tributaries to the Shoshone River during 137 sampling events, including stable and precipitation-runoff conditions. During irrigation season precipitation events, the mean total sediment yields ranged from 0.33 to 9.51 tons per day per square mile; during fallow season precipitation events, the mean total yields ranged from 0.04 to 0.95 ton per day per square mile. The mean total sediment yield per unit area across all samples at each tributary site ranged from 0.26 to 3.08 tons per day per square mile. Bedload was a minor fraction of the total load, constituting a mean of 4 percent across all samples; 3 and 6 percent for events and nonevents, respectively, during irrigation season; and 3 and 1 percent for events and nonevents, respectively, during the fallow season. With the exception of one tributary, Dry Creek, these mean yield values were within the range of watershed-scale background sediment yield values estimated from reservoir surveys and previous suspended-sediment studies. Imagery from irrigation seasons 2012, 2015, 2017, 2019, and 2022 was used to determine the planimetric backwater extent of the pool area in the Shoshone River behind Willwood Dam to identify any changes in sediment storage. Active river channel widths in the Shoshone River upstream from Willwood Dam were all similar between years except 2015, which was determined to be statistically different from all other years. Bathymetric data taken in the pool behind Willwood Dam during three different surveys between November 2017 and April 2022 indicated no statistically significant differences in bed elevations between the years. Results from the planimetric and bathymetric survey data provide multiple lines of evidence indicating that sediment did not accumulate behind the dam within the error of the methods used. Examination of how precipitation affects sediment transport in the Shoshone River upstream from Willwood Dam indicated that accumulated rainfall from the natural runoff events captured during the study period varied from a trace to as much as 4.26 inches, with associated predicted suspended-sediment loads varying from 112 to 232,000 tons of suspended sediment. The behavior of the sediment loads relative to accumulated precipitation did not appear to change depending on irrigation or fallow season. A model of suspended-sediment concentrations relative to the 2-day accumulated precipitation indicated that suspended-sediment concentrations in the Shoshone River upstream from Willwood Dam increased exponentially for accumulations of 0.3 inch or more; such storms accounted for 10 percent or less of precipitation events observed during the 1981 to 2018 period of record. The gaps in records, precision of the instrumentation, and large variation in grain sizes in suspended-sediment mixtures downstream from the dam made closing the sediment budgets for most seasons unattainable. The biggest recent change in sediment storage measured using the planimetric area of deposits behind Willwood Dam took place between 2015 and 2017. The main event between these two measurements was the installation of new Willwood Canal gates in October 2016, which resulted in the large unplanned sediment release. Because the sediment budgets were nearly always indeterminate and the planimetric and bathymetric data indicated little change in the bed and bank material, it is likely that the change in sediment storage behind the dam during the study period was small relative to the precision of the statistical models and other uncertainties. This body of evidence suggests that, averaged during the 3-year study period, no major changes in storage took place, and that the current operations may be keeping storage at near-equilibrium. This condition could have been initiated because the middle sluice gate has now been operational since 2014, and the sediment release in October 2016 evacuated a large amount of legacy sediment from storage. Although the uncertainties are large, sluicing events allow for controlled releases of sediment that contributed to the near equilibrium conditions observed over an annual basis during this study.

Wyoming↗

Dissolved arsenic concentrations in surface waters within the upper portions of the Klamath River Basin, Oregon and California

Arsenic toxicity is an environmental health problem. Levels of arsenic in surface waters at some locations in the Klamath River Basin in southern Oregon and northern California can exceed the U.S. Environmental Protection Agency (EPA) standard for drinking water. There are both anthropogenic and natural sources of arsenic. The Klamath River Basin consists primarily of volcanic deposits and contains an underground geothermal system with hot springs and warm water wells, all known natural sources of arsenic. Anthropogenic sources of arsenic are related to the agricultural use of herbicides, fungicides, and insecticides. Surface water arsenic levels can also be affected by fertilizer amendments, evaporative concentration, oxygen-level depletion, and various geochemical transformations that can increase arsenic mobilization. In this study by the U.S. Geological Survey and the Bureau of Reclamation, dissolved concentrations of arsenic, copper, and lead were measured in surface waters at 39 unique sites within the upper portions of the Klamath River Basin between 2018 and 2022. In every year, except 2022, sites were sampled four times between April and November. Surface-water arsenic concentrations varied up to four-orders of magnitude among sites. Median arsenic concentration was lowest at Cherry Creek (0.03 micrograms per liter [μg/L]) and highest at Wood Kimball Spring (36.7 μg/L), two sites located north of Upper Klamath Lake. The highest arsenic concentrations (17.4±4.9 μg/L, n =3) were found in drain sites (defined here as a waterbody returning used irrigation water) while the lowest arsenic concentrations were found in an artesian well (0.8 μg/L, n =1). The elevated arsenic concentrations of the drain sites suggest that arsenic might be concentrated or mobilized by agricultural activities, water re-use practices, and (or) by geochemical processes occurring around water stored in drains (that is, in the water column and across sediment water boundaries). A source of arsenic in drain water in the Klamath Strait Drain area includes water used for irrigation originating from Ady Canal. Other potential sources include groundwater, geothermal water, and local soils and sediments. Seasonal differences in surface-water arsenic concentrations were detected at 13 sites, 10 of which had higher arsenic concentrations in summer than in either spring or fall. The sites sampled around Upper Klamath Lake, the impounded rivers, one of the two canal sites, and 5 of the 14 river sites had higher surface-water arsenic concentrations in the summer than in either spring or fall. Surface-water arsenic concentrations from groundwater sources (that is, springs and in the artesian well) did not vary significantly among seasons (p-values greater than 0.1). Median surface-water concentrations of copper and lead ranged from 0.03 to 3.7 μg/L, and from 0.013 to 0.175 μg/L ( n =2–18), respectively. Dissolved concentrations of both metals were below acute toxicity endpoints reported by the EPA for freshwater animals. Surface-water arsenic concentrations varied independently from corresponding changes in surface-water lead or copper concentrations. However, arsenic concentrations measured in bed-sediment samples collected from a subset of sites located north of Upper Klamath Lake correlated strongly and significantly with the corresponding sedimentary lead concentrations ( p =0.015). Aqueous arsenic speciation measured in a subset of sites in 2019 and 2022 showed that all the arsenic existed as arsenic (V), the most oxidized arsenic species, and presumably, the least toxic. The highest proportions of arsenite (As(III)), the presumably most toxic arsenic species, relative to total arsenic concentrations were found at drain sites. Our assessment of dissolved arsenic concentrations in various surface-water bodies in the Upper Klamath River Basin reveals geographical areas of consistently low (below 2.1 μg/L), moderate (below 10 μg/L) and high (above 10 μg/L) surface-water arsenic concentrations. South of Upper Klamath Lake, surface-water arsenic concentrations were consistently higher than 20 μg/L at two drain sites located in an area of predominant agricultural land use with extensive water re-use practices. North of Upper Klamath Lake, surface-water arsenic concentrations greater than 20 μg/L were consistently measured at sites with limited nearby agricultural activities, suggesting a geogenic source. The consistently high arsenic levels from the Wood River at Jackson F. Kimball State Park, Fort Creek, and Crooked Creek, which are sites located at or near headwater spring sources, suggest a natural background source of arsenic. Water flowing downstream from this area could be a potential source of arsenic to Upper Klamath Lake and the Upper Klamath River.

California, Oregon↗

Evaluating the effects of replacing septic systems with municipal sewers on groundwater quality in a densely developed coastal neighborhood, Falmouth, Massachusetts, 2016–19

Land disposal of sewage wastewater through septic systems and cesspools is a major cause of elevated concentrations of nitrogen in the shallow coastal aquifers of southern New England. The discharge of nitrogen from these sources at the coast is affecting the environmental health of coastal saltwater bodies. In response, local, State, and Federal agencies are considering expensive actions to mitigate these effects, including installing municipal sewer systems. To increase the understanding of the effects of municipal sewering on groundwater quality discharging to coastal surface waters, a network of multilevel monitoring wells was established in a densely developed coastal neighborhood on the Maravista peninsula, Falmouth, Massachusetts, which was undergoing conversion from onsite septic disposal to municipal sewering. The geohydrology of the study area on the peninsula is generally characterized as consisting of fine to coarse, well-sorted sands containing 2.9 to 9.3 meters of fresh groundwater and a flow system characterized by a groundwater divide slightly west of the center of the peninsula. The magnitude of hydraulic gradients at the water table is gently sloping, ranging from 0.000032 to 0.00059, and affected by daily and bimonthly tidal fluctuations from adjacent coastal ponds. On the western side of the divide, upgradient from Little Pond, average linear groundwater velocities and traveltimes along shallow flow paths, estimated from observed hydraulic gradients and estimated aquifer hydraulic conductivity and effective porosity, range from 0.076 to 0.094 meters per day and 7.8 to 9.7 years, respectively. The groundwater monitoring network consists of 14 profile sites on the peninsula that each include a multilevel sampler for water-quality data collection and a shallow monitoring well for groundwater-level measurements. The study area encompasses about 230 residences that transitioned from onsite septic disposal to municipal sewering between spring 2017 and summer 2019. An additional multilevel sampler that was in a residential coastal setting but not undergoing sewering also was sampled periodically as a reference site. Elevated nitrogen, as compared to typical uncontaminated, fresh groundwater in the Cape Cod aquifer, predominately as nitrate, was measured in 15 water-quality profiles at nitrate concentrations as great as 26.2 milligrams per liter as nitrogen ( n =749; mean and median values were 5.1 and 4.1 milligrams per liter as nitrogen, respectively). At all 14 profile sites and the reference profile site on a nearby peninsula, wastewater effects were denoted by increased nitrate, boron, and specific conductance, and by decreased pH and dissolved oxygen. The highest concentrations of nitrate typically occurred in the deepest one-half of the freshwater zone and in intervals of suboxic and oxic groundwater. Thickness-weighted mean and maximum nitrate concentrations, and total nitrate mass from four sampling rounds, provided a metric to evaluate expected changes at the 14 profile sites on the peninsula. Nitrate concentrations varied moderately by site between sampling rounds through both the presewering (June 2016 and April 2017) and transitional periods (April 2018 and June 2019). Nitrate concentrations greater than the U.S. Environmental Protection Agency maximum contaminant level for nitrate in drinking water (10 milligrams per liter as nitrogen), were detected at 9 of the 14 profile sites and at the reference site. The average of the mean thickness-weighted nitrate concentrations for the four full sampling rounds was greater than 5.0 milligrams per liter as nitrogen at 8 sites (7 profile sites and the reference site) and greater than 8 milligrams per liter as nitrogen at 3 profile sites. The total nitrate mass per square meter of land area at each profile site ranged from 1,830 to 36,800 milligrams per square meter. Nitrate mass flux, across a 500-meter-long section upgradient from Little Pond and covering about 15 percent of the total pond shoreline length, ranged from 124.3 to 192.6 kilograms per year for the four full sampling rounds under three groundwater-flow conditions. The expected improvements in groundwater quality in the freshwater zone should be characterized by decreases in concentrations of dissolved total and inorganic nitrogen and common ions such as boron, chloride, and fluoride. A statistical analysis using the Regional Kendall test for sampling points grouped in specific depth ranges confirmed that water-quality changes were statistically significant in at least one depth group during the 3-year sampling period (nitrate: −0.76 milligram per liter per year; specific conductance: −12.1 microsiemens per centimeter at 25 degrees Celsius per year; dissolved oxygen: 0.82 milligram per liter per year); however, the rate at which the water-quality improvements will result in decreases in nitrate mass loads to the coastal ponds primarily depends on groundwater traveltimes and the rate of flushing of wastewater constituents from the aquifer.

Massachusetts↗

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Owyhee and Vale Projects, Oregon and Idaho, 1990-91

A reconnaissance investigation was conducted during 1990--91 in the Owyhee and Vale projects in eastern Oregon and southwestern Idaho, as well as at a number of sites in the Snake River and tributaries to the Snake River in the area of study. The objective of the study was to determine if agricultural drainwater entering the study area was causing, or had the potential to cause, significant harmful effects to human health, fish and wildlife, or may adversely affect the suitability of water for beneficial uses. Approximately 153,000 acres of land are irrigated annually within the areas of the Owyhee and Vale projects. Large quantities of water are required because of the semiarid climate and relatively high evaporation rates. Several reservoirs in the area are filled annually during the wet, nonirrigation season to sustain irrigation during the dry summer months. During the irrigation season, this impounded water, along with direct diversions from the Malheur, Owyhee, and Snake Rivers, is transported to the irrigated areas through a series of diversion tunnels, siphons, canals, aqueducts, ditches, and drains. Major crops grown in the area include sugar beets, alfalfa hay and other hay crops, onions, and winter wheat. Minor crops include corn, potatoes, mint, various seed crops, and fruit. In 1987, it was estimated that the following amounts of pesticides were used in the project areas: 2,4-D (21,000 lbs [pounds]), chlorpyrifos (1,000 lbs), dacthal (40,000 lbs), dicamba (320 lbs), endosulfan (2,500 lbs), ethion (11,000 lbs), malathion (24,000 lbs), parathion (5,000 lbs), and phorate (11,000 lbs). Median concentrations and values for total dissolved solids, alkalinity, sodium adsorption ratio, and hardness in the Vale project area were greater than 1.5 times those values observed in the Owyhee project area or at other Snake River locations. During irrigation (August 1990), total dissolved solids, alkalinity, sodium adsorption ratio, and hardness values increased in a downstream manner. Constituent values at drainwater sites generally were comparable to concentrations below the irrigated ureas in the Owyhee and Vale project areas. The trace elements arsenic, boron, copper, molybdenum, vanadium, and zinc were detected in most water samples; cadmium, chromium, lead, and selenium were detected in some samples at concentrations generally near the analytical reporting limit; mercury was not detected in any samples. In some water samples, concentrations of arsenic, boron, cadmium, copper, and lead exceeded State or Federal water-quality standards or criteria. Most trace elements in bottom sediment were detected at concentrations within the expected 95-percent baseline range for soils from the Western United States. Concentrations that exceeded the 95-percent baseline range for study area soils were: (1) arsenic and lead in one sample from a site in the Vale project area; (2) mercury, lead, and tin in one sample from a site in the Snake River system; (3) manganese in two samples from two sites in the Snake River system; and (4) manganese from one sample from a site in the Vale project area. Fifteen pesticides and metabolites were detected in whole-water samples collected from sites in the study area. DDT, plus its metabolites (DDE and DDD), dieldrin, endrin, 2,4-D, dicamba, and dacthal were detected in samples collected from seven or more sites. Other pesticides detected included chlorpyrifos, endosulfan, ethion, malathion, parathion, phorate, and lindane. Most of the detected pesticide concentrations generally were largest in drainwater and at the most downstream sampling locations in the Owyhee and Vale project areas. Concentrations exceeded water-quality criteria established for the protection of freshwater aquatic life in 86 percent of the whole-water samples analyzed for DDT plus its metabolites, 71 percent of the dieldrin samples, 14 percent of the endrin samples, and 10 percent of the parathion samples. Eight pesticides and

Water-Resources Investigations Report↗

Areas contributing recharge to selected production wells in unconfined and confined glacial valley-fill aquifers in Chenango River Basin, New York

In the Chenango River Basin of central New York, unconfined and confined glacial valley-fill aquifers are an important source of drinking-water supplies. The risk of contaminating water withdrawn by wells that tap these aquifers might be reduced if the areas contributing recharge to the wells are delineated and these areas protected from land uses that might affect the water quality. The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation and the New York State Department of Health, began an investigation in 2019 to improve understanding of groundwater flow and delineate areas contributing recharge to 16 production wells clustered in three study areas in the basin as part of an effort to protect the source of water to these wells. Areas contributing recharge were delineated on the basis of numerical steady-state groundwater-flow models representing long-term average hydrologic conditions. In the Cortland study area, four water suppliers operate 10 production wells that withdraw a total average rate of 2,480 gallons per minute from an unconfined aquifer consisting of well-sorted sand and gravel deposits. Simulated areas contributing recharge to these wells at their average pumping rates covered a total area of 6.93 square miles. Simulated areas contributing recharge extend upgradient from the wells to upland till deposits and to groundwater divides. Some simulated areas contributing recharge include isolated areas remote from the wells. Short simulated groundwater traveltimes from recharging locations to discharging wells indicated that the wells are vulnerable to contamination from land-surface activities; 50 percent of the traveltimes were 10 years or less. Land cover in some of the areas contributing recharge included a substantial amount of urban and agriculture land use. The groundwater-flow model of the Cortland study area was calibrated to available hydrologic data by inverse modeling using nonlinear regression. The parameter variance-covariance matrix from model calibration was used to create parameter sets that reflect the uncertainty of the parameter estimates and the correlation among parameters to evaluate the uncertainty associated with the single, predicted contributing areas to the wells. This analysis led to contributing areas expressed as a probability distribution. Because of the effects of parameter uncertainty, the size of the probabilistic contributing areas was larger than the size of the single, predicted contributing area for the wells. Thus, some areas not in the single, predicted contributing area might actually be in the contributing area, including additional areas of urban and agriculture land use that have the potential to contaminate groundwater. Additional areas that might be in the contributing area included recharge originating near the pumping wells that have relatively short groundwater-flow paths and traveltimes. In each of the Greene and Cincinnatus study areas, one water supplier operates three wells that are screened near the top of the bedrock surface in a confined aquifer consisting of poorly to well-sorted sand and gravel deposits. This confined aquifer is overlain by a lacustrine confining unit of very fine sand, silt, and clay, which in turn is overlain by a thin unconfined aquifer of sand and gravel. The groundwater-flow models for these two areas were manually calibrated because of the limited hydrologic data. Simulated areas contributing recharge to the Greene study area wells covered a total area of 0.35 square mile for the average pumping rate of 170 gallons per minute. The contributing areas extended southeastward of the wells to the groundwater divide in the till uplands. The contributing areas also included remote, isolated areas on the opposite side of the Chenango River from the wells primarily in the till uplands. For the Cincinnatus study area wells, which have a low average pumping rate (34 gallons per minute), the simulated contributing areas totaled 0.06 square mile and were on the same side of the river as the wells, but they are isolated areas remote from the wells primarily in the till-covered bedrock uplands. Land cover in these contributing areas for both study areas is primarily agriculture and forested, with the contributing areas to the Greene study area wells also including some urban land uses. Because the Greene and Cincinnatus study area wells are screened relatively deep and some flow paths to the wells partly travel through the confining unit, which impedes the connection with surface sources of recharge, overall groundwater traveltimes are greater than for wells in the Cortland study area. Fifty percent of Cortland study area wells, but only 9 and 44 percent of Greene and Cincinnatus study area wells, respectively, have groundwater traveltimes of 10 years or less.

New York↗

Significance of headwater streams and perennial springs in ecological monitoring in Shenandoah National Park

Shenandoah National Park has been monitoring water chemistry and benthic macroinvertebrates in stream ecosystems since 1979. These monitoring efforts were designed to assess the status and trends in stream condition associated with atmospheric deposition (acid rain) and changes in forest health due to gypsy moth infestations. The primary objective of the present research was to determine whether the current long-term macroinvertebrate and water-quality monitoring program in Shenandoah National Park was failing to capture important information on the status and trends in stream condition by not sufficiently representing smaller, headwater streams. The current benthic-macroinvertebrate and water-chemistry sampling designs do not include routine collection of data from streams with contributing watershed areas smaller than 100 hectares, even though these small streams represent the overwhelming proportion of total stream length in the park. In this study, we sampled headwater sites, including headwater stream reaches (contributing watershed area approximately 100 hectares (ha) and perennial springs, in the park for aquatic macroinvertebrates and water chemistry and compared the results with current and historical data collected at long-term ecological monitoring (LTEM) sites on larger streams routinely sampled as part of ongoing monitoring efforts. The larger purpose of the study was to inform ongoing efforts by park managers to evaluate the effectiveness and efficiency of the current aquatic monitoring program in light of other potential stressors (for example, climate change) and limited resources. Our results revealed several important findings that could influence management decisions regarding long-term monitoring of park streams. First, we found that biological indicators of stream condition at headwater sites and perennial springs generally were more indicative of lower habitat quality and were more spatially variable than those observed at sites on routinely monitored larger streams. We hypothesized that poorer stream condition observed in smaller streams was due to stream drying that occurs more frequently in headwater areas. We also found that biological and water-chemistry measures responded differently to landscape drivers. Variation in most biological endpoints was driven primarily by stream size and was only secondarily associated with bedrock geology. In contrast, water chemistry showed essentially the opposite pattern, with underlying geology explaining much of the variation and stream size being of secondary importance. Therefore, expanding the LTEM program to include headwater areas would yield substantially different biological information, whereas broad inferences regarding spatial patterns in water chemistry would probably not change. Although significant differences in community composition were observed among streams of different sizes, no taxa were unique to headwater sites. All taxa collected at the 45 headwater sites also had been collected at one or more LTEM sites during one or more years. This observation indicates that headwater sites in the park may be structured by biotic nestedness; consequently, focusing management efforts on preserving the species pool at the larger LTEM sites would likely result in the protection of most taxa parkwide. Finally, linkages (correlations) between water chemistry and biological measures of stream condition were signficantly stronger when assessed at the LTEM sites than when assessed at the springs or headwater sites, indicating that conditions at downstream sites may be better indicators of water-quality trends.

Virginia↗

Availability of ground water in the lower Pawcatuck River basin, Rhode Island

The lower Pawcatuck River basin in southwestern Rhode Island is an area of about 169 square miles underlain by crystalline bedrock over which lies a relatively thin mantle of glacial till and stratified drift. Stratified drift, consisting dominantly of sand and gravel, occurs in irregularly shaped linear deposits that are generally less than a mile wide and less than 125 feet thick; these deposits are found along the Pawcatuck River, its tributaries, and abandoned preglacial channels. Deposits of stratified sand and gravel constitute the principal aquifer in the lower Pawcatuck basin and the only one capable of sustaining yields of 100 gallons per minute or more to individual wells. Water available for development in this aquifer consists of water in storage--potential ground-water runoff to streams--plus infiltration that can be induced from streams. Minimum annual ground-water runoff from the sand and gravel aquifer is calculated to be at least 1.17 cubic feet per second per square mile, or 0.76 million gallons per day per square mile. Potential recharge by induced infiltration is estimated to range from about 250 to 600 gallons per day per linear foot of streambed for the principal streams. In most areas, induced infiltration from streams constitutes the major source of water potentially available for development by wells. Because subsurface hydraulic connection in the sand and gravel aquifer is poor in several places, the deposits are conveniently divisible into several ground-water reservoirs. The potential yield from five of the most promising ground-water reservoirs is evaluated by means of mathematical models. Results indicate that continuous withdrawals ranging from 1.3 to 10.3 million gallons per day, and totaling 31 million gallons per day, are obtainable from these reservoirs. Larger yields may be recovered by different well placement, spacing, construction and development, pumping practice, and so forth. Withdrawals at the rates indicated will reduce streamflow downstream from pumping centers but generally will not result in streams going dry, provided the water is returned to the basin. Export of water from the basin will require careful consideration of the effects of such withdrawals on low streamflow. Export from the Pawcatuck basin of 27 million gallons per day, estimated to be available from ground-water reservoirs in the upper Pawcatuck basin, in addition to 37.5 million gallons per day available in the lower Pawcatuck basin, will markedly reduce low streamflow. The 90-percent duration flow of the Pawcatuck River at Westerly would be reduced from 75 million gallons per day to perhaps as little as 21 million gallons per day. The chemical quality of water from both the sand and gravel aquifer and associated streams is suitable for most purposes. The water is soft, slightly acidic, and typically has a dissolved-solids content of less than 75 milligrams per liter. Some treatment may be required locally for removal of iron and manganese to meet recommended standards of the U.S. Public Health Service for drinking water.

Rhode Island↗

Source-water susceptibility assessment in Texas—Approach and methodology

Public water systems provide potable water for the public's use. The Safe Drinking Water Act amendments of 1996 required States to prepare a source-water susceptibility assessment (SWSA) for each public water system (PWS). States were required to determine the source of water for each PWS, the origin of any contaminant of concern (COC) monitored or to be monitored, and the susceptibility of the public water system to COC exposure, to protect public water supplies from contamination. In Texas, the Texas Commission on Environmental Quality (TCEQ) was responsible for preparing SWSAs for the more than 6,000 public water systems, representing more than 18,000 surface-water intakes or groundwater wells. The U.S. Geological Survey (USGS) worked in cooperation with TCEQ to develop the Source Water Assessment Program (SWAP) approach and methodology. Texas' SWAP meets all requirements of the Safe Drinking Water Act and ultimately provides the TCEQ with a comprehensive tool for protection of public water systems from contamination by up to 247 individual COCs. TCEQ staff identified both the list of contaminants to be assessed and contaminant threshold values (THR) to be applied. COCs were chosen because they were regulated contaminants, were expected to become regulated contaminants in the near future, or were unregulated but thought to represent long-term health concerns. THRs were based on maximum contaminant levels from U.S. Environmental Protection Agency (EPA)'s National Primary Drinking Water Regulations. For reporting purposes, COCs were grouped into seven contaminant groups: inorganic compounds, volatile organic compounds, synthetic organic compounds, radiochemicals, disinfection byproducts, microbial organisms, and physical properties. Expanding on the TCEQ's definition of susceptibility, subject-matter expert working groups formulated the SWSA approach based on assumptions that natural processes and human activities contribute COCs in quantities that vary in space and time; that increased levels of COC-producing activities within a source area may increase susceptibility to COC exposure; and that natural and manmade conditions within the source area may increase, decrease, or have no observable effect on susceptibility to COC exposure. Incorporating these assumptions, eight SWSA components were defined: identification, delineation, intrinsic susceptibility, point- and nonpoint-source susceptibility, contaminant occurrence, area-of-primary influence, and summary components. Spatial datasets were prepared to represent approximately 170 attributes or indicators used in the assessment process. These primarily were static datasets (approximately 46 gigabytes (GB) in size). Selected datasets such as PWS surface-water-intake or groundwater-well locations and potential source of contamination (PSOC) locations were updated weekly. Completed assessments were archived, and that database is approximately 10 GB in size. SWSA components currently (2011) are implemented in the Source Water Assessment Program-Decision Support System (SWAP-DSS) computer software, specifically developed to produce SWSAs. On execution of the software, the components work to identify the source of water for the well or intake, assess intrinsic susceptibility of the water- supply source, assess susceptibility to contamination with COCs from point and nonpoint sources, identify any previous detections of COCs from existing water-quality databases, and summarize the results. Each water-supply source's susceptibility is assessed, source results are weighted by source capacity (when a PWS has multiple sources), and results are combined into a single SWSA for the PWS.'SWSA reports are generated using the software; during 2003, more than 6,000 reports were provided to PWS operators and the public. The ability to produce detailed or summary reports for individual sources, and detailed or summary reports for a PWS, by COC or COC group was a unique capability of SWAP-DSS. In 2004, the TCEQ began a rotating schedule for SWSA wherein one-third of PWSs statewide would be assessed annually, or sooner if protection-program activities deemed it necessary, and that schedule has continued to the present. Cooperative efforts by the TCEQ and the USGS for SWAP software maintenance and enhancements ended in 2011 with the TCEQ assuming responsibility for all tasks.

Texas↗

Plasmid-mediated romet resistance of Edwardsiella ictaluri

Romet®, a potentiated sulfa drug composed of five parts sulfadimethoxine and one part ormetoprim, is used to treat channel catfish Ictalurus punctatus infected with Edwardsiella ictaluri , the causal agent of enteric septicemia of catfish (ESC). Recently, several Romet-resistant isolates of E. ictaluri were isolated from channel catfish that had died from ESC in Virginia and Mississippi. This antimicrobial resistance was determined to be plasmid-encoded, as shown by agarose gel electrophoresis of plasmid DNA, and by the fact that the plasmid and associated antimicrobial resistance could be transferred to a recipient by single-step conjugation. Size of the R plasmid was approximately 55 kilobase pairs. Plasmids also conferred resistance to tetracycline, oxytetracycline, streptomycin, trimethoprim, and SXT (another potentiated sulfonamide, composed of trimethoprim and sulfamethoxazole). Each Romet-resistant E. ictaluri isolate was mated with a plasmid recipient, the Romet-sensitive Escherichia coli isolate 1932. Transconjugates were selected by plating on Mueller-Hinton agar that contained antimicrobials, and the mean transfer frequency was 1.483 × 10 −3 transconjugates per donor cell in the mating mixture. Each E. coli transconjugate was then mated with 20 Romet-sensitive isolates of E. ictaluri to assess the propensity of these E. ictaluri isolates to accept the R plasmid. The average transfer frequency when E. ictaluri isolates of channel catfish origin (N = 14) were used as recipients was 1.197 × 10 −2 transconjugates per donor cell in the mating mixture; mean transfer frequency when E. ictaluri isolates not originating from channel catfish were used was 1.019 × 10 -3 transconjugates per donor cell, which was significantly less (P = 0.0002).

Journal of Aquatic Animal Health↗

Occurrence of cyanobacteria, microcystin, and taste-and-odor compounds in Cheney Reservoir, Kansas, 2001-16

Cheney Reservoir, located in south-central Kansas, is one of the primary drinking-water supplies for the city of Wichita and an important recreational resource. Since 1990, cyanobacterial blooms have been present occasionally in Cheney Reservoir, resulting in increased treatment costs and decreased recreational use. Cyanobacteria, the cyanotoxin microcystin, and the taste-and-odor compounds geosmin and 2-methylisoborneol have been measured in Cheney Reservoir by the U.S. Geological Survey, in cooperation with the city of Wichita, for about 16 years. The purpose of this report is to describe the occurrence of cyanobacteria, microcystin, and taste-and-odor compounds in Cheney Reservoir during May 2001 through June 2016 and to update previously published logistic regression models that used continuous water-quality data to estimate the probability of microcystin and geosmin occurrence above relevant thresholds. Cyanobacteria, microcystin, and geosmin were detected in about 84, 52, and 31 percent of samples collected in Cheney Reservoir during May 2001 through June 2016, respectively. 2-methylisoborneol was less common, detected in only 3 percent of samples. Microcystin and geosmin concentrations exceeded advisory values of concern more frequently than cyanobacterial abundance; therefore, cyanobacteria are not a good indicator of the presence of these taste-and-odor compounds in Cheney Reservoir. Broad seasonal patterns in cyanobacteria and microcystin were evident, though abundance and concentration varied by orders of magnitude across years. Cyanobacterial abundances generally peaked in late summer or early fall (August through October), and smaller peaks were observed in winter (January through February). In a typical year, microcystin was first detected in June or July, increased to its seasonal maxima in the summer (July through September), and then decreased. Seasonal patterns in geosmin were less consistent than cyanobacteria and microcystin, but geosmin typically had a small peak during winter (January through March) during most years and a large peak during summer (July through September) during some years. Though the relation between cyanobacterial abundance and microcystin and geosmin concentrations was positive, overall correlations were weak, likely because production is strain-specific and cyanobacterial strain composition may vary substantially over time. Microcystin often was present without taste-and-odor compounds. By comparison, where taste-and-odor compounds were present, microcystin frequently was detected. Taste-and-odor compounds, therefore, may be used as indicators that microcystin may be present; however, microcystin was present without taste-and-odor compounds, so taste or odor alone does not provide sufficient warning to ensure human-health protection. Logistic regression models that estimate the probability of microcystin occurrence at concentrations greater than or equal to 0.1 micrograms per liter and geosmin occurrence at concentrations greater than or equal to 5 nanograms per liter were developed. Models were developed using the complete dataset (January 2003 through June 2016 for microcystin [14-year dataset]; May 2001 through June 2016 for geosmin [16-year dataset]) and an abbreviated 4-year dataset (January 2013 through June 2016 for microcystin and geosmin). Performance of the newly developed models was compared with previously published models that were developed using data collected during May 2001 through December 2009. A seasonal component and chlorophyll fluorescence (a surrogate for algal biomass) were the explanatory variables for microcystin occurrence at concentrations greater than or equal to 0.1 micrograms per liter in all models. All models were relatively robust, though the previously published and 14-year models performed better over time; however, as a tool to estimate microcystin occurrence at concentrations greater than or equal to 0.1 micrograms per liter in a real-time notification system near the Cheney Dam, the 4-year model is most representative of recent (2013 through 2016) conditions. All models for geosmin occurrence at concentrations greater than or equal to 5 nanograms per liter had different explanatory variables and model forms. The previously published and 16-year models were not robust over time, likely because of changing environmental conditions and seasonal patterns in geosmin occurrence. By comparison, the abbreviated 4-year model may be a useful tool to estimate geosmin occurrence at concentrations greater than or equal to 5 nanograms per liter in a real-time notification system near the Cheney Dam. The better performance of the abbreviated 4-year geosmin model during 2013 through 2016 relative to the previously published and 16-year models demonstrates the need for continuous reevaluation of models estimating the probability of occurrence.

Kansas↗

Oregon OCS seafloor mapping: Selected lease blocks relevant to renewable energy

In 2014 the U.S. Geological Survey (USGS) and the Bureau of Ocean Energy Management (BOEM) entered into Intra-agency agreement M13PG00037 to map an area of the Oregon Outer Continental Shelf (OCS) off of Coos Bay, Oregon, under consideration for development of a floating wind energy farm. The BOEM requires seafloor mapping and site characterization studies in order to evaluate the impact of seafloor and sub-seafloor conditions on the installation, operation, and structural integrity of proposed renewable energy projects, as well as to assess the potential effects of construction and operations on archaeological resources. The mission of the USGS is to provide geologic, topographic, and hydrologic information that contributes to the wise management of the Nation's natural resources and that promotes the health, safety, and well being of the people. This information consists of maps, databases, and descriptions and analyses of the water, energy, and mineral resources, land surface, underlying geologic structure, and dynamic processes of the earth. For the Oregon OCS study, the USGS acquired multibeam echo sounder and seafloor video data surrounding the proposed development site, which is 95 km2 in area and 15 miles offshore from Coos Bay. The development site had been surveyed by Solmar Hydro Inc. in 2013 under a contract with WindFloat Pacific. The USGS subsequently produced a bathymetry digital elevation model and a backscatter intensity grid that were merged with existing data collected by the contractor. The merged grids were published along with visual observations of benthic geo-habitat from the video data in an associated USGS data release (Cochrane and others, 2015). This report includes the results of analysis of the video data conducted by Oregon State University and the geo-habitat interpretation of the multibeam echo sounder (MBES) data conducted by the USGS. MBES data was published in Cochrane and others (2015). Interpretive data associated with this publication is published in Cochrane (2017). All the data is provided as geographic information system (GIS) files that contain both Esri ArcGIS geotiffs or shapefiles. For those who do not own the full suite of Esri GIS and mapping software, the data can be read using Esri ArcReader, a free viewer that is available at http://www.esri.com/software/arcgis/arcreader/index.html (last accessed August 29, 2016). Web services, which consist of standard implementations of ArcGIS representational state transfer (REST) Service and Open Geospatial Consortium (OGC) GIS web map service (WMS), also are available for all published GIS data. Web services were created using an ArcGIS service definition file, resulting in data layers that are symbolized as shown on the associated report figures. Both the ArcGIS REST Service and OGC WMS Service include all the individual GIS layers. Data layers are bundled together in a map-area web service; however, each layer can be symbolized and accessed individually after the web service is ingested into a desktop application or web map. Web services enable users to download and view data, as well as to easily add data to their own workflows, using any browser-enabled, standalone or mobile device. Though the surficial substrate is dominated by combinations of mud and sand substrate, a diverse assortment of geomorphologic features are related to geologic processes—one anticlinal ridge where bedrock is exposed, a slump and associated scarps, and pockmarks. Pockmarks are seen in the form of fields of small pockmarks, a lineation of large pockmarks with methanogenic carbonates, and areas of large pockmarks that have merged into larger variously shaped depressions. The slump appears to have originated at the pockmark lineation. Video-supervised numerical analysis of the MBES backscatter intensity data and vector ruggedness derived from the MBES bathymetry data was used to produce a substrate model called a seafloor character raster for the study area. The seafloor character raster consists of three substrate classes: soft-flat areas, hard-flat areas, and hard-rugged areas. A Coastal and Marine Ecological Classification Standard (CMECS) geoform and substrate map was also produced using depth, slope, and benthic position index classes to delineate geoform boundaries. Seven geoforms were identified in this process, including ridges, slump scars, slump deposits, basins, and pockmarks. Statistical analysis of the video data for correlations between substrate, depth, and invertebrate assemblages resulted in the identification of seven biomes: three hard-bottom biomes and four softbottom biomes. A similar analysis of vertebrate observations produces a similar set of biomes. The biome between-group dissimilarity was very high or high. Invertebrates alone represent most of the structure of the whole benthic community into different assemblages. A biotope map was generated using the seafloor character raster and the substrate and depth values of the biomes. Hard substrate biotopes were small in size and were located primarily on the ridge and in pockmarks along the pockmark lineation. The soft-bottom bitopes consisted of large contiguous areas delimited by isobaths.

Open-File Report↗

Abrupt physical and chemical changes during 1992-1999, Anderson Springs, SE Geyser Geothermal Field, California

The Anderson Springs area is located about 90 miles (145 kilometers) north of San Francisco, California, in the southwestern part of Lake County. The area was first developed in the late 1800s as a health resort, which was active until the 1930s. Patrons drank a variety of cool to hot mineral waters from improved springs, swam in various baths and pools, and hiked in the rugged hills flanking Anderson Creek and its tributaries. In the bluffs to the south of the resort were four small mercury mines of the eastern Mayacmas quicksilver district. About 1,260 flasks of mercury were produced from these mines between 1909 and 1943. By the early 1970s, the higher ridges south and west of Anderson Springs became part of the southeast sector of the greater Geysers geothermal field. Today, several electric power plants are built on these ridges, producing energy from a vapor-dominated 240 °C reservoir. Only the main hot spring at Anderson Springs has maintained a recognizable identity since the 1930s. The hot spring is actually a cluster of seeps and springs that issue from a small fault in a ravine southwest of Anderson Creek. Published and unpublished records show that the maximum temperature (Tm) of this cluster fell gradually from 63°C in 1889 to 48°C in 1992. However, Tm of the cluster climbed to 77°C in 1995 and neared boiling (98°C) in 1998. A new cluster of boiling vents and small fumaroles (Tm = 99.3°C) formed in 1998 about 30 m north of the old spring cluster. Several evergreen trees on steep slopes immediately above these vents apparently were killed by the new activity. Thermal waters at Anderson Hot Springs are mostly composed of near-surface ground waters with some added gases and condensed steam from The Geysers geothermal system. Compared to gas samples from Southeast Geysers wells, the hot spring gases are higher in CO 2 and lower in H 2 S and NH 3 . As the springs increased in temperature, however, the gas composition became more like the mean composition of steam discharges from the Southeast Geysers. The hot spring waters are low in ions of Cl, B, and Li, but relatively high in HCO 3 , SO 4 and NH 4 . The stable-isotope compositions (deuterium and oxygen-18) of these waters plot near the global meteoric water line. Geochemical data through time reveal apparent maxima in the concentrations of SO 4 , Fe, and Mn in 1991 to 1992, before the cluster became hotter. The black-to-gray deposits from the new spring cluster are rich in pyrite and contain anomalous metals. About one-half mile to the east of the hot springs, mineralized water discharges intermittently from an old adit of the Schwartz (Anderson) mine, and enters a tributary of Anderson Creek. This drainage increased substantially in July 1998, and a slurry of mine water and precipitates were transported down the tributary and into Anderson Creek. In December 1998, the adit water was 22°C, and had a chemical composition that was similar to spring waters that once discharged in the ravines surrounding the old Anderson Springs resort. The cause for the abrupt changes that have occurred in thermal features at Anderson Springs is still not resolved. One possibility is that these changes are a response to withdrawal of steam from The Geysers geothermal field over more than 20 years of production. Pressure declines in the geothermal reservoir may have caused a "drying out" of the overlying condensation zone. Induced boiling in this zone and upflow of deep steam to shallower depths would cause heating and vaporization of shallow ground waters. In addition, earthquakes occurring in the vicinity of Anderson Springs have increased significantly after nearby geothermal power plants began operation. These earthquakes may have enhanced surface discharge of thermal fluids along fractures and faults.

California↗

Evaluation of pathogen risks and testing considerations for Chinook salmon egg movements between New Zealand and California

Executive Summary Oncorhynchus tshawytscha (Walbaum in Artedi, 1792; Chinook salmon) were historically abundant in the McCloud River but are now extirpated from this tributary owing to dam construction and lack of passage. Planning efforts to restore populations above Shasta and Keswick Dams are currently underway, including an evaluation of potential source populations. One potential source is New Zealand Chinook salmon, which are believed to have originated from tributaries of the Sacramento River. These fish could be returned to California if reintroduction risks, including risks of pathogen introduction, could be sufficiently mitigated. The U.S. Geological Survey was contracted to provide scientific support for reintroduction efforts, including evaluating the risks of pathogen transmission via the movement of Chinook salmon eggs from New Zealand to the McCloud River. This report estimates pathogen risks associated with egg movement and considers epidemiological and biosecurity measures to minimize these risks. Pathogen risks associated with the movement of Chinook salmon eggs from New Zealand were evaluated based on pathogen virulence, transmission route, and geographic distribution. These criteria identified 14 moderate- and high-risk pathogens out of the 30 pathogens evaluated. Pathogen species and strains were considered high risk if they have the potential for vertical transmission (that is, transmission from parent to offspring), are moderately or highly virulent, and are exotic to the Sacramento River Basin. According to these criteria, we identified the following pathogens as high risk: New Zealand rickettsia-like organisms 1 and 2. —These bacterial pathogens have been associated with mortality events in farmed Chinook salmon from the South Island of New Zealand but have not been detected in other regions. Pilchard orthomyxovirus (POMV). —POMV has been detected in Sardina pilchardus (Walbaum, 1792; pilchards) and Salmo salar (Linnaeus, 1758; Atlantic salmon) from the coasts of southern Australia and Tasmania. POMV can cause relatively high mortality rates and may be indirectly transmitted via contaminated water sources. Infectious pancreatic necrosis virus (IPNV). —IPNV has a wide geographic distribution and is present in the Sacramento River Basin, but the IPNV-like viruses detected in Australia and New Zealand are unique from those found in the United States. Yersinia ruckeri . —This bacterial pathogen is the causative agent of enteric redmouth disease and has a widespread geographic distribution. However, the strains that are present in Australia and New Zealand are unique from those found in North America. Strategic use of testing and biosecurity measures can minimize pathogen risks associated with the movement of eggs. The most effective measures include iodophor treatment of eggs to remove external pathogens, testing of all the adult fish from which gametes are obtained, and a quarantine period after transport to confirm pathogen testing results. Additional measures to enhance biosecurity could include testing the quarantined fish following emergence and (or) developing a fish health history of the source population through pathogen monitoring.

California↗

USGS Tampa Bay Pilot Study

Many of the nation's estuaries have been environmentally stressed since the turn of the 20th century and will continue to be impacted in the future. Tampa Bay, one the Gulf of Mexico's largest estuaries, exemplifies the threats that our estuaries face (EPA Report 2001, Tampa Bay Estuary Program-Comprehensive Conservation and Management Plan (TBEP-CCMP)). More than 2 million people live in the Tampa Bay watershed, and the population constitutes to grow. Demand for freshwater resources, conversion of undeveloped areas to resident and industrial uses, increases in storm-water runoff, and increased air pollution from urban and industrial sources are some of the known human activities that impact Tampa Bay. Beginning on 2001, additional anthropogenic modifications began in Tampa Bat including construction of an underwater gas pipeline and a desalinization plant, expansion of existing ports, and increased freshwater withdrawal from three major tributaries to the bay. In January of 2001, the Tampa Bay Estuary Program (TBEP) and its partners identifies a critical need for participation from the U.S. Geological Survey (USGS) in providing multidisciplinary expertise and a regional-scale, integrated science approach to address complex scientific research issue and critical scientific information gaps that are necessary for continued restoration and preservation of Tampa Bay. Tampa Bay stakeholders identified several critical science gaps for which USGS expertise was needed (Yates et al. 2001). These critical science gaps fall under four topical categories (or system components): 1) water and sediment quality, 2) hydrodynamics, 3) geology and geomorphology, and 4) ecosystem structure and function. Scientists and resource managers participating in Tampa Bay studies recognize that it is no longer sufficient to simply examine each of these estuarine system components individually, Rather, the interrelation among system components must be understood to develop conceptual and predictive modeling tools for effective ecosystem adaptive management. As a multidisciplinary organization, the USGS possesses the capability of developing and coordinating an integrated science strategy for estuarine research founded on partnerships and collaborative efforts, multidisciplinary teams of scientists, and integrated field work, data analysis and interpretation, and product development. The primary role of the USGS in Tamps Bay research was defined with our partners based upon this capability to address estuarine issues using an integrated science approach with a regional perspective and within a national context to complement the numerous ongoing scien efforts by state and local agencies that address local issues within Tamp Bay. Six primary components of the USGS Tamp Bay Study address critical gaps within each of the the four estuarine system components and focus on: 1.) Examining how natural and man-made physical changes affect ecosystem health through mapping and modeling. 2.) Identifying sources and quality of groundwater, surface water, and sediment, 3.) Identifying sources and quality of groundwater, surface water, and sediment, 4.) Assessing the natural and man-made changes affecting wetland health and restoration, 5.) Identifying and measuring the impact of urbanization on seafloor habitats, Providing a web-based digital information management system of information for scientists and the public, including a system that supports the work of those officials who must make decisions that affect the state of the bay. The Tampa Bay Study is in its sixth year and will continue through September 2007. This paper presents a non-inclusive summary of key findings associated with the six primary project components listed above. Component 4 (above) is described in detail in the following chapter 13. More information on the Tampa Bay Study is available from our on-line digital information system for the Tampa Bay Study at http://gulfsci.usgs.gov.

Florida↗

Water-quality trend analysis and sampling design for streams in the Red River of the North Basin, Minnesota, North Dakota, and South Dakota, 1970-2001

The Bureau of Reclamation is considering several alternatives to meet the future municipal, rural, and industrial water-supply needs in the Red River of the North (Red River) Basin, and an environmental impact statement is being prepared to evaluate the potential effects of the various alternatives on the water quality and aquatic health in the basin in relation to the historical variability of streamflow and constituent concentration. Therefore, a water-quality trend analysis was needed to determine the amount of natural water-quality variability that can be expected to occur in the basin, to determine if significant water-quality changes have occurred as a result of human activities, to explore potential causal mechanisms for water-quality changes, and to establish a baseline from which to monitor future water-quality trends. This report presents the results of a study conducted by the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, to analyze historical water-quality trends in two dissolved major ions, dissolved solids, three nutrients, and two dissolved trace metals for nine streamflow-gaging stations in the basin. Annual variability in streamflow in the Red River Basin was high during the trend-analysis period (1970-2001). The annual variability affects constituent concentrations in individual tributaries to the Red River and, in turn, affects constituent concentrations in the main stem of the Red River because of the relative streamflow contribution from the tributaries to the main stem. Therefore, an annual concentration anomaly, which is an estimate of the interannual variability in concentration that can be attributed to long-term variability in streamflow, was used to analyze annual streamflow-related variability in constituent concentrations. The concentration trend is an estimate of the long-term systematic changes in concentration that are unrelated to seasonal or long-term variability in streamflow. Concentrations that have both the seasonal and annual variability removed are called standardized concentrations. Numerous changes that could not be attributed to natural streamflow-related variability occurred in the standardized concentrations during the trend-analysis period. During various times from the late 1970's to the mid-1990's, significant increases occurred in standardized dissolved sulfate, dissolved chloride, and dissolved- solids concentrations for eight of the nine stations for which water-quality trends were analyzed. Significant increases also occurred from the early 1980's to the mid-1990's for standardized dissolved nitrite plus nitrate concentrations for the main-stem stations. The increasing concentrations for the main-stem stations indicate the upward trends may have been caused by human activities along the main stem of the Red River. Significant trends for standardized total ammonia plus organic nitrogen concentrations occurred for most stations. The fitted trends for standardized total phosphorus concentrations for one tributary station increased from the late 1970's to the early 1980's and decreased from the early 1980's to the mid-1990's. Small but insignificant increases occurred for two main-stem stations. No trends were detected for standardized dissolved iron or dissolved manganese concentrations. However, the combination of extreme high-frequency variability, few data, and the number of censored values may have disguised the streamflow-related variability for iron. The time-series model used to detect historical concentration trends also was used to evaluate sampling designs to monitor future water-quality trends. Various sampling designs were evaluated with regard to their sensitivity to detect both annual and seasonal trends during three 4-month seasons. A reasonable overall design for detecting trends for all stations and constituents consisted of eight samples per year, with monthly sampling from April to August and bimonthly sampling from October to February.

Scientific Investigations Report↗