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Observations of pockmark flow structure in Belfast Bay, Maine, Part 3: implications for sediment transport

Current observations and sediment characteristics acquired within and along the rim of two pockmarks in Belfast Bay, Maine, were used to characterize periods of sediment transport and to investigate conditions favorable to the settling of suspended sediment. Hourly averaged Shields parameters determined from horizontal current velocity profiles within the center of each pockmark never exceed the critical value (approximated with the theoretical model of Dade et al. 1992). However, Shields parameters estimated at the pockmark rims periodically exceed the critical value, consistent with conditions that support the onset of sediment transport and suspension. Below the rim in the near-center of each pockmark, depth-averaged vertical velocities were less than zero (downward) 60% and 55% of the time in the northern and southern pockmarks, and were often comparable to depth-averaged horizontal velocities. Along the rim, depth-averaged vertical velocities over the lower 8 m of the water column were primarily downward but much less than depth-averaged horizontal velocities indicating that suspended sediment may be moved to distant locations. Maximum grain sizes capable of remaining in suspension under terminal settling flow conditions (ranging 10–170 μm) were typically much greater than the observed median grain diameter (about 7 μm) at the bed. During upwelling flow within the pockmarks, and in the absence of flocculation, suspended sediment would not settle. The greater frequency of predicted periods of sediment transport along the rim of the southern pockmark is consistent with pockmark morphology in Belfast Bay, which transitions from more spherical to more elongated toward the south, suggesting near-bed sediment transport may contribute to post-formation pockmark evolution during typical conditions in Belfast Bay.

Maine↗

Hydrologic aspects of marsh ponds during winter on the Gulf Coast Chenier Plain, USA: Effects of structural marsh management

The hydrology of marsh ponds influences aquatic invertebrate and waterbird communities. Hydrologic variables in marsh ponds of the Gulf Coast Chenier Plain are potentially affected by structural marsh management (SMM: levees, water control structures and impoundments) that has been implemented since the 1950s. Assuming that SMM restricts tidal flows and drainage of rainwater, we predicted that SMM would increase water depth, and concomitantly decrease salinity and transparency in impounded marsh ponds. We also predicted that SMM would increase seasonal variability in water depth in impounded marsh ponds because of the potential incapacity of water control structures to cope with large flooding events. In addition, we predicted that SMM would decrease spatial variability in water depth. Finally, we predicted that ponds of impounded freshwater (IF), oligohaline (IO), and mesohaline (IM) marshes would be similar in water depth, temperature, dissolved oxygen ( O 2 ), and transparency. Using a priori multivariate analysis of variance (MANOVA) contrast, we tested these predictions by comparing hydrologic variables within ponds of impounded and unimpounded marshes during winters 1997-1998 to 1999-2000 on Rockefeller State Wildlife Refuge, near Grand Chenier, Louisiana. Specifically, we compared hydrologic variables (1) between IM and unimpounded mesohaline marsh ponds (UM); and (2) among IF, IO, and IM marshes ponds. As predicted, water depth was higher and salinity and O 2 were lower in IM than in UM marsh ponds. However, temperature and transparency did not differ between IM and UM marsh ponds. Water depth varied more among months in IM marsh ponds than within those of UM marshes, and variances among and within ponds were lower in IM than UM marshes. Finally, all hydrologic variables, except salinity, were similar among IF, IO, and IM marsh ponds. Hydrologic changes within marsh ponds due to SMM should (1) promote benthic invertebrate taxa that tolerate low levels of O 2 and salinity; (2) deter waterbird species that cannot cope with increased water levels; and (3) reduce waterbird species diversity by decreasing spatial variability in water depth among and within marsh ponds.

Louisiana↗

Morphological development of the Florida Escarpment: Observations on the generation of time transgressive unconformities in carbonate terrains

An unconformity of 100 m.yr magnitude continues to form on the western edge of the Florida-Bahama Platform, near 26??N, where distal Mississippi Fan sediments are progressively burying the Florida Escarpment. Multiple perspectives of the developing unconformity's morphology are revealed using available technologies including GLORIA images of the entire platform's edge, Seabeam bathymetric contours, and Deep-Tow's high resolution side-scan data calibrated with bottom photographs. The structure and stratigraphy of the buried escarpment and the associated unconformity are resolved by airgun, sparker, and Deep-Tow's 4 kHz seismic reflection data; we summarize the morphological data on the exposed part of the unconformity and the sedimentary deposits accumulating in the basin above the unconformity. The exposed cliff face is composed of a staircase of bedding-plane terraces which are developed along joint planes. The terraces extend 100-1000 m along the escarpment's face, and the intervening vertical walls are up to 100 m high. The jointed morphology of this Mesozoic limestone cliff apparently reflects erosional exposure of its interior anatomy rather than its accretionary shape. The change in slope between the platform face and the abyssal plain is very abrupt. In places along the contact between the escarpment and fan sediments, reduced chemical-charged brine seeps occur, which locally cause carbonate dissolution and precipitation, sulfide mineralization, and the deposition of a fossiliferous and organic carbon-rich lens associated with chemosynthetic communities. These seep deposits and escarpment-derived megabreccias intercalate with basinal sediments that overlie the unconformity. Because surface seismic reflection data do not produce images of the escarpment's face that closely reflect the exposed escarpment's morphology, they must also be of limited value in characterizing the surface of similar steeply dipping buried escarpments. Thus, the downslope extent of the heavily eroded platform edge is unclear.

Florida↗

Physical property characteristics of gas hydrate-bearing reservoir and associated seal sediments collected during NGHP-02 in the Krishna-Godavari Basin, in the offshore of India

India’s National Gas Hydrate Program Expedition 02 (NGHP-02), was conducted to better understand geologic controls on gas hydrate occurrence and morphology, targeting potentially coarse-grained sediments near the base of the continental slope offshore eastern India. This study combines seismic, logging-while-drilling data, and a petroleum systems approach to provide a regional geologic context for the core- and grain-scale analyses. This multi-scale approach provides insight on the gas hydrate distribution, morphology and anticipated system response to depressurization-induced methane extraction. The study area, NGHP-02 Area B in the Krishna-Godavari Basin, contains a buried anticline/syncline structure that hosts fracture-filling gas hydrate in fine-grained sediment overlying coarser sediments with pore-occupying gas hydrate. Core- and grain-scale measurements show fine-grained sediment exerts a primary control on the distribution and morphology of gas hydrate in Area B. Diatoms in the fine-grained overburden cause porosity to increase with depth, reaching ~70% at the underlying reservoir contact. High porosity, combined with near-vertical faults, suggests the overlying sediment is an imperfect seal. This allows methane to escape the gas hydrate reservoir sediments and form primarily grain-displacing gas hydrate veins in the fine-grained overburden. Within the reservoir, fine-grained layers are interbedded with coarser-grained gas hydrate reservoir sands. Even in the reservoir sands, however, a soil classification study shows the fines content is high enough to control hydraulic and mechanical properties, such as permeability, compressibility and shear strength. Fluid motion during methane extraction from gas hydrates can mobilize those fines, which can then clog pore throats, limiting production rates. Pore-water freshening during gas hydrate dissociation can increase fines mobilization, particularly given the smectite identified in the fine-grained interbeds. Accounting for fines content and specific fines mineralogy throughout the gas hydrate petroleum system is important for predicting production efficiency from gas hydrate occurrences along the crest of the anticline in NGHP-02 Area B.

Marine and Petroleum Geology↗

Historical methane hydrate project review

In 1995, U.S. Geological Survey made the first systematic assessment of the volume of natural gas stored in the hydrate accumulations of the United States. That study, along with numerous other studies, has shown that the amount of gas stored as methane hydrates in the world greatly exceeds the volume of known conventional gas resources. However, gas hydrates represent both a scientific and technical challenge and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of gas hydrates in nature, (2) assessing the volume of natural gas stored within various gas hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural gas hydrates, and (5) analyzing the effects of methane hydrate on drilling safety. Methane hydrates are naturally occurring crystalline substances composed of water and gas, in which a solid water-­‐lattice holds gas molecules in a cage-­‐like structure. The gas and water becomes a solid under specific temperature and pressure conditions within the Earth, called the hydrate stability zone. Other factors that control the presence of methane hydrate in nature include the source of the gas included within the hydrates, the physical and chemical controls on the migration of gas with a sedimentary basin containing methane hydrates, the availability of the water also included in the hydrate structure, and the presence of a suitable host sediment or “reservoir”. The geologic controls on the occurrence of gas hydrates have become collectively known as the “methane hydrate petroleum system”, which has become the focus of numerous hydrate research programs. Recognizing the importance of methane hydrate research and the need for a coordinated effort, the U.S. Congress enacted Public Law 106-­‐193, the Methane Hydrate Research and Development Act of 2000. This Act called for the Secretary of Energy to begin a methane hydrate research and development program in consultation with other U.S. federal agencies. At the same time a new methane hydrate research program had been launched in Japan by the Ministry of International Trade and Industry to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. Since this early start we have seen other countries including India, China, Canada, and the Republic of Korea establish large gas hydrate research and development programs. These national led efforts have also included the investment in a long list of important scientific research drilling expeditions and production test studies that have provided a wealth of information on the occurrence of methane hydrate in nature. The most notable expeditions and projects have including the following: -­‐Ocean Drilling Program Leg 164 (1995) -­‐Japan Nankai Trough Project (1999-­‐2000) -­‐Ocean Drilling Program Leg 204 (2004) -­‐Japan Tokai-­‐oki to Kumano-­‐nada Project (2004) -­‐Gulf of Mexico JIP Leg I (2005) -­‐Integrated Ocean Drilling Program Expedition 311 (2005) -­‐Malaysia Gumusut-­‐Kakap Project (2006) -­‐India NGHP Expedition 01 (2006) -­‐China GMGS Expedition 01 (2007) -­‐Republic of Korea UBGH Expedition 01 (2007) -­‐Gulf of Mexico JIP Leg II (2009) -­‐Republic of Korea UBGH Expedition 02 (2010) -­‐MH-­‐21 Nankai Trough Pre-­‐Production Expedition (2012-­‐2013) -­‐Mallik Gas Hydrate Testing Projects (1998/2002/2007-­‐2008) -­‐Alaska Mount Elbert Stratigraphic Test Well (2007) -­‐Alaska Iġnik Sikumi Methane Hydrate Production Test Well (2011-­‐2012) Research coring and seismic programs carried out by the Ocean Drilling Program (ODP) and Integrated Ocean Drilling Program (IODP), starting with the ODP Leg 164 drilling of the Blake Ridge in the Atlantic Ocean in 1995, have also contributed greatly to our understanding of the geologic controls on the formation, occurrence, and stability of gas hydrates in marine environments. For the most part methane hydrate research expeditions carried out by the ODP and IODP provided the foundation for our scientific understanding of gas hydrates. The methane hydrate research efforts under ODP-­‐IODP have mostly dealt with the assessment of the geologic controls on the occurrence of gas hydrate, with a specific goal to study the role methane hydrates may play in the global carbon cycle. Over the last 10 years, national led methane hydrate research programs, along with industry interest have led to the development and execution of major methane hydrate production field test programs. Two of the most important production field testing programs have been conducted at the Mallik site in the Mackenzie River Delta of Canada and in the Eileen methane hydrate accumulation on the North Slope of Alaska. Most recently we have also seen the completion of the world’s first marine methane hydrate production test in the Nankai Trough in the offshore of Japan. Industry interest in gas hydrates has also included important projects that have dealt with the assessment of geologic hazards associated with the presence of hydrates. The scientific drilling and associated coring, logging, and borehole monitoring technologies developed in the long list of methane hydrate related field studies are one of the most important developments and contributions associated with methane hydrate research and development activities. Methane hydrate drilling has been conducted from advanced scientific drilling platforms like the JOIDES Resolution and the D/V Chikyu, which feature highly advanced integrated core laboratories and borehole logging capabilities. Hydrate research drilling has also included the use of a wide array of industry, geotechnical and multi-­‐service ships. All of which have been effectively used to collect invaluable geologic and engineering data on the occurrence of methane hydrates throughout the world. Technologies designed specifically for the collection and analysis of undisturbed methane hydrate samples have included the development of a host of pressure core systems and associated specialty laboratory apparatus. The study and use of both wireline conveyed and logging-­‐while-­‐drilling technologies have also contributed greatly to our understanding of the in-­‐situ nature of hydrate-­‐bearing sediments. Recent developments in borehole instrumentation specifically designed to monitor changes associated with hydrates in nature through time or to evaluate the response of hydrate accumulations to production have also contributed greatly to our understanding of the complex nature and evolution of methane hydrate systems. Our understanding of how methane hydrates occur and behave in nature is still growing and evolving – we do not yet know if methane hydrates can be economically produced, nor do we know fully the role of hydrates as an agent of climate change or as a geologic hazard. But it is known for certain that scientific drilling has contributed greatly to our understanding of hydrates in nature and will continue to be a critical source of the information to advance our understanding of methane hydrates.

Report↗

Sedimentary and structural patterns on the northern Santa Rosa-Cortes Ridge, southern California

The Santa Rosa-Cortes Ridge is an 1800 m high, 180 km long feature lying approximately 90 km off the coast of southern California and directly south of the northern group of Channel Islands. Geophysical profiling and sampling cruises to the northern part of the ridge, an area of recent and future lease sales for petroleum development, provide a strong data base for interpretation of structural and sedimentary patterns and their relation to potential geologic hazards. The northern part of the ridge is a complexly folded and faulted northwest-trending anticlinorium composed mostly of lower and middle Miocene shale and mudstone. Erosional remnants of upper Miocene and Pliocene rocks unconformably overlie highly folded pre-upper Miocene strata. The major structure of the ridge developed almost continuously from Oligocene or early Miocene time to the end of the Tertiary; many small folds formed between post-late Miocene and pre-late Pleistocene time. Numerous small faults cut the rocks on the ridge top. Faults cut basement rocks on the west side of the ridge along the Ferrelo fault zone. Published data on historical epicenters and evidence of offsets on the seafloor from seismic reflection and side-scan profiles, including limited evidence of possible strike-slip movement along fault traces, indicate that the northern Santa Rosa-Cortes Ridge is tectonically active. The crest of the ridge was truncated as the result of repeated sea-level fluctuations in the Quaternary. A thin veneer of unconsolidated medium to fine sand, less than 3 m thick, mantles most of the ridge; locally in topographically low areas and on the upper flanks of the ridge, thickness exceeds 20 m. The meager sediment cover, coupled with available evidence of relatively strong currents flowing across the ridge top, indicate that the ridge is an area of nondeposition or winnowing of fine sediments. Modern sediments become thicker and finer-grained from the ridge top to the ridge flanks, suggesting active accretion in those areas. Slumps are present at various depths on the flanks, and it seems probable that the thicker deposits (> 20 m) of modern sediments on the upper flanks will be sites of future slumping.

California↗

Genetic structure of eelgrass Zostera marina meadows in an embayment with restricted water flow

Genetic structure of the seagrass Zostera marina in a coastal lagoon with restricted water flow, and with heterogeneous water residence times and oceanographic characteristics, was assessed using 8 polymorphic microsatellite loci. Analyses of genetic differentiation (θ) and Bayesian clustering suggested that the Z. marina population in San Quintin Bay (SQB) is genetically substructured, with at least 4 genetically different groups: (1) West Head, (2) Mouth, (3) East Arm, and (4) East Head. The greatest θ value was observed between the most distant sites (θ = 0.095). The lowest values were found among sites closest to the mouth of the coastal lagoon (θ = 0.000 to 0.009). The maximum likelihood approach showed that the sites at the mouth have a mixed pattern of gene flow without a unidirectional pattern. In contrast, there was a clear pattern of asymmetrical gene flow from the mouth towards the West Head. These results suggested that the restriction of water flow at the heads, current pattern, and the distance between sites can reduce genetic flow and promote genetic differences within Z. marina meadows in small water embayments such as SQB. Though the population is genetically substructured and a 14% decline in cover has been detected, this study did not show evidence of a recent genetic bottleneck. In contrast, mouth sites have experienced a recent expansion in their population size, and also perhaps a recent influx of rare alleles from genetically distinct immigrants

Marine Ecology Progress Series↗

Assessing inundation hazards to nuclear powerplant sites using geologically extended histories of riverine floods, tsunamis, and storm surges

Most nuclear powerplants in the United States are near rivers, large lakes, or oceans. As evident from the Fukushima Daiichi, Japan, disaster of 2011, these water bodies pose inundation threats. Geologic records can extend knowledge of rare hazards from flooding, storm surges, and tsunamis. This knowledge can aid in assessing the safety of critical structures such as dams and energy plants, for which even remotely possible hazards are pertinent. Quantitative analysis of inundation from geologic records perhaps is most developed for and applied to riverine flood hazards, but because of recent natural disasters, geologic investigations also are now used widely for understanding tsunami hazards and coastal storm surges. Layered sedimentary deposits commonly give the most complete geologic record of large floods, storm surges, and tsunamis. Sedimentary layers may be preserved for hundreds or thousands of years in suitable depositional environments, thereby providing an archive of rare, high-magnitude events. All inundation hazards discussed in this report—riverine floods, tsunamis, and storm surges—have had long records extracted from sedimentary sequences, many specifically for hazard assessment. Geologic records commonly are imprecise, so most hazard assessments benefit from evaluation of many sites and rigorous uncertainty assessment. Despite uncertainties, geologic records commonly can improve knowledge of the types and magnitudes of hazards threatening specific sites or regions. New statistical tools and approaches can efficiently incorporate geologic information into frequency assessments. These tools are most developed for riverine flood hazards, but are to some degree transferable to other episodic natural phenomena such as tsunamis and storm surges. Even with these efficient statistical approaches for examining geologic records, systematic landscape changes may reduce the applicability of retrospective assessments. These non-stationarity issues (such as climate change, sea‑level rise, land-use, dams and flow regulation) may all affect the validity of using past experience—no matter how complete the record—to assess future likelihoods. These issues require site-specific consideration for nearly all hazard assessments drawn from geologic evidence. A screening of the 104 nuclear powerplants in the United States licensed by the Nuclear Regulatory Commission (at 64 sites) indicates several sites for which paleoflood studies likely would provide additional flood-frequency information. Two sites—Duane Arnold, Iowa, on the Cedar River; and David-Besse, Ohio, on the Toussaint River—have geologic conditions suitable for creating and preserving stratigraphic records of flooding and few upstream dams that may complicate flood-frequency analysis. One site—Crystal River, Florida1, on the Withlacoochee River and only 4 kilometers from the coast—has high potential as a candidate for assessing riverine and marine inundation hazards. Several sites on the Mississippi River have high geologic potential, but upstream dams almost certainly now regulate peak flows. Nevertheless, studies on the Mississippi River to evaluate long-term flood frequency may provide results applicable to a wide spectrum of regional hazard issues. Several sites in the southeastern United States have high geologic potential, and studies at these sites also may be helpful in evaluating hazards from outburst floods from landslide dams (river blockages formed by mass movements), which may be a regional hazard. For all these sites, closer investigation and field reconnaissance would be needed to confirm suitable deposits and settings for a complete paleoflood analysis. Similar screenings may help identify high-potential sites for geologic investigations of tsunami and storm-surge hazards.

Scientific Investigations Report↗

Evaluation of extinction risk for stream fishes within an urban riverscape using population viability analysis

1. The Santa Ana River in the Los Angeles region of California demonstrates common habitat degradation symptoms that are characteristic of the urban stream syndrome. These impacts have altered the Santa Ana River community structure, with few species as impacted as the native Santa Ana sucker (sucker; Pantosteus santaanae ). 2. Consequently, a recovery plan developed for sucker identified the need for a population viability analysis (PVA) to assess sucker extirpation risk. However, PVAs can be data-intensive and are subject to several sources of bias when standardized protocols are absent. 3. More than 20 years of sucker and arroyo chub (chub; Gila orcuttii ) surveys using different methods were compiled to build an integrated hierarchical multi-population PVA to estimate trends in abundance and extirpation probability of these native fishes from the Santa Ana River. 4. PVA modelling indicated similar patterns in sucker and chub abundance along the Santa Ana River, with the highest abundance of both species in the upper regions of the river during the early 2000s and downstream in recent years (2018–2022). Extirpation risk was estimated to be greatest near wastewater treatment facilities, where native fish abundance estimates have been zero since 2018. Extirpation risk was lower downstream of the wastewater treatment facilities for both species, although extinction risk was higher for sucker than chub throughout the river. 5. As the model evolves and more data are collected, the PVA could be used to assess the effects of various management actions, such as non-native predator removals and native fish re-introductions, on sucker and chub persistence.

California↗

Perspectives on chemical oceanography in the 21st century: Participants of the COME ABOARD Meeting examine aspects of the field in the context of 40 years of DISCO

The questions that chemical oceanographers prioritize over the coming decades, and the methods we use to address these questions, will define our field's contribution to 21st century science. In recognition of this, the U.S. National Science Foundation and National Oceanic and Atmospheric Administration galvanized a community effort (the Chemical Oceanography MEeting: A BOttom-up Approach to Research Directions, or COME ABOARD) to synthesize bottom-up perspectives on selected areas of research in Chemical Oceanography. Representing only a small subset of the community, COME ABOARD participants did not attempt to identify targeted research directions for the field. Instead, we focused on how best to foster diverse research in Chemical Oceanography, placing emphasis on the following themes: strengthening our core chemical skillset; expanding our tools through collaboration with chemists, engineers, and computer scientists; considering new roles for large programs; enhancing interface research through interdisciplinary collaboration; and expanding ocean literacy by engaging with the public. For each theme, COME ABOARD participants reflected on the present state of Chemical Oceanography, where the community hopes to go and why, and actionable pathways to get there. A unifying concept among the discussions was that dissimilar funding structures and metrics of success may be required to accommodate the various levels of readiness and stages of knowledge development found throughout our community. In addition to the science, participants of the concurrent Dissertations Symposium in Chemical Oceanography (DISCO) XXV, a meeting of recent and forthcoming Ph.D. graduates in Chemical Oceanography, provided perspectives on how our field could show leadership in addressing long-standing diversity and early-career challenges that are pervasive throughout science. Here we summarize the COME ABOARD Meeting discussions, providing a synthesis of reflections and perspectives on the field.

Marine Chemistry↗

Origin of pockmarks and chimney structures on the flanks of the Storegga Slide, offshore Norway

Seafloor pockmarks and subsurface chimney structures are common on the Norwegian continental margin north of the Storegga Slide scar. Such features are generally inferred to be associated with fluid expulsion, and imply overpressures in the subsurface. Six long gravity and piston cores taken from the interior of three pockmarks were compared with four other cores taken from the same area but outside the pockmarks, in order to elucidate the origins and stratigraphy of these features and their possible association with the Storegga Slide event. Sulfate gradients in cores from within pockmarks are less steep than those in cores from outside the pockmarks, which indicates that the flux of methane to the seafloor is presently smaller within the pockmarks than in the adjacent undisturbed sediments. This suggests that these subsurface chimneys are not fluid flow conduits lined with gas hydrate. Methane-derived authigenic carbonates and Bathymodiolus shells obtained from a pockmark at >6.3 m below the seafloor indicate that methane was previously available to support a chemosynthetic community within the pockmark. AMS 14C measurements of planktonic Foraminifera overlying and interlayered with the shell-bearing sediment indicate that methane was present on the seafloor within the pockmark prior to 14 ka 14C years B.P., i.e., well before the last major Storegga Slide event (7.2 ka 14C years B.P., or 8.2 ka calendar years B.P.). These observations provide evidence that overpressured fluids existed within the continental margin sediments off Norway during the last major advance of Pleistocene glaciation.

Geo-Marine Letters↗

Assessment of the petroleum, coal, and geothermal resources of the Economic Community of West African States (ECOWAS) region

Approximately 85 percent of the land area of the ECOWAS (Economic Community of West African States) region is covered by basement rocks (igneous and highly metamorphosed rocks) or relatively thin layers of Paleozoic, Upper Precambrian, and 'Continental Intercalaire? sedimentary rocks. These areas have little or no petroleum potential. Areas of the ECOWAS region that have potential for petroleum production or potential for increased petroleum production include the narrow belt of sedimentary rocks that stretches along the continental margin from Mauritania to Nigeria and the Niger Delta and the Benue depression. The Senegal Basin, located on the continental margin of Mauritania, Senegal, Gambia, Guinea Bissau, and Guinea, has been intensely explored by the oil industry and most of the larger structures onshore and on the shelf probably have been tested by drilling with little or no resulting commercial production. Unless basic ideas pertaining to the petroleum geology of the Senegal Basin are revised, future discoveries are expected to be limited to small fields overlooked by industry at a time when petroleum prices were low. On the continental shelf of Sierra Leone and the continental shelf of northeast and central Liberia, the sedimentary rocks are relatively thin, and industry has shown little interest in the area. On the continental rise of these countries, however, the sedimentary section, deposited in a complex fault-block system, increases in thickness. A renewal of industry interest in this deep-water area will probably follow further development of deep-water production technology. A recent oil discovery on the continental slope off the Ivory Coast is expected to spur further exploration offshore of southeastern Liberia, Ivory Coast, Ghana, Togo, and Benin. This relatively unexplored area in the Gulf of Guinea has good possibilities .for the discovery of giant oil fields. Nigeria's oil development from the Niger Delta may have peaked, as 13 of 14 giant oil fields were discovered prior to 1969 and the greatest number of fields were discovered in the period 1965 through 1967. Like delta regions in other parts of the world, individual oil fields of the Niger Delta are small to medium by world standards and future discoveries, therefore, are likely to reflect this reality. The natural gas resources of the Niger Delta, unlike its oil resources, are comparatively underdeveloped. Parts of the Benue depression in Nigeria and Niger could contain significant deposits of petroleum. The lower Benue depression, immediately north of the Niger Delta, has been extensively explored by drilling. Except for noncommercial discoveries of oil and gas and traces of oil and gas on the ground surface, the results of exploration in the lower Benue depression were negative. However, in the Lake Chad area of Chad and in southern Chad near the Central African Republic boundary, oil and gas discoveries were made just prior to the cessation of all drilling and exploration activity in early 1979. It is rumored that these discoveries may be large although little information is available. The relation between the two areas in Chad and their overall relation to the Benue depression is poorly understood; however, the possibility of thick sedimentary sections containing Cretaceous marine source rock and Tertiary reservoir beds-all contained within grabens in a highly faulted failed-arm system subjected to high heat flow--is attractive. Of the ECOWAS countries, only Nigeria and Niger produce coal commercially. Nigeria produces subbituminous coal from Paleocene-Maestrichtian and Maestrichtian (Late Cretaceous) age rocks of the Niger Delta region; reserves are estimated, on the basis of extensive drilling, to be 350 million tons (standard coal equivalent). In addition, lignite deposits of the Niger Delta appear to be large but have not been developed. Niger produces small amounts of coal used locally by uranium mine and mill operations from C

Open-File Report↗

Speculations on the petroleum geology of the accretionary body: an example from the central Aleutians

In the 300 km wide Adak-Amlia sector of the central Aleutian Trench ??? 36 000 km3 of offscraped trench fill makes up the wedge-shaped mass of the Aleutian accretionary body. Within this wedge, seismic reflection profiles reveal an abundance of potential hydrocarbon-trapping structures. These structures include antiforms, thrust and normal faults, and stratigraphic pinchouts. Maximum closure on these features is 2 km. In addition, the silt and possibly sand size sediment within the offscraped turbidite deposits, and the porous diatomaceous pelagic deposits interbedded with and at the base of the wedge, may define suitable reservoirs for the entrapment of hydrocarbons. Potential seals for these reservoirs include diagenetically-altered and -produced siliceous and carbonate sediment. The organic carbon input into the central Aleutian Trench, based on carbon analyses of DSDP Legs 18 and 19 core samples, suggests that the average organic carbon content within the accretionary body is approximately 0.3-0.6%. Heat flow across the Aleutian Terrace indicates that at present the oil generation window lies at a depth of 3-6.5 km. At depths of 8 km (which corresponds to the maximum depth the offscraped sediment has been seismically resolved beneath the lower trench slope), the probable high (170-180??C) temperatures prohibit all but gas generation. The dewatering of trench sediment and subducted oceanic crust should produce an abundance of fluids circulating within the accretionary body. These fluids and gases can conduct hydrocarbons to any of the abundant trapping geometries or be lost from the system through sea floor seepage. In the Aleutian accretionary body all the conditions necessary for the formation of oil and gas deposits exist. The size and ultimate preservation of these deposits, however, are dependent on the deformational history of the prism both during accretion and after the accretion process has been superceded by subsequent tectonic regimes. ?? 1984.

Marine and Petroleum Geology↗

Submarine groundwater discharge to Tampa Bay: Nutrient fluxes and biogeochemistry of the coastal aquifer

To separately quantify the roles of fresh and saline submarine groundwater discharge (SGD), relative to that of rivers, in transporting nutrients to Tampa Bay, Florida, we used three approaches (Darcy's Law calculations, a watershed water budget, and a 222 Rn mass-balance) to estimate rate of SGD from the Pinellas peninsula. Groundwater samples were collected in 69 locations in the coastal aquifer to examine biogeochemical conditions, nutrient concentrations and stoichiometry, and salinity structure. Salinity structure was also examined using stationary electrical resistivity measurements. The coastal aquifer along the Pinellas peninsula was chemically reducing in all locations sampled, and that condition influences nitrogen (N) form and mobility of N and PO 4 3− . Concentrations of NH 4 + , PO 4 3− and ratio of dissolved inorganic N (DIN) to PO 4 3− were all related to measured oxidation/reduction potential (pε) of the groundwater. Ratio of DIN: PO 4 3− was below Redfield ratio in both fresh and saline groundwater. Nitrogen occurred almost exclusively in reduced forms, NH 4 + and dissolved organic nitrogen (DON), suggesting that anthropogenic N is exported from the watershed in those forms. In comparison to other SGD studies, rate of PO 4 3− flux in the seepage zone (μM m − 2 d − 1 ) in Tampa Bay was higher than previous estimates, likely due to 1) high watershed population density, 2) chemically reducing conditions, and 3) high ion concentrations in fresh groundwater. Estimates of freshwater groundwater flux indicate that the ratio of groundwater discharge to stream flow is ∼ 20 to 50%, and that the magnitudes of both the total dissolved nitrogen and PO 4 3− loads due to fresh SGD are ∼ 40 to 100% of loads carried by streams. Estimates of SGD based on radon inventories in near-shore waters were 2 to 5 times greater than the estimates of freshwater groundwater discharge, suggesting that brackish and saline SGD is also an important process in Tampa Bay and results in flux of regenerated N and P from sediment to surface water.

Florida↗

Metals in Devonian kerogenous marine strata at Gibellini and Bisoni properties in southern Fish Creek Range, Eureka County, Nevada

A kerogen-rich sequence of siliceous mudstone, siltstone, and chert as much as 60 m thick on ridge 7129 in the southern Fish Creek Range, referred to as Gibellini facies of the Woodruff Formation, has been evaluated on the surface and in drill holes principally for its potential resources of vanadium, zinc, selenium, molybdenum, and syncrude oil content. The strata are part of a strongly deformed allochthonous mass of eugeosynclinal Devonian marine rocks that overlie deformed allochthonous Mississippian siliceous rocks and relatively undeformed autochthonous Mississippian Antler flysch at this locality. The vanadium in fresh black rocks obtained from drill holes and fresh exposures in trenches and roadcuts occurs chiefly in organic matter. Concentrations of vanadium oxide (V2O5) in unoxidized samples range from 3,000 to 7,000 ppm. In oxidized and bleached rock that is prevalent at the surface, concentrations of vanadium oxide range from 6,000 to 8,000 ppm, suggesting a tendency toward enrichment due to surficial weathering and ground-water movement. Zinc occurs in sphalerite, and selenium occurs in organic matter; molybdenum appears to occur both in molybdenite and in organic matter. Concentrations of zinc in unoxidized rock range from 4,000 to 18,000 ppm, whereas in oxidized rock they range from 30 to 100 ppm, showing strong depletion due to weathering. Concentrations of selenium in unoxidized rock range from 30 to 200 ppm, whereas in oxidized rock they range from 200 to 400 ppm, indicating some enrichment upon weathering. Concentrations of molybdenum in unoxidized rock range from 70 to 960 ppm, whereas in oxidized rock they range from 30 to 80 ppm, indicating strong depletion upon weathering. Most fresh black rock is low-grade oil shale, and yields as much as 12 gallons/short ton of syncrude oil. Metahewettite is the principal vanadium mineral in the oxidized zone, but it also occurs sparsely as small nodules and fillings of microfractures in unweathered strata. In fresh rock, bluish-white opaline-like silica (chalcedonic quartz) fills microfractures, and is believed to have originated by diagenetic mobilization of opaline silica from radiolarian tests and sponge spicules. As revealed by microscopic study, the Gibellini facies originally consisted of siliceous muds, slimes, and oozes high in organic constituents. The organic matter is amorphous flaky and stringy sapropel, and probably includes remains of bacteria, phytoplankton, zooplankton, and minor higher plants. Recognizable organic remnants include radiolarian tests, sponge spicules, conodonts, brachiopod shells, algae, and humic debris. Diagnostic radiolarians indicate a Late Devonian age for the Gibellini facies of the Woodruff Formation. Some pyrite is disseminated through the rock and may be primary (syngenetic) but significant pyrite and marcasite occur in chalcedonic quartz veinlets and appear to be diagenetic. In fresh rock, black solid bitumen and liquid oil fill voids and microfractures. These early phase hydrocarbons probably were released during diagenesis from complex nonhydrocarbon molecular structures originating from living organisms, and formed without any major thermal degradation of the kerogen. Gas chromatographic analysis of the saturated hydrocarbon fraction indicates a very complex mixture dominated by branched and cyclic compounds. Conodont and palynomorph color alteration, vitrinite reflectance, and other organic geochemical data suggest that the organic matter in the rock is thermally immature and has not been subjected to temperatures greater than 60?C since deposition in Devonian time. All of these characteristics are consistent with the interpretation of a relatively low temperature and a shallow-burial history for the Gibellini facies on ridge 7129.

Open-File Report↗

Formation of ferromanganese crusts on northwest intertropical Pacific seamounts: Electron photomicrography and microprobe chemistry

Seven ferromanganese crusts from the northwest intertropical Pacific seamounts were analyzed for photomicroscopic growth structures, microprobe chemistry, and ages based on Co-chronometer growth rate. The crusts on the Marshall Islands seamounts are thick and ale divided into phosphatized lower older and nonphosphatized upper younger growth generations: the older crust consists of compact laminations and columns impregnated with carbonate fluoapatite (CFA), whereas the younger crust is characterized by porous botryoids and columns of ??-MnO2 and Fe oxyhydroxide. The crusts on the Federated States of Micronesia (FSM) and Palau Islands seamounts are thin and are often incorporated with inorganic opal-A in the uppermost part, comprising the younger generation. Some crusts show scours and fractures. Although the growth of crusts has been often interrupted by mass failure of slope sediments, the crusts on the Marshall Islands seamounts are estimated to have grown at rate of about 3 mm/Ma since the middle Eocene and to have been phosphatized in the late Oligocene during the host seamounts were located beneath the equatorial zone of high productivity. Prolonged infiltration of the oxygen minimum zone (OMZ) water into shallower water older crusts redistributed crust composition by precipitating CFA, enriching subsequent amounts of Mn and Ni, and removing some Co. The younger crust has formed at slower rate (about 2 mm/Ma) under the stronger influence of bottom-water circulation in the north of the equatorial zone, concentrating abundant Co. In the uppermost part of some crusts, siliceous skeletons transform with burial to inorganic opal-A and Si-rich Fe oxyhydroxide, suggesting that biosilica diagenesis can enhance crust growth. (C) 2000 Elsevier Science B.V.

Marine Geology↗

Pre-, syn-, and postcollisional stratigraphic framework and provenance of upper triassic-upper cretaceous strata in the northwestern talkeetna mountains, alaska

Mesozoic strata of the northwestern Talkeetna Mountains are located in a regional suture zone between the allochthonous Wrangellia composite terrane and the former Mesozoic continental margin of North America (i.e., the Yukon-Tanana terrane). New geologic mapping, measured stratigraphic sections, and provenance data define a distinct three-part stratigraphy for these strata. The lowermost unit is greater than 290 m thick and consists of Upper Triassic-Lower Jurassic mafic lavas, fossiliferous limestone, and a volcaniclastic unit that collectively we informally refer to as the Honolulu Pass formation. The uppermost 75 m of the Honolulu Pass formation represent a condensed stratigraphic interval that records limited sedimentation over a period of up to ca. 25 m.y. during Early Jurassic time. The contact between the Honolulu Pass formation and the overlying Upper Jurassic-Lower Cretaceous clastic marine strata of the Kahiltna assemblage represents a ca. 20 m.y. depositional hiatus that spans the Middle Jurassic and part of Late Jurassic time. The Kahiltna assemblage may to be up to 3000 m thick and contains detrital zircons that have a robust U-Pb peak probability age of 119.2 Ma (i.e., minimum crystallization age/maximum depositional age). These data suggest that the upper age of the Kahiltna assemblage may be a minimum of 10-15 m.y. younger than the previously reported upper age of Valanginian. Sandstone composition (Q-43% F-30% L-27%-Lv-71% Lm-18% Ls-11%) and U-Pb detrital zircon ages suggest that the Kahiltna assemblage received igneous detritus mainly from the active Chisana arc, remnant Chitina and Talkeetna arcs, and Permian-Triassic plutons (Alexander terrane) of the Wrangellia composite terrane. Other sources of detritus for the Kahiltna assemblage were Upper Triassic-Lower Jurassic plutons of the Taylor Mountains batholith and Devonian-Mississippian plutons; both of these source areas are part of the Yukon-Tanana terrane. The Kahiltna assemblage is overlain by previously unrecognized nonmarine strata informally referred to here as the Caribou Pass formation. This unit is at least 250 m thick and has been tentatively assigned an Albian-Cenomanian-to-younger age based on limited palynomorphs and fossil leaves. Sandstone composition (Q-65% F-9% L-26%-Lv-28% Lm-52% Ls-20%) from this unit suggests a quartz-rich metamorphic source terrane that we interpret as having been the Yukon-Tanana terrane. Collectively, provenance data indicate that there was a fundamental shift from mainly arc-related sediment derivation from sources located south of the study area during Jurassic-Early Cretaceous (Aptian) time (Kahiltna assemblage) to mainly continental margin-derived sediment from sources located north and east of the study area by Albian-Cenomanian time (Caribou Pass formation). We interpret the threepart stratigraphy defined for the northwestern Talkeetna Mountains to represent pre- (the Honolulu Pass formation), syn- (the Kahiltna assemblage), and post- (the Caribou Pass formation) collision of the Wrangellia composite terrane with the Mesozoic continental margin. A similar Mesozoic stratigraphy appears to exist in other parts of south-central and southwestern Alaska along the suture zone based on previous regional mapping studies. New geologic mapping utilizing the three-part stratigraphy interprets the northwestern Talkeetna Mountains as consisting of two northwest-verging thrust sheets. Our structural interpretation is that of more localized thrust-fault imbrication of the three-part stratigraphy in contrast to previous interpretations of nappe emplacement or terrane translation that require large-scale displacements. Copyright ?? 2007 The Geological Society of America.

Special Paper of the Geological Society of America↗

Development of the Astoria Canyon-Fan physiography and comparison with similar systems

A detailed bathymetric study of Astoria Canyon and Astoria Fan provides a model for typical submarine canyon-fan systems. The present canyon head is 9 miles (17 km) west of the Columbia River mouth but buried Pleistocene channels appear to have connected the two features in the past. The canyon, which is distinguished by its relief, V-shaped profiles, and numerous tributaries, winds sinuously and is coincident with apparent structural trends across the continental shelf and slope. At the fan apex, the canyon mouth merges smoothly into Astoria Channel, which is characterized by its U-shaped profiles, lower walls of even height, and levee development. Astoria Channel and the fan valley at the base of the continental slope are the most recently active of a series of main fan valleys that appear to have: ( 1 ) progressively “hooked left”; ( 2 ) migrated from north to south across the fan during its formation; and ( 3 ) been partly responsible for the asymmetrical shape of the fan. The deep, narrow upper fan valleys that characterize the steep (> 1:100, or 0°35′) and rough (10–30 fathoms, or 18–55 m) upper fan surface break into distributaries on the middle fan, where there is the sharpest change in gradient. The main valleys become broader and shallower down the fan, while the generally concave fan surface grades to nearly a flat seafloor (to gradients < 1:1000, or 0°0.5′), (< 10 fathoms, or 18 m relief). Similarity of Astoria Canyon-Fan system with other deep-sea fan and alluvial fan systems, suggests the hypothesis that size of drainage basin, sediment size, and sediment load control the size, gradient, and valley development of any fan system. Data from bathymetry, seismic refraction stations, and sediment load of the Columbia River indicate that the cutting of Astoria Canyon and the deposition of the unconsolidated sediment layer forming Astoria Fan could have been accomplished during the Pleistocene. A similar history can be suggested for other major submarine canyon-fan systems.

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