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USGS2005

Relation of organic contaminant equilibrium sorption and kinetic uptake in plants

Plant uptake is one of the environmental processes that influence contaminant fate. Understanding the magnitude and rate of plant uptake is critical to assessing potential crop contamination and the development of phytoremediation technologies. We determined (1) the partition-dominated equilibrium sorption of lindane (LDN) and hexachlorobenzene (HCB) by roots and shoots of wheat seedlings, (2) the kinetic uptake of LDN and HCB by roots and shoots of wheat seedlings, (3) the kinetic uptake of HCB, tetrachloroethylene (PCE), and trichloroethylene (TCE) by roots and shoots of ryegrass seedlings, and (4) the lipid, carbohydrate, and water contents of the plants. Although the determined sorption and the plant composition together suggest the predominant role of plant lipids for the sorption of LDN and HCB, the predicted partition with lipids of LDN and HCB using the octanol-water partition coefficients is notably lower than the measured sorption, due presumably to underestimation of the plant lipid contents and to the fact that octanol is less effective as a partition medium than plant lipids. The equilibrium sorption or the estimated partition can be viewed as the kinetic uptake limits. The uptakes of LDN, PCE, and TCE from water at fixed concentrations increased with exposure time in approach to steady states. The uptake of HCB did not reach a plateau within the tested time because of its exceptionally high partition coefficient. In all of the cases, the observed uptakes were lower than their respective limits, due presumably to contaminant dissipation in and limited water transpiration by the plants. ?? 2005 American Chemical Society.

Environmental Science & Technology↗

USGS2025

Module 4: Basic biology of wetland animals

An assortment of animals inhabit wetlands, with many invertebrates, amphibians and reptiles, fishes, birds, and some mammals being wetland specialists. Wetlands provide ample water, food, and cover that benefits resident animals, but periodic high floods, frequent drying, and harsh water qualities (low-oxygen, acidic, saline) can stress wetland animals. Animals that rely on wetlands have developed numerous adaptations to cope with these stresses. The animal biodiversity in wetlands is particularly valued by people, from deep historical and cultural connections, to modern ecotourists and bird watchers who observe it and hunters and anglers who appreciate the consumptive resources they provide. Animals such as alligators and beavers create or physically-modify wetland environments; this activity is called ecosystem engineering and makes these animals among the most important organisms to wetland ecology. Wetlands are high in biodiversity and support rich communities of wetland invertebrates, are primary breeding habitats for most amphibians, and nearly all migratory birds rely on wetlands during some part of their annual cycle. The interactions of animals with plants (herbivory, cutting) and each other (predation) strongly shape wetland environments and affect nutrient cycling. Human impacts on wetlands can negatively affect many animals through habitat loss and degradation, resulting in many wetland amphibians, reptiles, and birds being listed as threatened and endangered species. Thus, wetland conservation is vital to conserve many animal species.

Wetland Science & Practice↗

USGS2026

Inference of pattern-based geological CO2 sequestration and oil recovery potential in a commingled main pay and residual oil zone CO2-EOR flood

Several detailed studies have shown that residual oil zones (ROZs) can present significant resources for additional hydrocarbon recovery as well as subsurface carbon dioxide (CO 2 ) sequestration via enhanced oil recovery by injecting CO 2 (CO 2 -EOR). Field development strategies included new wells drilled dedicated to main pay zones (MPZ) and ROZs, or existing wells in MPZs deepened to ROZs for commingled injection-production using different well patterns. The latter presented a challenge when discerning the injection and production from each of the zones, and for subsequent quantification of CO 2 sequestration and EOR potential from different patterns and from the field. In this paper, an innovative method for analyzing commingled injections and productions from MPZs and ROZs, with application to pattern-based data from four staggered line drive patterns in Wasson Field's Denver Unit, Texas, USA, was developed. Decline curve and ratio-trend methods were used as means of history-matching and forecasting. Cumulative production-time and cumulative production-rate data for oil, gas, and water, as well as water-oil ratio (WOR) and gas-oil ratio (GOR), were analyzed along with injection data for time intervals covering major injection events in MPZ, or MPZ and ROZ combined. A combined analysis enabled inference of allocation of fluids into different zones during WAG (water alternating gas) injection and thereby estimation of CO 2 storage, utilization, and retention in different zones as a function of total injection. Results show that ROZs generally present higher CO 2 sequestration potential compared to MPZs, and a comparable incremental oil recovery factor of ∼20%, on average. Results based on ratio analysis further show that while the WOR trend of the pattern production is mostly dominated and controlled by ROZ, GOR is controlled by both intervals. Although the method relying on decline curves and the approach used in zonal fluid allocations are subject to their limitations, this study presents a practical and innovative well-pattern-based method to infer and forecast CO 2 sequestration and oil recovery quantities and fluid ratios from MPZs and ROZs in commingled operations and highlight the added potential offered by ROZs.

Texas↗

USGS2019

Exposure and potential effects of pesticides and pharmaceuticals in protected streams of the US National Park Service southeast Region

Globally protected areas offer refugia for a broad range of taxa including threatened and endangered species. The United States National Park Service (NPS) manages public lands to preserve biodiversity, but increasing park visitation and development of surrounding landscapes increase exposure to and effects from bioactive contaminants. The risk (exposure and hazard) to NPS protected-stream ecosystems within the highly urbanized southeast region (SER) from bioactive contaminants was assessed in five systems based on 334 pesticide and pharmaceutical analytes in water and 119 pesticides in sediment. Contaminant mixtures were common across all sampled systems, with approximately 24% of the unique analytes (80/334) detected at least once and 15% (49/334) detected in half of the surface-water samples. Pharmaceuticals were observed more frequently than pesticides, consistent with riparian buffers and concomitant spatial separation from non-point pesticide sources in four of the systems. To extrapolate exposure data to biological effects space, site specific cumulative exposure-activity ratios (ΣEAR) were calculated for detected surface-water contaminants with available ToxCast data; common exceedances of a 0.001 ΣEAR effects-screening threshold raise concerns for molecular toxicity and possible, sub-lethal effects to non-target, aquatic vertebrates. The results illustrate the need for continued management of protected resources to reduce contaminant exposure and preserve habitat quality, including prioritization of conservation practices (riparian buffers) near stream corridors and increased engagement with upstream/up-gradient property owners and municipal wastewater facilities.

Alabama, Florida, Georgia, Kentucky, Mississippi, ↗

USGS2018

Storm surge propagation and flooding in small tidal rivers during events of mixed coastal and fluvial influence

The highly urbanized estuary of San Francisco Bay is an excellent example of a location susceptible to flooding from both coastal and fluvial influences. As part of developing a forecast model that integrates fluvial and oceanic drivers, a case study of the Napa River and its interactions with the San Francisco Bay was performed. For this application we utilize Delft3D-FM, a hydrodynamic model that computes conservation of mass and momentum on a flexible mesh grid, to calculate water levels that account for tidal forcing, storm surge generated by wind and pressure fields, and river flows. We simulated storms with realistic atmospheric pressure, river discharge, and tidal forcing to represent a realistic joint fluvial and coastal storm event. Storm conditions were applied to both a realistic field-scale Napa river drainage as well as an idealized geometry. With these scenarios, we determine how the extent, level, and duration of flooding is dependent on these atmospheric and hydrologic parameters. Unsurprisingly, the model indicates that maximal water levels will occur in a tidal river when high tides, storm surge, and large fluvial discharge events are coincident. Model results also show that large tidal amplitudes diminish storm surge propagation upstream and that phasing between peak fluvial discharges and high tide is important for predicting when and where the highest water levels will occur. The interactions between tides, river discharge, and storm surge are not simple, indicating the need for more integrated flood forecasting models in the future.

California↗

USGS2018

Real-time nowcasting of microbiological water quality at recreational beaches: A wavelet and artificial neural network-based hybrid modeling approach

The number of beach closings caused by bacterial contamination has continued to rise in recent years, putting beachgoers at risk of exposure to contaminated water. Current approaches predict levels of indicator bacteria using regression models containing a number of explanatory variables. Data-based modeling approaches can supplement routine monitoring data and provide highly accurate short-term forecasts of beach water quality. In this paper, we apply the nonlinear autoregressive network with exogenous inputs (NARX) method with explanatory variables to predict Escherichia coli concentrations at four Lake Michigan beach sites. We also apply the nonlinear input–output network (NIO) and nonlinear autoregressive neural network (NAR) methods in addition to a hybrid wavelet-NAR (WA-NAR) model and demonstrate their application. All models were tested using 3 months of observed data. Results revealed that the NARX models provided the best performance and that the WA-NAR model, which requires no explanatory variables, outperformed the NIO and NAR models; therefore, the WA-NAR model is suitable for application to data scarce regions. The models proposed in this paper were evaluated using multiple performance metrics, including sensitivity and specificity measures, and produced results comparable or superior to those of previous mechanistic and statistical models developed for the same beach sites. The relatively high R 2 values between data and the NARX models ( R 2 values of ∼0.8 for the beach sites and ∼0.9 for the river site) indicate that the new class of models shows promise for beach management.

Environmental Science & Technology↗

USGS2010

Protocols for geologic hazards response by the Yellowstone Volcano Observatory to activity within the Yellowstone Volcanic System

Executive Summary The Yellowstone Plateau hosts an active volcanic system, with subterranean magma (molten rock), boiling, pressurized waters, and a variety of active faults with significant earthquake hazards. Within the next few decades, light-to-moderate earthquakes and steam explosions are certain to occur. Volcanic eruptions are less likely, but are ultimately inevitable in this active volcanic region. This document summarizes protocols, policies, and tools to be used by the Yellowstone Volcano Observatory (YVO) during earthquakes, hydrothermal explosions, or any geologic activity that could lead to a volcanic eruption. Yellowstone National Park is home to Yellowstone Caldera, the largest volcanic system by volume in the United States, as well as a vigorous hydrothermal system composed of pressurized subsurface boiling waters and active faults capable of generating substantial seismicity. The region is subject to hazards spanning a wide range of intensities, magnitudes, likelihood of occurrence, and geographic extent of impact. These hazards include small and comparatively common hydrothermal explosions, occasional strong earthquakes, rare relatively non-explosive lava flows, and very rare large explosive volcanic eruptions. Addressing the broad style of potential hazards and the vast spatial and temporal scales over which these hazards can occur requires a general plan that outlines the Yellowstone Volcano Observatory (YVO) response to a hazardous or potentially hazardous geological event or unrest (defined as departure from normal activity levels). The U.S. Geological Survey (USGS) Volcano Science Center (VSC) Response Plan for Significant Volcanic Events in the United States (Moran and others, 2024) forms the basis of any response by YVO but will be modified to suit the specific characteristics of the observatory, which operates as a consortium of nine federal, state, and academic institutions. Decisions on declaring an event response or “activity with potential” (defined as unrest that is not immediately hazardous but that may evolve into a hazardous event), as well as any changes in Volcano Alert Level and Aviation Color Code or the release of formal Information Statements, will be made by the USGS via the YVO Scientist-in-Charge (SIC) in consultation with the leads of the YVO member agencies. The YVO response to hazardous or potentially hazardous geological activity in or around Yellowstone National Park will focus on the collection and analysis of data relevant to the location and style of the activity. Those data will be interpreted within the existing geological framework for the region to develop probabilistic assessments of potential outcomes. These interpretations and assessments will be used to support decision making by emergency management officials including Yellowstone National Park managers or within the National Incident Management System if an Incident Command System (ICS) is activated. YVO will also convene a communications group open to each member agency to ensure consistent internal and external messaging and that the public is kept informed of the unrest through formal notifications, social media posts, online content, traditional media interviews, and community meetings. This response plan will be evaluated and updated as needed by the observatory and will be available through the YVO and USGS public websites. Responses to volcanic eruptions and responses outside of the Yellowstone region, but within the YVO area of responsibility (including Arizona, Utah, New Mexico, and Colorado), will follow the U.S. Geological Survey Volcano Science Center Response Plan for Significant Volcanic Events in the United States (Moran and others, 2024).

Idaho, Montana, Wyoming↗

USGS2012

Science strategy for Core Science Systems in the U.S. Geological Survey, 2013-2023

Core Science Systems is a new mission of the U.S. Geological Survey (USGS) that grew out of the 2007 Science Strategy, “Facing Tomorrow’s Challenges: U.S. Geological Survey Science in the Decade 2007–2017.” This report describes the vision for this USGS mission and outlines a strategy for Core Science Systems to facilitate integrated characterization and understanding of the complex earth system. The vision and suggested actions are bold and far-reaching, describing a conceptual model and framework to enhance the ability of USGS to bring its core strengths to bear on pressing societal problems through data integration and scientific synthesis across the breadth of science. The context of this report is inspired by a direction set forth in the 2007 Science Strategy. Specifically, ecosystem-based approaches provide the underpinnings for essentially all science themes that define the USGS. Every point on earth falls within a specific ecosystem where data, other information assets, and the expertise of USGS and its many partners can be employed to quantitatively understand how that ecosystem functions and how it responds to natural and anthropogenic disturbances. Every benefit society obtains from the planet—food, water, raw materials to build infrastructure, homes and automobiles, fuel to heat homes and cities, and many others, are derived from or effect ecosystems. The vision for Core Science Systems builds on core strengths of the USGS in characterizing and understanding complex earth and biological systems through research, modeling, mapping, and the production of high quality data on the nation’s natural resource infrastructure. Together, these research activities provide a foundation for ecosystem-based approaches through geologic mapping, topographic mapping, and biodiversity mapping. The vision describes a framework founded on these core mapping strengths that makes it easier for USGS scientists to discover critical information, share and publish results, and identify potential collaborations that transcend all USGS missions. The framework is designed to improve the efficiency of scientific work within USGS by establishing a means to preserve and recall data for future applications, organizing existing scientific knowledge and data to facilitate new use of older information, and establishing a future workflow that naturally integrates new data, applications, and other science products to make it easier and more efficient to conduct interdisciplinary research over time. Given the increasing need for integrated data and interdisciplinary approaches to solve modern problems, leadership by the Core Science Systems mission will facilitate problem solving by all USGS missions in ways not formerly possible. The report lays out a strategy to achieve this vision through three goals with accompanying objectives and actions. The first goal builds on and enhances the strengths of the Core Science Systems mission in characterizing and understanding the earth system from the geologic framework to the topographic characteristics of the land surface and biodiversity across the nation. The second goal enhances and develops new strengths in computer and information science to make it easier for USGS scientists to discover data and models, share and publish results, and discover connections between scientific information and knowledge. The third goal brings additional focus to research and development methods to address complex issues affecting society that require integration of knowledge and new methods for synthesizing scientific information. Collectively, the report lays out a strategy to create a seamless connection between all USGS activities to accelerate and make USGS science more efficient by fully integrating disciplinary expertise within a new and evolving science paradigm for a changing world in the 21st century.

Open-File Report↗

USGS2007

Differences in phosphorus and nitrogen delivery to the Gulf of Mexico from the Mississippi River Basin

Seasonal hypoxia in the northern Gulf of Mexico has been linked to increased nitrogen fluxes from the Mississippi and Atchafalaya River Basins, though recent evidence shows that phosphorus also influences productivity in the Gulf. We developed a spatially explicit and structurally detailed SPARROW water-quality model that reveals important differences in the sources and transport processes that control nitrogen (N) and phosphorus (P) delivery to the Gulf. Our model simulations indicate that agricultural sources in the watersheds contribute more than 70% of the delivered N and P. However, corn and soybean cultivation is the largest contributor of N (52%), followed by atmospheric deposition sources (16%); whereas P originates primarily from animal manure on pasture and rangelands (37%), followed by corn and soybeans (25%), other crops (18%), and urban sources (12%). The fraction of in-stream P and N load delivered to the Gulf increases with stream size, but reservoir trapping of P causes large local- and regional-scale differences in delivery. Our results indicate the diversity of management approaches required to achieve efficient control of nutrient loads to the Gulf. These include recognition of important differences in the agricultural sources of N and P, the role of atmospheric N, attention to P sources downstream from reservoirs, and better control of both N and P in close proximity to large rivers. ?? 2008 American Chemical Society.

Environmental Science & Technology↗

USGS2019

Probabilistic relationships between acid-base chemistry and fish assemblages in streams of the western Adirondack Mountains, New York, USA

Surface waters across much of the Adirondacks of New York were acidified in the late 20th century but began to recover after the 1990 amendments to the Clean Air Act. Little data, however, were available to characterize biological impacts and predict recovery of fish assemblages in regional streams. Quantitative fish and chemistry surveys were completed in 47 headwater streams during summer 2014-16 to develop logistic (probabilistic) models that characterize the status of contemporary fish assemblages and predict how different N and S deposition loads may affect future fish assemblages. Models for Ali and richness ≥1 species, ANC and total density >400 fish/0.1 ha, ANC and total biomass >1500 g/0.1, presence of Brook Trout, trout density >200 fish/0.1 ha, and trout biomass >1000 g/0.1 ha were suitable for evaluating community and population responses to changes in acid-base chemistry. Anticipated changes in national (US) secondary standards for atmospheric emissions of NOx and SOx to achieve target N and S deposition loads will alter acid-base chemistry and the probabilities for observing various levels of fish metrics in streams across the region and elsewhere.

New York↗

USGS2023

Evaluating regional length limits in freshwater fisheries

Length limits are often used in recreational fisheries management to prevent overharvest and manipulate fish size distributions. These regulations are ideally customized to meet water-specific stock dynamics and fishery objectives. However, in districts with numerous discrete waters, fisheries are commonly managed with a universal regional regulation. Evaluating alternative regional length limits requires consideration of management objectives that may not be important at the single-system level but that emerge as relevant at the regional scale, such as uniformity of regional harvest, diversity of average catch sizes, and opportunity to harvest. We developed a flexible tool for evaluating regional length limits. The tool joins the well-established Beverton–Holt yield-per-recruit model with elements of decision-support methods. The model quantifies regional management objectives as utility functions that are weighted and summed into a single value used to evaluate alternative length limits. The flexibility of the tool stems from its capacity to consider a mixture of stock parameters and associated uncertainty to evaluate multiple length limits, weighting an array of regional fishery objectives quantified by various performance metrics. This adjustability affords flexibility to consider a diversity of options that can stimulate innovation in setting regional length limits. We demonstrate the model by evaluating varying length limits on fishery objectives related to the management of hypothetical yellow perch ( Perca flavescens ) populations and real black crappie ( Pomoxis nigromaculatus ) populations.

Canadian Journal Fisheries and Aquatic Sciences↗

USGS2024

Fish conservation in streams of the agrarian Mississippi Alluvial Valley: Conceptual model, management actions, and field verification

The effects of agriculture and flood control practices accrued over more than a century have impaired aquatic habitats and their fish communities in the Mississippi Alluvial Valley, the historic floodplain of the Lower Mississippi River prior to leveeing. As a first step to conservation planning and adaptive management, we developed and tested a conceptual model of how changes to this floodplain have affected stream environments and fish assemblages. The model is deliberately simple in structure because it needs to be understood by stakeholders ranging from engineers to farmers who must remain engaged to ensure effective conservation. Testing involved multivariate correlative analyses that included descriptors of land setting, water quality, and fish assemblages representing 376 stream samples taken over two decades and ranging in Strahler stream order from 1 to 8. The conceptual model was adequately corroborated by empirical data, but with unexplained variability that is not uncommon in field surveys where gear biases, temporal biases, and scale biases prevent accurate characterizations. Our conceptual model distinguishes three types of conservation actions relevant to large agricultural floodplains: reforestation of large parcels and riparian zone conservation, in-channel interventions and connectivity preservation, and flow augmentation. Complete restoration of the floodplain may not be an acceptable option to the agriculture community. However, in most cases the application of even the most basic measures can support the return of sensitive aquatic species. We suggest that together these types of conservation actions can bring improved water properties to impacted reaches, higher reach biodiversity, more intolerant species, and more rheophilic fishes.

Mississippi Alluvial Valle↗

USGS2002

Development and evaluation of a local grid refinement method for block-centered finite-difference groundwater models using shared nodes

A new method of local grid refinement for two-dimensional block-centered finite-difference meshes is presented in the context of steady-state groundwater-flow modeling. The method uses an iteration-based feedback with shared nodes to couple two separate grids. The new method is evaluated by comparison with results using a uniform fine mesh, a variably spaced mesh, and a traditional method of local grid refinement without a feedback. Results indicate: (1) The new method exhibits quadratic convergence for homogeneous systems and convergence equivalent to uniform-grid refinement for heterogeneous systems. (2) Coupling the coarse grid with the refined grid in a numerically rigorous way allowed for improvement in the coarse-grid results. (3) For heterogeneous systems, commonly used linear interpolation of heads from the large model onto the boundary of the refined model produced heads that are inconsistent with the physics of the flow field. (4) The traditional method works well in situations where the better resolution of the locally refined grid has little influence on the overall flow-system dynamics, but if this is not true, lack of a feedback mechanism produced errors in head up to 3.6% and errors in cell-to-cell flows up to 25%. ?? 2002 Elsevier Science Ltd. All rights reserved.

Advances in Water Resources↗

USGS2016

Ordinary kriging as a tool to estimate historical daily streamflow records

Efficient and responsible management of water resources relies on accurate streamflow records. However, many watersheds are ungaged, limiting the ability to assess and understand local hydrology. Several tools have been developed to alleviate this data scarcity, but few provide continuous daily streamflow records at individual streamgages within an entire region. Building on the history of hydrologic mapping, ordinary kriging was extended to predict daily streamflow time series on a regional basis. Pooling parameters to estimate a single, time-invariant characterization of spatial semivariance structure is shown to produce accurate reproduction of streamflow. This approach is contrasted with a time-varying series of variograms, representing the temporal evolution and behavior of the spatial semivariance structure. Furthermore, the ordinary kriging approach is shown to produce more accurate time series than more common, single-index hydrologic transfers. A comparison between topological kriging and ordinary kriging is less definitive, showing the ordinary kriging approach to be significantly inferior in terms of Nash–Sutcliffe model efficiencies while maintaining significantly superior performance measured by root mean squared errors. Given the similarity of performance and the computational efficiency of ordinary kriging, it is concluded that ordinary kriging is useful for first-order approximation of daily streamflow time series in ungaged watersheds.

Hydrology and Earth System Sciences↗

USGS2003

An experimental investigation of barite formation in seawater

We report results from time-series decay and sequential leaching experiments of laboratory cultured and coastal plankton to elucidate the mechanisms controlling barite formation in seawater. Batch-cultured diatoms ( Stephanopyxis palmerina ) and coccolithophorids (Emiliania huxleyi) were let to decay in the dark for 8-10 weeks, suspended in aerated seawater. The development of barite crystals was monitored by Scanning Electron Microscopy (SEM). A similar experiment was conducted with plankton collected during the spring-bloom in Vineyard Sound (MA). In addition to SEM, suspended particles were sequentially leached for Ba (distilled water rinse; 10% (v/v) HNO3 rinse at room temperature; 30% (v/v) HCl at 80??C overnight; 50% (v/v) HNO3 at 80??C overnight) immediately after collection, and after 10-week decay in seawater, in seawater poisoned with HgCl2, and in seawater spiked with 135Ba. Both experiments showed an increase in the number of barite crystals during decay. The spring-bloom plankton had initially a large pool of labile Ba, soluble in distilled water and cold dilute HNO3 that was lost from the plankton after 10-week decay in both axenic and nonaxenic conditions. In contrast, Ba in the decayed plankton samples was predominantly in forms extracted by hot HCl and hot HNO3 acids, which were attributed to presence of barite Ba and refractory organic Ba respectively. The increase in barite crystal counts under a Scanning Electron Microscope (SEM), the increase in HCl extractable Ba relative to organic carbon, and the loss of a large fraction of Ba during plankton decay suggest that living plankton consists of a relatively large pool of labile Ba, which is rapidly released during plankton decomposition and acts as the main source of Ba for barite formation in supersaturated microenvironments. Since mass balance indicates that only a small proportion (2 to 4%) of the labile-Ba pool is converted to barite, the availability of microenvironments that could locally concentrate Ba released by plankton decay seems to be the main limiting factor in barite precipitation. ?? 2003 Elsevier Science Ltd.

Geochimica et Cosmochimica Acta↗

USGS2011

Porphyry copper assessment of British Columbia and Yukon Territory, Canada: Chapter C in Global mineral resource assessment

The U.S. Geological Survey does regional, national, and global assessments of resources (mineral, energy, water, biologic) to provide science in support of land management and decision making. Mineral resource assessments provide a synthesis of available information about where mineral deposits are known and suspected to be in the Earth’s crust, which commodities may be present, and estimates of amounts of resources that may be present in undiscovered deposits. Canada is an important source of copper, consistently ranking as one of the top 10 world producers during the past decade (2000–2010). The preponderance of this production has been from porphyry-copper-type deposits in the western Canadian Cordillera. A probabilistic mineral resource assessment of undiscovered resources associated with porphyry copper deposits in western Canada was completed as part of a global mineral resource assessment. The purpose of the assessment was to (1) compile a database of known deposits and significant prospects, (2) delineate permissive areas (tracts) for undiscovered porphyry copper deposits that may be present in the upper kilometer (minimally) of the Earth’s crust, and (3) provide probabilistic estimates of amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) that could be contained in undiscovered porphyry copper deposits in the tracts. The study was done by the U.S. Geological Survey (USGS) in collaboration with geologists from the British Columbia Geological Survey, Yukon Geological Survey, and industry consultants. The database of known deposits and significant prospects includes an inventory of mineral resources in 89 known porphyry copper (and 2 related copper-bearing polymetallic vein) ore zones, representing 50 porphyry copper deposits, and lists key characteristics of 280 additional porphyry copper and related copper-bearing prospects, as indicated by currently available exploration results, which also are summarized. Resource and exploration and development activity are updated with information current through April 2010. The delineation of permissive tracts and probabilistic estimation of resources in undiscovered deposits were done using the USGS three-part mineral resource assessment approach. Permissive tracts are defined in accordance with descriptive models for porphyry copper deposits to include igneous rocks and known deposits and prospects within magmatic arcs related to convergent plate-margin boundary zones. Frequency distributions of total tonnages and average grades of thoroughly explored deposits were used as models for undiscovered deposits and include a new grade and tonnage model for calc-alkaline porphyry Cu±Mo±Au deposits in western Canada. Five permissive tracts for the occurrence of porphyry copper deposits were delineated: 2 island-arc tracts, 1 tract of transitional, mixed island-arc and continental arc affinities, and 2 continental arc tracts. In permissive tract 003pCu2001, calc-alkaline igneous rocks of Middle Triassic to Late Jurassic age in accreted island-arc terranes of the Intermontane belt are assessed for calc-alkaline porphyry Cu±Mo±Au deposits. The area of this tract is 175,250 km 2 . In 12 known deposits, the total reported tonnage of ore is 8,100 million metric tons (Mt) containing 24.6 Mt copper. An estimated 6.9 undiscovered deposits contain a calculated mean of 8.9 Mt copper and a median of 6.9 Mt copper. The spatial density for the 18.9 known plus estimated undiscovered deposits in this tract is approximately 11 deposits per 100,000 km 2 . In permissive tract 003pCu2002, alkaline igneous rocks of Middle Triassic to Late Jurassic age within the Intermontane accreted island-arc terranes are assessed for alkaline porphyry Cu-Au deposits. The area of this tract is 109,290 km 2 . In 12 known deposits the total reported tonnage of ore is 6,440 Mt, containing 20.9 Mt copper. An estimated 7 undiscovered deposits contain a calculated mean of 22 Mt copper and a median of 13 Mt copper. The spatial density for the 19 known plus estimated undiscovered deposits in this tract is approximately 17 deposits per 100,000 km 2 . In permissive tract 003pCu2003, calc-alkaline igneous rocks of Late Triassic to Early Cretaceous age within the accreted Insular terranes of mixed island-arc and continental arc affinities are assessed for calc-alkaline porphyry Cu±Mo±Au deposits. The area of this tract is 58,360 km 2 . The total tonnage of ore reported in the 2 known deposits is 1,160 Mt containing 3.17 Mt copper. An estimated 2.3 undiscovered deposits contain a calculated mean of 3 Mt copper and a median of 1.9 Mt copper. The spatial density for the 4.3 known plus estimated undiscovered deposits in this tract is approximately 7 deposits per 100,000 km 2 . In permissive tract 003pCu2004, calc-alkaline igneous rocks in continental magmatic arcs of Jurassic to Eocene age are assessed for porphyry Cu±Mo±Au deposits. The area of this tract is 639,500 km 2 . The total tonnage of ore reported for the 23 known deposits is 6,520 Mt containing 17.9 Mt copper. An estimated 9.6 undiscovered deposits contain a calculated mean of 13 Mt copper and a median of 11 Mt copper. The spatial density for the 32.6 known deposits plus the estimated undiscovered deposits in this tract is approximately 5 deposits per 100,000 km 2 . In permissive tract 003pCu2005, calc-alkaline igneous rocks in continental magmatic arcs of Oligocene to Pliocene age are assessed for porphyry Cu±Mo±Au deposits. The area of this tract is 32,840 km 2 . The total tonnage of ore reported for the 1 known deposit is 44.8 Mt containing 0.224 Mt copper. An estimated 1.4 undiscovered deposits contain a calculated mean of 1.8 Mt copper and a median of 0.72 Mt copper. The spatial density for the 2.4 known plus estimated undiscovered deposits in this permissive tract is approximately 7 deposits per 100,000 km 2 . Western Canada has been thoroughly explored for porphyry copper deposits. The total estimated copper contained in known deposits is about 66.8 Mt (based on 2010 data), as compared to a 49 Mt mean of estimated copper in undiscovered deposits and a 34 Mt median of estimated copper in undiscovered deposits. The copper contained in known porphyry copper deposits represents about 58 percent of the total of known and undiscovered porphyry copper deposits (based on mean values). About 86 percent of the increase in estimated copper resources between 1993 and 2009 resulted from the discovery of extensions to known deposits. Nevertheless, exploration for undiscovered deposits continues, especially in and around significant prospects and in parts of permissive tracts that are mostly hidden beneath younger volcanic, sedimentary, or vegetated surficial cover.

British Columbia, Yukon Territory↗

USGS2006

Arsenic in ground water: A review of current knowledge and relation to the CALFED solution area with recommendations for needed research

Ground water with arsenic concentrations greater than the U.S. Environmental Protection Agency drinking water standard exists throughout much of the CALFED solution area. These high concentrations are of con-cern from the standpoint of both existing water supply and development of conjunctive use projects. Much is known about arsenic mobility in ground water subject to different hydrologic and geochemical conditions. However, some important knowledge gaps exist that limit the ability to design water supply projects that could prevent arsenic mobilization or promote arsenic removal from ground water. A few well studied sys-tems could provide a much better understanding of methods for preventing or eliminating high arsenic problems. Within the context of the examination of a few detailed field studies, some important research needs include: 1.) Determining the significance of metal-bridging aqueous complexes involving inorgan-ic arsenic and natural organic matter, 2.) In the con-text of in situ remediation, determining whether of metal oxides. Little is known about the quantitative significance competition of inorganic arsenic with other inorganic aqueous species in natu-ral systems. Experiments should be conducted with actual aquifer materials, as the effects of aging on arsenic desorption in laboratory studies are quite sig-nificant. 3.) Devise methods to detect and quantify rates of oxidation/reduction reactions of arsenic that are carried out by microorganisms at ambient concen-trations of arsenic and under in situ conditions. The findings from detailed field studies have the potential for greatly reducing the cost of meeting the new drinking-water standard for arsenic. The research would benefit a broad constituency.

San Francisco Estuary and Watershed Science↗

USGS2016

Wastewater disposal from unconventional oil and gas development degrades stream quality at a West Virginia injection facility

The development of unconventional oil and gas (UOG) resources has rapidly increased in recent years; however, the environmental impacts and risks are poorly understood. A single well can generate millions of liters of wastewater, representing a mixture of formation brine and injected hydraulic fracturing fluids. One of the most common methods for wastewater disposal is underground injection; we are assessing potential risks of this method through an intensive, interdisciplinary study at an injection disposal facility in West Virginia. In June 2014, waters collected downstream from the site had elevated specific conductance (416 μS/cm) and Na, Cl, Ba, Br, Sr, and Li concentrations, compared to upstream, background waters (conductivity, 74 μS/cm). Elevated TDS, a marker of UOG wastewater, provided an early indication of impacts in the stream. Wastewater inputs are also evident by changes in 87Sr/86Sr in streamwater adjacent to the disposal facility. Sediments downstream from the facility were enriched in Ra and had high bioavailable Fe(III) concentrations relative to upstream sediments. Microbial communities in downstream sediments had lower diversity and shifts in composition. Although the hydrologic pathways were not able to be assessed, these data provide evidence demonstrating that activities at the disposal facility are impacting a nearby stream and altering the biogeochemistry of nearby ecosystems.

Environmental Science & Technology↗