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USGS2023

Near-field receiving-water monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in south San Francisco Bay, California—2020

Trace-metal concentrations in sediment and in the clam Limecola petalum (World Register of Marine Species, 2020; formerly reported as Macoma balthica and M. petalum ), clam reproductive activity, and benthic macroinvertebrate community structure were investigated in a mudflat 1 kilometer (km) south of the discharge of the Palo Alto Regional Water Quality Control Plant (PARWQCP) in south San Francisco Bay, California. This report includes the data collected by the U.S. Geological Survey (USGS) for January 2020–December 2020 (Cain and others, 2022). These data append to long-term datasets extending back to 1974. A major focus of the report is an integrated description of the 2020 data within the context of the longer, multidecadal dataset. This dataset supports the City of Palo Alto’s Near-Field Receiving- Water Monitoring Program, initiated in 1994. Silver and copper contamination substantially decreased at the site in the 1980s following the implementation by PARWQCP of advanced wastewater-treatment and source-control measures. Since the 1990s, concentrations of these elements in surface sediments have continued to decrease, although more slowly. For example, from 1994 to 2020, the minimum annual mean silver concentration—0.20 milligram per kilogram (mg/kg)—was observed in multiple years. In 2020, silver concentrations ranged from 0.18 to 0.28 mg/kg. These concentrations are 2 to 3 times higher than the regional background concentration. Presently (2020), sediment-copper concentrations appear to be near the regional background level. Over the same period (1994–2020), sedimentary iron and zinc exhibited modest decreases. Sedimentary aluminum, chromium, mercury, nickel, and selenium have not exhibited any trend. Since 1994, silver and copper concentrations in L. petalum have varied seasonally, apparently in response to a combination of site-specific metal exposures and cyclic growth and reproduction, as reported previously. Seasonal patterns for other elements, including chromium, mercury, nickel, selenium, and zinc, generally were similar in timing and magnitude as those for silver and copper. Downward trends in the silver and zinc concentrations in L. petalum during 1994–2020 were evident and appeared to be related to the general physiological condition of the clam, indicated by a condition index. Biological effects of elevated silver and copper contamination at the Palo Alto site have been interpreted from data collected during and after the recession of these contaminants. Concentrations of both elements in the soft tissues of L. petalum decreased with sedimentary copper and silver. This pattern was associated with changes in the reproductive activity of L. petalum , as well as the structure of the benthic invertebrate community. Reproductive activity of L. petalum increased as metal concentrations in L. petalum decreased (Hornberger and others, 2000), and presently is stable with almost all animals initiating reproduction in the fall and spawning the following spring. Analyses of the benthic community structure indicate that the infaunal invertebrate community has shifted from one dominated by several opportunistic species when silver and copper exposures were highest to one in which the species abundance is more evenly distributed, a pattern that indicates a more stable community that is subjected to fewer stressors. Importantly, this long-term change is unrelated to other metals and other measured environmental factors, including salinity and sediment composition. In addition, two of the opportunistic species ( Ampelisca abdita and Streblospio benedicti ) that brood their young and live on the surface of the sediment in tubes have shown a continual decrease in dominance coincident with the decrease in metals. Both species had short-lived rebounds in abundance in 2008, 2009, and 2010 and showed signs of increasing abundance in 2020. Heteromastus filiformis (a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying its eggs on or in the sediment) showed a concurrent increase in dominance and, in the last several years before 2008, showed a stable population. H. filiformis abundance increased slightly from 2011 to 2012 and returned to pre-2011 numbers in 2020. The reproductive mode of most species that were present in 2020 was indicative of species that were capable of movement either as pelagic larvae or as mobile adults. Although oviparous species were lower in number in this group, the authors hypothesize that these species will return slowly as more species move back into the area. The use of functional ecology was highlighted in the 2020 benthic community data, which showed that the animals that have now returned to the mudflat are those that can respond successfully to a physical, nontoxic disturbance. Today, community data show a mix of species that consume the sediment, or filter feed, those that have pelagic larvae that must survive landing on the sediment, and those that brood their young. The long-term recovery observed after the 1970s can be ascribed to the decrease in sediment pollutants.

California↗

USGS2017

Rare earth element behavior during groundwater – seawater mixing along the Kona Coast of Hawaii

Groundwater and seawater samples were collected from nearshore wells and offshore along the Kona Coast of the Big Island of Hawaii to investigate rare earth element (REE) behavior in local subterranean estuaries. Previous investigations showed that submarine groundwater discharge (SGD) is the predominant flux of terrestrial waters to the coastal ocean along the arid Kona Coast of Hawaii. Groundwater and seawater samples were filtered through 0.45 μm and 0.02 μm pore-size filters to evaluate the importance of colloidal and soluble (i.e., truly dissolved ionic species and/or low molecular weight [LMW] colloids) fractions of the REEs in the local subterranean estuaries. Mixing experiments using groundwater collected immediately down gradient from a wastewater treatment facility (WWTF) proximal to the Kaloko-Hanokohau National Historic Park, and more “pristine” groundwater from a well constructed in a lava tube at Kiholo Bay, were mixed with local seawater to study the effect of solution composition (i.e., pH, salinity) on the concentrations and fractionation behavior of the REEs as groundwater mixes with seawater in Kona Coast subterranean estuaries. The mixed waters were also filtered through 0.45 or 0.02 μm filters to ascertain the behavior of colloidal and soluble fractions of the REEs across the salinity gradient in each mixing experiment. Concentrations of the REEs were statistically identical (two-tailed Student t -test, 95% confidence) between the sequentially filtered sample aliquots, indicating that the REEs occur as dissolved ionic species and/or LMW colloids in Kona Coast groundwaters. The mixing experiments revealed that the REEs are released to solution from suspended particles or colloids when Kona Coast groundwater waters mix with local seawater. The order of release that accompanies increasing pH and salinity follows light REE (LREE) > middle REE (MREE) > heavy REE (HREE). Release of REEs in the mixing experiments is driven by decreases in the free metal ion activity in solution and the concomitant increase in the amount of each REE that occurs in solution as dicarbonato complexes [i.e., Ln(CO 3 ) 2 - ] as pH increases across the salinity gradient. Input-normalized REE patterns of Kona Coast groundwater and coastal seawater are nearly identical and relatively flat compared to North Pacific seawater, indicating that SGD is the chief source of these trace elements to the ocean along the Kona Coast. Additionally, REE concentrations of the coastal seawater are between 10 and 50 times higher than previously reported open-ocean seawater values from the North Pacific, further demonstrating the importance of SGD fluxes of REEs to these coastal waters. Taken together, these observations indicate that large-scale removal of REEs, which characterizes the behavior of REEs in the low salinity reaches of many surface estuaries, is not a feature of the subterranean estuary along the Kona Coast. A large positive gadolinium (Gd) anomaly characterizes groundwater from the vicinity of the WWTF. The positive Gd anomaly can be traced to the coastal ocean, providing further evidence of the impact of SGD on the coastal waters. Estimates of the SGD fluxes of the REEs to the coastal ocean along the Kona Coast (i.e., 1.3 – 2.6 mmol Nd day -1 ) are similar to recent estimates of SGD fluxes of REEs along Florida’s east coast and to Rhode Island Sound, all of which points to the importance of SGD as significant flux of REEs to the coastal ocean.

Hawaii↗

USGS2009

Aquifer chemistry and transport processes in the zone of contribution to a public-supply well in Woodbury, Connecticut, 2002-06

A glacial aquifer system in Woodbury, Connecticut, was studied to identify factors that affect the groundwater quality in the zone of contribution to a community public-supply well. Water samples were collected during 2002-06 from the public-supply well and from 35 monitoring wells in glacial stratified deposits, glacial till, and fractured bedrock. The glacial aquifer is vulnerable to contamination from a variety of sources due to the short groundwater residence times and the urban land use in the contributing recharge area to the public-supply well. The distribution and concentrations of pH, major and trace elements, stable isotope ratios, recharge temperatures, dissolved organic carbon (DOC), and volatile organic compounds (VOCs), and the oxidation-reduction (redox) conditions, were used to identify recharge source areas, aquifer source material, anthropogenic sources, chemical processes, and groundwater-flow paths from recharge areas to the public-supply well, PSW-1. The major chemical sources to groundwater and the tracers or conditions used to identify them and their processes throughout the aquifer system include (1) bedrock and glacial stratified deposits and till, characterized by high pH and concentrations of sulfate (SO42-), bicarbonate, uranium (U), radon-222, and arsenic (As) relative to those of other wells, reducing redox conditions, enriched delta sulfur-34 (d34S) and delta carbon-13 (d13C) values, depleted delta oxygen-18 (d18O) and delta deuterium (dD) values, calcite near saturation, low recharge temperatures, and groundwater ages of more than about 9 years; (2) natural organic matter, either in sediments or in an upgradient riparian zone, characterized by high concentrations of DOC or manganese (Mn), low concentrations of dissolved oxygen (DO) and nitrate (NO3-), enriched d34S values, and depleted d18O and dD values; (3) road salt (halite), characterized by high concentrations of sodium (Na), chloride (Cl-), and calcium (Ca), and indicative chloride/bromide (Cl:Br) mass concentration ratios; (4) septic-system leachate, characterized by high concentrations of NO3-, DOC, Na, Cl-, Ca, and boron (B), delta nitrogen-15 (d15N) and d18O values, and indicative Cl:Br ratios; (5) organic solvent spills, characterized by detections of perchloroethene (PCE), trichloroethene (TCE), and 1,1-dichloroethene (1,1-DCE); (6) gasoline station spills, characterized by detections of fuel oxygenates and occasionally benzene; and (7) surface-water leakage, characterized by enriched d18O and dD values and sometimes high DOC and Mn-reducing conditions. Evaluation of Cl- concentrations and Cl:Br ratios indicates that most samples were composed of mixtures of groundwater and some component of road salt or septic-system leachate. Leachate from septic-tank drainfields can cause locally anoxic conditions with NO3- concentrations of as much as 19 milligrams per liter (mg/L as N) and may provide up to 15 percent of the nitrogen in water from well PSW-1, based on mixing calculations with d15N of NO3-. Most of the water that contributes to PSW-1 is young (less than 7 years) and derived from the glacial stratified deposits. Typically, groundwater is oxic, but localized reducing zones that result from abundances of organic matter can affect the mobilization of trace elements and the degradation of VOCs. Groundwater from fractured bedrock beneath the valley bottom, which is old (more than 50 years), and reflects a Mn-reducing to methanic redox environment, constitutes as much as 6 percent of water samples collected from monitoring wells screened at the bottom of the glacial aquifer. Dissolved As and U concentrations generally are near the minimum reporting level (MRL) (0.2 micrograms per liter or ?g/L and 0.04 ?g/L, respectively), but water from a few wells screened in glacial deposits, likely derived from underlying organic-rich Mesozoic rocks, contain As concentrations up to 7 ?g/L. At one location, concentrations of As and U were high

Scientific Investigations Report↗

USGS2012

Status of groundwater quality in the Upper Santa Ana Watershed, November 2006--March 2007--California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) Upper Santa Ana Watershed (USAW) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in southern California in Riverside and San Bernardino Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA USAW study was designed to provide a spatially unbiased assessment of untreated groundwater quality within the primary aquifer systems in the study unit. The primary aquifer systems (hereinafter, primary aquifers) are defined as the perforation interval of wells listed in the California Department of Public Health (CDPH) database for the USAW study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The assessment is based on water-quality and ancillary data collected by the U.S. Geological Survey (USGS) from 90 wells during November 2006 through March 2007, and water-quality data from the CDPH database. The status of the current quality of the groundwater resource was assessed based on data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the USAW study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and a relative-concentration less than or equal to (≤) 1.0 indicates a concentration equal to or less than a benchmark. Organic and special-interest constituent relative-concentrations were classified as "high" (> 1.0), "moderate" (0.1 < relative-concentration ≤ 1.0), or "low" (≤ 0.1). Inorganic constituent relative-concentrations were classified as "high" (> 1.0), "moderate" (0.5 < relative-concentration ≤ 1.0), or "low" ( ≤ 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. Aquifer-scale proportions are defined as the percentage of the area of the primary aquifer system with concentrations above or below specified thresholds relative to regulatory or aesthetic benchmarks. High aquifer-scale proportion is defined as the percentage of the area of the primary aquifers with a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal, rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers with moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the USAW study unit (within 90-percent confidence intervals). Inorganic constituents with human-health benchmarks had relative-concentrations that were high in 32.9 percent of the primary aquifers, moderate in 29.3 percent, and low in 37.8 percent. The high aquifer-scale proportion of these inorganic constituents primarily reflected high aquifer-scale proportions of nitrate (high relative-concentration in 25.3 percent of the aquifer), although seven other inorganic constituents with human-health benchmarks also were detected at high relative-concentrations in some percentage of the aquifer: arsenic, boron, fluoride, gross alpha activity, molybdenum, uranium, and vanadium. Perchlorate, as a constituent of special interest, was evaluated separately from other inorganic constituents, and had high relative-concentrations in 11.1 percent, moderate in 53.3 percent, and low or not detected in 35.6 percent of the primary aquifers. In contrast to the inorganic constituents, relative-concentrations of organic constituents (one or more) were high in 6.7 percent, moderate in 11.1 percent, and low or not detected in 82.2 percent of the primary aquifers. Of the 237 organic and special-interest constituents analyzed for, 39 constituents were detected (21 VOCs, 13 pesticides, 3 pharmaceuticals, and 2 constituents of special interest). All of the detected VOCs had health-based benchmarks, and five of these—1,1-dichloroethene, 1,2-dibromo-3-chloropropane (DBCP), tetrachloroethene (PCE), carbon tetrachloride, and trichloroethene (TCE)—were detected in at least one sample at a concentration above a benchmark (high relative-concentration). Seven of the 13 pesticides had health-based benchmarks, and none were detected above these benchmarks (no high relative-concentrations). Pharmaceuticals do not have health-based benchmarks. Thirteen organic constituents were frequently detected (detected in at least 10 percent of samples without regard to relative-concentrations): bromodichloromethane, chloroform, cis-1,2-dichloroethene, 1,1-dichloroethene, dichlorodifluoromethane (CFC-12), methyl tert-butyl ether (MTBE), PCE, TCE, trichlorofluoromethane (CFC-11), atrazine, bromacil, diuron, and simazine.

California↗

USGS1995

Uraniferous waters of the Arkansas River valley, Colorado, U.S.A.: A function of geology and land use

The effect of local geology and land-use practices on dissolved U was investigated by analysis of surface water and some springs in the Arkansas River valley of southeastern Colorado. Water samples were collected during a 2 week period in April, 1991. The rate of increase of U concentration with distance downriver increased markedly as the river flowed from predominantly undeveloped lands underlain by igneous and metamorphic rocks to agriculturally developed lands underlain by marine shale and limestone. An additional abrupt increase in dissolved U was observed along the section of river where discharge is often greatly reduced because of extensive diversions for irrigation and where remaining flow is largely composed of irrigation return water. Dissolved U in this last section of river and in most of its tributaries exceeded the proposed U.S. drinking water standard of 20 μ/L In water samples collected from agricultural areas dissolved U showed strong positive correlation with major dissolved constituents Na, Ca, Mg, and SO 4 that increase as a result of sulfate mineral dissolution and clay mineral ion-exchange reactions in weathered shale bedrock and shaley soils. Highly soluble minor and trace elements Cl, Li, B, Sr, and Se that are not subject to strong sorptive uptake or precipitation in this setting also correlated positively with U. These combined observations indicate that natural leaching of U-bearing shale bedrock and derivative soils, additional leaching of rock and soil by irrigation water, and evaporative concentration in a semi-arid climate can produce concentrations of dissolved U in surface water and shallow ground water that may threaten nearby drinking water supplies. Other agriculturally developed areas of the semi-arid Western U.S. with similar geology are likely to contain high concentrations of U in irrigation drain water.

Colorado↗

USGS2011

Near-field receiving water monitoring of trace metals and a benthic community near the Palo Alto Regional Water Quality Control Plant in South San Francisco Bay, California: 2010

Trace-metal concentrations in sediment and in the clam Macoma petalum (formerly reported as Macoma balthica ), clam reproductive activity, and benthic macroinvertebrate community structure were investigated in a mudflat 1 kilometer south of the discharge of the Palo Alto Regional Water Quality Control Plant (PARWQCP) in South San Francisco Bay, Calif. This report includes the data collected for the period January 2010 to December 2010 and extends a critical long-term biogeochemical record that dates back to 1974. These data serve as the basis for the City of Palo Alto’s Near-Field Receiving Water Monitoring Program initiated in 1994. In 2010, metal concentrations in both sediments and clam tissue were among the lowest concentrations on record and consistent with results observed since 1991. Following significant reductions in the late 1980s, silver (Ag) and copper (Cu) concentrations appear to have stabilized. Annual mean concentrations have fluctuated modestly (2–4 fold) in a nondirectional manner. Data for other metals, including chromium, mercury, nickel, selenium, vanadium, and zinc, have been collected since 1994. Over this period, concentrations of these elements, which likely reflect regional inputs and systemwide processes, have remained relatively constant, aside from typical seasonal variation that is common to all elements. Within years, the winter months (January–March) generally exhibit maximum concentrations, with a decline to annual minima in spring through fall. Concentrations of chromium (Cr) and vanadium (V) in sediments have shown an upward trend since 2005. Chromium concentrations are approaching the record maximum levels observed in 2003, and concentrations of V in sediments in 2010 were the highest annual average concentrations on record. Mercury (Hg) concentrations in sediments and M. petalum in 2010 were comparable to concentrations observed in 2009 and were generally consistent with data from previous years. Selenium (Se) concentrations in sediment varied among years and showed no sustained temporal trend. During 2009–2010, sedimentary Se concentrations declined from the record high observed in 2008 to concentrations that were among the lowest on record. Selenium in M. petalum was slightly higher in 2010 than in 2009. Overall, Cu and Ag concentrations in sediments and soft tissues of the clam, M. petalum , remained representative of the concentrations observed since 1991 following significant reductions in the discharge of these elements from the PARWQCP. This indicates that, as with other elements of regulatory interest, regional-scale factors now largely affect sedimentary and bioavailable concentrations of Ag and Cu. Analyses of the benthic community structure of a mudflat in South San Francisco Bay over a 37-year period show that changes in the community have occurred concurrent with reduced concentrations of metals in the sediment and in the tissues of the biosentinel clam, M. petalum , from the same area. Analysis of the M. petalum community shows increases in reproductive activity concurrent with the decline in metal concentrations in the tissues of this organism. Reproductive activity is presently stable (2010), with almost all animals initiating reproduction in the fall and spawning the following spring of most years. The community has shifted from being dominated by several opportunistic species to a community where the species are more similar in abundance, a pattern that indicates a more stable community that is subjected to fewer stressors. In addition, two of the opportunistic species ( Ampelisca abdita and Streblospio benedicti ) that brood their young and live on the surface of the sediment in tubes have shown a continual decline in dominance coincident with the decline in metals; both species had short-lived rebounds in abundance in 2008, 2009, and 2010. Heteromastus filiformis (a subsurface polychaete worm that lives in the sediment, consumes sediment and organic particles residing in the sediment, and reproduces by laying its eggs on or in the sediment) showed a concurrent increase in dominance and, in last several years prior to 2008, showed a stable population. An unidentified disturbance occurred on the mudflat in early 2008 that resulted in the loss of the benthic animals, except for those deep-dwelling animals like Macoma petalum . Animals immediately returned to the mudflat in 2008, which was the first indication that the disturbance was not due to a persistent toxin or to anoxia. The use of functional ecology was highlighted in the 2010 benthic community data, which show that the animals that have now returned to the mudflat are those that can respond successfully to a physical, nontoxic disturbance. Today, community data show a mix of animals that consume the sediment, filter feed, have pelagic larvae that must survive landing on the sediment, and brood their young. USGS scientists continue to observe the community’s response to the defaunation event because it allows them to examine the response of the community to a natural disturbance (possible causes include sediment accretion or freshwater inundation) and compare this recovery to the long-term recovery observed in the 1970s when the decline in sediment pollutants was the dominating factor.

California↗

USGS2013

Prioritization of constituents for national- and regional-scale ambient monitoring of water and sediment in the United States

A total of 2,541 constituents were evaluated and prioritized for national- and regional-scale ambient monitoring of water and sediment in the United States. This prioritization was done by the U.S. Geological Survey (USGS) in preparation for the upcoming third decade (Cycle 3; 2013–23) of the National Water-Quality Assessment (NAWQA) Program. This report provides the methods used to prioritize the constituents and the results of that prioritization. Constituents were prioritized by the NAWQA National Target Analyte Strategy (NTAS) work group on the basis of available information on physical and chemical properties, observed or predicted environmental occurrence and fate, and observed or anticipated adverse effects on human health or aquatic life. Constituents were evaluated within constituent groups that were determined on the basis of physical or chemical properties or on uses or sources. Some constituents were evaluated within more than one constituent group. Although comparable objectives were used in the prioritization of constituents within the different constituent groups, differences in the availability of information accessed for each constituent group led to the development of separate prioritization approaches adapted to each constituent group to make best use of available resources. Constituents were assigned to one of three prioritization tiers: Tier 1, those having the highest priority for inclusion in ambient monitoring of water or sediment on a national or regional scale (including NAWQA Cycle 3 monitoring) on the basis of their likelihood of environmental occurrence in ambient water or sediment, or likelihood of effects on human health or aquatic life; Tier 2, those having intermediate priority for monitoring on the basis of their lower likelihood of environmental occurrence or lower likelihood of effects on human health or aquatic life; and Tier 3, those having low or no priority for monitoring on the basis of evidence of nonoccurrence or lack of effects on human health or aquatic life, or of having insufficient evidence of potential occurrence or effects to justify placement into Tier 2. Of the 1,081 constituents determined to be of highest priority for ambient monitoring (Tier 1), 602 were identified for water and 686 were identified for sediment (note that some constituents were evaluated for both water and sediment). These constituents included various types of organic compounds, trace elements and other inorganic constituents, and radionuclides. Some of these constituents are difficult to analyze, whereas others are mixtures, isomers, congeners, salts, and acids of other constituents; therefore, modifications to the list of high-priority constituents for ambient monitoring could be made on the basis of the availability of suitable methods for preparation, extraction, or analysis. An additional 1,460 constituents were placed into Tiers 2 or 3 for water or sediment, including some constituents that had been placed into Tier 1 for a different matrix; 436 constituents were placed into Tier 2 for water and 246 constituents into Tier 2 for sediment; 979 constituents were placed into Tier 3 for water and 779 constituents into Tier 3 for sediment.

Scientific Investigations Report↗

USGS2017

Status and understanding of groundwater quality in the Bear Valley and Lake Arrowhead Watershed Study Unit, 2010: California GAMA Priority Basin Project

Groundwater quality in the 112-square-mile Bear Valley and Lake Arrowhead Watershed (BEAR) study unit was investigated as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit comprises two study areas (Bear Valley and Lake Arrowhead Watershed) in southern California in San Bernardino County. The GAMA-PBP is conducted by the California State Water Resources Control Board (SWRCB) in cooperation with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA BEAR study was designed to provide a spatially balanced, robust assessment of the quality of untreated (raw) groundwater from the primary aquifer systems in the two study areas of the BEAR study unit. The assessment is based on water-quality collected by the USGS from 38 sites (27 grid and 11 understanding) during 2010 and on water-quality data from the SWRCB-Division of Drinking Water (DDW) database. The primary aquifer system is defined by springs and the perforation intervals of wells listed in the SWRCB-DDW water-quality database for the BEAR study unit. This study included two types of assessments: (1) a status assessment , which characterized the status of the quality of the groundwater resource as of 2010 by using data from samples analyzed for volatile organic compounds, pesticides, and naturally present inorganic constituents, such as major ions and trace elements, and (2) an understanding assessment , which evaluated the natural and human factors potentially affecting the groundwater quality. The assessments were intended to characterize the quality of groundwater resources in the primary aquifer system of the BEAR study unit, not the treated drinking water delivered to consumers. Bear Valley study area and the Lake Arrowhead Watershed study area were also compared statistically on the basis of water-quality results and factors potentially affecting the groundwater quality. Relative concentrations (RCs), which are sample concentration of a particular constituent divided by its associated health- or aesthetic-based benchmark concentrations, were used for evaluating the groundwater quality for those constituents that have Federal or California regulatory or non-regulatory benchmarks for drinking-water quality. An RC greater than 1.0 indicates a concentration greater than a benchmark. Organic (volatile organic compounds and pesticides) and special-interest (perchlorate) constituent RCs were classified as “high” (RC greater than 1.0), “moderate” (RC less than or equal to 1.0 and greater than 0.1), or “low” (RC less than or equal to 0.1). For inorganic (radioactive, trace element, major ion, and nutrient) constituents, the boundary between low and moderate RCs was set at 0.5. Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating groundwater quality at the study-unit scale or for its component areas. High aquifer-scale proportion was defined as the percentage of the area of the primary aquifer system with a RC greater than 1.0 for a particular constituent or class of constituents; the percentage is based on area rather than volume. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifer system with moderate and low RCs, respectively. A spatially weighted statistical approach was used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. The status assessment for the Bear Valley study area found that inorganic constituents with health-based benchmarks were detected at high RCs in 9.0 percent of the primary aquifer system and at moderate RCs in 13 percent. The high RCs of inorganic constituents primarily reflected high aquifer-scale proportions of fluoride (in 5.4 percent of the primary aquifer system) and arsenic (3.6 percent). The RCs of organic constituents with health-based benchmarks were high in 1.0 percent of the primary aquifer system, moderate in 8.1 percent, and low in 70 percent. Organic constituents were detected in 79 percent of the primary aquifer system. Two groups of organic constituents and two individual organic constituents were detected at frequencies greater than 10 percent of samples from the USGS grid sites: trihalomethanes (THMs), solvents, methyl tert -butyl ether (MTBE), and simazine. The special-interest constituent perchlorate was detected in 93 percent of the primary aquifer system; it was detected at moderate RCs in 7.1 percent and at low RCs in 86 percent. The status assessment in the Lake Arrowhead Watershed study area showed that inorganic constituents with human-health benchmarks were detected at high RCs in 25 percent of the primary aquifer system and at moderate RCs in 41 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of radon‑222 (in 62 percent of the primary aquifer system) and uranium (26 percent). RCs of organic constituents with health-based benchmarks were moderate in 7.7 percent of the primary aquifer system and low in 46 percent. Organic constituents were detected in 54 percent of the primary aquifer system. The only organic constituents that were detected at frequencies greater than 10 percent of samples from the USGS grid sites were THMs. Perchlorate was detected in 62 percent of the primary aquifer system at uniformly low RCs. The second component of this study, the understanding assessment , identified the natural and human factors that could have affected the groundwater quality in the BEAR study unit by evaluating statistical correlations between water-quality constituents and potential explanatory factors. The potential explanatory factors evaluated were land use (including density of septic tanks and leaking or formerly leaking underground fuel tanks), site type, aquifer lithology, well construction (well depth and depth to the top-of-perforated interval), elevation, aridity index, groundwater-age distribution, and oxidation-reduction condition (including pH and dissolved oxygen concentration). Results of the statistical evaluations were used to explain the distribution of constituents in groundwater of the BEAR study unit. In the Bear Valley study area, high and moderate RCs of fluoride were found in sites known to be influenced by hydrothermic conditions or that had high concentrations of fluoride historically. The high RC of arsenic can likely be attributed to desorption of arsenic from aquifer sediments saturated in old groundwater with high pH under reducing conditions. The THMs were detected more frequently at USGS grid sites that were wells, part of a large urban water system, and surrounded by urban land use. Solvents, MTBE, and simazine were all detected more frequently at USGS grid sites that were wells with a greater urban percentage of surrounding land use and that accessed older groundwater than other USGS grid sites. Comparison between the observed and predicted detection frequencies of perchlorate at USGS grid sites indicated that anthropogenic sources could have contributed to low levels of perchlorate in the groundwater of the Bear Valley study area. In the Lake Arrowhead Watershed study area, high and moderate RCs of radon-222 and uranium can be attributed to older groundwater from the granitic fractured-rock primary aquifer system. Low RCs of THMs were detected at USGS grid sites that were wells and part of small water systems. The similarities between the observed and predicted detection frequencies of perchlorate in samples from USGS grid sites indicated that the source and distribution of perchlorate were most likely attributable to precipitation (rain and snow), with minimal, if any, contribution from anthropogenic sources.

California↗

USGS1996

Streambed-material characteristics and surface-water quality, Green Pond Brook and tributaries, Picatinny Arsenal, New Jersey, 1983-90

This report presents the results of a study conducted at Picatinny Arsenal, Morris County, New Jersey, to (1) determine whether streambed sediments in Green Pond Brook and its tributaries are contaminated with inorganic or organic constituents, (2) determine the extent of contamination in those reaches, and (3) characterize the quality of water in the brook. Shallow auger samples and results of an electromagnetic-conductivity and natural-gamma-ray survey were used to describe the distribution of streambed and substreambed sediment types and particle sizes. Forty-five streambed samples were analyzed for trace elements, base/neutral- and acid-extractable compounds, organochlorine and organophosphorus insecticides, polychlorinated biphenyls, and polychlorinated naphthalenes to determine whether contaminants have migrated to the brook from the surrounding area. Historical results of analyses of 63 surface-water and 27 streambed samples also are presented. Samples of streambed material collected from three areas in Green Pond Brook and its tributaries Green Pond Brook, from the area near the outflow of Picatinny Lake downstream to Parley Avenue; Bear Swamp Brook, from the area near building 241 downstream to the confluence with Green Pond Brook; and Green Pond Brook, from the open burning area downstream to the dam near building 1178 contained organic and (or) inorganic constituents in concentrations greater than those found under natural conditions and greater than those found in other areas sampled at the arsenal. Contaminants identified include trace elements, polynuclear aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine insecticides. Surface-water samples from Green Pond Brook contained several volatile organic compounds, including trichloroethylene, tetrachloroethylene, and 1,2-dichloroethylene, at maximum concentrations of 3.8,4.6, and 11 micrograms per liter, respectively. Volatilization and dilution by surface- water and ground-water inflow reduce concentrations of volatile organic compounds from surface water in the steep, fast-flowing reaches of the brook at the southern end of the arsenal. No organic or inorganic constituents were detected in surface-water samples in concentrations greater than the U.S. Environmental Protection Agency primary drinking-water regulations. Only two constituents, iron and manganese, were detected in concentrations greater than the U.S. Environmental Protection Agency secondary drinking-water regulations.

New Jersey↗

USGS2013

Geochemical and isotopic variations in shallow groundwater in areas of the Fayetteville Shale development, north-central Arkansas

Exploration of unconventional natural gas reservoirs such as impermeable shale basins through the use of horizontal drilling and hydraulic fracturing has changed the energy landscape in the USA providing a vast new energy source. The accelerated production of natural gas has triggered a debate concerning the safety and possible environmental impacts of these operations. This study investigates one of the critical aspects of the environmental effects; the possible degradation of water quality in shallow aquifers overlying producing shale formations. The geochemistry of domestic groundwater wells was investigated in aquifers overlying the Fayetteville Shale in north-central Arkansas, where approximately 4000 wells have been drilled since 2004 to extract unconventional natural gas. Monitoring was performed on 127 drinking water wells and the geochemistry of major ions, trace metals, CH 4 gas content and its C isotopes (δ 13 C CH4 ), and select isotope tracers (δ 11 B, 87 Sr/ 86 Sr, δ 2 H, δ 18 O, δ 13 C DIC ) compared to the composition of flowback-water samples directly from Fayetteville Shale gas wells. Dissolved CH 4 was detected in 63% of the drinking-water wells (32 of 51 samples), but only six wells exceeded concentrations of 0.5 mg CH 4 /L. The δ 13 C CH4 of dissolved CH 4 ranged from −42.3&permil; to −74.7&permil;, with the most negative values characteristic of a biogenic source also associated with the highest observed CH 4 concentrations, with a possible minor contribution of trace amounts of thermogenic CH 4 . The majority of these values are distinct from the reported thermogenic composition of the Fayetteville Shale gas (δ 13 C CH4 = −35.4&permil; to −41.9&permil;). Based on major element chemistry, four shallow groundwater types were identified: (1) low (<100 mg/L) total dissolved solids (TDS), (2) TDS > 100 mg/L and Ca–HCO 3 dominated, (3) TDS > 100 mg/L and Na–HCO 3 dominated, and (4) slightly saline groundwater with TDS > 100 mg/L and Cl > 20 mg/L with elevated Br/Cl ratios (>0.001). The Sr ( 87 Sr/ 86 Sr = 0.7097–0.7166), C (δ 13 C DIC = −21.3&permil; to −4.7&permil;), and B (δ 11 B = 3.9–32.9&permil;) isotopes clearly reflect water–rock interactions within the aquifer rocks, while the stable O and H isotopic composition mimics the local meteoric water composition. Overall, there was a geochemical gradient from low-mineralized recharge water to more evolved Ca–HCO 3 , and higher-mineralized Na–HCO 3 composition generated by a combination of carbonate dissolution, silicate weathering, and reverse base-exchange reactions. The chemical and isotopic compositions of the bulk shallow groundwater samples were distinct from the Na–Cl type Fayetteville flowback/produced waters (TDS &sim;10,000–20,000 mg/L). Yet, the high Br/Cl variations in a small subset of saline shallow groundwater suggest that they were derived from dilution of saline water similar to the brine in the Fayetteville Shale. Nonetheless, no spatial relationship was found between CH 4 and salinity occurrences in shallow drinking water wells with proximity to shale-gas drilling sites. The integration of multiple geochemical and isotopic proxies shows no direct evidence of contamination in shallow drinking-water aquifers associated with natural gas extraction from the Fayetteville Shale.

Applied Geochemistry↗

USGS1987

Chemical characteristics of water in the surficial aquifer system, Broward County, Florida

Water quality data was collected in 1981 and 1982 during the drilling of test holes at 27 sites throughout Broward County, Florida. Determinations were made for the following physical properties and chemical constituents: pH, alkalinity, specific conductance, major ions, selected nutrients and dissolved iron, aluminum, and manganese. Determinations for the trace elements-arsenic, barium, cadmium, chromium, lead, zinc, selenium, and mercury-were made at 14 wells. Water in the surficial aquifer system between the coastal ridge and the conservation areas is potable and usually is a calcium bicarbonate type for the first 140 ft or more below land surface. Between depths of 140 and 230 ft, groundwater generally grades into a mixed-ion water type. In some areas, diluted seawater occurs beneath the mixed water zone. Dissolved iron concentrations between the coastal ridge and the conservation areas are variable but generally exceed 1,000 micrograms/L. Beneath the conservation areas and the western edge of Broward County, groundwater in the first 100 ft below land surface generally is either a calcium bicarbonate type or a mixed-ion type. At depths between 100 and 200 ft, diluted residual seawater occurs, except along the far western edge of the county. Residual seawater is least diluted in the north. Dissolved iron concentrations generally are between 300 and 1 ,000 micrograms/L but increase to the east of the conservation areas. Other findings of the investigation include: (1) groundwater in some areas west of the coastal ridge probably would be suitable for most domestic, agricultural, and industrial uses if it were treated for carbonate hardness; (2) groundwater in much of Broward County is chemically altered by natural softening and magnesium enrichment (natural softening increases to the west and is very pronounced beneath the far western edge of the county); and (3) there is evidence of mineralized water from the conservation areas mixing with groundwater east of the levees. (Lantz-PTT)

Water-Resources Investigations Report↗

USGS2019

Hydrologic balance, water quality, chemical-mass balance, and geochemical modeling of hyperalkaline ponds at Big Marsh, Chicago, Illinois, 2016–17

Hyperalkaline (pH greater than 12) ponds and groundwater exist at Big Marsh near Lake Calumet, Chicago, Illinois, a site used by the steel industry during the mid-1900s to deposit steel- and iron-making waste, in particular, slag. The hyperalkaline ponds may pose a hazard to human health and the environment. The U.S. Geological Survey (USGS), in cooperation with the Environmental Protection Agency (EPA) and in collaboration with the City of Chicago’s Park District, completed a study to evaluate the hydrologic balance, water quality, and chemical-mass balance of hyperalkaline ponds at Big Marsh and geochemical modeling used to evaluate remediation options for water quality at the site based on data collected in 2016–17. Synoptic measurements of surface-water and groundwater elevations were used to determine flow directions and to enable a preliminary estimate of the hydrologic balance for the ponds. Water-quality samples also were collected and analyzed for selected constituents including major anions and cations, nutrients, metals, and trace elements. The results of the water-quality analyses were used to develop a geochemical model to evaluate concentrations, factors affecting pH, and the state of equilibrium between surface waters and atmospheric carbon dioxide. The geochemical model was used to evaluate remediation scenarios using riprap, spillways, or active aeration. The results indicate that active aeration will decrease the pH to near 7.5 in about 8 hours, the fastest rate of the scenarios. Passive aeration, such as riprap or spillways, also can be effective at decreasing the pH in about 45 hours, but spatial obstacles limit their implementation. Seasonal variations in temperature also affect the rate of equilibration, where colder temperatures may have a lower pH than warmer temperatures and may affect the timing and frequency of remediation.

Illinois↗

USGS2011

Status and understanding of groundwater quality in the Monterey Bay and Salinas Valley Basins, 2005-California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000 square mile (2,590 km2) Monterey Bay and Salinas Valley Basins (MS) study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in central California in Monterey, Santa Cruz, and San Luis Obispo Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA MS study was designed to provide a spatially unbiased assessment of the quality of untreated (raw) groundwater in the primary aquifer systems (hereinafter referred to as primary aquifers). The assessment is based on water-quality and ancillary data collected in 2005 by the USGS from 97 wells and on water-quality data from the California Department of Public Health (CDPH) database. The primary aquifers were defined by the depth intervals of the wells listed in the CDPH database for the MS study unit. The quality of groundwater in the primary aquifers may be different from that in the shallower or deeper water-bearing zones; shallow groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources in the primary aquifers of the MS study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California regulatory or non-regulatory benchmarks for drinking-water quality. A relative-concentration greater than (>) 1.0 indicates a concentration greater than a benchmark, and less than or equal to (≤) 1.0 indicates a concentration less than or equal to a benchmark. Relative-concentrations of organic and special interest constituents [perchlorate, N-nitrosodimethylamine (NDMA), and 1,2,3-trichloropropane (1,2,3-TCP)], were classified as "high" (relative-concentration > 1.0), "moderate" (0.1 < relative-concentration ≤ 1.0), or "low" (relative-concentration ≤ 0.1). Relative-concentrations of inorganic constituents were classified as "high" (relative-concentration > 1.0), "moderate" (0.5 < relative-concentration ≤ 1.0), or "low" (relative-concentration ≤ 0.5). Aquifer-scale proportion was used as the primary metric in the status assessment for evaluating regional-scale groundwater quality. High aquifer-scale proportion was defined as the percentage of the area of the primary aquifers with a relative-concentration greater than 1.0 for a particular constituent or class of constituents; percentage is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers with moderate and low relative-concentrations, respectively. Two statistical approaches-grid-based and spatially weighted-were used to evaluate aquifer-scale proportions for individual constituents and classes of constituents. Grid-based and spatially-weighted estimates were comparable in the MS study unit (within 90-percent confidence intervals). Inorganic constituents with human-health benchmarks were detected at high relative-concentrations in 14.5 percent of the primary aquifers, moderate in 35.5 percent, and low in 50.0 percent. High aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of nitrate (7.9 percent), molybdenum (2.9 percent), arsenic (2.8 percent), boron (1.9 percent), and gross alpha-beta radioactivity (1.5 percent). Relative-concentrations of organic constituents (one or more) were high in 0.2 percent, moderate in 6.6 percent, and low in 93.2 percent (not detected in 48.1 percent) of the primary aquifers. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of tetrachloroethene (0.1 percent) and methyl tert-butyl ether (0.1 percent). Relative-concentration for inorganic constituents with secondary maximum contaminant levels, manganese, total dissolved solids, iron, sulfate, and chloride were high in 18.6, 8.6, 7.1, 2.9, and 1.4 percent of the primary aquifers, respectively. Of the 205 organic and special-interest constituents analyzed, 32 constituents were detected. One organic constituent, the herbicide simazine, was frequently detected (in 10 percent or more of samples), but was detected at low relative-concentrations. The second component of this study, the understanding assessment, identified the natural and human factors that affect groundwater quality by evaluating land use, physical characteristics of the wells, and geochemical conditions of the aquifer. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit. The understanding assessment indicated that most wells that contained nitrate were classified as being in agricultural land-use areas, and depths to the top of perforations in most of the wells were less than 350 ft (76 m). High and moderate relative-concentrations of arsenic may be attributed to reductive dissolution of manganese or iron oxides, or to desorption or inhibition of arsenic sorption under alkaline conditions. Arsenic concentrations increased with increasing groundwater depth and residence time (age). Simazine was detected more often in groundwater from wells with surrounding land use classified as agricultural or urban, and with top of perforation depths less than 200 ft (61 m), than in groundwater from wells with natural land use or with deeper depths. Tritium, helium-isotope, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer since 1953), pre-modern (water that entered the aquifer prior to 1953 to tens of thousands of years ago), and mixed (mixtures of modern- and pre-modern-age waters). Arsenic concentrations were significantly greater in groundwater with pre-modern age classification than in groundwater with modern-age classification, suggesting that arsenic accumulates with groundwater residence time.

Scientific Investigations Report↗

USGS2018

Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

Groundwater quality in the approximately 7,820-square-kilometer (km 2 ) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km 2 ), Pajaro Valley (360 km 2 ), Salinas Valley (2,000 km 2 ), and Highlands (5,250 km 2 ). This study had two primary components: the status assessment and the understanding assessment . The first primary component of this study—the status assessment —assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment —identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system. Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low. Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids. Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA ( N -nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit. Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions. Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems. Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater. The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater. The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater. Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater. The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however. Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture. Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

California↗

USGS2010

Status and understanding of groundwater quality in the North San Francisco Bay groundwater basins, 2004: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,000-square-mile (2,590-square-kilometer) North San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in northern California in Marin, Napa, and Sonoma Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA North San Francisco Bay study was designed to provide a spatially unbiased assessment of untreated groundwater quality in the primary aquifer systems. The assessment is based on water-quality and ancillary data collected by the USGS from 89 wells in 2004 and water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer systems (hereinafter referred to as primary aquifers) were defined by the depth interval of the wells listed in the CDPH database for the North San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifers; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOC), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifers of the North San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the health- or aesthetic-based benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. Relative-concentrations of organic and special interest constituents were classified as “high” (relative-concentration > 1.0), “moderate” (0.1 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.1). Inorganic constituent relative-concentrations were classified as “high” (relative-concentration > 1.0), “moderate” (0.5 < relative-concentration ≤ 1.0), or “low” (relative-concentration ≤ 0.5). Aquifer-scale proportion was used as a metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the primary aquifers that have a relative-concentration greater than 1.0; proportion is calculated on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentage of the primary aquifers that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially-weighted—were used to evaluate aquifer-scale proportion for individual constituents and classes of constituents. Grid-based and spatially-weighted estimates were comparable in the North San Francisco Bay study unit (90-percent confidence intervals). For inorganic constituents with human-health benchmarks, relative-concentrations were high in 14.0 percent of the primary aquifers, moderate in 35.8 percent, and low in 50.2 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of arsenic (10.0 percent), boron (4.1 percent), and lead (1.6 percent). In contrast, relative-concentrations of organic constituents (one or more) were high in 1.4 percent, moderate in 4.9 percent, and low in 93.7 percent (not detected in 64.8 percent) of the primary aquifers. The high aquifer-scale proportion of organic constituents primarily reflected high aquifer-scale proportions of PCE (1.3 percent), TCE (0.1 percent), and 1,1-dichloroethene (0.1 percent). The inorganic constituents with secondary maximum contaminant levels (SMCL), manganese and iron, had relative-concentrations that were high in 40.8 percent and 24.4 percent of the primary aquifers, respectively. Of the 255 organic and special-interest constituents analyzed for, 26 constituents were detected. Two organic constituents were frequently detected (in 10 percent or more of samples), the trihalomethane chloroform and the herbicide simazine, but both were detected at low relative-concentrations. The second component of this study, the understanding assessment, identified the natural and human factors that affect groundwater quality by evaluating land use, physical characteristics of the wells, geochemical conditions of the aquifer, and water temperature. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit. The understanding assessment indicated that a majority of the wells that contained nitrate also had an urban or agricultural land-use classification, had a modern or mixed age classification, and had depths to their top perforations <100 ft (30 m). Geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the terminal and deeper parts of the flow system. High and moderate relative-concentrations of arsenic may be attributed to reductive dissolution of manganese or iron oxides, or to desorption or inhibition of arsenic sorption under alkaline conditions. Arsenic concentrations increased with increasing depth and groundwater age in the North San Francisco Bay study unit. High to moderate relative-concentrations of boron were primarily associated with hydrothermal activity or high-salinity waters in the Napa Sonoma lowlands. Simazine was detected in groundwater classified as modern and mixed age more often than in groundwater classified as pre-modern age, while chloroform was detected most often in groundwater classified as mixed age. Simazine and chloroform also were observed in wells that had surrounding land use classified as agricultural or land use classified as urban, and top of perforation depths less than 100 ft (30 m). Together, the occurrence of chloroform and simazine in shallow wells with modern or mixed groundwater located in urban or agricultural areas suggests that these constituents result from anthropogenic activities during the last 50 years. Tritium, helium-isotope, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years to tens of thousands of years ago), and mixed (mixtures of modern- and pre-modern-age waters). Arsenic, iron, and total dissolved solids (TDS) concentrations were significantly greater in groundwater having pre-modern-age classification than modern, suggesting that these constituents accumulate with groundwater residence time.

California↗

USGS2010

Status and understanding of groundwater quality in the central-eastside San Joaquin Basin, 2006: California GAMA Priority Basin Project

Groundwater quality in the approximately 1,695-square-mile Central Eastside San Joaquin Basin (Central Eastside) study unit was investigated as part of the Priority Basin Project (PBP) of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA PBP was developed in response to the California Groundwater Quality Monitoring Act of 2001, and is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The GAMA Central Eastside study unit was designed to provide a spatially unbiased assessment of untreated-groundwater quality, as well as a statistically consistent basis for comparing water quality throughout California. During March through June 2006, samples were collected from 78 wells in Stanislaus and Merced Counties, 58 of which were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells), and 20 of which were sampled to evaluate changes in water chemistry along groundwater-flow paths (understanding wells). Water-quality data from the California Department of Public Health (CDPH) database also were used for the assessment. An assessment of the current status of the groundwater quality included collecting samples from wells for analysis of anthropogenic constituents such as volatile organic compounds (VOCs) and pesticides, as well as naturally occurring constituents such as major ions and trace elements. The assessment of status is intended to characterize the quality of untreated-groundwater resources within the primary aquifer system, not the treated drinking water delivered to consumers by water purveyors. The primary aquifer system (hereinafter, primary aquifer) is defined as that part of the aquifer corresponding to the perforation interval of wells listed in the CDPH database for the Central Eastside study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifer; shallower groundwater may be more vulnerable to surficial contamination. The primary aquifer is represented by the grid wells, of which 90 percent had depths to the tops of their perforations of about 80 to 330 feet and depths to bottom of about 100 to 670 feet. Relative-concentrations (sample concentration divided by benchmark concentration) were used as the primary metric for assessing the status of water quality for those constituents that have Federal and (or) California human health or aesthetic benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration above a benchmark, and less than or equal to (≤) 1.0 indicates a concentration equal to or below a benchmark. For organic and special interest constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.1), or low (≤0.1). For inorganic constituents, relative-concentrations were classified as high (>1.0), moderate (≤1.0 and >0.5), or low (≤0.5). The threshold between low and moderate classifications was lower for organic and special interest constituents than for inorganic constituents because organic constituents generally are less prevalent and have smaller relative-concentrations than inorganic constituents. Grid-based and spatially-weighted approaches, the latter incorporating data from all CDPH wells, were used to evaluate the proportion of the primary aquifer (aquifer-scale proportions) with high, moderate, or low relative-concentrations. For individual constituents or classes of constituents, the aquifer-scale high proportion is the percentage of the area of the study unit having high relative-concentrations within the depth-zones of the primary aquifer. Aquifer-scale moderate and low proportions are defined similarly. Spatially-weighted aquifer-scale high proportions nearly always fell within the 90-percent confidence interval of grid-based aquifer-scale high proportions, indicating that the grid-based approach yielded statistically equivalent results to the spatially-weighted approach incorporating CDPH data. The status assessment for inorganic constituents showed that inorganic constituents (one or more) were high, relative to human-health benchmarks, in 18.0 percent of the primary aquifer, moderate in 44.0 percent, and low in 38.0 percent. Of inorganic constituents with human-health benchmarks, arsenic, vanadium, and nitrate were detected at high relative-concentrations in 15.6 percent, 3.6 percent, and 2.1 percent, respectively, of the primary aquifer. Of inorganic constituents with secondary maximum contaminant levels (SMCL), manganese, iron, and TDS were detected at high relative-concentrations in 4.5 percent, 2.2 percent, and 1.7 percent, respectively, of the primary aquifer. The status assessment for organic constituents showed that organic constituents (one or more) were high, relative to human-health benchmarks, in a smaller proportion of the primary aquifer (1.2 percent) than inorganic constituents (18.0 percent). Organic constituents had moderate relative-concentrations in 14.3 percent, and had low relative-concentrations or were not detected in 84.5 percent, of the primary aquifer. The proportion of the primary aquifer with high relative-concentrations of organic constituents reflected high proportions of the discontinued soil fumigant 1,2-dibromo-3-chlororopane (DBCP; 1.0 percent) and the solvent tetrachloroethene (PCE; 0.2 percent). Most of the organic and special interest constituents detected in groundwater in the Central Eastside study unit have human-health benchmarks. Of the 205 organic and special interest constituents analyzed for, 36 constituents were detected. Of these constituents, 32 were detected only at low relative-concentrations. Four constituents, chloroform, carbon tetrachloride, DBCP, and perchlorate, were detected at moderate relative-concentrations in grid wells. Nine organic and special-interest constituents were detected frequently (detected in greater than 10 percent of samples): the trihalomethanes chloroform, bromoform, bromodichloromethane, and dibromochloromethane; the solvent PCE; the herbicides atrazine, simazine, and metolachlor, and special-interest constituent perchlorate. An assessment of understanding of the groundwater quality included sampling of understanding wells, some of which were perforated in shallower or deeper portions of the aquifer system than the primary aquifer, and analysis of correlations of groundwater quality with land use, depth, age classification, and other potential explanatory factors. The understanding assessment indicated that the concentrations of many constituents were related to depth and groundwater age. However, concentrations of individual constituents or constituent classes also were sometimes related to geochemical conditions, lateral position in the flow system, or land use. High and moderate relative-concentrations of uranium, nitrate, and total dissolved solids (TDS) were detected in some wells where the tops of perforations are within the upper 200 feet of the aquifer system. In wells with the depth to the top of perforations below this depth, concentrations were low. A similar pattern occurred for the sum of herbicide concentrations. These vertical water-chemistry patterns are consistent with the hydrogeologic setting, in which return flows from agricultural and urban land use are the major source of recharge, and withdrawals for irrigation and urban supply are the major source of discharge, resulting in substantial vertical components of groundwater flow. The decrease in concentrations of many constituents with depth reflects in part that groundwater gets older with depth. Tritium, helium-isotopes, and carbon-14 data were used to classify the predominant age of groundwater samples into three categories: modern (water that has entered the aquifer in the last 50 years), pre-modern (water that entered the aquifer more than 50 years, up to tens of thousands of years, ago), and mixed (mixtures of waters with modern and pre-modern ages). Uranium, nitrate, and herbicide concentrations were significantly higher in groundwater having modern- and mixed-ages than pre-modern ages, indicating that these constituents may be affected by anthropogenic activities in the last 50 years. Other patterns in the distribution of nitrate, uranium, and TDS are evident. Isotopic and geochemical data are consistent with partial denitrification of nitrate in some reducing groundwaters in the western and deeper parts of the flow system. Uranium and TDS concentrations increase from east to west across the valley, along the direction of regional lateral groundwater flow. High and moderate relative-concentrations of arsenic can be attributed to reductive dissolution of manganese or iron oxides, or to desorption by high pH waters. Arsenic concentrations also increased with increasing depth and groundwater age. High to moderate relative-concentrations of vanadium primarily are related to high pH under oxic conditions. The frequency of detections of DBCP was greater in areas with orchard-vineyard land use >40 percent and at depths <200 feet. THMs and solvents were correlated positively with percent urban land use. Herbicide concentrations were correlated negatively with percent natural land use. Perchlorate concentrations were significantly greater in waters having modern and mixed ages than waters having pre-modern ages and were significantly and positively correlated with two land uses—percent orchard/vineyard land use and percent urban land use.

California↗

USGS2013

Status and understanding of groundwater quality in the San Francisco Bay groundwater basins, 2007—California GAMA Priority Basin Project

Groundwater quality in the approximately 620-square-mile (1,600-square-kilometer) San Francisco Bay study unit was investigated as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is located in the Southern Coast Ranges of California, in San Francisco, San Mateo, Santa Clara, Alameda, and Contra Costa Counties. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in collaboration with the U.S. Geological Survey (USGS) and the Lawrence Livermore National Laboratory. The GAMA San Francisco Bay study was designed to provide a spatially unbiased assessment of the quality of untreated groundwater within the primary aquifer system, as well as a statistically consistent basis for comparing water quality throughout the State. The assessment is based on water-quality and ancillary data collected by the USGS from 79 wells in 2007 and is supplemented with water-quality data from the California Department of Public Health (CDPH) database. The primary aquifer system is defined by the depth interval of the wells listed in the CDPH database for the San Francisco Bay study unit. The quality of groundwater in shallower or deeper water-bearing zones may differ from that in the primary aquifer system; shallower groundwater may be more vulnerable to surficial contamination. The first component of this study, the status of the current quality of the groundwater resource, was assessed by using data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally occurring inorganic constituents, such as major ions and trace elements. Water- quality data from the CDPH database also were incorporated for this assessment. This status assessment is intended to characterize the quality of groundwater resources within the primary aquifer system of the San Francisco Bay study unit, not the treated drinking water delivered to consumers by water purveyors. Relative-concentrations (sample concentration divided by the benchmark concentration) were used for evaluating groundwater quality for those constituents that have Federal and (or) California benchmarks. A relative-concentration greater than (>) 1.0 indicates a concentration greater than a benchmark, and a relative-concentration less than or equal to (≤) 1.0 indicates a concentration equal to or less than a benchmark. Relative-concentrations of organic and special-interest constituents were classified as low (relative- concentration ≤ 0.1), moderate (0.1 < relative- concentration ≤ 1.0), or high (relative-concentration > 1.0). Inorganic constituent relative- concentrations were classified as low (relative-concentration ≤ 0.5), moderate (0.5 < relative-concentration ≤ 1.0), or high (relative- concentration > 1.0). A lower threshold value of relative-concentration was used to distinguish between low and moderate values of organic constituents because organic constituents are generally less prevalent and have smaller relative-concentrations than naturally occurring inorganic constituents. Aquifer-scale proportion was used as the metric for evaluating regional-scale groundwater quality. High aquifer-scale proportion is defined as the percentage of the primary aquifer system that has relative-concentration greater than 1.0 for a particular constituent or class of constituents; proportion is based on an areal rather than a volumetric basis. Moderate and low aquifer-scale proportions were defined as the percentages of the primary aquifer system that have moderate and low relative-concentrations, respectively. Two statistical approaches—grid-based and spatially weighted—were used to evaluate aquifer-scale proportion for individual constituents and classes of constituents. Grid-based and spatially weighted estimates were comparable in the San Francisco Bay study unit (90-percent confidence intervals). Inorganic constituents with health-based benchmarks were present at high relative-concentrations in 5.1 percent of the primary aquifer system, and at moderate relative-concentrations in 25 percent. The high aquifer-scale proportion of inorganic constituents primarily reflected high aquifer-scale proportions of barium (3.0 percent) and nitrate (2.1 percent). Inorganic constituents with secondary maximum contaminant levels were present at high relative-concentrations in 14 percent of the primary aquifer system and at moderate relative-concentrations in 33 percent. The constituents present at high relative-concentrations included total dissolved solids (7.0 percent), chloride (6.1 percent), manganese (12 percent), and iron (3.0 percent). Organic constituents with health-based benchmarks were present at high relative-concentrations in 0.6 percent and at moderate relative-concentrations in 12 percent of the primary aquifer system. Of the 202 organic constituents analyzed for, 32 were detected. Three organic constituents were frequently detected (in 10 percent or more of samples): the trihalomethane chloroform, the solvent 1,1,1-trichloroethane and the refrigerant 1,1,2-trichlorotrifluoroethane. One special-interest constituent, perchlorate, was detected at moderate relative-concentrations in 42 percent of the primary aquifer system. The second component of this work, the understanding assessment, identified some of the primary natural and human factors that may affect groundwater quality by evaluating land use, physical characteristics of the wells, and geochemical conditions of the aquifer. Results from these evaluations were used to explain the occurrence and distribution of constituents in the study unit.

California↗

USGS2020

Hydrogeologic characterization, groundwater chemistry, and vulnerability assessment, Ute Mountain Ute Reservation, Colorado and Utah

The U.S. Geological Survey, in cooperation with the Ute Mountain Ute Tribe (UMUT), initiated a study in 2016 to increase understanding of the hydrogeology and chemistry of groundwater within select areas of the Ute Mountain Ute Reservation (UMUR) in Colorado and Utah, identify vulnerabilities to the system and other natural resources, and outline information needs to aid in the understanding and protection of groundwater resources. The results presented for this study can be used to support the UMUT’s goal of protecting their vital groundwater resources on the UMUR. Hydrogeologic conditions were characterized for the surficial aquifer contained in Quaternary-age unconsolidated surficial deposits and the Dakota aquifer contained in the Cretaceous-age Dakota Sandstone. In the surficial aquifer, median depth to water ranges from about 5.4 to 17.2 feet below land surface in the Farm and Ranch Enterprise area and 11 to 34 feet below land surface in the Towaoc area, and the water table slopes generally southwest or south. A map of depth to the top of the Dakota Sandstone was constructed from existing well data. Depths range from zero in outcrop areas to more than 3,000 feet below land surface on mesas in the southeastern part of the UMUR. Groundwater-chemistry data were collected by the UMUT from 13 springs and 31 wells from 1996 through 2017. Specific conductance was much lower for samples from springs than from wells; median values were 512 and 6,024 microsiemens per centimeter at 25 degrees Celsius, respectively. Spring samples were well oxygenated. A few well samples were anoxic (dissolved oxygen concentrations less than 0.5 milligrams per liter [mg/L]), indicating reducing conditions in the aquifer. About 75 percent of spring samples had fresh water (total dissolved solids concentrations less than 1,000 mg/L), and about 85 percent of well samples had brackish or highly saline water (total dissolved solids concentrations greater than 1,000 mg/L). Water type for springs on the Ute Mountains was calcium bicarbonate. Lower-altitude springs had a calcium-sulfate water type. Most well samples had sodium as the dominant cation, and sulfate, bicarbonate, and chloride as the dominant anions. Fluoride concentrations in about 45 percent of well samples were greater than an agricultural-use standard of 2 mg/L. Nitrate plus nitrite concentrations in most spring and well samples were less than about 1.6 mg/L per liter. Concentrations in samples from wells in the irrigated agricultural area were elevated; the maximum concentration was 78.5 mg/L. About one-half of the trace-element samples had concentrations that were less than laboratory reporting limits. Only aluminum, arsenic, and selenium in spring samples, and boron and selenium in well samples, were detected at concentrations greater than surface-water standards or water-quality standards for agricultural use of groundwater. Only three organic compounds, the pesticides alachlor and atrazine and the volatile organic compound di(2-ethylhexyl) phthalate, were detected in well samples. The Escherichia coli bacteria was detected in 47 and 23 percent of samples from wells and springs, respectively. The E. coli detections included samples from three culturally significant springs, which did not meet the UMUT cultural-use standard of total absence of E. coli. Tritium and carbon-14 were the primary environmental tracers used for interpreting groundwater ages for Lopez 2 Spring and five wells (AP–1, 5000 Block, Cottonwood Spring, Goodknight, and SE Toe). Water from the AP–1 well contained a mixture of pre- and post-1950s recharge. Tritium and carbon-14 recharge ages for Lopez 2 Spring (post-1950s in age), Goodknight and SE Toe wells (pre-1950s in age), and Cottonwood Spring well (primarily pre-1950s in age) are supported by helium-4 data. The helium-4 data for the 5000 Block well are inconsistent with the tritium and carbon-14 age of pre-1950s recharge because of interference caused by high methane concentrations in the water. Springs and surficial deposits are more vulnerable to contamination from anthropogenic chemicals than deeper bedrock wells. Bedrock aquifers are vulnerable in areas where the geologic formations containing the aquifers are exposed at the land surface. Groundwater in deep bedrock aquifers is likely thousands of years old and is not currently affected by present-day land uses. Both shallow and deep groundwater are vulnerable to naturally occurring salts and minerals, such as of total dissolved solids, major ions, nitrate, and trace elements. Effects of a changing climate on water resources and other ecological characteristics of the UMUR could include changes in evapotranspiration, a decrease in snowpack, decreased aquifer recharge and flow of springs, a decrease in soil moisture, and increased occurrence of wildfires and forest mortality. Of particular interest for the UMUT are possible effects of a changing climate on medicinal and culturally important plants and springs Several information needs were identified during this study that would aid in the understanding and protection of groundwater resources on the UMUR. These include well-completion information for bedrock wells, the collection of environmental tracer data at additional wells, the addition of methane and hydrocarbon analysis to well sampling plans, and the resampling of springs and wells that were last sampled in 2002 or earlier.

Colorado↗