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USGS2013

Abundance, size distributions and trace-element binding of organic and iron-rich nanocolloids in Alaskan rivers, as revealed by field-flow fractionation and ICP-MS

Water samples were collected from six small rivers in the Yukon River basin in central Alaska to examine the role of colloids and organic matter in the transport of trace elements in Northern high latitude watersheds influenced by permafrost. Concentrations of dissolved organic carbon (DOC), selected elements (Al, Si, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Rb, Sr, Ba, Pb, U), and UV-absorbance spectra were measured in 0.45 μm filtered samples. ‘Nanocolloidal size distributions’ (0.5–40 nm, hydrodynamic diameter) of humic-type and chromophoric dissolved organic matter (CDOM), Cr, Mn, Fe, Co, Ni, Cu, Zn, and Pb were determined by on-line coupling of flow field-flow fractionation (FFF) to detectors including UV-absorbance, fluorescence, and ICP-MS. Total dissolved and nanocolloidal concentrations of the elements varied considerably between the rivers and between spring flood and late summer base flow. Data on specific UV-absorbance (SUVA), spectral slopes, and the nanocolloidal fraction of the UV-absorbance indicated a decrease in aromaticity and size of CDOM from spring flood to late summer. The nanocolloidal size distributions indicated the presence of different ‘components’ of nanocolloids. ‘Fulvic-rich nanocolloids’ had a hydrodynamic diameter of 0.5–3 nm throughout the sampling season; ‘organic/iron-rich nanocolloids’ occurred in the <8 nm size range during the spring flood; whereas ‘iron-rich nanocolloids’ formed a discrete 4–40 nm components during summer base flow. Mn, Co, Ni, Cu and Zn were distributed between the nanocolloid components depending on the stability constant of the metal (+II)–organic complexes, while stronger association of Cr to the iron-rich nanocolloids was attributed to the higher oxidation states of Cr (+III or +IV). Changes in total dissolved element concentrations, size and composition of CDOM, and occurrence and size of organic/iron and iron-rich nanocolloids were related to variations in their sources from either the upper organic-rich soil or the deeper mineral layer, depending on seasonal variations in hydrological flow patterns and permafrost dynamics.

Alaska↗

USGS2015

Hydrogeochemical exploration: a reconnaissance study on northeastern Seward Peninsula, Alaska

A reconnaissance hydrogeochemical study employing high-resolution/high-sensitivity inductively coupled plasma mass spectrometry analysis of stream and seep water samples ( n = 171) was conducted in an area of limited bedrock exposure on the northeastern Seward Peninsula, Alaska. Sampling was focused in drainages around four main areas—at the Anugi Pb-Zn-Ag occurrence and in streams upstream of historically and currently mined placer gold deposits in the Candle Creek, Utica, and Monument Mountain areas. The objective of the study was to determine whether distribution of elevated metal concentrations in water samples could “see” through sediment cover and provide evidence of bedrock sources for base metals and gold. Some observations include (1) elevated Ag, As, Pb, and Zn concentrations relative to the study area as a whole in stream and seep samples from over and downstream of part of the Anugi Pb-Zn-Ag prospect; (2) abrupt downstream increases in Tl and Sb ± Au concentrations coincident with the upstream termination of productive placer deposits in the Inmachuk and Old Glory Creek drainages near Utica; (3) high K, Mo, Sb, and F throughout much of the Inmachuk River drainage near Utica; and (4) elevated As ± base metals and Au at two sites along Patterson Creek near the town of Candle and three additional contiguous sites identified when an 85th percentile cut-off was employed. Molybdenum ± gold concentrations (>90th percentile) were also measured in samples from three sites on Glacier Creek near Monument Mountain. The hydrogeochemistry in some areas is consistent with limited stream-sediment data from the region, including high Pb-Zn-Ag-As concentrations associated with Anugi, as well as historical reports of arsenopyrite-bearing veins upstream of placer operations in Patterson Creek. Chemistry of samples in the Inmachuk River-Old Glory Creek area also suggest more laterally extensive stibnite- (and gold-?) bearing veining than is currently known in the Old Glory Creek drainage. Our results indicate that hydrogeochemistry can be a useful method of geochemical exploration and offer targets for follow-up rock, soil, and subsurface sampling to ascertain the presence of mineralized bedrock.

Alaska↗

USGS2020

Selected geologic maps of the Kodiak batholith and other Paleocene intrusive rocks, Kodiak Island, Alaska

Kodiak Island in southern Alaska is one of the premier examples globally for the study of forearc magmatism. This location contains two Paleocene intrusive belts that formed due to the subduction of a migrating spreading ridge and slab-window: the Kodiak batholith and the trenchward magmatic belt. These magmatic rocks are part of the Sanak-Baranof belt, which extends for greater than 2,100 km along the southern Alaskan margin and vary in age from 61 to 50 Ma west to east. Trenchward-belt rocks, with an 40 Ar/ 39 Ar age of 60.2±0.9 Ma, intrude into the Paleocene Ghost Rocks Formation and are composed of granitoids, basaltic dikes, and small gabbroic plutons that lie along or southward of the Kalsin Bay Fault. Such intrusions were emplaced at shallow levels and have abundant evidence of incomplete intermingling of basaltic and granitic magmas. These textures indicate trenchward-belt intrusions that froze before complete assimilation, leaving behind features such as abundant locally stoped blocks, gabbroic pods within granitic intrusions, and microstructural evidence such as strongly embayed olivine and pyroxene phenocrysts in granitoid bodies. The Kodiak batholith and satellite intrusions extend for over 110 km along the axis of Kodiak Island and vary in width from 2 to 6 km. These intrude into the Late Cretaceous Kodiak Formation. U-Pb ages on zircon from the intrusions range from 59.2±0.2 Ma in the southwest to 58.4±0.2 Ma near its northwest tip. We interpret these ages as tracking the location of a migrating triple junction and associated slab-window. The batholith is composed of granite and granodiorite, with lesser amounts of tonalite and diorite. The center of the Kodiak batholith contains high-inclusion zones with abundant residual host rock fragments that were carried up from 5–10 km below current exposure levels. These high-inclusion zones contain biotite aggregates, pure quartz clots, and large xenocrysts of sillimanite, kyanite, andalusite, and garnet. This is a higher-pressure mineral assemblage than exists in the batholith metamorphic aureole. Gravity observations and modeling are consistent with the high-inclusion zones extending downward for 5–10 km. The Kodiak batholith results from a migrating triple junction and slab-window that led to high degrees of partial melting within the Kodiak accretionary prism.

Alaska↗

USGS1976

Platinum deposits of the Goodnews Bay district, Alaska

Platinum placers were discovered in 1926 in a small area south of Goodnews Bay, in southwestern Alaska. Beginning in 1927, the placers were worked for 7 years by small-scale mining methods; in later years dragline excavators and a dredge were utilized. These deposits are important, not only because they are of high grade but because they are the only commercial source of platinum metals in the United States. The bedded rocks of this area are sedimentary and volcanic rocks of late Paleozoic(?) age that have been intruded by a variety of ultrabasic rocks. The platinum metals of the placers have been derived from a mass of dunite and related rocks that constitute the bedrock of Red Mountain in the upper valley of the Salmon River. The western headwater tributaries of this stream are the fluvial conduits that have produced all the placers in the valley of the river. The principal placers lie in two pay streaks, one in the valley floor of the Salmon River and the other in an ancient stream channel along the east side of this valley. The stream-channel deposit, called the bench pay streak, was formed in early Pleistocene time; its alluvial materials consist largely of clay derived from an ancient moraine believed to be of Nebraskan age. The valley-floor deposit, called the pay streak of the valley floor, consists of alluvial materials of fluvial and glaciofluvial origin whose ages range from Yarmouth to Holocene. Both channels contain high-grade placers that have yielded a large volume of platinum metals. The platinum metals of these deposits are contained mainly in two alloys intergrown in a pseudoeutectic fabric. The major alloy is mainly platinum, with a small amount of iridium, still smaller amounts of rhodium and palladium, and probably some osmium and ruthenium. The minor alloy is dominantly iridium and osmium with less platinum and still less ruthenium and rhodium. The compositions of these two alloys are somewhat variable but tend to approach constant mean values. A small amount of free gold is recovered with the platinum metals. In addition to these two alloys, minute amounts of five platinum minerals have been identified. The weighted mean percentages of platinum, iridium, osmium, ruthenium, rhodium, palladium, and gold, as mined from 1936 to 1972, are respectively 82.25, 11.32, 2.15, 0.17, 1.30, 0.38, and 2.43. The lodes from which these placers have been derived are, or have been, localized in the Red Mountain ridge, where the principal rocks are dunite and serpentinite. No lodes have been recognized, either because the platinum metals are sparsely distributed or because a large part of the platiniferous rock has been eroded. It is known, however, that the amounts of iridium, osmium, and ruthenium, or of osmiridium, decrease from south to north. Other generalizations regarding the composition and granularity of these metals have been deduced. The size and shape of the platinum lodes may have ranged from diffuse disseminations to high-grade concentrations in small loci. Under certain assumptions, the tenor of platinum metals in the dunite can be roughly approximated. Utilizing two totally different methods of computation, the mean tenor has been estimated to lie between 0.19 and 0.27 grain of platinum metals per cubic yard of dunite, or 0.014 to 0.023 gram per stere. No large low-grade deposits of commercial value are likely to be found, but it is possible that some small high-grade concentrations occur.

Alaska↗

USGS1985

Geologic setting, petrology, and geochemistry of stratiform sphalerite-galena-barite deposits, Red Dog Creek and Drenchwater Creek areas, northwestern Brooks Range, Alaska

Similar stratiform sphalerite-galena-barite deposits occur in the Red Dog Creek area, De Long Mountains quadrangle, and in the Drenchwater Creek area, Howard Pass quadrangle, northwestern Brooks Range, Alaska. The deposits, located approximately 180 km apart, are hosted by Mississippian and Pennsylvanian strata of the Kagvik structural sequence of late Paleozoic and early Mesozoic age. This sequence is situated in the lowermost structural plate of a series of predominantly east-striking, shallow-dipping thrust plates that characterize the regional structure. The deposits occur in shale, tuff, tuffaceous sandstone, altered chert, and quartz exhalite. These units are in places interlayered with or adjacent to bedded or nodular barite or submarine keratophyre flows. Chert and shale commonly contain abundant highly altered, fine-grained feldspar, pumice lapilli, and mafic volcanic rock fragments.The main types of occurrences at Red Dog Creek are: (1) disseminated and stratiform sulfides thinly bedded in organic-rich Mississippian and Pennsylvanian shale and chert, (2) massive sulfide veins and breccia fillings in silicified Mississippian and Pennsylvanian shale, and (3) stratiform sulfide-bearing lenses subdivided into (3a) quartz-exhalite with up to several percent sulfides and barite, (3b) massive sulfide-quartz lenses with up to several percent barite, and (3c) barite-quartz lenses with up to several percent sulfides.At Drenchwater Creek sulfides and barite occur as: (1) disseminations in shale, chert, tuff, and tuffaceous sandstone; (2) disseminations to aggregates in quartz exhalite; and (3) occurrences in veins crosscutting cleavages in brecciated chert and shale.The stratiform sulfides occur in zones up to several thousand meters long and several tens of meters thick. Preliminary grades at Red Dog Creek are 17.1 percent zinc, 5.0 percent lead, and 2.4 oz silver per ton contained in at least 85 million tons.The range of sulfide sulfur isotope values at Red Dog Creek is -16.6 per mil to +3.6 per mil. Sphalerite averages 0.8 per mil. Pyrite is isotopically lighter than coexisting sphalerite in quartz exhalite and massive sulfide lenses. This isotopic relationship is compatible with paragenetic relationships which show pyrite crystallized both earlier and later than other sulfides. Galena is isotopically lighter than coexisting sphalerite. Three groups of geologically and isotopically distinct barites exist including isotopic values appropriate for derivation from late Paleozoic seawater sulfate.Early in the depositional sequence isotopically light pyrite formed from organically reduced seawater sulfate. Sphalerite, galena, late pyrite, and some barite precipitated from two sulfur-bearing solutions that mixed at the mineralization site. Isotopically light barite associated with sulfides precipitated from oxidized H 2 S without seawater sulfate contribution. Lead isotope data from Red Dog and Drenchwater Creeks are compatible with generation of lead in a Phanerozoic mature island-arc setting, a typical orogene, or possibly a back-arc type intracratonic basin.The stratiform sphalerite-galena-barite deposits probably formed in an incipient island-arc environment near a continental margin, containing magmas of keratophyric and andesitic composition, where metal-laden hydrothermal fluids discharged into a deep (?) water, low-energy environment. Later intense deformation, associated with plate docking and thrusting, disrupted and partly remobilized and stratiform deposits.

Alaska↗

USGS1992

Impact origin of the Avak Structure, Arctic Alaska, and genesis of the Barrow gas fields

Geophysical and subsurface geologic data suggest that the Avak structure, which underlies the Arctic Coastal Plain 12 km southeast of Barrow, Alaska, is a hypervelocity meteorite or comet impact structure. The structure is a roughly circular area of uplifted, chaotically deformed Upper Triassic to Lower Cretaceous sedimentary rocks 8 km in diameter that is bounded by a ring of anastomosing, inwardly dipping, listric normal faults 12 km in diameter. A zone of gently outward-dipping sedimentary country rocks forms a discontinuous ring of "rim anticlines" within the peripheral ring of normal faults. Beyond these anticlines, the sedimentary rocks are almost flat-lying. Basement consists of strongly deformed Ordovician and Silurian argillite. Density and acoustic impedance con rasts between the argillite and the overlying strata produce gravity and seismic-reflection signatures that define a ring of anticlines around the disturbed zone and a structural high surrounded by an annular structural low at its center. In the adjacent Barrow gas fields, the tops of the informally named Neocomian "pebble shale" unit and the gas-producing Lower Jurassic Barrow sand (local usage) lie at average subsea depths of 488 m and 670 m, respectively. In the Avak 1 well, drilled on the central high, the pebble shale and the Barrow sand lie near the surface, documenting more than 500 m of relative uplift at the high. The cores in this well have steep dips (30-90 degrees), mixed breccia with Franklinian argillite clasts 10 and 90 m above basement, quartz grains with shock mosaicism and multiple sets of shock lamellae, oriented concussion fractures in sand-size quartz grains, and shatter cones resembling those found in the peripheral zones of well-documented impact structures. In addition, above-background levels o fractured quartz grains in Barrow sand were found as far as 19 km beyond the rim of the Avak structure. Data concerning the age of the Avak structure are not definitive. If submarine landslide deposits in the upper part of the Aptian and Albian Torok Formation, in the subsurface 200 km to the east, were triggered by the Avak event, then the Avak meteorite struck a submerged marine shelf about 100 + or - 5 Ma. However, the impact features found at Avak (shatter cones, concussion fractures, shock lamellae and shock mosaicism in quartz grains, and widespread cataclasis) characterize the distal zones of meteorite impact structures. Fused rocks, plastic deformation, and shock-metamorphic minerals found in more proximal zones of impact structures are apparently missing. These observations, and the lack of Avak ejecta in cuttings and cores from the Torok Formation and Nanushuk Group (Albian to middle Cenomanian) in surrounding test wells, indicate that the impact event postdated these beds. In this case, the Avak meteorite struck a Late Cretaceous or Tertiary marine shelf or coastal plain between the Cenomanian (ca. 95 Ma), and deposition of the basal beds of the overlying late Pliocene and Quaternary Gubik Formation (ca. 3 Ma).

Alaska↗

USGS2012

Local-area-enhanced, high-resolution natural-color and color-infrared satellite-image mosaics of mineral districts in Afghanistan

The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Defense Task Force for Business and Stability Operations, prepared databases for mineral-resource target areas in Afghanistan. The purpose of the databases is to (1) provide useful data to ground-survey crews for use in performing detailed assessments of the areas and (2) provide useful information to private investors who are considering investment in a particular area for development of its natural resources. The set of satellite-image mosaics provided in this Data Series (DS) is one such database. Although airborne digital color-infrared imagery was acquired for parts of Afghanistan in 2006, the image data have radiometric variations that preclude their use in creating a consistent image mosaic for geologic analysis. Consequently, image mosaics were created using ALOS (Advanced Land Observation Satellite; renamed Daichi) satellite images, whose radiometry has been well determined (Saunier, 2007a,b). This DS consists of the locally enhanced ALOS image mosaics for each of the 24 mineral project areas (referred to herein as areas of interest), whose locality names, locations, and main mineral occurrences are shown on the index map of Afghanistan (fig. 1). ALOS was launched on January 24, 2006, and provides multispectral images from the AVNIR (Advanced Visible and Near-Infrared Radiometer) sensor in blue (420-500 nanometer, nm), green (520-600 nm), red (610-690 nm), and near-infrared (760-890 nm) wavelength bands with an 8-bit dynamic range and a 10-meter (m) ground resolution. The satellite also provides a panchromatic band image from the PRISM (Panchromatic Remote-sensing Instrument for Stereo Mapping) sensor (520-770 nm) with the same dynamic range but a 2.5-m ground resolution. The image products in this DS incorporate copyrighted data provided by the Japan Aerospace Exploration Agency, but the image processing has altered the original pixel structure and all image values of the JAXA ALOS data, such that original image values cannot be recreated from this DS. As such, the DS products match JAXA criteria for value added products, which are not copyrighted, according to the ALOS end-user license agreement. The selection criteria for the satellite imagery used in our mosaics were images having (1) the highest solar-elevation angles (near summer solstice) and (2) the least cloud, cloud-shadow, and snow cover. The multispectral and panchromatic data were orthorectified with ALOS satellite ephemeris data, a process which is not as accurate as orthorectification using digital elevation models (DEMs); however, the ALOS processing center did not have a precise DEM. As a result, the multispectral and panchromatic image pairs were generally not well registered to the surface and not coregistered well enough to perform resolution enhancement on the multispectral data. Therefore, it was necessary to (1) register the 10-m AVNIR multispectral imagery to a well-controlled Landsat image base, (2) mosaic the individual multispectral images into a single image of the entire area of interest, (3) register each panchromatic image to the registered multispectral image base, and (4) mosaic the individual panchromatic images into a single image of the entire area of interest. The two image-registration steps were facilitated using an automated control-point algorithm developed by the USGS that allows image coregistration to within one picture element. PRISM image orthorectification for one-half of the target areas was performed by the Alaska Satellite Facility, applying its photogrammetric software to PRISM stereo images with vertical control points obtained from the digital elevation database produced by the Shuttle Radar Topography Mission (Farr and others, 2007) and horizontal adjustments based on a controlled Landsat image base (Davis, 2006). Before rectification, the multispectral and panchromatic images were converted to radiance values and then to relative-reflectance values using the methods described in Davis (2006). Mosaicking the multispectral or panchromatic images started with the image with the highest sun-elevation angle and the least atmospheric scattering, which was treated as the standard image. The band-reflectance values of all other multispectral or panchromatic images within the area were sequentially adjusted to that of the standard image by determining band-reflectance correspondence between overlapping images using linear least-squares analysis. The resolution of the multispectral image mosaic was then increased to that of the panchromatic image mosaic using SPARKLE logic, which is described in Davis (2006). Each of the four-band images within each resolution-enhanced image mosaic was individually subjected to a local-area histogram stretch algorithm (described in Davis, 2007), which stretches each band's picture element based on the digital values of all picture elements within a specified radius that was usually 500 m. The final databases, which are provided in this DS, are three-band, color-composite images of the local-area-enhanced, natural-color data (the blue, green, and red wavelength bands) and color-infrared data (the green, red, and near-infrared wavelength bands). All image data were initially projected and maintained in Universal Transverse Mercator (UTM) map projection using the target area's local zone (either 41 or 42) and the WGS84 datum. Most final image mosaics were subdivided into overlapping tiles or quadrants because of the large size of the target areas. The image tiles (or quadrants) for each area of interest are provided as embedded geotiff images, which can be read and used by most geographic information system (GIS) and image-processing software. The tiff world files (tfw) are provided, even though they are generally not needed for most software to read an embedded geotiff image. Approximately one-half of the study areas have at least one subarea designated for detailed field investigations; the subareas were extracted from the area's image mosaic and are provided as separate embedded geotiff images.

Data Series↗

USGS2004

Paleozoic sedimentary rocks in the Red Dog Zn-Pb-Ag district and vicinity, western Brooks Range, Alaska: provenance, deposition, and metallogenic significance

Geochemical analyses of Paleozoic sedimentary rocks in the western Brooks Range reveal a complex evolutionary history for strata surrounding the large Zn-Pb-Ag deposits of the Red Dog district. Data for major elements, trace elements, and rare earth elements (REE) were obtained on 220 samples of unaltered and unmineralized siliciclastic rocks from the Upper Devonian-Lower Mississippian Endicott Group (Hunt Fork Shale, Noatak Sandstone, Kanayut Conglomerate, Kayak Shale), the overlying Carboniferous Lisburne Group (Kuna Formation, unnamed drowned shelf facies), and the Pennsylvanian-Permian Siksikpuk Formation. Major base metal sulfide deposits of the region are present only in the Kuna Formation, which in the Red Dog district comprises siliceous black shale and black chert, minor limestone (calcareous radiolarite), and sparse lithic turbidite and bedded siliceous rock. Gray and rare black shales of the Kayak Shale and common black shales of the Kuna Formation are anomalously low in iron (avg Fe/Ti = 6.25 and 6.34, respectively) relative to other Paleozoic shales in the region (9.58-10.6) and to average shales worldwide (10.1-10.5). In contrast, the bedded siliceous rocks contain appreciable hematite (avg Fe/Ti = 35.0) and high U/Ti and REE/Ti ratios that are interpreted to reflect low amounts of detrital material and a major Fe-rich eolian component. Geochemical data (e.g., MnO <0.01 wt %; avg Cr = 317 ppm), sizes of framboidal pyrite grains, and limited bioturbation suggest anoxic and denitrifying depositional conditions for most black shales of the Kuna Formation; low Mo/Ti ratios argue against euxinic (sulfate-reducing) conditions. Organic-rich black shales of the Kuna Formation with up to 8.4 wt percent C organic and gray to black shales of the Kayak Shale with up to 4.1 wt percent C organic typically have only sparse pyrite (<1 wt % S) and very low iron-limited S/C ratios (mostly <0.2). Immobile element plots (e.g., Th-Zr/10-Sc) suggest that source terranes for all of the formations were dominated by one or more felsic-rich continental arcs; a small proportion of recycled sediments is present locally. A minor mafic igneous component also occurs in several shales of the Kuna and Siksikpuk Formations. High average values for the chemical index of alteration [Al 2 O 3 /(Al 2 O 3 + CaO + Na 2 O + K 2 O)] ∞ 100 for shales of the Endicott Group (76.4-81.5) imply moderate to intense chemical weathering in source areas of these sediments. A lower average for black shales of the Kuna Formation (73.7) does not require such weathering. Textural and geochemical data record the effects of diagenetic and/or hydrothermal fluid flow in some of the Paleozoic rocks. Mobility of P, F, U, and light REE is documented in black shales of the Kuna Formation by phosphate replacements of carbonate clasts and of matrix material surrounding the clasts. A relatively low average Ce/Ce* value of 0.73 for P-poor black shales of the Kuna Formation ( < 0.05 wt % P 2 O 5 ) and a similar Ce/Ce* value of 0.78 for a siderite concretion in Kayak Shale suggest that these diagenetic fluids were oxidizing. Many shales of the Kuna Formation have high (K 2 O ∞ 100)/(K 2 O + Al 2 O 3 ) ratios of 21.0 to 23.0, which contrast with low ratios of generally <18.0 for shales of the underlying Endicott Group. The high ratios in shales of the Kuna Formation reflect preferential reaction of smectite to illite during the Jurassic-Cretaceous Brookian orogeny, owing to high silica activities in pore fluids that were generated by the dissolution of abundant biogenic silica. The distribution and composition of Paleozoic strata in the western Brooks Range may have played a fundamental role in Zn-Pb mineralization of the Red Dog district. In our model, deposition and early lithification of biogenic chert and bedded siliceous rocks in the upper part of the Kuna Formation served as a regional hydrologic seal, acting as a cap rock to heat and hydrothermal fluids during Late Mississippian base-metal mineralization. Equally important was the iron-poor composition of black shales of the Kuna Formation (i.e., low Fe/Ti ratios), which limited synsedimentary pyrite formation in precursor sediments, resulting in significant H 2 S production in pore waters through the interaction of aqueous sulfate with abundant organic matter. This H 2 S may have been critical to the subsurface deposition of the huge quantities of Zn and Pb in the district. On the basis of this model, we propose that low Fe/Ti and S/C ratios in black shale sequences are potential basin-scale exploration guides for giant sediment-hosted, stratiform Zn-Pb-Ag deposits.

Alaska↗

USGS2014

Geophysical investigations of the geologic and hydrothermal framework of the Pilgrim Springs Geothermal Area, Alaska

Pilgrim Hot Springs, located on the Seward Peninsula in west-central Alaska, is characterized by hot springs, surrounding thawed regions, and elevated lake temperatures. The area is of interest because of its potential for providing renewable energy for Nome and nearby rural communities. We performed ground and airborne geophysical investigations of the Pilgrim Springs geothermal area to identify areas indicative of high heat flow and saline geothermal fluids, and to map key structures controlling hydrothermal fluid flow. Studies included ground gravity and magnetic measurements, as well as an airborne magnetic and frequency-domain electromagnetic (EM) survey. The structural and conceptual framework developed from this study provides critical information for future development of this resource and is relevant more generally to our understanding of geothermal systems in active extensional basins. Potential field data reveal the Pilgrim area displays a complex geophysical fabric reflecting a network of intersecting fault and fracture sets ranging from inherited basement structures to Tertiary faults. Resistivity models derived from the airborne EM data reveal resistivity anomalies in the upper 100 m of the subsurface that suggest elevated temperatures and the presence of saline fluids. A northwest trending fabric across the northeastern portion of the survey area parallels structures to the east that may be related to accommodation between the two major mountain ranges south (Kigluaik) and east (Bendeleben) of Pilgrim Springs. The area from the springs southward to the range front, however, is characterized by east-west trending, range-front-parallel anomalies likely caused by late Cenozoic structures associated with north-south extension that formed the basin. The area around the springs (~10 km2 ) is coincident with a circular magnetic high punctuated by several east-west trending magnetic lows, the most prominent occurring directly over the springs. These features possibly result from hydrothermal alteration imposed by fluids migrating along intra-basin faults related to recent north-south extension. The Pilgrim River valley is characterized by a NE-elongate gravity low that reveals a basin extending to depths of ~300 m beneath Pilgrim Springs and deepening to ~800 m to the southwest. The margins of the gravity low are sharply defined by northeasttrending gradients that probably reflect the edges of fault-bounded structural blocks. The southeastern edge of the low, which lies very close to the springs, also corresponds with prominent NE-striking anomalies seen in magnetic and resistivity models. Together, these features define a structure we refer to as the Northeast Fault. The location of the hot springs appears to be related to the intersection of the Northeast Fault with a N-oriented structure marked by the abrupt western edge of a resistivity low surrounding the hot springs. While the hot springs represent the primary outflow of geothermal fluids, additional outflow extends from the springs northeast along the Northeast fault to another thaw zone that we interpret to be a secondary region of concentrated upflow of geothermal fluids. The Northeast Fault apparently controls shallow geothermal fluid flow, and may also provide an important pathway conveying deep fluids to the shallow subsurface. We suggest that geothermal fluids may derive from a reservoir residing beneath the sediment basin southwest of the springs. If so, the shape of the basin, which narrows and shallows towards the springs, may funnel fluids beneath the springs where they intersect the Northeast Fault allowing them to reach the surface. An alternative pathway for reservoir fluids to reach intermediate to shallow depths may be afforded by the main Kigluaik range front fault that coincides with a resistivity anomaly possibly resulting from fluid flow and associated hydrothermal mineralization occurring within the fault zone.

Conference Paper↗

USGS2022

The ~400 yr B.P. eruption of Half Cone, a post-caldera composite cone within Aniakchak caldera, Alaska Peninsula

Aniakchak volcano is a historically active caldera located on the central Alaska Peninsula. The largest eruption from Aniakchak since the ~3,400 yr B.P. caldera-forming eruption occurred ~400 yr B.P. from Half Cone volcano, an intracaldera composite cone on the northwest floor of the Aniakchak caldera that was largely destroyed by the eruption. The ~400 yr B.P. eruption produced a widely dispersed pumice fall deposit known as the Pink and Brown Pumice. Following small phreatomagmatic explosions, a buoyant Plinian eruption column combined with southwesterly winds dispersed ~1.3 km3 of crystal-poor dacite (66.1–67.1% SiO2) Pink Pumice at least 70 km to the northeast from Half Cone (~0.05 km3 dense rock equivalent; DRE). Fluctuations in the diameters of pyroclasts and accidental lithics in the Pink Pumice indicate at least two cycles of waxing and waning mass flux at the Half Cone vent. This vent produced an eruption column that twice expanded and gained altitudes of ~15–20 km before weakening to lower altitudes. Brown Pumice scoria (58.2– 66.9% SiO2) as well as compositionally banded pyroclasts at the top of the Pink Pumice indicate that both dacite magma and an increasing amount of low-SiO2 (58.2–60.5% SiO2) andesite magma were erupted simultaneously during the transition to the Brown Pumice phase of the eruption. The reversely graded Brown Pumice fall deposit records an escalating Plinian column dominated by low-SiO2 Brown Pumice scoria that reached altitudes of ~20–24 km and led to the emplacement of least ~3.5 km3 of fall deposits up to at least 230 km to the northeast (~1 km3 DRE). Over time, the Brown Pumice eruption column repeatedly experienced partial collapse that ultimately produced thick pyroclastic density current deposits, most of which were confined to within the caldera. Lithic-rich agglutinate and spatter exposed in 60-m-thick deposits atop the severed flanks of Half Cone and within ~2 km of Half Cone were emplaced at the end of the Brown Pumice phase. Agglutinate deposits range from 58.6 to.64.8% SiO2, which generally falls in the compositional range between Brown and Pink Pumice compositional endmembers. Most of the Half Cone edifice was destroyed by the end of the Brown Pumice phase. The ~0.1 km3 crystal-rich dacitic Cobweb lava flow (64.8–65.8% SiO2) filled a basin left behind by the destruction of Half Cone as a series of radiating lobes. Subsequently, a small andesitic tuff cone (62.2–62.8% SiO2) formed over the Cobweb lava flow vent. In all, we estimate that at least ~5.4 km3 of tephra and ~0.1 km3 of lava erupted during the ~400 yr B.P. eruption, yielding a total magmatic volume (DRE) of ~1.3 km3. Titanomagnetite-ilmenite pairs in Pink and Brown Pumice samples record similar equilibrium temperature ranges (944–997 °C and 959–985 °C, respectively) but different fO2 conditions—Pink Pumice pairs plot between NNO and NNO +0.5, Brown Pumice pairs plot below the NNO buffer. Titanomagnetite-ilmenite pairs in Brown Pumice agglutinate record a wider range of temperatures than either Pink or Brown Pumice samples (899–1018 °C) but also show two populations of fO2—one that overlaps the Pink Pumice array at higher fO2 and one that overlaps the Brown Pumice array at lower fO2. Titanomagnetite-ilmenite pairs from the Cobweb lava flow have the largest fO2 range (NNO -0.5 to NNO +0.5), although most pairs overlap Brown Pumice samples at lower fO2 conditions near NNO -0.5. Pairs in Cobweb lava samples record temperatures from 837 to 1054 °C, which is the largest temperature range recorded in deposits emplaced during any phase of the ~400 yr B.P. eruption. Geothermometry results of titanomagnetite-ilmenite pairs in ≤3,400 yr B.P. samples erupted from Aniakchak volcano record a similar temperature range and the presence of two fO2 arrays as the ~400 yr B.P. samples, which implies the existence of two magma regions of the mush column; each the product of slightly different evolution. In addition, results from in situ compositional analyses of plagioclase suggest that the ~400 yr B.P. eruption may have been initiated, at least in part, by intrusion of basaltic magma, which ascended from the lower crust into the shallow subvolcanic magma mush column prior to and during eruption. The bimodal distribution of whole-rock compositions and the two plagioclase populations in the low-SiO2 Brown Pumice—one defined by An40–An60 cores and one defined by An79–An95 cores—is consistent with an abbreviated period of mixing between intruding basalt and resident dacite mush prior to eruption. Progressive mixing between mafic and felsic magmas during and after the eruption likely produced the subsequently erupted Cobweb lava flow, which has an intermediate composition with abundant mineral disequilibria. Aniakchak volcano continues to show episodic signs of unrest, suggesting that eruptions will occur in the future.

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