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Analytical results for As species and related elements in interstitial porewater and sediment from the Maurice River and Union Lake in Vineland, New Jersey

Union Lake, the Maurice River, and the Blackwater Branch , a tributary of the Maurice River, all parts of a small watershed near Vineland, New Jersey, are contaminated by arsenic (As) from a local chemical factory (fig. l)(Faust and others, 1987). An indepth study to be used for the design of the remedial action at the Vineland Chemical Co. Superfund site was initiated by the U.S. Environmental Protection Agency to determine the extent and severity of the contamination. The Vineland Chemical Co. site is located in Cumberland County, New Jersey. Organic As herbicides were manufactured there from approximately 1949 to the late 1980's. As part of the effort, core samples were collected in the Maurice River close to the chemical factory and from Union Lake, a reservoir approximately seven miles from the factory. This report summarizes the analytical results for As speciation and various constituents in the interstitial porewater and associated sediment from these cores. Because the U.S. Geological Survey has the analytical expertise and necessary equipment, the samples were analyzed in USGS laboratories in Denver, Colorado and Seattle, Washington.

New Jersey↗

Occurrence of herbicides, nitrite plus nitrate, and selected trace elements in ground water from northwestern and northeastern Missouri, July 1991 and 1992

The U.S. Geological Survey and the Missouri Department of Health collected water samples for analysis of nitrite plus nitrate and herbicides from rural domestic wells in northwestern and northeastern Missouri in 1991 and 1992. In July 1991, samples were collected from 130 wells in Caldwell, Clinton, Daviess, Gentry, and Nodaway Counties in northwestern Missouri. Nitrite plus nitrate concentrations as nitrogen ranged from less than 0.05 to 63 milligrams per liter. Nitrite plus nitrate concentrations exceeded the State drinking-water standard of 10 milligrams per liter in water samples from 28 wells. One or more of the herbicides--alachlor, atrazine, cyanazine; metribuzin, metolachlor, and trifluralin--were detected at concentrations greater than or equal to 0.05 micrograms per liter in 19 samples. Atrazine was detected in water samples from 16 wells. In July 1992, water samples were collected from 147 wells in Audrain, Clark, Lewis, Monroe, Scotland, and Shelby Counties in northeastern Missouri. Nitrite plus nitrate as nitrogen concentrations in samples ranged from less than 0.05 to 60 milligrams per liter and exceeded 10 milligrams per liter in samples from 28 wells. One or more of the herbicides-alachlor, atrazine, cyanazine, metribuzin, and metolachlor-were detected at concentrations greater than 0.10 microgram per liter in water samples from 19 of the wells sampled. Atrazine was detected in water from 18 wells.

Open-File Report↗

Trace metals and major and rare earth elements in cuttings from five high-temperature wells in the northwest region of The Geysers, California, vapor-dominated geothermal system

Temperatures within the main vapor-dominated steam reservoir at The Geysers geothermal field generally are in the range 238°C to 244°C. A few deep wells in the northwestern part of the field have penetrated beneath this reservoir into a second vapor-dominated reservoir where temperatures are >315°C, while vapor pressure remains nearly constant at about 35.9 bars (Walters et al., 1992). Vapor-dominated reservoirs generally are thought to operate like heat pipes in which steam formed near the base of the system convects upward (along with other gases, such as CC>2 and H2S), while liquid that has condensed from steam near the top of the reservoir counterflows downward (White et al., 1971). To the extent that this steam condensate carries H2S in solution, it may dissolve gold from the surrounding rock during the counterflow. Re-evaporation of the down-flowing condensate and precipitation of dissolved material might occur at the base of the upper reservoir where there is a relatively sharp increase in temperature while vapor pressure remains nearly constant. In addition, brine that once was present throughout the system (Moore, 1992) may have deposited a variety of ore minerals when and where boiling was vigorous during the transition from previous hot water-dominated to present-day vapor-dominated conditions. The investigation reported here was a geochemical reconnaissance survey looking for evidence of accumulation of Au and other metals in the transition zone between the two reservoirs. The petrology of the cuttings was not examined as part of the investigation.

Open-File Report↗