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USGS1999

Water-quality assessment of south-central Texas — Descriptions and comparisons of nutrients, pesticides, and volatile organic compounds at three intensive fixed sites, 1996-98

Water-quality samples were collected during April 1996-April 1998 at three intensive fixed sites in the San Antonio region of the South-Central Texas study unit as part of the U.S. Geological Survey National Water-Quality Assessment Program. The sampling strategy for the intensive fixed-site assessment is centered on obtaining information about the occurrence and seasonal patterns of selected constituents including nutrients, pesticides, and volatile organic compounds. The three sites selected to determine the effects of agriculture and urbanization on surface-water quality in the study unit are Medina River at LaCoste (agriculture indicator site), Salado Creek (lower station) at San Antonio (urban indicator site), and San Antonio River near Elmendorf (integrator site). Concentrations of two nutrients, dissolved nitrite plus nitrate nitrogen and total phosphorus, were largest at the integrator site, which is downstream of municipal wastewater treatment plants. Nitrite plus nitrate nitrogen concentrations at this site often exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for drinking water. All total phosphorus concentrations at the site exceeded the EPA recommended maximum concentration for streams not discharging directly into reservoirs. Nitrite plus nitrate nitrogen concentrations at the integrator site tended to be smaller, and total phosphorus concentrations at the urban site tended to be larger in samples collected during stormflow than during base flow. The most detections and largest concentrations of three pesticides (atrazine, diazinon, and prometon) were in samples collected at the urban site. Some pesticide concentrations at the agriculture site showed a seasonal pattern of increasing concentrations during spring, the peak application season. Four pesticides (atrazine, deethylatrazine, diazinon, and prometon) were detected in at least 38 percent of samples collected at all three sites. The concentrations of all detected pesticides that have an MCL were less than the MCL at the three sites. More volatile organic compounds (VOC) were detected at the urban indicator site than at the agriculture indicator site, mostly likely because more sources are located in urbanized areas. The most VOCs detected and the largest concentrations of two VOCs (chloroform and tetrahydrofuran) were in samples from the integrator site. More VOCs were detected in samples collected at the integrator site during stormflow than during base flow. The concentrations of all detected VOCs that have an MCL were less than the MCL at the three sites.

Texas↗
USGS1999

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota↗
USGS2000

Hydrology and water and sediment quality at James Campbell National Wildlife Refuge near Kahuku, Island of Oahu, Hawaii

The James Campbell National Wildlife Refuge occupies two lowland marsh and pond complexes on the northern coastal plain of Oahu: the mostly natural ponds and wetlands of the Punamano Unit and the constructed ponds of the Kii Unit. The U.S. Fish and Wildlife Service manages the Refuge primarily to protect and enhance habitat for four endangered species of Hawaiian waterbirds. Kii Unit is fed by artesian wells and rainfall, whereas Punamano Unit is fed naturally by rainfall, runoff, and ground-water seepage. Streams drain from the uplands into lowland ditches that pass through Kii Unit on their way to the ocean. A high-capacity pump transfers water from the inner ditch terminus at Kii to the ocean outlet channel. Stormwaters also exit the inner ditch system over flood-relief swales near the outlet pump and through a culvert with a one-way valve. A hydrologic investigation was done from November 1996 through February 1998 to identify and quantify principal inflows and outflows of water to and from the Refuge, identify hydraulic factors affecting flooding, document ground-water/surface-water interactions, determine the adequacy of the current freshwater supply, and determine water and sediment quality. These goals were accomplished by installing and operating a network of stream-gaging stations, meteorology stations, and shallow ground-water piezometers, by computing water budgets for the two Refuge units, and by sampling and analyzing water and pond-bottom sediments for major ions, trace metals, and organic compounds. Streamflow during the study was dominated by winter stormflows, followed by a gradual recession of flow into summer 1997, as water that had been stored in alluvial fans drained to lowland ditches. Outflow at the ditch terminus in 1997 was 125 million gallons greater than measured inflow to the coastal plain, mainly reflecting gains from ground water along the ditches between outlying gages and the ditch terminus. Of the measured 1997 outflow, 98 percent was through the Kii outlet pump, with the outlet culvert valve only opening for brief periods during storms. Large volumes of stormflow overflowed the flood-relief swales unmeasured. The largest storm of the study, in November 1996, was estimated to have a flood frequency of about 3 to 4 years. Streamflow exceeded culvert capacity and overtopped Kamehameha Highway at Kalaeokahipa Stream and Hospital ditch. Slight overbank flooding in Kii ditch resulted strictly from high discharge. Minor overbank flooding farther out on the coastal plain probably was caused mainly by the small hydraulic gradients available to convey stormflows along the lowland ditches. Stormwaters flooded Kii ponds and flowed back upstream along Punamano ditch into Punamano marsh, introducing suspended sediment and possibly other contaminants to the Refuge. Two smaller storms in January 1997 resulted in smaller flows and no overbank flooding. The Kii outlet pump ran continuously for 7 days during the November 1996 storm and for 1 to 2 days during the January 1997 storms. During all three storms, the outlet culvert valve opened and the inner ditches overtopped the flood-relief swales, allowing free outflow of water from the inner ditch. Backwater effects hindered drainage during the January 1997 storms at Hospital ditch at Kamehameha Highway, and at Punamano ditch at Nudist Camp Road (where the backflow into Punamano marsh in November 1996 constituted an extreme backwater effect). A probable marine backwater effect was imposed at the ocean outlet ditch during the November 1996 storm through a combination of high spring tides and wave setup from large surf. Whether this backwater effect propagated upstream in the ditches to affect inland sites could not be determined conclusively. A sand plug may have built up in the ocean outlet channel before the November 1996 storm, but if so, it probably washed out prior to, or early in the storm, and was not present at the time of peak stage at inland sites. A season-long buildup of the sand plug in late 1997 was inferred from rising water levels in the outlet ditch. Seawater flows up the outlet channel or over the sand berm and into the outer ditch system on most high tides, and particularly during spring high tides. Ponds and ditches of the Refuge and surrounding lowlands have mud- and clay-lined bottoms that form an effective confining unit and inhibit interaction with an underlying shallow limestone aquifer. At Kii Unit, pond levels are higher than adjacent ditch levels and underlying ground-water levels, establishing lateral and downward head gradients that could foster seepage losses from the ponds. Regional ground-water discharge from the Koolau aquifer to the coastal-plain sediments is mostly diffuse, but is concentrated where ridges of Koolau Basalt plunge beneath coastal-plain sediments near Punamano Unit and at the head of Hospital ditch. Kii ditch gains brackish ground water downstream of Kamehameha Highway. Wastewater disposal from the sewage treatment plant adjoining Kii Unit poses little or no threat to Refuge habitat. Disposal is at six injection wells located 0.45 mi away at Kahuku, and the wells inject into confined limestone aquifers that do not extend to Kii Unit. The natural freshwater supply to Punamano Unit is adequate for maintaining the wildlife habitat, judging from stable pond levels and low salinities there. A monthly water budget for Punamano showed an apparent annual deficit in measurable flows in 1997, requiring unmeasured ground-water gains equalling 51 inches of water. The freshwater supply to Kii Unit is inadequate according to Refuge managers, because there is not enough water to manipulate levels adequately in the ponds during most of the year, and particularly during the driest months. This is confirmed by monthly deficits in the water budget for the Kii ponds during summer months. However, the Kii budget showed an annual surplus in measurable flows for 1997 equalling 24 inches of water. Unmeasured losses are required to explain the apparent annual surplus, such as discharge to the ditches through pond water-control structures and downward and/or lateral ground-water seepage. The apparent surplus at Kii is strictly hydrologic and is not a surplus in a management sense; it cannot be stored or used to supply the Refuge, but instead reflects losses from the system that render this amount of water unavailable for use. The budget year, 1997, was drier than normal (24 percent below long-term mean rainfall) and so the measured potential evaporation for 1997 was probably higher than the long-term mean. Few metals or organic compounds of potential concern were detected in pond and ditch waters and in pond-bottom sediments. Detected pesticides were at trace levels or just above minimum reporting limits. Exceptions that exceeded quality guidelines for freshwater sediment were copper and zinc in sediment from Kii ponds C and D, and copper in sediment from Punamano north pond. Therefore, urban and agricultural runoff probably have contributed little in the way of harmful metals or organic compounds to the Refuge, although the potential for such contribution remains from periodic flooding of the ponds by ditch stormflows. Salinity was low throughout most Refuge waters, qualifying as fresh to slightly brackish and suitable for the environmental needs of Refuge fauna. Higher salinities have been observed in ditches during past periods of sugarcane cultivation and saltwater aquaculture, however. Resumption of saltwater aquaculture could raise ditch salinities if saltwater effluents are disposed directly into the ditches, as they were in the past.

Hawaii↗
USGS1999

Characterization of selected biological, chemical, and physical conditions at fixed sites in the Upper Colorado River Basin, Colorado, 1995-98

Biological community samples were collected at 15 sites in the Upper Colorado River Basin (UCOL) in Colorado as part of the National Water-Quality Assessment (NAWQA) Program. Sites sampled in two physiographic provinces, the Southern Rocky Mountains and the Colorado Plateau, represented agriculture, mining, urban and recreation, and mixed land uses and background conditions. Nine measures of water quality, which include information on nutrients, specific conductance (a surrogate for salinity), trace elements in streambed sediment, pesticides in fish tissue, fish communities, and macroinvertebrate richness and composition and stream habitat were used for comparisons among sites within the two physiographic provinces. Sampling sites from three other NAWQA study units—the Rio Grande Valley, the South Platte River Basin, and the Upper Snake River Basin study units—were categorized on the basis of land use and stream size in order to develop a larger data set for comparison to sites in the UCOL. Three categories of land use—forested (includes mining, urban and recreation, and background), agriculture, and mixed—were used for comparison to the UCOL fixed sites. Results indicated that all sites other than the Colorado River below Baker Gulch (a background site) showed some water-quality characteristics to be significantly affected. Results indicated that the concentrations of cadmium and zinc in streambed sediment at mining land-use sites in the Southern Rocky Mountains physiographic province generally were orders of magnitude higher than streambed-sediment concentrations at the background site. Streambed-sediment concentrations at mining land-use sites in the UCOL were greater than the 75 th percentile of concentrations from sites in the three other NAWQA study units. Fish communities and habitat conditions were degraded at mining land-use sites compared to the background site. Ephemeroptera, Plecoptera, and Trichoptera (EPT) richness and the percentage of EPT were lower at mining land-use sites than at the background site and were less than the 50 th percentile of those for sites from the three other NAWQA study units. Nutrient concentrations at urban and recreation sites in the Southern Rocky Mountain physiographic province generally were greater than concentrations at the background site and generally were between the 25 th and 90 th percentile of concentrations for sites from the three other NAWQA study units. Habitat conditions and fish communities at urban and recreation sites were slightly degraded compared to the background site. EPT richness and the percentage of EPT were lower at urban and recreation sites than at the background site and were between the 25 th and 75 th percentile of those for sites from the three other NAWQA study units. The percentage of Chironomidae, which may be indicative of pollutant-tolerant organisms, was higher at urban and recreation sites than at the background site. Mixed land-use sites in the Southern Rocky Mountains physiographic province had similar nutrient concentrations and similar cadmium and zinc streambed-sediment concentrations. Fish-community degradation index values were very different among the three mixed land-use sites in the Southern Rocky Mountains physiographic province. Larger percentages of omnivores and anomalies such as lesions and deformities at two mixed land-use sites resulted in higher degradation values of the fish community. Agriculture land-use sites had higher concentrations of nutrients and selenium than the background site in the Colorado Plateau physiographic province. Concentrations of p,p '-DDE in fish tissue at agriculture sites were higher than the 75 th percentile of concentrations for sites from the three other NAWQA study units. Fish communities had degradation values near the 75 th percentile for agriculture sites. The percentage of EPT was low at agriculture sites when compared to the background site. Two mixed land-use sites in the Colorado Plateau physiographic province had similar concentrations of nutrients, selenium, and p,p '-DDE, and similar EPT richness and composition. These two sites were located downstream from agricultural and urban activities. Some water-quality measures at these two sites indicated degradation compared to a mixed land-use site upstream from most of the agriculture and urban activities in the Colorado Plateau physiographic province.

Colorado↗
USGS1999

Water quality of Rob Roy Reservoir and Lake Owen, Albany County, and Granite Springs and Crystal Lake Reservoirs, Laramie County, Wyoming, 1997-98

The water quality of four reservoirs was assessed during 1997 and 1998 as a cooperative project between the Cheyenne Board of Public Utilities and the U. S. Geological Survey. The four reservoirs, Rob Roy, Lake Owen, Granite Springs, and Crystal Lake, provide approximately 75 percent of the public water supply for Cheyenne, Wyoming. Samples of water and bottom sediment were collected and analyzed for selected physical, chemical, and biological characteristics to provide data about the reservoirs. Water flows between the reservoirs through a series of pipelines and stream channels. The reservoirs differ in physical characteristics such as elevation, volume, and depth. Profiles of temperature, dissolved oxygen, specific conductance, and pH were examined. Three of the four reservoirs exhibited stratification during the summer. The profiles indicate that stratification develops in all reservoirs except Lake Owen. Stratification developed in Rob Roy, Granite Springs, and Crystal Lake Reservoirs by mid-July in 1998 and continued until September, with the thickness of the epilimnion increasing during that time. Secchi disk readings indicated Rob Roy Reservoir had the clearest water of the four reservoirs studied. The composition of the phytoplankton community was different in the upper two reservoirs from that in the lower two reservoirs. Many of the species found in Rob Roy Reservoir and Lake Owen are associated with oligotrophic, nutrient-poor conditions. In contrast, many of the species found in Granite Springs and Crystal Lake Reservoirs are associated with mesotrophic or eutrophic conditions. The total number of taxa identified also increased downstream. The chemical water type in the reservoirs was similar, but dissolved-solids concentrations were greater in the downstream reservoirs. Water in all four reservoirs was a calcium-bicarbonate type. In the fall of 1997, Rob Roy Reservoir had the lowest dissolved-solids concentration (19 milligrams per liter), whereas Crystal Lake Reservoir had the highest concentration (63 milligrams per liter). Relatively little differences in the concentrations of major-ion species were noted between samples collected near the surface and near the bottom of the same reservoir. In contrast, iron and manganese concentrations generally were higher in samples collected near the bottom of a reservoir than in near-surface samples collected from the same reservoir. Composite bottom-sediment samples from all four reservoirs contained similar concentrations of bulk constituents such as aluminum, iron, phosphorus and titanium, but varied in concentrations of trace elements. Trace-element concentrations in Rob Roy Reservoir and Lake Owen were similar to the crustal average, whereas in Granite Springs and Crystal Lake Reservoirs the concentrations were similar to granitic rocks.

Wyoming↗
USGS1999

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado↗
USGS2000

Water quality of the Quaternary and Ada-Vamoosa aquifers on the Osage Reservation, Osage County, Oklahoma, 1997

The project was to provide information on the quality of ground water from rural-domestic-water wells within the Osage Reservation and compare the water-quality to proximity to oil wells. About 38,500 oil wells have been drilled in the Reservation since drilling began in 1896. About 1,480 square miles or 64 percent of the Reservation is within a quarter mile of an oil well. The unconfined Quaternary sand aquifer covers about 315 square miles or about 14 percent of the Reservation and the confined Ada-Vamoosa sandstone aquifer covers about 800 square miles or about 35 percent of the Reservation. Fifty-eight percent of the Quaternary aquifer and 69 percent of the outcrop area of the Ada-Vamoosa aquifer are within a quarter mile of an oil well. One hundred twenty domestic ground-water wells were sampled from the Quaternary and Ada-Vamoosa aquifers. Forty-nine percent of the Reservation is underlain by the aquifers. Ground-water quality is good on most of the Reservation, but the use of domestic-water-supply wells tend to minimize water-quality problems. Existing water-supply wells commonly are located in areas that produce usable volumes of potable water. Several constituents in samples from the Ada-Vamoosa aquifer within a quarter mile of an oil well were significantly greater than from the aquifer not near oil wells. The constituents include specific conductance, dissolved solids, sodium, sulfate, chloride, bromide, and silica. These ions are probably derived from brine water. In the Ada-Vamoosa aquifer subgroups, 57 percent of the samples near oil wells and 24 percent of the samples not near oil wells had dissolved-solids concentrations greater than 500 milligrams per liter. The water quality in the Quaternary and Ada-Vamoosa aquifers is similar in areas where no oil wells have been drilled but is significantly different for several constituents. Median concentrations of major constituents from the Ada-Vamoosa aquifer not near oil wells were less than or equal to values from the Quaternary aquifer. Sixty-four percent of the water-quality samples from the Quaternary and 51 percent from the Ada-Vamoosa aquifers have dissolved-solids concentrations less than the secondary drinking water regulations of 500 milligrams per liter. Fifty-nine percent of the aquifer samples in the Quaternary aquifer subgroups not near oil wells and 70 percent of the samples near oil wells had dissolved solids less than 500 milligrams per liter. Areas in the Ada-Vamoosa aquifer near Hominy, Pershing, and Hula Lake have dissolved-solids concentrations greater than the secondary drinking water regulations. Water-quality samples from the Quaternary aquifer in these areas also have dissolved-solids concentrations greater than 500 milligrams per liter.

Oklahoma↗
USGS2000

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee↗
USGS2024

Conceptual hydrogeologic framework and groundwater budget near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This report presents information used to characterize the groundwater-flow system and the development of a numerical model in the AMA. Included are descriptions of the geology and conceptual hydrogeologic framework, groundwater levels and flow directions, groundwater recharge and discharge, numerical groundwater-flow model construction and results, and model limitations. The study area encompasses the western part of Pierce County and the southwestern part of King County, Washington. The study area extends south to the Nisqually River, southwest to Tanwax Creek, northeast to the Green River, and north through the valley near Auburn and adjacent uplands. It is bounded on the east by foothills of the Cascade Range, and on the northwest by Puget Sound.

Washington↗
USGS2024

Temperature

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.1, provides guidance and protocols for the measurement of temperature of air, of a surface-water body or in groundwater, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration verification, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.1, version 2.0, by Franceska D. Wilde. Temperature of air and water is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring temperature described in this chapter is applicable to air and most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗
USGS2024

Peak streamflow trends in South Dakota and their relation to changes in climate, water years 1921–2020

Peak-flow (flood) frequency analysis is essential to water-resources management applications, including the design of critical infrastructure such as bridges and culverts, and floodplain mapping. Federal guidelines for performing peak-flow flood frequency analyses are presented in a U.S. Geological Survey Techniques and Methods Report known as Bulletin 17C. A basic assumption within Bulletin 17C, which documents the guidelines for determining annual peak streamflow frequency, is that, for basins without major hydrologic alterations (for example, regulation, diversion, and urbanization), statistical properties of the distribution of annual peak streamflows are stationary; that is, the mean, variance, and skew are constant through time. Nonstationarity is a statistical property of a peak-flow series such that the long-term (on the order of decades) distributional properties change one or more times either gradually or abruptly through time. Individual nonstationarities may be attributed to one source such as flow regulation, land-use change, or climate but are often the result of a combination of sources, making detection and attribution of nonstationarities challenging. In response to a growing concern regarding nonstationarity in peak streamflows in the region, the U.S. Geological Survey, in cooperation with the Departments of Transportation of Illinois, Iowa, Michigan, Minnesota, Missouri, South Dakota, and Wisconsin; the Montana Department of Natural Resources and Conservation; and the North Dakota Department of Water Resources, assessed the potential nonstationarity in peak streamflows in the north-central United States. This chapter characterizes the effects of natural hydroclimatic shifts and potential climate change on annual peak streamflows in the State of South Dakota. Annual peak and daily streamflow as well as model-simulated gridded climatic data were examined for temporal monotonic trends, change points, and other statistical properties indicative of changing climatic and environmental conditions. Changes in annual peak and daily flows were evaluated among 13, 35, and 81 qualifying U.S. Geological Survey streamgages for the 75-, 50-, and 30-year trend periods through water year 2020 (the period from October 1, 2019, to September 30, 2020) in South Dakota, respectively. No qualifying streamgages were in the 100-year trend period in the State. Statistical tests for autocorrelation (independent and identically distributed assumption), monotonic trends, and change points in the median and scale are analyzed to evaluate potential stationarity violations (nonstationarity) for performing at-site peak-flow flood-frequency analysis. The trends are reported using a likelihood approach as an alternative to simply reporting significant trends with an arbitrary p -value cutoff point. A distinct east-west spatial pattern of likely upward and downward monotonic trends and change points, respectively, was detected in 75- and 50-year trend periods, but an inconsistent spatial pattern was detected in the 30-year trend period. Additionally, change points in the median annual peak streamflows were detected in the late 1970s and early 1980s in the western part of the State, but in the east, the change point was more commonly detected in 1992–93. A similar east-west spatial pattern of likely upward and downward trends was detected in the annual peak-flow timing, the day of the year of the annal peak streamflow. In the western part of the State, the annual peak streamflows are arriving earlier, but in the east, the annual peak streamflows are arriving later. A peaks-over-threshold (POT) analysis where, on average, there are two events per year (POT2) and four events per year (POT4) was also used to evaluate changes in the frequency (count) of daily streamflows exceeding the threshold. Similar to detected changes in the annual peak streamflow, an east-west likely upward or downward change corresponding to an increase or decrease, respectively, in the frequency of daily streamflow greater than a POT2 and POT4 threshold was detected. A monthly water-balance model was used to evaluate hydroclimatic variation in annual and seasonal precipitation, snowfall, potential evapotranspiration, and soil moisture storage for all qualifying streamgages in the 75-, 50-, and 30-year trend periods. Detected trends in the annual hydroclimatic metrics for the 75- and 50-year trend periods indicate a spatially consistent statewide increase in precipitation, decrease in snowfall, increase in potential evapotranspiration, and increase in soil moisture storage. Furthermore, detected trends in seasonal precipitation in the 75- and 50-year trend periods highlight a pronounced change in precipitation in winter and later into the summer season, especially in the 50-year trend period in the eastern part of the State. Statewide increases in seasonal soil moisture storage were also detected, highlighting year-round increasing flood magnitudes, particularly in the eastern part of the State. Based on the results of these stationarity tests for the qualifying streamgages in South Dakota among the 75-, 50-, and 30-year trend periods, consistent temporal and spatial patterns of nonstationarity were detected among the 75- and 50-year trend periods. Furthermore, when nonstationarity is detected in daily streamflow, increased streamflow and volume (increasing frequency in POT), as well as potentially bridge scour, may have implications on culvert and highway design in the eastern part of South Dakota. Thus, when performing at-site peak-flow flood-frequency analyses in South Dakota, potential nonstationarities and alternative approaches are important considerations.

South Dakota↗
USGS2024

Characterization of groundwater resources near the southeastern part of Puget Sound, Washington

More than 1 million people live within the active model area (AMA) in the southeastern part of the lowlands surrounding Puget Sound, or Puget Lowland, Washington, and groundwater is the source for approximately one-half of their public, domestic, and irrigation water demands. The 887-square-mile AMA, located in King and Pierce Counties, represents the area of analysis for the conceptual hydrogeologic framework and numerical groundwater-flow models within the study area and includes the Puyallup River and Chambers-Clover Creek watersheds. To assess the potential hydrologic and anthropogenic impacts to groundwater and the connected surface-water resources, conceptual and numerical groundwater-flow models of groundwater flow were developed by the U.S. Geological Survey Washington Water Science Center in close cooperation with 18 water-resource agencies and stakeholders. This multichapter volume documents the development of the conceptual and numerical groundwater-flow models of groundwater flow. Chapters A, B, and C provide an overall introduction to the multichapter volume (Chapter A), the conceptual hydrogeologic framework (Chapter B), and the groundwater budget (Chapter C). Chapters D and E describe numerical groundwater-flow model construction and calibration (Chapter D) and the numerical groundwater-flow model results (Chapter E). Collectively, these reports present a characterization and simulation tool for groundwater resources near the southeastern part of Puget Sound, Washington.

Scientific Investigations Report↗
USGS2025

Assessment and validation of depressions in digital elevation models from multiple elevation data sources and delineation of depressions, sinking streams, and their watersheds in Tennessee and parts of Kentucky, Virginia, North Carolina, Georgia, Alabama, and Mississippi

Closed depressions and sinking streams in karst landscapes pose difficulties for water-resources management, in the construction of roads and other public works, and in hydrologic and hydrogeomorphic analyses. Digital elevation models (DEMs) can be used to identify the location and determine the size and shape of closed depressions, but separating artificial depressions due to error from real depressions in DEMs can be difficult. Artificial depressions in the DEMs can result from errors that were inherited from limitations in the source data, the interpolation of the elevation data into a grid of values, or horizontal and vertical accuracy of the elevation data. Because the source dataset used to derive DEMs is only a model of the true landscape, field verification is necessary to separate artificial depressions from real ones in DEMs. DEM analysis alone can only be used to determine whether a depression is likely or unlikely to exist in the landscape. The U.S. Geological Survey has applied methods to delineate depressions, sinking streams, and their watersheds by using DEMs derived from two sources of elevation data within karst areas of Tennessee and parts of surrounding States. Preliminary depressions, which include all depressions before separating the likely depressions from the unlikely depressions, were delineated from the DEMs with 30- by 30-foot cells derived from each elevation data source. The characteristics of these preliminary depressions were compared to occurrence probabilities for depressions derived from numerical error propagation tests in 10 test areas across the study area and to topographic-contour source data within a 17,739-square-mile test area in middle Tennessee and northern Alabama. The comparison was conducted to determine depression characteristics that, when combined with depression-proximity filters, could be used to separate unlikely from likely depressions. Preliminary depressions were examined in the field at 91 sites in Tennessee, and field observations were compared to digital determinations of unlikely and likely depressions. The density and size of depressions derived from each elevation dataset were compared within eight karst regions in the study area. Depressions and their watersheds were compiled from each elevation dataset. Sinking streams derived from the National Hydrography Dataset and their watersheds also were compiled for the study area.

Alabama, Georgia, Kentucky, Mississippi, North Car↗
USGS2024

Preparing for today's and tomorrow's water-resources challenges in eastern Long Island, New York

Freshwater is a vital natural resource. Although New York is a water-rich State, the wise and economical use of water resources is needed to ensure that there is enough water of adequate quality for both human and ecological needs—both for today and for tomorrow. Nowhere in New York is this more evident than in Nassau and Suffolk Counties on Long Island, where the public water supply is obtained from the sole-source aquifers located directly beneath the nearly 3 million people who live there. In 2023, in eastern Long Island’s Suffolk County, groundwater was pumped from these aquifers by more than 1,100 public water-supply wells to meet the needs of about 1.5 million people.

New York↗
USGS1976

Results of phytoplankton sampling at National Stream Quality Accounting Network stations in Montana, 1975 water year

Twelve National Stream Quality Accounting Network stations were operated in Montana during the 1975 water year. The network was established for the purpose of acquiring a base of hydrologic data for use by agencies engaged in water-resources planning on a national or regional scale. Among the characteristics analyzed were phytoplankton identification and cell counts. Samples consisted of composites of equal aliquots, collected at the center of each quartile of flow, using modified suspended-sediment samplers and sediment collection techniques. Identification and counting were done using the Sedgwick-Rafter cell method. Cell counts ranged from 21 cells per millilitre at Flathead River at Flathead, British Columbia to 27,000 cells per millilitre at Yellowstone River near Sidney. The class Bacillariophyceae was most abundant in both number and variety at all sampling sites. Anabaena and Aphanizomenon of the phyllum Cyanophyta were found at six stations and two stations respectively. These two genera of blue-green algae often become abundant in enriched waters resulting in nuisance conditions.

Montana↗
USGS2025

Updating and recalibrating the integrated Santa Rosa Plain Hydrologic Model to assess stream depletion and to simulate future climate and management scenarios in Santa Rosa, Sonoma County, California

The Santa Rosa Plain Hydrologic Model (SRPHM) was developed and published in 2014 through a collaboration between the U.S. Geological Survey (USGS) and Sonoma Water to analyze the hydrologic system in the Santa Rosa Plain watershed, help meet the increasing demand for fresh water, and prepare for future uncertainties in water resources. The original model simulated hydrological conditions and water use from water years 1975 to 2010. Recently (2023), the USGS, in cooperation with Sonoma Water and the California State Water Resources Control Board, updated the SRPHM model to extend its simulation period to the end of the 2018 calendar year, incorporate new estimates of rural and agricultural water use, and use efficient input format for climate variables. The updated model was recalibrated, and evaluation of the new model calibration is included in this report. This report presents the results of comparing the hydraulic heads, streamflow, and groundwater budget simulated by the updated model with those generated by the original model and observed data. The main difference in the simulated budget between the original and updated SRPHM is the estimates of agricultural pumping, rural domestic pumping, and return flow generated from rural water use that was not simulated in the original model. The revised agricultural pumping is simulated using the agricultural package, which constrains pumping to available groundwater. The use of the agricultural package leads to a more realistic estimation of agricultural water use, with revised agricultural pumping being one-third less than that in the original model. The revised rural pumping is about half of the pumping in the original model because of using detailed parcel data to estimate population density in rural areas instead of coarse census tracts. Overall, average total inflows for water years 2006–10 simulated by the updated model were about 2 percent less than the original model, and the average total updated outflows were nearly 5 percent less than the original model. The updated model was then used to generate stream depletion maps, simulate climate change scenarios during 2019–99, and simulate water rights allocation using the Model for Decision Support in Integrated River Basin Management (MODSIM). The results from simulating eight future climate scenarios indicated either an increase in groundwater storage or no significant change in the next 80 years, along with an increase in recharge, an increase in actual evapotranspiration in six out of eight climate projections, and an increase in surface runoff. The increases in the simulated future groundwater storage, recharge, evapotranspiration, and runoff in most climate projections are mainly driven by the projected increase in precipitation in most of the future climate scenarios. The updated model also was used to test a pilot case study demonstrating water-resource allocation among different users with different water rights using the integrated MODSIM-Groundwater and Surface-Water Flow Model (GSFLOW) platform. The updated SRPHM serves as a valuable tool for analyzing historical and future hydrologic conditions in the Santa Rosa Plain watershed and preparing for future uncertainties.

California↗
USGS2025

Application of Hydrologic Simulation Program—FORTRAN (HSPF) as part of an integrated hydrologic model for the Salinas Valley, California

The U.S. Geological Survey (USGS), in cooperation with the Monterey County Water Resources Agency, conducted studies to help evaluate the surface-water and groundwater resources of the Salinas Valley study area, consisting of the entire Salinas River watershed and several smaller, adjacent coastal watersheds draining into Monterey Bay. The Salinas Valley study area is a highly productive agricultural region that depends on the coordinated use of surface water and groundwater to meet demand for irrigation and public water supply. To continue to meet these demands, a better understanding of the historical water balance and the effects of water-resource development on the long-term sustainability of water resources in the Salinas Valley study area is needed.

California↗