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An update of hydrologic conditions and distribution of selected constituents in water, Snake River Plain aquifer, Idaho National Laboratory, Idaho, Emphasis 1999-2001

Radiochemical and chemical wastewater discharged since 1952 to infiltration ponds, evaporation ponds, and disposal wells at the Idaho National Laboratory (INL) has affected water quality in the Snake River Plain aquifer underlying the INL. The U.S. Geological Survey (USGS), in cooperation with the U.S. Department of Energy, maintains ground-water monitoring networks at the INL to determine hydrologic trends, and to delineate the movement of radiochemical and chemical wastes in the aquifer. This report presents an analysis of water-level and water-quality data collected from wells in the USGS ground-water monitoring networks during 1999-2001. Water in the Snake River Plain aquifer moves principally through fractures and interflow zones in basalt, generally flows southwestward, and eventually discharges at springs along the Snake River. The aquifer is recharged principally from infiltration of irrigation water, infiltration of streamflow, ground-water inflow from adjoining mountain drainage basins, and infiltration of precipitation. Water levels in wells rose in the northern and west-central parts of the INL by 1 to 3 feet, and declined in the southwestern parts of the INL by up to 4 feet during 1999-2001. Detectable concentrations of radiochemical constituents in water samples from wells in the Snake River Plain aquifer at the INL generally decreased or remained constant during 1999-2001. Decreases in concentrations were attributed to decreased rates of radioactive-waste disposal, radioactive decay, changes in waste-disposal methods, and dilution from recharge. Tritium concentrations in water samples decreased as much as 8.3 picocuries per milliliter (pCi/mL) during 1999-2001, ranging from 0.43?0.14 to 13.6?0.6 pCi/mL in October 2001. Tritium concentrations in five wells near the Idaho Nuclear Technology and Engineering Center (INTEC) increased a few picocuries per milliliter from October 2000 to October 2001. Strontium-90 concentrations decreased or remained constant during 1999-2001, ranging from 2.1?0.6 to 42.4?1.4 pCi/L in October 2001. During 1999-2001, concentrations of cesium-137, plutonium-238, and plutonium-239, -240 (undivided) were less than the reporting level in water samples from all wells sampled at the INL. The concentration of americium-241 in one sample was 0.003?0.001 pCi/L, the reporting level for that constituent. Cobalt-60 was not detected in any samples collected during 1999-2001. Changes in detectable concentrations of nonradioactive chemical constituents in water from the Snake River Plain aquifer at the INL varied during 1999-2001. In October 2001, water from one well south of the Reactor Technology Complex (RTC) [known as the Test Reactor Area (TRA) until 2005] contained 139 micrograms per liter (?g/L) of chromium, a decrease from the concentration of 168 ?g/L detected in October 1998. Other water samples contained from less than 16.7 to 21.3 ?g/L of chromium. In October 2001, concentrations of sodium in water samples from most of the wells in the southern part of the INL were larger than the background concentration of 10 mg/L, but were similar to or slightly less than October 1998 concentrations. The largest sodium concentration was 75 milligrams per liter (mg/L) in water from well USGS 113. In 2001, chloride concentrations in most water samples from the INTEC and the Central Facilities Area (CFA) exceeded ambient concentrations of 10 and 20 mg/L, respectively. Chloride concentrations in water from wells near the RTC were less than 20 mg/L. At the Radioactive Waste Management Complex (RWMC), chloride concentrations in water from wells USGS 88, 89, and 120 were 81, 40, and 23 mg/L, respectively. Concentrations of chloride in all other wells near the RWMC were less than 19 mg/L. During 2001, concentrations of sulfate in water from two wells near the RTC, two wells near the RWMC, and one well near the CFA exceeded 40 mg/L, the estimated background concentration of sulfate in the Snake River

Scientific Investigations Report

Effects of Regulation and Technology on End Uses of Nonfuel Mineral Commodities in the United States

The regulatory system and advancement of technologies have shaped the end-use patterns of nonfuel minerals used in the United States. These factors affected the quantities and types of materials used by society. Environmental concerns and awareness of possible negative effects on public health prompted numerous regulations that have dramatically altered the use of commodities like arsenic, asbestos, lead, and mercury. While the selected commodities represent only a small portion of overall U.S. materials use, they have the potential for harmful effects on human health or the environment, which other commodities, like construction aggregates, do not normally have. The advancement of technology allowed for new uses of mineral materials in products like high-performance computers, telecommunications equipment, plasma and liquid-crystal display televisions and computer monitors, mobile telephones, and electronic devices, which have become mainstream products. These technologies altered the end-use pattern of mineral commodities like gallium, germanium, indium, and strontium. Human ingenuity and people?s demand for different and creative services increase the demand for new materials and industries while shifting the pattern of use of mineral commodities. The mineral commodities? end-use data are critical for the understanding of the magnitude and character of these flows, assessing their impact on the environment, and providing an early warning of potential problems in waste management of products containing these commodities. The knowledge of final disposition of the mineral commodity allows better decisions as to how regulation should be tailored.

Scientific Investigations Report

Paleomagnetic correlation of surface and subsurface basaltic lava flows and flow groups in the southern part of the Idaho National Laboratory, Idaho, with paleomagnetic data tables for drill cores

Paleomagnetic inclination and polarity studies have been conducted on thousands of subcore samples from 51 coreholes located at and near the Idaho National Laboratory. These studies are used to paleomagnetically characterize and correlate successive stratigraphic intervals in each corehole to similar depth intervals in adjacent coreholes. Paleomagnetic results from 83 surface paleomagnetic sites, within and near the INL, are used to correlate these buried lava flow groups to basaltic shield volcanoes still exposed on the surface of the eastern Snake River Plain. Sample handling and demagnetization protocols are described as well as the paleomagnetic data averaging process. Paleomagnetic inclination comparisons between coreholes located only kilometers apart show comparable stratigraphic successions of mean inclination values over tens of meters of depth. At greater distance between coreholes, comparable correlation of mean inclination values is less consistent because flow groups may be missing or additional flow groups may be present and found at different depth intervals. Two shallow intersecting cross-sections, A-A- and B-B- (oriented southwest-northeast and northwest-southeast, respectively), drawn through southwest Idaho National Laboratory coreholes show the corehole to corehole or surface to corehole correlations derived from the paleomagnetic inclination data. From stratigraphic top to bottom, key results included the (1) Quaking Aspen Butte flow group, which erupted from Quaking Aspen Butte southwest of the Idaho National Laboratory, flowed northeast, and has been found in the subsurface in corehole USGS 132; (2) Vent 5206 flow group, which erupted near the southwestern border of the Idaho National Laboratory, flowed north and east, and has been found in the subsurface in coreholes USGS 132, USGS 129, USGS 131, USGS 127, USGS 130, USGS 128, and STF-AQ-01; and (3) Mid Butte flow group, which erupted north of U.S. Highway 20, flowed northwest, and has been found in the subsurface at coreholes ARA-COR-005 and STF-AQ-01. The high K20 flow group erupted from a vent that may now be buried south of U.S. Highway 20 near Middle Butte, flowed north, and is found in the subsurface in coreholes USGS 131, USGS 127, USGS 130, USGS 128, USGS 123, STF-AQ-01, and ARA-COR-005 ending near the Idaho Nuclear Technology and Engineering Center. The vent 5252 flow group erupted just south of U.S. Highway 20 near Middle and East Buttes, flowed northwest, and is found in the subsurface in coreholes ARA-COR-005, STF-AQ-01, USGS 130, USGS 128, ICPP 214, USGS 123, ICPP 023, USGS 121, USGS 127, and USGS 131. The Big Lost flow group erupted from a now-buried vent near the Radioactive Waste Management Complex, flowed southwest to corehole USGS 135, and northeast to coreholes USGS 132, USGS 129, USGS 131, USGS 127, USGS 130, STF-AQ-01, and ARA-COR-005. The AEC Butte flow group erupted from AEC Butte near the Advanced Test Reactor Complex and flowed south to corehole Middle 1823, northwest to corehole USGS 134, northeast to coreholes USGS 133 and NRF 7P, and south to coreholes USGS 121, ICPP 023, USGS 123, and USGS 128. Evidence of progressive subsidence of the axial zone of the ESRP is shown in these cross-sections, distorting the original attitudes of the lava flow groups and interbedded sediments. A deeper cross-section, C-C- (oriented west to east), spanning the entire southern Idaho National Laboratory shows correlations of the lava flow groups in the saturated part of the ESRP aquifer. Areally extensive flow groups in the deep subsurface (from about 100-800 meters below land surface) can be traced over long distances. In cross-section C-C-, the flow group labeled "Matuyama" can be correlated from corehole USGS 135 to corehole NPR Test/W-02, a distance of about 28 kilometers (17 miles). The flow group labeled "Matuyama 1.21 Ma" can be correlated from corehole Middle 1823 to corehole ANL-OBS-A-001, a distance of 26 kilometers (16 miles). Other flo

Idaho

Comparison of base flows to selected streamflow statistics representative of 1930-2002 in West Virginia

Base flows were compared with published streamflow statistics to assess climate variability and to determine the published statistics that can be substituted for annual and seasonal base flows of unregulated streams in West Virginia. The comparison study was done by the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection, Division of Water and Waste Management. The seasons were defined as winter (January 1-March 31), spring (April 1-June 30), summer (July 1-September 30), and fall (October 1-December 31). Differences in mean annual base flows for five record sub-periods (1930-42, 1943-62, 1963-69, 1970-79, and 1980-2002) range from -14.9 to 14.6 percent when compared to the values for the period 1930-2002. Differences between mean seasonal base flows and values for the period 1930-2002 are less variable for winter and spring, -11.2 to 11.0 percent, than for summer and fall, -47.0 to 43.6 percent. Mean summer base flows (July-September) and mean monthly base flows for July, August, September, and October are approximately equal, within 7.4 percentage points of mean annual base flow. The mean of each of annual, spring, summer, fall, and winter base flows are approximately equal to the annual 50-percent (standard error of 10.3 percent), 45-percent (error of 14.6 percent), 75-percent (error of 11.8 percent), 55-percent (error of 11.2 percent), and 35-percent duration flows (error of 11.1 percent), respectively. The mean seasonal base flows for spring, summer, fall, and winter are approximately equal to the spring 50- to 55-percent (standard error of 6.8 percent), summer 45- to 50-percent (error of 6.7 percent), fall 45-percent (error of 15.2 percent), and winter 60-percent duration flows (error of 8.5 percent), respectively. Annual and seasonal base flows representative of the period 1930-2002 at unregulated streamflow-gaging stations and ungaged locations in West Virginia can be estimated using previously published values of statistics and procedures.

West Virginia

Groundwater quality in West Virginia, 1993-2008

Approximately 42 percent of all West Virginians rely on groundwater for their domestic water supply. However, prior to 2008, the quality of the West Virginia’s groundwater resource was largely unknown. The need for a statewide assessment of groundwater quality prompted the U.S. Geological Survey (USGS), in cooperation with West Virginia Department of Environmental Protection (WVDEP), Division of Water and Waste Management, to develop an ambient groundwater-quality monitoring program. The USGS West Virginia Water Science Center sampled 300 wells, of which 80 percent were public-supply wells, over a 10-year period, 1999–2008. Sites for this statewide ambient groundwater-quality monitoring program were selected to provide wide areal coverage and to represent a variety of environmental settings. The resulting 300 samples were supplemented with data from a related monitoring network of 24 wells and springs. All samples were analyzed for field measurements (water temperature, pH, specific conductance, and dissolved oxygen), major ions, trace elements, nutrients, volatile organic compounds, fecal indicator bacteria, and radon-222. Sub-sets of samples were analyzed for pesticides or semi-volatile organic compounds; site selection was based on local land use. Samples were grouped for comparison by geologic age of the aquifer, Groups included Cambrian, Ordovician, Silurian, Devonian, Pennsylvanian, Permian, and Quaternary aquifers. A comparison of samples indicated that geologic age of the aquifer was the largest contributor to variability in groundwater quality. This study did not attempt to characterize drinking water provided through public water systems. All samples were of raw, untreated groundwater. Drinking-water criteria apply to water that is served to the public, not to raw water. However, drinking water criteria, including U.S. Environmental Protection Agency (USEPA) maximum contaminant level (MCL), non-enforceable secondary maximum contaminant level (SMCL), non-enforceable proposed MCL, or non-enforceable advisory health-based screening level (HBSL), were used as benchmarks against which to compare analytical results. Constituent concentrations were less than the MCLs in most samples. However, some samples exceeded non-enforceable SMCLs, proposed MCLs, or advisory HBSLs. Radon-222 concentrations exceeded the proposed MCL of 300 pCi/L in 45 percent of samples, and iron concentrations exceeded the SMCL of 300 µg/L in 57 percent of samples. Manganese concentrations were greater than the SMCL (50 µg/L) in 62 percent of samples and greater than the HBSL (300 µg/L) in 25 percent of the samples. Other sampled constituents, including organic compounds and trace elements, exceeded drinking-water criteria at much lower frequencies. The radon-222 median concentrations in samples from Cambrian, Ordovician, Silurian, Permian, and Quaternary aquifers exceeded the proposed 300 pCi/L MCL. Although median radon concentrations for wells in Devonian, Mississippian, and Pennsylvanian aquifers were less than the proposed MCL, radon concentrations greater than the proposed MCL were measured in samples from aquifers of all geologic ages. The median iron concentrations for samples from Devonian and Pennsylvanian aquifers were greater than the 300 µg/L SMCL. Iron concentrations exceeded the SMCL in aquifers of all geologic ages, except Cambrian. Median concentrations of manganese exceeded the SMCL in samples from Devonian, Pennsylvanian, and Quaternary aquifers. As with iron, manganese concentrations were found to exceed the SMCL in at least one sample from aquifers of all geologic ages, except Cambrian. Pesticides were detected most frequently and in higher concentrations in limestone-dominated areas. Most of West Virginia’s agriculture is concentrated in those areas. This study, the most comprehensive assessment of West Virginia groundwater quality to date, indicates the water quality of West Virginia’s groundwater is generally good; in the majority of cases raw-water samples met primary drinking water-criteria. However, some constituents, notably iron and manganese, exceeded the secondary drinking criteria in more than half the samples.

West Virginia

Paleomagnetic correlation and ages of basalt flow groups in coreholes at and near the Naval Reactors Facility, Idaho National Laboratory, Idaho

Paleomagnetic inclination and polarity studies were conducted on subcore samples from eight coreholes located at and near the Naval Reactors Facility (NRF), Idaho National Laboratory (INL). These studies were used to characterize and to correlate successive stratigraphic basalt flow groups in each corehole to basalt flow groups with similar paleomagnetic inclinations in adjacent coreholes. Results were used to extend the subsurface geologic framework at the INL previously derived from paleomagnetic data for south INL coreholes. Geologic framework studies are used in conceptual and numerical models of groundwater flow and contaminant transport. Sample handling and demagnetization protocols are described, as well as the paleomagnetic data averaging process. Paleomagnetic inclination comparisons among NRF coreholes show comparable stratigraphic successions of mean inclination values over tens to hundreds of meters of depth. Corehole USGS 133 is more than 5 kilometers from the nearest NRF area corehole, and the mean inclination values of basalt flow groups in that corehole are somewhat less consistent than with NRF area basalt flow groups. Some basalt flow groups in USGS 133 are missing, additional basalt flow groups are present, or the basalt flow groups are at depths different from those of NRF area coreholes. Age experiments on young, low potassium olivine tholeiite basalts may yield inconclusive results; paleomagnetic and stratigraphic data were used to choose the most reasonable ages. Results of age experiments using conventional potassium argon and argon-40/argon-39 protocols indicate that the youngest and uppermost basalt flow group in the NRF area is 303 ± 30 ka and that the oldest and deepest basalt flow group analyzed is 884 ± 53 ka. A south to north line of cross-section drawn through the NRF coreholes shows corehole-to-corehole basalt flow group correlations derived from the paleomagnetic inclination data. From stratigraphic top to bottom, key results include the following: * The West of Advanced Test Reactor Complex (ATRC) flow group is the uppermost basalt flow group in the NRF area and correlates among seven continuously cored holes in this study under surficial sediments. The West of ATRC flow group is also found in coreholes near the ATRC, the Idaho Nuclear Technology and Engineering Center (INTEC), and in corehole USGS 129. * The ATRC Unknown Vent flow group correlates among seven continuously cored holes in this study underlying the West of ATRC flow group and a sedimentary interbed. Additional paleomagnetic inclination and stratigraphic data derived from the NRF coreholes changed the previously reported interpretation of the subsurface distribution of this basalt flow group. The ATRC Unknown Vent flow group also is found in coreholes near the ATRC and INTEC. * The Central Facilities Area (CFA) Buried Vent flow group correlates among all eight coreholes in the NRF area. It also is found in coreholes near the CFA and the Radioactive Waste Management Complex (RWMC) to the south. This basalt flow group is thickest near the CFA, which may indicate proximity to the vent. The State Butte flow group is found below the CFA Buried Vent flow group in the four northern NRF coreholes. It correlates to the State Butte surface vent located just northeast of the NRF. It is not found in coreholes south of the NRF. * The Atomic Energy Commission (AEC) Butte flow group is found in coreholes USGS 133, NRF 6P, and NRF 7P. It probably underlies coreholes NRF B18-1, NRF 89-05, and NRF 89-04, but those coreholes were not drilled deeply enough to penetrate the flow group. The AEC Butte flow group vent is exposed at the surface near the ATRC, and its flows are found in many coreholes near the ATRC and INTEC. The AEC Butte flow group abruptly pinches out against the Matuyama Chron reversed polarity flows of the East Matuyama Middle flow group between coreholes NRF 7P and NRF 15. * The East Matuyama Middle flow group correlates between coreholes NRF 15 and NRF 16 and may correlate to coreholes NPR Test/W-02 and ANL-OBS-A-001. * The North Late Matuyama flow group correlates among coreholes USGS 133, NRF 6P, NRF 7P, NRF 15, and NRF 16. It probably underlies coreholes NRF B18-1, NRF 89-05, and NRF 89-04, but those coreholes were not drilled deeply enough to penetrate the flow group. The vent that produced the North Late Matuyama flow group may be located in the general NRF area because it is thickest near corehole NRF 6P. * The Matuyama flow group is found in coreholes in the southern INL from south of the RWMC to corehole USGS 133 and may extend north to corehole NRF 15. The Matuyama flow group is thickest near the RWMC and thins to the north. * The Jaramillo (Matuyama) flow group is found in corehole NRF 15, which is the deepest NRF corehole, and shows that the basalt flow group is thick in the subsurface at NRF. This flow group is thickest between the RWMC and INTEC and thins towards the ATRC and NRF.

Idaho

Water quality of groundwater and stream base flow in the Marcellus Shale Gas Field of the Monongahela River Basin, West Virginia, 2011-12

The Marcellus Shale gas field underlies portions of New York, Pennsylvania, Ohio, Virginia, Maryland, Tennessee, and West Virginia. Development of hydraulic fracturing and horizontal drilling technology led to extensive development of gas from the Marcellus Shale beginning about 2007. The need to identify and monitor changes in water-quality conditions related to development of the Marcellus Shale gas field prompted the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection, Division of Water and Waste Management, to document water quality for comparison with water quality in samples collected at a future date. The identification of change in water-quality conditions over time is more difficult if baseline water-quality conditions have not been documented. U.S. Geological Survey personnel sampled groundwater and surface water in West Virginia’s Monongahela River Basin during 2011–12. A groundwater survey, in which 39 wells and 2 springs were sampled, was conducted during June through September 2011. A base-flow survey was conducted during July through October 2012; 50 stream sites were sampled under base-flow conditions in this survey. Because additives to hydraulic fracturing fluids are variable and decrease in flowback water over a relatively short time, water-quality analyses for this study focused on documenting the water-quality characteristics typical of water from shallow aquifers; water derived from contact with the Marcellus Shale (flowback from hydraulic fracturing or formation water); and water with constituents from conventional oil and gas development, sewage effluent, and coal-mine drainage. All samples were analyzed for field properties (water temperature, pH, specific conductance, dissolved oxygen, and turbidity), major ions, trace elements, naturally occurring radioactive materials, and stable isotopes. In addition to documenting baseline water-quality conditions for an area of shale-gas development, these data were examined for patterns in water quality. Groundwater and base-flow survey data were compared to historical data from the Monongahela River Basin in West Virginia. Additionally, groundwater- and base-flow survey samples were grouped by Marcellus Shale gas production in the subbasin in which that sampling site was located. The comparisons of data collected as part of this study with historical data identified few differences. No significant difference was found in a comparison of groundwater survey data and historical data. Base-flow survey samples differed significantly from historical data for pH, chloride, and strontium, all of which had higher concentrations in the base-flow survey samples. Differences in pH are likely related to changes in mining regulation beginning in 1977. Concentrations of chloride and strontium elevated above background concentrations may be related to saline groundwater; saline water is within 300 feet of the land surface in parts of the study area. In the comparison of base-flow survey samples grouped by shale-gas-production setting, significant differences were found for fluoride and barium. Concentrations of fluoride and barium were higher in stream subbasins with active Marcellus Shale production than in subbasins not near active Marcellus Shale production. Elevated fluoride and barium are associated with deep brines. Generally, naturally occurring radioactive materials were not found in elevated concentrations in either groundwater or base-flow samples. Only 3 samples, 2 from the groundwater survey and one from the base-flow survey, exceeded the U.S. Environmental Protection Agency maximum contaminant level for radium isotopes of 5.0 picocurie per liter for either a single isotope or a combined value of radium-226 and radium-228. Stable isotope composition indicates broad similarity among surface water, shallow groundwater, and precipitation in the region. Neither shallow groundwater nor surface water showed a marked similarity with the deep brines associated with shale gas. In most of the groundwater survey samples, 38 of 41 samples, dissolved gas profiles were similar to those previously found in samples from shallow, domestic wells in the region. This study provides a baseline of water-quality conditions in the Monongahela River Basin in West Virginia during the early phases of development of the Marcellus Shale gas field. Although not all inclusive, the results of this study provide a set of reliable water-quality data against which future data sets can be compared and the effects of shale-gas development may be determined.

West Virginia

Interpretation of dye tracing data collected November 13–December 2, 2017, at the Savoy Experimental Watershed as part of the Advanced Groundwater Field Techniques in Karst Terrains course, Savoy, Arkansas

The first course on the use of advanced groundwater field techniques for karst aquifers was conducted November 13–17, 2017, at the University of Arkansas Savoy Experimental Watershed (SEW), which is located on pastures for beef livestock research conducted by the Department of Animal Sciences at the University of Arkansas at Savoy, Arkansas. The SEW is an interdisciplinary, collaborative, long-term research site for the study of animal-waste management in a mantled karst setting. The course focused on advanced field activities appropriate for karst aquifer studies: dye tracing, groundwater/surface-water interactions, geophysical methods, and geochemistry. This report summarizes the data collected and interpreted from the dye tracing part of the November 2017 course, other USGS field courses, and past dye tracing investigations conducted by University of Arkansas students.

Arkansas

Factors affecting the distribution of water-bearing fractures in the bedrock aquifers of West Virginia

Bedrock aquifers cover 23,601 square miles within the State of West Virginia and comprise 97.4 percent of the surficial area within the State; the remaining 2.6 percent (621 square miles) consists of alluvial sand-and-gravel and glacial outwash aquifers bordering the State’s major rivers. While West Virginia’s alluvial aquifers have been studied extensively, bedrock aquifers have only been characterized for studies completed in a few areas in Jefferson, McDowell, and Monroe Counties. Bedrock aquifers are water supplies for public supply, agriculture, industry, and residential homeowner use. In this study, the U.S. Geological Survey, in cooperation with the West Virginia Department of Environmental Protection Division of Water and Waste Management, provides a statewide assessment of the occurrence and distribution of fractures within bedrock aquifers of the State and the various topographic, physiographic, and lithologic influences controlling the occurrence and distribution of bedrock fractures. The results of this study provide an increased understanding of the distribution of fractures in bedrock aquifers in West Virginia and help to verify trends that have been suspected for many years but were never well documented or verified by data. The results confirmed that the density of fractures and those that were determined to be water bearing decrease significantly with depth. A statistically significant difference in the density of fractures was observed at a depth of 215 feet for wells in the Appalachian Plateaus Physiographic Province’s and in the Valley and Ridge Physiographic Province’s aquifers; a higher density of fractures and water-bearing fractures were above a depth of 215 feet than below that depth. This is an important consideration when drilling wells for residential, commercial, industrial, or agricultural water supply. Abandoned underground coal mines are commonly believed to form large pools of water in the interconnected mine entries in abandoned room and pillar coal mines. Such pools of water can and do exist in abandoned underground coal mines, but many mines lack open entries and are held up by overburden strata and pillars that can collapse and form aquifers comprised of vast interconnected rubble zones (gob), especially in older mines. Data assessed for this study showed that shale-corrected values of effective porosity for limestone aquifers in West Virginia had a median value of 2 percent and an average value of 4 percent and generally are mineralized with low effective porosity. Argillaceous or sandy limestone has a median shale-corrected porosity of 4 percent and an average shale-corrected porosity of 5 percent. The median and average shale-corrected porosity of sandstone aquifers was estimated to be 14 percent, but the median shale-corrected porosity for argillaceous or calcareous sandstone was 5 percent and the average shale-corrected porosity for argillaceous or calcareous sandstone was 6 percent. Even though shale has a relatively high total sonic porosity compared to other lithologies, shale and siltstone had relatively low shale-corrected porosity, ranging from 0 to 2 percent. Well yields were previously documented to be highest in valley settings, lowest on hilltops, and intermediate on hillsides. Transmissivity data provided by this study confirm this general pattern within the Appalachian Plateaus Province; however, the Valley and Ridge Province does not follow this pattern. While still lowest on hilltop settings, the highest well yields were in hillside settings. The trend for the Valley and Ridge Province was likely skewed because of 9 high-yield wells specifically targeting deeper thin limestone units, such as the Tonoloway and Helderberg Limestones, at depths with transmissivity in excess of 2,000 feet squared per day in Mineral County, West Virginia, or targeting karst aquifers in Berkeley, Jefferson, or Greenbrier Counties, West Virginia. Finally, water-bearing fractures have been hypothesized to comprise a small number of all fractures within a typical bedrock well in West Virginia. Data collected for this study support this theory. A total of 3,403 fractures were identified during this study; 3,151 (92.6 percent) of those fractures are low-transmissive, and only 252 (7.4 percent) fractures are water-bearing. Even though a well may contain many fractures, less than 8 percent are considered water-bearing fractures.

West Virginia

Measurement of sedimentary interbed hydraulic properties and their hydrologic influence near the Idaho Nuclear Technology and Engineering Center at the Idaho National Engineering and Environmental Laboratory

Disposal of wastewater to unlined infiltration ponds near the Idaho Nuclear Technology and Engineering Center (INTEC), formerly known as the Idaho Chemical Processing Plant, at the Idaho National Engineering and Environmental Laboratory (INEEL) has resulted in the formation of perched water bodies in the unsaturated zone (Cecil and others, 1991). The unsaturated zone at INEEL comprises numerous basalt flows interbedded with thinner layers of coarse- to fine-grained sediments and perched ground-water zones exist at various depths associated with massive basalts, basalt-flow contacts, sedimentary interbeds, and sediment-basalt contacts. Perched ground water is believed to result from large infiltration events such as seasonal flow in the Big Lost River and wastewater discharge to infiltration ponds. Evidence from a large-scale tracer experiment conducted in 1999 near the Radioactive Waste Management Complex (RWMC), approximately 13 km from the INTEC, indicates that rapid lateral flow of perched water in the unsaturated zone may be an important factor in contaminant transport at the INEEL (Nimmo and others, 2002b). Because sedimentary interbeds, and possibly baked-zone alterations at sediment-basalt contacts (Cecil and other, 1991) play an important role in the generation of perched water it is important to assess the hydraulic properties of these units.

Idaho

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Naval Station Mayport, Florida

Ground-water flow through the surficial aquifer system at Naval Station Mayport near Jacksonville, Florida, was simulated with a two-layer finite-difference model as part of an investigation conducted by the U.S. Geological Survey. The model was calibrated to 229 water-level measurements from 181 wells during three synoptic surveys (July 17, 1995; July 31, 1996; and October 24, 1996). A quantifiable understanding of ground-water flow through the surficial aquifer was needed to evaluate remedial-action alternatives under consideration by the Naval Station Mayport to control the possible movement of contaminants from sites on the station. Multi-well aquifer tests, single-well tests, and slug tests were conducted to estimate the hydraulic properties of the surficial aquifer system, which was divided into three geohydrologic units�an S-zone and an I-zone separated by a marsh-muck confining unit. The recharge rate was estimated to range from 4 to 15 inches per year (95 percent confidence limits), based on a chloride-ratio method. Most of the simulations following model calibration were based on a recharge rate of 8 inches per year to unirrigated pervious areas. The advective displacement of saline pore water during the last 200 years was simulated using a particle-tracking routine, MODPATH, applied to calibrated steady-state and transient models of the Mayport peninsula. The surficial aquifer system at Naval Station Mayport has been modified greatly by natural and anthropogenic forces so that the freshwater flow system is expanding and saltwater is being flushed from the system. A new MODFLOW package (VAR1) was written to simulate the temporal variation of hydraulic properties caused by construction activities at Naval Station Mayport. The transiently simulated saltwater distribution after 200 years of displacement described the chloride distribution in the I-zone (determined from measurements made during 1993 and 1996) better than the steady-state simulation. The advective movement of contaminants from selected sites within the solid waste management units to discharge points was simulated using MODPATH. Most of the particles were discharged to the nearest surface-water feature after traveling less than 1,000 feet in the ground-water system. Most areas within 1,000 feet of a surface-water feature or storm sewer had traveltimes of less than 50 years, based on an effective porosity of 40 percent. Contributing areas, traveltimes, and pathlines were identified for 224 wells at Naval Station Mayport under steady-state and transient conditions by back-tracking a particle from the midpoint of the wetted screen of each well. Traveltimes to contributing areas that ranged between 15 and 50 years, estimated by the steady-state model, differed most from the transient traveltime estimates. Estimates of traveltimes and pathlines based on steady-state model results typically were 10 to 20 years more and about twice as long as corresponding estimates from the transient model. The models differed because the steady-state model simulated 1996 conditions when Naval Station Mayport had more impervious surfaces than at any earlier time. The expansion of the impervious surfaces increased the average distance between contributing areas and observation wells.

Florida

Nitrogen saturation in the Rocky Mountains: Linking emissions, deposition, and ecosystem effects using stable isotopes of nitrogen compounds

Elevated levels of atmospheric N deposition are affecting terrestrial and aquatic ecosystems at high elevations in Rocky Mountain National Park and adjacent areas of the Front Range of Colorado. Federal and state agencies are now working together to develop cost-effective means for reducing atmospheric N deposition. A discussion on N saturation covers the need for better understanding of N emission source areas and source types that contribute to N deposition in the Rocky Mountains Front Range of Colorado; reductions in NO emissions that resulted from Clean Air Act Amendments, which caused NO3 deposition to decrease between 1984 and 2003; factors contributing to N deposition, e.g., rapid population growth and energy development; origins of NO3, e.g., as NO emissions from fossil fuel combustion, including stationary sources (e.g. emission from coal combustion in electric generating units), and mobile sources (vehicle emissions); disperse stationary sources from energy resource development, e.g., natural gas production; and the importance of incorporating local source characterization and finer spatial and temporal sampling into future studies, which could provide additional insight into N deposition source attribution. This is an abstract of a paper presented at the 100th Annual Conference and Exhibition of the Air and Waste Management Association (Pittsburgh, PA 6/26-29/2007).

Conference Paper

3-D reconstructions of subsurface Pleistocene basalt flows from paleomagnetic inclination data and 40 Ar/ 39 Ar ages in the southern part of the Idaho National Laboratory (INL), Idaho (USA)

The U. S. Geological Survey, in cooperation with the U.S. Department of Energy, is mapping the distribution of basalt flows and sedimentary interbeds at the Idaho National Laboratory in three dimensions to provide data for refining numerical models of groundwater flow and contaminant transport in the eastern Snake River Plain aquifer. Paleomagnetic inclination and polarity data from basalt samples from 47 coreholes are being used to create a three-dimensional (3-D) model of the subsurface of the southern part of the INL. Surface and sub-surface basalt flows can be identified in individual cores and traced in three dimensions on the surface and in the subsurface for distances of more than 20 km using a combination of paleomagnetic, stratigraphic, and 40 Ar/ 39 Ar data. Eastern Snake River Plain olivine tholeiite basalts have K 2 O contents of 0.2 to 1.0 weight per cent. In spite of the low-K content, high-precision 40 Ar/ 39 Ar ages were obtained by applying a protocol that employs short irradiation times (minimizing interferences from Ca derived 36 Ar), frequent measurement of various size atmospheric Ar pipettes to monitor and correct for temporal variation, and signal size dependent nonlinearity in spectrometer mass bias, resulting in age dates with resolution generally between 2 to 10% of the age. 3-D models of subsurface basalt flows are being used to: (1) Estimate eruption volumes; (2) locate the approximate vent areas and extent of sub-surface flows; and (3) Help locate high and low transmissivity zones. Results indicate that large basalt eruptions (>3 km 3 ) occurred at and near the Central Facilities Area between 637 ka and 360 ka; at and near the Radioactive Waste Management Complex before 540 ka; and north of the Naval Reactors Facility at about 580 ka. Since about 360 ka, large basalt flows have erupted along the Arco-Big Southern Butte Volcanic Rift Zone and the Axial Volcanic Zone, and flowed northerly towards the Central Facilities Area. Basalt eruptions shifted the course of the Big Lost River from a more southerly course to its present one.

Idaho

Statewide agent-based model for management of chronic wasting disease in white-tailed deer: PAOvCWD

Chronic wasting disease (CWD) is an always-fatal disease infecting wild cervids globally. Ecologically and economically important, CWD presents a challenge for managing white-tailed deer ( Odocoileus virginianus ). We built an agent-based model to simulate CWD transmission and assess potential management actions that could slow disease spread: PAOvCWD . We developed PAOvCWD using contact rates and other behavioral and ecological metrics estimated from deer monitored in Pennsylvania, USA. We programmed potential management responses (e.g., culling, altered hunter harvest) for all 22 Pennsylvania wildlife management units and validated the efficacy of PAOvCWD using a deer population in south-central Pennsylvania infected with CWD for > 10 years. To support applications of our model, we developed a user-friendly R pipeline that allows implementation with relatively minor modifications. Our pipeline includes four steps: • Steps 1 and 2 generate regional percent forest cover rasters and curate population-level demographics. • Step 3 initializes landscapes and agents using our PAOvPOP model. • Step 4 assesses CWD transmission and management responses using our PAOvCWD model.

Pennsylvania

Movement of white‐tailed deer in contrasting landscapes influences management of chronic wasting disease

Chronic wasting disease (CWD) continues to expand in distribution and prevalence across North America. Upon detection, either for the first time in a novel area or in a region with an existing outbreak, wildlife management agencies are tasked with responding to mitigate the disease. This response often entails creation or modification of a management zone with modified rules and regulations that support an agency's disease management plan. To guide the process of creating an appropriately sized CWD management zone, assuming that wild deer movements are a major risk factor for disease spread, we used data from global positioning system (GPS)-collared white-tailed deer ( Odocoileus virginianus ) in southeastern Minnesota and southcentral Pennsylvania, USA, between 2018 and 2021 to estimate long-distance movements associated with dispersal and migratory behaviors. These contrasting study areas with active CWD outbreaks permitted an evaluation of deer movement dynamics in different parts of their range. We quantified the proportion, distribution, timing, and orientation of dispersing and migratory deer. We observed 21% of female and 58% of male yearlings disperse from their apparent natal home range in Minnesota, while in Pennsylvania 4% of female and 68% of male yearlings dispersed. We also documented 20% of females and 6% of males migrated between seasonal home ranges in Minnesota, while in Pennsylvania no females and 5% of males migrated. The average distance deer dispersed or migrated in Minnesota was 20 km and 11 km, respectively, while in Pennsylvania male deer dispersed only about 4 km. Both sexes in Minnesota tended to disperse in a consistent, westerly direction; however, there was no directional preference observed for migratory deer or for dispersing deer in Pennsylvania. We found differences between natal and adult home range size for both sexes in Minnesota but not for males in Pennsylvania. Our results identify the considerable variability in dispersal and migration dynamics of white-tailed deer in disparate landscapes, which is important to agencies managing CWD. We summarize the distribution of these movements and suggest agencies use this information to help make decisions about optimal management zone size. We suggest the development of formalized assessments of the tradeoffs associated with optimizing decisions about creation of CWD management zones across white-tailed deer populations that exhibit variation in dispersal behavior and suggest careful evaluation to avoid using an arbitrary size or shape to create disease management zones.

Minnesota, Pennsylvania

Perceptions and management of chronic wasting disease in Washington State: A survey of cervid hunters

Chronic wasting disease (CWD) is a fatal neurological disease caused by a misfolded protein, or prion, and is found in cervids (e.g., deer, elk, moose). It represents a serious threat to cervid populations and is one of the most important ungulate management issues facing state wildlife management agencies. Issues associated with CWD can affect many groups including hunters, tribal groups, biologists, rehabilitators, and farmers among others, and many can play an essential role in CWD management (e.g., hunters can help with cervid population control methods). In 2021, the Washington Department of Fish and Wildlife (WDFW) adopted the CWD Management Plan for Washington State, which specifically called for incorporating human dimensions of disease management with the ecological and epidemiological elements in CWD management. It is essential to develop a strong human dimensions component as management actions in other states have shown that when the public is not appropriately engaged, the probability of success is diminished. The study presented here sought to understand public preferences and perceptions of CWD and CWD management. We conducted 15 key constituent interviews and deployed a survey instrument in summer of 2023. (CWD was detected in Washington in July 2024, but this survey was completed ahead of that detection). The survey was emailed to 165,700 resident hunters in Washington State who had purchased a big game license since 2015 and the results presented below are based on interviews and completed survey responses from 7,403 individuals.

Washington

Geohydrologic considerations in the management of radioactive waste

Nongaseous radioactive wastes occur as liquids containing high-level concentrations of radionuclides, liquids containing low concentrations of radionuclides, and solids contaminated by radioactivity. Whether released by accident or design into the earth or onto the earth’s surface, only water is capable of transporting significant quantities of radionuclides away from burial sites. Geohydrologic information that must be determined to predict the velocity and direction of waste movement from a site include climate, hydrology, detailed subsurface geology, permeability, porosity, sorptive potential, seismic potential, and geologic history of the area. Since the late 1960’s mathematical models have been used to make predictions of waste transport in some hydrologic systems. Intensive field investigations at each site are needed before these models can be used.

Nuclear Technology

A system dynamics model to understand the integrated ecological and human dimension aspects of wildlife health and disease management

Chronic wasting disease (CWD) presents an ongoing challenge for the management of deer populations and sustaining harvest opportunities across North America. Existing disease models often fail to fully capture the complex interplay between disease dynamics, host ecology, and socio-economic factors. We developed a comprehensive system dynamics (SD) model that integrates demographic, epidemiological, ecological, and socio-economic processes within a single model to more fully characterize the complex network of causal feedbacks throughout the system. The model was calibrated using a Bayesian approach that incorporates prior knowledge to generate biologically interpretable outcomes, even with sparse data. For estimating the joint posterior distribution of model parameters, we leveraged time series of deer abundance, harvest composition, genetic profiles, CWD surveillance, and hunter demographics and behavior. Model outputs reproduced key system behaviors, including observed CWD prevalence trends, deer population dynamics, and hunter license purchasing patterns. Model predictions were most sensitive to parameters governing initial deer population size and recruitment. While model predictions generally aligned with observed data, discrepancies in early CWD detection and overestimation of the reactivation of long-inactive hunters reflect data limitations and modeling challenges. Key results suggest that indirect transmission is necessary to explain observed prevalence, that transmission is moderately density-dependent, and that observed population-level genetic shifts driven by CWD may play a role in transmission and progression. The SD modelling approach enabled estimation of difficult-to-measure parameters and identified potential leverage points for management—such as prioritizing increasing participation in antlerless harvest of existing hunters over the recruitment of new hunters. This integrated modeling approach offers a flexible foundation for adaptive wildlife disease management and emphasizes the value of unifying biological and human dimension processes to better inform effective, evidence-based policy.

BioRxiv