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Climate-driven sulfate export in alpine watersheds may stimulate methylmercury production

Climate change is increasing sulfate export and changing wetland extent in mountain regions. These changes may increase microbially mediated production of the neurotoxic substance methylmercury due to enhanced sulfate metabolism in mountain environments. Here, we assess methylmercury concentrations and formation rates across high-elevation wetlands in the Colorado Rocky Mountains. We also investigate sulfate controls on methylmercury production within subalpine peatlands by amending soils with sulfate to mimic increased stream export of sulfate from the alpine zone and measuring methylmercury formation rates for different sulfate treatments. We found that subalpine peatlands have statistically significant higher methylmercury concentrations and formation rates compared to alpine, mineral-soil wetlands. Methylmercury production in subalpine peatlands also increased significantly ( p < 0.05) following sulfate additions; the highest rates occurred in sediments with intermediate extractable sulfate concentrations (∼0.60–1.4 mg sulfate g −1 dry soil). Our study is the first to identify soil sulfate-related thresholds for methylmercury production and sulfate-limitation of methylmercury production in subalpine peatlands. These findings highlight important linkages between climate-driven mineral weathering and mercury cycling in mountain regions globally.

Colorado

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee

Remote compositional analyses of space-weathered lunar maria

Visible-to-shortwave infrared (VSWIR) reflectance spectroscopy has revolutionized our understanding of planetary surface compositions. However, space-weathering processes on airless bodies complicate quantitative compositional analyses. Here, we present a framework to isolate the signatures of space weathering in VSWIR spectra of lunar maria by leveraging radiative transfer modeling under the assumptions that (i) a space-weathered target can be expressed as a mixture of fresh and fully space-weathered components and (ii) remaining signatures can be modeled by including agglutinates as an end-member component. We first validate this approach against laboratory spectra of space-weathered Apollo mare soils of known mineral compositions using a probabilistic Markov Chain Monte Carlo implementation of the Hapke radiative transfer model. Second, we illustrate how this approach can be applied to orbital Moon Mineralogy Mapper data. The proposed space-weathering correction workflow for lunar maria could be expanded to other lunar lithologies and applied to existing and future data sets.

Planetary Science Journal

Statewide cumulative human health risk assessment of inorganics-contaminated groundwater wells, Montana, USA

Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.

Montana

Prospectivity modeling of the NASA VIPER landing site at Mons Mouton near the Lunar South Pole

We use a high-resolution digital elevation model and a numerical thermal model to produce a variety of inputs for a water-ice prospectivity model for the Volatiles Investigating Polar Exploration Rover (VIPER) landing site. These input data are maps of topography, surface slope, surface aspect, surface curvature, maximum temperature, depth to ice stability, permanently shadowed regions (PSRs), distance to PSRs, and PSR density. This model predicts where water ice is most likely within the top meter of regolith, assuming plausible relationships between ice concentration and the various inputs. The model is designed to be adjusted in near-real time as data are collected during the VIPER mission. As such, it is a tool for both analyzing data from the mission as well as planning operations. Since the current model, at this point, relies only on orbital remote sensing, the final version will also be a tool to extrapolate the VIPER mission results across the lunar poles.

Planetary Science Journal

Rapid fault healing from cementation controls the dynamics of deep slow slip and tremor

Despite its status as one of the most important discoveries in geophysics, the physical mechanism(s) responsible for slow slip events (SSEs) are not well understood. Here, we synthesize observations of deep SSEs in the Cascadia Subduction Zone and argue that rapid, cohesive fault strengthening may control the dynamics of deep SSEs. Cohesive strength is frequently ignored in constitutive laws used to describe fault rheology in numerical simulations of earthquakes and SSEs alike. To demonstrate its importance, we perform and analyze a suite of petrological experiments that simulate fault healing under representative pressure and temperature conditions. We show that significant cohesive strength recovery caused by dissolution-precipitation processes occurs on timescales of just a few hours. Together, our experimental and observational results support the idea that cohesion is a key component of fault strength under SSE conditions and highlight the need for its inclusion in both future experiments and numerical models of fault slip.

British Columbia, Washington

Long-term dynamics of earthquake swarms in the Yellowstone caldera

The factors controlling the spatial distribution and temporal evolution of earthquake swarms in volcanic systems remain unclear. We leverage leading-edge deep learning algorithms and a detailed three-dimensional velocity model to construct a 15-year high-resolution earthquake catalog of the Yellowstone caldera region. More than half of the region’s earthquakes are clustered into swarm-like families characterized by episodes of hypocenter expansion and migration. Adjacent earthquake swarms, separated by long quiescent periods, are found to be a dominant feature. We suggest that these swarms are controlled by the interplay between slowly diffusing aqueous fluids and rapid episodic fluid injections, which may result from the breaking of permeability seals. Our analyses also indicate that clustered seismicity beneath the caldera occurs on relatively immature, rougher fault structures, compared to more planar faults outside. Our results provide additional context for understanding seismicity in hydrothermal systems, highlighting the key role played by long-term fluid diffusion processes in driving the occurrence of earthquake swarms.

Idaho, Montana, Wyoming

Effects of human activity on Khumbu Glacier: Towards a sustainable Everest Base Camp

The Everest Base Camp (EBC), a critical staging area for mountaineers attempting to summit Mount Everest, has seen a significant increase in human activity over the past few decades. The increasing number of climbers, trekkers, and support staff, particularly at the campsite area, has intensified environmental impacts on the Khumbu Glacier. This study investigates the effects of human activity at EBC, focusing on three contributors to glacier melt: global climate change, local fossil fuel consumption, and human urinary discharge. Through field data collected during the spring 2023 climbing season, this study examines the energy released through the use of liquefied petroleum gas (LPG), kerosene, and petrol for cooking, heating, and electricity, as well as the heat generated by human urinary discharge. The total heat energy released from these activities at EBC in the spring of 2023 was 849,174 ± 179,774 MJ, which would be sufficient to melt 2492 ± 528 tons of glacier ice and snow. Trends in land surface temperature at EBC and adjacent environments during the 1991–2023 period were calculated from Landsat 5, 7, and 9 satellite data. The 32-year Landsat record reveals that EBC surface temperature increased by 0.28 °C year −1 , which was roughly twice the rate of warming at the surface of Khumbu Glacier adjacent to EBC and about 15% higher than the temperature increase of the debris-covered terrain immediately to the north of EBC. The findings suggest that addressing these anthropogenic influences could help to preserve the Khumbu Glacier and support the sustainability of mountaineering in the region. This paper also takes a transformative approach and explores stable and safer locations in case there is a necessity to relocate the current EBC. Two sites have been identified southwest of the existing EBC, which, unlike the current supraglacial site, are situated on stable ground.

Everest Base Camp, Khumbu Glacier

Evaluation of the lithium resource in the Smackover Formation brines of southern Arkansas using machine learning

Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies, and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. High concentrations of lithium in brines have been observed in the Smackover Formation in southern Arkansas (>400 milligrams per liter). We used published and newly collected brine lithium concentration data to train a random forest machine-learning model using geologic, geochemical, and temperature explanatory variables and create a map of predicted lithium concentrations in Smackover Formation brines across southern Arkansas. Using these predicted lithium maps with reservoir parameters and geologic information, we calculated that there are 5.1 to 19 million tons of lithium in Smackover Formation brines in southern Arkansas, which represents 35 to 136% of the current US lithium resource estimate. Based on these calculations, in 2022, 5000 tons of dissolved lithium were brought to the surface within brines as waste streams of the oil, gas, and bromine industries.

Arkansas

As above, so below? A framework for integrating long-term water quantity trends reveals divergent patterns in groundwater and low streamflow across the United States

Climate, land-use, and disturbance drive long-term global trends in groundwater levels and streamflow. At large scales, these trends are typically considered separately, despite the well-established concept that groundwater and surface water comprise a single resource. Joint trend assessment at national scales is challenging because it requires pairing and aggregating data from spatially disparate streamflow and groundwater monitoring sites for which no established framework exists. Here, we evaluate alternative approaches for integrating groundwater and streamflow data to enable joint trend analysis—a critical step toward understanding how water-budget components respond concurrently and interactively to environmental drivers. Mann–Kendall trends were computed for individual groundwater (annual mean depth) and streamflow (annual low of 7 d averages) sites across the U.S over 21- (2000–2020), 31- (1990–2020), and 41-year (1980–2020) periods. Regional Kendall trends were calculated using five spatially contiguous and noncontiguous regional classifications for aggregation based on subsurface (e.g. aquifer, geology) and surface (e.g. watershed, landscape) characteristics. Site-level results revealed contrasting trends, with tendencies toward increasing low flows (wetting) and increasing groundwater depths (drying). Agreement between streamflow and groundwater trends increased with regional aggregation and longer timeframes, though persistent skew toward streamflow wetting and groundwater drying remained. Results varied by region and trend period, with notable consistencies: unified drying in the West/Southwest and wetting in the Upper Midwest. Directional mismatches in long-term trends were prominent in the High Plains and Mississippi Alluvial Plain, whereas near-term mismatches were most evident in the Northwest. Aggregation by hydrologic landscape regions (HLR) yielded the greatest agreement between groundwater and streamflow trends. These findings indicate that coupled responses may represent combined influences of climate, relief, and geology, as captured by HLR, more strongly than geography or geology alone. Integrated water availability assessments may benefit from a multi-characteristic classification framework to treat groundwater and surface water as a unified resource.

Environmental Research: Water

Widespread abyssal turbidites record megathrust earthquake-triggered landslides and coseismic deformation in the Cascadia subduction zone

Abyssal marine turbidites provide some of the longest and most spatially extensive records of subduction zone earthquake recurrence globally; however, correlation of these deposits over long distances and interpretation of synchronous emplacement requires both an understanding of the turbidite generating systems and precise dating. Here, we present an integrated suite of high-resolution bathymetry, subbottom profiles, and sediment cores from combined autonomous underwater vehicle, remotely operated vehicle, and ship-based studies at a key paleoseismic site in the southern Cascadia subduction zone. We demonstrate how widespread, earthquake-triggered landslides on the lower slope deposit discrete, proximal mass transport deposits (MTDs) that grade offshore into complex, interfingered abyssal turbidites, which correspond to records of megathrust earthquake history. We propose accretion and oversteepening of thrust folds on the lower slope both preconditions the slope to fail and provides a perpetual source of unstable material to fail during every earthquake cycle. Furthermore, we suggest the periodic and pervasive landsliding indicates coseismic deformation of the outer accretionary wedge during megathrust rupture.

California, Oregon

Estimating paleotemperature using stable isotopes of soil-formed phyllosilicates from paleosols: A review

Fossilized soils, or paleosols, contain soil-formed phyllosilicates whose stable isotopic compositions may be used to calculate paleotemperature and thus reconstruct ancient terrestrial environments. Though paleosols are common in the geologic record, the use of phyllosilicates as paleotemperature proxies is limited in the literature owing to difficulties with selecting optimal paleosols, isolation from non-clay minerals and organic materials, mixtures of phyllosilicates in natural samples, wide variations of chemical compositions for phyllosilicates, and limited to undefined equilibrium fractionation factors between phyllosilicates-water. Here, we address these challenges by examining and comparing methods used for sample selection, mineral isolation, pretreatments, mineral identification, conventional and developing methods for oxygen and hydrogen isotopic analyses, and determination of phyllosilicate-water equilibrium fractionation factors, concluding with recommendations for best approaches for paleotemperature estimation. Additionally, we discuss how to identify and avoid detrital phyllosilicates, the impacts of diagenesis, comparison of stable isotope and non-isotope paleosol paleotemperature proxies, and challenges and opportunities for broadly using paleosols as paleoclimate archives. With ongoing efforts to refine this multi-faceted paleotemperature approach, the stable isotope geochemistry of soil-formed phyllosilicates continues to be an invaluable proxy system, enhancing our understanding of terrestrial paleoenvironments and paleoclimate.

Kansas

Identifying overlap between native fish movements and a possible seasonal Grass Carp deterrent in the Sandusky River, Ohio, USA

Riverine fishes are vulnerable to habitat fragmentation caused by interrupted access to vital habitats. Fragmentation using artificial structures can be used to limit the spread of invasive fishes by inhibiting movement between critical habitats. Thus, tradeoffs exist between maintaining connectivity for native species and restricting movement of invasive fishes. A nonphysical deterrent has been proposed to prevent invasive Grass Carp ( Ctenopharyngodon idella ) from reaching spawning habitats in the Sandusky River, a tributary to Lake Erie, during late spring–summer. However, this timing overlaps with spawning periods of a suite of native fishes. We used acoustic telemetry and ichthyoplankton surveys to examine movement and spawning activity of multiple native species and to assess potential impacts of deterrent operation on reproduction. All species used the proposed deterrent location during the Grass Carp spawning period, and their movements corresponded with larval fish collections, indicating upstream spawning. These findings suggest the deterrent could unintentionally restrict native species’ access to essential habitats. Balancing habitat connectivity and invasive species control will likely depend on species-specific responses and careful timing of deterrent operation.

Ohio

Pathways for potential exposure to onshore oil and gas wastewater: What we need to know to protect human health

Produced water is a chemically complex waste stream generated during oil and gas development. Roughly four trillion liters were generated onshore in the United States in 2021 (ALL Consulting, 2022, https://www.gwpc.org/wp-content/uploads/2021/09/2021_Produced_Water_Volumes.pdf ). Efforts are underway to expand historic uses of produced water to offset freshwater needs in water-stressed regions, avoid induced seismic activity associated with its disposal, and extract commodities. Understanding the potential exposures from current and proposed produced water uses and management practices can help to inform health-protective practices. This review summarizes what is known about potential human exposure to produced water from onshore oil and gas development in the United States. We synthesize 236 publications to create a conceptual model of potential human exposure that illustrates the current state of scientific inquiry and knowledge. Exposure to produced water can occur following its release to the environment through spills or leaks during its handling and management. Exposure can also arise from authorized releases, including permitted discharges to surface water, crop irrigation, and road treatment. Knowledge gaps include understanding the variable composition and toxicity of produced water released to the environment, the performance of treatment methods, migration pathways through the environment that can result in human exposure, and the significance of the exposures for human and ecosystem health. Reducing these uncertainties may help in realizing the benefits of produced water use while simultaneously protecting human health.

Environmental Health Perspectives

Subsurface water ice mapping on Mars: A probabilistic approach

Subsurface water ice deposits on Mars are an important resource for potential future human exploration. They are also an indicator of the planet’s past climate. However, the distribution of subsurface water ice in Mars’s midlatitudes is uncertain because spacecraft imagery cannot directly observe subsurface ice in most cases. Various spacecraft remote sensing instruments are sensitive to subsurface water ice, including thermal imaging spectrometers, radar sounders, and neutron spectrometers. Geomorphic analyses of images can also implicate subsurface ice. Building upon the data products from the Mars Subsurface Water Ice Mapping project, we provide a probabilistic framework to jointly interpret existing data and estimate the likelihood of subsurface water ice in the Martian midlatitudes between 60 ∘ S and 60 ∘ N with uncertainty. Broadly, we find that near-surface ice is likely present poleward of ∼45 ∘ in both the northern and southern hemispheres. However, closer to the equator, existing remote sensing data cannot uniquely constrain the presence of subsurface water ice. Our probabilistic results provide a framework for quantifying the abundance of ice on Mars, and our uncertainty estimates allow future analysis and exploration to target regions of high uncertainty.

Planetary Science Journal

Irrigated agriculture influences selenium levels in an endangered marsh bird

Selenium bioaccumulation in aquatic food webs poses risks to wildlife, particularly in wetlands receiving irrigation runoff. The Salton Sea, California’s largest lake, is primarily sustained by agricultural drainage. This drainage creates wetland habitat along the lakeshore that many bird species depend on, including the federally endangered Yuma Ridgway’s rail ( Rallus obsoletus yumanensis ). However, these marshes may pose an ecological trap – attracting rails despite high selenium exposure. We captured rails during the 2020–2023 breeding seasons and compared rail selenium levels within three types of marshes (fed with irrigation runoff, Colorado River water, or groundwater). We collected blood, breast feathers, and head feathers of rails in all three water sources for selenium comparisons. We tagged adult rails with GPS transmitters to locate nests and foraging locations where we collected eggshells, unhatched eggs, and prey. We assessed selenium exposure by collecting multiple prey species commonly eaten by rails in all three water sources. Selenium concentrations varied among sampling locations. Selenium concentrations in most sample types were predominately influenced by water source and marsh inflow velocity (sometimes in combination with marsh size). Distance to inflow, however, did not influence selenium concentrations in any sample type. Selenium concentrations were highest in agricultural-fed marshes compared to river-fed and spring-fed marshes. Increased marsh inflow velocities resulted in lower selenium concentrations. Given the risk of an ecological trap, our results suggest that supplementing wetlands with Colorado River water could mitigate selenium bioaccumulation in Yuma Ridgway’s rails.

California

A method to obtain remotely sensed grain size distributions from nonplanar granular deposits

Constraining the grain size distribution of granular deposits with complex surfaces is difficult with existing approaches. Field and laboratory techniques are time consuming and limited by the maximum grain size that laboratories can accommodate. In this study, we present a new method to identify the coarse fraction of the grain size distribution at a debris-flow fan deposit surveyed with terrestrial laser scanning (TLS) in Glenwood Canyon, Colorado, USA. This method is a novel grain segmentation algorithm developed for application to point cloud data of deposits with complex surfaces and angular grains ranging in size from centimeters to a meter. This approach combines an existing random forest machine learning method with a novel iterative clustering algorithm. We compared the grain size distribution from our algorithm with a Wolman pebble count conducted in the field, and found a root mean squared error of less than 2 cm from the 5th to 95th percentile of the grain size distribution of grains ranging from cobble to boulder sized (6.3–78 cm in our application). Finally, we compared our new algorithm with an existing open-source grain segregation algorithm, and our method outperformed the selected alternative when applied to the debris-flow deposit point cloud.

Colorado

Light-dependent activity of deepwater sculpin (Myoxocephalus thompsonii) across substrates with and without predation risk

Light availability strongly influences predator–prey interactions in deepwater ecosystems, where visual constraints shape both foraging success and prey behavior. The behavioral response of deepwater sculpin ( Myoxocephalus thompsonii ) to siscowet lake trout ( Salvelinus namaycush siscowet ) was studied under ecologically relevant light intensities spanning several orders of magnitude typical of daytime downwelling light in the 20–100 m depth range of Lake Superior. Trials were conducted over varying substrates (gravel, sand, and black fabric). Deepwater sculpin showed a significant preference for gravel over sand and black fabric. In the absence of siscowet, sculpin movement frequency increased as light intensity decreased. Sculpin reaction distance to siscowet was influenced by both light and substrate. Reaction distance was shortest at low light intensities, peaked at intermediate light intensities (3.05 × 10⁹ to < 6.0 × 10⁹ photons m⁻2 s⁻1), and declined again at the highest light intensities tested. In the presence of siscowet, sculpin activity was suppressed at the upper end of the light range (≥ 6.0 × 10⁹ photons m⁻2 s⁻1). The greatest increase in movement occurred between 6.0 × 10⁹ and 3.05 × 10⁹ photons m⁻2 s⁻1, which corresponded to the range where siscowet prey capture declined, suggesting sculpin exploit this low-light window to move with reduced risk. Reduced activity in the presence of predators is common among cryptic species, and our findings suggest that sculpin restrict movement at higher light levels to avoid detection by siscowet.

Wisconsin