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USGS2025

Oligocene–Miocene development and evolution of the south Dome Rock Mountains basin, lower Colorado River corridor, Arizona, USA

Sedimentary basins in the Colorado River extensional corridor record large-magnitude Basin and Range extension and younger dextral shear deformation in the evolving Pacific−North America plate boundary. The south Dome Rock Mountains basin is located in west-central Arizona (USA), where the history of basin evolution, style of deformation, and timing of the transition between extension and dextral shear are not well constrained. We integrate new geologic mapping of the south Dome Rock Mountains basin with zircon U-Pb geochronology of six marker beds to characterize the timing of basin evolution and the slip history of the south Dome Rock Mountains normal fault. Structural analysis defines structures consistent with regional extension and younger dextral shear deformation. We use sedimentological and petrological analysis to interpret the depositional environments of three basin sequences. A lower basin sequence consists of fluvial strata deposited in an internally drained intermontane basin from ca. 35 Ma to 24.4 Ma. A sequence of volcanic rocks was emplaced in the basin between 24.4 Ma and 23.3 Ma, before the onset of local extensional faulting. An upper basin sequence of coarse conglomerate and sedimentary breccia was deposited on the hanging wall of a half graben structure after 23.3 Ma and through ca. 12.8 Ma, synchronous with 3−7 km of dip slip on the west-dipping, listric south Dome Rock Mountains fault. The basin was subsequently deformed by dextral shear after 12.8 Ma and before 4.8 Ma. These results document how distributed deformation related to the evolving Pacific−North America plate boundary occurred >100 km from the primary plate boundary.

Arizona, California↗

USGS2015

Coupled interactions between volatile activity and Fe oxidation state during arc crustal processes

Arc magmas erupted at the Earth’s surface are commonly more oxidized than those produced at mid-ocean ridges. Possible explanations for this high oxidation state are that the transfer of fluids during the subduction process results in direct oxidation of the sub-arc mantle wedge, or that oxidation is caused by the effect of later crustal processes, including protracted fractionation and degassing of volatile-rich magmas. This study sets out to investigate the effect of disequilibrium crustal processes that may involve coupled changes in H 2 O content and Fe oxidation state, by examining the degassing and hydration of sulphur-free rhyolites. We show that experimentally hydrated melts record strong increases in Fe 3+ /∑Fe with increasing H 2 O concentration as a result of changes in water activity. This is relevant for the passage of H 2 O-undersaturated melts from the deep crust towards shallow crustal storage regions, and raises the possibility that vertical variations in f O 2 might develop within arc crust. Conversely, degassing experiments produce an increase in Fe 3+ /∑Fe with decreasing H 2 O concentration. In this case the oxidation is explained by loss of H 2 as well as H 2 O into bubbles during decompression, consistent with thermodynamic modelling, and is relevant for magmas undergoing shallow degassing en route to the surface. We discuss these results in the context of the possible controls on f O 2 during the generation, storage and ascent of magmas in arc settings, in particular considering the timescales of equilibration relative to observation as this affects the quality of the petrological record of magmatic f O 2 .

Journal of Petrology↗

USGS1980

The Boulder Creek Batholith, Front Range, Colorado

The Boulder Creek batholith is the best known of several large Precambrian batholiths of similar rock composition that crop out across central Colorado. The rocks in the batholith belong to the calc-alkaline series and range in composition from granodiorite through quartz diorite (tonalite) to gneissic aplite. Two rock types dominate': the Boulder Creek Granodiorite, the major rock unit, and a more leucocratic and slightly younger unit herein named Twin Spruce Quartz Monzonite. Besides mafic inclusions, which occur mainly in hornblende-bearing phases of the Boulder Creek Granodiorite, there are cogenetic older and younger lenses, dikes, and small plutons of hornblende diorite, hornblendite, gabbro, and pyroxenite. Pyroxenite is not found in the batholith. The Boulder Creek Granodiorite in the batholith represents essentially two contemporaneous magmas, a northern body occurring in the Gold Hill and Boulder quadrangles and a larger southern body exposed in the Blackhawk and the greater parts of the Tungsten and Eldorado Springs quadrangles. The two bodies are chemically and mineralogically distinct. The northern body is richer in CaO and poorer in K2O, is more mafic, and has a larger percentage of plagioclase than the southern body. A crude sequence of rock types occurs from west to east in the batholith accompanied by a change in plagioclase composition from calcic plagioclase on the west to sodic on the east. Ore minerals tend to decrease, and the ratio potassium feldspar:plagioclase increases inward from the western contact of the batholith, indicating that the Boulder Creek batholith is similar to granodiorite batholiths the world over. Emplacement of the Boulder Creek batholith was contemporaneous with plastic deformation and high-grade regional metamorphism that folded the country rock and the batholith contact along west-northwest and north-northwest axes. Also, smaller satellitic granodiorite bodies tend to conform to the trends of foliation and fold axes in the country rock, suggesting that emplacement was controlled by preexisting structures in the country rock. On a gross scale, chemical equilibrium in the Boulder Creek Granodiorite is expressed by a near 1:1 ratio, or straight-line relationship in the distribution of iron, magnesium, and manganese in biotite and hornblende. General mineralogical trends in the Boulder Creek Granodiorite indicate that modal biotite, hornblende, and plagioclase tend to increase and quartz and microcline tend to decrease as CaO increases. These trends were not found in the Twin Spruce Quartz Monzonite. Differentiation is believed to have played a major role and assimilation a minor role in the development of the Boulder Creek batholith. The Boulder Creek Granodiorite is of probable mantle or lower crust origin, and, based on the scant data available, the Twin Spruce Quartz Monzonite may be of crustal origin, but the magma was extensively altered by contaminants of ambiguous origin. Mafic inclusions, possibly derived from a dioritic magma which was an early differentiate associated temporally with the Boulder Creek Granodiorite and (or) the Twin Spruce Quartz Monzonite, were in jected into the Boulder Creek Granodiorite during the mush stage and before the batholith was completely crystallized. Biotite, hornblende, and potassium feldspar were studied extensively. Their chemistry and petrology indicate a homogeneity throughout the batholith not believed possible by a casual observance of the batholithic rocks in the field. The accessory minerals, where investigated, also tend to indicate this same pervasive homogeneity.

Professional Paper↗

USGS2024

Special topic—Eruption plumes and clouds

Introduction Explosive eruptions create plumes of volcanic ash and gas that can rise more than 30,000 feet (9.1 kilometers [km]) above sea level within minutes of eruption onset. The resulting clouds disperse under prevailing winds and may cause hazardous conditions hundreds to thousands of kilometers from the volcano, including in international airspace. Rapid detection and characterization of explosive activity is vital to mitigate the wide-ranging effects of volcanic ash. Ashfall thicknesses as small as a millimeter or so on the ground can affect infrastructure, agriculture, and air quality, requiring extensive clean-up procedures (Schuster, 1981; Warrick and others, 1981, U.S. Geological Survey, 2022). Volcanic clouds also pose substantial threats to aircraft. Since 1953, 88 encounters between airplanes and ash clouds have been documented worldwide (International Civil Aviation Organization, 2015, appendix F), resulting in aircraft damage and, in 9 cases, engine failure (Guffanti and others, 2010). In 1982, two large passenger planes suffered complete engine failure owing to eruptions in Indonesia (Global Volcanism Program, 1982) and a similar incident occurred over Alaska in 1989 (Casadevall, 1994). In all three cases, they were able to restart some engine capability and land safely once they emerged from the ash clouds, although with substantial damage (Guffanti and others, 2010). The clear threat to aviation has led to establishment of nine Volcanic Ash Advisory Centers (VAAC) around the world to monitor and rapidly disseminate information about volcanic eruptions to the aviation community. U.S. Geological Survey (USGS) volcano observatories issue the Volcano Observatory Notice for Aviation that informs of preeruptive unrest or eruptive activity. When ash-producing eruptions do occur, volcano observatories work closely with their regional VAAC to ensure consistency and accuracy in eruption onset time, cloud altitude, ash production, and duration as reported in Volcanic Ash Advisories. Explosive volcanism in the United States and Commonwealth of the Northern Mariana Islands prompts 50–100 such advisories in any given year (table J1). This collaborative effort is greatly aided by USGS detection and monitoring of eruption clouds to ensure a timely and coordinated response. To support these efforts to provide guidance on ash transport and fallout, the USGS developed the Ash3d volcanic ash dispersion model ( https://vsc-ash.wr.usgs.gov/ash3d-gui ) (Schwaiger and others, 2012). Automated simulations are run daily by the USGS for volcanoes that are in elevated states of unrest, and in response mode when eruptions occur. During eruptions, the model output is provided to local National Weather Service Weather Forecast Offices to guide them in the issuance of their information products (such as special weather statements, ashfall advisories, or ashfall warnings), as well as to State and local governments and the public. Characterization of the eruption source is needed to estimate the parameters used to initialize the Ash3d model, and by the Anchorage and Washington VAACs to initialize other dispersion models that inform forecasts for the airborne volcanic cloud. The source parameters that can be provided by observation during an eruption include eruption start time, eruption cloud height over time, and eruption duration. Other, nonobservable source parameters, such as mass eruption rate and grain-size distribution, are based on empirical correlations and study of historical deposits. The goal is to provide a time series of cloud heights, mass eruption rates, and particle-size distributions that accurately reflects current conditions. When feasible, the USGS also provides guidance on the nature of ongoing eruptions and forecasts future activity using petrologic monitoring of collected tephra samples. The aims of providing accurate observable parameters are achieved through analysis of (1) near-real-time meteorological satellite data, (2) ground-based cameras (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–G, 11 p., https://doi.org/10.3133/sir20245062g.">chapter G , this volume; Orr and others, 2024), (3) weather radar, (4) volcanic lightning detection, and (5) ground-based ash sensors and sampling. Explosive eruptions can be detected by a variety of geophysical monitoring, including infrasound (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–C, 11 p., https://doi.org/10.3133/sir20245062c.">chapter C , this volume; Lyons and others, 2024) and seismicity (see of Flinders, A.F., Lowenstern, J.B., Coombs, M.L., and Poland, M.P., eds., Recommended capabilities and instrumentation for volcano monitoring in the United States: U.S. Geological Survey Scientific Investigations Report 2024–5062–B, 9 p., https://doi.org/10.3133/sir20245062b.">chapter B , this volume; Thelen and others, 2024). However, those methods cannot quantify the altitude, ash content, and dispersal dynamics of resulting volcanic clouds. Ideally, all available sources of monitoring data are synthesized to develop a coherent understanding of eruptive activity. The guidance summarized here provides a framework for characterizing volcanic clouds in the atmosphere and tracking the evolution of explosive eruption dynamics.

Scientific Investigations Report↗

USGS1977

Application of Sr and O isotope relations to the petrogenesis of the alkaline rocks of the Red Hill complex, New Hampshire, USA

The Red Hill ring complex in central New Hampshire is composed of apparently cogenetic syenites, nepheline-sodalite syenite, and granite. The ages and petrogenetic relations among five of the six recognized units have been investigated by rubidiumstrontium and oxygen isotope analysis of whole rocks and separated minerals. Whole-rock samples from three syenite units are consistent with a single Rb-Sr isochron which gives an age of 198??3 m.y. and an initial (87Sr/86Sr)o ratio of 0.70330??0.00016 (??2 sigma; ??=1.42?? 10-11y-1). However, Sr isotope data for two other units, nepheline syenite and granite, are not consistent with this isochron but rather indicate higher initial ratios which range from 0.7033 to about 0.707. Whole-rock O isotope analyses give ??18O values which range from+6.2 to+9.3??? Sr and O isotope analyses on mineral separates indicate that observed whole-rock variations in (87Sr/86Sr)o are primary and are not due to any secondary process. The fact that the isotope systematics correlate with rock type, suggests that crustal interaction is likely to have played a significant role in the development of this over-and undersaturated association. Such process(es), while still not fully delineated, could be of fundamental importance to the genesis of associations of critically undersaturated and oversaturated intrusives. The data support the idea that interaction between magmas and crustal materials strongly influenced the compositional relations of similar complexes elsewhere including those of the White Mountain magma series. ?? 1977 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2005

Petrology, mineralogy and geochemistry of mined coals, western Venezuela

Upper Paleocene to middle Miocene coal samples collected from active mines in the western Venezuelan States of Táchira, Mérida and Zulia have been characterized through an integrated geochemical, mineralogical and petrographic investigation. Proximate, ultimate, calorific and forms of sulfur values, major and trace element, vitrinite reflectance, maceral concentrations and mineral matter content have been determined for 16 channel samples from 14 mines. Ash yield generally is low, ranging from < 1 to 17 wt.% (mean = 5 wt.%) on a dry basis (db). Total sulfur content is low to moderate, ranging from 1 to 6 wt.%, db (average = 1.7 wt.%). Calorific value ranges from 25.21 to 37.21 MJ/kg (10,840–16,000 Btu/lb) on a moist, mineral-matter-free basis (average = 33.25 MJ/kg, 14,300 Btu/lb), placing most of the coal samples in the apparent rank classification of high-volatile bituminous. Most of the coal samples exhibit favorable characteristics on the various indices developed to predict combustion and coking behavior and concentrations of possible environmentally sensitive elements (As, Be, Cd, Cr, Co, Hg, Mn, Ni, Pb, Sb, Se, Th and U) generally are similar to the concentrations of these elements in most coals of the world, with one or two exceptions. Concentrations of the liptinite maceral group range from < 1% to 70 vol.%. Five samples contain > 20 vol.% liptinite, dominated by the macerals bituminite and sporinite. Collotelinite dominates the vitrinite group; telinite was observed in quantities of ≤ 1 vol.% despite efforts to better quantify this maceral by etching the sample pellets in potassium permanganate and also by exposure in an oxygen plasma chamber. Inertinite group macerals typically represent < 10 vol.% of the coal samples and the highest concentrations of inertinite macerals are found in distantly spaced (> 400 km) upper Paleocene coal samples from opposite sides of Lago de Maracaibo, possibly indicating tectonic controls on subsidence related to construction of the Andean orogen. Values of maximum reflectance of vitrinite in oil ( R o max ) range between 0.42% and 0.85% and generally are consistent with the high-volatile bituminous rank classification obtained through ASTM methods. X-ray diffraction analyses of low-temperature ash residues indicate that kaolinite, quartz, illite and pyrite dominate the inorganic fraction of most samples; plagioclase, potassium feldspar, calcite, siderite, ankerite, marcasite, rutile, anatase and apatite are present in minor or trace concentrations. Semiquantitative values of volume percent pyrite content show a strong correlation with pyritic sulfur and some sulfide-hosted trace element concentrations (As and Hg). This work provides a modern quality dataset for the western Venezuela coal deposits currently being exploited and will serve as the foundation for an ongoing coal quality research program in Venezuela.

International Journal of Coal Geology↗

USGS2012

Petrology and comparative thermal and mechanical histories of clasts in breccia 62236

Lunar breccia 62236 contains large lithic fragments of troctolite, norite, and anorthosite. The mafic phases, olivine, inverted pigeonite, and augite, fill interstitial areas between larger plagioclases and appear to be cumulate phases with extensive adcumulus growth. Pyroxene compositional homogeneity indicates that cation exchange during cooling was limited to an area of about 1 mm. Primary augite and pigeonite both contain 30 μm-wide lamellae of the other along ‘001’. Pigeonite inverted to orthopyroxene without retaining any crystallographic orientation and subsequently exsolved fine lamellae of augite on (100). Profiles across orthopyroxene-augite interfaces obtained in the analytical transmission electron microscope show an increase of ∼5% wollastonite in augite within 0.5 μm of the interface, suggesting that short-range cation exchange continued to temperatures below 500°C. The entire sample has undergone heterogeneous shock deformation. Shock melting of the troctolitic clast suggests pressures of 200–300 kb and well-developed basal twinning in augite from the norite clasts suggests pressures of 50–300 kbars. The present evidence indicates that 62236 contains parts of a slowly cooled microlayered adcumulate that has been heterogeneously shocked several times and combined into the present breccia.

Journal of Geophysical Research Solid Earth↗

USGS1978

Origin of a South Texas roll-type deposit; II, Sulfide petrology and sulfur isotope studies

Petrologic and sulfur isotopic studies have been carried out on drill core samples from a roll-type uranium deposit in the mid-Tertiary Catahoula Tuff, Webb County, south Texas. Epigenetic iron disulfide minerals formed in two distinct stages. The first stage involved sulfidization of the host rock by sulfide (H 2 S, HS-)-bearing solutions that emanated from a fault about 1.5 km downdip from and subparallel to the orebody. Pyrite was the dominant iron disulfide mineral formed from this fault sulfide. The isotopic composition (delta 34 S) of first-stage iron disulfide is quite heavy (>0 per mil), in part because the fault-derived H 2 S was isotopically heavy. The development of the second-stage sulfides was related to processes that formed the uranium roll. Iron disulfide minerals produced during this second stage commonly occur as rims around the first-stage sulfides. The rims are exclusively marcasite in and adjacent to ore, but the pyrite content in these rims increases with increasing distance from ore. The sulfur of the second-stage sulfides in the vicinity of the roll front is isotopically light (--25 to --40 per mil). The virtual absence of organic carbon in the host sand precludes a bacterial origin for the ore-stage iron disulfide minerals and, therefore, eliminates bacterial metabolism as the mechanism for isotopic fractionation. Instead, the sulfur source for ore-stage sulfides was preore (first stage) sulfides, remobilized via partial oxidation to soluble metastable sulfur oxyanions.

Texas↗

USGS2013

Melts of garnet lherzolite: experiments, models and comparison to melts of pyroxenite and carbonated lherzolite

Phase equilibrium experiments on a compositionally modified olivine leucitite from the Tibetan plateau have been carried out from 2.2 to 2.8 GPa and 1,380–1,480 °C. The experiments-produced liquids multiply saturated with spinel and garnet lherzolite phase assemblages (olivine, orthopyroxene, clinopyroxene and spinel ± garnet) under nominally anhydrous conditions. These SiO 2 -undersaturated liquids and published experimental data are utilized to develop a predictive model for garnet lherzolite melting of compositionally variable mantle under anhydrous conditions over the pressure range of 1.9–6 GPa. The model estimates the major element compositions of garnet-saturated melts for a range of mantle lherzolite compositions and predicts the conditions of the spinel to garnet lherzolite phase transition for natural peridotite compositions at above-solidus temperatures and pressures. We compare our predicted garnet lherzolite melts to those of pyroxenite and carbonated lherzolite and develop criteria for distinguishing among melts of these different source types. We also use the model in conjunction with a published predictive model for plagioclase and spinel lherzolite to characterize the differences in major element composition for melts in the plagioclase, spinel and garnet facies and develop tests to distinguish between melts of these three lherzolite facies based on major elements. The model is applied to understand the source materials and conditions of melting for high-K lavas erupted in the Tibetan plateau, basanite–nephelinite lavas erupted early in the evolution of Kilauea volcano, Hawaii, as well as younger tholeiitic to alkali lavas from Kilauea.

Contributions to Mineralogy and Petrology↗

USGS1973

Oxidation during magmatic differentiation, Finnmarka Complex, Oslo area, Norway: Part 2, the mafic silicates

Electron-microprobe analyses are presented for pyroxene, amphibole, and biotite from monzonite, granodiorite, and granite at Finnmarka, Norway. Compositional trends measured in biotite, present in all three rock types, and in amphibole, present in the monzonite and granodiorite, are markedly atypical and are interpreted as reflecting crystallization under progressively more oxidizing conditions. The average Fe/Fe + Mg for biotites from successively more silicic rock types changes from 0.64 → 0.35 → 0.28, and for amphiboles changes from 0.58 in the monzonite to 0.29 in the granodiorite. Analyses of selected areas within amphibole grains in the granodiorite show marked chemical variations, although single-crystal X-ray photographs are sharp and do not reveal multiple phases. On the basis of 33 such analyses, four coupled substitutions are identified as operative; the most unusual finding is the relation of 1 Ti cation to 4 Al IV cations in the unit cell. Variations within individual amphibole grains of the granodiorite resemble changes noted in evolution of amphibole composition from monzonite to granodiorite and are interpreted as reflecting progressive oxidation. Consideration of these data for the mafic silicates, data for the opaque oxides, and the extensive formation of sphene in the granodiorite, has allowed development of schematic reactions and an overall picture of magmatic environment and evolution at Finnmarka. Crystallization apparently took place at PH 2 o of 1000 bars or less and a temperature of about 700 °C. The trend of oxidation during differentiation is more extreme than any heretofore reported. Amphiboles, as well as biotites, may participate in oxidation reactions and may reflect the oxidation-reduction processes that occurred during magmatic evolution.

Oslo↗

USGS2004

Neoproterozoic A-type granitoids of the central and southern Appalachians: Intraplate magmatism associated with episodic rifting of the Rodinian supercontinent

Emplacement of compositionally distinctive granitic plutons accompanied two pulses (765-680 and 620-550Ma) of crustal extension that affected the Rodinian craton at the present location of the central Appalachians during the Neoproterozoic. The dominantly metaluminous plutons display mineralogical and geochemical characteristics of A-type granites including high FeO t/MgO ratios, high abundances of Nb, Zr, Y, Ta, and REE (except Eu), and low concentrations of Sc, Ba, Sr, and Eu. These dike-like, sheet complexes occur throughout the Blue Ridge province of Virginia and North Carolina, and were emplaced at shallow levels in continental crust during active extension, forming locally multiple-intrusive plutons elongated perpendicular to the axis of extension. New U-Pb zircon ages obtained from the Polly Wright Cove (706??4Ma) and Suck Mountain (680??4Ma) plutons indicate that metaluminous magmas continued to be replenished near the end of the first pulse of rifting. The Suck Mountain body is presently the youngest known igneous body associated with earlier rifting. U-Pb zircon ages for the Pound Ridge Granite Gneiss (562??5Ma) and Yonkers Gneiss (563??2Ma) in the Manhattan prong of southeastern New York constitute the first evidence of plutonic felsic activity associated with the later period of rifting in the U.S. Appalachians, and suggest that similar melt-generation processes were operative during both intervals of crustal extension. Fractionation processes involving primary minerals were responsible for much of the compositional variation within individual plutons. Compositions of mapped lithologic units in a subset of plutons studied in detail define overlapping data arrays, indicating that, throughout the province, similar petrologic processes operated locally on magmas that became successively more chemically evolved. Limited variation in source-sensitive Y/Nb and Yb/Ta ratios is consistent with results of melting experiments and indicates that metaluminous granitoids of the supersuite likely were derived through melting of lower crustal sources. Mildly peralkaline rocks of the Robertson River batholith and Irish Creek pluton may be derived from more chemically primitive sources similar in composition to ocean-island basalts. Blue Ridge granitoids define a plutonic episode that occurred during an unsuccessful pulse of crustal extension which predated opening of Iapetus by more than 100 million years. Granitoid gneisses in New York were emplaced during an extension-related, dominantly mafic magmatic episode that ultimately led to development of Iapetus. ?? 2003 Elsevier B.V. All rights reserved.

Precambrian Research↗

USGS2017

Constraining the magmatic system at Mount St. Helens (2004–2008) using Bayesian inversion with physics-based models including gas escape and crystallization

Physics-based models of volcanic eruptions track conduit processes as functions of depth and time. When used in inversions, these models permit integration of diverse geological and geophysical data sets to constrain important parameters of magmatic systems. We develop a 1-D steady state conduit model for effusive eruptions including equilibrium crystallization and gas transport through the conduit and compare with the quasi-steady dome growth phase of Mount St. Helens in 2005. Viscosity increase resulting from pressure-dependent crystallization leads to a natural transition from viscous flow to frictional sliding on the conduit margin. Erupted mass flux depends strongly on wall rock and magma permeabilities due to their impact on magma density. Including both lateral and vertical gas transport reveals competing effects that produce nonmonotonic behavior in the mass flux when increasing magma permeability. Using this physics-based model in a Bayesian inversion, we link data sets from Mount St. Helens such as extrusion flux and earthquake depths with petrological data to estimate unknown model parameters, including magma chamber pressure and water content, magma permeability constants, conduit radius, and friction along the conduit walls. Even with this relatively simple model and limited data, we obtain improved constraints on important model parameters. We find that the magma chamber had low (<5wt%) total volatiles and that the magma permeability scale is well constrained at ~10-11.4 m2 to reproduce observed dome rock porosities. Compared with previous results, higher magma overpressure and lower wall friction are required to compensate for increased viscous resistance while keeping extrusion rate at the observed value.

Washington↗

USGS1971

Structure and petrology of the alpine-type peridotite at Burro Mountain, California, U.S.A.

The alpine-type peridotite at Burro Mountain is a partially serpentinized harzburgite-dunite body approximately 2 km in diameter. It lies in a chaotic mélange derived from the Franciscan Formation (Upper Jurassic to Upper Cretaceous) of the southern Coast Ranges of California. The peridotite is bounded on the east by a vertical fault in the Nacimiento fault zone that brings sedimentary rocks of Taliaferro's (1943 b ) Asuncion Group (Upper Cretaceous) into contact with the peridotite. The peridotite appears to be one of a number of tectonic lenses, having a wide range in size, that make up the mélange . These lenses include metagraywacke, metachert, greenstone, amphibolite, and blueschist, as well as ultramafic rocks, and represent a wide range of pressure-temperature environments. The outer shell of the peridotite is a sheared serpentinite zone 10–15 m thick. The peridotite was tectonically emplaced at its present level as a cold solid mass and had little effect on the mineral assemblages of the Franciscan Formation. Local development of lawsonite and aragonite in shear zones may be related to the peridotite emplacement. Foliated harzburgite forms approximately 60 per cent of the peridotite. It is a lithologically uniform rock that has an olivine: orthopyroxene ratio of approximately 75:25. Accessory clinopyroxene and chromian spinel generally make up less than 5 per cent of the harzburgite. Dunite, composed of olivine, accessory chromian spinel (< 5 per cent), and trace amounts of pyroxene, makes up approximately 40 per cent of the peridotite and occurs as dikes, sills, and irregular bodies in the harzburgite. Olivine and pyroxene show small but significant compositional variations and chromian spinel shows a large range in the cation ratio Cr/(Cr+Al+ Fe 3+ ). The compositional variations in these minerals are related to original differences in bulk chemical composition. The following compositional ranges were determined for minerals in the harzburgite: olivine, Fo 91.1 −Fo 91.4 ; orthopyroxene, En 89.8 −En 91.1 ; clinopyroxene, Ca 47.0 Mg 50.0 Fe 3.0 −Ca 48.7 Mg 48.2 Fe 3.1 ; chromian spinel, Cr/(Cr+Al+Fe 3+ ) 0.37−0.55. The pyroxenes have a range in A1 2 O 3 content of 1.3−3.0 wt per cent. Olivine from dunite ranges from Fo 91 to Fo 92 7 and the chromian spinel has a range in the Cr/(Cr+Al+Fe 3+ ) ratio of 0.30−0.75. Although all the dunites are lithologically similar, three distinct types are recognized on the basis of composition of coexisting olivine and chromian spinel. Structural relations between the three types of dunite suggest three periods of emplacement (possibly overlapping) of dunite into harzburgite. The evidence indicates that the dunite, and probably also the harzburgite crystallized from an ultramafic magma, probably in the upper mantle. After the magmatic episode and crystallization, the peridotite was subjected to a deep-seated plastic deformation and recrystallization. The first phase of the deformation produced a pervasive, planar structural element (S 1 ) that crosscuts many harzburgite-dunite contacts. It is probable that some of the dunite sills were emplaced during this deformation. The foliation, S 1 , is defined by layers of different orthopyroxene content in harzburgite, and by discontinuous layers of chromian spinel in dunite. Flow or slip along S 1 produced slip folds in harzburgite—dunite contacts with axial planes parallel to S 1 . At a later stage, isoclinal folds developed in S 1 , and the present olivine microfabric was probably formed by recrystallization in the stress field that produced the isoclinal folding. In the olivine microfabric, X tends to be perpendicular to the axial planes (S 2 ) of the isoclinal folds and Y and Z tend to form double maxima in S 2 approximately 90° apart. Mg−Fe 2+ distribution between coexisting mineral pairs yields a calculated temperature of formation of approximately 1200 °C. Although this temperature is only a nominal value, it indicates that the mineral pairs equilibrated at a significantly high temperature. In view of the deformation and recrystallization, the calculated temperature possibly represents subsolidus re-equilibration of the minerals during this event. The deformation and recrystallization probably occurred shortly after crystallization while the peridotite was still at a high temperature. A later deep-seated deformation produced small scattered kink folds in S 1 that tend to disrupt the major olivine microfabric. The kink folding was accompanied or followed by the development of kink bands in olivine that reflect intragranular gliding on the system T = [ Okl ], t = [100]. The kink bands probably formed at a minimum temperature of 1000 °C. Following the deep-seated deformation, which probably took place in the mantle, the peridotite mass was tectonically detached and moved upward to its present level in the crust. Cleavages, joints, and faults provided channels for water to pervade the peridotite and allow alteration of the primary minerals.

California↗

USGS2006

U.S. Geological Survey and Bureau of Land Management Cooperative Coalbed Methane Project in the Powder River Basin, Wyoming

The Bureau of Land Management (BLM) Wyoming Reservoir Management Group and the U.S. Geological Survey (USGS) began a cooperative project in 1999 to collect technical and analytical data on coalbed methane (CBM) resources and quality of the water produced from coalbeds in the Wyoming part of the Powder River Basin. The agencies have complementary but divergent goals and these kinds of data are essential to accomplish their respective resource evaluation and management tasks. The project also addresses the general public need for information pertaining to Powder River Basin CBM resources and development. BLM needs, which relate primarily to the management of CBM resources, include improved gas content and gas in-place estimates for reservoir characterization and resource/reserve assessment, evaluation, and utilization. USGS goals include a basinwide assessment of CBM resources, an improved understanding of the nature and origin of coalbed gases and formation waters, and the development of predictive models for the assessment of CBM resources that can be used for such purposes in other basins in the United States (for example, the Bighorn, Greater Green River, and Williston Basins) and in other countries throughout the world (for example, Indonesia, New Zealand, and the Philippines). Samples of coal, produced water, and gas from coalbed methane drill holes throughout the Powder River Basin, many of which are adjacent to several active mine areas (figs. 1, 2), have been collected by personnel in the USGS, BLM Reservoir Management Group, and Casper and Buffalo BLM Field Offices. Sampling was done under confidentiality agreements with 29 participating CBM companies and operators. Analyses run on the samples include coal permeability, coal quality and chemistry, coal petrography and petrology, methane desorption and adsorption, produced-water chemistry, and gas composition and isotopes. The USGS has supplied results to the BLM Reservoir Management Group for their resource management needs, and data are released when the terms of the confidentiality agreements are completed and consent is obtained.

Fact Sheet↗

USGS2009

Low-fluorine Stockwork Molybdenite Deposits

Low-fluorine stockwork molybdenite deposits are closely related to porphyry copper deposits, being similar in their tectonic setting (continental volcanic arc) and the petrology (calc-alkaline) of associated igneous rock types. They are mainly restricted to the Cordillera of western Canada and the northwest United States, and their distribution elsewhere in the world may be limited. The deposits consist of stockwork bodies of molybdenite-bearing quartz veinlets that are present in and around the upper parts of intermediate to felsic intrusions. The deposits are relatively low grade (0.05 to 0.2 percent Mo), but relatively large, commonly >50 million tons. The source plutons for these deposits range from granodiorite to granite in composition; the deposits primarily form in continental margin subduction-related magmatic arcs, often concurrent with formation of nearby porphyry copper deposits. Oxidation of pyrite in unmined deposits or in tailings and waste rock during weathering can lead to development of acid-rock drainage and limonite-rich gossans. Waters associated with low-fluorine stockwork molybdenite deposits tend to be nearly neutral in pH; variable in concentrations of molybdenum (<2 to >10,000 ug/L); below regulatory guidelines for copper, iron, lead, zinc, and mercury; and locally may exceed guidelines for arsenic, cadmium, and selenium.

Open-File Report↗

USGS1991

A lead isotopic study of the Stillwater Complex, Montana: constraints on crustal contamination and source regions

Analyses of the Pb isotopic compositions of plagioclase from 23 samples covering the stratigraphic thickness of the Stillwater Complex indicate a narrow range of apparent initial isotopic compositions (206Pb/ 204Pb=13.95; 207Pb/204Pb=14.95-15.01; 208Pb/204Pb=33.6). The uniformity of our data is in contrast to, but not necessarily contradictory to, other recent investigations which give indications that the complex formed by repeated injection of magmas with at least two distinct compositions that were presumably derived from different source regions. Samples from the Basal series of the complex have consistently higher 207Pb/204Pb ratios, suggesting either minor contamination from adjacent country rocks or a slight distinction between parental magmas. Apparent initial Pb isotopic compositions of the complex are very radiogenic compared to Late Archean model-mantle values, but are nearly identical to initial Pb isotopic compositions found for the the adjacent, slightly older (2.73-2.79 Ga), Late Archean crustal suite in the Beartooth Mountains. Contamination of magmas parental to the Stillwater Complex by the Late Archean crustal suite is rejected for two reasons: (1) Th and U concentrations in Stillwater rocks and plagioclase are very low (about 0.08 and 0.02 ppm respectively), yet Th/U ratios are uniform at about 4, in contrast to the highly variable (2-26) but often high Th/U ratios found for the Late Archean crustal complex; (2) it seems improbable that any contamination process would have adjusted the isotopic compositions of the diverse magmas entering the Stillwater chamber to near-identical values. The preferred hypothesis to explain the Pb isotopic data for the Stillwater Complex and the associated Late Archean crustal suite involves a major Late Archean crust-forming event that resulted in a compositionally complex crust/mantle system with relatively homogeneous and unusual Pb isotopic compositions. The parental magmas of the Stillwater Complex were generated at different levels within this crust/mantle system, before isotopic contrasts could develop by radioactive decay within compositionally discrete reservoirs. This situation limits the utility of all isotopic tracer systems in discriminating among the various mantle and crustal reservoirs that may have affected the final isotopic character of the Stillwater magmas. The late Archean crustal complex and the Stillwater Complex melts were ultimately derived from the same distinct mantle without obvious direct interaction with the Middle to Early Archean crust present in the region. ?? 1991 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2006

Protolith and metamorphic ages of the Haiyangsuo Complex, eastern China: A non-UHP exotic tectonic slab in the Sulu ultrahigh-pressure terrane

The Haiyangsuo Complex in the NE Sulu ultrahigh-pressure (UHP) terrane has discontinuous, coastal exposures of Late Archean gneiss with amphibolitized granulite, amphibolite, Paleoproterozoic metagabbroic intrusives, and Cretaceous granitic dikes over an area of about 15 km2. The U-Pb SHRIMP dating of zircons indicates that theprotolith age of a garnet-biotite gneiss is >2500 Ma, whereas the granulite-facie metamorphism occurred at around 1800 Ma. A gabbroic intrusion was dated at ???1730 Ma, and the formation of amphibolite-facies assemblages in both metagabbro and granulite occurred at ???340-460 Ma. Petrologic and geochronological data indicate that these various rocks show no evidence of Triassic eclogite-facies metamorphism and Neoproterozoic protolith ages that are characteristics of Sulu-Dabie HP-UHP rocks, except Neoproterozoic inherited ages from post-collisional Jurassic granitic dikes. Haiyangsuo retrograde granulites with amphibolite-facies assemblages within the gneiss preserve relict garnet formed during granulite-facies metamorphism at ???1.85 Ga. The Paleoproterozoic metamorphic events are almost coeval with gabbroic intrusions. The granulite-bearing gneiss unit and gabbro-dominated unit of the Haiyangsuo Complex were intruded by thin granitic dikes at about 160 Ma, which is coeval with post-collisional granitic intrusions in the Sulu terrane. We suggest that the Haiyangsuo Complex may represent a fragment of the Jiao-Liao-Ji Paleoproterozoic terrane developed at the eastern margin of the Sino-Korean basement, which was juxtaposed with the Sulu terrane prior to Jurassic granitic activity and regional deformation. ?? Springer-Verlag 2006.

Conference Paper↗

USGS1990

H, O, Sr, Nd, and Pb isotope geochemistry of the Latir volcanic field and cogenetic intrusions, New Mexico, and relations between evolution of a continental magmatic center and modifications of the lithosphere

Over 200 H, O, Sr, Nd, and Pb isotope analyses, in addition to geologic and petrologic constraints, document the magmatic evolution of the 28.5-19 Ma Latir volcanic field and associated intrusive rocks, which includes multiple stages of crustal assimilation, magma mixing, protracted crystallization, and open- and closed-system evolution in the upper crust. In contrast to data from younger volcanic centers in northern New Mexico, relatively low and restricted primary ??18O values (+6.4 to +7.4) rule out assimilation of supracrustal rocks enriched in 18O. Initial 87Sr/86Sr ratios (0.705 to 0.708), ??18O values (-2 to-7), and 206Pb/204Pb ratios (17.5 to 18.4) of metaluminous precaldera volcanic rocks and postcaldera plutonic rocks suggest that most Latir rocks were generated by fractional crystallization of substantial volumes of mantle-derived basaltic magma that had near-chondritic Nd isotope ratios, accompanied by assimilation of crustal material in two main stages: 1) assimilation of non-radiogenic lower crust, followed by 2) assimilation of middle and upper crust by inter-mediate-composition magmas that had been contaminated during the first stage. Magmatic evolution in the upper crust peaked with eruption of the peralkaline Amalia Tuff (???26 Ma), which evolved from metaluminous parental magmas. A third stage of late, roofward assimilation of Proterozoic rocks in the Amalia Tuff magma is indicated by trends in initial 87Sr/86Sr and 206Pb/204Pb ratios from 0.7057 to 0.7098 and 19.5 to 18.8, respectively, toward the top of the pre-eruptive magma chamber. Highly evolved postcaldera plutons are generally fine grained and are zoned in initial 87Sr/86Sr and 206Pb/204Pb ratios, varying from 0.705 to 0.709 and 17.8 to 18.6, respectively. In contrast, the coarser-grained Cabresto Lake (???25 Ma) and Rio Hondo (???21 Ma) plutons have relatively homogeneous initial 87Sr/86Sr and 206Pb/204Pb ratios of approximately 0.7053 and 17.94 and 17.55, respectively. ??18O values for all the postcaldera plutons overlap those of the precaldera rocks and Amalia Tuff, except for those for two late-stage rhyolite dikes associated with the Rio Hondo pluton that have ??18O values of-8.6 and-9.5; these dikes are the only Latir rocks which may be largely crustal melts. Chemical and isotopic data from the Latir field suggest that large fluxes of mantle-derived basaltic magma are necessary for developing and sustaining large-volume volcanic centers. Development of a detailed model suggests that 6-15 km of new crust may have been added beneath the volcanic center; such an addition may result in significant changes in the chemical and Sr and Nd isotopic compositions of the crust, although Pb isotope ratios will remain relatively unchanged. If accompanied by assimilation, crystallization of pooled basaltic magma near the MOHO may produce substantial cumulates beneath the MOHO that generate large changes in the isotopic composition of the upper mantle. The Latir field may be similar to other large-volume, long-lived intracratonal volcanic fields that fundamentally owe their origins to extensive injection of basaltic magma into the lower parts of their magmatic systems. Such fields may overlie areas of significant crustal growth and hybridization. ?? 1990 Springer-Verlag.

Contributions to Mineralogy and Petrology↗