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At least 1,063 records · Page 59Linked to original sources

Sequestration of non-pure carbon dioxide streams in iron oxyhydroxide-containing saline repositories

Iron oxyhydroxide, goethite (α-FeOOH), was evaluated as a potential formation mineral reactant for trapping CO 2 in a mineral phase such as siderite (FeCO 3 ), when a mixture of CO 2 -SO 2 flue gas is injected into a saline aquifer. Two thermodynamic simulations were conducted, equilibrating a CO 2 -SO 2 fluid mixture with a NaCl-brine and Fe-rich rocks at 150 °C and 300 bar. The modeling studies evaluated mineral and fluid composition at equilibrium and the influence of pH buffering in the system. Results show siderite precipitates both in the buffered and unbuffered system; however, the presence of an alkaline pH buffer enhances the stability of the carbonate. Based on the model, an experiment was designed to compare with thermodynamic predictions. A CO 2 -SO 2 gas mixture was reacted in 150 ml of NaCl-NaOH brine containing 10 g of goethite at 150 °C and 300 bar for 24 days. Mineralogical and brine chemistry confirmed siderite as the predominant reaction product in the system. Seventy-six mg of CO 2 are sequestered in siderite per 10 g of goethite.

International Journal of Greenhouse Gas Control↗

Saltwater intrusion in the Floridan aquifer system near downtown Brunswick, Georgia, 1957–2015

Introduction The Floridan aquifer system (FAS) consists of the Upper Floridan aquifer (UFA), an intervening confining unit of highly variable properties, and the Lower Floridan aquifer (LFA). The UFA and LFA are primarily composed of Paleocene- to Oligocene-age carbonate rocks that include, locally, Upper Cretaceous rocks. The FAS extends from coastal areas in southeastern South Carolina and continues southward and westward across the coastal plain of Georgia and Alabama, and underlies all of Florida. The thickness of the FAS varies from less than 100 feet (ft) in aquifer outcrop areas of South Carolina to about 1,700 ft near the city of Brunswick, Georgia. Locally, in southeastern Georgia and the Brunswick– Glynn County area, the UFA consists of an upper water-bearing zone (UWBZ) and a lower water-bearing zone (LWBZ), as identified by Wait and Gregg (1973), with aquifer test data indicating the upper zone has higher productivity than the lower zone. Near the city of Brunswick, the LFA is composed of two permeable zones: an early middle Eocene-age upper permeable zone (UPZ) and a highly permeable lower zone of limestone (LPZ) of Paleocene and Late Cretaceous age that includes a deeply buried, cavernous, saline water-bearing unit known as the Fernandina permeable zone. Maslia and Prowell (1990) inferred the presence of major northeast–southwest trending faults through the downtown Brunswick area based on structural analysis of geophysical data, northeastward elongation of the potentiometric surface of the UFA, and breaches in the local confining unit that influence the area of chloride contamination. Pronounced horizontal and vertical hydraulic head gradients, caused by pumping in the UFA, allow saline water from the FPZ to migrate upward into the UFA through this system of faults and conduits. Saltwater was first detected in the FAS in wells completed in the UFA near the southern part of the city of Brunswick in late 1957. By the 1970s, a plume of groundwater with high chloride concentrations had migrated northward toward two major industrial pumping centers, and since 1965, chloride concentrations have steadily increased in the northern part of the city. In 1978, data obtained from a 2,720-ft-deep test well (33H188) drilled south of the city showed water with a chloride concentration of 33,000 milligrams per liter (mg/L), suggesting the saltwater source was located below the UFA in the Fernandina permeable zone (FPZ) of the LFA. All U.S. Geological Survey (USGS) data collected for this study, including groundwater levels in wells and water-chemistry data, are available in the USGS National Water Information System.

Georgia↗

Oil and gas resources of the Arctic Alaska Petroleum Province

The Arctic Alaska Petroleum Province, encompassing all the lands and adjacent Continental Shelf areas north of the Brooks Range-Herald arch, is one of the most petroleum-productive areas in the United States, having produced about 15 billion bbl of oil. Seven unitized oil fields currently contribute to production, and three additional oil fields have been unitized but are not yet producing. Most known petroleum accumulations involve structural or combination structural-stratigraphic traps related to closure along the Barrow arch, a regional basement high, which has focused regional hydrocarbon migration since Early Cretaceous time. Several oil accumulations in stratigraphic traps have been developed in recent years. In addition to three small gas fields producing for local consumption, more than 20 additional oil and gas discoveries remain undeveloped. This geologically complex region includes prospective strata within passive-margin, rift, and foreland-basin sequences. Oil and gas were generated from multiple source rocks throughout the region. Although some reservoired oils appear to be derived from a single source rock, evidence for significant mixing of hydrocarbons from multiple source rocks indicates a composite petroleum system. Both extensional and contractional tectonic structures provide ample exploration targets, and recent emphasis on stratigraphic traps has demonstrated a significant resource potential in shelf and turbidite sequences of Jurassic through Tertiary age. Recent estimates of the total mean volume of undiscovered resources in the Arctic Alaska Petroleum Province by the U.S. Geological Survey and U.S. Minerals Management Service are more than 50 billion bbl of oil and natural-gas liquids and 227 trillion ft3 of gas, distributed approximately equally between Federal offshore and combined onshore and State offshore areas.

Alaska↗

Geologic framework and hydrogeologic characteristics of the outcrops of the Edwards and Trinity aquifers, Medina Lake area, Texas

The hydrogeologic subdivisions of the Edwards aquifer outcrop in the Medina Lake area in Medina and Bandera Counties generally are porous and permeable. The most porous and permeable appear to be hydrogeologic subdivision VI, the Kirschberg evaporite member of the Kainer Formation; and hydrogeologic subdivision III, the leached and collapsed members, undivided, of the Person Formation. The porosity of the rocks in the Edwards aquifer outcrop is related to depositional or diagenetic elements along specific stratigraphic horizons (fabric selective) and to dissolution and structural elements that can occur in any lithostratigraphic horizon (not fabric selective). Permeability depends on the physical properties of the rock such as size, shape, and distribution of pores. The Edwards aquifer has relatively large porosity and permeability resulting, in part, from the development or redistribution of secondary porosity. Lithology, stratigraphy, diagenesis, and karstification account for the effective porosity and permeability in the Edwards aquifer outcrop. Karst features that can greatly enhance effective porosity and permeability in the Edwards aquifer outcrop include sinkholes, dolines, and caves. Field observations in the Medina Lake area confirm the findings of previous investigators that Medina Lake mostly overlies rocks of the upper member of the Glen Rose Limestone. The channel downstream of Medina Dam to the upper end of Diversion Lake also overlies the upper member of the Glen Rose Limestone. Most of Diversion Lake overlies a thin section of the Edwards aquifer— hydrogeologic subdivision VIII (basal nodular member) and the basal part of hydrogeologic subdivision VII (dolomitic member). Hydrogeologic subdivisions VIII and VII might be hydraulically connected to Medina Lake at high lake stages. The Trinity aquifer, which crops out in the northern part of the Medina Lake area and underlies the Edwards aquifer in the southern part, is much less permeable and productive than the Edwards aquifer. Where the Trinity aquifer underlies the Edwards, the Trinity acts as a lower confining unit on the Edwards.

Texas↗

Ground water: the hidden resource

Ground water is water underground in saturated zones beneath the land surface. Contrary to popular belief, ground water does not form underground "rivers." It fills the pores and fractures in underground materials such as sand, gravel, and other rock. If ground water flows from rock materials or can be removed by pumping from the saturated rock materials In useful amounts, the rock materials are called aquifers. Ground water moves slowly, typically at rates of 7 to 60 centimeters per day in an aquifer. As a result, water could remain in an aquifer for hundreds or thousands of years. Ground water is the source of about 40 percent of water used for public supplies and about 38 percent of water used for agriculture in the United States.

General Information Product↗

Low temperature basalt alteration by sea water: an experimental study at 70°C and 150°C

Basaltic glass and diabase were reacted with seawater at 70°C at 1 bar and 150°C at 500 bars to determine fluid composition and alteration mineralogy. All experiments were performed at a water/ rock mass ratio of 10. The changes in seawater chemistry depended on temperature and crystallinity of the basalt. The experiment at 70°C produced a slight but continuous loss of Mg, Na and K and enrichment of Ca and SiO 2 in the seawater while pH decreased slowly. At 150°C, in contrast, Mg and SO 4 were quickly and quantitatively removed while Ca, SiO 2 , Na, K, Fe, Mn and Ba were added to the seawater. pH rose to values between 5.5 and 6.5 after an initial drop to lower values. Basalt glass reacted more extensively at 150°C than diabase. Smectite was the major alteration product (iron-rich saponite) at 150°C for both the glass and diabase experiments. Smectite from the diabase experiment was well crystallized while that from the glass experiment was poorly crystallized. The smectites are similar to smectites found in altered oceanic ophiolitic basalts.

Geochimica et Cosmochimica Acta↗

Isotopic and geochemical assessment of the sensitivity of groundwater resources of Guam, Mariana Islands, to intra- and inter-annual variations in hydroclimate

Assessing the sensitivity of groundwater systems to hydroclimate variability is critical to sustainable management of the water resources of Guam, US territory. We assess spatial and temporal variability of isotopic and geochemical compositions of vadose and phreatic groundwater sampled from cave drip sites and production wells, respectively, to better understand the vulnerability of the freshwater lens on Guam to variability in hydroclimate. We independently evaluate the existing conceptual model of the Northern Guam Lens Aquifer that is largely based on physical, as opposed to geochemical, observations. Sampling was conducted from 2008 to 2015, over which rainfall gradually increased. Major ion geochemistry and Sr isotope values of groundwater show varying influence from soil, limestone bedrock, and seawater. Geochemical modeling that can explain spatial variability in groundwater Na+ and Mg2+ concentrations and Sr/Ca and 87Sr/86 Sr values indicates that groundwater compositions are dominantly controlled by mixing of freshwater with seawater and water-rock interaction. Differences between amount-weighted annual average precipitation δ18 O values and groundwater δ18 O values indicate a recharge bias toward the wet season, consistent with other tropical carbonate island aquifer settings. Intra- and inter-annual variations in Na+ concentrations and δ18 O values in groundwater reflect sensitivity of recharge to seasonal variations in rainfall amount and changes in annual rainfall amounts. Our results indicate the influence of multiple modes of recharge on groundwater compositions and spatial variability in the sensitivity of groundwater to seawater mixing. This sensitivity of the freshwater lens points to the vulnerability of groundwater resources to changes in recharge associated with climate, land-use change, and increases in population.

Journal of Hydrology↗

Utica/Point Pleasant brine isotopic compositions (δ7Li, δ11B, δ138Ba) elucidate mechanisms of lithium enrichment in the Appalachian Basin

Global Li production will require a ~500 % increase to meet 2050 projected energy storage demands. One potential source is oil and gas wastewater (i.e., produced water or brine), which naturally has high total dissolved solids (TDS) concentrations, that can also be enriched in Li (>100 mg/L). Understanding the sources and mechanisms responsible for high naturally-occurring Li concentrations can aid in efficient targeting of these brines. The isotopic composition (δ 7 Li, δ 11 B, δ 138 Ba) of produced water and core samples from the Utica Shale and Point Pleasant Formation (UPP) in the Appalachian Basin, USA indicates that depth-dependent thermal maturity and water-rock interaction, including diagenetic clay mineral transformations, likely control Li concentrations. A survey of Li content in produced waters throughout the USA indicates that Appalachian Basin brines from the Marcellus Shale to the UPP have the potential for economic resource recovery.

Maryland, Ohio, Pennsylvania, West Virginia↗

Geology and hydrology for environmental planning in Washtenaw County, Michigan

Washteaw County is underlain by glacial deposits that range in thickness from about 50 feet to about 450 feet. Underlying the glacial deposits are sedimentary rocks of Mississippian and Devonian age. The youngest of these rocks are the sandstones of the Marshall Formation in the western part of the county; the oldest are the limestones of the Detroit River Group in the southeast corner. Sand and gravel deposits in some places in the county may yield more than 500 gallons per minute of water. Approximately 50 percent of the wells tapping the Marshall Formation, the most reliable bedrock aquifer, can yield as much as 60 gallons per minute. Washtenaw County has sand and gravel deposits that are more than 50 feet thick. The deposits are mined in several areas and are of economic importance. In addition, there may be potential for peat production in the western part of the county and for clay production in the eastern part.

Michigan↗

Geologic map of the Paeroa Fault block and surrounding area, Taupo Volcanic Zone, New Zealand

The Taupo Volcanic Zone (TVZ), New Zealand, is the most productive area of explosive silicic volcanism in the world. Faulted early and middle Pleistocene volcanic products are generally concealed beneath voluminous, generally unfaulted, younger volcanic products. An exception is the southeast margin of the TVZ where the two parallel, northeast-trending Paeroa and Te Weta Fault blocks expose Quaternary volcanic products consisting predominantly of caldera-related, rhyolitic ignimbrites and lacustrine sediments. The Taupo-Reporoa Basin is situated along the eastern part of the map area, and its northernmost part underwent collapse to form Reporoa Caldera. The Paeroa Fault block is the largest exposed fault block within the TVZ, and it encompasses early and middle Pleistocene ignimbrites and sedimentary deposits that are buried throughout the Taupo-Reporoa Basin to the east. This map displays the volcanic and sedimentary geology of ~430 km 2 of the Paeroa Fault block and the adjacent Te Weta Fault block at a scale of 1:50,000. Volcanic and sedimentary rocks are divided into the Reporoa Group, Whakamaru Group, and Huka Group (from oldest to youngest), which are overlain by relatively unfaulted late Pleistocene and Holocene surficial volcanic and sedimentary deposits.

Open-File Report↗

Ground-water quality and geochemistry of aquifers associated with coal in the Allegheny and Monongahela formations, southeastern Ohio

Ground water from aquifers associated with coal beds in the Allegheny and Monongahela Formations in southeastern Ohio is predominantly a calcium magnesium bicarbonate type. Sodium bicarbonate type water is less common. Isolated areas of sodium chloride and calcium sulfate types also are present. The water is predominantly very hard, and has a median hardness concentration of 258 milligrams per liter as calcium carbonate and a median dissolved-solids concentration of 436 milligrams per liter. Few wells contain water with dissolved-solids concentrations in excess of 1,000 milligrams per liter. Bicarbonate concentration in ground water was found to be significantly different among coals, whereas concentrations of bicarbonate, hardness, calcium, magnesium, sodium, iron, manganese, and strontium were significantly different between ground water in the Allegheny and Monongahela Formations. Many constituents are significantly correlated, but few correlation coefficients are high. The presence of sulfate or iron is attributed to the kinetic mechanism operating during the oxidation of pyrite. The position along the sulfide or ferrous-iron oxidation pathways controls the reaction products of pyrite found in solution, and the formation of either the sulfate of iron constituents. The availability and rate of diffusion of oxygen in the formations exerts control on the water quality. Discriminant-function analysis correctly classifies 89 percent of the observations into the Allegheny or Monongahela Formations. As a verifications, 39 of 41 observations from another study were correctly classified by formation. The differences in water chemistry between the Allegheny and the Monongahela Formations are gradational and are attributed the oxidation of iron sulfide. The diffusion and availability of oxygen, which controls the chemical reaction, is regulated by the porosity and permeability of the rock with respect to oxygen and the presence or absence of carbonates, which controls the pH.

Water-Resources Investigations Report↗

Hydrologic characteristics of the Madison Limestone, the Minnelusa Formation, and equivalent rocks as determined by well-logging formation evaluation, Wyoming, Montana, South Dakota, and North Dakota

Geophysical logs from wells distributed throughout the Powder River Basin were digitized, processed, and interpreted to get a regional understanding of the lithologic and ground-water characteristics of aquifers in the Madison Limestone and Minnelusa Formation. The percentage of sand, porosity, and apparent ground-water resistivity of the Minnelusa closely follow structural trends in the basin. Values increase from the structural axis of the basin toward the flanks. Close correlations between the water resistivities in the Madison and the Minnelusa indicate possible hydrologic connection between the two units. The low primary porosity from geophysical logs in the Madison indicates that secondary porosity is necessary to develop water supplies of economic importance from the Madison. Because of increased porosity and better water quality, the flanks of the basin appear to be the most favorable places for water production from either the Madison or the Minnelusa.

Wyoming, Montana, South Dakota, North Dakota↗

Geochemistry of thermal waters in Long Valley, Mono County, California

Thermal springs and wells in Long Valley, California, issue sodium bicarbonate‐chloride waters containing 1000–1420 mg/l of dissolved solids. Thermal waters of sodium bicarbonate‐chloride composition are usually associated with hot‐water reservoirs. Chloride concentrations and stable isotope data indicate that the thermal waters have had varied histories. All of the thermal springs issue a mixture of fluid from the thermal reservoir and less saline, cooler water from one or more shallow aquifers. The composition of springs in Hot Creek Gorge may have been further altered by minor subsurface boiling. Thermal springs between Hot Creek and Lake Crowley issue mixtures of fresh and thermal waters which have lost heat by conductive cooling and changed composition by reaction with rock in the shallow aquifer. The silica content of water from Magma Richie 5 and mixing calculations based on the concentrations of silica in thermal waters collected from springs in Hot Creek Gorge and along Little Hot Creek indicate a temperature of at least 200°C in the thermal reservoir. The sodium‐potassium‐calcium geothermometer yields a reservoir temperature estimate near 200°C for most of the thermal springs. If geothermal energy is developed in Long Valley, the high concentrations of arsenic (up to 2.2 mg/l), boron (up to 15 mg/l), and total dissolved solids in the thermal fluids will make it necessary to isolate the effluent of production wells from the freshwater system.

California↗

Water-resources of the Antelope Valley-East Kern Water Agency area, California

The Antelope Valley-East Kern Water Agency (AVEK) area, most of which is within the Mojave Desert region of southern California, lacks adequate water resources to sustain the existing rate of ground-water pumpage for irrigation, industrial, and domestic use. However, by 1972 the California Aqueduct, a part of the California Water Plan, will be completed and will begin to convey water from northern California into the area. The chief economic pursuits in the area are irrigated agriculture and poultry production. At present, the major industries are related to national defense and mining. In the future, industry will increase and probably become the major economic activity. The Mojave Desert region, part of which lies within the AVEK area, is characterized by fault-block mountains and fault-block basins. The Tehachapi and San Gabriel Mountains are the major bordering fault blocks. The adjacent lowland areas of Antelope and Fremont Valleys have been depressed by movements along major faults. There are two major ground-water basins in the AVEK area: Antelope Valley and Fremont Valley basins. Each large basin is divided by faults or bodies of consolidated rock into several groundwater subunits.

California↗

Evaluation of LANDSAT-2 (ERTS) images applied to geologic structures and mineral resources of South America: Type II progress report for period March 14, 1975-June 30, 1975

The author has identified the following significant results. Work with the Image 100 clearly demonstrates that radiance values of LANDSAT data can be used for correlation of geologic formations across international boundaries. The Totora Formation of the Corocoro Group of Tertiary age was traced from known outcrops near Tiahuanaco, Bolivia, along the south side of Lake Titicaca westward into Peru where the same rocks are considered to be Cretaceous in age. This inconsistency suggests: (1) that a review of this formation is needed by joint geological surveys of both countries to determine similarities, differences, and the true age; (2) that recognition of the extension of the copper-bearing Totora Formation of Bolivia into Peru may provide Peru with a new target for exploration. Equal radiance maps made by use of the Image 100 system show as many as eight different units within salar deposits (salt flats) of the Bolivian Altiplano. Standard film processed images show them as nearly uniform areas of white because of lack of dynamic range in film products. The Image 100 system, therefore, appears to be of great assistance in subdividing the salt flats on the basis of moisture distribution, surface roughness, and distribution of windblown materials. Field work is needed to determine these relationships to mineral composition and distribution. Images representing seasonal changes should also improve the accuracy of such maps. Radiance values of alteration zones related to the occurrence of porphyry copper ores were measured at the San Juan del Abra deposit of northern Chile using the Image 100 system. The extent to which these same values may be used to detect similar alteration zones in other areas has not yet been tested.

Bolivian Altiplano, Lake Titicaca↗

Stratiform barite deposits in the Roberts Mountains allochthon, Nevada: A review of potential analogs in modern sea-floor environments

The United States is a net importer of barite, a critical mineral for the oil and gas industry; more than 80 percent of current domestic consumption of barite is imported from China. Nearly all of the domestic production of barite comes from stratiform deposits in Nevada. The 'modern analogs' approach adopted in this review can contribute to improving deposit models and the long-term resource picture in the United States. Massive barite deposits in Nevada are interlayered with deep-water siliceous sedimentary strata of Paleozoic age within the Roberts Mountains Allochthon. Although the barite deposits formed along the long-lived, tectonically active margin of western North America before the Antler orogeny, uncertainty still exists regarding key aspects of their genesis, especially with respect to tectonic setting and depositional processes. Proposed tectonic settings include a continental slope adjacent to an ocean basin, and a rifted basin formed on continental crust. A margin dominated by other stress configurations and strike-slip faulting may also have been present during the Paleozoic. Hypotheses for the genesis of sediment-hosted, stratiform barite deposits in Nevada can be grouped into two categories: (1) a synsedimentary hydrothermal model and (2) an ocean-circulation/productivity-zone model. Both models include a stage involving bacterial reduction of seawater sulfate. Disseminated, diagenetic, and hydrothermal barite deposits are widespread features of the modern ocean. In the Pacific Ocean, disseminated barite deposits (max 9 weight percent BaSO4) are forming below high-productivity zones (for example, in equatorial belts) and on the flanks of ocean ridges (as fallout of 'black smoker' particles). Massive barite deposits of diagenetic (in the subsea floor and at cold seeps) and hydrothermal origins are present in several sediment-covered tectonic settings, including ocean ridges (Escanaba Trough and Guaymas Basin), oceanic transform faults (Blanco Fracture Zone), marginal basins (Sea of Okhotsk), convergent margins (Peru, Oregon, Alaska), and transform margins (California Continental Borderland). Both hydrothermal and diagenetic barite deposits may be present in some environments (for example, the California California Borderland). On the basis of a consideration of tectonic settings and a comparison of deposit attributes (associated rock types, size, structure), mineralogy (BaSO4 content, SiO2 content), and geochemistry (S- and Sr-isotopic ratios) for modern and ancient massive barite deposits, cold seeps along transform margins (or, possibly, marginal basins) represent the most promising present-day metallogenetic analogs for stratiform barite. Hydrothermal systems can also produce high-grade barite, but the ubiquity of associated sulfide mineralization on the modern sea floor (and the paucity of sulfides in Nevada deposits) is problematic. On the basis of data from modern barite deposits, the presence of vent-specific faunas (tubeworms) and the variation in d34S values for barite (related to bacterial reduction of seawater sulfate) may not permit discrimination between a diagenetic or hydrothermal origin for ancient barite deposits.

Nevada↗

Natural gas production and anomalous geothermal gradients of the deep Tuscaloosa Formation

For the largest producing natural gas fields in the onshore Gulf of Mexico Basin, the relation between temperature versus depth was investigated. Prolific natural gas reservoirs with the highest temperatures were found in the Upper Cretaceous downdip Tuscaloosa trend in Louisiana. Temperature and production trends from the deepest field, Judge Digby field, in Pointe Coupe Parish, Louisiana, were investigated to characterize the environment of natural gas in the downdip Tuscaloosa trend. The average production depth in the Judge Digby field is approximately 22,000 ft. Temperatures as high as 400 degrees F are typically found at depth in Judge Digby field and are anomalously low when compared to temperature trends extrapolated to similar depths regionally. At 22,000 ft, the minimum and maximum temperatures for all reservoirs in Gulf Coast producing gas fields are 330 and 550 degrees F, respectively; the average temperature is 430 degrees F. The relatively depressed geothermal gradients in the Judge Digby field may be due to high rates of sediment preservation, which may have delayed the thermal equilibration of the sediment package with respect to the surrounding rock. Analyzing burial history and thermal maturation indicates that the deep Tuscaloosa trend in the Judge Digby field is currently in the gas generation window. Using temperature trends as an exploration tool may have important implications for undiscovered hydrocarbons at greater depths in currently producing reservoirs, and for settings that are geologically analogous to the Judge Digby fiel

Open-File Report↗

Rare earth element deposits in China

China is the world’s leading rare earth element (REE) producer and hosts a variety of deposit types. Carbonatite- related REE deposits, the most significant deposit type, include two giant deposits presently being mined in China, Bayan Obo and Maoniuping, the first and third largest deposits of this type in the world, respectively. The carbonatite-related deposits host the majority of China’s REE resource and are the primary supplier of the world’s light REE. The REE-bearing clay deposits, or ion adsorption-type deposits, are second in importance and are the main source in China for heavy REE resources. Other REE resources include those within monazite or xenotime placers, beach placers, alkaline granites, pegmatites, and hydrothermal veins, as well as some additional deposit types in which REE are recovered as by-products. Carbonatite-related REE deposits in China occur along craton margins, both in rifts (e.g., Bayan Obo) and in reactivated transpressional margins (e.g., Maoniuping). They comprise those along the northern, eastern, and southern margins of the North China block, and along the western margin of the Yangtze block. Major structural features along the craton margins provide first-order controls for REE-related Proterozoic to Cenozoic carbonatite alkaline complexes; these are emplaced in continental margin rifts or strike-slip faults. The ion adsorption-type REE deposits, mainly situated in the South China block, are genetically linked to the weathering of granite and, less commonly, volcanic rocks and lamprophyres. Indosinian (early Mesozoic) and Yanshanian (late Mesozoic) granites are the most important parent rocks for these REE deposits, although Caledonian (early Paleozoic) granites are also of local importance. The primary REE enrichment is hosted in various mineral phases in the igneous rocks and, during the weathering process, the REE are released and adsorbed by clay minerals in the weathering profile. Currently, these REE-rich clays are primarily mined from open-pit operations in southern China. The complex geologic evolution of China’s Precambrian blocks, particularly the long-term subduction of ocean crust below the North and South China blocks, enabled recycling of REE-rich pelagic sediments into mantle lithosphere. This resulted in the REE-enriched nature of the mantle below the Precambrian cratons, which were reactivated and thus essentially decratonized during various tectonic episodes throughout the Proterozoic and Phanerozoic. Deep fault zones within and along the edges of the blocks, including continental rifts and strike-slip faults, provided pathways for upwelling of mantle material.

Book chapter↗