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At least 1,063 records · Page 59Linked to original sources

Present and past ground-water conditions in the Morrison Formation in southwestern Colorado and southeastern Utah

Field and laboratory studies of ground-water conditions in the carnotite-bearing Morrison formation in southwestern Colorado and southeastern Utah were undertaken to determine possible relations between ground waters and the carnotite deposits. The ore-bearing sandstone consists of lenticular sandstone strata, interbedded within discontinuous layers of mudstone; these strata were deposited in a stream environment. The porosity and permeability of the ore-bearing sandstone in one area are relatively low, porosity averaging about 15 percent and permeability ranging between 30 and 3300 millidarcys. Permeability studies in this same area show that sandstone classed as favorable for ore is slightly more permeable than and has nearly twice the transmissibility of sandstone classed as semifavorable; outcrop studies also suggest a lower transmissibility for sandstone that is unfavorable. Samples of water from the ore-bearing and associated strata show considerable variation in chemical charter. These water samples are generally low in uranium, vanadium, copper, and lead, most samples containing less than 1 part per million (ppm) of each metal. General geologic relations suggest that ground-water movement probably was active through the ore-bearing strata during their deposition and shortly afterward. Movement during this time probably occurred largely through the more permeable sand strata and in the general direction of initial dip and stream flow. During Cretaceous time, when several thousand feet of marine sediments accumulated over the Morrison, the water contained in the ore-bearing strata probably was immobile or nearly so and was protected from escape or contamination. Following Tertiary deformation and erosion, active ground-water circulation no doubt was restored, but because of the low permeability and the lenticular character and therefore low transmissibility of the ore-bearing sandstone, ground-water movement probably was slow. Faulting probably also influenced the direction and rate of ground-water movement during Tertiary time. Movement and localization of ground water would permit the concentration of metal-bearing solutions during Salt Wash and early Brushy Basin time in the beds that now contain ore deposits. It is more difficult to explain the formation of these deposits, which have a wide geographic distribution at a restricted stratigraphic position, from solutions circulating through the rocks at a later date. Whatever mode of origin is used to explain the deposits, geologists almost without exception, agree that the metals were transported by solutions that have migrated through the sediments for considerable distances. For this reason, a study of the horizontal and vertical transmissibility characteristics of all exposed sedimentary formations on the Colorado Plateau is planned.

Colorado, Utah↗

Two-dimensional advective transport in ground-water flow parameter estimation

Nonlinear regression is useful in ground-water flow parameter estimation, but problems of parameter insensitivity and correlation often exist given commonly available hydraulic-head and head-dependent flow (for example, stream and lake gain or loss) observations. To address this problem, advective-transport observations are added to the ground-water flow, parameter-estimation model MODFLOWP using particle-tracking methods. The resulting model is used to investigate the importance of advective-transport observations relative to head-dependent flow observations when either or both are used in conjunction with hydraulic-head observations in a simulation of the sewage-discharge plume at Otis Air Force Base, Cape Cod, Massachusetts, USA. The analysis procedure for evaluating the probable effect of new observations on the regression results consists of two steps: (1) parameter sensitivities and correlations calculated at initial parameter values are used to assess the model parameterization and expected relative contributions of different types of observations to the regression; and (2) optimal parameter values are estimated by nonlinear regression and evaluated. In the Cape Cod parameter-estimation model, advective-transport observations did not significantly increase the overall parameter sensitivity; however: (1) inclusion of advective-transport observations decreased parameter correlation enough for more unique parameter values to be estimated by the regression; (2) realistic uncertainties in advective-transport observations had a small effect on parameter estimates relative to the precision with which the parameters were estimated; and (3) the regression results and sensitivity analysis provided insight into the dynamics of the ground-water flow system, especially the importance of accurate boundary conditions. In this work, advective-transport observations improved the calibration of the model and the estimation of ground-water flow parameters, and use of regression and related techniques produced significant insight into the physical system.

Massachusetts↗

Ground-water quality in selected areas serviced by septic tanks, Dade County, Florida

During 1971-74, the U.S. Geological Survey investigated the chemical, physical, bacteriological, and virological characteristics of the ground water in five selected areas serviced by septic tanks in Dade County, Florida. Periodic water samples were collected from multiple-depth groups of monitor wells ranging in depth from 10 to 60 ft at each of the five areas. Analyses of ground water from base-line water-quality wells in inland areas remote from urban development indicated that the ground water is naturally high in organic nitrogen, ammonia, organic carbon and chemical oxygen demand. Some enrichment of ground water with sodium provided a possible key to differentiating septic-tank effluent from other urban ground-water contaminant sources. High ammonia nitrogen, phosphorus, and the repetitive detection of fecal coliform bacteria were characteristic of two 10-foot monitor wells that consistently indicated the presence of septic-tank effluent in ground water. Dispersion, dilution, and various chemical processes have presumably prevented accumulation of septic-tank effluent at depths greater than 20 ft, as indicated by the 65 types of water analyses used in the investigation. Fecal coliform bacteria were present on one or two occasions in many monitor wells but the highest concentration, 1,600 colonies/100 ml, was related to storm-water infiltration rather than septic-tank discharge. Areal variations in the composition and the hydraulic conductivity of the sand and limestone aquifer had the most noticeable influence on the overall ground-water quality. The ground water in the more permeable limestone in south Dade County near Homestead contained low concentrations of septic-tank related constituents, but higher concentrations of dissolved sulfate and nitrate. The ground water in north Dade County, where the aquifer is less permeable, contained the highest dissolved iron, manganese, COD, and organic carbon.

Florida↗

Quality of ground water at selected sites in the upper Mahoning Creek Basin, Pennsylvania

The ground-water quality of the upper Mahoning Creek Basin is largely unknown. Human activities in the basin have altered much of the landscape. The presence of coal mining, oil and gas exploration, agriculture, on-lot septic systems, and commercial development within the basin can introduce contaminants altering the natural chemistry of the ground water. Data collected to document current ground-water quality also can serve as a baseline for comparison of any future water-quality changes by continuing human activities. This report presents the results of a synoptic ground-water-quality sampling in the upper Mahoning Creek Basin. Present ground-water quality in the basin is characterized in relation to published standards, local land-use activities, and other areas with similar natural characteristics.

Fact Sheet↗

Ground-Water Temperature, Noble Gas, and Carbon Isotope Data from the Espanola Basin, New Mexico

Ground-water samples were collected from 56 locations throughout the Espanola Basin and analyzed for general chemistry (major ions and trace elements), carbon isotopes (delta 13C and 14C activity) in dissolved inorganic carbon, noble gases (He, Ne, Ar, Kr, Xe, and 3He/4He ratio), and tritium. Temperature profiles were measured at six locations in the southeastern part of the basin. Temperature profiles suggest that ground water generally becomes warmer with distance from the mountains and that most ground-water flow occurs at depths <250 m below ground surface. The two dominant water types in the basin are Ca/CO3+HCO3 and Na/CO3+HCO3, followed by mixed-cation/CO3+HCO3. Waters generally evolve from Ca/CO3+HCO3 to Na/CO3+HCO3 with increasing residence time through Ca-Na cation exchange with clay minerals. Basin ground water can be divided into four hydrochemical zones based on chemical and isotopic composition: West, Southeast, Northeast, and Central Deep. Hydrochemical zone boundaries are roughly correlated with contacts between geologic units or lithosome transitions within the Tesuque Formation. Geochemical mass-transfer modeling was performed using NETPATH and 14C ages were adjusted accordingly. Isotopic input parameters were varied within reasonable limits to assess uncertainty in the adjusted 14C ages. For each sample, a preferred adjusted age was selected from multiple possible adjusted ages based primarily on the fit between measured and modeled delta 13C values. The range of possible age adjustments for most samples is about 6,000 years or less, indicating that the preferred adjusted age for most samples has a total range of uncertainty of <6,000 years. Preferred adjusted ages range from 0 to 35,400 years. First-order trends in the age distribution include older ages generally occurring farther from rivers on the east side of the basin and farther from the mountains, consistent with both mountain-front recharge and recharge on the basin floor in the form of stream-loss and arroyo recharge. Ages also increase with depth in the Southeast zone, the only area where discrete-depth samples could be collected. Recharge temperatures derived from noble gas concentrations were used in conjunction with an empirically derived local relationship between recharge temperature and elevation to constrain recharge elevation and to estimate fractions of mountain-block recharge (MBR) in sampled waters of Holocene age. Noble gas recharge temperatures indicate that ground water in the Southeast zone contains a significant fraction of MBR, commonly 20-50 percent or more. The same is apparently true for the Northeast zone, though only two data points could be used to evaluate the MBR fraction in this area. Recharge temperatures indicate that the upper 30 m of the regional aquifer on the Pajarito Plateau typically contain little or no MBR. Tritium concentrations and apparent 3H/3He ages indicate that water in the mountain block is dominantly <50 years old, and water in the basin-fill is dominantly >50 years old, consistent with the 14C ages. Terrigenic He (Heterr) concentrations in ground water are high (log Delta Heterr of 2 to 5) throughout much of the basin. High Heterr concentrations are probably caused by in situ production in the Tesuque Formation from locally high concentrations of U-bearing minerals (Northeast zone only), or by upward diffusive/advective transport of crustal- and mantle-sourced He possibly enhanced by basement piercing faults, or by both. The 3He/4He ratio of Heterr (Rterr) is commonly high (Rterr/Ra of 0.3-2.0, where Ra is the 3He/4He ratio in air) suggesting that Espanola Basin ground water commonly contains mantle-sourced He. The 3He/4He ratio of Heterr is generally the highest in the western and southern parts of the basin, closest to the western border fault system and the Quaternary to Miocene volcanics of the Jemez Mountains and Cerros del Rio.

Scientific Investigations Report↗

Hydrogeology and simulation of ground-water flow in the Rochester area, southeastern Minnesota, 1987-88

Ground-water flow in the St. Peter-Prairie du Chien-Jordan aquifer was studied in a 700 square-mile area surrounding Rochester, Minnesota. The aquifer consisting of sandstone, limestone, and dolomite is locally confined by the Decorah-Platteville-Glenwood sequence of shales and limestones. Regional flow in the aquifer is from a ground-water divide on the western, southern, and eastern sides of the city toward various rivers. A 140-square-mile area of the aquifer is a source of water supply for the Rochester area. A cone of depression in the potentiometric surface of the aquifer throughout most of the year is centered around high-capacity (greater than about 200 gallons per minute) wells in downtown Rochester. The cone covered an area of about 2.3 square miles in August 1988. Most streams in the area gain water from the ground-water system. One reach of the South Fork Zumbro River, however, loses water to the system. This loss is probably caused by the pumping of nearby high-capacity wells. A ground-water-flow model was used to simulate the effects of an extended drought near Rochester. Conclusions based on the simulations are that (1) reduced recharge and increased pumping, conditions that could exist during a 3-year drought, would probably lower water levels 5 to 10 feet regionally and more than 30 feet in the city; (2) pumping of six additional municipal wells on the perimeter of the city would lower regional water levels about 1 to 5 feet; and (3) that water levels would recover 1 to 18 feet if pumping from six municipal wells in downtown Rochester were discontinued. The area encompasses five recharge zones that can be delineated on the basis of recharge rate. About 54 percent of recharge to the aquifer in the area contributing water to Rochester is from a zone along the edge of the Decorah-Platteville-Glenwood confining unit. About 10 percent of recharge in this contributing area is to the sewered area of Rochester.

Minnesota↗

Ground-water quality in the carbonate-rock aquifer of the Great Basin, Nevada and Utah, 2003

The carbonate-rock aquifer of the Great Basin is named for the thick sequence of Paleozoic limestone and dolomite with lesser amounts of shale, sandstone, and quartzite. It lies primarily in the eastern half of the Great Basin and includes areas of eastern Nevada and western Utah as well as the Death Valley area of California and small parts of Arizona and Idaho. The carbonate-rock aquifer is contained within the Basin and Range Principal Aquifer, one of 16 principal aquifers selected for study by the U.S. Geological Survey’s National Water- Quality Assessment Program. Water samples from 30 ground-water sites (20 in Nevada and 10 in Utah) were collected in the summer of 2003 and analyzed for major anions and cations, nutrients, trace elements, dissolved organic carbon, volatile organic compounds (VOCs), pesticides, radon, and microbiology. Water samples from selected sites also were analyzed for the isotopes oxygen-18, deuterium, and tritium to determine recharge sources and the occurrence of water recharged since the early 1950s. Primary drinking-water standards were exceeded for several inorganic constituents in 30 water samples from the carbonate-rock aquifer. The maximum contaminant level was exceeded for concentrations of dissolved antimony (6 μg/L) in one sample, arsenic (10 μg/L) in eleven samples, and thallium (2 μg/L) in one sample. Secondary drinking-water regulations were exceeded for several inorganic constituents in water samples: chloride (250 mg/L) in five samples, fluoride (2 mg/L) in two samples, iron (0.3 mg/L) in four samples, manganese (0.05 mg/L) in one sample, sulfate (250 mg/L) in three samples, and total dissolved solids (500 mg/L) in seven samples. Six different pesticides or metabolites were detected at very low concentrations in the 30 water samples. The lack of VOC detections in water sampled from most of the sites is evidence thatVOCs are not common in the carbonate-rock aquifer. Arsenic values for water range from 0.7 to 45.7 μg/L, with a median value of 9.6 μg/L. Factors affecting arsenic concentration in the carbonate-rock aquifer in addition to geothermal heating are its natural occurrence in the aquifer material and time of travel along the flow path. Most of the chemical analyses, especially for VOCs and nutrients, indicate little, if any, effect of overlying land-use patterns on ground-water quality. The water quality in recharge areas for the aquifer where human activities are more intense may be affected by urban and/or agricultural land uses as evidenced by pesticide detections. The proximity of the carbonate-rock aquifer at these sites to the land surface and the potential for local recharge to occur through the fractured rock likely results in the occurrence of these and other land-surface related contaminants in the ground water. Water from sites sampled near outcrops of carbonate-rock aquifer likely has a much shorter residence time resulting in a potential for detection of anthropogenic or land-surface related compounds. Sites located in discharge areas of the flow systems or wells that are completed at a great depth below the land surface generally show no effects of land-use activities on water quality. Flow times within the carbonate-rock aquifer, away from recharge areas, are on the order of thousands of years, so any contaminants introduced at the land surface that will not degrade along the flow path have not reached the sampled sites in these areas.

Nevada, Utah↗

Chemistry and movement of ground water, Nevada Test Site

Three chemical types of ground water are distinguished at the Nevada Test Site and vicinity. A sodium-potassium water is related to tuff (in part zeolitized) and to alluvium containing detrital tuff. A calcium-magnesium water is related to limestone and dolomite, or to alluvium containing detritus of these rock types. A mixed chemical type, containing about as much sodium and potassium as calcium and magnesium, may result from the addition of one of the first two types of water to the other; to passage of water first through tuff and then through carbonate rock, or vice versa; and to ion-exchange during water travel. Consideration of the distribution of these water types, together with the distribution of sodium in the water and progressive changes in the dissolved solids, suggests that the ground water in the Nevada Test Site probably moves toward the Amargosa Desert, not into Indian Spring Valley and thence southeastward toward Las Vegas. The low dissolved solids content of ground-water reservoirs in alluvium and tuff of the enclosed basins indicates that recharge is local in origin.

Open-File Report↗

Ground-water hydrology and water quality of the southern high plains aquifer, Melrose Air Force Range, Cannon Air Force Base, Curry and Roosevelt Counties, New Mexico, 2002-03

In cooperation with the U.S. Air Force, the U.S. Geological Survey characterized the ground-water hydrology and water quality at Melrose Air Force Range in east-central New Mexico. The purpose of the study was to provide baseline data to Cannon Air Force Base resource managers to make informed decisions concerning actions that may affect the ground-water system. Five periods of water-level measurements and four periods of water-quality sample collection were completed at Melrose Air Force Range during 2002 and 2003. The water-level measurements and water-quality samples were collected from a 29-well monitoring network that included wells in the Impact Area and leased lands of Melrose Air Force Range managed by Cannon Air Force Base personnel. The purpose of this report is to provide a broad overview of ground-water flow and ground-water quality in the Southern High Plains aquifer in the Ogallala Formation at Melrose Air Force Range. Results of the ground-water characterization of the Southern High Plains aquifer indicated a local flow system in the unconfined aquifer flowing northeastward from a topographic high, the Mesa (located in the southwestern part of the Range), toward a regional flow system in the unconfined aquifer that flows southeastward through the Portales Valley. Ground water was less than 55 years old across the Range; ground water was younger (less than 25 years) near the Mesa and ephemeral channels and older (25 years to 55 years) in the Portales Valley. Results of water-quality analysis indicated three areas of different water types: near the Mesa and ephemeral channels, in the Impact Area of the Range, and in the Portales Valley. Within the Southern High Plains aquifer, a sodium/chloride-dominated ground water was found in the center of the Impact Area of the Range with water-quality characteristics similar to ground water from the underlying Chinle Formation. This sodium/chloride-dominated ground water of the unconfined aquifer in the Impact Area indicates a likely connection with the deeper water-producing zone. No pesticides, explosives, volatile organic compounds, semivolatile organic compounds, organic halogens, or perchlorate were found in water samples from the Southern High Plains aquifer at the Range.

Scientific Investigations Report↗

Description of the ground-water flow system in the Portland Basin, Oregon and Washington

An increasing dependence on ground-water resources in the Portland Basin has made it necessary for State and local governments to evaluate the capability of the ground-water system to meet present and future demands for water. This report describes the regional ground-water system and provides a conceptualization of the aquifer system. Aquifer geometry, recharge, ground-water flow directions, ground-water/surface water relations, water use, and water-level changes with time are presented.

Water Supply Paper↗

Ground-water geology and pump irrigation in Frenchman Creek Basin above Palisade, Nebraska

This report describes the geography, geology, and ground-water resources of that part of the Frenchman Creek basin upstream from Palisade, Nebr., an area of about 4,900 square miles. The basin includes all of Phillips County, Colo., and Chase County, Nebr., and parts of Logan, Sedgwick, Washington, and Yuma Counties, Colo., and Dundy, Hayes, Hitchcock, and Perkins Counties, Nebr. The land surface ranges from nearly flat to rolling; choppy hills and interdune saddles are common in the areas of dune sand, and steep bluffs and gullies cut the edges of the relatively flat loess plateaus. Most of the basin is drained by tributaries of Frenchman Creek, but parts of the sandhills are undrained. Farming and livestock raising are the principal industries. Irrigation with ground water has expanded rapidly since 1934. The rocks exposed in the basin are largely unconsolidated and range in age from Pliocene to Recent. They comprise the Ogallala formation (Pliocene), the Sanborn formation (Pleistocene and Recent?), dune sand (Pleistocene and Recent), and alluvium (Recent). The rocks underlying the Ogallala are the Pierre shale (Late Cretaceous) and the White River group (Oligocene). The Pierre shale is relatively impermeable and yields little or no water to wells. The White River group also is relatively impermeable and yields little or no water to wells; however, small to moderate quantities of water possibly may be obtained from wells that penetrate fractured or 'porous' zones in the upper part of the White River group or permeable channel deposits within the group. The Ogallala formation is the main aquifer in the basin and yields moderate to large quantities of water to wells. The Sanborn formation and the dune sand generally lie above the water table, but in areas of high water table the dune sand yields small quantities of water to wells for domestic and stock supplies. The alluvium, which includes the low terrace deposits bordering the major streams, yields small to large quantities of water to wells. The ground-water reservoir is recharged only from precipitation on the basin. Of the average annual precipitation of 19.5 inches, about 0.9 inch infiltrates to the water table, thereby contributing about 220,000 acre-feet of water annually to the ground-water reservoir. About 81 million acre-feet of water that could drain under gravity, and thus theoretically is available to wells, is held in groundwater storage in the basin. Water is discharged from the ground-water reservoir by wells, evaporation and transpiration, springs, seepage into streams, and movement into adjacent areas to the east and southeast. Most of the domestic, stock, and irrigation water supplies and all the public supplies are pumped from wells. During 1953, 96 wells were used to irrigate 10,000 acres of land with 19,000 acre-feet of water. About 34,000 acre-feet of water is evaporated and transpired annually in the valleys of the main streams and in areas of shallow water table in the sandhills. From the projection of base-flow measurements made during 1952, it was estimated that the average annual flow of Frenchman Creek into the reservoir above Enders Dam is about 57,000 acre-feet. By similar determinations, the average annual flow of Frenchman Creek at the gaging station at Palisade, Nebr., about 22 miles downstream from Enders Dam, is about 76,000 acre-feet, and the flow of Stinking Water Creek at the gaging station near Palisade is about 22,000 acre-feet. The combined flow of Frenchman and Stinking Water Creeks at their confluence near Palisade thus is about 98,000 acre-feet per year. About 90,000 acre-feet of ground water is estimated to move eastward each year across the Colorado-Nebraska State line within the basin. Additional irrigation wells that will tap the Ogallala formation and the alluvium in the major valleys undoubtedly will be drilled. On the basis of current estimates of future irrigation.withdrawals, it is concluded that by the

Water Supply Paper↗

California GAMA program: Ground-water quality data in the northern San Joaquin Basin Study Unit, 2005

Growing concern over the closure of public-supply wells because of ground-water contamination has led the State Water Board to establish the Ground-Water Ambient Monitoring and Assessment (GAMA) Program. With the aid of the U.S. Geological Survey (USGS) and Lawrence Livermore National Laboratory, the program goals are to enhance understanding and provide a current assessment of ground-water quality in areas where ground water is an important source of drinking water. The Northern San Joaquin Basin GAMA study unit covers an area of approximately 2,079 square miles (mi2) across four hydrologic study areas in the San Joaquin Valley. The four study areas are the California Department of Water Resources (CADWR) defined Tracy subbasin, the CADWR-defined Eastern San Joaquin subbasin, the CADWR-defined Cosumnes subbasin, and the sedimentologically distinct USGS-defined Uplands study area, which includes portions of both the Cosumnes and Eastern San Joaquin subbasins. Seventy ground-water samples were collected from 64 public-supply, irrigation, domestic, and monitoring wells within the Northern San Joaquin Basin GAMA study unit. Thirty-two of these samples were collected in the Eastern San Joaquin Basin study area, 17 in the Tracy Basin study area, 10 in the Cosumnes Basin study area, and 11 in the Uplands Basin study area. Of the 32 samples collected in the Eastern San Joaquin Basin, 6 were collected using a depth-dependent sampling pump. This pump allows for the collection of samples from discrete depths within the pumping well. Two wells were chosen for depth-dependent sampling and three samples were collected at varying depths within each well. Over 350 water-quality field parameters, chemical constituents, and microbial constituents were analyzed and are reported as concentrations and as detection frequencies, by compound classification as well as for individual constituents, for the Northern San Joaquin Basin study unit as a whole and for each individual study area. Results are presented in a descending order based on detection frequencies (most frequently detected compound listed first), or alphabetically when a detection frequency could not be calculated. Only certain wells were measured for all constituents and water-quality parameters. The results of all of the analyses were compared with U.S. Environmental Protection Agency (USEPA) and California Department of Health Services (CADHS) Maximum Contaminant Levels (MCLs), Secondary Maximum Contaminant Levels (SMCLs), USEPA lifetime health advisories (HA-Ls), the risk-specific dose at a cancer risk level equal to 1 in 100,000 or 10E-5 (RSD5), and CADHS notification levels (NLs). When USEPA and CADHS MCLs are the same, detection levels were compared with the USEPA standard; however, in some cases, the CADHS MCL may be lower. In those cases, the data were compared with the CADHS MCL. Constituents listed by CADHS as 'unregulated chemicals for which monitoring is required' were compared with the CADHS 'detection level for the purposes of reporting' (DLR). DLRs unlike MCLs are not health based standards. Instead, they are levels at which current laboratory detection capabilities allow eighty percent of qualified laboratories to achieve measurements within thirty percent of the true concentration. Twenty-three volatile organic compounds (VOCs) and seven gasoline oxygenates were detected in ground-water samples collected in the Northern San Joaquin Basin GAMA study unit. Additionally, 13 tentatively identified compounds were detected. VOCs were most frequently detected in the Eastern San Joaquin Basin study area and least frequently detected in samples collected in the Cosumnes Basin study area. Dichlorodifluoromethane (CFC-12), a CADHS 'unregulated chemical for which monitoring is required,' was detected in two wells at concentrations greater than the DLR. Trihalomethanes were the most frequently detected class of VOC constituents. Chloroform (trichloromethane) was the m

California↗

Raster dataset showing the probability of elevated concentrations of nitrate in ground water in Colorado, hydrogeomorphic regions and fertilizer use estimates included

This dataset is one of eight datasets produced by this study. Four of the datasets predict the probability of detecting atrazine and(or) desethyl-atrazine (a breakdown product of atrazine) in ground water in Colorado; the other four predict the probability of detecting elevated concentrations of nitrate in ground water in Colorado. The four datasets that predict the probability of atrazine and(or) desethyl-atrazine (atrazine/DEA) are differentiated by whether or not they incorporated atrazine use and whether or not they incorporated hydrogeomorphic regions. The four datasets that predict the probability of elevated concentrations of nitrate are differentiated by whether or not they incorporated fertilizer use and whether or not they incorporated hydrogeomorphic regions. Each of the eight datasets has its own unique strengths and weaknesses. The user is cautioned to read Rupert (2003, Probability of detecting atrazine/desethyl-atrazine and elevated concentrations of nitrate in ground water in Colorado: U.S. Geological Survey Water-Resources Investigations Report 02-4269, 35 p., http://water.usgs.gov/pubs/wri/wri02-4269/) to determine if he(she) is using the most appropriate dataset for his(her) particular needs. This dataset specifically predicts the probability of detecting elevated concentrations of nitrate in ground water in Colorado with hydrogeomorphic regions and fertilizer use included. The following text was extracted from Rupert (2003). Draft Federal regulations may require that each State develop a State Pesticide Management Plan for the herbicides atrazine, alachlor, metolachlor, and simazine. Maps were developed that the State of Colorado could use to predict the probability of detecting atrazine/DEA in ground water in Colorado. These maps can be incorporated into the State Pesticide Management Plan and can help provide a sound hydrogeologic basis for atrazine management in Colorado. Maps showing the probability of detecting elevated nitrite plus nitrate as nitrogen (nitrate) concentrations in ground water in Colorado also were developed because nitrate is a contaminant of concern in many areas of Colorado. Maps showing the probability of detecting atrazine/DEA at or greater than concentrations of 0.1 microgram per liter and nitrate concentrations in ground water greater than 5 milligrams per liter were developed as follows: (1) Ground-water quality data were overlaid with anthropogenic and hydrogeologic data by using a geographic information system (GIS) to produce a dataset in which each well had corresponding data on atrazine use, fertilizer use, geology, hydrogeomorphic regions, land cover, precipitation, soils, and well construction. These data then were downloaded to a statistical software package for analysis by logistic regression. (2) Relations were observed between ground-water quality and the percentage of land-cover categories within circular regions (buffers) around wells. Several buffer sizes were evaluated; the buffer size that provided the strongest relation was selected for use in the logistic regression models. (3) Relations between concentrations of atrazine/DEA and nitrate in ground water and atrazine use, fertilizer use, geology, hydrogeomorphic regions, land cover, precipitation, soils, and well-construction data were evaluated, and several preliminary multivariate models with various combinations of independent variables were constructed. (4) The multivariate models that best predicted the presence of atrazine/DEA and elevated concentrations of nitrate in ground water were selected. (5) The accuracy of the multivariate models was confirmed by validating the models with an independent set of ground-water quality data. (6) The multivariate models were entered into a geographic information system and the probability GRIDS were constructed.

Open-File Report↗

Ground water: a review.

There is growing documentation that a significant portion of the Nation's fresh ground water in the densely populated areas of the USA is contaminated. Because of the slow rates of ground-water movement, ground water once contaminated will remain so for decades, often longer. Cleanup of contaminated ground water is almost always expensive and often technically unfeasible; the expense is often prohibitive. -from Author

Reviews of Geophysics and Space Physics↗

Records and water-level measurements of selected wells and chemical analysis of ground water, East Shore area, Davis, Weber, and Box Elder Counties

This report is intended to serve two purposes: (1) to make available to the public basic ground-water data useful in planning and studying development of water resources and (2) to supplement an interpretive report that will be published later. Records were collected during the period 1935-61 by the U.S. Geological Survey in cooperation with the Utah State Engineer as a part of the investigation of the ground-water resources of the East Shore area in Davis, Weber, and southern Box Elder Counties, Utah. During the period 1952-61 additional records were collected by the U.S. Bureau of Reclamation. The interpretive material will be published cooperatively by the U.S. Geological Survey and the Utah State Engineer as a report entitled "Groundwater conditions in the East Shore area, Utah, 1953-61," by Ralph E. Smith. This report is most useful in predicting conditions likely to be found in areas that are being considered as well sites. The person considering the new well can spot the proposed site on plate 1 and examine the records of nearby wells as shown on the tables and figures. From table 1 he can note (1) the depth and diameter of wells in the vicinity and the yield of some of those wells, and (2) the depth to water or the feet of water pressure in wells in the vicinity; from table 2 and figure 2 he may note the historic fluctuations and trends of water levels in the vicinity; and from tables 3 and l he may note the chemical quality of the water from wells in the vicinity and the use made of this water. If the reader decides from his examination that conditions are favorable, he may place an application to drill a well with the State Engineer. If the State Engineer believes unappropriated water is available, the application may be approved after minimum statutory requirements have been satisfied. The report is also useful when planning large-scale developments of water supply. This and other uses of the report will be helped by use of the interpretive report upon its release.

Utah↗

Simulation of ground-water discharge to Biscayne Bay, southeastern Florida

As part of the Place-Based Studies Program, the U.S. Geological Survey initiated a project in 1996, in cooperation with the U.S. Army Corps of Engineers, to quantify the rates and patterns of submarine ground-water discharge to Biscayne Bay. Project objectives were achieved through field investigations at three sites (Coconut Grove, Deering Estate, and Mowry Canal) along the coastline of Biscayne Bay and through the development and calibration of variable-density, ground-water flow models. Two-dimensional, vertical cross-sectional models were developed for steady-state conditions for the Coconut Grove and Deering Estate transects to quantify local-scale ground-water discharge patterns to Biscayne Bay. A larger regional-scale model was developed in three dimensions to simulate submarine ground-water discharge to the entire bay. The SEAWAT code, which is a combined version of MODFLOW and MT3D, was used to simulate the complex variable-density flow patterns. Field data suggest that ground-water discharge to Biscayne Bay relative to the shoreline is restricted to within 300 meters at Coconut Grove, 600 to 1,000 meters at Deering Estate, and 100 meters at Mowry Canal. The vertical cross-sectional models, which were calibrated to the field data using the assumption of steady state, tend to focus ground-water discharge to within 50 to 200 meters of the shoreline. With homogeneous distributions for aquifer parameters and a constant-concentration boundary for Biscayne Bay, the numerical models could not reproduce the lower ground-water salinities observed beneath the bay, which suggests that further research may be necessary to improve the accuracy of the numerical simulations. Results from the cross-sectional models, which were able to simulate the approximate position of the saltwater interface, suggest that longitudinal dispersivity ranges between 1 and 10 meters, and transverse dispersivity ranges from 0.1 to 1 meter for the Biscayne aquifer. The three-dimensional, regional-scale model was calibrated to ground-water heads, canal baseflow, and the general position of the saltwater interface for nearly a 10-year period from 1989 to 1998. The mean absolute error between observed and simulated head values is 0.15 meter. The mean absolute error between observed and simulated baseflow is 3 x 105 cubic meters per day. The position of the simulated saltwater interface generally matches the position observed in the field, except for areas north of the Miami Canal where the simulated saltwater interface is located about 5 kilometers inland of the observed saltwater interface. Results from the regional-scale model suggest that the average rate of fresh ground-water discharge to Biscayne Bay for the 10-year period (1989-98) is about 2 x 105 cubic meters per day for 100 kilometers of coastline. This simulated discharge rate is about 6 percent of the measured surface-water discharge to Biscayne Bay for the same period. The model also suggests that nearly 100 percent of the fresh ground-water discharge is to the northern half of Biscayne Bay, north of the Cutler Drain Canal. South of the Cutler Drain Canal, coastal lowlands prevent the water table from rising high enough to drive measurable quantities of ground water to Biscayne Bay. Annual variations in sea-level elevation, which can be as large as 0.3 meter, have a substantial effect on rates of ground-water discharge. During 1989-98, simulated rates of ground-water discharge to Biscayne Bay generally are highest when sea level is relatively low.

Florida↗

Approach to an assessment of volatile organic compounds in the nation's ground water and drinking-water supply wells

The National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey (USGS) developed an approach for a national assessment of the occurrence, status, and distribution of volatile organic compounds (VOCs) in samples of ground water from aquifer studies and in samples from drinking-water supply wells, specifically domestic and public wells. Data on VOCs in samples from aquifers and from domestic and public wells had three sources: (1) NAWQA sampling of ground water in aquifer studies and of shallow ground water in areas of agricultural or urban land use from 1993-2002, (2) retrospective data from other Federal, State, and local agencies that sampled ground water in aquifer studies from 1985-1997, and (3) sampling of ground water from public wells used as a source of drinking water from 1999-2000 (source-water survey). Data for assessing VOCs in ground water came from the NAWQA sampling of aquifers and from retrospective data (1 and 2). Domestic wells were the most commonly sampled well type in these aquifer studies. Data for assessing VOCs in domestic well samples came from the NAWQA sampling of aquifers and shallow ground water and from retrospective data (1 and 2). Data for assessing VOCs in public well samples came from NAWQA sampling of aquifers and shallow ground water and from the source-water survey (1, 2, and 3). Fifty-five VOCs were included in the national assessment. All ground-water samples were collected using consistent, prescribed field protocols and were analyzed using approved analytical methods. All ground-water collection activities and laboratory procedures included the collection of various quality-control samples in order to ensure the quality of the data. Comparisons of detection frequencies and detected concentrations among individual VOCs, groups of VOCs, aquifer studies, and data sets were performed using two assessment levels: (1) an assessment level of 0.2 microgram per liter (?g/L), and (2) an assessment level of 0.02 ?g/L. Selection of the 0.2-?g/L assessment level was based on historical laboratory reporting levels of VOCs used by the USGS National Water-Quality Laboratory (NWQL) prior to April 1996, and selection of the 0.02-?g/L assessment level was based on a new, low-level analytical method developed by the NWQL and used since April 1996. Relational analyses using multivariate logistic regression were performed on VOC data from aquifers, domestic wells, and public wells to better understand the natural and anthropogenic factors that control or influence the occurrence of VOCs. Ancillary data used in the relational analyses represent a variety of anthropogenic and hydrogeologic controls on the occurrence of VOCs. For aquifers, relational analyses were performed only on NAWQA data analyzed using the new low-level analytical method for 10 frequently detected VOCs. For domestic wells, relational analyses were performed at assessment levels of 0.2 ?g/L and 0.02 ?g/L for 6 and 10 frequently detected VOCs at these levels. For public wells, relational analyses were performed at an assessment level of 0.2 ?g/L for nine frequently detected VOCs.

Open-File Report↗

Ground-Water Quality Data in the Upper Santa Ana Watershed Study Unit, November 2006-March 2007: Results from the California GAMA Program

Ground-water quality in the approximately 1,000-square-mile Upper Santa Ana Watershed study unit (USAW) was investigated from November 2006 through March 2007 as part of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The GAMA Priority Basin project was developed in response to the Groundwater Quality Monitoring Act of 2001, and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB). The Upper Santa Ana Watershed study was designed to provide a spatially unbiased assessment of raw ground-water quality within USAW, as well as a statistically consistent basis for comparing water quality throughout California. Samples were collected from 99 wells in Riverside and San Bernardino Counties. Ninety of the wells were selected using a spatially distributed, randomized grid-based method to provide statistical representation of the study unit (grid wells). Nine wells were selected to provide additional understanding of specific water-quality issues identified within the basin (understanding wells). The ground-water samples were analyzed for a large number of organic constituents (volatile organic compounds [VOCs], pesticides and pesticide degradates, pharmaceutical compounds, and potential wastewater-indicator compounds), constituents of special interest (perchlorate, N-nitrosodimethylamine [NDMA], 1,4-dioxane, and 1,2,3-trichloropropane [1,2,3-TCP]), naturally occurring inorganic constituents (nutrients, major and minor ions, and trace elements), radioactive constituents, and microbial indicators. Naturally occurring isotopes (tritium, carbon-14, and stable isotopes of hydrogen and oxygen in water) and dissolved noble gases also were measured to help identify sources and ages of the sampled ground water. Dissolved gases, and isotopes of nitrogen gas and of dissolved nitrate also were measured in order to investigate the sources and occurrence of nitrate in the study unit. In total, nearly 400 constituents and water-quality indicators were investigated for this study. This study did not attempt to evaluate the quality of water delivered to consumers; after withdrawal from the ground, water typically is treated, disinfected, and (or) blended with other waters to maintain acceptable water quality. Regulatory thresholds apply to treated water that is served to the consumer, not to raw ground water. However, to provide some context for the results, concentrations of constituents measured in the raw ground water were compared with regulatory and non-regulatory health-based thresholds established by the U.S. Environmental Protection Agency (USEPA) and the California Department of Public Health (CDPH) and thresholds established for aesthetic concerns (secondary maximum contaminant levels, SMCL-CA) by CDPH. Volatile organic compounds (VOCs) were detected in more than 80 percent of USAW grid wells. Most VOCs detected were at concentrations far less than thresholds established for drinking water to protect human health; however, six wells had VOC concentrations above health-based thresholds. Twenty-four of the 85 VOCs investigated were detected in the study unit;11 were detected in more than 10 percent of the wells. The VOCs detected above health-based thresholds in at least one well were dibromochloropropane (DBCP), tetrachloroethene (PCE), trichloroethene (TCE), carbon tetrachloride, and 1,1-dichoroethene. Pesticide compounds were detected in more than 75 percent of the grid wells. However, of the 134 different pesticide compounds investigated, 13 were detected at concentrations greater than their respective long-term method detection limits, and only 7 compounds (all herbicides or herbicide degradates) were detected in more than 10 percent of the wells. No pesticide compound was detected above its health-based threshold, although thresholds exist for fewer than half of the pesticide compounds investigat

Data Series↗