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Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems

Critical mineral inventory of select IOA-IOCG deposits, southwestern USA

Critical minerals are necessary for modern technology and strategic purposes. Their increasing importance requires finding new and nontraditional resources. Samples of ore, altered, and unaltered host rock were collected from 26 iron mines and prospects in California, Nevada, and Utah to assess the potential of these deposits to host economic quantities of different critical minerals. Geochemical analyses were conducted by 61 element ICP-OES-MS sodium peroxide fusion and major elements determined by WDXRF. These deposits concentrated many critical minerals beyond what is found in average upper crustal abundances, such as Sb, As, Bi, Co, Ga, Mg, Mn, Ni, Nb, Pd, REE, Sc, Te, Sn, Ti, W, V, and Zn. However, most of these are not concentrated enough in the ore to be considered as economic resources. Those critical minerals that are enriched enough in some of these deposits to possibly be considered as by-product commodities are Ni, REE, V, and potentially Co and Ga. These enrichments were not uniform, with REE more likely to be enriched in IOA deposits, whereas Co, Ga, Ni, and V could be found enriched in either IOA or IOCG deposits.

California, Nevada, Utah

Following the tug of the audience from complex to simplified hazards maps at Cascade Range volcanoes

Volcano-hazard maps are broadly recognized as important tools for forecasting and managing volcanic crises and for disseminating spatial information to authorities and people at risk. As scientists, we might presume that hazards maps can be developed at the time and with the methods of our discretion, yet the co-production of maps with stakeholder groups, who have programmatic needs of their own, can sway the timing, usability, and acceptance of map products. We examine two volcano hazard map-making efforts by staff at the U.S. Geological Survey. During the 1990s and early 2000s scientists developed a series of hazard assessments and maps with detailed zonations for volcanoes in Washington and Oregon. In 2009, the National Park Service expressed the need for simplified versions of the existing hazard maps for a high-profile visitor center exhibit. This request created an opportunity for scientists to rethink the objectives, scope, content, and map representations of hazards. The primary focus of this article is a discussion of processes used by scientists to distill the most critical information within the official parent maps into a series of simplified maps using criteria specified. We contextualize this project with information about development of the parent maps, public response to the simplified hazard maps, the value of user engagement in mapmaking, and with reference to the abundance of guidance available to the next generation of hazard-mapmakers. We argue that simplified versions of maps should be developed in tandem with any hazard maps that contain technical complexities, not as a replacement, but as a mechanism to broaden awareness of hazards. We found that when scientists endeavor to design vivid and easy-to-understand maps, people in many professions find uses for them within their organization’s information products, resulting in extensive distribution.

Washington

Flood-Inundation Maps of the Current and Jacks Fork Rivers including the Ozark National Scenic Riverways, Southeast Missouri, 2023

Digital flood-inundation maps for a 131.8-mile reach of the Current River and a 44.6-mile reach of the Jacks Fork River, in southeast Missouri, were created by the U.S. Geological Survey (USGS) in cooperation with the Ozark Foothills Regional Planning Commission and the South Central Ozark Council of Governments. The maps also encompass the 134 miles of the Current and Jacks Fork Rivers within the Ozark National Scenic Riverways, which is the first national park area to protect a river system. The flood-inundation maps, which can be accessed through the USGS Flood Inundation Mapping Program website at https://water.usgs.gov/osw/flood_inundation/ , depict estimates of the areal extent and depth of flooding corresponding to selected water levels (hereafter referred to as “stages”) at eight reference USGS streamgages—five on the Current River (USGS station numbers 07064440, 07064533, 07066510, 07067000, and 07068000) and three on the Jacks Fork River (USGS station numbers 07065200, 07065495, and 07066000). Near-real-time stages at these streamgages may be obtained from the USGS National Water Information System at https://doi.org/10.5066/F7P55KJN or the National Weather Service National Water Prediction Service at http://water.noaa.gov/ , which also forecasts flood hydrographs at four of these sites (USGS station numbers 07067000, 07068000, 07065495, and 07066000). Flood profiles were computed for seven of the eight map reaches by means of two-dimensional hydraulic models and the remaining reach by a one-dimensional hydraulic model. The models were calibrated by using stage-streamflow relations or streamflow measurements at the USGS streamgages and from high-flow stage measurements from water-level loggers distributed throughout the reaches. The hydraulic models were used to compute water-surface profiles for flood stages at 1-foot intervals referenced to the streamgage datums. The profile stages ranged from the National Weather Service “action stage” or near bankfull, to a stage exceeding the highest recorded water level at each streamgage. The simulated water-surface profiles were then combined with a digital elevation model (derived from light detection and ranging data having a nonvegetated vertical accuracy of a maximum 10-centimeter root mean square error) to delineate the area flooded at each water level and the associated water depths. The availability of these maps, along with information regarding current stage from the USGS streamgage and forecasted high-flow stages from the National Weather Service, will provide emergency management personnel, resource managers, and residents with information that is critical for flood-response activities such as evacuations and road closures, as well as for postflood recovery efforts.

Missouri

Remote sensing evapotranspiration in ensemble-based framework to enhance cascade routing and re-infiltration concept in integrated hydrological model applied to support decision making

Integrated hydrological models (IHMs) help characterize the complexity of surface–groundwater interactions. The cascade routing and re-infiltration (CRR) concept, recently applied to a MODFLOW 6 IHM, improved conceptualization and simulation of overland flow processes. The CRR controls the transfer of rejected infiltration and groundwater exfiltration from upslope areas to adjacent downslope areas where that water can be evaporated, re-infiltrated back to subsurface, or discharged to streams as direct runoff. The partitioning between these three components is controlled by uncertain parameters that must be estimated. Thus, by quantifying and reducing those uncertainties, next to uncertainties of the other model parameters (e.g. hydraulic and storage parameters), the reliability of the CRR is improved and the IHM is better suited for decision support modelling, the two key objectives of this work. To this end, the remotely sensed MODIS-ET product was incorporated into the calibration process for complementing traditional hydraulic head and streamflow observations. A total of approximately 150,000 observations guided the calibration of a 13-year MODFLOW 6 IHM simulation of the Sardon catchment (Spain) with daily stress periods. The model input uncertainty was represented by grid-cell-scale parameterization, yielding approximately 500,000 unknown input parameters to be conditioned. The calibration was carried out through an iterative ensemble smoother. Incorporating the MODIS-ET data improved the CRR implementation, and reduced uncertainties associated with other model parameters. Additionally, it significantly reduced the uncertainty associated with net recharge, a critical flux for water management that cannot be directly measured and rather is commonly estimated by IHM simulations.

Sardon catchment

Evaluating the potential of co-located non-petroleum energy resources in the Gulf Coast using play fairwayaAnalysis

Geological resources critical to the energy transition, such as sedimentary geothermal, carbon storage potential, and lithium in brines, commonly struggle for economic feasibility as stand-alone developments but can have greater viability when the potential for more than one of these resources exist within the same reservoir or stacked in different stratigraphic intervals. There may also be instances where development of one resource inhibits development of others and decisions need to be made on how to best prioritize the use of those resources in the subsurface. Subsurface data sets were analyzed and integrated to evaluate the distribution of non-petroleum energy and related resources in the onshore and nearshore U.S. Gulf Coast. Temperature, pressure, brine composition (lithium content), and reservoir quality data for thirty-four depositional units have been compiled and visualized to high-grade areas where multiple resource opportunities likely coexist. For sedimentary geothermal, possible resource areas are defined as low potential (<90°C), moderate potential (90–150°C), and high potential (>150°C). For CO 2 storage, high potential areas exhibit supercritical CO 2 conditions less than 80% of the fracture gradient. Areas with pore pressure between 80% and 100% of the fracture gradient are considered to exhibit moderate potential and areas where the fracture gradient is equal to or greater than 100% are assigned low potential. Lithium resources in brines were defined by lithium concentrations as low potential (<100ppm), moderate potential (100-200ppm), or high potential (>200ppm). Reservoir quality affects the viability of all three of these resources and is evaluated using depositional environment maps of each unit. The resulting play fairway maps can be used for regional scale screening evaluations of these resources and to identify areas of interest where more detailed, prospect-scale studies can be undertaken.

Gulf Coast

Mapping karst groundwater flow paths and delineating recharge areas for springs in the Little Sequatchie and Pryor Cove watersheds, Tennessee

The Little Sequatchie River and Pryor Cove Branch, in southern Tennessee, drain the eastern escarpment of the Cumberland Plateau to the Sequatchie River near the southern end of the Sequatchie Valley. The Little Sequatchie River is the largest tributary to the Sequatchie River by drainage area, covering over 120 square miles. The hydrology of the two drainage areas has been largely altered by karst processes, which has caused the majority of the streams to sink at the contact between the Mississippian Pennington Formation and the underlying Mississippian Bangor Limestone. The U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service and Tennessee Department of Environment and Conservation, initiated a study in 2021 to map the karst groundwater pathways in both watersheds in order to delineate recharge areas for several springs. One of these springs, Sequatchie Cave, represents a significant habitat for two Species of Greatest Conservation Need, the Glyphopsyche sequatchie (Sequatchie caddisfly) and the federally endangered Marstonia ogmorhaphe (royal marstonia). Springs and springflow-dominated streams in the Little Sequatchie River valley and Pryor Cove also provide water for agricultural practices and serve as a drinking water source for nearby communities. During the study, a total of 25 dye injections were conducted over eight rounds from January 2022 through March 2023. Dye traces from these injections helped to delineate recharge areas for six major springs, ranging from 7.3 to 65.2 square miles in area. The majority of the dye traces remained subsurface (from sinkpoint to recovery site) for long distances, with karst groundwater travelling nearly 8 miles before resurfacing. The dye traces also had rapid traveltimes, often travelling hundreds to thousands of feet per hour. The goal of this project was to provide scientific data related to karst groundwater pathways and spring recharge areas to aid State and Federal agencies in making informed decisions to protect and preserve this unique and vulnerable karst system.

Tennessee

Shallow hydrogeologic framework of the Tully Valley mudboil area, Onondaga County, New York

Mudboils have been documented in the Tully Valley in southern Onondaga County, New York, since the late 1890s. Sediment-laden water from the mudboils flows into Onondaga Creek, which empties into Onondaga Lake at Syracuse 15 miles to the north. Turbidity from the mudboils has degraded the water quality of Onondaga Creek despite a series of mitigation efforts that began in the early 1990s. Turbidity mitigation actions presently (2025) being considered include creek relocation and offline sediment settling. In support of these proposed actions during 2021–23, the U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, U.S. Environmental Protection Agency, Onondaga Nation, Onondaga Environmental Institute, and Central New York Regional Planning and Development Board, collected and analyzed geologic, hydrologic, geophysical, and geotechnical data to characterize the shallow hydrogeology along four proposed creek-relocation paths and in the proposed offline settling basin area. The investigation indicated that the four proposed creek-relocation paths, two east of Onondaga Creek and two west of Onondaga Creek, are underlain by sediments including muck, alluvium, mudboil deposits, alluvial-fan sand and gravel, and lacustrine fines. The proposed excavations would penetrate partially to fully saturated conditions: generally, the water table is shallow near the creek and deep on the alluvial fans. The shallowest excavation, about 5 feet below land surface, would be near the creek and primarily in alluvium, and the deepest excavation, as much as 30 feet below land surface, would be in the alluvial-fan deposits. Brackish waters would be penetrated by proposed channel excavations on the eastern side of Onondaga Creek in an area downgradient from a potentially leaking historical salt-exploration borehole and near the main mudboil area. Excavation in these areas likely would provide a continuous source of brackish groundwater to the relocated creek. Proposed channel excavations of muck, soft to very soft lacustrine fines, and mudboil-type sediments in mudboil and suspected mudboil areas would pose an excavation and slope stability challenge and would have the greatest potential to create new mudboils. Proposed channel excavations below the water table on the Rattlesnake Gulf and Rainbow Creek alluvial fans would intercept groundwater and make the constructed streambank susceptible to seepage-induced slope instability. The substantial water-level fluctuation in the sediments of both alluvial fans would aggravate the stability condition. In addition, excavation on the Rattlesnake Gulf alluvial fan would have the potential to affect water-supply springs at the toe of the fan. The proposed offline settling basin area is in the northern part of the Rattlesnake Gulf alluvial fan. Natural and man-made diversions of Rattlesnake Gulf have resulted in saturated conditions in the general area of the proposed basin. The proposed offline settling basin would be excavated in, and berms would be constructed on, alluvial-fan deposits and lacustrine fines. In the proposed basin area, the alluvial deposits overlying the lacustrine fines are less than 10 feet thick. Excavation, berm construction, and loading of the saturated, soft to very soft lacustrine fines may be problematic and require soil strengthening.

New York

Three-dimensional temperature maps of the Williston Basin, USA: Implications for deep hot sedimentary and enhanced geothermal resources

As part of U.S. Geological Survey's (USGS) efforts to identify and assess geothermal energy resources of the US, a three-dimensional (3D) geologic and thermal model has been constructed for the Williston Basin, USA. The geologic model consists of all sedimentary units above the Proterozoic and Archean crystalline rock (called basement herein), with a total sedimentary thickness of up to 5 km near the basin center. Twenty-nine geologic units were mapped from interpreted formation tops from 16,465 wells. A 3D temperature model was constructed to a depth of 7 km by constructing a 3D heat flow model for the sedimentary units, followed by estimating underlying temperature using a one-dimensional (1D) analytic solution for heat flow within the underlying crystalline basement. Using the sedimentary basin model, heat flow was simulated in 3D and was calibrated using three temperature datasets: 1) 24 high-confidence static temperature logs (equilibrium thermal profiles), 2) more than15,000 drill stem test (DST) measurements from >7,000 wells, and 3) more than 45,000 bottomhole temperature (BHT) measurements from >14,000 wells. The DST and BHT datasets provide broad spatial coverage, but are lower confidence, primarily because measurements were made prior to attaining thermal equilibrium. DST and BHT measurements were binned regionally to develop representative thermal profiles that generally agree with these lower quality data (hereafter called pseudowell temperature profiles). Layer properties (primarily thermal conductivity and compaction curves) were set to best estimate values, then the heat flow model was calibrated to fit pseudowell and static temperature logs primarily by adjusting basal heat flow to approximate the overall temperature profile. Minor adjustments to thermal conductivity allowed adjusting changes in slope at lithologic contacts. Resulting maps include 3D temperature and basal (bottom of sedimentary units) heat flow estimates, which are used as input for the temperature model of the basement. The crystalline basement temperature model uses an analytic 1D solution to the heat flow equation that requires estimates of heat flow and temperature at the upper boundary (i.e., the sediment/basement contact), radiogenic heat production within the crystalline basement, and reference thermal conductivity (i.e., uncorrected for temperature). Two regions of high heat flow are identified: 1) in western North Dakota along the North American Central Plains Conductivity Anomaly and 2) in eastern Montana near the Poplar dome. Within the sedimentary column in the center of the basin of the basin, an area of approximately 100,000 km2 is predicted to have moderate- to high-temperature geothermal resources (>90 °C) under the thickest sequences of sediments. Where thick insulation and high heat flow coincide, electric-grade resources can be less than 4 km deep. Assuming a maximum feasible drilling depth of 7 km, temperatures are predicted to be as high as 175 °C. The geologic model may be used to identify strata at sufficient temperatures that may have natural permeability or that may have conditions that favor development of enhanced/engineered geothermal systems resources.

Montana, North Dakota, South Dakota

Spatio-temporal evolution of distributed volcanic fields, case studies—Sierra Chichinautzin and Michoacán-Guanajuato, México

An analysis of 1,375 volcanoes in the Michoacán-Guanajuato (1,148 volcanoes in a 26,200 square-kilometer area) and Sierra Chichinautzin (227 volcanoes in a 3,500 square-kilometer area) volcanic fields in central Mexico identified patterns in the spatial and temporal distribution of past eruptions. A cluster agglomerative hierarchical method and kernel analysis confirmed that the Michoacán-Guanajuato volcanic field comprises four volcanic fields (Valle de Santiago, Uruapan, Apatzingán, and Pátzcuaro volcanic fields) controlled by different fault systems, indicating that it is not a single volcanic field but rather a group of volcanic fields (a “superfield”), each of which has distinct characteristics. In the Sierra Chichinautzin volcanic field, well-constrained isotopic ages were used to build a model of how the spatial distribution of the eruptions has changed over time. Two new 40Ar/39Ar ages from a locally recognized volcanic feature near the town of El Cantil, herein called El Cantil volcano (1,537±17 kilo-annum [ka]) and the volcanic feature at Cerro el Elefante (herein called El Elefante dome) (1,485±92 ka) belong to the oldest volcanic group identified in the Sierra Chichinautzin volcanic field, confirming the timing of the beginning of monogenetic volcanism in the region. Based on the volcanic groups identified in the Sierra Chichinautzin volcanic field, the youngest volcanism (less than 35 ka) is found only in the central-western sector of the field. Principal component analysis determined the directional trends of feeder dikes only for vents <10 ka in the Sierra Chichinautzin volcanic field. Possible magma migration paths through the crust were identified using seismic data from both volcanic fields using an earthquake catalog from 1973 to 2023, which includes 9,016 earthquakes in the Michoacán-Guanajuato volcanic field and 841 in the Sierra Chichinautzin volcanic field. The spatial distribution of the hypocenters does not highlight any trend that could be associated with superficial movement of magma in the Sierra Chichinautzin volcanic field. In the Michoacán-Guanajuato volcanic field, however, eight seismic swarms since 1997 have been detected. These swarms are interpreted to result from ascending magma. Strengthening monitoring systems and reinforcing mitigation measures to address volcanic hazards and risk are important means of preparing for future eruptions in both regions. Analysis such as those herein provide insights as to where an eruption might occur and may help mitigate volcanic hazards.

Michoacán-Guanajuato, Sierra Chichinautzin

Pre-eruptive characteristics of “suspect” silicic magmas in Carlin-type Au-forming systems

World-class Carlin-type Au deposits hosted in sedimentary rock were formed when profuse Eocene silicic magmatism swept across northern Nevada in response to arc migration. Carlin-type Au deposits formed along with porphyry/skarn Cu-Mo-W-Au deposits, epithermal Ag-Au deposits, and distal disseminated Ag-Au deposits. But unlike these other Au-bearing deposits that have clear associations with igneous intrusions, Carlin-type ore deposits appear to have formed distant from concealed plutons, and their origin remains controversial. Despite decades of abundant geophysical, geochronological, and geochemical studies suggesting the involvement of magmas, concrete evidence for magmatic involvement is still lacking. Consequently, the involvement of contemporaneous igneous systems remains inferred based on age, proximity, and variable isotopic, geochemical, and geophysical clues. A recent synthesis of deposit models postulates that Carlin-type Au deposits are intrusion-related, but that the causative magmas reside deeper (∼6–12 km) than in typical porphyry and peripheral systems (∼3–5 km), meaning that Carlin-type deposits are perhaps more distal expressions of igneous intrusions. We investigate a collection of “suspect” magmatic systems over a ∼7 m.y. timespan (∼41–34 Ma) that are contemporaneous with and near known Carlin-type ore deposits. We report results of a multifaceted array of in situ geochemical analyses (FTIR, EMP, SHRIMP-RG, LA-ICP-MS) of quartz-hosted melt inclusions, biotite, and quartz to better characterize the pre-eruptive characteristics of these magmas. We also report results of thermobarometry and thermodynamic phase equilibria modeling to help place constraints on magmatic reservoir depths and processes. Rather than a single “flavor” of silicic magma, we observe a surprisingly broad compositional spectrum of rhyolites, with one end of the spectrum exhibiting more arc-like (I-type) characteristics and the other end displaying more post-subduction, thick-crust extensional (A-type) characteristics. This broad compositional spectrum suggests a more complex picture of silicic crustal magmatism operating over a narrow span of time during slab rollback. Despite this spectrum, magmatic systems in this study are consistently ferroan and generally peraluminous, which we interpret as an expression of the relatively elevated geotherm at the time and incorporation of variable amounts of highly peraluminous metasedimentary crustal components. The silicic magma spectrum encompasses a range of mineralization associations, including subduction-related Cu-Mo-W-Au-Ag and post-subduction, thick-crust extensional rare-metal Mo-Sn-W-F-Be-Ag-Au, consistent with the prolific and diverse array of ore deposits that formed during this time. Carlin-type Au deposition appears to be associated with nearly the entire magmatic spectrum. This apparent indifference to silicic magma “flavor” would seem to imply that if magmas are involved in Carlin-type Au deposit genesis, they perhaps do not need to be compositionally specialized and/or possibly are only relevant as heat sources driving circulation to remobilize and redistribute metals.

Nevada

Water quality of selected springs and public-supply wells, Pine Ridge Indian Reservation, South Dakota, 1992-97

This report presents results of a water-quality study for the Pine Ridge Indian Reservation, South Dakota. The study was a cooperative effort between the U.S. Geological Survey and the Water Resources Department of the Oglala Sioux Tribe. Discharge and water-quality data were collected during 1992-97 for 14 contact springs located in the northwestern part of the Reservation. Data were collected to evaluate potential alternative sources of water supply for the village of Red Shirt, which currently obtains water of marginal quality from a well completed in the Inyan Kara aquifer. During 1995-97, water-quality data also were collected for 44 public-supply wells that serve about one-half of the Reservation's population. Quality-assurance sampling was used to evaluate the precision and accuracy of environmental samples. Ten of the springs sampled contact the White River Group, and four contact the Pierre Shale. Springs contacting the White River Group range from calcium bicarbonate to sodium bicarbonate water types. Two springs contacting the Pierre Shale have water types similar to this; however, sulfate is the dominant anion for the other two springs. In general, springs contacting the White River Group are shown to have better potential as alternative sources of water supply for the village of Red Shirt than springs contacting the Pierre Shale. Nine of the springs with better water quality were sampled repeatedly; however, only minor variability in water quality was identified. Six of these nine springs, of which five contact the White River Group, probably have the best potential for use as water supplies. Discharge from any of these six springs probably would provide adequate water supply for Red Shirt during most periods, based on a limited number of discharge measurements collected. Concentrations of lead exceeded the U.S. Environmental Protection Agency (USEPA) action level of 15 µg/L for three of these six springs. Five of these six springs also had arsenic concentrations that exceeded 10 µg/L, which could be problematic if the current maximum contaminant level (MCL) is lowered. Blending of water from one or more springs with water from the existing Inyan Kara well may be an option to address concerns regarding both quantity and quality of existing and potential sources. All nine springs that were sampled for indicator bacteria had positive detections on one or more occasions during presumptive tests. Although USEPA standards for bacteria apply only to public-water supplies, local residents using spring water for domestic purposes need to be aware of the potential health risks associated with consuming untreated water. One spring contacting the White River Group and two springs contacting the Pierre Shale exceeded 15 pCi/L for gross alpha; these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Nine springs were sampled for selected pesticides and tritium. The pesticides atrazine, carbaryl, and 2,4-D were not detected in any of the samples. The nine springs were analyzed for tritium in order to generally assess the age of the water and to determine if concentrations exceeded the MCL established for gross beta-particle activity. Tritium results indicated two springs are composed primarily of water recharged prior to atmospheric testing of nuclear bombs and two other springs have a relatively large percentage of test-era water. The remaining five springs had tritium values that indicated some percentage of test-era water; however, additional sampling would be needed to determine whether water is predominantly pre- or post-bomb age. Of the 44 public-supply wells sampled, 42 are completed in the Arikaree aquifer, one is completed in an alluvial aquifer, and one is completed in the Inyan Kara aquifer. Water from the alluvial well is a sodium bicarbonate water type, water from Arikaree aquifer ranges from calcium bicarbonate to sodium bicarbonate types, and water from the Inyan Kara well is a calcium sulfate bicarbonate type. Of the 44 wells sampled, 28 (64 percent) tested positive for indicator bacteria in presumptive tests. Because these were single samples that generally were collected upstream from chemical treatment feeders, positive detections do not necessarily constitute exceedances of drinking-water standards. A single sample from an Arikaree well exceeded the MCL for arsenic of 50 µg/L. Arsenic exceeded 10 µg/L for six additional Arikaree wells and for the alluvial well and the Inyan Kara well, which could be problematic if the current MCL is lowered. The alluvial well also exceeded the secondary maximum contaminant level (SMCL) for dissolved solids, which is non-enforceable, and the action level for lead. The Inyan Kara well exceeded the SMCL's for iron and for manganese and the MCL of 5 pCi/L for radium-226 and 228 combined. Several Arikaree wells exceeded SMCL's for either pH, sulfate, dissolved solids, iron, or manganese. One Arikaree well exceeded the MCL of 4.0 mg/L for fluoride and another exceeded the MCL of 10 mg/L for nitrite plus nitrate. Ten Arikaree wells equalled or exceeded 15 pCi/L for gross alpha; however, these values do not necessarily constitute exceedances of the MCL, which excludes radioactivity contributed by uranium and radon. Additional sampling using different analysis techniques would be needed to conclusively determine if any samples exceeded this MCL. Eight wells, all from the Arikaree aquifer, equalled or exceeded the proposed MCL of 20 µg/L for uranium and 33 wells (75 percent) equalled or exceeded one-half of the proposed MCL. Although this standard has only been proposed, additional information regarding the extent of elevated uranium concentrations in the Arikaree aquifer, and the geochemical processes involved, may be beneficial. It was determined from analyses of uranium isotope data for five wells that the source of elevated uranium concentrations is naturally occurring, rather than anthropogenic.

South Dakota

Late Pleistocene kinematics of the Great Southern Puerto Rico Fault Zone, Puerto Rico

Several onshore faults in southern Puerto Rico have recently been recognized as Quaternary active. However, the kinematics of these faults, particularly any lateral component, remain largely unconstrained. It is difficult to characterize low strain‐rate faults, partially due to extensive erosional and anthropogenic landscape modification, steep relief, and frequent landsliding, limiting the preservation of geomorphic features that could serve as recorders of fault motion. Here, we constrain the kinematics along sections of the Great Southern Puerto Rico Fault Zone (GSPRFZ) on the southern coastal plain of Puerto Rico. We integrate ∼1‐m‐resolution light detection and ranging (lidar)‐derived topography, historical air photos, and field mapping to identify a series of ∼50–1200‐m‐long fault scarps and lineaments that trend northwest–southeast and extend for ≥25 km across the southern coastal plain. Fault scarps are primarily south facing, cut across topography, and displace Quaternary deposits and landforms. We document multiple offset geomorphic markers, including channel thalwegs and interfluves formed in deposits previously mapped as Quaternary piedmont alluvial plain. We observe both vertical (south‐side‐down) and right‐lateral meter‐scale displacements, which indicate that the GSPRFZ accommodates right‐lateral oblique motion in the late Pleistocene, consistent with northeast motion of the Puerto Rico and the Virgin Islands microplate away from the Hispaniola block.

Puerto Rico

Geospatial PDF map of the compilation of GIS data for the mineral industries of select countries in the Indo-Pacific region

Introduction In 2024, the U.S. Geological Survey's (USGS) National Minerals Information Center (NMIC) completed the project titled "Compilation of geospatial data for the mineral industries of select countries in the Indo-Pacific." This project aimed to leverage the expertise and capabilities of the NMIC to collect, synthesize, and interpret geospatial data to inform on the extractive resources of select countries in the Indo-Pacific region (area of study) and expand the NMIC's understanding on the impact of mineral industry of these countries in the global economy. The 19 countries of interest in the Indo-Pacific study area include Bangladesh, Bhutan, Brunei, Burma, Fiji, Malaysia, Mongolia, Nauru, New Caledonia, New Zealand, Papua New Guinea, Philippines, Singapore, Solomon Islands, South Korea (Republic of Korea), Sri Lanka, Taiwan, Timor-Leste, and Vietnam. The primary objective of this effort was to create a fully attributed Geographic Information System (GIS) portraying existing mining infrastructure, resources, and production capacities across the Indo-Pacific study area as well as highlight mineral production and processing sites under development and potential areas of future extractive industry operations and development in the region. The compiled GIS geodatabase with supporting documentation including comprehensive metadata was published as a USGS data release titled "Compilation of Geospatial Data (GIS) for the Mineral Industries of Select Countries in the Indo-Pacific." This georeferenced portable document format (GeoPDF) map sheet presents a new geographic information product containing a partial representation of the GIS data. This GeoPDF map provides a visual comparison of the distribution of mineral industry GIS data, which contributes to a deeper understanding of the intersections and complexities of the extractive industries within the select countries in the Indo-Pacific region.

Open-File Report

Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund Site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

EarthArXiv

Pesticides in surface waters of the Upper Colorado River Basin, Colorado, 1996-98

Forty-four river, stream, and drain sites in the Upper Colorado River Basin in Colorado were sampled during 1996-98 to determine the occurrence and distribution of pesticides in the basin. In a fixed-station study, 57 surface-water samples were collected from October 1996 through January 1998 at four sites. Each site was sampled approximately monthly for up to a year, with more frequent sampling during the spring and summer growing season. In a synoptic study, surface-water samples were collected at 43 sites in the agricultural areas of the Grand Valley and the Uncompahgre River Valley in May 1998. Each site was sampled once. Pesticide concentrations generally were low and varied seasonally and across land uses. Thirty-five pesticides were detected at least once in the two studies, and 11 pesticides accounted for almost 82 percent of the detections. Herbicides were more commonly detected than insecticides, and only the herbicides alachlor and atrazine were detected in more than 50 percent of the samples. Carbofuran was the most commonly detected insecticide and was detected in 19 percent of the samples. Pesticide detections increased and were measured at higher concentrations in the summer months and at the agriculture sites. All pesticide concentrations were less than drinking-water standards, and most complied with human-health advisories and criteria for the protection of freshwater aquatic life. Pesticides in the Upper Colorado River Basin in Colorado were detected slightly less frequently and generally at lower concentrations than in 20 National Water-Quality Assessment Program study-unit basins that collected water-quality data from 1992 through 1996. Results from surface-water sampling conducted during 1996?98 in the Upper Colorado River Basin in Colorado indicate that beneficial uses of water were not being impaired by the presence of pesticides in surface waters in the basin.

Colorado

Evidence for offset of Cretaceous plutons by the Tintina fault in eastern Alaska: Implications for regional metallogeny

Cretaceous magmatism in eastern interior Alaska is voluminous, but temporally and spatially diverse – suggestive of varying sources and drivers. More than 150 new U-Pb zircon and more than 500 geochemical analyses of Cretaceous plutonic units allow for the grouping of distinct plutonic suites. Magmatism was continuous from 120-66 Ma but can be grouped into temporally distinct pulses from ca. 115-100 Ma, 100-90 Ma, and 75-66 Ma. Geochemical diversity occurs during each pulse, further distinguishing multiple suites. Diverse metallogenic epochs are strongly correlated to pluton chemistry. Mineralization is largely absent prior to 108 Ma. From 108-100 Ma, plutonism is coeval with sparse, but notable Au-quartz veins with variable Bi, As, W, and Mo. From 100-90 Ma, intrusion-related mineralization zones from Au-Cu(-Bi) and U-Th in the northwest to central Au- Bi-As-Te(-W), and Mo-W to the southeast. Porphyry style Cu-Mo(-Au) occurrences occur with the latest Cretaceous plutons emplaced from 75-66 Ma . Restoration of ~450 km of dextral movement on the Tintina fault and comparison of metallogenic and geochemical characteristics of Alaska plutons suggest 100-90 Ma plutons may be the continuation of the metallogenically significant Tombstone, Mayo, and Tungsten suites from the Yukon.

Alaska

Environmental setting and water-quality issues in the lower Tennessee River basin

The goals of the National Water-Quality Assessment Program are to describe current water-quality conditions for a large part of the Nation's water resources, identify water-quality changes over time, and identify the primary natural and human factors that affect water quality. The lower Tennessee River Basin is one of 59 river basins selected for study. The water-quality assessment of the lower Tennessee River Basin study unit began in 1997. The lower Tennessee River Basin study unit encompasses an area of about 19,500 square miles and extends from Chattanooga, Tennessee, to Paducah, Kentucky. The study unit had a population of about 1.5 million people in 1995. The study unit was subdivided into subunits with relatively homogeneous geology and physiography. Subdivision of the study unit creates a framework to assess the effects of natural and cultural settings on water quality. Nine subunits were delineated in the study unit; their boundaries generally coincide with level III and level IV ecoregion boundaries. The nine subunits are the Coastal Plain, Transition, Western Highland Rim, Outer Nashville Basin, Inner Nashville Basin, Eastern Highland Rim, Plateau Escarpment and Valleys, Cumberland Plateau, and Valley and Ridge.The lower Tennessee River Basin consists of predominantly forest (51 percent) and agricultural land (40 percent). Activities related to agricultural land use, therefore, are the primary cultural factors likely to have a widespread effect on surface- and ground-water quality in the study unit. Inputs of total nitrogen and phosphorus from agricultural activities in 1992 were about 161,000 and 37,900 tons, respectively. About 3.7 million pounds (active ingredient) of pesticides was applied to crops in the lower Tennessee River Basin in 1992. State water-quality agencies identified nutrient enrichment and pathogens as water-quality issues affecting both surface and ground water in the lower Tennessee River Basin. Water-quality data collected by State and Federal agencies between 1980 and 1996 were summarized to characterize surface- and ground-water quality of the subunits with respect to these issues. Median concentrations of nitrogen species generally were less than 1 milligram per liter in surface and ground water in all subunits, and were highest throughout the subunits that had the largest percentages of agricultural land use. Median phosphorus concentrations also were less than 1 milligram per liter in all subunits. Phosphatic limestones present in two subunits had a larger effect on phosphorus concentrations in surface and ground water than did the amount of agricultural land use in these subunits. Median counts of fecal coliform were higher in surface water than in ground water in all subunits. The highest median counts in surface water were in the Valley and Ridge (7,500 colonies per 100 milliliters) and the Outer Nashville Basin subunits (5,000 colonies per 100 milliliters). Highest median counts in ground water were in the Inner and Outer Nashville Basin subunit. Natural setting likely has an important effect with respect to fecal contamination of surface and ground water in the lower Tennessee River Basin.

Alabama, Georgia, Kentucky, Mississippi, Tennessee