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Airborne gamma-ray and magnetic anomaly signatures of serpentinite in relation to soil geochemistry, northern California

Serpentinized ultramafic rocks and associated soils in northern California are characterized by high concentrations of Cr and Ni, low levels of radioelements (K, Th, and U) and high amounts of ferrimagnetic minerals (primarily magnetite). Geophysical attributes over ultramafic rocks, which include airborne gamma-ray and magnetic anomaly data, are quantified and provide indirect measurements on the relative abundance of radioelements and magnetic minerals, respectively. Attributes are defined through a statistical modeling approach and the results are portrayed as probabilities in chart and map form. Two predictive models are presented, including one derived from the aeromagnetic anomaly data and one from a combination of the airborne K, Th and U gamma-ray data. Both models distinguish preferential values within the aerogeophysical data that coincide with mapped and potentially unmapped ultramafic rocks. The magnetic predictive model shows positive probabilities associated with magnetic anomaly highs and, to a lesser degree, anomaly lows, which accurately locate many known ultramafic outcrops, but more interestingly, locate potentially unmapped ultramafic rocks, possible extensions of ultramafic bodies that dip into the shallow subsurface, as well as prospective buried ultramafic rocks. The airborne radiometric model shows positive probabilities in association with anomalously low gamma radiation measurements over ultramafic rock, which is similar to that produced by gabbro, metavolcanic rock, and water bodies. All of these features share the characteristic of being depleted in K, Th and U. Gabbro is the only rock type in the study area that shares similar magnetic properties with the ultramafic rock. The aerogeophysical model results are compared to the distribution of ultramafic outcrops and to Cr, Ni, K, Th and U concentrations and magnetic susceptibility measurements from soil samples. Analysis of the soil data indicates high positive correlation between magnetic susceptibilities and concentration of Cr and Ni. Although the study focused on characterizing the geophysical properties of ultramafic rocks and associated soils, it has also yielded information on other rock types in addition to ultramafic rocks, which can also locally host naturally-occurring asbestos; specifically, gabbro and metavolcanic rocks.

Applied Geochemistry↗

Summary of the Oahu, Hawaii, regional aquifer-system analysis

Oahu, the third largest of the Hawaiian islands, is formed by the eroded remnants of two elongated shield volcanoes with broad, low profiles. Weathering and erosion have modified the original domed surfaces of the volcanoes, leaving a landscape of deep valleys and steep interfluvial ridges in the interior highlands. The Koolau Range in eastern Oahu and the Waianae Range in western Oahu are the eroded remnants of the Koolau and Waianae Volcanoes. The origin, mode of emplacement, texture, and composition of the rocks of Oahu affect their ability to store and transmit water. The volcanic rocks are divided into four groups: (1) lava flows, (2) dikes, (3) pyroclastic deposits, and (4) saprolite and weathered basalt. Stratified sequences of thin-bedded lava flows form the most productive aquifers in Hawaii. Dikes are near-vertical sheets of massive intrusive rock that typically contain only fracture permeability. Pyroclastic deposits include ash, cinder, and spatter; they are essentially granular, with porosity and permeability similar to those of granular sediments. Weathering of basaltic rocks in the humid, subtropical climate of Oahu alters igneous minerals to clays and oxides, reducing the permeability of the parent rock. Saprolite is weathered material that has retained textural features of the parent rock. Estimates of hydraulic conductivity along the plane of dike-free lava flows tend to fall within about one order of magnitude, from about 500 to about 5,000 feet per day. Estimates of specific yield range from about 1 to 20 percent; most of the values lie within a narrow range of about 5 to 10 percent. The occurrence of ground water on Oahu is determined by the type and character of the rocks and by the presence of geohydrologic barriers. The primary modes of freshwater occurrence on Oahu are as a basal lens of fresh ground water floating on saltwater, as dike-impounded ground water, and as perched ground water. Saltwater occurs at depth throughout much of the island. A regional aquifer system composed of the Waianae aquifer in the Waianae Volcanics and the Koolau aquifer in the Koolau Basalt is subdivided into well-defined areas by geohydrologic barriers. The aquifers are separated by the Waianae confining unit formed by weathering along the Waianae-Koolau unconformity. In some coastal areas, a caprock of sedimentary deposits overlies and confines the aquifers. The island of Oahu has been divided into seven major ground-water areas delineated by deep-seated structural geohydrologic barriers; these areas are further subdivided by shallower internal barriers to ground-water flow. The Koolau rift zone along the eastern (windward) side of the island and the Waianae rift zone to the west (Waianae area) constitute two of the major ground-water areas. North-central Oahu is divided into three smaller ground-water areas, Mokuleia, Waialua, and Kawailoa. The Schofield ground-water area encompasses much of the Schofield Plateau of central Oahu. Southern Oahu is divided into six areas, Ewa, Pearl Harbor, Moanalua, Kalihi, Beretania, and Kaimuki. Southeastern Oahu is divided into the Waialae and Wailupe-Hawaii Kai areas. Along the northeast coast of windward Oahu is the Kahuku ground-water area. The aquifers of Oahu contain shallow freshwater and deeper saltwater flow systems. There are five fresh ground-water flow systems: meteoric freshwater flow diverges from ground-water divides that lie somewhere within the Waianae and Koolau rift zones, forming an interior flow system in central Oahu (which is divided into the northern and southern Oahu flow systems) and exterior flow systems in western (Waianae area) Oahu, eastern (windward) Oahu, and southeastern Oahu. Development of the ground-water resources on Oahu began when the first well was drilled near Honouliuli in the summer of 1879. By 1890, 86 wells had been drilled on the island. From about 1891 to about 1910, development increased rapidly with the drilling of a

Hawaii↗

Uranium deposits of the northern part of the Boulder Batholith, Montana

Uranium minerals and radioactivity anomalies occur in many silverlead veins and chalcedony veins and vein zones in the Boulder batholith of southwestern Montana. Pitchblende has been identified in a few silverlead veins. These silver-lead veins occupy shear zones along which there is no evidence of large-scale lateral displacement. The wall rock adjacent to the veins is intensely silicified and sericitized quartz monzonite and granodiorite. The veins have yielded substantial quantities of lead, silver, zinc, and gold. The silver-lead veins consist principally of galena, sphalerite, tetrahedrite, chalcopyrite, and pyrite in a gangue of light- to dark-gray quartz, altered rock, gouge, and subordinate chalcedony and carbonate minerals. No anomalous radioactivity nor uranium minerals have been found in similar veins in prebatholithic rocks of the area.Chalcedony veins and vein zones, some of which are uraniferous, are distinctly different from the silver-lead veins and, with a single exception, are known only in the batholith. The chalcedony vein zones consist of one or more discontinuous stringers or veins of chalcedony and microcrystalline quartz in silicified and sericitized quartz monzonite and granodiorite, and in less strongly altered alaskite. Only small amounts of silver ore have been produced from these chalcedony veins and vein zones. All of the veins are early Tertiary in age, but the silver-lead veins probably are older than the chalcedony veins. Uranium is closely associated with chalcedony and microcrystalline quartz in both types of veins. This association suggests that all of the uranium in the area is of the same age. If so, some of the silver-lead veins must have been re-opened during the period of chalcedony vein formation.

Montana↗

U-Pb (zircon) and geochemical constraints on the age, origin, and evolution of Paleozoic arc magmas in the Oyu Tolgoi porphyry Cu-Au district, southern Mongolia

Uranium–Pb (zircon) ages are linked with geochemical data for porphyry intrusions associated with giant porphyry Cu–Au systems at Oyu Tolgoi to place those rocks within the petrochemical framework of Devonian and Carboniferous rocks of southern Mongolia. In this part of the Gurvansayhan terrane within the Central Asian Orogenic Belt , the transition from Devonian tholeiitic marine rocks to unconformably overlying Carboniferous calc-alkaline subaerial to shallow marine volcanic rocks reflects volcanic arc thickening and maturation. Radiogenic Nd and Pb isotopic compositions ( ε Nd(t) range from + 3.1 to + 7.5 and 206 Pb/ 204 Pb values for feldspars range from 17.97 to 18.72), as well as low high-field strength element (HFSE) contents of most rocks (mafic rocks typically have < 1.5% TiO 2 ) are consistent with magma derivation from depleted mantle in an intra-oceanic volcanic arc. The Late Devonian and Carboniferous felsic rocks are dominantly medium- to high-K calc-alkaline and characterized by a decrease in Sr/Y ratios through time, with the Carboniferous rocks being more felsic than those of Devonian age. Porphyry Cu–Au related intrusions were emplaced in the Late Devonian during the transition from tholeiitic to calc-alkaline arc magmatism . Uranium–Pb (zircon) geochronology indicates that the Late Devonian pre- to syn-mineral quartz monzodiorite intrusions associated with the porphyry Cu–Au deposits are ~ 372 Ma, whereas granodiorite intrusions that post-date major shortening and are associated with less well-developed porphyry Cu–Au mineralization are ~ 366 Ma. Trace element geochemistry of zircons in the Late Devonian intrusions associated with the porphyry Cu–Au systems contain distinct Th/U and Yb/Gd ratios, as well as Hf and Y concentrations that reflect mixing of magma of distinct compositions. These characteristics are missing in the unmineralized Carboniferous intrusions. High Sr/Y and evidence for magma mixing in syn- to late-mineral intrusions distinguish the Late Devonian rocks associated with giant Cu–Au deposits from younger magmatic suites in the district.

Southern Mongolia↗

Tertiary volcanic rocks and uranium in the Thomas Range and northern Drum Mountains, Juab County, Utah

The Thomas Range and northern Drum Mountains have a history of volcanism, faulting, and mineralization that began about 42 m.y. (million years) ago. Volcanic activity and mineralization in the area can be divided into three stages according to the time-related occurrence of rock types, trace-element associations, and chemical composition of mineral deposits. Compositions of volcanic rocks changed abruptly from rhyodacite-quartz latite (42-39 m.y. ago) to rhyolite (38-32 m.y. ago) to alkali rhyolite (21 and 6-7 m.y. ago); these stages correspond to periods of chalcophile and siderophile metal mineralization, no mineralization(?), and lithophile metal mineralization, respectively. Angular unconformities record episodes of cauldron collapse and block faulting between the stages of volcanic activity and mineralization. The youngest angular unconformity formed between 21 and 7 m.y. ago during basin-and-range faulting. Early rhyodacite-quartz latite volcanism from composite volcanoes and fissures produced flows, breccias, and ash-flow tuff of the Drum Mountains Rhyodacite and Mt. Laird Tuff. Eruption of the Mt. Laird Tuff about 39 m.y. ago from an area north of Joy townsite was accompanied by collapse of the Thomas caldera. Part of the roof of the magma chamber did not collapse, or the magma was resurgent, as is indicated by porphyry dikes and plugs in the Drum Mountains. Chalcophile and siderophile metal mineralization, resulting in deposits of copper, gold, and manganese, accompanied early volcanism. Te middle stage of volcanic activity was characterized by explosive eruption of rhyolitic ash-flow tuffs and collapse of the Dugway Valley cauldron. Eruption of the Joy Tuff 38 m.y. ago was accompanied by subsidence of this cauldron and was followed by collapse and sliding of Paleozoic rocks from the west wall of the cauldron. Landslides in The Dell were covered by the Dell Tuff, erupted 32 m.y. ago from an unknown source to the east. An ash flow of the Needles Range(?) Formation was erupted 30-31 m.y. ago from an unknown source. Mineralization probably did not occur during the rhyolitic stage of volcanism. The last stage of volcanism was contemporaneous with basin-and-range faulting and was characterized by explosive eruption of ash and pumice, forming stratified tuff, and by quiet eruption of alkali rhyolite as viscous flows and domes. The first episode of alkali rhyolite volcanism deposited the beryllium tuff and porphyritic rhyolite members of the Spor Mountain Formation 21 m.y. ago. After a period of block faulting, the stratified tuff and alkali rhyolite of the Topaz Mountain Rhyolite were erupted 6-7 m.y. ago along faults and fault intersections. Erosion of Spor Mountain, as well as explosive eruptions through dolomite, provided abundant dolomite detritus to the beryllium tuff member. The alkali rhyolite of both formations is fluorine rich, as is evident from abundant topaz, and contains anomalous amounts of lithophile metals. Alkali rhyolite volcanism was accompanied by lithophile metal mineralization which deposited fluorite, beryllium, and uranium. The structure of the area is dominated by the Thomas caldera and the younger Dugway Valley cauldron, which is nested within the Thomas caldera; the Thomas caldera is surrounded by a rim of Paleozoic rocks at Spor Mountain and Paleozoic to Precambrian rocks in the Drum Mountains. The Joy fault and Dell fault system mark the ring-fracture zone of the Thomas caldera. These structural features began to form about 39 m.y. ago during eruption of the Mt. Laird Tuff and caldera subsidence. The Dugway Valley cauldron sank along a series of steplike normal faults southeast of Topaz Mountain in response to collapse of the magma chamber of the Joy Tuff. Caldera structure was modified by block faulting between 21 and 7 m.y. ago, the time of widespread extensional faulting in the Basin and Range Province. Vents erupted alkali rhyolite 6-7 m.y. ago along basin-and-range faults.

Professional Paper↗

Porosity, strength, and alteration – Towards a new volcano stability assessment tool using VNIR-SWIR reflectance spectroscopy

Volcano slope stability analysis is a critical component of volcanic hazard assessments and monitoring. However, traditional methods for assessing rock strength require physical samples of rock which may be difficult to obtain or characterize in bulk. Here, visible to shortwave infrared (350–2500 nm; VNIR–SWIR) reflected light spectroscopy on laboratory-tested rock samples from Ruapehu, Ohakuri, Whakaari, and Banks Peninsula (New Zealand), Merapi (Indonesia), Chaos Crags (USA), Styrian Basin (Austria) and La Soufrière de Guadeloupe (Eastern Caribbean) volcanoes was used to design a novel rapid chemometric-based method to estimate uniaxial compressive strength (UCS) and porosity. Our Partial Least Squares Regression models return moderate accuracies for both UCS and porosity, with R 2 of 0.43–0.49 and Mean Absolute Percentage Error (MAPE) of 0.2–0.4. When laboratory-measured porosity is included with spectral data, UCS prediction reaches an R 2 of 0.82 and MAPE of 0.11. Our models highlight that the observed changes in the UCS are coupled with subtle mineralogical changes due to hydrothermal alteration at wavelengths of 360–438, 532–597, 1405–1455, 2179–2272, 2332–2386, and 2460–2490 nm. These mineralogical changes include mineral replacement, precipitation hydrothermal alteration processes which impact the strength of volcanic rocks, such as mineral replacement, precipitation, and/or silicification. Our approach highlights that spectroscopy can provide a first order assessment of rock strength and/or porosity or be used to complement laboratory porosity-based predictive models. VNIR-SWIR spectroscopy therefore provides an accurate non-destructive way of assessing rock strength and alteration mineralogy, even from remote sensing platforms.

Earth and Planetary Science Letters↗

The geochemical and textural transition between the Reef Package and its hanging wall, Stillwater Complex, Montana, USA

The highest grade Pd-Pt deposit on Earth, the J-M Reef, is hosted in coarse-grained to pegmatoidal cumulates called the Reef Package. Decades of mine development of the J-M Reef have revealed that a distinct discontinuity in rock fabric marks the top of the rock unit that hosts economic-grade sulfide mineralization. Mine geologists refer to this discontinuity as the hanging wall contact. This contact is the top of the Reef Package and is always locatable—either by the change in rock fabric or by distinctive hanging wall textures of silicate minerals—even when the reef sulfide mineralization is absent. This rather subtle textural feature is used reliably by mine geologists to follow the Reef during exploration and mine development. Although some high tenor sulfides (>1000 ppm Pd in 100% sulfide) are found sporadically in the hanging wall cumulates, these accumulations are too small to be economically viable. We present quantitative rock fabric data for four Reef Package and hanging wall intersections collected by electron back-scattered diffraction (EBSD). Plagioclase fabrics in the hanging wall are characterized by low variance in grain sizes and a strong point maximum concentration of (010) and a perpendicular girdle distribution of [100] consistent with an axial B-type fabric. These fabrics are indicative of either compaction of the crystal mush or crystal settling of nucleated crystals, the bulk magma in a chamber. Conversely, the fabrics of the Reef Package show higher variance grain in size distributions and weak to undeveloped preferred orientation of plagioclase crystals that did not undergo significant alignment or textural equilibration of plagioclase grains. The absence of foliation in the Reef Package stands in contrast both to hanging wall fabrics and to other reported EBSD datasets of plagioclase crystals orientations from the Bushveld Complex, the Skaergaard Intrusion, and the Rum Intrusion. Furthermore, plagioclase crystal size distributions for the Reef Package show flatter slopes and convex profiles with fewer crystals at small size fractions indicating the dissolution of small crystals during partial melting and textural coarsening (i.e . Ostwald ripening) and crystal growth. Crystal growth was favored over the nucleation of new crystals during prolonged interaction with a hot infiltrating melt into the resident mush resulting in the coarse-grained textures of the Reef Package cumulates. The hanging wall contact represents a boundary between partially remelted crystal mush of the Reef Package, where sulfide mineralization formed and accumulated, and an overlying essentially barren cumulate pile. The hanging wall cumulates formed following the cessation of footwall erosion and the resumption of crystal accumulation by normal magma chamber processes.

Montana↗

Geologic Map of the Eaton Reservoir Quadrangle, Larimer County, Colorado and Albany County, Wyoming

New geologic mapping of the Eaton Reservoir 7.5' quadrangle defines geologic relationships in the northern Front Range along the Colorado/Wyoming border approximately 35 km south of Laramie, Wyo. Previous mapping within the quadrangle was limited to regional reconnaissance mapping (Tweto, 1979; Camp, 1979; Burch, 1983) and some minor site-specific studies (Carlson and Marsh, 1986; W. Braddock, unpub. mapping, 1982). Braddock and others (1989) mapped the Diamond Peak 7.5' quadrangle to the east, Burch (1983) mapped rocks of the Rawah batholith to the south, W. Braddock (unpub. mapping, 1981) mapped the Sand Creek Pass 7.5' quadrangle to the west, and Ver Ploeg and Boyd (2000) mapped the Laramie 30' x 60' quadrangle to the north. Field work was completed during 2005 and 2006 and the mapping was compiled at a scale of 1:24,000. Minimal petrographic work and isotope dating was done in connection with the present mapping, but detailed petrographic and isotope studies were carried out on correlative map units in surrounding areas as part of a related regional study of the northern Front Range. Classification of Proterozoic rocks is primarily based upon field observation of bulk mineral composition, macroscopic textural features, and field relationships that allow for correlation with rocks studied in greater detail outside of the map area.

Scientific Investigations Map↗

Geologic map of the Sand Creek Pass quadrangle, Larimer County, Colorado, and Albany County, Wyoming

New geologic mapping within the Sand Creek Pass 7.5 minute quadrangle defines geologic relationships within the northern Front Range of Colorado along the Wyoming border approximately 35 km south of Laramie, Wyo. Previous mapping within the quadrangle was limited to regional reconnaissance mapping; Eaton Reservoir 7.5 minute quadrangle to the east (2008), granite of the Rawah batholith to the south (1983), Laramie River valley to the west (1979), and the Laramie 30' x 60' quadrangle to the north (2007). Fieldwork was completed during 1981 and 1982 and during 2007 and 2008. Mapping was compiled at 1:24,000-scale. Minimal petrographic work was done and no isotope work was done in the quadrangle area, but detailed petrographic and isotope studies were performed on correlative map units in surrounding areas as part of a related regional study of the northern Front Range. Stratigraphy of Proterozoic rocks is primarily based upon field observation of bulk mineral composition, macroscopic textural features, and field relationships that allow for correlation with rocks studied in greater detail outside of the map area. Stratigraphy of Phanerozoic rocks is primarily based upon correlation with similar rocks to the north in the Laramie Basin of Wyoming and to the east in the Front Range of Colorado.

Scientific Investigations Map↗

Mineral remains of early life on Earth? On Mars?

The oldest sedimentary rocks on Earth, the 3.8‐Ga Isua Iron‐Formation in southwestern Greenland, are metamorphosed past the point where organic‐walled fossils would remain. Acid residues and thin sections of these rocks reveal ferric microstructures that have filamentous, hollow rod, and spherical shapes not characteristic of crystalline minerals. Instead, they resemble ferric‐coated remains of bacteria. Modern so‐called iron bacteria were therefore studied to enhance a search image for oxide minerals precipitated by early bacteria. Iron bacteria become coated with ferrihydrite, a metastable mineral that converts to hematite, which is stable under high temperatures. If these unusual morphotypes are mineral remains of microfossils, then life must have evolved somewhat earlier than 3.8 Ga, and may have involved the interaction of sediments and molecular oxygen in water, with iron as a catalyst. Timing is constrained by the early in fall of planetary materials that would have heated the planet's surface. Because there are no earlier sedimentary rocks to study on Earth, it may be necessary to expand the search elsewhere in the solar system for clues to any biotic precursors or other types of early life. Evidence from Mars shows geophysical and geochemical differentiation at a very early stage, which makes it an important candidate for such a search if sedimentation is an important process in life's origins. Not only does Mars have iron oxide‐rich soils, but its oldest regions have river channels where surface water and sediment may have been carried, and seepage areas where groundwater may have discharged. Mars may have had an atmosphere and liquid water in the crucial time frame of 3.9–4.0 Ga. A study of morphologies of iron oxide minerals collected in the southern highlands during a Mars sample return mission may therefore help to fill in important gaps in the history of Earth's earliest biosphere.

Geomicrobiology Journal↗

Reconnaissance geologic map of the Solomon D-6 quadrangle, Seward Peninsula, Alaska

The Solomon D-6 15- by 30-minute quadrangle lies 20 miles northeast of Nome, Alaska, and adjoins on the east the Nome D-l quadrangle mapped by Hummel (1962b) and on the west the Solomon D-5 quadrangle mapped by Smith (1910). Placer gold has been produced from Iron Creek and many of its tributaries, and a small amount of copper was shipped from the Wheeler mine. Many lode prospects contain small amounts of copper in silicified limestone within and near the base of thrust plates of carbonate rocks. Other lodes consist of well-defined veins containing gold and base-metal sulfide minerals, but none has been commercially productive. Mapped rock units include the "York Slate," of Precambrian age, which consists of a highly deformed and thick sequence of graphitic calcareous siltite, which contains thin limestone beds and intercalated(?) volcaniclastic rocks, and Paleozoic carbonate rocks, which have been converted largely to marble and schistose marble. Along and near the Kigluaik Mountains in the north part of the quadrangle, quartzo-feldspathic gneisses of Precambrian age are intruded by fine-grained granite. A very thick sequence of schistose thin-bedded argillaceous and dolomitic limestone overlies the York Slate and is correlative with a similar rock originally mapped in the York Mountains. Surficial deposits, consisting principally of moraine and stream-reworked moraine, mantle large parts of the quadrangle.

Alaska↗

Groundwater resources of the Dallas-Monmouth area, Polk, Benton, and Marion Counties, Oregon

The Dallas-Monmouth area is in the west-central Willamette Valley of western Oregon. It comprises a total of about 400 square miles in Polk, Benton, and Marion Counties. Tertiary consolidated rocks underlie the entire area. These rocks include marine sandstone, siltstone, shale, tuff, basalt, and gabbro. In the lowlands, the consolidated rocks are overlain by unconsolidated deposits of clay, silt, sand, and gravel which reach a maximum thickness of about 125 feet locally. The consolidated rocks generally are poor water-bearing formations and yield only small quantities of ground water to wells. From 1956 to 1976, about 6 percent of all wells completed in basalt and 14 percent of those completed in marine sedimentary rocks were reported to be "dry holes." The median yield of wells completed in the consolidated rocks was less than 10 gallons per minute, and the maximum reported yield was 200 gallons per minute. Shallow ground water in the consolidated rocks is generally of good quality, but with increasing depth in these rocks the water contains increasing concentrations of dissolved minerals. It is estimated that about 5 percent of all the wells completed in the consolidated rocks yield poor-quality water. The best water-bearing units are sand-and-gravel beds in the unconsolidated deposits. Near Independence, the sand-and-gravel beds are hydraulically continuous and exceed a saturated thickness of 10 feet over an area covering several tens of square miles chiefly within the Willamette River flood plain. Properly constructed wells in these deposits can generally obtain yields of 100 to 500 gallons per minute, and large quantities of additional ground water can be developed from this source. Outside the above area, sand-and-gravel beds generally are less than 10 feet thick, lenticular in shape, local in extent, and generally yield less than 30 gallons per minute to wells. Sand-and-gravel beds probably are absent in the Baskett Slough drainage basin, in the E. E. Wilson Wildlife Management area, and in the Luckiamute and Little Luckiamute River valleys upstream from the U.S. Highway 99W bridge.

Oregon↗

Geology of the Anlauf and Drain Quadrangles, Douglas and Lane Counties, Oregon

The Anlauf and Drain quadrangles, Oregon, lie about 20 miles south of the city of Eugene, in Douglas and Lane Counties. They constitute an area of about 435 square miles that includes parts of both the Cascade Range and Coast Range physiographic provinces. A sequence of lower Tertiary sedimentary and volcanic rocks with a maximum thickness of about 20,000 feet is exposed in the area. The oldest part of this sequence is the Umpqua formation of early Eocene age consisting of a lower member of vesicular and amygdaloidal olivine basalt flows, a middle member of water-laid vitric and lapilli crystal tuff, and an upper member of interbedded fissile siltstone and basaltic sandstone which contains a 300-foot tongue of massive to thick-bedded basaltic sandstone near its top. These rocks are predominantly of marine origin, although the general absence of pillow structures which are common in basaltic lavas of equivalent age elsewhere in the Coast Ranges suggests that some of the flows were poured out subaerially. The overlying tuff member, however, contains Foraminifera and in places has a lime content slightly in excess of 10 percent. Mollusca and Foraminifera indicate that the Umpqua formation is of early Eocene age and is a correlative of the Capay formation of California. The Tyee formation of middle Eocene age overlies the Umpqua formation and consists of more than 5,000 feet of rhythmically deposited sandstone and siltstone in beds 2 to 30 feet thick. The basal part of each bed consists of medium- to coarse-grained sandstone that grades upward into fine-grained sand- stone and siltstone. The principal constituents of the sandstone are quartz, partly a1tered feldspar, mica, clay, and fragments of basalt, fine-grained argillaceous rocks, and mica schist. Other detrital minerals include epidote, garnet, blue-green hornblende, tourmaline, and zoisite. The depositional environment of the Tyee formation is poorly known, although the rhythmic-graded bedding suggests turbidity currents. About 500 feet of sandstone and siltstone assigned to the Spencer formation of late Eocene age unconformably overlies the Tyee formation. The Spencer formation, better exposed in the east-central part of the Coast Ranges, contains marine fossils but also has thin impure coal beds, indicative of strand-line accumulation. The sandstone in the Spencer formation is very similar to that in the Tyee formation, from which it was probably derived. The Fisher formation contains about 5,500 feet of nonmarine pyroclastic and volcanic rocks that are related to the volcanic rock sequences of the western Cascade Range. The formation is characterized by a wide variety of rock types, including conglomerate, tuffaceous sandstone and siltstone, vitric and crystal tuff, waterlaid and mudflow breccia, and andesitic lava flows. These rocks gen- erally occur in lenticular beds that have little stratigraphic significance. The rocks apparently accumulated on a plain slightly above sea level that was subjected alternately to fiooding by running water and to desiccation. Fossil leaves from the lowermost part of the Fisher formation are of late Eocene age; the upper part of the formation is of early, and possibly niiddle, Oligocene age. A few exposures of olivine basalt were mapped in the extreme northern part of the Anlauf quadrangle. The flows, more extensively exposed to the north, overlie the Fisher formation, and, therefore, are tentatively considered to be post-Oligocene in age. All these stratigraphic units, but principally the Fisher formation, are cut by dikes, sills, and stocklike bodies of 'porphyritic basalt, diabase, and norite. Contemporaneously with the emplacement of most of these rocks, in late Miocene (?) time, hydrothermal solutions locailly altered the sedimentary and extrusive igneous racks and deposited cinnabar and other sulfide minerals, carbonates, and silica. Three parallel nartheastward-trending

Bulletin↗

Evolution of the magmatic-hydrothermal acid-sulfate system at Summitville, Colorado: Integration of geological, stable-isotope, and fluid-inclusion evidence

The Summitville Au-Ag-Cu deposit is a classic volcanic dome-hosted high-sulfidation deposit. It occurs in the Quartz Latite of South Mountain, a composite volcanic dome that was emplaced along the coincident margins of the Platoro and Summitville calderas at 22.5??0.5 Ma, penecontemporaneous with alteration and mineralization. A penecontemporaneous quartz monzonite porphyry intrusion underlies the district and is cut and overlain by pyrite-quartz stockwork veins with traces of chalcopyrite and molybdenite. Alteration and mineralization proceeded through three hypogene stages and a supergene stage, punctuated by at least three periods of hydrothermal brecciation. Intense acid leaching along fractures in the quartz latite produced irregular pipes and lenticular pods of vuggy silica enclosed sequentially by alteration zones of quartz-alunite, quartz-kaolinite, and clay. The acid-sulfate-altered rocks host subsequent covellite+enargite/luzonite+chalcopyrite mineralization accompanied by kaolinite, and later barite-base-metal veins, some containing high Au values and kaolinite. The presence of both liquid- and vapor-rich fluid inclusions indicates the episodic presence of a low-density fluid at all levels of the system. In the mineralized zone, liquid-rich fluid inclusions in healed fractures in quartz phenocrysts and in quartz associated with mineralization homogenize to temperatures between 160 and 390 ??C (90% between 190 and 310 ??C), consistent with the range (200-250 ??C) estimated from the fractionation of sulfur isotopes between coexisting alunite and pyrite. A deep alunite-pyrite pair yielded a sulfur-isotope temperature of 390 ??C, marking a transition from hydrostatic to lithostatic pressure at a depth of about 1.5 km. Two salinity populations dominate the liquid-rich fluid inclusions. One has salinities between 0 and 5 wt.% NaCl equivalent; the other has salinities of up to 43 wt.% NaCl equivalent. The occurrence of high-salinity fluid inclusions in vein quartz associated with mineralization, as well as in the deep stockwork veins, suggests that brines originating deep in the system transported the metals. The ??34S values of sulfides in magnetite (-2.3???) and of sulfate in apatite (5.4???) in unaltered quartz latite indicate that ??34S???S was near 0???. The ??34S values of coexisting alteration alunite and pyrite are 18.2??? to 24.5??? and -8.1??? to -2.2???, respectively. Deep in the system, most of the change in ??34S values occurs in the sulfates, indicating that the fluids were initially H2S-dominant, their redox state buffered at depth by equilibration with igneous rocks. However, in the main alteration zone, most of the change in ??34S values occurs in pyrite, indicating that the fluids moved off the rock buffer and became SO42- -dominant as pyrite precipitated and SO2 disproportionation produced the sulfuric acid requisite for acid leaching. The ??34S values of the late-stage barite and sulfides indicate that the system returned to high H2S/SO42- ratios typical of the original rock-buffered fluid. The ??DH2O of alunite parent fluids was near -45??? and their ??18O ranged from 7??? to -1???, depending on the degree of exchange in the alteration zone at low water-rock ratio, or mixing with unexchanged meteoric water. The low ??D values of some alunite samples are interpreted to result from postdepositional exchange with later ore fluids. Fluid exsolved fr om the magma at depth had ??DH2O and ??18OH2O values near -70??? and 10???, respectively. During and following migration to the top of the magma chamber, the fluid underwent isotopic exchange with the partially crystallized magma and its solid and cooler, but still plastic, carapace just below the transition from a lithostatic to hydrostatic pressure regime. These evolved magmatic fluids had ??DH2O and ??18OH2O values close to -40??? and 5???, respectively, prior to release into the superjacent hydrostatically pressured fracture zone, wherein the fluids separat

Chemical Geology↗

Peralkaline and peraluminous granites and related mineral deposits of the Arabian Shield, Kingdom of Saudi Arabia

In the Precambrian Arabian Shield, granitoid plutonic rocks are widespread and range in age from 800 to 550 Ma old; but the mineral-resource potential associated with these plutonic rocks is restricted mainly to the younger, postorogenic granites. Two granite types of current economic interest are zirconium- niobium-enriched per alkaline granites and tin-tungsten-enriched peraluminous granites. Both types are highly evolved, are enriched in lithium, rubidium, and fluorine, and have distinctive mineralogy, textures, and chemistry. The zirconium-niobium-enriched granites are related to medium- to large-sized plutons and complexes of peralkaline granite, and the tin-tungsten-enriched granites are related to medium-sized plutons of biotite or biotite-muscovite granite. Existing geochemical and geologic data for many parts of the Arabian Shield were compiled as a basis for evaluating the resource potential of the granites of the Shield. Commodities associated with granites that have potential for economic mineral deposits include tin, tungsten, molybdenum, beryllium, niobium, tantalum, zirconium, uranium, thorium, rare-earth elements, and fluorite. Prospecting methods useful in discriminating those granites having significant economic potential include reconnaissance geologic mapping, petrographic and mineralogic studies, geochemical sampling of rock and wadi sediment, and radiometric surveying.

Open-File Report↗

Mineral deposits of the Mesoproterozoic Midcontinent Rift system in the Lake Superior region – A space and time classification

The Mesoproterozoic Midcontinent Rift System (MRS) of North America hosts a diverse suite of magmatic and hydrothermal mineral deposits in the Lake Superior region where rift rocks are exposed at or near the surface. Historically, hydrothermal deposits, such as Michigan’s native copper deposits and the White Pine sediment-hosted stratiform copper deposit, were major MRS metal producers. On-going exploration for and potential development of copper-nickel sulfide deposits hosted by the Duluth Complex of Minnesota and the opening of the Eagle nickel mine in Michigan indicate an expanding interest in MRS magmatic deposits. MRS hydrothermal and magmatic mineral deposits, many of which are significant past, present, and likely future providers of critical minerals, here are placed into a space and time metallogenic framework. To construct this framework, regional MRS mineral deposits extracted from the U.S. Geological Survey Mineral Resources Data System (MRDS) and the Ontario Ministry of Energy, Northern Development and Mines Mineral Deposit Inventory (MDI) were supplemented by other known and recently recognized mineral deposits described in the literature. All mineral deposits were classified by deposit type, host rock age and type, and estimated timing of mineralization. Deposits were then put into a tectonic evolutionary framework (stages) for the MRS, which shows that deposits formed within discrete spatial and temporal stages of rift evolution.

Lake Superior region↗

Rare earth mineral potential in the southeastern U.S. Coastal Plain from integrated geophysical, geochemical, and geological approaches

We combined geophysical, geochemical, mineralogical, and geological data to evaluate the regional presence of rare earth element (REE)−bearing minerals in heavy mineral sand deposits of the southeastern U.S. Coastal Plain. We also analyzed regional differences in these data to determine probable sedimentary provenance. Analyses of heavy mineral separates covering the region show strong correlations between thorium, monazite, and xenotime, suggesting that radiometric equivalent thorium (eTh) can be used as a geophysical proxy for those REE-bearing minerals. Airborne radiometric data collected during the National Uranium Resource Evaluation (NURE) program cover the southeastern United States with line spacing varying from ∼2 to 10 km. These data show eTh highs over Cretaceous and Tertiary Coastal Plain sediments from the Cape Fear arch in North Carolina to eastern Alabama; these highs decrease with distance from the Piedmont. Quaternary sediments along the modern coasts show weaker eTh anomalies, except near coast-parallel ridges from South Carolina to northern Florida. Prominent eTh anomalies are also observed over large riverbeds and their floodplains, even north of the Cape Fear arch where surrounding areas are relatively low. These variations were verified using ground geophysical measurements and sample analyses, indicating that radiometric methods are a useful exploration tool at varying scales. Further analyses of heavy mineral separates showed regional differences, not only in concentrations of monazite, but also of rutile and staurolite, and in magnetic susceptibility. The combined properties suggest the presence of subregions where heavy mineral sediments are primarily sourced from high-grade metamorphic, low-grade metamorphic, or igneous terrains, or where they represent a mixing of these sources. Comparisons between interpreted sources of heavy mineral sands near the Fall Line and igneous and metamorphic Piedmont and Blue Ridge units showed a strong correspondence with rocks closest to the Fall Line and poor correspondence with rocks farther inland. This strongly suggests that the primary source of those heavy minerals, especially monazite, is the rocks that formed the rocky coast that was present during opening of the Atlantic Ocean, which in turn indicates the importance of coastal processes in forming heavy mineral sand concentrations. Furthermore, narrow radiometric eTh and K anomalies are associated with major rivers, indicating limited spatial influence of fluvial processes. Later coastal plain sediment deposition appears to have involved reworking of sediments, providing an “inheritance” of the rocky coast composition that persists for some distance from the Fall Line. However, this inheritance is reduced with distance, and sediments within ∼100 km of the coast in Georgia and Florida exhibit properties indicative of mixing from multiple sources.

GSA Bulletin↗

Metallization and post-mineral hypogene argillization, Lost River tin mine, Alaska

The Lost River tin and tungsten deposit occurs in a buried granite pluton and in associated rhyolite dikes that intrude Paleozoic limestone. The dikes and parts of the granite were greisenized and then argillized irregularly. Metallization accompanied greisenization rather than argilli-zation, although both processes probably were closely related in time. Iron-zinc ratios in sphalerite indicate that the ore minerals were deposited at a temperature between 425°C and 740°C. This temperature is within the range of the temperatures at which topaz, a comman associate of the ore minerals, has been synthesized in the laboratory. The temperature of deposition of the ore minerals is above the temperature interval in which clay minerals are stable. Thus, clay minerals could not have formed while ore was being deposited. As temperatures fell and entered the stability range of the clay minerals, argillic alteration encroached upon greisen ores and wall rocks. Reaction rims between quartz and topaz indicate that kaolinite could have formed according to the following reaction: topaz + quartz + water + limestone -* kaolinite + fluorite + Cajj"C (Al,F)2Si04 + Si02 +3H2O+ CaCOa - Al2Si20B(OH)41 + CaF2 + H2CO3 The clay minerals, which formed from diverse rock types, consist of kaolinite, dickite, mixed-layered chlorite-montmorillonite, and minor montmorillonite, accompanied by variable amounts of muscovite and zinnwaldite. The dickite is most common in and near late veins that cut the earlier-formed greisen. Temperature is believed to be the principal agent governing the relations between ore deposition and argillization . Similar relations are to be expected in other high-temperature deposits where abundant veining and fracturing indicate that wall rocks reached an isothermal condition above a maximum temperature of 480°C during ore deposition.

Bering land bridge↗