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Petrology and geochemistry of the 2006 eruption of Augustine Volcano: Chapter 15 in The 2006 eruption of Augustine Volcano, Alaska

Deposits from the 2006 eruption of Augustine Volcano, Alaska, record a complex history of magma mixing before and during the eruption. The eruption produced five major lithologies: low-silica andesite scoria (LSAS; 56.5 to 58.7 weight percent SiO 2 ), mostly during the initial explosive phase; high-silica andesite pumice (HSA; 62.2 to 63.3 weight percent SiO 2 ), prevalent during the continuous phase; dense low-silica andesite (DLSA; 56.4 to 59.3 weight percent SiO 2 ), predominantly during the late effusive phase; and dense intermediate andesite (DIA) and banded clasts, present throughout the eruption but most abundant in the continuous phase. The DIA and banded clasts have compositions that fall between and partially overlap the ranges noted above. All rock types are phenocryst-rich (36 to 44 volume percent), containing plagioclase, orthopyroxene, augite, Fe-Ti oxides, olivine, and rare amphibole, apatite, and anhydrite. Glasses from tephra and flow-deposit clasts range from 66 to nearly 80 weight percent SiO 2 and represent highly evolved melt relative to the bulk rock compositions. Fe-Ti oxides recorded f O2 ~2 log units above the Ni-NiO buffer and temperatures of 904±47°C and 838±14°C from LSAS and HSA samples, respectively, with the intermediate lithologies falling in the middle of these ranges. The dense low-silica andesite and scoria (collectively LSA) are compositionally nearly identical, and trace-element patterns show that the HSA is not the result of shallow crustal fractionation of the LSA. The petrological and geochemical data indicate that two-component magma mixing between the LSA and HSA caused the compositional spread in eruptive products. The phenocryst population in the LSA suggests that it represents a hybrid formed from the HSA and an unerupted, basaltic “replenishing” magma. On the basis of petrological and geophysical observations reported here and elsewhere in this volume, the HSA was stored as a crystal-rich mush with its top at ~5-km depth. An influx of basalt remobilized and partially mixed with a portion of the mush, forming the hybrid LSA. The lower viscosity LSA ascended towards the surface as a dike, erupting during the explosive phase in mid-January 2006. In late January, a large explosion produced the first significant volumes of HSA, followed by several days of rapid HSA effusion during the eruption’s continuous phase. After a three-week hiatus marked by elevated gas output, signifying an open system, degassed LSA erupted during the final, effusive phase. Consistency in eruptive styles and compositions suggests that the HSA magma body may have been similarly rejuvenated during the past several eruptions.

Alaska↗

Uranium-lead isotopic ages from the Sierra Nevada Batholith, California

This study provides new information on the timing and distribution of Mesozoic magmatic events in the Sierra Nevada batholithic complex chiefly between 36° and 37°N. latitude. U-Pb ages have been determined for 133 zircon and 7 sphene separates from 82 samples of granitoid rocks. Granitoid rocks in this area range in age from 217 to 80 m.y. Triassic intrusions are restricted to the east side of the batholith; Jurassic plutons occur south of the Triassic plutons east of the Sierra Nevada, as isolated masses within the Cretaceous batholith, and in the western foothills of the range; Cretaceous plutons form a continuous belt along the axis of the batholith and occur as isolated masses east of the Sierra Nevada. No granitic intrusions were emplaced for 37 m.y. east of the Sierra Nevada following the end of Jurassic plutonism. However, following emplacement of the eastern Jurassic granitoids, regional extension produced a fracture system at least 350 km long into which the dominantly mafic, calc-alkalic Independence dike swarm was intruded 148 m.y. ago. The dike fractures probably represents a period of regional crustal extension caused by a redistribution of the regional stress pattern accompanying the Nevadan orogeny. Intrusion of Cretaceous granitic plutons began in large volume about 120 m.y. ago in the western Sierra Nevada and migrated steadily eastward for 40 m.y. at a rate of 2.7 mm/y. This slow and constant migration indicates remarkably uniform conditions of subduction with perhaps downward migration of parent magma generation or a slight flattening of the subduction zone. Such steady conditions could be necessary for the production of large batholithic complexes such as the Sierra Nevada. The abrupt termination of plutonism 80 m.y. ago may have resulted from an increased rate of convergence of the American and eastern Pacific plates and dramatic flattening of the subduction zone. U-Pb ages of the Giant Forest-alaskite sequence in Sequoia National Park are all in the range 99±3 m.y., indicating a relatively short period of emplacement and cooling for this nested group of plutons. U-Pb ages of a mafic inclusion and its host granodiorite indicate that both were derived from a common source or that the mafic inclusion was totally equilibrated with the granodioritic magma. Comparison of isotopic ages determined by different methods such as zircon U-Pb, sphene U-Pb, hornblende K-Ar, and biotite K-Ar suggests that zircon U-Pb ages generally approximate the emplacement age of a pluton. However, some plutons probably contain inherited or entrained old zircons, and the zircons of some samples are disturbed by younger thermal and metamorphic events. The ages reported here are consistent with U-Pb age determinations previously made on granitic rocks to the north [Stern et al., 1981], The age distribution of granitic belts determined here is in general agreement with those established by K-Ar dating [Evernden and Kistler, 1970] but does not differentiate the five epochs of plutonism determined in their study.

California↗

Arsenic(III) fuels anoxygenic photosynthesis in hot spring biofilms from Mono Lake, California

Phylogenetic analysis indicates that microbial arsenic metabolism is ancient and probably extends back to the primordial Earth. In microbial biofilms growing on the rock surfaces of anoxic brine pools fed by hot springs containing arsenite and sulfide at high concentrations, we discovered light-dependent oxidation of arsenite [As(III)] to arsenate [As(V)] occurring under anoxic conditions. The communities were composed primarily of Ectothiorhodospira-like purple bacteria or Oscillatoria-like cyanobacteria. A pure culture of a photosynthetic bacterium grew as a photoautotroph when As(III) was used as the sole photosynthetic electron donor. The strain contained genes encoding a putative As(V) reductase but no detectable homologs of the As(III) oxidase genes of aerobic chemolithotrophs, suggesting a reverse functionality for the reductase. Production of As(V) by anoxygenic photosynthesis probably opened niches for primordial Earth's first As(V)-respiring prokaryotes.

Science↗

Duststones on Mars: Source, transport, deposition and erosion

Dust is an abundant material on Mars, and there is strong evidence that it is a contributor to the rock record as “duststone,” analogous in many ways to loess on Earth. Although a common suite of dust formation mechanisms has operated on the two planets, fundamental differences in environments and geologic histories have resulted in vastly different weighting functions, causing distinct depositional styles and erosional mechanisms. On Earth, dust is derived predominantly from glacial grinding and, in nonglacial environments, by other processes, such as volcanism, eolian abrasion, and fluvial comminution. Hydrological and biological processes convert dust accumulations to loess deposits. Active hydrology also acts to clean dust from the atmosphere and convert loess into soil or erode it entirely. On Mars, glacial production of dust has been minor, with most fine particles probably produced from ancient volcanic, impact, and fluvial processes. Dust is deposited under arid conditions in which aggregate growth and cementation are the stabilizing agents. Thick accumulations result in duststone.

SEPM Special Publication↗

Geologic map of the eastern quarter of the Flagstaff 30’ x 60’ quadrangle, Coconino County, northern Arizona

The eastern quarter of the Flagstaff 30′ x 60′ quadrangle includes eight USGS 1:24,000-scale quadrangles in Coconino County, northern Arizona (fig. 1, map sheet): Anderson Canyon, Babbitt Wash, Canyon Diablo, Grand Falls, Grand Falls SE, Grand Falls SW, Grand Falls NE, and Meteor Crater. The map is bounded by lat 35° to 35°30′ N. and long 111° to 111°15′ W. and is on the southern part of the Colorado Plateaus geologic province (herein Colorado Plateau). Elevations range from 4,320 ft (1,317 m) at the Little Colorado River in the northwest corner of the map area to about 6,832 ft (2,082 m) at the southwest corner of the map. This geologic map provides an updated geologic framework for the eastern quarter of the Flagstaff 30′ x 60′ quadrangle and is adjacent to two other recent geologic maps, the Cameron and Winslow 30′ x 60′ quadrangles (Billingsley and others, 2007, 2013). This geologic map is the product of a cooperative effort between the U.S. Geological Survey (USGS) and the Navajo Nation. It provides geologic information for resource management officials of the U.S. Forest Service, the Arizona Game and Fish Department, and the Navajo Nation Reservation (herein the Navajo Nation). Funding for the map was provided by the USGS geologic mapping program, Reston, Virginia. Field work on the Navajo Nation was conducted under a permit from the Navajo Nation Minerals Department. Any persons wishing to conduct geologic investigations on the Navajo Nation must first apply for, and receive, a permit from the Navajo Nation Minerals Department, P.O. Box 1910, Window Rock, Arizona 86515, telephone (928) 871-6587.

Arizona↗

Preliminary depth to basement modeling at Salton Sea, California

The San Andreas Fault – Imperial Fault (SAF-IF) transtensional step-over zone along the southern margin of the Salton Sea hosts substantial geothermal production and lithium brine resources. Recent volcanism at the Salton Buttes and active seismicity along the SAFIF fault system highlight active tectonic and magmatic processes that pose natural hazards and may impact energy and mineral production. Characterizing the subsurface architecture and extent of concealed alteration associated with this tectono-magmatic system enhances understanding of these active processes, associated hazards, and resources. We have compiled a gravity database, consisting of new and re-processed existing data, from which we have constructed a new isostatic residual gravity anomaly map of the Salton trough. We have used this new gravity dataset together with a compilation of publicly available borehole data to develop new depth to basement inversion models for the region. These depth to basement models help to constrain basin geometries, inform alteration mapping, and reveal variations in basement rocks. Due to the concealed nature of the complex tectonic framework at the Salton trough, it is necessary to utilize geophysical methods for subsurface characterization. These new depth to basement models are a first step toward constructing 2D and 3D geophysical and geologic models of the Imperial Valley and Salton Sea geothermal area. This analysis complements other geophysical initiatives, including magnetotelluric (MT) modeling (Tokmakoff et al., 2024), magnetic mapping (Glen and Earney, 2023, 2024) and potential field modeling, and seismic studies focused on hazard and resource investigations in the Imperial Valley.

California↗

Ground-water resources of Snohomish County, Washington

Snohomish County comprises an east-west strip, six townships wide, extending 60 miles from the eastern shore of Puget Sound to the drainage divide of the Cascade Mountains. Topographically, the eastern two-thirds of the county varies frown hills and low mountain spurs at the west to the continuous high, maturely carved mountains of the Cascade Range at the east. The western third of the county lies in the Puget Sound lowland section: it is made up largely of unconsolidated deposits, as contrasted with the hard rocks of the mountain section. High-level deposits of glacial debris in some places form a transitional ramp from the lowlands to the mountain topography; in other places the transition is abrupt. The principal rivers--the Snohomish, Skykomish, Stillaguamish, and Sauk--drain westward and northwestward to Puget Sound. The Puget Sound lowland, with its extensions up the river valleys, is economically the important part. of the county. Within that part., ground-water development is of particular importance. The climate is equable and dominantly oceanic, with an average of about 32 h. of rainfall annually, but with a pronounced dry season from June to September. A mean annual temperature of 52 F, a growing season of more than 200 days, and a variety of good soils form a setting in which supplemental irrigation can at least double the average crop production. Within the coastal lowland, plateau segments 200 to 600 ft or more in altitude are separated by flat-bottomed, alluviated river gorges. The river flats in some eases represent the surface of as much as 500 to 600 ft of glacial and alluvial deposits backfilled into canyonlike arms of the aneestral drainage system. The plateau segments are formed of the till-smoothed remnants of bedrock or the tabular segments of Pleistocene deposits. The Pleistocene deposits consist, above sea level, of about 200 ft of Admiralty clay and as much as 1,000 ft of deposits of the Vashon glaciation. The latter include as much as 300 ft of either clay or sand units of advance outwash, up to 150 ft of till, and variable thicknesses of outwash-terrace and train material. The Admiralty clay is composed largely of clayey materials without important quantities of ground water. Similar clayey sediments are known to continue downward for more than 1,000 ft below sea level. The sand unit and, to a lesser extent, the clay unit, are largely advance outwash of the Vashon glaciation. They are water bearing, and the position of their ground-water reservoirs--in flat-shaped bodies perched on the Admiralty clay beneath the plateau surfaces and slopes--makes them particularly susceptible to useful development. The till is a persistent ground-moraine deposit that mantles most of the area of the plateau segments and passes beneath much of the outwash and alluvium of the valleys. The till is a great vaster of precipitation; it. sheds off to the creeks much water that would otherwise recharge the ground-water reservoirs. A small amount of water percolates irregularly into and through the till or accumulates in the soil zones on top, where it is tapped by a great many 'hardpan' wells of small yield. Outwash terraces of gravels and sands, where they lie below the local water table, carry large quantities of ground water. The alluvial materials of the river valleys are good aquifers, but the water is iron bearing in many places and is saline in places in the lower parts of the Snohomish and Stillaguamish Valleys. At present, no good aquifers are known to exist in the bedrock formations. The metamorphic, granitic, and volcanic rocks of the mountainous parts of the county are largely nonpermeable. The Tertiary strata, which underlie the coastal lowland at depth and crop out about its inner margin, contain little or no water, and that which is present is usually of poor quality. The chemical quality of the ground waters is in general excellent. The iron- bearing water of the alluvial valleys is the princ

Water Supply Paper↗

Accumulation of fossil fuels and metallic minerals in active and ancient rift lakes

A study of active and ancient rift systems around the world suggests that accumulations of fossil fuels and metallic minerals are related to the interactions of processes that form rift valleys with those that take place in and around rift lakes. The deposition of the precursors of petroleum, gas, oil shale, coal, phosphate, barite, Cu-Pb-Zn sulfides, and uranium begins with erosion of uplifted areas, and the consequent input of abundant nutrients and solute loads into swamps and tectonic lakes. Hot springs and volcanism add other nutrients and solutes. The resulting high biological productivity creates oxidized/reduced interfaces, and anoxic and H 2 S-rich bottom waters which preserves metal-bearing organic tissues and horizons. In the depositional phases, the fine-grained lake deposits are in contact with coarse-grained beach, delta, river, talus, and alluvial fan deposits. Earthquake-induced turbidites also are common coarse-grained deposits of rift lakes. Postdepositional processes in rifts include high heat flow and a resulting concentration of the organic and metallic components that were dispersed throughout the lakebeds. Postdepositional faulting brings organic- and metal-rich sourcebeds in contact with coarse-grained host and reservoir rocks. A suite of potentially economic deposits is therefore a characteristic of rift valleys.

Tectonophysics↗

Demersal fish distribution and habitat use within and near Baltimore and Norfolk Canyons, U.S. Middle Atlantic Slope

Numerous submarine canyons along the United States middle Atlantic continental margin support enhanced productivity, diverse and unique habitats, active fisheries, and are vulnerable to various anthropogenic disturbances. During two cruises (15 Aug–2 Oct 2012 and 30 Apr–27 May 2013), Baltimore and Norfolk canyons and nearby areas (including two cold seeps) were intensively surveyed to determine demersal fish distributions and habitat associations. Overall, 34 ROV dives (234–1612 m) resulted in 295 h of bottom video observations and numerous collections. These data were supplemented by 40, 30-min bottom trawl samples. Fish observations were assigned to five general habitat designations: 1) sand-mud (flat), 2) sloping sand-mud with burrows, 3) low profile gravel, rock, boulder, 4) high profile, canyon walls, rocks or ridges, and 5) seep-mixed hard and soft substrata, the later subdivided into seven habitats based on amounts of dead mussel and rock cover. The influence of corals, sponges and live mussels (seeps only) on fish distributions was also investigated. Both canyon areas supported abundant and diverse fish communities and exhibited a wide range of habitats, including extensive areas of deep-sea corals and sponges and two nearby methane seeps (380–430 m, 1455–1610 m). All methods combined yielded a total of 123 species of fishes, 12 of which are either new records for this region or have new range data. Depth was a major factor that separated the fish faunas into two zones with a boundary around 1400 m. Fishes defining the deeper zone included Lycodes sp.,Dicrolene introniger, Gaidropsaurus ensis, Hydrolagus affinis, Antimora rostrata, andAldrovandia sp. Fishes in the deep zone did not exhibit strong habitat affinities, despite the presence of a quite rugged, extensive methane seep. We propose that habitat specificity decreases with increasing depth. Fishes in the shallower zone, characterized by Laemonema sp., Phycis chesteri, Nezumia bairdii, Brosme brosme, and Helicolenus dactylopterus, exhibited a variety of habitat use patterns. In general, fish assemblages in the soft substrata areas (dominated by P. chesteri, N. bairdii, Glyptocephalus cynoglossus, Lophius americanus, Merluccius albidus) were different from those in more complex habitats (dominated by Laemonema spp., Hoplostethus spp., B. brosme,Benthocometes robustus, L. americanus, Dysommina rugosa). Although, when present, the dense coral and sponge cover did not statistically affect general fish assemblage patterns in hard bottom habitats, these sessile organisms markedly increased habitat complexity, and some fish species exhibited close association with them. Fish species compositions in the two canyons were not substantially different from the surrounding slopes. However, the diversity of habitats within both the canyons and seeps exerted an important influence on assemblage structure. At least for some species (e.g., B. brosme) canyon and seep environments may be a refuge from intensive bottom fishing activities. We frequently observed evidence of commercial and recreational fishing activity (lost gear on bottom and fishing boats in the area) throughout the canyons and some resulting habitat damage. Conservation measures for the unique and more vulnerable areas (seep and coral habitats) have recently been approved.

Baltimore Canyon, Norfolk Canyon↗

Geoenvironmental model for roll-type uranium deposits in the Texas Gulf Coast

Geoenvironmental models were formulated by the U.S. Geological Survey in the 1990s to describe potential environmental effects of extracting different types of ore deposits in different geologic and climatic regions. This paper presents a geoenvironmental model for roll-front (roll-type) uranium deposits in the Texas Coastal Plain. The model reviews descriptive and quantitative information derived from environmental studies and existing databases to depict existing conditions and potential environmental concerns associated with mining this deposit type. This geoenvironmental model describes how features of the deposits including host rock; ore and gangue mineralogy; geologic, hydrologic, and climatic settings; and mining methods (legacy open-pit and in situ recovery [ISR]) influence potential environmental effects from mining. Element concentrations in soil and water are compared to regulatory thresholds to depict ambient surface water and groundwater conditions. Although most open-pit operations in this region have been reclaimed, concerns remain about groundwater quality at three of the four former mills that supported former open-pit mines and are undergoing closure activities. The primary environmental concerns with ISR mining are (1) radon gas at active ISR operations, (2) radiation or contaminant leakage during production and transport of ISR resin or yellowcake, (3) uranium excursions into groundwater surrounding active ISR operations, and (4) contamination of groundwater after ISR mining. Although existing regulations attempt to address these concerns, some problems remain. Researchers suggest that reactive transport modeling and a better understanding of geology, stratigraphy, and geochemistry of ISR production areas could minimize excursions into surrounding aquifers and improve results of groundwater restoration.

Texas↗

Response to critique by lucas et al. (2009) of paper by Fassett (2009) documenting Paleocene dinosaurs in the San Juan Basin

In this issue of Palaeontologia Electronica Lucas, et al. (2009) question the validity f the Fassett (2009) paper that presented evidence for Paleocene dinosaurs in the San Juan Basin of New Mexico and Colorado. Their challenges focus primarily on the lithostratigraphy, palynology, and paleomagnetism of the dinosaur-bearing Ojo Alamo Sandstone, shown by Fassett to be of Paleocene age. The lithostratigraphy of the Ojo Alamo is addressed by Lucas et al. (2009) based on detailed studies of outcrops of this formation in two relatively small areas in the southern San Juan Basin where Ojo Alamo dinosaur fossils have been found. When viewed over its 13,000 km2 extent, the Ojo Alamo is seen to be a much more complex formation than these authors recognize, thus their perception and description of the lithostratigraphy of this rock unit is limited and provincial. Fassett (2009) presented a detailed discussion of the palynology of the rocks adjacent to the Cretaceous-Tertiary (K-T) interface in the San Juan Basin, including a 67-page appendix and 25 tables listing the 244 palynomorph species identified from these strata. The Ojo Alamo Sandstone produced 103 palynomorphs from five principal localities including one especially prolific sample set from drill core through K-T strata. Without exception, all samples collected from the Ojo Alamo Sandstone for palynologic analysis were found to contain Paleocene palynomorph assemblages. Lucas et al. challenge only one Ojo Alamo palynomorph assemblage from one of the five areas studied, stating that they were unable to find palynomorph-productive samples at that locality. They submit no new palynologic data that refutes the Paleocene palynologic age of the Ojo Alamo Sandstone. In addressing the paleomagnetism of the Ojo Alamo, these authors dismiss the presence of a critical normal-polarity magnetochron discovered in the lower part of the Ojo Alamo - magnetochron C29n.2n of Fassett (2009) with no evidence to justify this dismissal. This magnetochron has been identified at five localities in the basin, thus its existence seems unquestionable. At the Mesa Portales locality, this normal chron was found in Ojo Alamo strata containing Paleocene palynomorph assemblages verifying its identification as chron C29n. Other minor arguments of Lucas et al. (2009) are also addressed in this paper. In sum, Lucas et al. (2009) present no new data to contradict the data presented in Fassett (2009).

Palaeontologia Electronica↗

Geology and undiscovered resource assessment of the potash-bearing, Middle Devonian (Givetian), Prairie Evaporite, Elk Point Basin, Canada and United States

The U.S. Geological Survey (USGS) assessed undiscovered potash resources in the Elk Point Basin in Canada and the United States as part of a global mineral resource assessment. The Elk Point Basin is a large, Middle Devonian (Givetian) intracratonic evaporite basin covering approximately 1,200,000 square kilometers (km 2 ) and filled mainly with marine evaporite and minor clastic sedimentary rocks that contain stratabound potash-bearing salt. The potash-bearing salt is concentrated in four stratigraphic members (Patience Lake, Belle Plaine, White Bear, and Esterhazy) in the upper 100 meters (m) of the Prairie Evaporite and are separated by beds of halite (NaCl) that contain lesser—presently non-economic—amounts of sylvite (KCl) and carnallite (KMgCl 3 ·6H 2 O). The principal ore-bearing salt contains mainly sylvite. Four permissive tracts were defined that permit the presence of undiscovered stratabound potash (both sylvite- and carnallite-bearing salt) using geological criteria. Permissive tracts are defined by the spatial extent of each stratigraphic member that is at least 1 m thick, are less than 3 kilometers (km) from the surface, contain at least 4 percent equivalent potassium oxide (K 2 O), and contain the currently known resources. The permissive tracts include known potash deposits and potash occurrences as wells or mines not in production and show where undiscovered potash resources may be present. Well data are used to define the extent, thickness, average K 2 O equivalent grades, and volumes of each member. Data were supplied by the Saskatchewan Geological Survey or were obtained from published National Instrument (NI) 43-101 technical reports and other published reports, such as annual 10-K reports or news releases. The Elk Point Basin is the world’s largest source of potash, producing 23.0 million metric tons (Mt) of potassium chloride (KCl) (the equivalent of about 14.4 Mt of K 2 O) in 2018. In terms of global importance, the Elk Point Basin may contain 40 to greater than 50 percent of the world’s potash resources. Since 1962, potash companies have mined more than 1.5 trillion metric tons of ore containing 605 Mt of KCl (the equivalent of about 380 Mt of K 2 O). The total value of the ore produced through 2018 is on the order of $70 trillion (CAD). Potash is currently produced from eight conventional and three underground solution mines at depths ranging from 900 m to nearly 1,800 m. Estimates of the amount of potash in the Elk Point Basin vary considerably and the data and methods used in those estimations are not well documented. Known potash resources are approximately 99 billion metric tons (Bt) of ore containing 22 Bt of K 2 O equivalent. As a result of new mine openings and increased production capacity at existing mines, the total production capacity of mines in the Elk Point Basin has increased significantly (to about 32.8 Mt of KCl or 22.8 Mt of K 2 O equivalent per year). Additional production capacity of about 31 Mt of KCl (or 17 Mt of K 2 O equivalent) per year could be realized over the next decade if several current (as of 2019) exploration and development projects reach production status. Stratabound potash-bearing salt of the Prairie Evaporite presently underlies a total area of about 188,000 km 2 and has a total volume of about 2,690 cubic kilometers (km 3 ). Post-depositional solution processes considerably modified the mineralogy and presence of the potash-bearing salt. These changes had a profound effect on the volume and grade of potash resources that remained in the Prairie Evaporite and are a major consideration of exploration and mining operations as well as in this assessment of undiscovered potash resources. This USGS assessment includes the locations and possible amounts of undiscovered potash resources in the Prairie Evaporite. Volumes for each stratigraphic member were computed using member thicknesses and areal extent modified by actual, estimated geologic loss owing to salt dissolution and extraction ratios, as well as estimated distribution of carnallite and sylvite. Both sylvite- and carnallite-bearing salts were assessed for potash in this study. The assessment uses modern published grade and tonnage data. The amount of undiscovered potash is estimated by using Monte Carlo simulations to combine volume estimates of the potash-bearing members with probability distributions for average grade and bulk density. Mean potash grades (expressed as percentage of K 2 O equivalent) calculated using drill core analyses are 17.76 for the Patience Lake Member, 15.98 for the Belle Plaine Member, 10.66 for the White Bear Member, and 15.30 for the Esterhazy Member. Geologic losses reported as extraction ratios during mining may range from 27.5 to 41.6 percent and are dependent on mining method and local geologic conditions. The assessment determined that mean estimated undiscovered K 2 O equivalent resources for the Patience Lake, Belle Plaine, White Bear, and Esterhazy Members are 340, 220, 34, and 190 Bt, respectively, and estimated a total mean of 790 Bt for the entire Prairie Evaporite above a depth of 3 km. The total mineralized rock tonnage is estimated to be about 5,000 Bt. Most of the assessed potash is located within Saskatchewan with lesser amounts in Alberta and Manitoba as well as Montana and North Dakota within the United States. Although carnallite is mined for potash in Europe, it has historically been avoided in mining plans for potash-producing companies in Saskatchewan because of mining, processing, and grade considerations. Carnallite-rich salt is locally present in concentrations and volumes that could be a significant resource of magnesium chloride (MgCl 2 ) obtained as a byproduct of processing the carnallite for potash. Previously estimated reserves (not NI 43-101 compliant) of mineralized material from 1955 to 2019 are 695 Mt at 22.1 percent MgCl 2 . The total amount of K 2 O equivalent as carnallite was estimated during this USGS assessment to be about 120 Bt (or 180 Bt KCl). With uncertainties in defining the areal extent of carnallite in each of the potash-bearing members, the amount of MgCl 2 as carnallite in the Elk Point Basin could be approximately 180 Bt.

Elk Point basin↗

Geologic map of Okmok Volcano

The geologic map and description of map units presented here cover approximately 880 km2 of northeastern Umnak Island, Aleutian Islands, Alaska. This report focuses on Okmok Volcano and its eruptive products and updates the mid-20th-century geologic map of Byers (1959). Mapped deposits reflect the state of the volcano just prior to the 2008 eruption. Published information about other portions of Umnak Island geology, including Mount Recheshnoi and Mount Vsevidof, can be found in Byers (1959). The 2008 eruption and its deposits are described in Larsen and others (2009, 2013, 2015). Okmok Volcano is one of 54 historically active volcanoes in the Alaska–Aleutian volcanic arc that stretches across southern mainland Alaska and the Aleutian Islands (fig. 1; Wood and Kienle, 1990; Miller and others, 1998; Cameron and others, 2020). The highest point of the modern Okmok Caldera is along the caldera’s northern rim, 967 m in elevation, and formally named “Mount Okmok” (U.S. Board on Geographic Names, www.usgs.gov/core-science-systems/ngp/boardon-geographic-names/domestic-names). Okmok Volcano dominates the northeastern portion of Umnak Island, which is 100 km southwest of Unalaska/Dutch Harbor and 1,400 km southwest of Anchorage (figs. 1, 2). The Port of Dutch Harbor on Unalaska Island produces the highest volume of seafood for any port in the United States (see fisheries.noaa.gov/resource/document/fisheries-united-states-2018-report). Unalaska city and the Port of Dutch Harbor have been impacted by ash fall and drifting ash clouds from Okmok Volcano’s explosive eruptions as recently as 2008. Holocene and late Pleistocene volcanic rocks and deposits of Okmok Volcano rest upon glaciated Tertiary volcanic and sedimentary rocks (Byers, 1959). The first geologic mapping expedition to Okmok Volcano was by the U.S. Geological Survey (USGS) after the 1945 eruption, largely in response to concerns about volcanic hazards to U.S. military activities in the Aleutians Islands (Byers and others, 1947, 1959; Byers and Brannock, 1949; Byers, 1955, 1959, 1961). The State of Alaska conducted further mapping and geochemical studies as part of its geothermal exploration program in the 1980s (Nye, 1983; Nye and Reid, 1986; Motyka and others, 1993). Additional modern geological work focused on Okmok Volcano and the rest of Umnak Island to address the geochemistry and origin of primary Aleutian arc magmas and subduction zone mass recycling (Marsh, 1982; Brophy and Marsh, 1986; Nye and Reid, 1986; Myers and Marsh, 1987; Miller and others, 1992; Fournelle and others, 1994; Kay and Kay, 1994). In 1998, the Alaska Volcano Observatory (AVO) began a multi-year effort to expand geophysical monitoring in the central Aleutians Islands, including at Okmok Volcano. As part of this effort, AVO geologists from the University of Alaska Fairbanks Geophysical Institute (UAF/GI), the Alaska Division of Geological & Geophysical Surveys (DGGS), and USGS also began a renewed effort to document Okmok Volcano’s recent eruption products. The project started with reconnaissance fieldwork to document and sample products from the 1997 eruption within Okmok Caldera. This evolved into an effort to produce an updated geologic map of Okmok Volcano and gather more information about its eruptive history and hazards. Three significant eruptions occurred at Okmok Volcano in 1958, 1997, and 2008—after fieldwork had been conducted for the original 1:63,360-scale geologic map produced by Byers (1959)—resulting in new volcanic deposits not previously described. Okmok Volcano is one of the most frequently active volcanoes in the Aleutian volcanic arc. Seismic and geodetic monitoring indicate ongoing unrest at Okmok Volcano since at least 1997. Geodetic observations of inflation before and after the 1997 and 2008 eruptions indicate a nearly continuous input of new magma from a depth consistent with frequent eruptions of basalt and basaltic andesite magmas over the past 200 years (Larsen and others, 2013; Lu and others, 2000, 2003, 2005; Mann, 2002; Mann and others, 2002). To better understand the likelihood and character of future eruptions from Okmok Volcano, it is necessary to understand its past behavior, including eruptions since the first geologic map was published by Byers (1959).

Alaska↗

Sequestration of non-pure carbon dioxide streams in iron oxyhydroxide-containing saline repositories

Iron oxyhydroxide, goethite (α-FeOOH), was evaluated as a potential formation mineral reactant for trapping CO 2 in a mineral phase such as siderite (FeCO 3 ), when a mixture of CO 2 -SO 2 flue gas is injected into a saline aquifer. Two thermodynamic simulations were conducted, equilibrating a CO 2 -SO 2 fluid mixture with a NaCl-brine and Fe-rich rocks at 150 °C and 300 bar. The modeling studies evaluated mineral and fluid composition at equilibrium and the influence of pH buffering in the system. Results show siderite precipitates both in the buffered and unbuffered system; however, the presence of an alkaline pH buffer enhances the stability of the carbonate. Based on the model, an experiment was designed to compare with thermodynamic predictions. A CO 2 -SO 2 gas mixture was reacted in 150 ml of NaCl-NaOH brine containing 10 g of goethite at 150 °C and 300 bar for 24 days. Mineralogical and brine chemistry confirmed siderite as the predominant reaction product in the system. Seventy-six mg of CO 2 are sequestered in siderite per 10 g of goethite.

International Journal of Greenhouse Gas Control↗

Saltwater intrusion in the Floridan aquifer system near downtown Brunswick, Georgia, 1957–2015

Introduction The Floridan aquifer system (FAS) consists of the Upper Floridan aquifer (UFA), an intervening confining unit of highly variable properties, and the Lower Floridan aquifer (LFA). The UFA and LFA are primarily composed of Paleocene- to Oligocene-age carbonate rocks that include, locally, Upper Cretaceous rocks. The FAS extends from coastal areas in southeastern South Carolina and continues southward and westward across the coastal plain of Georgia and Alabama, and underlies all of Florida. The thickness of the FAS varies from less than 100 feet (ft) in aquifer outcrop areas of South Carolina to about 1,700 ft near the city of Brunswick, Georgia. Locally, in southeastern Georgia and the Brunswick– Glynn County area, the UFA consists of an upper water-bearing zone (UWBZ) and a lower water-bearing zone (LWBZ), as identified by Wait and Gregg (1973), with aquifer test data indicating the upper zone has higher productivity than the lower zone. Near the city of Brunswick, the LFA is composed of two permeable zones: an early middle Eocene-age upper permeable zone (UPZ) and a highly permeable lower zone of limestone (LPZ) of Paleocene and Late Cretaceous age that includes a deeply buried, cavernous, saline water-bearing unit known as the Fernandina permeable zone. Maslia and Prowell (1990) inferred the presence of major northeast–southwest trending faults through the downtown Brunswick area based on structural analysis of geophysical data, northeastward elongation of the potentiometric surface of the UFA, and breaches in the local confining unit that influence the area of chloride contamination. Pronounced horizontal and vertical hydraulic head gradients, caused by pumping in the UFA, allow saline water from the FPZ to migrate upward into the UFA through this system of faults and conduits. Saltwater was first detected in the FAS in wells completed in the UFA near the southern part of the city of Brunswick in late 1957. By the 1970s, a plume of groundwater with high chloride concentrations had migrated northward toward two major industrial pumping centers, and since 1965, chloride concentrations have steadily increased in the northern part of the city. In 1978, data obtained from a 2,720-ft-deep test well (33H188) drilled south of the city showed water with a chloride concentration of 33,000 milligrams per liter (mg/L), suggesting the saltwater source was located below the UFA in the Fernandina permeable zone (FPZ) of the LFA. All U.S. Geological Survey (USGS) data collected for this study, including groundwater levels in wells and water-chemistry data, are available in the USGS National Water Information System.

Georgia↗

Oil and gas resources of the Arctic Alaska Petroleum Province

The Arctic Alaska Petroleum Province, encompassing all the lands and adjacent Continental Shelf areas north of the Brooks Range-Herald arch, is one of the most petroleum-productive areas in the United States, having produced about 15 billion bbl of oil. Seven unitized oil fields currently contribute to production, and three additional oil fields have been unitized but are not yet producing. Most known petroleum accumulations involve structural or combination structural-stratigraphic traps related to closure along the Barrow arch, a regional basement high, which has focused regional hydrocarbon migration since Early Cretaceous time. Several oil accumulations in stratigraphic traps have been developed in recent years. In addition to three small gas fields producing for local consumption, more than 20 additional oil and gas discoveries remain undeveloped. This geologically complex region includes prospective strata within passive-margin, rift, and foreland-basin sequences. Oil and gas were generated from multiple source rocks throughout the region. Although some reservoired oils appear to be derived from a single source rock, evidence for significant mixing of hydrocarbons from multiple source rocks indicates a composite petroleum system. Both extensional and contractional tectonic structures provide ample exploration targets, and recent emphasis on stratigraphic traps has demonstrated a significant resource potential in shelf and turbidite sequences of Jurassic through Tertiary age. Recent estimates of the total mean volume of undiscovered resources in the Arctic Alaska Petroleum Province by the U.S. Geological Survey and U.S. Minerals Management Service are more than 50 billion bbl of oil and natural-gas liquids and 227 trillion ft3 of gas, distributed approximately equally between Federal offshore and combined onshore and State offshore areas.

Alaska↗

Geologic framework and hydrogeologic characteristics of the outcrops of the Edwards and Trinity aquifers, Medina Lake area, Texas

The hydrogeologic subdivisions of the Edwards aquifer outcrop in the Medina Lake area in Medina and Bandera Counties generally are porous and permeable. The most porous and permeable appear to be hydrogeologic subdivision VI, the Kirschberg evaporite member of the Kainer Formation; and hydrogeologic subdivision III, the leached and collapsed members, undivided, of the Person Formation. The porosity of the rocks in the Edwards aquifer outcrop is related to depositional or diagenetic elements along specific stratigraphic horizons (fabric selective) and to dissolution and structural elements that can occur in any lithostratigraphic horizon (not fabric selective). Permeability depends on the physical properties of the rock such as size, shape, and distribution of pores. The Edwards aquifer has relatively large porosity and permeability resulting, in part, from the development or redistribution of secondary porosity. Lithology, stratigraphy, diagenesis, and karstification account for the effective porosity and permeability in the Edwards aquifer outcrop. Karst features that can greatly enhance effective porosity and permeability in the Edwards aquifer outcrop include sinkholes, dolines, and caves. Field observations in the Medina Lake area confirm the findings of previous investigators that Medina Lake mostly overlies rocks of the upper member of the Glen Rose Limestone. The channel downstream of Medina Dam to the upper end of Diversion Lake also overlies the upper member of the Glen Rose Limestone. Most of Diversion Lake overlies a thin section of the Edwards aquifer— hydrogeologic subdivision VIII (basal nodular member) and the basal part of hydrogeologic subdivision VII (dolomitic member). Hydrogeologic subdivisions VIII and VII might be hydraulically connected to Medina Lake at high lake stages. The Trinity aquifer, which crops out in the northern part of the Medina Lake area and underlies the Edwards aquifer in the southern part, is much less permeable and productive than the Edwards aquifer. Where the Trinity aquifer underlies the Edwards, the Trinity acts as a lower confining unit on the Edwards.

Texas↗

Ground water: the hidden resource

Ground water is water underground in saturated zones beneath the land surface. Contrary to popular belief, ground water does not form underground "rivers." It fills the pores and fractures in underground materials such as sand, gravel, and other rock. If ground water flows from rock materials or can be removed by pumping from the saturated rock materials In useful amounts, the rock materials are called aquifers. Ground water moves slowly, typically at rates of 7 to 60 centimeters per day in an aquifer. As a result, water could remain in an aquifer for hundreds or thousands of years. Ground water is the source of about 40 percent of water used for public supplies and about 38 percent of water used for agriculture in the United States.

General Information Product↗