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At least 1,045 records · Page 58Linked to original sources
USGS2021

Assessment of water-quality constituents monitored for total maximum daily loads in Johnson County, Kansas, January 2015 through December 2018

Stormwater discharges from municipalities are regulated by provisions in the Clean Water Act of 1972 to protect the Nation’s water resources from harmful pollutants. In 2014, the Kansas Department of Health and Environment issued new stormwater discharge permits for 17 municipalities in Johnson County, Kansas, in the northeastern part of the State. The county is largely suburban and has 20 municipalities within 22 watersheds. Municipalities in Johnson County are required to implement stormwater management programs that reduce discharges of pollutants, protect water quality, and satisfy applicable water-quality regulations. In 2015, the U.S. Geological Survey, in cooperation with the Johnson County Stormwater Management Program, began a 4-year monitoring program designed to meet new stormwater monitoring requirements for some municipalities in Johnson County. Additional data were collected to evaluate the usefulness of continuous water-quality monitoring and different sampling methods in assessing changes in water quality. Twelve of the 22 watersheds in the county were within the sampling network for this project. Discrete water-quality samples were collected at 25 stream sites and 2 lake sites using passive, grab, and equal-width increment sampling methods. Samples at all sites were analyzed for nutrients, Escherichia coli bacteria, total suspended solids, and suspended-sediment concentration. Ninety-nine percent of storm-event samples and 98 percent of low-flow samples were less than the Kansas Surface Water Quality Standard for nitrate plus nitrite. Eight percent of storm-event samples and 100 percent of low-flow samples were less than the total suspended solids screening value of 50 milligrams per liter. Passive samples generally had higher concentrations when compared to equal-width increment and grab samples, and grab samples and equal-width increment samples generally had similar concentrations. Continuous water-quality data were collected at one site. Ordinary least squares regression analysis was used to relate continuous (15-minute) water-quality sensor measurements to discretely sampled constituent concentrations at one site. Numerous factors affect water quality in urban runoff. Urban areas have many possible contaminant sources, including municipal and industrial wastewater discharges, stormwater runoff from impervious surfaces, and failing infrastructure. A better understanding of these factors can inform future monitoring efforts, leading to datasets that are representative of storm runoff and can be used to detect differences between sites and over time.

Kansas↗
USGS2012

A novel antibody-based biomarker for chronic algal toxin exposure and sub-acute neurotoxicity

The neurotoxic amino acid, domoic acid (DA), is naturally produced by marine phytoplankton and presents a significant threat to the health of marine mammals, seabirds and humans via transfer of the toxin through the foodweb. In humans, acute exposure causes a neurotoxic illness known as amnesic shellfish poisoning characterized by seizures, memory loss, coma and death. Regular monitoring for high DA levels in edible shellfish tissues has been effective in protecting human consumers from acute DA exposure. However, chronic low-level DA exposure remains a concern, particularly in coastal and tribal communities that subsistence harvest shellfish known to contain low levels of the toxin. Domoic acid exposure via consumption of planktivorous fish also has a profound health impact on California sea lions ( Zalophus californianus ) affecting hundreds of animals yearly. Due to increasing algal toxin exposure threats globally, there is a critical need for reliable diagnostic tests for assessing chronic DA exposure in humans and wildlife. Here we report the discovery of a novel DA-specific antibody response that is a signature of chronic low-level exposure identified initially in a zebrafish exposure model and confirmed in naturally exposed wild sea lions. Additionally, we found that chronic exposure in zebrafish caused increased neurologic sensitivity to DA, revealing that repetitive exposure to DA well below the threshold for acute behavioral toxicity has underlying neurotoxic consequences. The discovery that chronic exposure to low levels of a small, water-soluble single amino acid triggers a detectable antibody response is surprising and has profound implications for the development of diagnostic tests for exposure to other pervasive environmental toxins.

PLoS ONE↗
USGS2020

Accurate bathymetric maps from underwater digital imagery without ground control

Structure-from-Motion (SfM) photogrammetry can be used with digital underwater photographs to generate high-resolution bathymetry and orthomosaics with millimeter-to-centimeter scale resolution at relatively low cost. Although these products are useful for assessing species diversity and health, they have additional utility for quantifying benthic community structure, such as coral growth and fine-scale elevation change over time, if accurate length scales and georeferencing are included. This georeferencing is commonly provided with “ground control,” such as pre-installed seafloor benchmarks or identifiable “static” features, which can be difficult and time consuming to install, survey, and maintain. To address these challenges, we developed the SfM Quantitative Underwater Imaging Device with Five Cameras (SQUID-5), a towed surface vehicle with an onboard survey-grade Global Navigation Satellite System (GNSS) and five rigidly mounted downward-looking cameras with overlapping views of the seafloor. The cameras are tightly synchronized with both the GNSS and each other to collect quintet photo sets and record the precise location of every collection event. The system was field tested in July 2019 in the U.S. Florida Keys, in water depths ranging from 3 to 9 m over a variety of bottom types. Surveying accuracy was assessed using pre-installed stations with known coordinates, machined scale bars, and two independent surveys of a site to evaluate repeatability. Under a range of sea conditions, ambient lighting, and water clarity, we were able to map living and senile coral reef habitats and sand waves at mm-scale resolution. Data were processed using best practice SfM techniques without ground control and local measurement errors of horizontal and vertical scales were consistently sub-millimeter, equivalent to 0.013% RMSE relative to water depth. Survey-to-survey repeatability RMSE was on the order of 3 cm without georeferencing but could be improved to several millimeters with the incorporation of one or more non-surveyed marker points. We demonstrate that the SQUID-5 platform can map complex coral reef and other seafloor habitats and measure mm-to-cm scale changes in the morphology and location of seafloor features over time without pre-existing ground control.

Florida↗
USGS2008

Simulations of Ground-Water Flow, Transport, Age, and Particle Tracking near York, Nebraska, for a Study of Transport of Anthropogenic and Natural Contaminants (TANC) to Public-Supply Wells

Contamination of public-supply wells has resulted in public-health threats and negative economic effects for communities that must treat contaminated water or find alternative water supplies. To investigate factors controlling vulnerability of public-supply wells to anthropogenic and natural contaminants using consistent and systematic data collected in a variety of principal aquifer settings in the United States, a study of Transport of Anthropogenic and Natural Contaminants to public-supply wells was begun in 2001 as part of the U.S. Geological Survey National Water-Quality Assessment Program. The area simulated by the ground-water flow model described in this report was selected for a study of processes influencing contaminant distribution and transport along the direction of ground-water flow towards a public-supply well in southeastern York, Nebraska. Ground-water flow is simulated for a 60-year period from September 1, 1944, to August 31, 2004. Steady-state conditions are simulated prior to September 1, 1944, and represent conditions prior to use of ground water for irrigation. Irrigation, municipal, and industrial wells were simulated using the Multi-Node Well package of the modular three-dimensional ground-water flow model code, MODFLOW-2000, which allows simulation of flow and solutes through wells that are simulated in multiple nodes or layers. Ground-water flow, age, and transport of selected tracers were simulated using the Ground-Water Transport process of MODFLOW-2000. Simulated ground-water age was compared to interpreted ground-water age in six monitoring wells in the unconfined aquifer. The tracer chlorofluorocarbon-11 was simulated directly using Ground-Water Transport for comparison with concentrations measured in six monitoring wells and one public supply well screened in the upper confined aquifer. Three alternative model simulations indicate that simulation results are highly sensitive to the distribution of multilayer well bores where leakage can occur and that the calibrated model resulted in smaller differences than the alternative models between simulated and interpreted ages and measured tracer concentrations in most, but not all, wells. Results of the first alternative model indicate that the distribution of young water in the upper confined aquifer is substantially different when well-bore leakage at known abandoned wells and test holes is removed from the model. In the second alternative model, simulated age near the bottom of the unconfined aquifer was younger than interpreted ages and simulated chlorofluorocarbon-11 concentrations in the upper confined aquifer were zero in five out of six wells because the conventional Well Package fails to account for flow between model layers though well bores. The third alternative model produced differences between simulated and interpreted ground-water ages and measured chlorofluorocarbon-11 concentrations that were comparable to the calibrated model. However, simulated hydraulic heads deviated from measured hydraulic heads by a greater amount than for the calibrated model. Even so, because the third alternative model simulates steady-state flow, additional analysis was possible using steady-state particle tracking to assess the contributing recharge area to a public supply well selected for analysis of factors contributing to well vulnerability. Results from particle-tracking software (MODPATH) using the third alternative model indicates that the contributing recharge area of the study public-supply well is a composite of elongated, seemingly isolated areas associated with wells that are screened in multiple aquifers. The simulated age distribution of particles at the study public-supply well indicates that all water younger than 58 years travels through well bores of wells screened in multiple aquifers. The age distribution from the steady-state model using MODPATH estimates the youngest 7 percent of the water to have a flow-weighted mean age

Scientific Investigations Report↗
USGS2003

Simulation of Temperature, Nutrients, Biochemical Oxygen Demand, and Dissolved Oxygen in the Catawba River, South Carolina, 1996-97

Time-series plots of dissolved-oxygen concentrations were determined for various simulated hydrologic and point-source loading conditions along a free-flowing section of the Catawba River from Lake Wylie Dam to the headwaters of Fishing Creek Reservoir in South Carolina. The U.S. Geological Survey one-dimensional dynamic-flow model, BRANCH, was used to simulate hydrodynamic data for the Branched Lagrangian Transport Model. Waterquality data were used to calibrate the Branched Lagrangian Transport Model and included concentrations of nutrients, chlorophyll a, and biochemical oxygen demand in water samples collected during two synoptic sampling surveys at 10 sites along the main stem of the Catawba River and at 3 tributaries; and continuous water temperature and dissolved-oxygen concentrations measured at 5 locations along the main stem of the Catawba River. A sensitivity analysis of the simulated dissolved-oxygen concentrations to model coefficients and data inputs indicated that the simulated dissolved-oxygen concentrations were most sensitive to watertemperature boundary data due to the effect of temperature on reaction kinetics and the solubility of dissolved oxygen. Of the model coefficients, the simulated dissolved-oxygen concentration was most sensitive to the biological oxidation rate of nitrite to nitrate. To demonstrate the utility of the Branched Lagrangian Transport Model for the Catawba River, the model was used to simulate several water-quality scenarios to evaluate the effect on the 24-hour mean dissolved-oxygen concentrations at selected sites for August 24, 1996, as simulated during the model calibration period of August 23 27, 1996. The first scenario included three loading conditions of the major effluent discharges along the main stem of the Catawba River (1) current load (as sampled in August 1996); (2) no load (all point-source loads were removed from the main stem of the Catawba River; loads from the main tributaries were not removed); and (3) fully loaded (in accordance with South Carolina Department of Health and Environmental Control National Discharge Elimination System permits). Results indicate that the 24-hour mean and minimum dissolved-oxygen concentrations for August 24, 1996, changed from the no-load condition within a range of - 0.33 to 0.02 milligram per liter and - 0.48 to 0.00 milligram per liter, respectively. Fully permitted loading conditions changed the 24-hour mean and minimum dissolved-oxygen concentrations from - 0.88 to 0.04 milligram per liter and - 1.04 to 0.00 milligram per liter, respectively. A second scenario included the addition of a point-source discharge of 25 million gallons per day to the August 1996 calibration conditions. The discharge was added at S.C. Highway 5 or at a location near Culp Island (about 4 miles downstream from S.C. Highway 5) and had no significant effect on the daily mean and minimum dissolved-oxygen concentration. A third scenario evaluated the phosphorus loading into Fishing Creek Reservoir; four loading conditions of phosphorus into Catawba River were simulated. The four conditions included fully permitted and actual loading conditions, removal of all point sources from the Catawba River, and removal of all point and nonpoint sources from Sugar Creek. Removing the point-source inputs on the Catawba River and the point and nonpoint sources in Sugar Creek reduced the organic phosphorus and orthophosphate loadings to Fishing Creek Reservoir by 78 and 85 percent, respectively.

South Carolina↗
USGS2011

Groundwater quality in the San Diego Drainages Hydrogeologic Province, California

More than 40 percent of California's drinking water is from groundwater. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State's groundwater quality and increases public access to groundwater-quality information. The San Diego Drainages Hydrogeologic Province (hereinafter referred to as San Diego) is one of the study units being evaluated. The San Diego study unit is approximately 3,900 square miles and consists of the Temecula Valley, Warner Valley, and 12 other alluvial basins (California Department of Water Resources, 2003). The study unit also consists of all areas outside defined groundwater basins that are within 3 kilometers of a public-supply well. The study unit was separated, based primarily on hydrogeologic settings, into four study areas: Temecula Valley, Warner Valley, Alluvial Basins, and Hard Rock (Wright and others, 2005). The sampling density for the Hard Rock study area, which consists of areas outside of groundwater basins, was much lower than for the other study areas. Consequently, aquifer proportions for the Hard Rock study area are not used to calculate the aquifer proportions shown by the pie charts. An assessment of groundwater quality for the Hard Rock study area can be found in Wright and Belitz, 2011. The temperatures in the coastal part of the study unit are mild with dry summers, moist winters, and an average annual rainfall of about 10 inches. The temperatures in the mountainous eastern part of the study unit are cooler than in the coastal part, with an annual precipitation of about 45 inches that occurs mostly in the winter. The primary aquifers consist of Quaternary-age alluvium and weathered bedrock in the Temecula Valley, Warner Valley, and Alluvial Basins study areas, whereas in the Hard Rock study area the primary aquifers consist mainly of fractured and decomposed granite of Mesozoic age. The primary aquifers are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health (CDPH) database. Public-supply wells typically are drilled to depths between 200 and 700 feet, consist of solid casing from the land surface to a depth of about 60 to 170 feet, and are perforated, or consist of an open hole, below the solid casing. Water quality in the shallow and deep parts of the aquifer system may differ from water quality in the primary aquifers. Municipal water use accounts for approximately 70 percent of water used in the study unit; the majority of the remainder is used for agriculture, industry, and commerce. Groundwater accounts for approximately 8 percent of the municipal supply, and surface water, the majority of which is imported, accounts for the rest. Recharge to groundwater occurs through stream-channel infiltration from rivers and their tributaries, infiltration in engineered recharge basins, and infiltration of water from precipitation and irrigation. The primary source of discharge is water pumped from wells.

California↗
USGS1990

Multiplication of infectious hematopoietic necrosis virus in rainbow trout following immersion infection: whole-body assay and immunohistochemistry

The sites of replication of infectious hematopoietic necrosis virus (IHNV) in infected tissues were detected in fingerling rainbow trout Oncorhynchus mykiss by in situ histologic techniques following immersion infection. Virus antigens in tissues were detected by a neutralizing mouse monoclonal antibody and a one-step anti-mouse biotin-streptavidin conjugated to horseradish peroxidase. The efficiency of infection and virulence of the virus determined by mortality rates showed high virulence of the selected IHNV isolates, and viral replication in individual fish showed that virus content of the fish increased rapidly from the second day to the seventh day postinfection. The earliest viral lesions following infection were detected in the epidermis of the pectoral fins, opercula, and ventral surface of the body. Virus lesions became evident in kidneys on the third day. By the fifth day, when there was a significant increase in virus titer, foci of viral replication were detected in gill tissue and in the anterior internal tissues below the epidermis. Subsequently, extensive virus replication and tissue destruction were observed in the spleen, dorsal adipose tissues, ventricle, and pseudobranch. Replication in the liver, the muscularis layers of the digestive tract, and the general body musculature followed later. These infection experiments indicated that the epidermis and gills of fish constitute important sites of early IHNV replication.

Journal of Aquatic Animal Health↗
USGS2003

Ground-water use, locations of production wells, and areas irrigated using ground water in 1998, middle Humboldt River basin, north-central Nevada

In 1998, ground water was being pumped from about 420 production wells in the middle Humboldt River Basin for a variety of uses. Principal uses were for agriculture, industry, mining, municipal, and power plant purposes. This report presents a compilation of the number and types of production wells, areas irrigated by ground water, and ground-water use in 14 hydrographic areas of the middle Humboldt River Basin in 1998. Annual pumping records for production wells usually are reported to the Nevada Division of Water Resources. However, operators of irrigation wells are not consistently required to report annual pumpage. Daily power-consumption and pump-discharge rates measured at 20 wells during the 1998 irrigation season and total power use at each well were used to estimate the amount of water, in feet of depth, applied to 20 alfalfa fields. These fields include about 10 percent of the total area, 36,700 acres, irrigated with ground water in the middle Humboldt River Basin. In 1998 an average of 2.0 feet of water was applied to 14 fields irrigated using center-pivot sprinkler systems, and an average of 2.6 feet of water was applied to 6 fields irrigated using wheel-line sprinkler systems. A similar approach was used to estimate the amount of water pumped at three wells using pumps powered by diesel engines. The two fields served by these three wells received 3.9 feet of water by flood irrigation during the 1998 irrigation season. The amount of water applied to the fields irrigated by center-pivot and wheel-line irrigation systems during the 1998 irrigation season was less than what would have been applied during a typical irrigation season because late winter and spring precipitation exceeded long-term monthly averages by as much as four times. As a result, the health of crops was affected by over-saturated soils, and most irrigation wells were only used sporadically in the first part of the irrigation season. Power consumption at 19 of the 20 wells in the 1994-97 irrigation seasons was 110 to 235 percent of the power consumption in the 1998 irrigation season. If the amount of water applied to fields during the 1998 irrigation season were adjusted to account for these differences in power consumption, the average amount of water applied to a field during a typical season using center-pivot and wheel-line sprinkler systems would be 3.1 feet and 3.7 feet, respectively. Total ground water pumped in the middle Humboldt River Basin during 1998 was about 298,000 acre-feet. This pumpage was distributed as follows: 78 percent for mining, 19 percent for irrigation, and 3 percent for industrial, municipal, and power plants combined. Mining pumpage is by far the largest source of ground-water use because several large gold mines have extended below local ground-water levels and the area around each mine must be dewatered in order to maintain a dry and workable mine. Total mining pumpage in 1998 was 233,000 acre-feet, of this total, 23,600 acre-feet was for consumptive use and 209,000 acre-feet was for dewatering eight mines. Excess water from the mines being dewatered was distributed as follows: 74,500 acre-feet was returned to aquifers by infiltration; 33,100 acre-feet was used for irrigation and for consumptive use at two mines and a power plant; 96,700 acre-feet was released to the Humboldt River or one of its tributaries; and 5,260 acre-feet was lost to evaporation.

Water-Resources Investigations Report↗
USGS2020

Groundwater quality in relation to drinking water health standards and hydrogeologic and geochemical characteristics for 47 domestic wells in Potter County, Pennsylvania, 2017

As part of a regional effort to characterize groundwater in rural areas of Pennsylvania, water samples from 47 domestic wells in Potter County were collected from May through September 2017. The sampled wells had depths ranging from 33 to 600 feet in sandstone, shale, or siltstone aquifers. Groundwater samples were analyzed for physicochemical properties that could be evaluated in relation to drinking-water health standards, geology, land use, and other environmental factors. Laboratory analyses included concentrations of major ions, nutrients, bacteria, trace elements, volatile organic compounds (VOCs), ethylene and propylene glycol, alcohols, gross-alpha/beta-particle activity, uranium, radon-222, and dissolved gases. A subset of samples was analyzed for radium isotopes (radium-226 and -228) and for the isotopic composition of methane. Results of this 2017 study show that groundwater quality generally met most drinking-water standards that apply to public water supplies. However, a percentage of samples exceeded maximum contaminant levels (MCLs) for total coliform bacteria (69.6 percent), Escherichia coli (30.4 percent), arsenic, and barium; and secondary maximum contaminant levels (SMCLs) for field pH, manganese, sodium, iron, total dissolved solids, aluminum, and chloride. All of the analyzed VOCs were below limits of detection and associated drinking water criteria. Radon-222 activities exceeded the proposed drinking-water standard of 300 picocuries per liter in 80.9 percent of the samples. The field pH of the groundwater ranged from 4.6 to 9.0. Generally, the lower pH samples had greater potential for elevated concentrations of dissolved metals, including beryllium, copper, lead, nickel, and zinc, whereas the higher pH samples had greater potential for elevated concentrations of total dissolved solids, sodium, fluoride, boron, and uranium. Near-neutral samples (pH 6.5 to 7.5) had greater hardness and alkalinity concentrations than other samples with pH values outside this range. Calcium/bicarbonate waters were the predominant hydrochemical type for the sampled aquifers, with mixed water types for many samples, including variable contributions from calcium, magnesium, and sodium combined with bicarbonate, sulfate, chloride, and nitrate. Water from 45 wells had concentrations of methane greater than the 0.0002 milligrams per liter (mg/L) detection limit. One sample had the maximum value of 11 mg/L, which exceeds the Pennsylvania action level of 7 mg/L. Additionally, three other samples had concentrations of methane greater than 4 mg/L. Outgassing of such levels of methane from the water to air within a confined space can result in a potential hazard. The elevated concentrations of methane generally were associated with suboxic groundwater (dissolved oxygen less than 0.5 mg/L) that had near-neutral to alkaline pH with relatively elevated concentrations of iron, manganese, ammonia, lithium, fluoride, and boron. Other constituents, including barium, sodium, chloride, and bromide, commonly were elevated, but not limited to, those well-water samples with elevated methane. Low levels of ethane (as much as 1.2 mg/L) were present in eight samples with the highest methane concentrations. Five samples were analyzed for methane isotopes. The isotopic and hydrocarbon compositions in these five samples suggest the methane may be of microbial origin or a mixture of thermogenic and microbial gas, but differed from the compositions reported for mud-gas logging samples collected during drilling of gas wells. The concentrations of sodium (median 8.2 mg/L), chloride (median 7.64 mg/L), and bromide (median 0.02 mg/L) for the 47 groundwater samples collected for this study ranged widely and were positively correlated with one another and with specific conductance and associated measures of ionic strength. Sixty percent of the Potter County well-water samples had chloride concentrations less than 10 mg/L. Samples with higher chloride concentrations had variable bromide concentrations and corresponding chloride/bromide ratios that are consistent with sources such as road-deicing salt and septic effluent (low bromide) or brine (high bromide). Brines are naturally present in deeper parts of the regional groundwater system and, in some cases, may be mobilized by gas drilling. It is also possible that valley wells were drilled close to or into the brine-freshwater interface, so brine signatures do not necessarily indicate contamination due to drilling. The chloride, bromide, and other constituents in road-deicing salt or brine solutions tend to be diluted by mixing with fresh groundwater in shallow aquifers used for water supply. Although 1 of 8 groundwater samples with the highest methane concentrations (greater than 0.2 mg/L) had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with road-deicing salt, the other 7 of 8 samples with elevated methane had concentrations of chloride and bromide with corresponding chloride/bromide ratios that indicated mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported for gas and oil well brines in Pennsylvania. In several eastern Pennsylvania counties where gas drilling is absent, groundwater with comparable chloride/bromide ratios and chloride concentrations have been reported. Approximately 50 percent of Potter County well-water samples, including two samples with the fourth (72.9 mg/L) and fifth (47.0 mg/L) highest chloride concentrations, have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt or septic effluent.

Pennsylvania↗
USGS2013

Groundwater quality and the relation between pH values and occurrence of trace elements and radionuclides in water samples collected from private wells in part of the Kickapoo Tribe of Oklahoma Jurisdictional Area, central Oklahoma, 2011

From 1999 to 2007, the Indian Health Service reported that gross alpha-particle activities and concentrations of uranium exceeded the Maximum Contaminant Levels for public drinking-water supplies in water samples from six private wells and two test wells in a rural residential neighborhood in the Kickapoo Tribe of Oklahoma Jurisdictional Area, in central Oklahoma. Residents in this rural area use groundwater from Quaternary-aged terrace deposits and the Permian-aged Garber-Wellington aquifer for domestic purposes. Uranium and other trace elements, specifically arsenic, chromium, and selenium, occur naturally in rocks composing the Garber-Wellington aquifer and in low concentrations in groundwater throughout its extent. Previous studies have shown that pH values above 8.0 from cation-exchange processes in the aquifer cause selected metals such as arsenic, chromium, selenium, and uranium to desorb (if present) from mineral surfaces and become mobile in water. On the basis of this information, the U.S. Geological Survey, in cooperation with the Kickapoo Tribe of Oklahoma, conducted a study in 2011 to describe the occurrence of selected trace elements and radionuclides in groundwater and to determine if pH could be used as a surrogate for laboratory analysis to quickly and inexpensively identify wells that might contain high concentrations of uranium and other trace elements. The pH and specific conductance of groundwater from 59 private wells were measured in the field in an area of about 18 square miles in Lincoln and Pottawatomie Counties. Twenty of the 59 wells also were sampled for dissolved concentrations of major ions, trace elements, gross alpha-particle and gross beta-particle activities, uranium, radium-226, radium-228, and radon-222 gas. Arsenic concentrations exceeded the Maximum Contaminant Level of 10 micrograms per liter in one sample having a concentration of 24.7 micrograms per liter. Selenium concentrations exceeded the Maximum Contaminant Level of 50 micrograms per liter in one sample having a concentration of 147 micrograms per liter. Both samples had alkaline pH values, 8.0 and 8.4, respectively. Uranium concentrations ranged from 0.02 to 383 micrograms per liter with 5 of 20 samples exceeding the Maximum Contaminant Level of 30 micrograms per liter; the five wells with uranium concentrations exceeding 30 micrograms per liter had pH values ranging from 8.0 to 8.5. Concentrations of uranium and radon-222 and gross alpha-particle activity showed a positive relation to pH, with the highest concentrations and activity in samples having pH values of 8.0 or above. The groundwater samples contained dissolved oxygen and high concentrations of bicarbonate; these characteristics are also factors in increasing uranium solubility. Concentrations of radium-226 and radium-228 (combined) ranged from 0.03 to 1.7 picocuries per liter, with a median concentration of 0.45 picocuries per liter for all samples. Radon-222 concentrations ranged from 95 to 3,600 picocuries per liter with a median concentration of 261 picocuries per liter. Eight samples having pH values ranging from 8.0 to 8.7 exceeded the proposed Maximum Contaminant Level of 300 picocuries per liter for radon-222. Eight samples exceeded the 15 picocuries per liter Maximum Contaminant Level for gross alpha-particle activity at 72 hours (after sample collection) and at 30 days (after the initial count); those samples had pH values ranging from 8.0 to 8.5. Gross beta-particle activity increased in 15 of 21 samples during the interval from 72 hours to 30 days. The increase in gross beta-particle activity over time probably was caused by the ingrowth and decay of uranium daughter products that emit beta particles. Water-quality data collected for this study indicate that pH values above 8.0 are associated with potentially high concentrations of uranium and radon-222 and high gross alpha-particle activity in the study area. High pH values also are associated with potentially high concentrations of arsenic, chromium, and selenium in groundwater when these elements occur in the aquifer matrix along groundwater-flow paths.

Oklahoma↗
USGS2019

Southern sea otter (Enhydra lutris nereis) population biology at Big Sur and Monterey, California --Investigating the consequences of resource abundance and anthropogenic stressors for sea otter recovery

The range of the southern sea otter ( Enhydra lutris nereis ) spans most of the central California coast from Half Moon Bay to Gaviota. Some coastal areas within this range are heavily developed and highly impacted by humans, while other areas are wild and largely pristine. Determining the relative importance of food resource abundance, environmental conditions, and anthropogenic increases in pathogens and pollutants to population change in sea otters is critical to understanding limitations to population growth. To investigate the causal links between the sluggish population growth of sea otters in central California and factors that could be driving variation in survival and reproduction, we designed a study to compare two distinct subpopulations—one in an area of low human impact (Big Sur) and one in an area of high human impact (Monterey). Between 2008 and 2011, the U.S. Geological Survey and collaborators conducted a telemetry-based study of sea otters at these two locations. The results of this study were not consistent with the hypothesis that sea otters adjacent to human population centers (Monterey) experience higher exposure to pollutants and pathogens than those in lower impacted areas (Big Sur). In fact, based on serological analysis, female sea otters from Big Sur showed higher exposure rates to Toxoplasma gondii than did female otters from Monterey, while domoic acid exposure appeared to be similar at both sites. Gene expression (specifically transcription) analysis did not indicate any consistent differences between the two populations that would have suggested a response to pathogen or toxin exposure, although there were temporal changes in gene transcription for sea otters at Big Sur following potential exposure to run-off from wildfires that occurred during the study. Together, these metrics suggest that variation in exposure to environmental stressors occurred, but patterns were not clearly attributable to differences in human population densities or land-use patterns. When compared to Monterey, sea otters in Big Sur spent more time feeding, had a higher degree of dietary specialization, were in poorer body condition, and had lower survival rates (both pups and adults). Together, these metrics suggest that otters at Big Sur had greater nutritional stress, consistent with lower per-capita resource abundance. Overall, study results indicate that density-dependent population regulation, mediated by per-capita resource abundance, is the most significant factor currently limiting population growth in the center part of the range. Additionally, spatial and temporal variation in environmental and anthropogenic stressors also can affect sea otter health, although patterns of variation are complex and are not simply a function of proximity to human populations. We also found that exposure to environmental stressors (either natural or anthropogenic in origin) often is associated with resource limitation. Finally, our results indicate that sea otter populations are structured at relatively small spatial scales, and the processes that regulate population abundance (including density-dependent resource abundance) also occur at these smaller, more local scales.

California↗
USGS2021

Hydrogeologic framework, water levels, and selected contaminant concentrations at Valmont TCE Superfund Site, Luzerne County, Pennsylvania, 2020

The Valmont TCE Superfund Site, Luzerne County, Pennsylvania is underlain by fractured and folded sandstones and shales of the Pottsville and Mauch Chunk Formations, which form a fractured-rock aquifer recharged locally by precipitation. Industrial activities at the former Chromatex Plant resulted in trichloroethene (TCE) contamination of groundwater at and near the facility, which was identified in 1987 and led to listing as a Superfund site by the U.S. Environmental Protection Agency (EPA) in 1989. To address the problem of TCE concentrations in nearby residential wells that exceed the maximum contaminant level (MCL) of 5 micrograms per liter (μg/L), alternate water supplies were provided. A 2015 review of initial characterization and subsequent remediation by the EPA identified the need for an updated understanding of the complex hydrogeology and the conceptual site model. Additional contaminants present in groundwater at the site include some other volatile organic compounds (VOCs) and per- and polyfluoroalkyl substances (PFAS), predominantly consisting of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) present in concentrations that exceeded the EPA Health Advisory (HA) level of 5 nanograms per liter (ng/L) for combined PFOA and PFOS. In response to a request from the EPA in 2019, the U.S. Geological Survey (USGS) prepared cross sections and maps to provide more information about the hydrogeologic framework at and near the site and assist in improving the conceptual site model using water level and contaminant data collected by the EPA in 2020. The cross sections present lithologic correlations from available geophysical logs collected in wells from 2002 to 2014; they show alternating intervals of relatively elevated and reduced natural gamma activity that correspond to changes in lithology, with water-bearing zones and well screens commonly located at lithologic contacts, sometimes near thin coal seams. Water-bearing zones commonly are associated with fractures at or near lithologic contacts but also may be associated with fractures at or near apparent faulting. Recent (March 2020) water-level data shown on cross sections and maps indicate large downward vertical gradients and apparent radial gradients laterally to the northeast, northwest, and southwest that generally following topography. Recent (February to March 2020) data for TCE groundwater concentration shown on cross sections and maps indicate the highest TCE concentrations (greater than 3,000 μg/L and as much as 75,000 μg/L) and combined PFOA and PFOS concentrations (greater than 1,000 ng/L and up to at least 2,350 ng/L) are from shallow (less than 60 feet [ft] below land surface [bls]) and intermediate depth (60 to 100 ft bls) wells near the center of the former Chromatex Plant. TCE and PFAS (as combined PFOA and PFOS) contamination is present at greater depths, as much as 304 ft bls, as evidenced by samples collected from one well (a reconstructed former production well) near the plant, that contained concentrations of about 240 μg/L and 508 ng/L, respectively. The 2020 data also indicate that TCE and PFAS concentrations which exceed drinking-water MCL or HA levels are present in groundwater depths of less than 200 ft in an area that extends predominantly in a northeast direction from the former Chromatex Plant, and is apparently influenced by hydraulic gradients, lithology, and geologic structure.

Pennsylvania↗
USGS2005

Estimation of constituent concentrations, densities, loads, and yields in lower Kansas River, northeast Kansas, using regression models and continuous water-quality monitoring, January 2000 through December 2003

The lower Kansas River is an important source of drinking water for hundreds of thousands of people in northeast Kansas. Constituents of concern identified by the Kansas Department of Health and Environment (KDHE) for streams in the lower Kansas River Basin include sulfate, chloride, nutrients, atrazine, bacteria, and sediment. Real-time continuous water-quality monitors were operated at three locations along the lower Kansas River from July 1999 through September 2004 to provide in-stream measurements of specific conductance, pH, water temperature, turbidity, and dissolved oxygen and to estimate concentrations for constituents of concern. Estimates of concentration and densities were combined with streamflow to calculate constituent loads and yields from January 2000 through December 2003. The Wamego monitoring site is located 44 river miles upstream from the Topeka monitoring site, which is 65 river miles upstream from the DeSoto monitoring site, which is 18 river miles upstream from where the Kansas River flows into the Missouri River. Land use in the Kansas River Basin is dominated by grassland and cropland, and streamflow is affected substantially by reservoirs. Water quality at the three monitoring sites varied with hydrologic conditions, season, and proximity to constituent sources. Nutrient and sediment concentrations and bacteria densities were substantially larger during periods of increased streamflow, indicating important contributions from nonpoint sources in the drainage basin. During the study period, pH remained well above the KDHE lower criterion of 6.5 standard units at all sites in all years, but exceeded the upper criterion of 8.5 standard units annually between 2 percent of the time (Wamego in 2001) and 65 percent of the time (DeSoto in 2003). The dissolved oxygen concentration was less than the minimum aquatic-life-support criterion of 5.0 milligrams per liter less than 1 percent of the time at all sites. Dissolved solids, a measure of the dissolved material in water, exceeded 500 milligrams per liter about one-half of the time at the three Kansas River sites. Larger dissolved-solids concentrations upstream likely were a result of water inflow from the highly mineralized Smoky Hill River that is diluted by tributary flow as it moves downstream. Concentrations of total nitrogen and total phosphorus at the three monitoring sites exceeded the ecoregion water-quality criteria suggested by the U.S. Environmental Protection Agency during the entire study period. Median nitrogen and phosphorus concentrations were similar at all three sites, and nutrient load increased moving from the upstream to downstream sites. Total nitrogen and total phosphorus yields were nearly the same from site to site indicating that nutrient sources were evenly distributed throughout the lower Kansas River Basin. About 11 percent of the total nitrogen load and 12 percent of the total phosphorus load at DeSoto during 2000-03 originated from wastewater-treatment facilities. Escherichia coli bacteria densities were largest at the middle site, Topeka. On average, 83 percent of the annual bacteria load at DeSoto during 2000-03 occurred during 10 percent of the time, primarily in conjunction with runoff. The average annual sediment loads at the middle and downstream monitoring sites (Topeka and DeSoto) were nearly double those at the upstream site (Wamego). The average annual sediment yield was largest at Topeka. On average, 64 percent of the annual suspended-sediment load at DeSoto during 2000-03 occurred during 10 percent of the time. Trapping of sediment by reservoirs located on contributing tributaries decreases transport of sediment and sediment-related constituents. The average annual suspended-sediment load in the Kansas River at DeSoto during 2000-03 was estimated at 1.66 million tons. An estimated 13 percent of this load consisted of sand-size particles, so approximately 216,000 tons of sand were transported

Scientific Investigations Report↗
USGS2007

A multiple-tracer approach for identifying sewage sources to an urban stream system

The presence of human-derived fecal coliform bacteria (sewage) in streams and rivers is recognized as a human health hazard. The source of these human-derived bacteria, however, is often difficult to identify and eliminate, because sewage can be delivered to streams through a variety of mechanisms, such as leaking sanitary sewers or private lateral lines, cross-connected pipes, straight pipes, sewer-line overflows, illicit dumping of septic waste, and vagrancy. A multiple-tracer study was conducted to identify site-specific sources of sewage in Accotink Creek, an urban stream in Fairfax County, Virginia, that is listed on the Commonwealth's priority list of impaired streams for violations of the fecal coliform bacteria standard. Beyond developing this multiple-tracer approach for locating sources of sewage inputs to Accotink Creek, the second objective of the study was to demonstrate how the multiple-tracer approach can be applied to other streams affected by sewage sources. The tracers used in this study were separated into indicator tracers, which are relatively simple and inexpensive to apply, and confirmatory tracers, which are relatively difficult and expensive to analyze. Indicator tracers include fecal coliform bacteria, surfactants, boron, chloride, chloride/bromide ratio, specific conductance, dissolved oxygen, turbidity, and water temperature. Confirmatory tracers include 13 organic compounds that are associated with human waste, including caffeine, cotinine, triclosan, a number of detergent metabolites, several fragrances, and several plasticizers. To identify sources of sewage to Accotink Creek, a detailed investigation of the Accotink Creek main channel, tributaries, and flowing storm drains was undertaken from 2001 to 2004. Sampling was conducted in a series of eight synoptic sampling events, each of which began at the most downstream site and extended upstream through the watershed and into the headwaters of each tributary. Using the synoptic sampling approach, 149 sites were sampled at least one time for indicator tracers; 52 of these sites also were sampled for confirmatory tracers at least one time. Through the analysis of multiple-tracer levels in the synoptic samples, three major sewage sources to the Accotink Creek stream network were identified, and several other minor sewage sources to the Accotink Creek system likely deserve additional investigation. Near the end of the synoptic sampling activities, three additional sampling methods were used to gain better understanding of the potential for sewage sources to the watershed. These additional sampling methods included optical brightener monitoring, intensive stream sampling using automated samplers, and additional sampling of several storm-drain networks. The samples obtained by these methods provided further understanding of possible sewage sources to the streams and a better understanding of the variability in the tracer concentrations at a given sampling site. Collectively, these additional sampling methods were a valuable complement to the synoptic sampling approach that was used for the bulk of this study. The study results provide an approach for local authorities to use in applying a relatively simple and inexpensive collection of tracers to locate sewage sources to streams. Although this multiple-tracer approach is effective in detecting sewage sources to streams, additional research is needed to better detect extremely low-volume sewage sources and better enable local authorities to identify the specific sources of the sewage once it is detected in a stream reach.

Virginia↗
USGS2024

Quantitative support for the benefits of proactive management for wildlife disease control

Finding effective pathogen mitigation strategies is one of the biggest challenges humans face today. In the context of wildlife, emerging infectious diseases have repeatedly caused widespread host morbidity and population declines of numerous taxa. In areas yet unaffected by a pathogen, a proactive management approach has the potential to minimize or prevent host mortality. However, typically critical information on disease dynamics in a novel host system is lacking, empirical evidence on efficacy of management interventions is limited, and there is a lack of validated predictive models. As such, quantitative support for identifying effective management interventions is largely absent, and the opportunity for proactive management is often missed. We considered the potential invasion of the chytrid fungus, Batrachochytrium salamandrivorans (Bsal), whose expected emergence in North America poses a severe threat to hundreds of salamander species in this global salamander biodiversity hotspot. We developed and parameterized a dynamic multistate occupancy model to forecast host and pathogen occurrence, following expected emergence of the pathogen, and evaluated the response of salamander populations to different management scenarios. Our model forecasted that taking no action is expected to be catastrophic to salamander populations. Proactive action was predicted to maximize host occupancy outcomes relative to wait-and-see reactive management, thus providing quantitative support for proactive management opportunities. The eradication of Bsal was unlikely under all the evaluated management options. Contrary to our expectations, even early pathogen detection had little effect on Bsal or host occupancy outcomes. Our results provide quantitative support that proactive management is the optimal strategy for promoting persistence of disease-threatened salamander populations. Our approach fills a critical gap by defining a framework for evaluating management options prior to pathogen invasion and can thus serve as a template for addressing novel disease threats that jeopardize wildlife and human health.

Conservation Biology↗
USGS2018

The risk of rodent introductions from shipwrecks to seabirds on Aleutian and Bering Sea islands

Accidental introductions of rodents present one of the greatest threats to indigenous island biota, especially seabirds. On uninhabited remote islands, such introductions are likely to come from shipwrecks. Here we use a comprehensive database of shipwrecks in Western Alaska to model the frequency of shipwrecks per Aleutian and Bering Sea island, taken as a proxy for the threat of rodent introductions, using physical variables, and the intensity of nearby fishing traffic and activity as predictors. Using data spanning from 1950 to 2013, we found that shipwrecks were particularly common in the 1980s to early 2000s, with a major peak in wrecks during the late 1980s. Amount of fishing activity within 5 km of an island was the strongest predictor of shipwrecks, followed by the strength of tidal currents and density of large-vessel traffic. Islands with the highest frequency of shipwrecks are all in the eastern Aleutians, including Unimak, Unalaska, and Akun Islands. By contrast, the largest seabird colonies are in the western Aleutian and Pribilof Islands, including Buldir, Kiska, and Saint George islands. Multiplying the frequency of a shipwreck by the number of seabirds breeding per island provides a measure of risk. The risk of rodent introductions from shipwrecks to seabirds was then greatest for Saint George (Bering Sea), Buldir (Western Aleutians) and Saint Matthew islands (Bering Sea). Keeping these high-risk islands rodent free would maintain their high a conservation value. Most islands with a high predicted frequency of shipwrecks already have established rodent populations and therefore few remaining seabirds. Of those islands with established rodent populations, Attu and Kiska Islands would make suitable targets for eradication, given their relatively low expected frequency of shipwrecks for their size. Further improvements in rat prevention on vessels and shipping safety would benefit the economy, human health and safety, and to the long-term conservation of island ecosystems.

Alaska↗
USGS2022

Observed and forecasted changes in land use by polar bears in the Beaufort and Chukchi Seas, 1985–2040

Monitoring changes in the distribution of large carnivores is important for managing human safety and supporting conservation. Throughout much of their range, polar bears ( Ursus maritimus ) are increasingly using terrestrial habitats in response to Arctic sea ice decline. Their increased presence in coastal areas has implications for bear-human conflict, inter-species interactions, and polar bear health and survival. We examined observed trends in land use over three decades by polar bears in the southern Beaufort Sea (SB) and Chukchi Sea (CS) where bears have traditionally spent most of the year on the sea ice. Using data from 408 adult females fitted with satellite radio-collars, we examined trends in the annual proportion of bears coming onshore (hereafter referred to as “percent of bears”) during the summer for ≥21 days, arrival and departure dates, duration spent onshore and relationships with sea ice metrics. We then estimated future land use through 2040 by extrapolating trends and by combining observed relationships between land use and sea ice with projections of future sea ice from an ensemble of earth system models. The observed percent of bears summering onshore and their duration onshore was correlated with the percent of open water that occurred within their population’s range between July and October. As sea ice declined, the percent of bears summering onshore increased from ~5 to 30% in the SB and ~10 to 50% in the CS and duration onshore increased by >30 days to 60–70 days in both populations. Using a range of greenhouse gas emission scenarios and adjustments for faster than forecasted sea ice loss we estimated that 50-62% of SB and 79-88% of CS bears will spend 90–108 and 110–126 days onshore during summer in the SB and CS, respectively, by 2040. Sea ice projections varied little between greenhouse gas emission scenarios prior to 2040 but diverged thereafter. Observed and forecasted increases in polar bear land occupancy puts more bears in proximity to human activities and settlements for longer durations while extending the lack of access to their primary prey. Because human conflict is one of the primary factors affecting the conservation of large carnivores worldwide, mitigation of bear-human interactions on land will be an increasingly important component of polar bear conservation.

Alaska↗
USGS2021

Assessing cyanobacterial frequency and abundance at surface waters near drinking water intakes across the United States

This study presents the first large-scale assessment of cyanobacterial frequency and abundance of surface water near drinking water intakes across the United States. Public water systems serve drinking water to nearly 90% of the United States population. Cyanobacteria and their toxins may degrade the quality of finished drinking water and can lead to negative health consequences. Satellite imagery can serve as a cost-effective and consistent monitoring technique for surface cyanobacterial blooms in source waters and can provide drinking water treatment operators information for managing their systems. This study uses satellite imagery from the European Space Agency's Ocean and Land Colour Instrument (OLCI) spanning June 2016 through April 2020. At 300-m spatial resolution, OLCI imagery can be used to monitor cyanobacteria in 685 drinking water sources across 285 lakes in 44 states, referred to here as resolvable drinking water sources. First, a subset of satellite data was compared to a subset of responses ( n = 84) submitted as part of the U.S. Environmental Protection Agency's fourth Unregulated Contaminant Monitoring Rule (UCMR 4). These UCMR 4 qualitative responses included visual observations of algal bloom presence and absence near drinking water intakes from March 2018 through November 2019. Overall agreement between satellite imagery and UCMR 4 qualitative responses was 94% with a Kappa coefficient of 0.70. Next, temporal frequency of cyanobacterial blooms at all resolvable drinking water sources was assessed. In 2019, bloom frequency averaged 2% and peaked at 100%, where 100% indicated a bloom was always present at the source waters when satellite imagery was available. Monthly cyanobacterial abundances were used to assess short-term trends across all resolvable drinking water sources and effect size was computed to provide insight on the number of years of data that must be obtained to increase confidence in an observed change. Generally, 2016 through 2020 was an insufficient time period for confidently observing changes at these source waters; on average, a decade of satellite imagery would be required for observed environmental trends to outweigh variability in the data. However, five source waters did demonstrate a sustained short-term trend, with one increasing in cyanobacterial abundance from June 2016 to April 2020 and four decreasing.

Water Research↗