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The Gas Hills uranium district and some probable controls for ore deposition

Uranium deposits occur in the upper coarse-grained facies of the Wind River formation of Eocene age in the Gas Hills district of the southern part of the Wind River Basin. Some of the principal deposits lie below the water table in the unoxidized zone and consist of uraninite and coffinite occurring as interstitial fillings in irregular blanket-like bodies. In the near-surface deposits that lie above the water table, the common yellow uranium minerals consist of uranium phosphates, silicates, and hydrous oxides. The black unoxidized uraninite -coffinite ores show enrichment of molybdenum, arsenic, and selenium when compared to the barren sandstone. Probable geologic controls for ore deposits include: 1) permeable sediments that allowed passage of ore-bearing solutions; 2) numerous faults that acted as impermeable barriers impounding the ore -bearing solutions; 3) locally abundant pyrite, carbonaceous material, and natuial gas containing hydrogen sulfide that might provide a favorable environment for precipitation of uranium. Field and laboratory evidence indicate that the uranium deposits in the Gas Hills district are very young and related to the post-Miocene to Pleistocene regional tilting to the south associated with the collapse of the Granite Mountains fault block. This may have stopped or reversed ground water movement from a northward (basinward) direction and alkaline ground water rich in carbonate could have carried the uranium into the favorable environment that induced precipitation.

Trace Elements Memorandum↗

Geologic framework and hydrogeologic characteristics of the Edwards Aquifer outcrop, Medina County, Texas

The hydrogeologic subdivisions of the Edwards aquifer outcrop in Medina County generally are porous and permeable. The most porous and permeable appear to be hydrogeologic subdivision VI, the Kirschberg evaporite member of the Kainer Formation; and hydrogeologic subdivision III, the leached and collapsed members, undivided, of the Person Formation. The most porous and permeable rocks of the Devils River Formation in Medina County appear to be in the top layer. The upper member of the Glen Rose Limestone, the lower confining unit, has much less porosity and permeability than that observed in the Edwards aquifer. The Edwards aquifer has relatively large porosity and permeability resulting, in part, from the development or redistribution of secondary porosity. Lithology, stratigraphy, diagenesis, and karstification account for the effective porosity and permeability in the Edwards aquifer outcrop. Karst features that can greatly enhance effective porosity and permeability in the Edwards aquifer outcrop include sinkholes, dolines, and caves. The Edwards aquifer rocks in Medina County change from the eight-member Edwards Group to the essentially indivisible Devils River Formation. The facies change occurs along a line extending northwestward from just south of Medina Lake.

Texas↗

Stratigraphy and vertical hydraulic conductivity of the St. Francois confining unit in townships 25-27 N. and ranges 01-02 W., southeastern Missouri

The St. Francois confining unit (DerbyDoerun Dolomite and Davis Formation) lies beneath the Ozark aquifer (Jefferson City Dolomite to the Potosi Dolomite) and impedes the circulation of water between the overlying Ozark aquifer and the underlying St. Francois aquifer (Bonneterre Formation and Lamotte Sandstone). The Bonneterre Formation is the potential host formation for lead-zinc deposits in the area. There is concern that mine dewatering in the Bonneterre Formation could lower water levels in the Ozark aquifer. To address this concern, the vertical hydraulic conductivity of the St. Francois confining unit in six townships (T. 25-27 N. and R. 01- 02 W.) of Oregon, Carter, and Ripley Counties of southeastern Missouri was evaluated by describing the stratigraphy and measuring the vertical hydraulic conductivity of core samples. The Davis Formation is an intrashelf basin facies consisting of a series of shales interbedded with shaley limestones, shale-free limestones, and local dolostones, and ranges from 24 to 320ft (feet) thick, but typically the thickness is 100 to 200 ft. Shale-dominant sequences can be tens of feet thick, and contain as much as 90 percent shale. Carbonate-dominant zones may be 70 ft thick or greater. The top of the Davis Formation (based on 56 data points) ranges from 620 to 2,022 ft deep and ranges in altitude from 40ft below sea level in the northern part of the study area to 1, 182 ft below sea level in the southern part of the study area. The Derby-Doerun Dolomite represents a pair of superimposed carbonate ramp cycles. Where present, the basal shaley sequence represents a transition with the Davis Formation. The formation (based on 50 data points) ranges from 50 to 386ft thick, but typically is 120 to 180ft thick in the study area. The top of the DerbyDoerun Dolomite ranges from 495 to 2,020 ft deep (based on 53 data points), and ranges in altitude from 85 ft above sea level to 94 7 ft below sea level. The St. Francois confining unit is thickest in the central and southern parts of the study area. The thickness, as determined by 51 core logs that completely penetrate the unit, ranges from less than 200ft in the northwestern and east-central parts of the study area to 411 ft in the central part, but typically ranges from 270 to 340 ft. The net shale thickness of the confining unit (based on 29 data points) ranges from 1. 7 ft in the east -central part of the study area to 89 ft in the southwest part. These net shale thickness values include the cumulative shale thickness of rock from the top of the Derby-Doerun Dolomite to the base of the False Davis. Vertical hydraulic conductivities of 35 rock core samples from the St. Francois confining unit in the study area range from 7.6 x 10 -15 to 2.1 x 10 -10 ft/s (foot per second). The logarithmic transformed vertical hydraulic conductivities of the Derby-Doerun Dolomite and Davis Formation are similar (p-value = 0.073) using the statistical twosample t-test; however, this p-value approaches the level of significance value of 0.05. The vertical hydraulic conductivity of the Derby-Doerun Dolomite is larger and less variable than the Davis Formation. When grouped by rock type, the vertical hydraulic conductivity of samples that contain carbonate, shale, or both carbonate and shale, are similar. A comparison on the ranked data using the Mann-Whitney test shows the confining unit in the study area is statistically different (p-value = 0.020) from the confining unit in the prospecting area (west and adjacent to the study area). The median value of the vertical hydraulic conductivity data from the study area (6.7 x 10 -13 ft/s) is three times larger than the median vertical hydraulic conductivity value for the prospecting area (2.2 x 10 -13 ft/s ). The interquartile range shows that the variability of the study area data spans one order of magnitude (2.0 x 10 -13 to 2.2 x 10 -12 ft/s) and that the corresponding data from the prospecting area spans nearly two orders of magnitude (3.2 x 10 -14 to 1.1 x 10 -12 ft/s). The ranked vertical hydraulic conductivities of the Derby-Doerun Dolomite in the two areas are statistically similar (p-value = 0.514). The median vertical hydraulic conductivity of the study area data ( 1.2 X 10 -12 ft/s) is about three times greater than the median value of the prospecting area data (4.4 x 10 -13 ft/s). The variability of the data, as shown by the interquartile range, is less in the study area (5.5 x 10 -13 to 2.2 x 10 -12 ft/s; spanning less than one order of magnitude) as compared to the prospecting area (3.2 x 10 -14 to 6.3 x 10 -10 ft/s; spanning over four orders of magnitude). The ranked vertical hydraulic conductivities of the Davis Formation in the two areas show these data sets are statistically similar (p-value = 0.076). The median vertical hydraulic conductivity value of study area samples ( 4.5 x 10 -13 ft/s) is three times greater than the median value of the prospecting area data (1.6 x 10 -13 ft/s). The interquartile range of the study area data spans one order of magnitude (1.2 x 10 -13 to 1.4 x 10 -12 ft/s) and the corresponding data from the prospecting area spans nearly 1.5 orders of magnitude (3.2 x 10 -14 to 7.4 x 10 -13 ft/s). The Mann-Whitney test shows the ranked vertical hydraulic conductivities of each rock type from the study area are statistically similar to the same rock type in the prospecting area [carbonates (p-value = 0.225), shales (p-value = 0.668), and carbonates and shales (p-value = 0.227)]. However, in each of the three cases the study area samples have larger median values and less variability than the prospecting area samples. Because the vertical hydraulic conductivity of the various rock types of the confining unit in the study area are statistically similar, the entire carbonate-shale thickness is the primary factor determining the effectiveness of the confining unit. The range of effective vertical hydraulic conductivity of the St. Francois confining unit in the study area using appropriate minimum and maximum thickness, net shale thickness, and vertical hydraulic conductivities is 3 X 10 -13 to 2 X 10 -12 ft/s. The vertical hydraulic conductivity of the confining unit is small, and the confining unit effectively impedes the ground-water flow between the Ozark aquifer and the St. Francois aquifer, unless preferred- path secondary permeability has developed along faults and fractures that extend through the confining unit.

Missouri↗

Geologic framework of the regional ground-water flow system in the Upper Deschutes Basin, Oregon

Ground water is increasingly relied upon to satisfy the needs of a growing population in the upper Deschutes Basin, Oregon. Hydrogeologic studies are being undertaken to aid in management of the ground-water resource. An understanding of the geologic factors influencing ground-water flow is basic to those investigations. The geology of the area has a direct effect on the occurrence and movement of ground water. The permeability and storage properties of rock material are influenced by the proportion, size, and degree of interconnection of open spaces the rocks contain. These properties are the result of primary geologic processes such as volcanism and sedimentation, as well as subsequent processes such as faulting, weathering, or hydrothermal alteration. The geologic landscape in the study area evolved during about 30 million years of volcanic activity related to a north-south trending volcanic arc, the current manifestation of which are today’s Cascade Range volcanoes. The oldest rock unit in the upper Deschutes Basin study area, the John Day Formation, is a sequence of upper Eocene to lower Miocene volcanic and sedimentary rocks. Weathering and alteration of the rocks has resulted in very low permeability; consequently, the unit forms the hydrologic basement for the regional ground- water flow system throughout much of the area. The Deschutes Formation and age-equivalent deposits that overlie the John Day Formation, in contrast, are highly permeable and are the most widely used ground-water-bearing units in the study area. The Deschutes Formation consists of a variety of volcanic and sedimentary deposits ranging in age from late Miocene to Pliocene (approximately 7.5 to 4.0 million years). Three distinct depositional environments previously described for the formation provide useful hydrogeologic subdivisions. The ancestral Deschutes River deposits and some units within the arc- adjacent alluvial-plain region are among the highest yielding units within the Deschutes Formation, with some wells producing up to a few thousand gallons per minute. Opal Springs basalt, Pelton basalt, and the rhyodacite dome complex near Steelhead Falls are particularly productive subunits within the Deschutes Formation and provide tens to hundreds of cubic feet per second of ground-water discharge to the Deschutes and Crooked Rivers, upstream of Round Butte Dam. Most ground-water recharge in the upper Deschutes Basin occurs in Quaternary deposits of the Cascade Range and Newberry Volcano. These deposits are highly permeable, and the fractured character of the lava flows facilitates rapid infiltration of precipitation and snowmelt, as well as movement of ground water to lower elevations. Additional recharge from canal leakage occurs along sections of unlined canals near Bend, constructed on lava flows from Newberry Volcano. Hydrothermal alteration and secondary mineralization at depth beneath the Cascade Range and Newberry Volcano has drastically reduced the permeability of the material in those regions, effectively restricting most ground water to the strata above the altered rocks. The top of the hydrothermally altered region is considered the base of the regional ground-water system beneath the Cascade Range and Newberry Volcano. Structural features influence ground-water flow within the upper Deschutes Basin mainly by juxtaposing materials with contrasting permeability. This juxtaposition can be caused by fault movement or by the influence of a fault on subsequent deposition. Several depositional centers have formed along the base of fault-line scarps or in grabens within the study area, and the infilling sedimentary deposits have permeability that differs from the surrounding rocks. The effects of faults on ground-water flow may be masked in some areas. For example, the water-table gradient changes slope in the vicinity of the Sisters fault zone, but the slope change also corresponds with a major precipitation gradient change; therefore, any influence of the fault zone is unclear. Geologic units in the Deschutes Basin were divided into several distinct hydrogeologic units. In some instances the units correspond to existing stratigraphic divisions. In other instances, hydrogeologic units correspond to different facies within a single stratigraphic unit or formation. The hydrogeologic units include Quaternary sediment, deposits of the Cascade Range and Newberry Volcano, four zones within the Deschutes Formation and age-equivalent rocks that roughly correspond with depositional environments, and pre-Deschutes-age strata.

Water-Resources Investigations Report↗

Development and calibration of a ground-water flow model for the Sparta Aquifer of southeastern Arkansas and north-central Louisiana and simulated response to withdrawals, 1998-2027

The Sparta aquifer, which consists of the Sparta Sand, in southeastern Arkansas and north-central Louisiana is a major water resource and provides water for municipal, industrial, and agricultural uses. In recent years, the demand in some areas has resulted in withdrawals from the Sparta aquifer that substantially exceed replenishment of the aquifer. Considerable drawdown has occurred in the potentiometric surface forming regional cones of depression as water is removed from storage by withdrawals. These cones of depression are centered beneath the Grand Prairie area and the cities of Pine Bluff and El Dorado in Arkansas, and Monroe in Louisiana. The rate of decline for hydraulic heads in the aquifer has been greater than 1 foot per year for more than a decade in much of southern Arkansas and northern Louisiana where hydraulic heads are now below the top of the Sparta Sand. Continued hydraulic-head declines have caused water users and managers alike to question the ability of the aquifer to supply water for the long term. Concern over protecting the Sparta aquifer as a sustainable resource has resulted in a continued, cooperative effort by the Arkansas Soil and Water Conservation Commission, U.S. Army Corps of Engineers, and the U.S. Geological Survey to develop, maintain, and utilize numerical ground-water flow models to manage and further analyze the ground-water system. The work presented in this report describes the development and calibration of a ground-water flow model representing the Sparta aquifer to simulate observed hydraulic heads, documents major differences in the current Sparta model compared to the previous Sparta model calibrated in the mid-1980's, and presents the results of three hypothetical future withdrawal scenarios. The current Sparta model-a regional scale, three-dimensional numerical ground-water flow model-was constructed and calibrated using available hydrogeologic, hydraulic, and water-use data from 1898 to 1997. Significant changes from the previous model include grid rediscretization of the aquifer, extension of the active model area northward beyond the Cane River Formation facies change, and representation of model boundaries. The current model was calibrated with the aid of parameter estimation, a nonlinear regression technique, combined with trial and error parameter adjustment using a total of 795 observations from 316 wells over 4 different years-1970, 1985, 1990, and 1997. The calibration data set provides broad spatial and temporal coverage of aquifer conditions. Analysis of the residual statistics, spatial distribution of residuals, simulated compared to observed hydrographs, and simulated compared to observed potentiometric surfaces were used to analyze the ability of the calibrated model to simulate aquifer conditions within acceptable error. The calibrated model has a root mean square error of 18 feet for all observations, an improvement of more than 12 feet from the previous model. The current Sparta model was used to predict the effects of three hypothetical withdrawal scenarios on hydraulic heads over the period 1998-2027 with one of those extended indefinitely until equilibrium conditions were attained, or steady state. In scenario 1a, withdrawals representing the time period from 1990 to 1997 was held constant for 30 years from 1998 to 2027. Hydraulic heads in the middle of the cone of depression centered on El Dorado decreased by 10 feet from the 1997 simulation to 222 feet below NGVD of 1929 in 2027. Hydraulic heads in the Pine Bluff cone of depression showed a greater decline from 61 feet below NGVD of 1929 to 78 feet below NGVD of 1929 in the center of the cone. With these same withdrawals extended to steady state (scenario 1b), hydraulic heads in the Pine Bluff cone of depression center declined an 2 Development and Calibration of a Ground-Water Flow Model for the Sparta Aquifer of Southeastern Arkansas and North-Central Louisiana and Simulated Response to Withdrawa

Water-Resources Investigations Report↗

Continuous seismic-reflection survey defining shallow sedimentary layers in the Charlotte Harbor and Venice areas, southwest Florida

A continuous marine seismic-reflection survey system was used to define the configuration of shallow sedimentary layers underlying the Charlotte Harbor and Venice areas, southwest Florida. Seismic profiling was conducted over a distance of about 57 miles of Charlotte Harbor, the Peace and Myakka Rivers, and the Intracoastal Waterway near Venice using a high resolution energy source capable of penetrating 200 feet of sediments with a resolution of 1 to 3 feet. Five stratigraphic units defined from the seismic records includes sediments to Holocene to early Miocene age. All seismic-profile records are presented, along with geologic sections constructed from the records. Seismic reflection amplitude, frequency, continuity, configuration, external form, and areal association were utilized to interpret facies and depositional environments of the stratigraphic units. The despositional framework of the units ranges from shallow shelf to prograded slope. The stratigraphic units are correlated with the surficial aquifer and intermediate artesian aquifers, and permeable zones of the aquifers are related to the seismic records. (USGS)

Florida↗

Digital simulation of the regional effects of subsurface injection of liquid waste near Pensacola, Florida

Industrial, organic, liquid waste has been injected into a part of the lower limestone of the Floridan aquifer at one site since 1963 and at another site since 1975, raising water levels in the injection zone throughout a large region. The hydrogeologic conceptual model of the injection zone is a layer tightly confined above by a thick layer of clay and in which lateral hydraulic conductivity decreases rapidly below the upper 60 feet. Recharge areas are to the north and east, where the confining layer pinches out. There appear to be permeability barriers to the northwest, west, and southwest due to facies changes, faults, or pinchouts. Measured and reconstructed preinjection water levels suggested that flow in the aquifer is from the northern recharge areas toward the southeast. A steady-state model simulation incorporating the cited boundary assumptions approximately simulated this pattern. A two-dimensional flow model and the subsurface waste injection program (SWIP) were calibrated to simulate the water level increases at various monitor wells since 1963. Sensitivity analyses showed the simulations to be quite sensitive to moderate errors in either transmissivity or storage parameter specifications. The predictive use of the hydraulic model is understood to be restricted to the geographical locations of data used for model calibration. (USGS)

Water-Resources Investigations Report↗

Nomenclature of regional hydrogeologic units of the Southeastern Coastal Plain aquifer system

Clastic sediments of the Southeastern Coastal Plain aquifer system can be divided into four regional aquifers separated by three regional confining units. The four regional aquifers have been named for major rivers that cut across their outcrop areas and expose the aquifer materials. From youngest to oldest, the aquifers are called the Chickasawhay River, Pearl River, Chattahoochee River, and Black Warrior River aquifers, and the regional confining units separating them are given the same name as the aquifer they overlie. Most of the regional hydrogeologic units are subdivided within each of the four States that comprise the study area. Correlation of regional units is good with hydrogeologic units delineated by a similar regional study to the west and southwest. Because of complexity created by a major geologic structure to the northeast of the study area and dramatic facies change from clastic to carbonate strata to the southeast, correlation of regional hydrogeologic units is poor in these directions. (Author 's abstract)

Water-Resources Investigations Report↗

US Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Phoenix, Arizona, September 26-30, 1988

Crude oil floating at the surface of a shallow aquifer of glacial outwash, near Bemidji, Minnesota, is altered by geochemical processes. Hydrocarbons from the oil are attenuated by several reactions that include aerobic and anaerobic microbial degradation. These degradation reactions result in the development of geochemical facies in the shallow groundwater system. Groundwater most affected by the presence of organic compounds is anoxic, and concentrations of methane, dissolved organic carbon, and total inorganic are high--0.76 millimole/L, 2.9 millimole/L, and 12.3 millimole/L, respectively. The concentrations of chemical species and delta-(13)C isotope values indicate that the plume near the oil lens has become progressively more reducing. Over a 4-year period (1984 through 1987), the concentrations of methane and iron have increased by a factor of > 25. The data suggest that sequential degradation occurs, as predicted by thermo-dynamics: manganese is reduced before iron is reduced, which occurs before methanogenesis. These data provide field evidence that reduction of iron and manganese is an important mechanism of decomposition of organic matter in aquifers. The delta-(13)C values of inorganic carbon of the native groundwater range from -12 ppt to -15 ppt as a result of mixing of soil CO2 with CO2 from the dissolution of carbonates. Non methanogenic biodegradation of oil constituents adds isotopically light CO2 to the groundwater because the oil has a delta-(13)C value of 28 ppt. The delta-(13)C value of inorganic carbon in the reducing zone have become progressively heavier from 1985 through 1987. The maximum change occurs 15 m downgradient from the oil lens, where the delta-(13)C values increased from -21.6 ppt to -5.35 ppt. This change indicates that the plume has become more reducing and methanogenic over time.

Water-Resources Investigations Report↗

Hydrogeology, geochemistry, and quality of water of The Basin and Oak Spring areas of the Chisos Mountains, Big Bend National Park, Texas

Test drilling near two sewage lagoons in The Basin area of the Chisos Mountains, Big Bend National Park, Texas, has shown that the alluvium and colluvium on which the lagoons are located is not saturated in the immediate vicinity of the lagoons. A shallow aquifer, therefore, does not exist in this critical area at and near the lagoons. Should seepage outflow from the lagoons occur, the effluent from the lagoons might eventually be incorporated into shallow ground water moving westward in the direction of Oak Spring. Under these conditions such water could reach the spring. Test borings that bottomed in bedrock below the alluvial and colluvial fill material are dry, indicating that no substantial leakage from the lagoons was detected. Therefore, no contaminant plume was identified. Fill material in The Basin does not contain water everywhere in its extensive outcropping area and supplies only a small quantity of ground water to Window Pouroff, which is the only natural surface outlet of The Basin. Oak Spring, which is almost 2 miles downgradient from the lagoons, is the sole source of water for The Basin the principal tourist area in Big Bend National Park. Test drilling in the Oak Spring area revealed that the aquifer in the immediate vicinity of Oak Spring is a 5-foot thick sand bed hydraulically confined above and below by relatively thick, compact clay. The sand bed might be bounded locally by faults to the east and west of the spring. The test drilling and seismic surveys in the area also established the existence of a thick, extensive, surficial layer of colluvium consisting of large rhyolite boulders. The colluvial layer, which overlies sedimentary bedrock containing the Oak Spring aquifer, was unsaturated at the borehole sites. Information from drilling and from hydrogeologic observation indicates that the water from Oak Spring originates as precipitation in the Oak Spring area west of The Basin, with possibly a contribution originating as discharge from The Basin. The rhyolite boulder field in the Oak Spring area, which includes talus from Vernon Bailey Peak, is an effective receptacle for rapid recharge of precipitation. This water could then be efficiently routed into the Oak Spring aquifer in places to the east of Oak Spring where any shallow ground water in the boulder field might enter the subcropping truncated aquifer. Water-chemistry data, hydrochemical facies, and isotopic data also indicate that water from Oak Spring originates principally from precipitation onto the land surface of the Oak Spring area. Tritium data indicate that Oak Spring water is "modern," with an average age of recharge less than 14 years. The flow rates recorded almost continuously at Oak Spring beginning in December 1986 show a close relation between precipitation and discharge. The highest recorded spring flow of 167 gallons per minute in December 1986 is attributed to record high precipitation in the area during 1986. The lowest recorded flow of 22.4 gallons per minute, in December 1989, followed a period of 20 out of 26 months of below-normal precipitation. Flow at Oak Spring typically lags behind precipitation by about 1 month. This fairly rapid response indicates the spring is fed by a shallow aquifer having good permeability and effective recharge areas with the ability to absorb precipitation rapidly.

Texas↗

Selected geochemical characteristics of ground water from the Saginaw aquifer in the central Lower Peninsula of Michigan

Chemical and stable-isotope data of water from wells completed in the Saginaw aquifer in the central Lower Peninsula of Michigan were used to prepare maps that show areal variation of δ 18 O; distribution of dissolved solids, dissolved chloride, dissolved iron, dissolved sulfate; and distribution of hydrochemical facies. Delta oxygen-18 values indicate the presence of modern meteoric water (δ 18 O approximately -10 parts per thousand) and glacial-age meteoric water, which is isotopically light (δ 18 O less than -15 parts per thousand). Isotopically light ground water is present in the Saginaw Bay Area in the eastern part of the study area. Dissolved-solids concentration ranges from 41 to 92,300 milligrams per liter, and dissolved-chloride concentrations range from less than 1 to 55,000 milligrams per liter. Dissolved-solids and dissolved-chloride concentrations increase toward Saginaw Bay. Dissolved-iron and dissolved-sulfate concentration ranges from 0.01 to 7.80 and 0.2 to 3,500 milligrams per liter, respectively. Most ground water from the Saginaw aquifer is classified as calcium bicarbonate, calcium sulfate, or sodium chloride.

Michigan↗

Selected geochemical characteristics of ground water from the Glaciofluvial aquifer in the central Lower Peninsula of Michigan

Chemical and stable-isotope data for water from wells completed in the Glaciofluvial aquifer in the central Lower Peninsula of Michigan were used to prepare maps that show the areal variation of 8180; distribution of dissolved solids, dissolved chloride, dissolved iron, and dissolved sulfate; and distribution of hydrochemical facies. Delta oxygen-18 values indicate the presence of modem meteoric water (6180 approximately 40 parts per thousand) and glacial-age meteoric water, which is isotopically light 0180 less than -15 parts per thousand). Isotopically light ground water is present in the Saginaw Bay Area in the eastern part of the study area. Dissolved-solids concentrations are generally less than 1,000 milligrams per liter, and dissolved-chloride concentrations are generally less than 100 milligrams per liter. These concentrations are greatest in ground water from the Saginaw Bay Area where measured concentrations are as large as 12,000 milligrams per liter for dissolved solids and 6,700 milligrams per liter for dissolved chloride. Dissolved-iron concentrations range from 0.001 to 6.0 milligrams per liter. Dissolved-sulfate concentrations range from 1 to 1,800 milligrams per liter. Most ground water from the Glaciofluvial aquifer is classified as a calcium bicarbonate type. In the Saginaw Bay Area, ground water is a sodium chloride type.

Michigan↗

Selected geochemical characteristics of ground water from the Marshall aquifer in the central Lower Peninsula of Michigan

Chemistry and stable-isotope data for water from wells completed in the Marshall aquifer within the Michigan Basin were used to prepare maps that show area! variations of δ 18 O; distribution of dissolved solids, dissolved chloride, dissolved iron, and dissolved sulfate; and distribution of hydrochemical facies. Delta oxygen-18 values indicate the presence of modern meteoric water ( δ 18 O approximately -10 parts per mil) as well as isotopically light meteoric water ( δ 18 O less than -15 parts per mil). Isotopically light ground water is present in the Michigan Lowland. Dissolved-solids concentrations range from 273 to 412,000 milligrams per liter, and dissolved-chloride concentrations range from less than 10 to greater than 250,000 milligrams per liter. Dissolved-solids and dissolved-chloride concentrations increase toward the center of the study area. Dissolved-iron concentrations which range from less than 0.002 to 100 milligrams per liter, are low in the subcrop areas, and increase toward the center of the study area. Dissolved-sulfate concentrations range from 4.5 to 3,500 milligrams per liter and generally increase then decrease from the subcrop area toward the center of the study area. Most ground water in the Marshall aquifer is classified as either a calcium bicarbonate or a sodium chloride type.

Michigan↗

Geohydrologic reconnaissance of Lake Mead National Recreation Area: Las Vegas Wash to Virgin River, Nevada

This study is the last of a series of eight geohydrologic reconnaissance studies that were done in the Lake Mead National Recreation Area. The studies were done to evaluate the water resources in the recreation area and to identify areas having potential for the development of water supplies that would be adequate for marinas and campgrounds. The study area includes about 250 square miles north of Lake Mead from Las Vegas Wash to the Virgin River (Overton Arm), Nevada. Volcanic rocks, consolidated sedimentary rocks, and unconsolidated to semiconsolidated sedimentary rocks underlie the area. Surface-water sources include the Colorado River, Virgin River, Muddy River, and Las Vegas Wash. Elsewhere in the area, streamflow is meager and extremely variable. Ground water originates from four sources: (1) subsurface flow in local basins, (2) infiltration of water from Lake Mead into permeable rocks near the lake, (3) subsurface flow in valleys of perennial streams, and (4) subsurface flow in consolidated rocks of the Muddy Mountains. The quantity of water from Lake Mead that has saturated rocks adjacent to the lake probably is greater than the quantity of ground water from all the other sources. Rocks saturated by water from the lake probably extend less than 0.5 mile inland from the lake shore. The quality of virtually all the ground water in the area is not acceptable for drinking purposes. The most favorable areas for obtaining ground water are those underlain by the coarse-grained deposits of the older alluvium and the younger alluvium adjacent to Lake Mead. The least favorable areas are those underlain by the mudstone facies of the Muddy Creek Formation and fine-grained rocks of the Horse Spring Formation. Four areas identified as having potential for ground-water development are (1) near Overton Beach, (2) west of Callville Bay, (3) near Middle Point, and (4) in the lower Moapa Valley. Usable quantities of water probably can be obtained at these sites, but the quality of the water may not be acceptable for drinking purposes. Test drilling for potable water supplies should be considered only as exploration.

Nevada↗

Geohydrology of Pipe Spring National Monument area, northern Arizona

Pipe Spring National Monument is on the Arizona Strip, an area between the Utah border to the north and the north rim of the Grand Canyon to the south. Four springs at the base of Winsor Point on Winsor Mountain (known collectively as Pipe Spring) are a part of the historical significance of the monument. The relation between declining discharges from springs in the monument and ground-water development north of the monument was studied to provide information that could be used for management of the monument resources. Ground-water elevations from wells indicate that ground-water movement is from north to south along the west side of a branch of Sevier Fault. Faulting in the areas has downthrown permeable water-bearing sediments relative to impermeable sediments and is evinced by cliffs along the western and northern edges and flat-lying areas to the east. The Navajo Sandstone and Kayenta Formation are the primary water-bearing units on the west side of the fault. The semipermeable sediments of the Chinle and Moenkopi Formations on the east side of the fault inhibit ground-water movement from the west to the east side of the fault. Ground water south of Moccasin Canyon is higher in total dissolved solids than ground water north of Moccasin Canyon. Wells north of Moccasin Canyon are open primarily in the Navajo Sandstone, and wells south of Moccasin Canyon are open primarily in the upper sandstone facies of the Kayenta Formation. A water-budget estimate for the study area indicates a storage deficit of 780 acre-feet per year. This deficit suggests that some recharge may be occurring outside the study area. Oxygen and hydrogen stable- isotopic data suggest no isotopic variation in recharging waters in the study area and surrounding region. Radiocarbon and tritium activities indicate apparent ground-water ages at wells and springs are between 45 and 9,000 years.

Arizona↗

Distribution of Trichloroethylene and Geologic Controls on Contaminant Pathways near the Royal River, McKin Superfund Site Area, Gray, Maine

Vapor-diffusion samplers were used in the autumn of 1997 to determine the lateral extent and distribution of concentrations of a trichloroethylene (TCE) plume in the ground-water discharge area near the McKin Superfund Site, Gray, Maine. Analyses of vapor in the samplers identified a plume about 800 feet wide entering the river near Boiling Springs, an area of ground-water discharge on the flood plain of the Royal River. The highest observed concentration of TCE in vapor was in an area of sand boils on the western bank of the river and about 200 feet downstream from Boiling Springs. Previous studies showed that most of the TCE load in the river originated in the area of the sand boils. In general, highest concentrations were observed on the western side of the river on the upgradient side of the plume, but TCE also was detected at numerous locations in the center and eastern bank of the river. The TCE plume discharges to the river where fine-grained glaciomarine sediments of the Presumpscot Formation are absent and where coarse-grained facies of buried glaciomarine fan deposits provide a pathway for ground-water flow. Based on results of analyses of vapor-diffusion samples and other previous studies, the plume appears to pass under and beyond the river near Boiling Springs and along the river for about 300 feet downstream from the sand boils. A coarse-grained, organic-rich layer at the base of the alluvial flood plain sediments is confined by overlying fine-grained alluvial sediments and may provide a conduit for ground-water leaking upward from buried glaciomarine fan deposits.

Water-Resources Investigations Report↗

Geologic and hydrologic features of the San Bernardino area, California; with special reference to underflow across the San Jacinto fault

This is the second in a series of interpretive reports on subsurface outflow from the ground-water basins of San Bernardino County, Calif., prepared by the U.S. Geological Survey in cooperation with the San Bernardino County Flood Control District. One principal purpose of the study was to estimate the ground-water outflow from the Bunker Hill basin to the Rialto-Colton basin across the San Jacinto fault, which, except locally, forms a nearly impermeable boundary between the two basins. In addition, the report deals qualitatively with the geology, the fault barriers that divide the area into several ground-water basins, the physical nature and degree of imperviousness of the barriers, the occurrence and movement of ground water and fluctuations of water level in the basins, and the chemical quality of surface and ground waters in the San Bernardino area. The report includes a geologic map and sections, water-level-contour maps and profiles, and hydrographs of selected well. The Santa Ana River, the principal stream, flows generally westward across the area. Channels of the river and its tributaries overlie a large irregular structural depression filled with alluvial deposits ranging in age from late Tertiary to Recent and forming a valley bounded on the north by the San Gabriel Mountains, on the east by the San Bernardino Mountains, and on the south by an irregular group of hills. Large alluvial fans underlie most of the area, but its landforms also include alluvial benches and terraces near the mountains, stream channels, and elongate hills, ridges, and scarps along the trace of the San Jacinto fault, which strikes northwestward across the valley about in the center of the area. This fault and others divide the area into ground-water basins, which include the Bunker Hill, Rialto-Colton, upper and lower Lytle and Chino basins. The water-bearing deposits include the following units: the younger alluvium. of Recent age, which occupies principally the backfilled channels beneath the Santa Ana River and its tributaries and through which ground water moves from Bunker Hill basin to Rialto-Colton basin; the older alluvium, of Pleistocene age, which is the principal water-bearing unit of the area and yields water to more than a thousand wells; and continental deposits of Tertiary to Quaternary age, which crop out along the southern margin of the area and locally along the San Gabriel Mountains on the north. The younger alluvium attains a maximum thickness of about 125 feet beneath the Santa Ana River south of San Bernardino. Locally in the Bunker Hill basin it is composed of two members, an upper member of relatively impermeable clay and a lower member of highly permeable material in which water is confined by the upper member. The older alluvium locally has a known thickness greater than 700 feet; elsewhere in the San Bernardino Valley it may exceed 1,400 feet. Locally, where ground water is confined in Bunker Hill basin, the older alluvium is divided into three permeable water-bearing zones separated from each other and from the younger alluvium above by less permeable zones. In parts of Chino and Rialto-Colton basins the alluvium consists of a coarse-grained facies along a former course of a major stream that is interfingered with and overlain by relatively fine-grained deposits. The permeability of the younger alluvium in the area beneath the Santa Ana River downstream from the San Jacinto fault was determined from tests to be about 2,700 gallons per day per square foot. The permeability of the coarse water-yielding materials of the older alluvium several miles downstream was estimated from tests to be about the same magnitude. Rocks that yield practically no water include continental rocks of Tertiary age, which are not exposed in the area but are tapped by wells in Rialto-Colton basin, and crystalline and metamorphic rocks of pre-Tertiary age that form the bedrock of the area.

California↗

Geology and ground water of the Luke area, Maricopa County, Arizona

Luke Air Force Base, in the Salt River Valley in central Arizona. is within an intermontane basin--the Phoenix basin--in the Basin and Range lowlands province. The Luke area, the subject of this study, extends beyond the limits of the base. Ground-water resources of the Luke area were studied to determine the possibility of developing a water supply of optimum quantity and quality to supplement the base supply. Several wells drilled for this purpose, prior to the study, either produced an inadequate supply of water or produced ware-that had a high dissolved-solids content. The Phoenix basin is filled with unconsolidated to semiconsolidated Tertiary and Quaternary sedimentary rocks that are referred to as valley fill. Although its total thickness is unknown, 2,784 feet of valley fill--primarily consisting of clay, silt, sand, and gravel--has been penetrated. Percentage-distribution maps of fine-grained materials indicate a gross-facies pattern and a selective depositional area of the valley-fill materials. The maps also indicate that the areal distribution of fine-grained materials increases with depth. In general, the better producing wells, regardless of depth, are in areas where tee valley fill is composed of less than 60 percent fine-grained materials. The water table in the area is declining because large quantities of water are withdrawn and recharge is negligible. The decline near Luke Air Force Base during the period 1941-61 was about 150 feet. Ground water was moving generally southwest in the spring of 1961. Locally, changes in the direction of movement indicate diversion toward two major depressions. The dissolved-solids content of the ground water ranged from about 190 to 6,300 ppm. The highest concentration of dissolved solids is in water from the southern part of the area and seems to come from relatively shallow depths; wells in the northern part generally yield water of good quality. After a reconnaissance of the area, the U.S. Geological Survey located and supervised the drilling of two test wells--wells (B-2-1) 9bcb and (B-2-1) 5abc?on Luke Air Force Base. The quantity of water produced by the wells was adequate. The dissolved-solids content of water from the wells was low, and the overall quality of water from well (B-2-1) 5abc was good. When well (B-2-1) 9bcb was perforated between 907 and 977 feet, the water had a fluoride concentration of 4.4 ppm; however, the fluoride concentration decreased to 2.8 ppm when new perforations were cut at a shallower depth, and it was decided that dilution with other base water supplies probably would alleviate any possible fluoride problem.

Water Supply Paper↗