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Evolving wildlife management cultures of governance through Indigenous Knowledges and perspectives

Within governance agencies, academia, and communities alike, there are increasing calls to recognize the value and importance of culture within social-ecological systems and to better implement Indigenous sciences in research, policy, and management. Efforts thus far have raised questions about the best ethical practices to do so. Engaging with plural worldviews and perspectives on their own terms reflects cultural evolutionary processes driving paradigm shifts in 3 fundamental areas of natural resource management: conceptualizations of natural resources and ecosystems, processes of public participation and governance, and relationships with Indigenous Peoples and communities with differing worldviews. We broadly describe evolution toward these paradigm shifts in fish and wildlife management. We then use 3 case studies to illustrate the ongoing cultural evolution of relationships between wildlife management and Indigenous practices within specific historical and social-ecological contexts and reflect on common barriers to appropriately engaging with Indigenous paradigms and lifeways. Our case studies highlight 3 priorities that can assist the field of wildlife management in achieving the changes necessary to bridge incommensurable worldviews: acknowledging and reconciling historical legacies and their continued power dynamics as part of social-ecological systems, establishing governance arrangements that move beyond attempts to extract cultural information from communities to integrate Indigenous Knowledges into dominant management paradigms, and engaging in critical reflexivity and reciprocal, accountable relationship building. Implementing these changes will take time and a commitment to processes that may initially feel uncomfortable and unfamiliar but have potential to be transformative. Ethical and culturally appropriate methods to include plural and multivocal perspectives and worldviews on their own terms are needed to transform wildlife management to achieve more effective and just management outcomes for all.

Journal of Wildlife Management↗

Frameworks for assessing tsunami hazard and risk

Tsunamis are multiscale phenomena resulting from a water column displacement that may be induced by multiple sources, and range from local scale inundation processes to ocean-wide scale wave propagation. Different strategies may be required to model tsunami evolution at different scales and to characterize various intensity measures. Research in tsunami hazard and risk has focused mostly on the tsunami effects such as the wave heights or flow depths. This chapter reviews the evolution of tsunami hazard and risk assessment methodologies, with particular emphasis on the development of probabilistic approaches. Building on advances in numerical modeling and uncertainty analysis, two main frameworks for Probabilistic Tsunami Hazard and Risk Analysis (PTHA/PTRA) are described. Framework 1 (FW1) focuses on quantitative methods, including fully simulation-based assessments (FW1A), integration of hazard with vulnerability and loss models (FW1B), consideration of dynamic processes such as tidal and sea-level variations (FW1C), and approaches using limited scenario sets (FW1D). Framework 2 (FW2) complements this by incorporating indicator-based vulnerability assessments, both physical (FW2A) and social, multi-dimensional (FW2B).

Book chapter↗

Exposure of a late cretaceous layered mafic-felsic magma system in the central Sierra Nevada batholith, California

New U-Pb zircon ages for the Lamarck Granodiorite, associated synplutonic gabbro and diorite plutons, and two large mafic intrusive complexes that underlie them in the Sierra Nevada batholith are 92??1 Ma. These ages establish the Late Cretaceous as a period of extensive mafic-felsic magmatism in the central part of the batholith, and confirm the significance of mafic magmatism in the evolution of the voluminous silicic plutions in the Sierran arc. The lack of significant zircon inheritance in any of the units analyzed supports isotopic evidence that the Lamarck and other Late Cretaceous Sierran plutons were derived predominantly from young crust. Recognition of an extensive mafic-felsic magma system in the Sierra Nevada batholith emphasizes the importance of basaltic liquids in the evolution of continental crust in arc settings. ?? 1995 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Garnet compositions and their use as indicators of peraluminous granitoid petrogenesis - southeastern Arabian Shield

Garnet, an uncommon accessory mineral in igneous rocks, occurs in seven small peraluminous granitoid plutons in the southeastern Arabian Shield; textural equilibrium between garnet and other host granitoid minerals indicates that the garnets crystallized from their host magmas. Compositions of the garnets form three groups that reflect host-granitoid compositions, which in turn reflect source compositions and tectonic regimes in which the host magmas were generated. Garnets from the seven plutons have almandine-rich cores and spessartine-rich rims. This reverse zoning depicts host magma compositional evolution; i.e. rimward spessartine enrichment resulted from progressive, host-magma manganese enrichment. The garnets are heavy rare-earth element enriched; (Lu/La)N ranges from 13 to 355 and one of the garnets contains spectacularly elevated abundances of Y, Ta, Th, U, Zn, Zr, Hf, Sn, and Nb. Involvement of garnets with these trace element characteristics in magma genesis or evolution can have dramatic effects on trace element signatures of the resulting magmas. Other researchers suggest that Mn-enriched magmas are most conducive to garnet nucleation. Although the garnetiferous granitoids discussed here are slightly Mn enriched, other genetically similar peraluminous Arabian granitoids lack garnet; Mn enrichment alone does not guarantee garnet nucleation. The presence of excess alumina in the magma may be a prerequisite for garnet nucleation. ?? 1988 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

Fire adaptation in Neblinaria celiae (Theaceae), a high-elevation rosette shrub endemic to a wet equatorial tepui

Neblinaria celiae (Theaceae), a rosette shrub endemic to the exceedingly rainy summit of remote Cerro de la Neblina in southern Venezuela, has a previously undescribed set of adaptations to fire. Its growth form entails sparse branching, massive terminal leaf rosettes, and thick bark. It is highly fire-tolerant, with a survival rate of 93% in a stand recently ignited by lightning, vs. 0% in seven co-occurring woody species. Survival increases sharply with rosette height, favoring a sparsely branched habit that would maximize the rate of upward growth through the sparse fuel layer supported by a sterile substrate. Thick bark and massive rosettes help protect cambial and foliar meristems from brief exposure to high temperatures. Rosettes on shorter plants are exposed to greater damage from fire near the ground and, as expected, are bigger and impound more rainwater; the greater number of leaves nearly balances the greater leaf mortality caused by fire. We relate Neblinaria's growth form to its dominance atop Neblina, to a general model for the evolution of sparse branching, and to the evolution of growth form in other tepui plants.

Oecologia↗

Geology of the peralkaline volcano at Pantelleria, Strait of Sicily

Situated in a submerged continental rift, Pantelleria is a volcanic island with a subaerial eruptive history longer than 300 Ka. Its eruptive behavior, edifice morphologies, and complex, multiunit geologic history are representative of strongly peralkaline centers. It is dominated by the 6-km-wide Cinque Denti caldera, which formed ca. 45 Ka ago during eruption of the Green Tuff, a strongly rheomorphic unit zoned from pantellerite to trachyte and consisting of falls, surges, and pyroclastic flows. Soon after collapse, trachyte lava flows from an intracaldera central vent built a broad cone that compensated isostatically for the volume of the caldera and nearly filled it. Progressive chemical evolution of the chamber between 45 and 18 Ka ago is recorded in the increasing peralkalinity of the youngest lava of the intracaldera trachyte cone and the few lavas erupted northwest of the caldera. Beginning about 18 Ka ago, inflation of the chamber opened old ring fractures and new radial fractures, along which recently differentiated pantellerite constructed more than 25 pumice cones and shields. Continued uplift raised the northwest half of the intracaldera trachyte cone 275 m, creating the island's present summit, Montagna Grande, by trapdoor uplift. Pantellerite erupted along the trapdoor faults and their hingeline, forming numerous pumice cones and agglutinate sheets as well as five lava domes. Degassing and drawdown of the upper pantelleritic part of a compositionally and thermally stratified magma chamber during this 18-3-Ka episode led to entrainment of subjacent, crystal-rich, pantelleritic trachyte magma as crenulate inclusions. Progressive mixing between host and inclusions resulted in a secular decrease in the degree of evolution of the 0.82 km3 of magma erupted during the episode. The 45-Ka-old caldera is nested within the La Vecchia caldera, which is thought to have formed around 114 Ka ago. This older caldera was filled by three widespread welded units erupted 106, 94, and 79 Ka ago. Reactivation of the ring fracture ca. 67 Ka ago is indicated by venting of a large pantellerite centero and a chain of small shields along the ring fault. For each of the two nested calderas, the onset of postcaldera ring-fracture volcanism coincides with a low stand of sea level. Rates of chemical regeneration within the chamber are rapid, the 3% crystallization/Ka of the post-Green Tuff period being typical. Highly evolved pantellerites are rare, however, because intervals between major eruptions (averaging 13-6 Ka during the last 190 Ka) are short. Benmoreites and mugearites are entirely lacking. Fe-Ti-rich alkalic basalts have erupted peripherally along NW-trending lineaments parallel to the enclosing rift but not within the nested calderas, suggesting that felsic magma persists beneath them. The most recent basaltic eruption (in 1891) took place 4 km northwest of Pantelleria, manifesting the long-term northwestward migration of the volcanic focus. These strongly differentiated basalts reflect low-pressure fractional crystallization of partial melts of garnet peridotite that coalesce in small magma reservoirs replenished only infrequently in this continental rift environment. ?? 1986 Springer-Verlag.

Bulletin of Volcanology↗

A lead isotope study of mineralization in the Saudi Arabian Shield

New lead isotope data are presented for some late Precambrian and early Paleozoic vein and massive sulfide deposits in the Arabian Shield. Using the Stacey Kramers (1975) model for lead isotope evolution, isochron model ages range between 720 m.y. and 420 m.y. Most of the massive sulfide deposits in the region formed before 680 m.y. ago, during evolution of the shield. Vein type mineralization of higher lead content occurred during the Pan African event about 550 m.y. ago and continued through the Najd period of extensive faulting in the shield that ended about 530 m.y. ago. Late post-tectonic metamorphism may have been responsible for vein deposits that have model ages less than 500 m.y. Alternatively some of these younger model ages may be too low due to the mineralizing fluids acquiring radiogenic lead from appreciably older local crustal rocks at the time of ore formation. The low207Pb/204Pb ratios found for the deposits in the main part of the shield and for those in north-eastern Egypt, indicate that the Arabian craton was formed in an oceanic crustal environment during the late Precambrian. Involvement of older, upper-crustal material in the formation of the ore deposits in this part of the shield is precluded by their low207Pb/204Pb and208Pb/204Pb characteristics. In the eastern part of the shield, east of longitude 44??20???E towards the Al Amar-Idsas fault region, lead data are quite different. They exhibit a linear207Pb/204Pb-206Pb/204Pb relationship together with distinctly higher208Pb/204Pb characteristics. These data imply the existence of lower crustal rocks of early Proterozoic age that apparently have underthrust the shield rocks from the east. If most of the samples we have analyzed from this easterly region were mineralized 530 m.y. ago, then the age of the older continental rocks is 2,100??300 m.y. (2??). The presence of upper crustal rocks, possibly also of early Proterozoic age, is indicated by galena data from Hailan in South Yemen and also from near Muscat in Oman. These data are the first to indicate such old continental material in these regions. ?? 1980 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

A study of the 2015 Mw 8.3 Illapel earthquake and tsunami: Numerical and analytical approaches

The September 16, 2015 Illapel, Chile earthquake triggered a large tsunami, causing both economic losses and fatalities. To study the coastal effects of this earthquake, and to understand how such hazards might be accurately modeled in the future, different finite fault models of the Illapel rupture are used to define the initial condition for tsunami simulation. The numerical code Non-hydrostatic Evolution of Ocean WAVEs (NEOWAVE) is employed to model the tsunami evolution through the Pacific Ocean. Because only a short time is available for emergency response, and since the earthquake and tsunami sources are close to the coast, gaining a rapid understanding of the near-field run-up behavior is highly relevant to Chile. Therefore, an analytical solution of the 2 ? 1 D shallow water wave equations is considered. With this solution, we show that we can quickly estimate the run-up distribution along the coastline, to first order. After the earthquake and tsunami, field observations were measured in the surrounded coastal region, where the tsunami resulted in significant run-up. First, we compare the analytical and numerical solutions to test the accuracy of the analytical approach and the field observations, implying the analytic approach can accurately model tsunami run-up after an earthquake, without sacrificing the time necessary for a full numerical inversion. Then, we compare both with field run-up measurements. We observe the consistency between the two approaches. To complete the analysis, a tsunami source inversion is performed using run-up field measurements only. These inversion results are compared with seismic models, and are shown to capture the broad-scale details of those models, without the necessity of the detailed data sets they invert.

Illapel↗

Small-scale sediment transport patterns and bedform morphodynamics: New insights from high resolution multibeam bathymetry

New multibeam echosounder and processing technologies yield sub-meter-scale bathymetric resolution, revealing striking details of bedform morphology that are shaped by complex boundary-layer flow dynamics at a range of spatial and temporal scales. An inertially aided post processed kinematic (IAPPK) technique generates a smoothed best estimate trajectory (SBET) solution to tie the vessel motion-related effects of each sounding directly to the ellipsoid, significantly reducing artifacts commonly found in multibeam data, increasing point density, and sharpening seafloor features. The new technique was applied to a large bedform field in 20–30 m water depths in central San Francisco Bay, California (USA), revealing bedforms that suggest boundary-layer flow deflection by the crests where 12-m-wavelength, 0.2-m-amplitude bedforms are superimposed on 60-m-wavelength, 1-m-amplitude bedforms, with crests that often were strongly oblique (approaching 90°) to the larger features on the lee side, and near-parallel on the stoss side. During one survey in April 2008, superimposed bedform crests were continuous between the crests of the larger features, indicating that flow detachment in the lee of the larger bedforms is not always a dominant process. Assessment of bedform crest peakedness, asymmetry, and small-scale bedform evolution between surveys indicates the impact of different flow regimes on the entire bedform field. This paper presents unique fine-scale imagery of compound and superimposed bedforms, which is used to (1) assess the physical forcing and evolution of a bedform field in San Francisco Bay, and (2) in conjunction with numerical modeling, gain a better fundamental understanding of boundary-layer flow dynamics that result in the observed superimposed bedform orientation.

California↗

Monitoring the cooling of the 1959 Kīlauea Iki lava lake using surface magnetic measurements

Lava lakes can be considered as proxies for small magma chambers, offering a unique opportunity to investigate magma evolution and solidification. Repeated magnetic ground surveys over more than 50 years each show a large vertical magnetic intensity anomaly associated with Kīlauea Iki Crater, partly filled with a lava lake during the 1959 eruption of Kīlauea Volcano (Island of Hawai’i). The magnetic field values recorded across the Kīlauea Iki crater floor and the cooling lava lake below result from three simple effects: the static remnant magnetization of the rocks forming the steep crater walls, the solidifying lava lake crust, and the hot, but shrinking, paramagnetic non-magnetic lens (>540 °C). We calculate 2D magnetic models to reconstruct the temporal evolution of the geometry of this non-magnetic body, its depth below the surface, and its thickness. Our results are in good agreement with the theoretical increase in thickness of the solidifying crust with time. Using the 2D magnetic models and the theoretical curve for crustal growth over a lava lake, we estimate that the former lava lake will be totally cooled below the Curie temperature in about 20 years. This study shows the potential of magnetic methods for detecting and monitoring magmatic intrusions at various scales.

Hawaii↗

Lateral edifice collapse and volcanic debris avalanches: A post-1980 Mount St. Helens perspective

The 1980 eruption of Mount St. Helens was instrumental in advancing understanding of how volcanoes work. Lateral edifice collapses and the generation of volcanic debris avalanches were not widely recognized prior to that eruption, making assessment of their hazards and risks challenging. The proliferation of studies since 1980 on resulting deposits and evaluation of processes leading to their generation has built on the insights from the 1980 eruption. Volcano-related destabilizing phenomena, such as strength reduction by hydrothermal alteration, deformation and structural modifications from shallow magma intrusion, and thermal pressurization of pore fluids supplement those factors also affecting nonvolcanic slopes and can lead to larger failures. Remote and ground-based monitoring techniques can aid in detecting potentially destabilizing dynamic processes and in forecasting the size and location of future large lateral collapses, although forecasting remains a topic of investigation. More than a thousand large lateral collapse events likely ≥ 0.01 km 3 in volume have now been identified from deposits or inferred from source area morphology, leading to a recognition of their importance in the evolution of volcanoes and the hazards they pose. Criteria for recognition of debris-avalanche deposits include morphological factors and textural characteristics from outcrop to microscopic scale, allowing discrimination from other volcaniclastic deposits. Lateral edifice failure impacts a broad spectrum of volcanic structures in diverse tectonic settings and can occur multiple times during the evolution of individual volcanoes. Globally, collapses ≥ 0.1 km 3 in volume have been documented 5–6 times per century since 1500 CE, with about one per century having a volume ≥ 1 km 3 . Smaller events < 0.1 km 3 are underrepresented in the earlier record but also have high hazard impact.

Wasgington↗

Deformation of Mauna Loa volcano before, during, and after its 2022 eruption

Mauna Loa on the Island of Hawaiʻi erupted on 27 November 2022, the first eruption since 1984, which marked the culmination of decades-long period of non-eruptive unrest and relative quiescence. We briefly describe the evolution of the USGS Hawaiian Volcano Observatory’s geodetic monitoring network at Mauna Loa and show patterns of deformation as measured by Global Navigation Satellite Systems (GNSS), interferometric synthetic aperture radar (InSAR), and borehole tilt. We highlight the long-term buildup and the imminent pre-eruptive geodetic signals, including subtle changes observed in early 2021 that suggested a potential eruption. We then describe the significant ramp up of activity in September 2022 that provided strong evidence of likely impending eruptive activity. Of particular importance are the first borehole tilt excursions related to magma movement measured at Mauna Loa’s summit, which began in 2021 and were accompanied by increased rates of seismicity. In addition to describing the evolution of surface displacements, we also model the co-eruption deformation, which can be fit by dike-like opening that matches the geometry of the surface eruptive fissures.

Hawaii↗

Topographic, climatic, and age controls on the reworking of volcanic debris avalanche deposits

Volcanic debris avalanches have deposited as much as 1000 km 3 of largely unconsolidated material on landscapes and remodeled existing drainage networks. The landscape disturbances created by these events pose severe, cascading downstream sedimentation hazards that can require long-term societal management, as demonstrated by decades of observations and ongoing interventions after the deposition of the 1980 debris avalanche of Mount St. Helens (United States). There, post-emplacement sediment yields caused by deposit erosion remain several times above estimated background yield and lakes impounded by the deposit still pose threats of downstream flooding. Despite the length and quality of measurements of the geomorphic evolution and consequent sediment release at Mount St. Helens, the long-term trajectory of drainage network evolution across, and the associated sediment release from, large volcanic debris avalanches remains uncertain. Observations and modeling at Mount St. Helens, however, indicate channel instability can persist many decades and may persist for centuries to millennia. We examined potential influences on the erosion and preservation of volcanic debris avalanche deposits (VDADs) by mapping valley networks developed on 89 VDADs selected from volcanic arcs across the world and spanning a variety of topographic settings and climate regimes. Using the best available topographic data (1 m lidar to 30 m radar-derived data depending on location) and aerial imagery, we estimated the areas of deposits that have been reworked relative to initial deposit footprints as a proxy for post-emplacement erosion. We found that a primary influence on reworking is the topographic confinement of the VDAD: confined, valley-filling deposits are systematically more reworked than unconfined deposits. There is no apparent relationship between deposit age and reworking for valley-filling deposits, indicating that drainage networks on deposits in confined topographic settings like at Mount St. Helens reform rapidly after emplacement. In contrast, our data indicate that the reworking of unconfined deposits has a monotonic positive relationship with age. This observation agrees with a conceptual model of channel formation at Mount Taranaki (New Zealand), which posits that an unconfined VDAD created a topographic high that initially (e.g., 2–8 ky for the Pungarehu formation at Taranaki) diverted erosion to the deposit margins. We found only a weak to moderate relationship between reworking and modern precipitation regimes, which may reflect differences between modern and paleo-precipitation conditions at many of our study sites. We also found no correlation between the size (surface area or volume) of deposits and the degree of reworking. The work presented here implies that downstream cascading sediment hazards from landscape-resetting processes like VDADs (such as thick, extensive pyroclastic flow deposits) depend on the relief and organization of the surrounding landscape.

Washington↗

Lava flow emplacement dynamics during the Mauna Loa 2022 eruption

On November 27, 2022, Mauna Loa erupted for the first time in 38 years, threatening a major highway on the Island of Hawaiʻi. The opening phases of the eruption were focused at the volcano’s summit, before magma propagated into the upper Northeast Rift Zone to erupt at four fissure segments that localized at fissure 3 by December 2. This fissure produced a braided ʻaʻā flow that traversed the steep north flank at >1 km/hr, before slowing as slopes shallowed. Effusion rates peaked in the early hours of the eruption and then steadied at around 100 m3/s at fissure 3. Lava effusion became variable and dropped abruptly on December 7. The eruption ended on December 10 with a final flow length of 18 km. We tracked lava effusion rates, flow advance, channel dynamics, and 3-D flow field development with field and remote sensing observations throughout this eruption to inform lava flow forecasts and investigate ʻaʻā flow dynamics. Flows were mapped using optical and infrared imagery, uncrewed aircraft systems, and airborne single-pass InSAR. Video- and time-lapse cameras were deployed to record lava fountaining and channelized flow at frequent intervals, supplemented by field measurements. Analyses of these data built a detailed record of effusion rates and associated flow dynamics. We combine these high frequency observations of the proximal flow field with broader thermal and 3-D mapping of the evolution in the medial and distal flow field to examine ʻaʻā flow dynamics from source to toe. Within the steep, medial section of the flow field, channel blockages caused back-ups and overflows as the eruption progressed. Disrupted lava supply to the distal flow field and low slopes resulted in stalling, widening, and thickening at the toe. Overall, 142 million m3 of lava covered 36 km2 over 13 days. Our results inform the controls on development and evolution of lava flow fields, with implications for forecasting primary flow advance and secondary flow field growth.

Hawaii↗

The future of hydrogeology

“The Future of Hydrogeology” would seem to be an overly ambitious topic for a theme issue of Hydrogeology Journal or for any other journal. Only a modicum of common sense and experience provides the insight that predicting the future of a science is a task fraught with uncertainty that should be approached with caution and humility. Please be assured that the intent of this issue of the journal is not to predict the future but rather to instigate discussion and to inspire creative thinking about hydrogeology. In their articles, authors have presented personal opinions concerning the future evolution of their subjects based on their experience. This is an acceptable approach, considering that any view of the future can be no more than an educated guess. Most authors have given their opinion after an expert and insightful review of the evolution of their subject to the present time or after reviewing the current state of knowledge or practice of their subject. Consequently, this issue of the Hydrogeology Journal provides an exciting view of potential developments in crucial aspects of hydrogeology founded upon developments to date.

Hydrogeology Journal↗

Isotope geochemistry of recent magmatism in the Aegean arc: Sr, Nd, Hf, and O isotopic ratios in the lavas of Milos and Santorini-geodynamic implications

In this comparative study of variations in the isotopic compositions (Sr, Nd, O and Hf) of the calc-alkaline magmas of the largest two volcanoes, Milos and Santorini, of the Aegean arc (eastern Mediterranean) we demonstrate the complexity of the processes governing the evolution of the magmas on the scale both of the arc and of each volcano. On Santorini, the crustal contamination processes have been limited, effecting the magma gradually during its differentiation. The most differentiated lavas (rhyodacite and pumice) are also the most contaminated. On Milos, by contrast, these processes are very extensive. They are expressed in the 143 Nd/ 144 Nd vs. 87 Sr/ 86 Sr diagram as a continuous mixing curve between a mantle and a crustal end member pole defined by schists and metavolcanic rocks outcropping on these volcanoes. In contrast with Santorini, the least differentiated lavas on Milos are the most contaminated. These isotopic singularities can be correlated with the geodynamic evolution of the Aegean subduction zone, consisting of alternating tectonic phases of distension and compression. The genesis of rhyolitic magmas can be linked to the two phases of distension, and the contamination of the calc-alkaline mantle-derived magmas with the intermediate compressive phase. The isotopic characteristics of uncontaminated calc-alkaline primitive magmas of Milos and Santorini are directly comparable to those of magmas generated in subduction zones for which a contribution of subducted sediments to partial melts from the mantle is suggested, such as in the Aleutian, Sunda, and lesser Antilles island arcs. However, in spite of the importance of the sediment pile in the eastern Mediterranen oceanic crust (6–10 km), the contribution of the subducted terrigenous materials remains of limited amplitude.

Earth and Planetary Science Letters↗

The initial instability and finite-amplitude stability of alternate bars in straight channels

The initial instability and fully developed stability of alternate bars in straight channels are investigated using linearized and nonlinear analyses. The fundamental instability leading to these features is identified through a linear stability analysis of the equations governing the flow and sediment transport fields. This instability is explained in terms of topographically induced steering of the flow and the associated pattern of erosion and deposition on the bed. While the linear theory is useful for examining the instability mechanism, this approach is shown to yield relatively little information about well-developed alternate bars and, specifically, the linear analysis is shown to yield poor predictions of the fully developed bar wavelength. A fully nonlinear approach is presented that permits computation of the evolution of these bed features from an initial perturbation to their fully developed morphology. This analysis indicates that there is typically substantial elongation of the bar wavelength during the evolution process, a result that is consistent with observations of bar development in flumes and natural channels. The nonlinear approach demonstrates that the eventual stability of these features is a result of the interplay between topographic steering effects, secondary flow production as a result of streamline curvature, and gravitationally induced modifications of sediment fluxes over a sloping bed.

Earth-Science Reviews↗

Sulphur in char and char desulphurization by acid leaching and hydropyrolysis

Sulphur compounds volatilized during pyrolysis of acid-leached char were measured to determine characteristics of char desulphurization reactions. Pyrolysis of char in a hydrogen atmosphere (hydropyrolysis) produced a much higher concentration of thiophenic organics compared with that produced during pyrolysis in a nitrogen atmosphere. Hydrogen sulphide gas evolution, at progressively increasing pyrolysis temperature in a helium atmosphere, was measured on five char samples: untreated char, hydrochloric acid-leached char, and three model chars: a demineralized char and two demineralized chars incorporated with sulphur via reactions with elemental sulphur. Hydrogen sulphide gas evolution in untreated char and acid-leached char was found to peak in three temperature regions; the maxima are thought to relate to sulphur in different bonding environments. The amounts of hydrogen sulphide volatilized were much higher for acid-leached char than for untreated char. The gas evolved from each of the remaining three samples showed a single peak region corresponding closely to one of the three peak regions observed for the first two chars. The results of this study indicate that elemental sulphur was produced during hydrochloric acid leaching of the untreated char and suggested that the improved rate of desulphurization observed in the char that had been acid-leached before hydropyrolysis was due in part to the conversion of strongly bound mineral sulphur forms to more weakly bound sulphur forms that are predominantly elemental sulphur in character, and are more easily removed by hydrogen.

Fuel↗