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Methods of analysis—Determination of pesticides in filtered water and suspended sediment using liquid chromatography- and gas chromatography-tandem mass spectrometry

The widespread application of pesticides in agricultural and urban areas leads to their presence in surface waters. Presence of these biologically active chemicals in environmental waters potentially has adverse effects on nontarget organisms. To better understand the environmental fate of these contaminants, a robust method to capture chemicals with wide-ranging physicochemical properties has been developed. The method was developed by the U.S. Geological Survey’s Organic Chemistry Research Laboratory to monitor pesticides, pesticide degradates, and other agrochemicals in environmental surface waters throughout the country. The analysis involves a multiresidue method to determine 183 pesticides and pesticide degradates in filtered water samples and 178 pesticides and pesticide degradates in paired suspended sediment samples. After the filtration of whole water, contaminants are individually measured in the filtered water and the collected suspended sediment. Filtered water is extracted via solid-phase extraction, whereas suspended sediment is extracted using an ultrasonication, solid-liquid extraction. Samples are analyzed by liquid chromatography-tandem mass spectrometry using an electrospray ionization source in positive and negative modes and analyzed by gas chromatography-tandem mass spectrometry using an advanced electron ionization source in positive mode. Instrument parameters were optimized for the highest sensitivity, and at least two transitions (quantifier and qualifier) were monitored for each analyte. Recoveries in test filtered water ( n =9; 183 analytes) from the American River, California, and suspended sediment ( n =9; 178 analytes) samples fortified at 15 nanograms per liter (ng/L) ranged from 70.1 to 121.0 and 71.1 to 117.0 percent in water and suspended sediment filter samples, respectively. Method detection limits of pesticides and pesticide degradates ranged from 0.5 to 10.6 ng/L in water and 0.7 to 11.8 ng/L in suspended sediment filters. Reporting limits were 1.1–21.1 ng/L and 1.5–23.7 ng/L in water and filter samples, respectively. The developed method is applied to surface-water samples for the analysis of pesticides, pesticide degradates, and other agrochemicals.

Techniques and Methods↗

Optical properties of pseudovitrinite; implications for its origin

A set of Pennsylvanian coals from the North American coal basins, ranging in vitrinite reflectance from 0.65% to 1.75%, was examined, with special emphasis on the optical properties of pseudovitrinite. The results suggest that pseudovitrinite originates from the same material as telocollinite. Slits in the pseudovitrinite seem to have originated in situ due to low-temperature oxidation of woody material; their opening might have been facilitated by devolatilization during coalification. The dominant orientation of the slits is perpendicular to bedding. The intensity and orientation of the slits in pseudovitrinite could be important factors in predicting coalbed gas extraction from coal. ?? 2005 Elsevier B.V. All rights reserved.

International Journal of Coal Geology↗

The road to NHDPlus — Advancements in digital stream networks and associated catchments

A progression of advancements in Geographic Information Systems techniques for hydrologic network and associated catchment delineation has led to the production of the National Hydrography Dataset Plus (NHDPlus). NHDPlus is a digital stream network for hydrologic modeling with catchments and a suite of related geospatial data. Digital stream networks with associated catchments provide a geospatial framework for linking and integrating water-related data. Advancements in the development of NHDPlus are expected to continue to improve the capabilities of this national geospatial hydrologic framework. NHDPlus is built upon the medium-resolution NHD and, like NHD, was developed by the U.S. Environmental Protection Agency and U.S. Geological Survey to support the estimation of streamflow and stream velocity used in fate-and-transport modeling. Catchments included with NHDPlus were created by integrating vector information from the NHD and from the Watershed Boundary Dataset with the gridded land surface elevation as represented by the National Elevation Dataset. NHDPlus is an actively used and continually improved dataset. Users recognize the importance of a reliable stream network and associated catchments. The NHDPlus spatial features and associated data tables will continue to be improved to support regional water quality and streamflow models and other user-defined applications.

Journal of the American Water Resources Associatio↗

Surface-water nutrient conditions and sources in the United States Pacific Northwest

The SPAtially Referenced Regressions On Watershed attributes (SPARROW) model was used to perform an assessment of surface-water nutrient conditions and to identify important nutrient sources in watersheds of the Pacific Northwest region of the United States (U.S.) for the year 2002. Our models included variables representing nutrient sources as well as landscape characteristics that affect nutrient delivery to streams. Annual nutrient yields were higher in watersheds on the wetter, west side of the Cascade Range compared to watersheds on the drier, east side. High nutrient enrichment (relative to the U.S. Environmental Protection Agency's recommended nutrient criteria) was estimated in watersheds throughout the region. Forest land was generally the largest source of total nitrogen stream load and geologic material was generally the largest source of total phosphorus stream load generated within the 12,039 modeled watersheds. These results reflected the prevalence of these two natural sources and the low input from other nutrient sources across the region. However, the combined input from agriculture, point sources, and developed land, rather than natural nutrient sources, was responsible for most of the nutrient load discharged from many of the largest watersheds. Our results provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to environmental managers in future water-quality planning efforts.

Journal of the American Water Resources Associatio↗

Chlorinated solvents in groundwater of the United States

Four chlorinated solvents-methylene chloride, perchloroethene (PCE), 1,1,1-trichloroethane, and trichloroethene (TCE)-were analyzed in samples of groundwater taken throughout the conterminous United States by the U.S. Geological Survey. The samples were collected between 1985 and 2002 from more than 5,000 wells. Of 55 volatile organic compounds (VOCs) analyzed in groundwater samples, solvents were among the most frequently detected. Mixtures of solvents in groundwater were common and may be the result of common usage of solvents or degradation of one solvent to another. Relative to other VOCs with Maximum Contaminant Levels (MCLs), PCE and TCE ranked high in terms of the frequencies of concentrations greater than or near MCLs. The probability of occurrence of solvents in groundwater was associated with dissolved oxygen content of groundwater, sources such as urban land use and population density, and hydraulic properties of the aquifer. The results reinforce the importance of understanding the redox conditions of aquifers and the hydraulic properties of the saturated and vadose zones in determining the intrinsic susceptibility of groundwater to contamination by solvents. The results also reinforce the importance of controlling sources of solvents to groundwater. ?? 2007 American Chemical Society.

Environmental Science & Technology↗

Bathymetric map, surface area, and capacity of Grand Lake O’ the Cherokees, northeastern Oklahoma, 2019

The U.S. Geological Survey (USGS), in cooperation with the Grand River Dam Authority, completed a high-resolution multibeam bathymetric survey to compute a new area and capacity table for Grand Lake O’ the Cherokees in northeastern Oklahoma. Area and capacity tables identify the relation between the elevation of the water surface and the volume of water that can be impounded at each water-surface elevation. The area and capacity of Grand Lake O’ the Cherokees were computed from a triangular irregular network surface created in Global Mapper Version 21.0.1. The triangular irregular network surface was created from three datasets: (1) a multibeam mapping system bathymetric survey of Grand Lake O’ the Cherokees completed during April–July 2019, (2) a previous bathymetric survey of the Neosho, Spring, and Elk Rivers, and (3) a 2010 USGS lidar-derived digital elevation model. The digital elevation model data were used in areas with land-surface elevations greater than 744 feet above the North American Vertical Datum of 1988 where the multibeam sonar data could not be collected. The 2019 multibeam sonar data were the predominant data used to compute the new area and capacity table for Grand Lake O’ the Cherokees.

Oklahoma↗

IASPEI workshop: Seismic modeling of laterally varying structures

During the past 10 years, significant progress has been made in the methods of collection and analysis of seismic reflection and refraction data. This progress has led to the development of new models for the structure and composition of the earth's crust, based on sophisticated analysis of numerous profiles in many areas of geologic importance. The third triannual meeting of the IASPEI (International Association of Seismology and Physics of the Earth's Interior) Commission of Controlled Source Seismology was convened in Park City, Utah, on August 11–17, 1980, to bring together seismologists and geologists to explore and assess the progress of controlled source techniques (controlled sources include explosions, air guns, and Vibroseis‐type sources), and to evaluate its significance in terms of current models of the seismic velocity structure and composition of the crust and upper mantle. Particular attention was paid to the progress and problems in the modeling of two‐ and three‐dimensional structures.

Eos, Transactions, American Geophysical Union↗

Application of a multipurpose unequal probability stream survey in the Mid-Atlantic Coastal Plain

A stratified, spatially balanced sample with unequal probability selection was used to design a multipurpose survey of headwater streams in the Mid-Atlantic Coastal Plain. Objectives for the survey include unbiased estimates of regional stream conditions, and adequate coverage of unusual but significant environmental settings to support empirical modeling of the factors affecting those conditions. The design and field application of the survey are discussed in light of these multiple objectives. A probability (random) sample of 175 first-order nontidal streams was selected for synoptic sampling of water chemistry and benthic and riparian ecology during late winter and spring 2000. Twenty-five streams were selected within each of seven hydrogeologic subregions (strata) that were delineated on the basis of physiography and surficial geology. In each subregion, unequal inclusion probabilities were used to provide an approximately even distribution of streams along a gradient of forested to developed (agricultural or urban) land in the contributing watershed. Alternate streams were also selected. Alternates were included in groups of five in each subregion when field reconnaissance demonstrated that primary streams were inaccessible or otherwise unusable. Despite the rejection and replacement of a considerable number of primary streams during reconnaissance (up to 40 percent in one subregion), the desired land use distribution was maintained within each hydrogeologic subregion without sacrificing the probabilistic design.

Journal of the American Water Resources Associatio↗

Evaluation of three electronic report processing systems for preparing hydrologic reports of the U.S Geological Survey, Water Resources Division

In 1987, the Water Resources Division of the U.S. Geological Survey undertook three pilot projects to evaluate electronic report processing systems as a means to improve the quality and timeliness of reports pertaining to water resources investigations. The three projects selected for study included the use of the following configuration of software and hardware: Ventura Publisher software on an IBM model AT personal computer, PageMaker software on a Macintosh computer, and FrameMaker software on a Sun Microsystems workstation. The following assessment criteria were to be addressed in the pilot studies: The combined use of text, tables, and graphics; analysis of time; ease of learning; compatibility with the existing minicomputer system; and technical limitations. It was considered essential that the camera-ready copy produced be in a format suitable for publication. Visual improvement alone was not a consideration. This report consolidates and summarizes the findings of the electronic report processing pilot projects. Text and table files originating on the existing minicomputer system were successfully transformed to the electronic report processing systems in American Standard Code for Information Interchange (ASCII) format. Graphics prepared using a proprietary graphics software package were transferred to all the electronic report processing software through the use of Computer Graphic Metafiles. Graphics from other sources were entered into the systems by scanning paper images. Comparative analysis of time needed to process text and tables by the electronic report processing systems and by conventional methods indicated that, although more time is invested in creating the original page composition for an electronically processed report , substantial time is saved in producing subsequent reports because the format can be stored and re-used by electronic means as a template. Because of the more compact page layouts, costs of printing the reports were 15% to 25% less than costs of printing the reports prepared by conventional methods. Because the largest report workload in the offices conducting water resources investigations is preparation of Water-Resources Investigations Reports, Open-File Reports, and annual State Data Reports, the pilot studies only involved these projects. (USGS)

Open-File Report↗

Water-level altitudes 2017 and water-level changes in the Chicot, Evangeline, and Jasper Aquifers and compaction 1973–2016 in the Chicot and Evangeline Aquifers, Houston-Galveston region, Texas

Most of the land-surface subsidence in the Houston-Galveston region, Texas, has occurred as a direct result of groundwater withdrawals for municipal supply, commercial and industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers, thereby causing compaction of the aquifer sediments, mostly in the fine-grained silt and clay layers. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and measured cumulative compaction of subsurface sediments in the Chicot and Evangeline aquifers in the Houston-Galveston region. This report contains regional-scale maps depicting approximate 2017 water-level altitudes (represented by measurements made during December 2016 through March 2017) and long-term water-level changes for the Chicot, Evangeline, and Jasper aquifers; a map depicting locations of borehole-extensometer (hereinafter referred to as “extensometer”) sites; and graphs depicting measured long-term cumulative compaction of subsurface sediments at the extensometers during 1973–2016. In 2017, water-level-altitude contours for the Chicot aquifer ranged from 200 feet (ft) below the North American Vertical Datum of 1988 (hereinafter referred to as “datum”) in two localized areas in southwestern and northwestern Harris County to 200 ft above datum in west-central Montgomery County. The largest water-level-altitude decline (120 ft) depicted by the 1977–2017 water-level-change contours for the Chicot aquifer was in northwestern Harris County. A broad area where water-level altitudes declined in the Chicot aquifer extends from northwestern, north-central, and southwestern Harris County across parts of north-central, eastern, and south-central Fort Bend County into southeastern Waller County. Adjacent to the areas where water levels declined was a broad area where water levels rose in central, eastern, and southeastern Harris County, most of Galveston County, eastern and northernmost Brazoria County, and northeastern Fort Bend County. The largest rise (200 ft) in water-level altitudes in the Chicot aquifer from 1977 to 2017 was in southeastern Harris County. The water-level-altitude contours for the Evangeline aquifer in 2017 indicated two areas where the water-level altitudes were 250 ft below datum—one area extending from south-central Montgomery County into north-central Harris County and another area in western Harris County. Water-level altitudes in the Evangeline aquifer ranged from 50 to 200 ft below datum throughout most of Harris County in 2017. In Montgomery County, water-level altitudes in the Evangeline aquifer in 2017 ranged from the aforementioned area where they were 250 ft below datum to an area where they were 200 ft above datum in the northwestern part of the county. The 1977–2017 water-level-change contours for the Evangeline aquifer depict a broad area where water-level altitudes declined in north-central Harris and south-central Montgomery Counties, extending through north-central, northwestern, and southwestern Harris County into western Liberty, southeastern and northeastern Waller, and northeastern and east-central Fort Bend Counties. The largest water-level-altitude decline (280 ft) was in north-central Harris and south-central Montgomery Counties. Water-level altitudes rose in a broad area from central, east-central, and southern Harris County extending into the northernmost part of Brazoria County, the northernmost part of Galveston County, and the southwestern area of Liberty County. The largest rise in water-level altitudes in the Evangeline aquifer from 1977 to 2017 (240 ft) was in southeastern Harris County. Water-level-altitude contours for the Jasper aquifer in 2017 ranged from 200 ft below datum in three isolated areas of south-central Montgomery County (the westernmost of these areas extended slightly into north-central Harris County) to 250 ft above datum in extreme northwestern Montgomery County, northeastern Grimes County, and southwestern Walker County. The 2000–17 water-level-change contours for the Jasper aquifer depict water-level declines in a broad area throughout most of Montgomery County and in parts of Waller, Grimes, and Harris Counties, with the largest decline (220 ft) in an isolated area in south-central Montgomery County. Compaction of subsurface sediments (mostly in the fine-grained silt and clay layers) in the Chicot and Evangeline aquifers was recorded continuously by using 13 extensometers at 11 sites that were either activated or installed between 1973 and 1980. During the period of record beginning in 1973 (or later depending on activation or installation date) and ending in late November or December 2016, measured cumulative compaction at the 13 extensometers ranged from 0.096 ft at the Texas City-Moses Lake extensometer to 3.700 ft at the Addicks extensometer. From January through late November or December 2016, the Addicks, Lake Houston, Southwest, and Northeast extensometers recorded net decreases in land-surface elevation, but the Baytown C–1 (shallow), Baytown C–2 (deep), Clear Lake (shallow), Clear Lake (deep), East End, Johnson Space Center, Pasadena, Seabrook, and Texas City-Moses Lake extensometers recorded net increases in land-surface elevation. The rate of compaction varies from site to site because of differences in rates of groundwater withdrawal in the areas adjacent to each extensometer site; differences among sites in the ratios of sand, silt, and clay and their corresponding compressibilities; and previously established preconsolidation heads. It is not appropriate, therefore, to extrapolate or infer a rate of compaction for an adjacent area on the basis of the rate of compaction recorded by proximal extensometers.

Texas↗

The periodic structure of the natural record, and nonlinear dynamics

Concepts of cyclicity in geology have involved many famous protagonists in the history of Earth sciences. Early in this century, sophisticated theories of terrestrial rhythms had been formulated by such pioneers as T. C. Chamberlin [1909], R. T. , Chamberlin [1914], Barrell [1917], Stille [1924], Joly [1925, 1930], Holmes [1926], Lull [1929], Schuchert [1932], Grabau [1940], and Umbgrove [1939 a,b, 1947] (see the review by Williams [1981]). The physical chemist S. Arrhenius [1908] had also formulated a general hypothesis for cosmological origins of terrestrial phenomena. Khain [1964] later proposed resonances between terrestrial and cosmological rhythms, and McCrea [1975] and Williams [1975] summarized evidence of galactic correlations with glaciation.

Eos, Transactions, American Geophysical Union↗

The Finley Site: Antiquity of the Finley Site

This report is based on two months reconnaissance in the summer of 1941 in the Eden Valley, Wyoming. The work is as yet far from complete and the conclusions presented here must be regarded as tentative. It is hoped that in the future more extensive geological work may be undertaken. The Finley site provides a promising opportunity for a determination of the age of the Yuma culture. The points and bones described by Dr. Howard occur in a culture layer which has been found in a large dune area, here called the Killpecker dunes. The deposition of the culture layer is one of a series of events in the dune area which can be correlated with the cutting and filling of gravel terraces in the Eden Valley to the west, and these in turn may be related to the glacial chronology in the Wind River Mountains which lie to the north.

Wyoming↗

Temporal patterns of apparent leg band retention in North American geese

An important assumption of mark?recapture studies is that individuals retain their marks, which has not been assessed for goose reward bands. We estimated aluminum leg band retention probabilities and modeled how band retention varied with band type (standard vs. reward band), band age (1-40 months), and goose characteristics (species and size class) for Canada (Branta canadensis), cackling (Branta hutchinsii), snow (Chen caerulescens), and Ross?s (Chen rossii) geese that field coordinators double-leg banded during a North American goose reward band study (N = 40,999 individuals from 15 populations). We conditioned all models in this analysis on geese that were encountered with >1 leg band still attached (n = 5,747 dead recoveries and live recaptures). Retention probabilities for standard aluminum leg bands were high (estimate of 0.9995, SE = 0.001) and constant over 1-40 months. In contrast, apparent retention probabilities for reward bands demonstrated an interactive relationship between 5 size and species classes (small cackling, medium Canada, large Canada, snow, and Ross?s geese). In addition, apparent retention probabilities for each of the 5 classes varied quadratically with time, being lower immediately after banding and at older age classes. The differential retention probabilities among band type (reward vs. standard) that we observed suggests that 1) models estimating reporting probability should incorporate differential band loss if it is nontrivial, 2) goose managers should consider the costs and benefits of double-banding geese on an operational basis, and 3) the United States Geological Survey Bird Banding Lab should modify protocols for receiving recovery data.

Journal of Wildlife Management↗

Hydrogeology of Webb County, Texas

Introduction Webb County, in semiarid South Texas on the U.S.-Mexico border, is a region confronted by increasing stresses on natural resources. Laredo (fig. 1), the largest city in Webb County (population 193,000 in 2000), was one of the 10 fastest-growing metropolitan areas in the country during 1990-2000 (Perry and Mackun, 2001). Commercial and industrial activities have expanded throughout the region to support the maquiladora industry (manufacturing plants in Mexico) along the border and other growth as a result of the passage of the North American Free Trade Agreement. The Rio Grande currently (2002) is the primary source of public water supply for Laredo and other cities along the border in Webb County (fig. 1). Other cities, such as Bruni and Mirando City in the southeastern part of the county, rely on ground-water supplies to meet municipal demands. Increased water demand associated with development and population growth in the region has increased the need for the City of Laredo and Webb County to evaluate alternative water sources to meet future demand. Possible options include (1) supplementing the surface-water supply with ground water, and (2) applying artificial storage and recovery (ASR) technology to recharge local aquifers. These options raise issues regarding the hydraulic capability of the aquifers to store economically substantial quantities of water, current or potential uses of the resource, and possible effects on the quality of water resulting from mixing ground water with alternative source waters. To address some of these issues, the U.S. Geological Survey (USGS), in cooperation with the City of Laredo, began a study in 1996 to assess the ground-water resources of Webb County. A hydrogeologic study was conducted to review and analyze available information on the hydrogeologic units (aquifers and confining units) in Webb County, to locate available wells in the region with water-level and water-quality information from the aquifers, and to analyze the hydraulic properties of the aquifers. The purpose of this report is to document the findings of the study. The information is organized by hydrogeologic unit and presented on this and six other sheets.

Texas↗

Validation of the ASTER instrument level 1A scene geometry

An independent assessment of the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) instrument geometry was undertaken by the U.S. ASTER Team, to confirm the geometric correction parameters developed and applied to Level 1A (radiometrically and geometrically raw with correction parameters appended) ASTER data. The goal was to evaluate the geometric quality of the ASTER system and the stability of the Terra spacecraft. ASTER is a 15-band system containing optical instruments with resolutions from 15- to 90-meters; all geometrically registered products are ultimately tied to the 15-meter Visible and Near Infrared (VNIR) sub-system. Our evaluation process first involved establishing a large database of Ground Control Points (GCP) in the mid-western United States; an area with features of an appropriate size for spacecraft instrument resolutions. We used standard U.S. Geological Survey (USGS) Digital Orthophoto Quads (DOQS) of areas in the mid-west to locate accurate GCPs by systematically identifying road intersections and recording their coordinates. Elevations for these points were derived from USGS Digital Elevation Models (DEMS). Road intersections in a swath of nine contiguous ASTER scenes were then matched to the GCPs, including terrain correction. We found no significant distortion in the images; after a simple image offset to absolute position, the RMS residual of about 200 points per scene was less than one-half a VNIR pixel. Absolute locations were within 80 meters, with a slow drift of about 10 meters over the entire 530-kilometer swath. Using strictly simultaneous observations of scenes 370 kilometers apart, we determined a stereo angle correction of 0.00134 degree with an accuracy of one microradian. The mid-west GCP field and the techniques used here should be widely applicable in assessing other spacecraft instruments having resolutions from 5 to 50-meters. ?? 2008 American Society for Photogrammetry and Remote Sensing.

Photogrammetric Engineering and Remote Sensing↗

Inventory of montane-nesting birds in Katmai and Lake Clark national parks and preserves

As part of the National Park Service’s Inventory and Monitoring Program, biologists from the U. S. Geological Survey’s Alaska Science Center conducted an inventory of birds in montane regions of Katmai and Lake Clark National Parks and Preserves during 2004–2006. We used a stratified random survey design to allocate samples by ecological subsection. To survey for birds, we conducted counts at 468 points across 29, 10-km x 10-km (6.2-mi x 6.2-mi) sample plots in Katmai and 417 points across 25, 10-km x 10-km sample plots in Lake Clark. We detected 92 and 104 species in Katmai and Lake Clark, respectively, including 40 species of conservation concern. We detected three species not previously recorded in Katmai (Ring-necked Duck [ Aythya collaris ], Lesser Scaup [ Aythya affinis ], and White-tailed Ptarmigan [ Lagopus leucurus ]) and two species not previously recorded in Lake Clark (Northern Flicker [ Colaptes auratus ] and Olive-sided Flycatcher [ Contopus cooperi ]). The most commonly detected species in both parks was Golden-crowned Sparrow ( Zonotrichia atricapilla ); Fox Sparrow ( Passerella iliaca ) and American Pipit ( Anthus rubescens ) were abundant and widely-distributed as well. We defined sites as low (100–350 m), middle (351–600 m), or high (601–1,620 m) elevation based on the distribution of vegetation cover, and similarly categorized the 34 most-commonly detected species based on the mean elevation of sample points at which they were detected. High elevation (i.e., alpine) sites were characterized by high percent cover of dwarf shrub and bare ground habitat and supported species like Rock Ptarmigan ( L. mutus ), American Golden-Plover ( Pluvialis dominica ), Wandering Tattler ( Tringa incana ), Surfbird ( Aphriza virgata ), and Snow Bunting ( Plectrophenax nivalis ), all species of conservation concern. This inventory represents the first systematic survey of birds nesting in montane regions of both parks. Results from this inventory can form the foundation of subsequent monitoring efforts

Alaska↗

Lithotectonic assemblages as portrayed on the new bedrock geologic map of Massachusetts.

Scale of 1:250,000. The map units are grouped into eight lithotectonic packages. Five "zones" of older rocks that cover the whole state are, from west to east, the Taconic-Berkshire, Rowe-Hawley, Bronson Hill, Nashoba, and Milford-Dedham. In central and western Massachusetts, these zones are overlain by the Connecticut Valley and Merrimack "belts" of Silurian-Devonian, and local Carboniferous, strata; the two belts are distinguished from each other on the basis of the lithofacies of the Silurian strata. In eastern Massachusetts, the Milford-Dedham Zone also includes Silurian-Devonian, Carboniferous, Mesozoic, and Tertiary strata. A Mesozoic "basin" is separately identified in the Connecticut Valley region

Massachusetts↗

The Penobscot River and environmental contaminants: Assessment of tribal exposure through sustenance lifeways

EPA in collaboration with the Penobscot Indian Nation, U.S. Geological Survey (USGS), Agency for Toxic Substances and Disease Registry (ATSDR), and the U.S. Fish and Wildlife Service (USF&WS) collectively embarked on a four year research study to evaluate the environmental health of the riverine system by targeting specific cultural practices and using traditional science to conduct a preliminary contaminant screening of the flora and fauna of the Penobscot River ecosystem. This study was designed as a preliminary screening to determine if contaminant concentrations in fish, eel, snapping turtle, wood ducks, and plants in Regions of the Penobscot River relevant to where PIN tribal members hunt, fish and gather plants were high enough to be a health concern. This study was not designed to be a statistically validated assessment of contaminant differences among study sites or among species. The traditional methodology for health risk assessment used by the U. S. Environmental Protection Agency (EPA) is based on the use of exposure assumptions (e.g. exposure duration, food ingestion rate, body weight, etc.) that represent the entire American population, either as a central tendency exposure (e.g. average, median) or as a reasonable maximum exposure (e.g. 95% upper confidence limit). Unfortunately, EPA lacked exposure information for assessing health risks for New England regional tribes sustaining a tribal subsistence way of life. As a riverine tribe, the Penobscot culture and traditions are inextricably tied to the Penobscot River watershed. It is through hunting, fishing, trapping, gathering and making baskets, pottery, moccasins, birch-bark canoes and other traditional practices that the Penobscot culture and people are sustained. The Penobscot River receives a variety of pollutant discharges leaving the Penobscot Indian Nation (PIN) questioning the ecological health and water quality of the river and how this may affect the practices that sustain their way of life. The objectives of this Regional Applied Research Effort (RARE) study were to: Develop culturally sensitive methodologies for assessing the potential level of exposure tocontaminants that Penobscot Indian Nation tribal members may have from maintainingtribal sustenance practices. Conduct field surveys and laboratory analysis on targeted flora and fauna for chemicalexposure to dioxins/furans, polychlorinated biphenyls (PCBs), total mercury and methyl-mercury. Assist the Agency for Toxic Substances and Disease Registry (ATSDR) by providing thenecessary data to conduct a Public Health Assessment for the Penobscot Indian Nation. Establish protocols for assessing the level of exposure to PCBs, dioxins/furans and mercuryto PIN tribal members as a consequence of gathering tribal plants for medicinal andnutritional purposes; as well as consuming fish, wood duck, and snapping turtle as a primarysource of nutrition. Survey surface water, drinking water, and sediment from the Penobscot River and IndianIsland to assess the exposure of PIN tribal members to environmental genotoxicants thatcontinue cultural sustenance practices. This research initiative collected and analyzed sediment and biota to determine the level of contaminant exposure to Penobscot tribal members. Natural resource utilization patterns and exposure pathways were identified based on discussions with the Tribal elders. Identification of Tribal exposure factors (exposure pathways and contaminant concentrations) was essential for accurately assessing potential long-term Penobscot Indian Nation tribal members’ exposure. Based on this study, ATSDR’s Public Health Assessment (PHA) concluded that the Penobscot Indian Nation (PIN) tribal members who eat fish and snapping turtle at the ingestion levels suggested in the Wabanaki Traditional Cultural Lifeways Exposure Scenario Report (Wabanaki Exposure Scenario) may be exposed to harmful levels of mercury, dioxins/furans, dioxin-like PCBs, and ot

Maine↗