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Manganese

Manganese is an essential element for modern industrial societies. Its principal use is in steelmaking, where it serves as a purifying agent in iron-ore refining and as an alloy that converts iron into steel. Although the amount of manganese consumed to make a ton of steel is small, ranging from 6 to 9 kilograms, it is an irreplaceable component in the production of this fundamental material. The United States has been totally reliant on imports of manganese for many decades and will continue to be so for at least the near future. There are no domestic reserves, and although some large low-grade resources are known, they are far inferior to manganese ores readily available on the international market. World reserves of manganese are about 630 million metric tons, and annual global consumption is about 16 million metric tons. Current reserves are adequate to meet global demand for several decades. Global resources in traditional land-based deposits, including both reserves and rocks sufficiently enriched in manganese to be ores in the future, are much larger, at about 17 billion metric tons. Manganese resources in seabed deposits of ferromanganese nodules and crusts are larger than those on land and have not been fully quantified. No production from seabed deposits has yet been done, but current research and development activities are substantial and may bring parts of these seabed resources into production in the future. The advent of economically successful seabed mining could substantially alter the current scenario of manganese supply by providing a large new source of manganese in addition to traditional land-based deposits. From a purely geologic perspective, there is no global shortage of proven ores and potential new ores that could be developed from the vast tonnage of identified resources. Reserves and resources are very unevenly distributed, however. The Kalahari manganese district in South Africa contains 70 percent of the world’s identified resources and about 25 percent of its reserves. South Africa, Brazil, and Ukraine together accounted for nearly 65 percent of reserves in 2013. The combination of total import reliance for manganese, the mineral commodity’s essential uses in our industrialized society, and the potential for supply disruptions because of the limited sources of the ore makes manganese among the most critical minerals for the United States. Manganese is the 12th most abundant element in Earth’s crust. Its concentration varies among common types of rocks, mostly in the range of from 0.1 to 0.2 percent. The highest quality manganese ores contain from 40 to 45 percent manganese. The formation of these ores requires specialized geologic conditions that concentrate manganese at several hundred times its average crustal abundance. The dominant processes in forming the world’s principal deposits take place in the oceans. As a result, most important manganese deposits occur in ancient marine sedimentary rocks that are now exposed on continents as a result of subsequent tectonic uplift and erosion. In many cases, other processes have further enriched these manganiferous sedimentary rocks to form some of today’s highest grade ores. Modern seabed resources of ferromanganese nodules cover vast areas of the present ocean floor and are still forming by complex interactions of marine microorganisms, manganese dissolved in seawater, and chemical processes on the seabed. Manganese is ubiquitous in soil, water, and air. It occurs most often in solid form but can become soluble under acidic conditions. Manganese mining, like any activity that disturbs large areas of Earth’s surface, has the potential to produce increases in manganese concentrations that could be harmful to humans or the environment if not properly controlled. Although manganese is an essential nutrient for humans and most other organisms, overexposure can lead to neurotoxicity in humans. Workers at manganese mining and processing facilities have the greatest potential to inhale manganese-rich dust. Without proper protective equipment, these workers may develop a permanent neurological disorder known as manganism. Each manganese mine is unique and presents its own suite of potential hazards and preventative measures. Likewise, various nations have their own sets of standards to ensure safe mining, isolation of mine waste, treatment of mine waters, and mine closure and restoration. Interest in mining trace metals contained in ferromanganese nodules and crusts on the seabed has increased rapidly in the past decade. Prime areas for future research include overcoming the technological challenges presented by mining as deep as 6,500 meters below sea level and understanding and mitigating the potential impacts of seabed mining on marine ecosystems.

Professional Paper↗

Hydrogeologic Framework and Occurrence and Movement of Ground Water in the Upper Humboldt River Basin, Northeastern Nevada

The upper Humboldt River basin encompasses 4,364 square miles in northeastern Nevada, and it comprises the headwaters area of the Humboldt River. Nearly all flow of the river originates in this area. The upper Humboldt River basin consists of several structural basins, in places greater than 5,000 feet deep, in which basin-fill deposits of Tertiary and Quaternary age and volcanic rocks of Tertiary age have accumulated. The bedrock of each structural basin and adjacent mountains is composed of carbonate and clastic sedimentary rocks of Paleozoic age and crystalline rocks of Paleozoic, Mesozoic and Cenozoic age. The permeability of bedrock generally is very low except for carbonate rocks, which can be very permeable where circulating ground water has widened fractures through geologic time. The principal aquifers in the upper Humboldt River basin occur within the water-bearing strata of the extensive older basin-fill deposits and the thinner, younger basin-fill deposits that underlie stream flood plains. Ground water in these aquifers moves from recharge areas along mountain fronts to discharge areas along stream flood plains, the largest of which is the Humboldt River flood plain. The river gains flow from ground-water seepage to its channel from a few miles west of Wells, Nevada, to the west boundary of the study area. Water levels in the upper Humboldt River basin fluctuate annually in response to the spring snowmelt and to the distribution of streamflow diverted for irrigation of crops and meadows. Water levels also have responded to extended periods (several years) of above or below average precipitation. As a result of infiltration from the South Fork Reservoir during the past 20 years, ground-water levels in basin-fill deposits have risen over an area as much as one mile beyond the reservoir and possibly even farther away in Paleozoic bedrock.

Scientific Investigations Report↗

Site selection for DOE/JIP gas hydrate drilling in the northern Gulf of Mexico

In the late spring of 2008, the Chevron-led Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) expects to conduct an exploratory drilling and logging campaign to better understand gas hydrate-bearing sands in the deepwater Gulf of Mexico. The JIP Site Selection team selected three areas to test alternative geological models and geophysical interpretations supporting the existence of potential high gas hydrate saturations in reservoir-quality sands. The three sites are near existing drill holes which provide geological and geophysical constraints in Alaminos Canyon (AC) lease block 818, Green Canyon (GC) 955, and Walker Ridge (WR) 313. At the AC818 site, gas hydrate is interpreted to occur within the Oligocene Frio volcaniclastic sand at the crest of a fold that is shallow enough to be in the hydrate stability zone. Drilling at GC955 will sample a faulted, buried Pleistocene channel-levee system in an area characterized by seafloor fluid expulsion features, structural closure associated with uplifted salt, and abundant seismic evidence for upward migration of fluids and gas into the sand-rich parts of the sedimentary section. Drilling at WR313 targets ponded sheet sands and associated channel/levee deposits within a minibasin, making this a non-structural play. The potential for gas hydrate occurrence at WR313 is supported by shingled phase reversals consistent with the transition from gas-charged sand to overlying gas-hydrate saturated sand. Drilling locations have been selected at each site to 1) test geological methods and models used to infer the occurrence of gas hydrate in sand reservoirs in different settings in the northern Gulf of Mexico; 2) calibrate geophysical models used to detect gas hydrate sands, map reservoir thicknesses, and estimate the degree of gas hydrate saturation; and 3) delineate potential locations for subsequent JIP drilling and coring operations that will collect samples for comprehensive physical property, geochemical and other analyses

Gulf of Mexico↗

Geologic map of the Leadville North 7.5’ quadrangle, Eagle and Lake Counties, Colorado

The Leadville North 7.5’ quadrangle lies at the northern end of the Upper Arkansas Valley, where the Continental Divide at Tennessee Pass creates a low drainage divide between the Colorado and Arkansas River watersheds. In the eastern half of the quadrangle, the Paleozoic sedimentary section dips generally 20–30 degrees east. At Tennessee Pass and Missouri Hill, the core of the Sawatch anticlinorium is mapped as displaying a tight hanging-wall syncline and foot-wall anticline within the basement-cored structure. High-angle, west-dipping, Neogene normal faults cut the eastern margin of the broad, Sawatch anticlinorium. Minor displacements along high-angle, east- and west-dipping Laramide reverse faults occurred in the core of the north-plunging anticlinorium along the western and eastern flanks of Missouri Hill. Within the western half of the quadrangle, Meso- and Paleoproterozoic metamorphic and igneous rocks are uplifted along the generally east-dipping, high-angle Sawatch fault system and are overlain by at least three generations of glacial deposits in the western part of the quadrangle. 10 Be and 26 Al cosmogenic nuclide ages of the youngest glacial deposits indicate a last glacial maximum age of about 21–22 kilo-annum and complete deglaciation by about 14 kilo-annum, supported by chronologic studies in adjacent drainages. No late Pleistocene tectonic activity is apparent within the quadrangle.

Colorado↗

Dextral, normal, and sinistral faulting across the eastern California shear zone-Mina deflection transition, California-Nevada

Strike-slip faults commonly include extensional and contractional bends and stepovers, whereas rotational stepovers are less common. The Volcanic Tableland, Black Mountain, and River Spring areas (California and Nevada, USA) (hereafter referred to as the VBR region) straddle the transition from the dominantly NW-striking dextral faults that define the northwestern part of the eastern California shear zone into a rotational stepover characterized by dominantly NE-striking sinistral faults that define the southwestern Mina deflection. New detailed geologic mapping, structural studies, and 40 Ar/ 39 Ar geochronology across the VBR region allow us to calculate Pliocene to Pleistocene fault slip rates and test predictions for the kinematics of fault slip transfer into this rotational stepover. In the VBR, Mesozoic basement is nonconformably overlain by a Miocene sequence of rhyolite, dacite, and andesite volcanic rocks that yield 40 Ar/ 39 Ar ages between 22.878 ± 0.051 Ma and 11.399 ± 0.041 Ma. Miocene rocks are unconformably overlain by an extensive sequence of Pliocene basalt and andesite lava flows and cinder cones that yield 40 Ar/ 39 Ar ages between 3.606 ± 0.060 Ma and 2.996 ± 0.027 Ma. The Pliocene sequence is, in turn, unconformably overlain by Quaternary tuffs and sedimentary rocks. This sequence of rocks is cut by NS- to NW-striking normal faults across the Volcanic Tableland that transition northward into NS-striking normal faults across the Black Mountain area and that, in turn, transition northward into NW-striking dextral and NE-striking sinistral faults in the River Spring area. A range of geologic markers were used to measure offset across the faults in the VBR, and combined with the age of the markers, yield minimum ∼EW-extension rates of ∼0.5 mm/yr across the Volcanic Tableland and Black Mountain regions, and minimum NW-dextral slip and NE-sinistral slip rates of ∼0.7 and ∼0.3 mm/yr, respectively, across the River Spring region. In the River Spring area, our preferred minimum dextral slip and sinistral slip rates are 0.8–0.9 mm/yr and 0.7–0.9 mm/yr, respectively. We propose three kinematic fault slip models, two irrotational and one rotational, whereby the VBR region transfers a portion of dextral Owens Valley fault slip northwestward into the Mina deflection. In irrotational model 1, Owens Valley fault slip is partitioned into two components, one northeastward onto the White Mountain fault zone and one northwestward into the Volcanic Tableland. Slip from the two zones is then transferred northward into the southwestern Mina deflection. In irrotational model 2, Owens Valley fault slip is partitioned into three components, with the third component partitioned west-northwest onto the Sierra Nevada frontal fault zone. In the rotational model, predicted sinistral slip rates across the southwestern Mina deflection are at least 115% greater than our observed minimum slip rates, implying our minimum observed rates underestimate true sinistral slip rates. A comparison of summed geologic fault slip rates, parallel to motion of the Sierra Nevada block relative to the central Great Basin, from the Sierra Nevada northeastward across the VBR region and into western Nevada are the same as geodetic rates, if our assumptions about the geologic slip rate across the dextral White Mountain fault zone is correct.

California, Nevada↗

Late Quaternary fluvial history of Santa Cruz Island, California, USA

The geologic history of fluvial systems on Santa Cruz Island (SCI) is complex, involving responses to both allogenic and autogenic forcings. During periods of low or lowering sea level, canyons on the island were eroded and sediment was transported off the island onto the exposed marine shelf. When sea level rose, streams aggraded, building a sedimentary wedge that progressed from the shelf upstream into the canyons. This cycle of erosion and aggradation in response to glacial–interglacial sea-level cycles was likely repeated numerous times during the Quaternary, although clear evidence of only the most recent cycle is present in the island’s alluvial sequences. Christy, Sauces, and Pozo Canyons contain thick packages of fine-grained sediments that were deposited as a result of the interaction between autogenic depositional processes and allogenic forcing of continuous base-level rise. Other canyons on the island either have little alluvial fill due to their steep gradients or are filled with coarse-grained, recent (likely late Holocene) alluvium that covers the older alluvial deposits. Differences in the nature and extent of the alluvial exposures on SCI relative to those on neighboring Santa Rosa Island reflect differences in the local topography, geology, and ranching histories of the 2 islands.

California↗

Petrographic observations on the Exmore breccia, ICDP-USGS drilling at Eyreville, Chesapeake Bay impact structure, USA

The International Continental Scientific Drilling Program (ICDP)-U.S. Geological Survey (USGS) Eyreville A and B drill cores sampled crater fill in the region of the crater moat, ??9 km to the NE of the center of the Chesapeake Bay impact structure, Virginia, USA. They provide a 953 m section (444-1397 m depth) of sedimentary clast breccia and intercalated sedimentary and crystalline megablocks knownas Exmore beds, deposited on top of the impactite sequence between 1397 and 1551 m depth. We petrographically investigated the sandy-clayey groundmass-dominated breccia, which resembles a diamictite ("Exmore breccia"), and which, in its lower parts, carries sedimentary and crystalline blocks. The entire breccia interval is characterizedby the presence of glauconite and bioclastic carbonate, which distinguishes the Exmore breccia from other sandy facies above and below in the stratigraphy. The sediment-clast breccia exhibits strong heterogeneity from sample to sample with respect to groundmass nature, e.g., clay versus sand content, as well as clast content, in general, and shocked clast content, in particular. There is a consistently signifi cantly larger macroscopic sedimentary to crystalline clast content. On the microscopic scale, the intersample sediment to crystalline clast ratios are quite variable. A very small component of shocked material, in the form of shock-deformed quartz, and to an even lesser degree feldspar, and somewhat more abundant but still relatively scarce shardshaped,altered melt particles, is present throughout the section. However, between ??458 and 469 m, and between 514 and 527 m depths, the abundance of such melt particlesis notably enhanced. These sections are also chemically distinct and relatively more mafic than the other parts of the Exmore breccia. It appears that from the time of deposition of the 527 m material, calming of the ocean occurred over the crater area as a result of abatement of resurge activity, so that ejecta from the plume abovethe crater could accumulate within the crater area to a larger degree. Deposition ofejecta fallout from the collapsing ejecta plume was terminated by the time of deposition of the 458 m material. This raises questions about the positioning of the exact upper contact of Exmore breccia to post-Exmore sediment (Chickahominy Formation), which is currently placed at 444 m depth and which possibly should be revisedto 458 m depth. Based on a signifi cant record of granite-derived material with shocked minerals, the shocked debris component seems to be largely derived from crystalline target rocks. This provides further evidence that the basement-derived material of the basal section of the Eyreville drill cores, which is essentially unshocked, is likely of an allochthonous nature and that the drilling did not intersect the actual crater floor. 76??W. ?? 2009 Geological Society of America.

Special Paper of the Geological Society of America↗

Geology of the Sierra de Fiambala, northwestern Argentina: Implications for Early Palaeozoic Andean tectonics

Field mapping in conjunction with structural, metamorphic, and geochronological data document the tectono-thermal history of exhumed deep crustal rocks in the Sierra de Fiambalá, NW Argentina. The range consists of two structural blocks distinguished by different metasedimentary sequences and different grades of metamorphism. Orthogneiss and paragneiss in the northern structural block may have a Precambrian history. Greenschist- to amphibolite-facies metamorphism, intrusion, and injection migmatization affected all rocks at 540–550 Ma. A subsequent event in the Late Cambrian to Ordovician ( c. 515 to 470 Ma) involved amphibolite- to granulite-facies metamorphism, mafic intrusion, and deformation, followed by cooling through mid-Palaeozoic time. The emplacement of Carboniferous (325–350 Ma) post-tectonic granites caused reheating and retrogression that was strongest toward the northeast part of the range. The Cambrian, Ordovician, and Carboniferous events in the Sierra de Fiambalá were of regional extent as indicated by temporal correlations with events reported for other deep crustal rocks of the northern Sierras Pampeanas. Correlations between periods of intrusion and high-grade metamorphism in the northern Sierras Pampeanas and volcanic-sedimentary events in the adjacent supracrustal exposures confirm that rocks in the northern Sierras Pampeanas formed at deep (10–25 km) structural levels in the early Palaeozoic continental margin of Gondwana.

Geological Society Special Publication↗

Inside the crater, outside the crater: Stratigraphic details of the margin of the Chesapeake Bay impact structure, Virginia, USA

Two cores at the outer margin of the Chesapeake Bay impact structure show significant structural and depositional variations that illuminate its history. Detailed stratigraphy of the Watkins School core reveals that this site is outside the disruption boundary of the crater with respect to its lower part (nonmarine Cretaceous Potomac Formation), but just inside the boundary with respect to its upper part (Exmore Formation and a succession of upper Eocene to Pleistocene postimpact deposits). The site of the U.S. Geological Survey-National Aeronautics and Space Administration Langley core, 6.4 km to the east, lies wholly within the annular trough of the crater . The Potomac Formation in the Watkins School core is not noticeably impact disrupted. The lower part of crater unit A in the Langley core represents stratigraphically lower, but similarly undeformed material. The Exmore Formation is only 7.8 m thick in the Watkins School core, but it is over 200 m thick in the Langley core, where it contains blocks up to 24 m in intersected diameter. The upper part of the Exmore Formation in the two cores is a polymict diamicton with a stratified zone at the top. The postimpact sedimentary units in the two cores have similar late Eocene and late Miocene depositional histories and contrasting Oligocene, early Miocene, and middle Miocene histories. A paleochannel of the James River removed Pliocene deposits at the Watkins School site, to be filled later with thick Pleistocene deposits. At the Langley site, a thick Pliocene and thinner Pleistocene record is preserved. © 2010 The Geological Society of America. All rights reserved.

Virginia↗

Interferometric Sidescan Bathymetry, Sediment and Foraminiferal Analyses; a New Look at Tomales Bay, California

The United States Geological Survey (USGS) in collaboration with Point Reyes National Sea Shore (PRNS), and the Tomales Bay Watershed Council [http://www.tomalesbaywatershed.org/] has completed a detailed bathymetric survey, and sediment and foraminiferal analyses of the floor of Tomales Bay, California. The study goals are to detail the submarine morphology, the sediment distribution, sedimentary features, and distribution of foraminifera to provide a framework for future studies. The USGS collected swath bathymetric data with a SEA SWATHplus interferometric sidescan sonar system (2004, 2005) and an echo sounder system (2006). The data were processed into continuous mosaic images that show bathymetric detail of the bay floor with 0.2-m vertical and 4.0-m horizontal resolution. Acoustic backscatter data from the 2004 and 2005 surveys were processed into 2-m resolution grids. In addition, 27 sediment samples were collected from various parts of the bay for grain size analyses and a comprehensive study of the distribution of foraminifera in Tomales Bay. The foraminiferal analysis determined that the invasive foraminifera Trochammina hadai from Japan was present in Tomales Bay. The project was conducted in response to a request from the National Park Service, and the Tomales Bay Watershed Council who voiced a need to look at the environmental impacts of human input to the surrounding watersheds that ultimately flow into the bay. The mapping, sediment, and foraminiferal data establish a baseline survey for future comparisons of possible geologic and anthropogenic changes that might occur due to changes in land use or development in the surrounding watershed. These data may also aid in determining the possible pathways of pollutants entering the bay from the surrounding watersheds.

Open-File Report↗

Possible effects of multiphase methane evolution during a glacial cycle on underpressure development in sedimentary basins: An analysis with application to the northeast Michigan Basin

In low-permeability systems, groundwater may be accompanied by separate-phase fluids, and measured pore water pressures may deviate from those expected in steady-state, single-phase systems. These same systems may be of interest for storage of nuclear waste in Deep Geologic Repositories. Therefore, it is important to understand the relationship between the presence of a separate phase and anomalous pressure development. At the Bruce site in Southern Ontario, a significant underpressure was observed, and there is evidence for the presence of gas-phase methane in situ. This study used a one-dimensional (vertical) numerical model of the subsurface down to a depth of 844 m beneath the Bruce site to evaluate possible effects of hydromechanical coupling with multiphase flow on pressure evolution during glacial loading and unloading. The simulated pressure conditions were affected strongly by the amount of methane initially present in the system, and the maximum simulated underpressure varied nonmonotonically with increasing initial methane content. When the initial methane content was below the solubility limit, exsolution led to underpressures that briefly exceeded those that formed in the single-phase case. At intermediate initial methane contents (sufficient to produce an immobile gas phase), the gas phase dampened the hydromechanical effects of the glacial cycle. At large initial methane contents (when a mobile gas phase was present), gas migration caused a large decrease in relative liquid permeability, which further contributed to underpressure development in the pore water. Multiple scenarios that spanned a range of initial methane contents yielded underpressures like those observed at the Bruce site.

Journal of Geophysical Research - Solid Earth↗

Geology and energy resources of the Sand Butte Rim NW Quadrangle, Sweetwater County, Wyoming

The Sand Butte Rim NW 71-minute quadrangle occupies 56 square miles of an arid, windy, sparsely vegetated area of ridges and valleys on the east flank of the Rock Springs uplift in southwest Wyoming. The area is underlain by a succession of sedimentary rocks, about 20,000 feet thick, that includes 28 formations ranging in age from Cambrian to Tertiary. Upper Cretaceous and lower Tertiary formations crop out and dip 3?-6? southeast. They are unfaulted and generally homoclinal, but a minor anticlinal nose is present. Older rocks in the subsurface are faulted and folded. Coal resources are estimated to be nearly I billion short tons of subbituminous coal, in beds more than 2.5 feet thick, under less than 3,000 feet of overburden, in the Fort Union Formation of Paleocene age and the Lance and Almond Formations of Cretaceous age.

Professional Paper↗

Quantifying permanent uplift due to lithosphere-hotspot interaction

Vertical motions that accompany the passage of the lithosphere over a mantle hotspot can shed light on the nature of the hotspot and its effect on the lithosphere. However, quantifying the temporal vertical and spatial extent, is challenging due to the paucity of evidence in the geological record. Here, we utilize dense seismic and well data covering the intersection of the Great Meteor Hotspot (GMH) track with the U.S. Atlantic continental margin to constrain the surface expression of the hotspot passage under the lithosphere. The continuous sedimentary record of the eastern North American margin during its passage over the hotspot allows determination of the timing, magnitude, width and rate of denudation. We find that a ∼300 km wide region was denuded by up to 850 m between ∼97 and 86 Ma, ∼10 m.y. after the passage of the GMH. Stratigraphic relationships suggest a decaying rock uplift rate with time and no subsequent sagging. The broad, long-lasting, and delayed uplift was modeled as a surface manifestation of either sub-lithospheric mantle depletion, permanently eroded base of the continental lithosphere, or intrusions of depleted magma. We consider sub-lithospheric depletion to be the most likely cause, based on seismic imaging results.

Tectonics↗

Map showing distribution of small-scale deformation structures in a part of the upper coastal plain of South Carolina and adjacent Georgia

As a contribution to the assessment of neotectonics in the area of the Upper Coastal Plain of South Carolina, field traverses were made between Columbia, S.C., and Augusta, Ga., in 1975 and early 1976 in order to locate and describe small-scale deformation structures within exposed Coastal Plain rocks. The study covered most of the area between the Fall Line (northwest margin of the Coastal Plain) and the Orangeburg (Citronelle) escarpment (fig. 1). Fieldwork was done principally by vehicle along roads, but also included railroad cuts and excavation sites, such as quarries and landfills. Natural exposures are rare and provided no examples of deformation structures for this study. The geologic units exposed in the area are chiefly clastic sediments deposited in nearshore marine to continental environments. They include semi-consolidated sand, silt, clay, and rare thin impure limestone beds of Late Cretaceous to Eocene age (fig. 2). These sedimentary beds generally have a gentle regional dip to the southeast (Faye and Prowell, 1982, p. 6).

Georgia, South Carolina↗

Field-trip guide to volcanic and volcaniclastic deposits of the lower Jurassic Talkeetna formation, Sheep Mountain, south-central Alaska

This guide provides information for a one-day field trip in the vicinity of Sheep Mountain, just north of the Glenn Highway in south-central Alaska. The Lower Jurassic Talkeetna Formation, consisting of extrusive volcanic and volcaniclastic sedimentary rocks of the Talkeetna arc complex, is exposed on and near Sheep Mountain. Field-trip stops within short walking distance of the Glenn Highway (approximately two hours’ drive from Anchorage) are described, which will be visited during the Geological Society of America Penrose meeting entitled Crustal Genesis and Evolution: Focus on Arc Lower Crust and Shallow Mantle , held in Valdez, Alaska, in July 2006. Several additional exposures of the Talkeetna Formation on other parts of Sheep Mountain that would need to be accessed with longer and more strenuous walking or by helicopter are also mentioned.

Alaska↗

Preliminary geologic map of the Lunenburg and Fort Mitchell 7.5' quadrangles, Virginia

The Lunenburg and Fort Mitchell 7.5' quadrangles have been mapped as part of the Geology of the South-Central Virginia Piedmont Project, a regional geologic mapping project of the U.S. Geological Survey. The two quadrangles include parts of Lunenburg, Mecklenburg, and Charlotte counties, and are located in the east-central part of the South Boston 30'x60' quadrangle (Figure 1). A preliminary geologic map of this quadrangle has been published (Norton and others, 1993), and a reconnaissance map by Laney (1917) includes the western Fort Mitchell quadrangle. Aeromagnetic and aeroradioactivity maps that include the field area have been published by the U.S. Geological Survey (1978a, 1978b). The Lunenburg and Fort Mitchell quadrangles are adjacent to the north and northwest, respectively, to the previously mapped Wightman 7.5' quadrangle (Burton, 1993; Figure 1). With respect to geologic provinces, the Lunenburg and Fort Mitchell quadrangles are located within the Carolina slate belt of the Carolina Terrane (Figure 1) and have not been previously mapped in detail. The Carolina slate belt in this area consists of volcanic and sedimentary rocks and associated intrusive igneous rocks that possess a regional slatey cleavage and have been subjected to lower greenschistfacies metamorphism. An earlier, pre-cleavage deformation and low-grade metamorphism may have occurred in the Late Proterozoic (Glover and Sinha, 1973). The rocks are locally poorly dated but probably are Late Proterozoic and Early Cambrian in age (Butler and Secor, 1991, and references therein). The Carolina slate belt may represent a subduction-related volcanic arc (Butler and Secor, 1991), or riftedarc complex (Feiss and others, 1993). Geochemical analysis and radioisotopic dating (U-Pb and 40 Ar/ 39 Ar) of slate belt rocks in the South Boston 30 x 60' quadrangle by the U.S.G.S. are in progress.

Virginia↗

S-wave refraction survey of alluvial aggregate

An S-wave refraction survey was conducted in the Yampa River valley near Steamboat Springs, Colo., to determine how well this method could map alluvium, a major source of construction aggregate. At the field site, about 1 m of soil overlaid 8 m of alluvium that, in turn, overlaid sedimentary bedrock. The traveltimes of the direct and refracted S-waves were used to construct velocity cross sections whose various regions were directly related to the soil, alluvium, and bed-rock. The cross sections were constrained to match geologic logs that were developed from drill-hole data. This constraint minimized the ambiguity in estimates of the thickness and the velocity of the alluvium, an ambiguity that is inherent to the S-wave refraction method. In the cross sections, the estimated S-wave velocity of the alluvium changed in the horizontal direction, and these changes were attributed to changes in composition of the alluvium. The estimated S-wave velocity of the alluvium was practically constant in the vertical direc-tion, indicating that the fine layering observed in the geologic logs could not be detected. The S-wave refraction survey, in conjunction with independent information such as geologic logs, was found to be suitable for mapping the thickness of the alluvium.

Scientific Investigations Report↗

Geology and quality of water in the Modesto-Merced area, San Joaquin Valley, California, with a brief section on hydrology

The Modesto-Merced area includes about 1,800 square miles on the northeast side of the San Joaquin Valley. The physiographic units in the area are (1) Sierra Nevada, (2) dissected uplands, (3) low alluvial plains and fans, (4) river flood plains and channels, and (5) overflow lands. Geologic units consist of consolidated rocks and unconsolidated deposits. The dominant structure of the geologic units is that of a homocline, which reflects the southwestward-tilted fault block of the Sierra Nevada. The consolidated rocks include: (1) basement complex (pre-Tertiary), (2) marine sandstone and shale (Cretaceous), (3) Ione Formation and other sedimentary rocks (Eocene), (4) Valley Springs Formation (late? Miocene), and (5) the Mehrten Formation (Miocene and Pliocene). In the eastern part of the area, the consolidated rocks generally yield small quantities of water to wells except for the Mehrten Formation which is an important aquifer. The unconsolidated deposits include: (1) continental deposits (Pliocene and Pleistocene?), (2) lacustrine and marsh deposits (Pleistocene), (3) older alluvium (Pleistocene and Holocene?), (4) younger alluvium (Holocene), and (5) flood-basin deposits (Holocene). The continental deposits and older alluvium are the main water-yielding units in the unconsolidated deposits. The lacustrine and marsh deposits (E-clay) and the flood-basin deposits yield little water to wells, and the younger alluvium in most places probably yields only moderate quantities of water to wells. There are three ground-water bodies in the Modesto-Merced area: (1) the unconfined water body, (2) the confined water body, and (3) the water body in consolidated rocks. The unconfined water body occurs in the unconsolidated deposits above and east of the E-clay, except in the western and southern parts of the area where clay lenses occur and semiconfined conditions exist. The confined water body occurs in the unconsolidated deposits below the E-clay and extends downward to the base of fresh water. The water body in consolidated rocks occurs under both perched and confined conditions. Ground-water movement in the unconfined and the confined water bodies is generally westward toward the valley trough. In the unconfined water body, the water also moves toward the major rivers, and toward pumping depressions at Modesto and near El Nido. Because of the higher head in the unconfined water body, water slowly moves from it through the E-clay to the underlying confined water body. Surface water is used extensively for irrigation in most of the study area; consequently, shallow water in the unconfined water body has to be controlled by pumping. Nevertheless, water levels near Modesto declined about 6 feet between 1958 and 1962, for the most part during the dry years 1959-61. Near El Nido, water levels declined about 70 feet between 1942 and 1967. In the confined water body, water levels were high in the winter and spring and low in the summer and fall, reflecting irrigation practices. In the southwestern part of the area, water levels in the confined water body declined about 14 feet from 1962 to 1968 and rose slightly after 1968, whereas in the northwestern part water levels remained fairly constant. Water from the upper reaches of the Stanislaus, Tuolumne, Merced, and Chowchilla Rivers is calcium bicarbonate in chemical type and is of excellent quality. As those rivers cross the valley floor, their water quality is generally degraded by return flows from irrigated land, and in the Tuolumne River by saline water discharged from abandoned gas wells. Average dissolvedsolids content in the major rivers, as indicated by chemical analyses, do not exceed 400 mg/1 (milligrams per liter) except in the San Joaquin River where average dissolved-solids content has not exceeded 1,050 mg/l. Water from minor streams in the area is bicarbonate in chemical type with dissolved-solids content ranging from 56 mg/1 to about 350 mg/l. Although chloride-type fresh ground water occurs in the unconfined and confined water bodies and in the water body in consolidated rocks, most of the fresh ground water is a bicarbonate type that has a dissolved-solids content of less than 500 mg/l. Water having dissolved solids in excess of about 2,000 mg/1 is considered to be saline. Saline water extends below the base of fresh water to the basement complex and, except in the extreme eastern part, underlies most of the study area. Saline water also occurs as lenses above the base of fresh water in the unconfined and confined water bodies.

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