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New techniques for the quantification and modeling of remotely sensed alteration and linear features in mineral resource assessment studies

Linear structural features and hydrothermally altered rocks that were interpreted from Landsat data have been used by the U.S. Geological Survey (USGS) in regional mineral resource appraisals for more than a decade. In the past, linear features and alterations have been incorporated into models for assessing mineral resources potential by manually overlaying these and other data sets. Recently, USGS research into computer-based geographic information systems (GIS) for mineral resources assessment programs has produced several new techniques for data analysis, quantification, and integration to meet assessment objectives.

Pecora XI Symposium↗

Differentiation and magma mixing on Kilauea's east rift zone: A further look at the eruptions of 1955 and 1960. Part II. The 1960 lavas

New and detailed petrographic observations, mineral compositional data, and whole-rock vs glass compositional trends document magma mixing in lavas erupted from Kilauea's lower east rift zone in 1960. Evidence includes the occurrence of heterogeneous phenocryst assemblages, including resorbed and reversely zoned minerals in the lavas inferred to be hybrids. Calculations suggest that this mixing, which is shown to have taken place within magma reservoirs recharged at the end of the 1955 eruption, involved introduction of four different magmas. These magmas originated beneath Kilauea's summit and moved into the rift reservoirs beginning 10 days after the eruption began. We used microprobe analyses of glass to calculate temperatures of liquids erupted in 1955 and 1960. We then used the calculated proportions of stored and recharge components to estimate the temperature of the recharge components, and found those temperatures to be consistent with the temperature of the same magmas as they appeared at Kilauea's summit. Our studies reinforce conclusions reached in previous studies of Kilauea's magmatic plumbing. We infer that magma enters shallow storage beneath Kilauea's summit and also moves laterally into the fluid core of the East rift zone. During this process, if magmas of distinctive chemistry are present, they retain their chemical identity and the amount of cooling is comparable for magma transported either upward or laterally to eruption sites. Intrusions within a few kilometers of the surface cool and crystallize to produce fractionated magma. Magma mixing occurs both within bodies of previously fractionated magma and when new magma intersects a preexisting reservoir. Magma is otherwise prevented from mixing, either by wall-rock septa or by differing thermal and density characteristics of the successive magma batches.

Bulletin of Volcanology↗

Results of a geochemical survey, Aban Al Ahmar Quadrangle, Sheet 25F, Kingdom of Saudi Arabia

The interpretation of geochemical data from a regional survey of the Aban al Ahmar quadrangle resulted in the selection of areas for follow-up studies. The results of detailed geochemical studies of these areas, combined with field observation, resulted in the selection of areas of moderate to high mineral resource potential. The most important areas are (1) the Jibal Minyah area, Aban al Asmar area, Jibal Suwaj area, and Nubayah area where tin and tungsten mineralization are associated with Abanat-suite rocks or possible buried Abanat-suite plutons; (2) several areas containing rocks of the Murdama group in the northern part of the quadrangle, the Buqaya al Luaah area, and the Jabal Akkash area where precious- and base-metal mineralization are generally associated with small Idah-suite plutons; and (3) the southern periphery of Jibal Qitan associated with skarn mineralization. The Aban al Ahmar quadrangle (sheet 25F) lies in the northeastern part of the Proterozoic Arabian Shield. Plots showing the distribution of single elements and factor scores of the regional geochemical data for wadi concentrates were used to select favorable areas for follow-up work. Detailed follow-up studies consisted of the collection of samples of rocks, wadi concentrates, and wadi sediments. The most useful pathfinder elements for precious- and base-metal mineralization are Cu and Pb, and for tin and tungsten mineralization they are Sn, La, Nb, Y, and Be. R-mode factor analysis of the regional geochemical data resulted in two factors that reflect mineralization: precious- and base-metal mineralization; and Abanat-suite lithology and, therefore, tin and tungsten mineralization. A major problem in the interpretation of the regional geochemical data resulted from incomplete removal of magnetite from the samples prior to analysis. The presence of magnetite can cause anomalous values of Ni, Fe, V, Cu, and Co in samples because of it's ability to incorporate these elements into its structure during magmatic crystallization.

Open-File Report↗

Mesozoic magmatism and base-metal mineralization in the Fortymile mining district, eastern Alaska — Initial results of petrographic, geochemical, and isotopic studies in the Mount Veta area

We present here the initial results of a petrographic, geochemical, and isotopic study of Mesozoic intrusive rocks and spatially associated Zn-Pb-Ag-Cu-Au prospects in the Fortymile mining district in the southern Eagle quadrangle, Alaska. Analyzed samples include mineralized and unmineralized drill core from 2006 and 2007 exploration by Full Metal Minerals, USA, Inc., at the Little Whiteman (LWM) and Fish prospects, and other mineralized and plutonic samples collected within the mining district is part of the USGS study. Three new ion microprobe U-Pb zircon ages are: 210 ± 3 Ma for quartz diorite from LWM, 187 ± 3 Ma for quartz monzonite from Fish, and 70.5 ± 1.1 Ma for altered rhyolite porphyry from Fish. We also present 11 published and unpublished Mesozoic thermal ionization mass spectrometric U-Pb zircon and titanite ages and whole-rock geochemical data for the Mesozoic plutonic rocks. Late Triassic and Early Jurassic plutons generally have intermediate compositions and are slightly foliated, consistent with synkinematic intrusion. Several Early Jurassic plutons contain magmatic epidote, indicating emplacement of the host plutons at mesozonal crustal depths of greater than 15 km. Trace-element geochemical data indicate an arc origin for the granitoids, with an increase in the crustal component with time. Preliminary study of drill core from the LWM Zn-Pb-Cu-Ag prospect supports a carbonate-replacement model of mineralization. LWM massive sulfides consist of sphalerite, galena, and minor pyrite and chalcopyrite, in a gangue of calcite and lesser quartz; silver resides in Sb-As-Ag sulfosalts and pyrargyrite, and probably in submicroscopic inclusions within galena. Whole-rock analyses of LWM drill cores also show elevated In, an important metal in high-technology products. Hypogene mineralized rocks at Fish, below the secondary Zn-rich zone, are associated with a carbonate host and also may be of replacement origin, or alternatively, may be a magnetite-bearing Zn skarn. Cu-Zn-Pb-Ag-Au showings at the Oscar pros-pect occur in marble-hosted magnetite and pyrrhotite skarn that is spatially related to the stocks, dikes, and sills of the Early Jurassic syenite of Mount Veta. Mineralized rocks at the Eva Creek Ag-Zn-Pb-Cu prospect are within 1.5 km of the Mount Veta pluton, which is epidotized and locally altered along its contact with metamorphosed country rock east of the prospect. We report five new sulfide Pb-isotopic analyses from the LWM, Oscar, and Eva Creek prospects and compare these sulfide Pb-isotopic ratios with those for sulfides from nearby deposits and prospects in the Yukon-Tanana Upland and with feldspar Pb-isotopic ratios for Mesozoic plutons in the region. Disparities between the Pb-isotopic ratios for sulfides and igneous feldspars are consistent with a carbonate-replacement model for both the LWM and Eva Creek prospects. The presence in the Fortymile district of base-metal sulfides within both calc-silicate-rich skarns and the calc-silicate-free carbonate replacement deposits may reflect multistage mineralization by magmatic-hydrothermal systems during the emplacement of two or more magmatically unrelated igneous intrusions. Alternatively, all of the mineralized occurrences could be products of one regionally zoned system that formed during the intrusion of a single pluton. In addition to the likely origin of some of the base-metal occurrences by intrusion-related hydrothermal fluids, proximity of the LWM prospect to the northeast-striking, high-angle Kechumstuk Fault suggests that fluid flow along the fault also played an important role during carbonate-replacement mineralization.

Alaska↗

Similarities, differences, and some genetic problems of the Wyoming and Colorado plateau types of uranium deposits in sandstone

Uranium deposits of the Wyoming roll type and the Colorado Plateau peneconcordant type are the principal domestic resources of uranium. Both types occur in lenticular sandstone beds of continental origin, have a similar suite of elements and minerals, are associated with mildly altered rock, and are thought to have formed by reduction precipitation from ground waters before significant regional deformation. They differ in several respects. The Wyoming deposits are in unlithified sandstone that is highly arkosic, whereas the Colorado Plateau deposits are in lithified sandstone that is only slightly to moderately arkosic. Uranium is the only ore metal in the Wyoming deposits, whereas vanadium or copper is more abundant than uranium in some of the Plateau deposits. The Wyoming deposits are elongate crescent-shaped bodies that extend vertically through, or partly through, a sandstone unit and which are scattered, like widely spaced beads on a string, along miles-long interfaces between oxidized (altered) and unoxidized sandstone, whereas the Plateau deposits are thin tabular layers that are nearly concordant to bedding and which occur as discrete bodies, like raisins in raisin bread, enveloped in rock altered by reduction. The Wyoming ore rolls and interfaces were dynamic, having been pushed downdip by downward-moving oxygen-bearing water that passed through the interfaces and deposited the ore minerals on the reducing side, whereas the Plateau deposits seemingly formed as static bodies, localized by intensive reducing "patches" in a mildly reducing environment. These differences focus attention on genetic problems relating to the Eh of the ore-bearing and altering solutions, the shape and localization of deposits, and the source of the uranium.

Arizona, Colorado, New Mexico, South Dakota, Utah,↗

Genesis of ore deposits in the San Juan Volcanic Field, Southwestern Colorado-lead isotope evidence

In the San Juan volcanic area of southwestern Colorado, the isotopic composition of lead in ores and ore prospects of Cenozoic age ranges widely: 17.72 to 21.13 for 206 Pb/ 204 Pb; 15.50 to 15.81 for 207 Pb/ 204 Pb; and 37.21 to 38 for 208 Pb/ 204 Pb. Examination of the lead isotope data indicates that once deposition of lead minerals begins, further exchange of lead between fluid and wall rock is insignificant. This conclusion is supported by the relatively constant isotopic composition of the lead in these ores, which is not affected by the grade of ore mineralization or type of wall rock. The values of 206 Pb/ 204 Pb in some vein-type deposits exceed the maximum value known for all Mesozoic and Cenozoic igneous rocks of the Rocky Mountain region. These isotopic relations show that if ore-forming solutions are composed of meteoric water, as indicated in studies of light stable isotopes, they must have penetrated deep enough to acquire lead from Pre-cambrian rocks or sediments derived from them. The fact that some of these vein ores are now in Cenozoic igneous rocks indicates the ore fluid had an upward vertical component to its movement. The lead isotope data therefore support a circulating cell hypothesis for these kinds of ores, as suggested by many recent studies of light stable isotopes as related to mineralization. Some other deposits (Summitville, Jasper, Red Mountain district) have values of 206 Pb/ 204 Pb similar to those of the large volumes of altered rock that enclose them ( 206 Pb/ 204 Pb ∼ 18.5), suggesting that in places the lead may have been locally derived by leaching of the adjacent rocks or from magmatogenic fluids. When the lead isotope data are treated in detail, the rocks and galenas of the Platoro caldera complex, of the central San Juan caklera complex, and of the Baughman Creek center appear to contain significant components derived from 1,400- to l,500-m.y.-old and 1,700- to 1,800 m.y.-old source materials. These also are the ages of the two main groups of rocks that comprise the Precambrian basement under the San Juan volcanic area. Although the data from the western San Juan caldera complex scatter considerably, the only obvious source for the lead seems to be the 1,700- to l,800-m.y.-old rocks or detritus of such age in Phanerozoic sediments. Where the involvement of 1,400- to l,500-m.y.-old sources is greatest, the Th/U ratio in the source material is small (calculated to be about 0.7), whereas the Th/U ratio of the 1,700- to l,800-m.y.-old source material appears to be 2.3 to 3.3. The largest Th/U values are from the western San Juan caldera complex. © 1979 Society of Economic Geologists, Inc.

Colorado↗

Reconstruction of an early Permian, sublacustrine magmatic-hydrothermal system: Mount Carlton epithermal Au-Ag-Cu deposit, northeastern Australia

The Mt. Carlton Au-Ag-Cu deposit, northern Bowen basin, northeastern Australia, is an uncommon example of a sublacustrine hydrothermal system containing economic high-sulfidation epithermal mineralization. The deposit formed in the early Permian and comprises vein- and hydrothermal breccia-hosted Au-Cu mineralization within a massive rhyodacite porphyry (V2 open pit) and stratabound Ag-barite mineralization within volcano-lacustrine sedimentary rocks (A39 open pit). These orebodies are all associated with extensive advanced argillic alteration of the volcanic host rocks. Stable isotope data for disseminated alunite ( δ 34 S = 6.3–29.2‰; δ 18 OSO 4 = –0.1 to 9.8‰; δ 18 O OH = –15.3 to –3.4‰; δ D = –102 to –79‰) and pyrite ( δ 34 S = –8.8 to –2.7‰), and void-filling anhydrite ( δ 34 S = 17.2–19.2‰; δ 18 O SO4 = 1.8–5.7‰), suggest that early advanced argillic alteration formed within a magmatic-hydrothermal system. The ascending magmatic vapor ( δ 34 S ΣS ≈ –1.3‰) was absorbed by meteoric water (~50–60% meteoric component), producing an acidic (pH ≈ 1) condensate that formed a silicic → quartz-alunite → quartz-dickite-kaolinite zoned alteration halo with increasing distance from feeder structures. The oxygen and hydrogen isotope compositions of alunite-forming fluids at Mt. Carlton are lighter than those documented at similar deposits elsewhere, probably due to the high paleolatitude (~S60°) of northeastern Australia in the early Permian. Veins of coarse-grained, banded plumose alunite ( δ 34 S = 0.4– 7.0‰; δ 18 O SO4 = 2.3–6.0‰; δ 18 O OH = –10.3 to –2.9‰; δ D = –106 to –93‰) formed within feeder structures during the final stages of advanced argillic alteration. Epithermal mineralization was deposited subsequently, initially as fracture- and fissure-filling, Au-Cu–rich assemblages within feeder structures at depth. As the mineralizing fluids discharged into lakes, they produced syngenetic Ag-barite ore. Isotope data for ore-related sulfides and sulfosalts ( δ 34 S = –15.0 to –3.0‰) and barite ( δ 34 S = 22.3–23.8‰; δ 18 O SO4 = –0.2 to 1.3‰), and microthermometric data for primary fluid inclusions in barite (Th = 116°– 233°C; 0.0–1.7 wt % NaCl), are consistent with metal deposition at temperatures of ~200 ± 40°C (for Au-Cu mineralization in V2 pit) and ~150 ± 30°C (Ag mineralization in A39 pit) from a low-salinity, sulfur- and metal-rich magmatic-hydrothermal liquid that mixed with vapor-heated meteoric water. The mineralizing fluids initially had a high-sulfidation state, producing enargite-dominated ore with associated silicification of the early-altered wall rock. With time, the fluids evolved to an intermediate-sulfidation state, depositing sphalerite- and tennantite-dominated ore mineral assemblages. Void-filling massive dickite ( δ 18 O = –1.1 to 2.1‰; δ D = –121 to –103‰) with pyrite was deposited from an increasingly diluted magmatic-hydrothermal liquid (≥70% meteoric component) exsolved from a progressively degassed magma. Gypsum ( δ 34 S = 11.4–19.2‰; δ 18 O SO4 = 0.5–3.4‰) occurs in veins within postmineralization faults and fracture networks, likely derived from early anhydrite that was dissolved by circulating meteoric water during extensional deformation. This process may explain the apparent scarcity of hypogene anhydrite in lithocaps elsewhere. While the Mt. Carlton system is similar to those that form subaerial high-sulfidation epithermal deposits, it also shares several key characteristics with magmatic-hydrothermal systems that form base and precious metal mineralization in shallow-submarine volcanic arc and back-arc settings. The lacustrine paleosurface features documented at Mt. Carlton may be useful as exploration indicators for concealed epithermal mineralization in similar extensional terranes elsewhere.

Economic Geology↗

Miocene magmatism in the Bodie Hills volcanic field, California and Nevada: A long-lived eruptive center in the southern segment of the ancestral Cascades arc

The Middle to Late Miocene Bodie Hills volcanic field is a >700 km 2 , long-lived (∼9 Ma) but episodic eruptive center in the southern segment of the ancestral Cascades arc north of Mono Lake (California, U.S.). It consists of ∼20 major eruptive units, including 4 trachyandesite stratovolcanoes emplaced along the margins of the field, and numerous, more centrally located silicic trachyandesite to rhyolite flow dome complexes. Bodie Hills volcanism was episodic with two peak periods of eruptive activity: an early period ca. 14.7–12.9 Ma that mostly formed trachyandesite stratovolcanoes and a later period between ca. 9.2 and 8.0 Ma dominated by large trachyandesite-dacite dome fields. A final period of small silicic dome emplacement occurred ca. 6 Ma. Aeromagnetic and gravity data suggest that many of the Miocene volcanoes have shallow plutonic roots that extend to depths ≥1–2 km below the surface, and much of the Bodie Hills may be underlain by low-density plutons presumably related to Miocene volcanism. Compositions of Bodie Hills volcanic rocks vary from ∼50 to 78 wt% SiO 2 , although rocks with <55 wt% SiO 2 are rare. They form a high-K calc-alkaline series with pronounced negative Ti-P-Nb-Ta anomalies and high Ba/Nb, Ba/Ta, and La/Nb typical of subduction-related continental margin arcs. Most Bodie Hills rocks are porphyritic, commonly containing 15–35 vol% phenocrysts of plagioclase, pyroxene, and hornblende ± biotite. The oldest eruptive units have the most mafic compositions, but volcanic rocks oscillated between mafic and intermediate to felsic compositions through time. Following a 2 Ma hiatus in volcanism, postsubduction rocks of the ca. 3.6–0.1 Ma, bimodal, high-K Aurora volcanic field erupted unconformably onto rocks of the Miocene Bodie Hills volcanic field. At the latitude of the Bodie Hills, subduction of the Farallon plate is inferred to have ended ca. 10 Ma, evolving to a transform plate margin. However, volcanism in the region continued until 8 Ma without an apparent change in rock composition or style of eruption. Equidimensional, polygenetic volcanoes and the absence of dike swarms suggest a low differential horizontal stress regime throughout the lifespan of the Bodie Hills volcanic field. However, kinematic data for veins and faults in mining districts suggest a change in the stress field from transtensional to extensional approximately coincident with the inferred cessation of subduction. Numerous hydrothermal systems were operative in the Bodie Hills during the Miocene. Several large systems caused alteration of volcaniclastic rocks in areas as large as 30 km 2 , but these altered rocks are mostly devoid of economic mineral concentrations. More structurally focused hydrothermal systems formed large epithermal Au-Ag vein deposits in the Bodie and Aurora mining districts. Economically important hydrothermal systems are temporally related to intermediate to silicic composition domes. Rock types, major and trace element compositions, petrographic characteristics, and volcanic features of the Bodie Hills volcanic field are similar to those of other large Miocene volcanic fields in the southern segment of the ancestral Cascade arc. Relative to other parts of the ancestral arc, especially north of Lake Tahoe in northeastern California, the scarcity of mafic rocks, relatively K-rich calc-alkaline compositions, and abundance of composite dome fields in the Bodie Hills may reflect thicker crust beneath the southern ancestral arc segment. Thicker crust may have inhibited direct ascent and eruption of mafic, mantle-derived magma, instead stalling its ascent in the lower or middle crust, thereby promoting differentiation to silicic compositions and development of porphyritic textures characteristic of the southern ancestral arc segment.

California, Nevada↗

Effects of mother lode-type gold mineralization on 187Os/188Os and platinum group element concentrations in peridotite: Alleghany District, California

Osmium isotope compositions and concentrations of Re, platinum group elements (PGE), and Au were determined for host peridotites (serpentinites and barzburgites) and hydrothermally altered ultramafic wall rocks associated with Mother Lode-type hydrothermal gold-quartz vein mineralization in the Alleghany district, California. The host peridotites have Os isotope compositions and Re, PGE, and Au abundances typical of the upper mantle at their presumed formation age during the late Proterozoic or early Paleozoic. The hydrothermally altered rocks have highly variable initial Os isotope compositions with ??os, values (% deviation of 187OS/188OS from the chondritic average calculated for the approx. 120 Ma time of mineralization) ranging from -1.4 to -8.3. The lowest Os isotope compositions are consistent with Re depletion of a chondritic source (e.g., the upper mantle) at ca. 1.6 Ga. Most of the altered samples are enriched in Au and have depleted and fractionated abundances of Re and PGE relative to their precursor peridotites. Geoehemical characteristics of the altered samples suggest that Re and some PGE were variably removed from the ultramafic rocks during the mineralization event. In addition to Re, the Pt and Pd abundances of the most intensely altered rocks appear to have been most affected by mineralization. The 187Os-depleted isotopic compositions of some altered rocks are interpreted to be a result of preferential 187Os loss via destruction of Re-rich phases during the event. For these rocks, Os evidently is not a useful tracer of the mineralizing fluids. The results do, however, provide evidence for differential mobility of these elements, and mobility of 187Os relative to the initial bulk Os isotope composition during hydrothermal metasomatic alteration of ultramafic rocks. ?? 2007 Society of Economic Geologists, Inc.

Economic Geology↗

Summaries of data on and lists of references to metallic and selected nonmetallic mineral deposits in the Talkeetna Mountains Quadrangle, Alaska

These summaries of data on metallic and selected nonmetallic mineral occurrences and lists of selected references to them in Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys (and predecessor State agencies) reports and maps are designed to aid in library research on the mineral resources of the Talkeetna Mountains quadrangle, Alaska. The references listed are selected in the sense that mainly statistical reports such as the annual Minerals Yearbook of the U.S. Bureau of Mines and many annual and biennial reports of the Alaska Division of Geological and Geophysical Surveys and its predecessor agencies are not included. Also not included are data on many claims about which little more than their locations is known (for example, localities 3 and 6 in Csejtey and Miller, 1978 (OF 78- 558B)). These omissions should not be interpreted as a judgement that the claims are not on valid mineral occurrences, but only that there are insufficient data to describe any mineral deposit that might be present. Geochemical anomalies determined by analyses of rock and stream—sediment samples in which no metallic mineral was identified are also omitted. This report is divided into three parts: a section made up of summaries of data and reference lists arranged alphabetically by occurrence name; a second section that lists synonyms for names in the first section and the names of owners and operators of mines and prospects; and a final section that lists alphabetically by author all references mentioned in the first section and in these introductory paragraphs.

Alaska↗

Summaries of data on and lists of references to metallic and selected nonmetallic mineral deposits in fifteen quadrangles in southwestern and west-central Alaska

These summaries of data on metallic and selected nonmetallic mineral occurrences and lists of selected references to them in Geological Survey, U.S. Bureau of Mines, and State of Alaska Division of Geological and Geophysical Surveys (and predecessor State and Territorial agencies) reports and maps released before Jan. 1, 1980, and in one abstract of a report presented orally at a scientific meeting, are designed to aid in library research on the mineral resources of 14 quadrangles in southwestern Alaska and the Saint Lawrence quadrangle in west—central Alaska. The references are selected in the sense that mainly statistical reports such as the annual Minerals Yearbook of the U.S. Bureau of Mines and many annual and biennial reports of the Alaska Division of Geological and Geophysical Surveys and its predecessor agencies are not included. Also not included are data on many claims about which little more than their locations is known (for example, localities 11 to 14 in MacKevett and Holloway, 1977 (OF 77-169D), p. 28). These omissions should not be interpreted as a judgement that the claims are not on valid mineral occurrences, but only that there are insufficient data to describe any mineral deposit that might be present. Geochemical anomalies determined by analyses of rock and stream—sediment samples in which no metallic mineral was identified are also omitted. Work now in progress should add greatly to the knowledge of mineral resources in several quadrangles on the Alaska Peninsula.

Alaska↗

USGS Mineral Resources Program: A National Perspective

Minerals are chemical compounds abundant in the rocks, soil, and water around us and they have a profound impact on the lives of all beings. Naturally occurring minerals define the landscape in which we live. They affect our ecosystems, influence the availability of nutrients that support biota, impact the distribution of vegetation, and may also contribute to contamination of the environment. Minerals are used in fertilizers for farming, in concrete and building materials for construction, in aggregate for roads, in steel for cars and all manner of transportation, and in materials crucial to the communications industry.

Fact Sheet↗

Stratigraphy of Slick Rock district and vicinity, San Miguel and Dolores Counties, Colorado

The Slick Rock district covers about 570 square miles in western San Miguel and Dolores Counties, in southwestern Colorado. It is at the south edge of the salt-anticline region of southwestern Colorado and southeastern Utah and of the Uravan mineral belt. Deposition of Paleozoic sedimentary rocks in the district and vicinity was principally controlled by development of the Paradox Basin, and of Mesozoic rocks by development of a depositional basin farther west. The Paleozoic rocks generally are thickest at the northeast side of the Paradox Basin in a northwest- trending trough which seems to be a wide graben in Precambrian igneous and metamorphic basement rocks; Mesozoic rocks generally thicken westward and southwestward from the district. Sedimentary rocks rest on a Precambrian basement consisting of a variety of rocks, including granite and amphibolite. The surface of the Precambrian rocks is irregular and generally more than 2,000 feet below sea level and 7,000-11,000 feet below the ground surface. In the northern part of the district the Precambrian surface plunges abruptly northeastward into the trough occupying the northeast side of the Paradox Basin, and in the southern part it sags in a narrow northeasterly oriented trough. Deepening of both troughs, or crustal deformation in their vicinity, influenced sedimentation during much of late Paleozoic and Mesozoic time. The maximum total thickness of sedimentary rocks underlying the district is 13,000 feet, and prior to extensive erosion in the late Tertiary and the Quaternary it may have been as much as about 18,000 feet. The lower 5,000 feet or more of the sequence of sedimentary rocks consists of arenaceous strata of early Paleozoic age overlain by dominantly marine carbonate rocks and evaporite beds interbedded with lesser amounts of clastic sediments of late Paleozoic age. Overlying these rocks is about 4,500 feet of terrestrial clastic sediments, dominantly sandstone with lesser amounts of shale, mudstone, siltstone, and conglomerate, of late Paleozoic and Mesozoic age. Above these rocks is as much as 2,300 feet of marine shale of late Mesozoic age. Perhaps about 5,000 feet of clastic sedimentary rocks, dominantly sandstone and in part shale, of late Mesozoic and early Cenozoic age, overlay the older rocks of the district prior to late Cenozoic erosion... Outside the Slick Rock district the Mancos Shale is overlain by dominantly terrestrial sandstone, mudstone, and coaly beds of the Mesaverde Group of Late Cretaceous age, and younger units such as the Wasatch and Green River Formations of Tertiary age, which once may have extended across the district. These units, totaling possibly 5,000 feet in thickness, were removed by erosion following middle Tertiary uplift of the Colorado Plateau. Igneous rocks of Tertiary age crop out in only one small area in the district, but they are intruded extensively in the Mancos Shale east of the district, and, as shown by deep oil test wells, appear to be intruded widely in the Paradox Member of the Hermosa Formation in the southern part of the district and southeast of the district. Andesite porphyry occurs in a dike on Glade Mountain, microgranogabbro and microgranodiorite occur in thin sills east of the district, and rocks of similar composition form thick sills in the subsurface. All are similar chemically to igneous rocks in the San Juan Mountains southeast of the district and probably were the result of a specific igneous episode. They were intruded most likely during the Miocene. Surficial deposits of Quaternary age include glacial till, terrace gravels, alluvial fans, landslide debris, loess, other soil, alluvium, colluvium, and talus. On Glade Mountain, glacial till of probable early Pleistocene age merges westward with terrace gravels that are correlative with terrace gravels which lie on an old weathered surface of Mancos Shale farther west on the rim of the Dolores River Canyon.

Colorado↗

A channel sampling strategy for measurement of mineral modal and chemical composition of drill cores: Application to lower oceanic crustal rocks from IODP Expedition 345 to the Hess Deep rift

We report a new sampling strategy for collecting representative samples of drill core. By splitting the core with a diamond saw into working and archive halves, the saw cuttings constitute a “channel” sample, the best subsample from which to obtain an average mineralogical and geochemical composition of a core. We apply this procedure to sampling core of the lower oceanic crust in the Hess Deep obtained during Expedition 345 of the Integrated Ocean Drilling Program (now International Ocean Discovery Program). Our results show that particles produced by sawing range from sand to clay sizes. Sand- and silt-sized cuttings can be sampled with a spatula, whereas clay-sized particles remained in suspension after 12 h and could be collected only by settling, aided by centrifuge. X-ray diffraction (XRD) analysis and Rietveld refinement show that phyllosilicates were fractionated into the clay-sized fraction. Thus, collection of both the sedimented fraction and the clay-sized suspended fraction (commonly > 15 wt % of the total) is necessary to capture the whole sample. The strong positive correlation between the recovered sample mass (in grams) and length of core cut demonstrates that this sampling protocol was uniform and systematic, with almost 1.4 g sediment produced per centimeter of core cut. We show that major-element concentrations of our channel samples compare favorably with the compositions of billet-sized samples analyzed aboard the JOIDES Resolution , but the results show that individual billet analyses are rarely representative of the whole core recovered. A final test of the validity of our methods comes from the strong positive correlation between the loss on ignition (LOI) values of our channel samples and the H 2 O contents calculated from the modal mineralogy obtained by X-ray diffraction and Rietveld refinement. This sampling procedure shows that grain-sized fractionation modifies both mineralogical and chemical compositions; nevertheless, this channel sampling method is a reliable method of obtaining representative samples of bulk cores. With the ever-increasing precision offered by modern analytical instrumentation, this sampling protocol allows the accuracy of the analytical results to keep pace.

Scientific Drilling↗

Hydrothermal alteration, ore fluid characteristics, and gold depositional processes along a trondhjemite-komatiite contact at Tarmoola, Western Australia

Tarmoola is a structurally controlled Archean orogenic gold deposit hosted in greenschist facies metamorphosed komatiite and trondhjemite in the Leonora district of the Eastern Goldfields province, Yilgarn craton. High-grade (>1 g/t Au) orebodies are located in komatiite wall rock adjacent to the eastern and northeastern margins of the asymmetrical, north-south-striking, Tarmoola trondhjemite intrusion. Gold-bearing veins post-date trondhjemite emplacement (ca. 2700 Ma), quartz diorite dikes (ca. 2667 Ma), and regional greenschist facies metamorphism. Textures and crosscutting relationships in gold-bearing veins indicate two stages of hydrothermal fluid infiltration associated with a single gold-related hydrothermal event: a volumetrically dominant, but gold-poor, stage I fluid and a gold-rich stage II fluid. Gold-bearing veins contain stage I milky quartz and pyrite that are overprinted by stage II quartz-ankerite-muscovite-chalcopyrite-sphalerite-galena-gold-tellurides ?? albite ?? chlorite ?? fuchsite ?? epidote ?? scheelite. Stage I hydrothermal alteration assemblages are different in trondhjemite and komatiite due to contrasting reactions between a common ore fluid and disparate wall-rock chemistry. Stage II fluid-wall rock interaction was minor compared to stage I and is indicated by the overprinting of stage I mineral assemblages by stage II microveins. Wall-rock alteration proximal to veins in trondhjemite is characterized by replacement of igneous plagioclase, amphibole, biotite, and metamorphic chlorite by hydrothermal quartz, muscovite, ankerite, calcite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold, whereas in proximal alteration in komatiite, metamorphic chlorite and talc are replaced by ankerite, quartz, muscovite, albite, chlorite, fuchsite, pyrite, chalcopyrite, sphalerite, galena, tellurides, and gold. The stage II fluid was enriched in H2O, CO2, Si, Ca, K, Na, S, Au, Ag, Cu, Pb, W, Bi, As, Mo, Zn, and Te. Based on fluid inclusion studies and stage II mineral equilibria, gold deposited from a homogeneous, neutral to slightly alkaline (pH 5.1-5.5), reduced, low-salinity (<5.5 wt % NaCl equiv) fluid that had a bulk composition of 78 mole percent H2O and 21 mole percent CO2, and trace amounts of CH4, C2H6, H2, Ar, H2S, and He. Gold deposition occurred at 300?? ?? 50??C and 0.5 to 3.0 kbars. Assuming lithostatic fluid pressures, gold precipitated at a 2- to 10-km depth. Stage II gray quartz ??18Ofluid values range from 5.9 to 7.5 per mil, whereas ??Dfluid values calculated from the dehydration of muscovite grains and measured directly from bulk fluid inclusion analyses of stage II gray quartz have ranges of -9 to -35 and -27 to -28 per mil, respectively. Hydrothermal ore fluids were transported from greater crustal depths to the site of gold deposition during the district-scale D3 event by shallowly W dipping, reverse brittle-ductile shear zones in supracrustal rock and along the steeply east dipping trondhjemite contact. Associated subhorizontal east-west shortening caused the reactivation of the eastern trondhjemite margin and subparallel foliation, which facilitated the transport of hydrothermal fluids and the generation of gold-bearing veins and hydrothermal alteration zones in komatiite. East-west-striking fractures in trondhjemite aided the lateral migration of ore fluids away from trondhjemite margins and the formation of east-west-striking gold-bearing veins and broad alteration zones. Gold was most likely transported in the stage II fluid as bisulfide complexes. The sulfidation of trondhjemite and komatiite wall rock by the stage II fluid caused the destabilization of An bisulfide complexes and gold deposition. Potassium, Ca, and CO2 metasomatism of komatiite wall rock may have enhanced gold deposition via the acidification of the stage II fluid. The physicochemical characteristics of the Tarmoola ore fluid and relative timing of gold mineralization are consistent with the Yilgarn-wide,

Economic Geology↗

Evolution of volcanic rocks and associated ore deposits in the Marysvale volcanic field, Utah

A geological account on the igneous activity and associated mineral deposition in the volcanic field of Marysvale in Utah is presented. Three episodes (34-22 Ma, 22-14 Ma and 9-5 Ma) involved in the volcanic rock eruption and associated mineralization are described. The first episode is believed to have occurred during the time of tectonic convergence when two contrasting suites of rocks, Mount Dutton Formation and Bullion Canyon Volcanics, erupted concurrently. Mineralization during this period was sparse. In the second episode, change from intermediate to bimodal volcanism occurred. During the third episode, basaltic compositions did not change. Although major element constituent had rhyolites similar to that of the second episode, rhyolites had a marked radiogenic isotope characteristic difference.

Utah↗

The Kanuti ophiolite, Alaska

The Kanuti ophiolite is a mafic-ultramafic thrust sheet of probable Jurassic age, formerly considered to be the upper part of the Yukon-Koyukuk ophiolite belt (Angayucham terrane). It is here called the Kanuti ophiolite after the Kanuti River region on the southeastern flank of the Yukon-Koyukuk Basin. The thrust sheet crops out discontinuously for a distance of more than 900 km along the northern and southeastern margins of the basin. It is probably correlative with similar ophiolite thrust sheets to the north in the western Brooks Range and to the south in the Ruby geanticline. Technically, the ophiolite is considered to be the Kanuti thrust panel of the Angayucham-Totzitna terrane. The Kanuti consistently overlies another extensive thrust sheet, consisting mostly of pillow basalt and radiolarian chert of Devonian to Jurassic age (Narvak thrust panel). This sheet is thrust over a third sheet consisting of probable Devonian phyllite and metagraywacke, which is in turn thrust over older metamorphic rocks (Slate Creek thrust panel). The Kanuti ophiolite is a partial ophiolite that consists of a lower residual mantle suite and an upper magmatic suite, but dikes, extrusives, and sediments are absent. The residual mantle suite is composed of harzburgite and dunite with refractory mineral compositions. The harzburgite is attributed to partial melting and extraction of basaltic magma; residual dunite is attributed to partial melting or to reaction of orthopyroxene out of harzburgite in contact with ascending melt diapirs. The magmatic suite consists of layered ultramafic and gabbroic rocks, containing minerals having limited iron enrichment. The absence of large volumes of magmatic rocks intermediate in composition between cumulus ultramafics and evolved gabbros favors periodic introduction of magma, rather than closed system fractional crystallization. The ultramafic rocks of both the residual mantle and magmatic suites are tectonites, which have undergone high-temperature deformation involving isoclinal folding on all scales and related syntectonic recrystallization. The olivine fabric is consistent with the glide system {0kl} [100], which has been produced experimentally at 800°–1190°C at 20 kbar. Olivine Z axes and subparallel isoclinal fold axes have consistent, northeast trends throughout the Kanuti region (>100 km NE-SW) and may be close to the original upper mantle flow direction, despite later low-angle thrust faulting. The order of crystallization in the cumulus ultramafic rocks of the magmatic suite is olivine, clinopyroxene, plagioclase, and orthopyroxene. The high Mg numbers of clinopyroxene (0.85–0.93) coexisting with olivine suggest that the cumulus ultramafic rocks crystallized at relatively high pressures (>10 kbar). The effects of parental magma composition cannot be evaluated, but the small difference in Mg numbers of coexisting olivine and clinopyroxene in the cumulus ultramafic rocks and in residual harzburgite suggests that regardless of absolute pressures, the pressure difference between the melting that produced the basalt magma and the initial fractional crystallization of the magma is small. Because of the limited range in rock types in the ophiolite, the tectonic environment cannot be interpreted unambiguously. However, the structural and petrological data are best reconciled with an origin in a volcanic arc tectonic setting.

Journal of Geophysical Research Solid Earth↗