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At least 1,027 records · Page 57Linked to original sources

Testing alternative conceptual models of seawater intrusion in a coastal aquifer using computer simulation, southern California, USA

Two alternative conceptual models of the physical processes controlling seawater intrusion in a coastal basin in California, USA, were tested to identify a likely principal pathway for seawater intrusion. The conceptual models were tested by using a two-dimensional, finite-element groundwater flow and transport model. This pathway was identified by the conceptual model that best replicated the historical data. The numerical model was applied in cross section to a submarine canyon that is a main avenue for seawater to enter the aquifer system underlying the study area. Both models are characterized by a heterogeneous, layered, water-bearing aquifer. However, the first model is characterized by flat-lying aquifer layers and by a high value of hydraulic conductivity in the basal aquifer layer, which is thought to be a principal conduit for seawater intrusion. The second model is characterized by offshore folding, which was modeled as a very nearshore outcrop, thereby providing a shorter path for seawater to intrude. General conclusions are that: 1) the aquifer system is best modeled as a flat, heterogeneous, layered system; 2) relatively thin basal layers with relatively high values of hydraulic conductivity are the principal pathways for seawater intrusion; and 3) continuous clay layers of low hydraulic conductivity play an important role in controlling the movement of seawater.

Hydrogeology Journal↗

Suspected microbial-induced sedimentary structures (MISS) in Furongian (Upper Cambrian; Jiangshanian, Sunwaptan) strata of the Upper Mississippi Valley

The Furongian (Upper Cambrian; Jiangshanian and Sunwaptan) Tunnel City Group (Lone Rock Formation and Mazomanie Formation), exposed in Wisconsin and Minnesota, represents a shallow-marine clastic environment during a time of exceptionally high sea level. Lithofacies from shoreface to transitional-offshore settings document deposition in a wave- and storm-dominated sea. Flooding of the cratonic interior was associated with formation of a condensed section and the extensive development of microbial mats. Biolamination, mat fragments, wrinkle structures, and syneresis cracks are preserved in various sandstone facies of the Lone Rock Formation, as is evidence for the cohesive behavior of sand. These microbial-induced sedimentary structures (MISS) provide unique signals of biological–physical processes that physical structures alone cannot mimic. The MISS are associated with a trilobite extinction event in the Steptoean–Sunwaptan boundary interval. This may support recent claims that Phanerozoic microbial mats were opportunistic disaster forms that flourished during periods of faunal turnover. Further investigation of stratigraphic, taphonomic, and other potential biases, however, is needed to fully test this hypothesis.

Minnesota;Wisconsin↗

Stock composition of Atlantic sturgeon (Acipenser oxyrinchus oxyrinchus) encountered in marine and estuarine environments on the U.S. Atlantic Coast

Atlantic sturgeon ( Acipenser oxyrinchus oxyrinchus ) is a large, anadromous fish native to the Atlantic Coast of North America. Although this species once supported important fisheries, centuries of exploitation and habitat degradation have resulted in dramatic declines, presumed extirpation in some rivers, and ultimately listing under the U.S. Endangered Species Act (ESA). Under the ESA, Atlantic sturgeon are listed as five separate Distinct Population Segments (DPSs), which form the basis for federal management. Despite state and federal protections Atlantic sturgeon still face significant threats to their recovery, including fisheries bycatch mortality, marine construction, dredging, dams, and vessel strikes. However, because subadult and adult Atlantic sturgeon migrate extensively across estuarine and marine environments and frequently form mixed-stock aggregations in non-natal habitats, it can be difficult to determine how these threats impact specific populations and DPSs. To better understand ontogenetic shifts in habitat use and stock-specific exposure to anthropogenic threats, we performed a mixed-stock analysis of 1704 Atlantic sturgeon encountered across the U.S. Atlantic Coast. Collections made north of Cape Cod, MA and south of Cape Hatteras, NC were dominated by individuals from regional stocks; however, we found extensive stock mixing in the mid-Atlantic region, particularly in coastal environments where individuals from all five DPSs were commonly observed. Subadults and adults that were encountered in offshore environments had moved, on average, 277 km from their natal source; however, 23% were sampled over 500 km from their natal river suggesting long-distance movements are relatively common in these age classes. Overall, our work highlights that Atlantic sturgeon populations are vulnerable to threats over vast areas and emphasizes the need for continued genetic monitoring to track recovery progress.

Atlantic Coast↗

Feeding habitats of the Gulf sturgeon, Acipenser oxyrinchus desotoi, in the Suwannee and Yellow rivers, Florida, as identified by multiple stable isotope analyses

Stable 13 C, 15 N, and 34 S isotopes were analyzed to define the feeding habitats of Acipenser oxyrinchus desotoi in the Suwannee and Yellow River populations. For the majority (93.9%) of Suwannee subadults and adults, 13 C and 34 S signatures indicate use of nearshore marine waters as primary winter feeding habitat, probably due to the limiting size of the Suwannee Sound estuary. In the Yellow River population, 13 C isotope signatures indicate that adults remain primarily within Pensacola Bay estuary to feed in winter, rather than emigrating to the open Gulf of Mexico. A minor Suwannee River subset (6% of samples), comprised of juveniles and subadults, displayed 13 C signatures indicating continued feeding in freshwater during the spring immigration and fall emigration periods. This cannot be interpreted as incidental feeding since it resulted in a 20.5% turnover in tissue δ 13 C signatures over a 1–3 month period. Cessation of feeding in the general population does not coincide with high river water temperatures. The hypothesis of reduced feeding in freshwater due to localized prey depletion as a result of spatial activity restriction is not supported by the present study. Instead, Suwannee River A. o. desotoi appear to follow two trophic alternatives; 1) complete cessation of feeding immediately upon immigration in spring, continuing through emigration 8–9 months later (the predominant alternative); 2) continued intensive feeding for 1–3 months following immigration, switching to freshwater prey, selected primarily from high trophic levels (i.e., large prey). Stable – 34 S data verifies that recently immigrated, fully-anadromous A. o. desotoi adults had fed in nearshore marine waters, not offshore waters.

Florida↗

Continued feeding on Diporeia by deepwater sculpin in Lake Huron

Monitoring changes in diets of fish is essential to understanding how food web dynamics respond to changes in native prey abundances. In the Great Lakes, Diporeia, a benthic macroinvertebrate and primary food of native benthivores, declined following the introduction of invasive Dreissena mussels and these changes were reflected in fish diets. We examined the diets of deepwater sculpin Myoxocephalus thompsonii collected in bottom trawls during 2010–2014 in the main basin of Lake Huron, and compared these results to an earlier diet study (2003–2005) to assess if their diets have continued to change after a prolonged period of Dreissena mussel invasion and declined Diporeia densities. Diporeia , Mysis , Bythotrephes , and Chironomidae were consumed regularly and other diet items included ostracods, copepods, sphaerid clams, and fish eggs. The prey-specific index of relative importance calculated for each prey group indicated that Mysis importance increased at shallow (≤55 m) and mid (64–73 m) depths, while Diporeia importance increased offshore (≥82 m). The average number of Diporeia consumed per fish increased by 10.0% and Mysis decreased by 7.5%, while the frequency of occurrence of Diporeia and Mysis remained comparable between time periods. The weight of adult deepwater sculpin (80 mm and 100 mm TL bins) increased between time periods; however, the change in weight was only significant for the 80 mm TL group ( p < 0.01). Given the historical importance of Diporeia in the Great Lakes, the examination of deepwater sculpin diets provides unique insight into the trophic dynamics of the benthic community in Lake Huron.

Environmental Biology of Fishes↗

Occurrence, distribution and transport of pesticides into the Salton Sea Basin, California, 2001-2002

The Salton Sea is a hypersaline lake located in southeastern California. Concerns over the ecological impacts of sediment quality and potential human exposure to dust emissions from exposed lakebed sediments resulting from anticipated shrinking of shoreline led to a study of pesticide distribution and transport within the Salton Sea Basin, California, in 2001-2002. Three sampling stations-upriver, river mouth, and offshore-were established along each of the three major rivers that discharge into the Salton Sea. Large-volume water samples were collected for analysis of pesticides in water and suspended sediments at the nine sampling stations. Samples of the bottom sediment were also collected at each site for pesticide analysis. Sampling occurred in October 2001, March-April 2002, and October 2002, coinciding with the regional fall and spring peaks in pesticide use in the heavily agricultural watershed. Fourteen current-use pesticides were detected in water and the majority of dissolved concentrations ranged from the limits of detection to 151 ng/l. Diazinon, EPTC and malathion were detected at much higher concentrations (940-3,830 ng/l) at the New and Alamo River upriver and near-shore stations. Concentrations of carbaryl, dacthal, diazinon, and EPTC were higher in the two fall sampling periods, whereas concentrations of atrazine, carbofuran, and trifluralin were higher during the spring, which matched seasonal use patterns of these pesticides. Current-use pesticides were also detected on suspended and bed sediments in concentrations ranging from detection limits to 106 ng/g. Chlorpyrifos, dacthal, EPTC, trifluralin, and DDE were the most frequently detected pesticides on sediments from all three rivers. The number of detections and concentrations of suspended sediment-associated pesticides were often similar for the river upriver and near-shore sites, consistent with downstream transport of pesticides via suspended sediment. While detectable suspended sediment pesticide concentrations were more sporadic than detected aqueous concentrations, seasonal trends were similar to those for dissolved concentrations. Generally, the pesticides detected on suspended sediments were the same as those on the bed sediments, and concentrations were similar, especially at the Alamo River upriver site. With a few exceptions, pesticides were not detected in suspended or bed sediments from the off-shore sites. The partitioning of pesticides between water and sediment was not predictable from solely the physical-chemical properties of individual pesticide compounds, but appear to be a complicated function of the quantity of pesticide applied in the watershed, residence time of sediments in the water, and compound solubility and hydrophobicity. Sediment concentrations of most pesticides were found to be 100-1,000 times lower than the low-effects levels determined in human health risk assessment studies. However, maximum concentrations of chlorpyrifos on suspended sediments were approximately half the low-effects level, suggesting the need for further sediment characterization of lake sediments proximate to riverine inputs. ?? 2008 Springer Science+Business Media B.V.

Hydrobiologia↗

High-resolution surveys for geohazards and shallow gas: NW Adriatic (Italy) and Iskenderun Bay (Turkey)

The need for quantifying and understanding the distribution of shallow gas is both of academic interest and of relevance to offshore facilities. The combination of seafloor mapping, subbottom profiling, and multi-channel seismic data can provide information on regions of possible shallow gas, where the gas impacts the acoustic properties of the host material and the seafloor. In this paper, we present two case studies - one academic and one industry - that evaluate the distribution of shallow gas in two field areas in the Mediterranean. In the first case study, geophysical data from Iskenderun Bay, southeastern Turkey, indicate the presence and distribution of shallow gas. Pockmarks on the seafloor are associated with acoustic wipeout in the shallow subbottom data. Although deeper seismic data do not show bright spots or other indicators of possible gas, instantaneous frequency analysis clearly shows laterally restricted anomalies indicating gas-rich zones. The interpretation of possible shallow gas resulted in moving a proposed drilling location to a nearby area characterized by fewer (but still present) shallow gas signatures. In the second case study, cores acquired in the Po Delta, Adriatic Sea, provide quantitative ground-truthing of shallow gas - as suggested by geophysical data - and provide minimum estimates of the percentage of gas in the subsurface. Cores targeted on anomalous subbottom data yielded up to 41,000 ppm methane; cores with anomalous gas content are associated with thick recent flood deposits which may effectively isolate reactive terrigenous organic matter from biologic and physical re-working. ?? Springer 2005.

Marine Geophysical Research↗

Risk, liability, and economic issues with long-term CO 2 storage—A review

Given a scarcity of commercial-scale carbon capture and storage (CCS) projects, there is a great deal of uncertainty in the risks, liability, and their cost implications for geologic storage of carbon dioxide (CO 2 ). The probabilities of leakage and the risk of induced seismicity could be remote, but the volume of geologic CO 2 storage (GCS) projected to be necessary to have a significant impact on increasing CO 2 concentrations in the atmosphere is far greater than the volumes of CO 2 injected thus far. National-level estimates of the technically accessible CO 2 storage resource (TASR) onshore in the United States are on the order of thousands of gigatons of CO 2 storage capacity, but such estimates generally assume away any pressure management issues. Pressure buildup in the storage reservoir is expected to be a primary source of risk associated with CO 2 storage, and only a fraction of the theoretical TASR could be available unless the storage operator extracts the saltwater brines or other formation fluids that are already present in the geologic pore space targeted for CO 2 storage. Institutions, legislation, and processes to manage the risk, liability, and economic issues with CO 2 storage in the United States are beginning to emerge, but will need to progress further in order to allow a commercial-scale CO 2 storage industry to develop in the country. The combination of economic tradeoffs, property rights definitions, liability issues, and risk considerations suggests that CO 2 storage offshore of the United States may be more feasible than onshore, especially during the current (early) stages of industry development.

Natural Resources Research↗

Tsunami impact to Washington and northern Oregon from segment ruptures on the southern Cascadia subduction zone

This paper explores the size and arrival of tsunamis in Oregon and Washington from the most likely partial ruptures of the Cascadia subduction zone (CSZ) in order to determine (1) how quickly tsunami height declines away from sources, (2) evacuation time before significant inundation, and (3) extent of felt shaking that would trigger evacuation. According to interpretations of offshore turbidite deposits, the most frequent partial ruptures are of the southern CSZ. Combined recurrence of ruptures extending ~490 km from Cape Mendocino, California, to Waldport, Oregon (segment C) and ~320 km from Cape Mendocino to Cape Blanco, Oregon (segment D), is ~530 years. This recurrence is similar to frequency of full-margin ruptures on the CSZ inferred from paleoseismic data and to frequency of the largest distant tsunami sources threatening Washington and Oregon, ~M w 9.2 earthquakes from the Gulf of Alaska. Simulated segment C and D ruptures produce relatively low-amplitude tsunamis north of source areas, even for extreme (20 m) peak slip on segment C. More than ~70 km north of segments C and D, the first tsunami arrival at the 10-m water depth has an amplitude of <1.9 m. The largest waves are trapped edge waves with amplitude ≤4.2 m that arrive ≥2 h after the earthquake. MM V–VI shaking could trigger evacuation of educated populaces as far north as Newport, Oregon for segment D events and Grays Harbor, Washington for segment C events. The NOAA and local warning systems will be the only warning at greater distances from sources.

Oregon;Washington↗

New constraints on coseismic slip during southern Cascadia subduction zone earthquakes over the past 4600 years implied by tsunami deposits and marine turbidites

Forecasting earthquake and tsunami hazards along the southern Cascadia subduction zone is complicated by uncertainties in the amount of megathrust fault slip during past ruptures. Here, we estimate slip on hypothetical ruptures of the southern part of the megathrust through comparisons of late Holocene Cascadia earthquake histories derived from tsunami deposits on land and marine turbidites offshore. Bradley Lake in southern Oregon lies ~600 m landward of the shoreline and contains deposits from 12 tsunamis in the past 4600 years. Tsunami simulations that overtop the 6-m-high lake outlet, generated by ruptures with most slip south of Cape Blanco, require release of at least as much strain on the megathrust as would accumulate in 430–640 years (>15–22 m). Such high slip is inconsistent with global seismic data for a rupture ~300-km long and slip deficits over the past ~4700 years on the southern Cascadia subduction zone. Assuming slip deficits accumulated during the time intervals between marine turbidites, up to 8 of 12 tsunami inundations at the lake are predicted from a marine core site 170 km north of the lake (at Hydrate Ridge) compared to 4 of 12 when using a core site ~80 km south (at Rogue Apron). Longer time intervals between turbidites at Hydrate Ridge imply larger slip deficits compared to Rogue Apron. The different inundations predicted by the two records suggest that Hydrate Ridge records subduction ruptures that extend past both Rogue Apron and Bradley Lake. We also show how turbidite-based estimates of CSZ rupture length relate to tsunami source scenarios for probabilistic tsunami hazard assessments consistent with lake inundations over the last ~4600 years.

Oregon↗

Learnings from rapid response efforts to remotely detect landslides triggered by the August 2021 Nippes earthquake and Tropical Storm Grace in Haiti

On August 14, 2021, a Mw 7.2 earthquake struck the Tiburon Peninsula of western Haiti triggering thousands of landslides. Three days after the earthquake on August 17, 2021, Tropical Storm Grace crossed shallow waters offshore of southern Haiti triggering more landslides worsening the situation. In the aftermath of these events, several organizations with disaster response capabilities or programs activated to provide information on the location of landslides to first responders on the ground. Utilizing remote sensing to support rapid response, one organization manually mapped initiation point of landslides and three automatically detected landslides. The 2021 Haiti event also provided a unique opportunity to test different automated landslide detection methods that utilized both SAR and optical data in a rapid response scenario where rapid situational awareness was critical. As the methods used are highly replicable, the main goal of this study is to summarize the landslide rapid response products released by the organizations, detection methods, quantify accuracy and provide guidelines on how some of the shortcomings encountered in this effort might be addressed in the future. To support this validation, a manually mapped polygon-based landslide inventory covering the entire affected area was created and is also released through this effort.

Natural Hazards↗

Towards vibrant fish populations and sustainable fisheries that benefit all: Learning from the last 30 years to inform the next 30 years

A common goal among fisheries science professionals, stakeholders, and rights holders is to ensure the persistence and resilience of vibrant fish populations and sustainable, equitable fisheries in diverse aquatic ecosystems, from small headwater streams to offshore pelagic waters. Achieving this goal requires a complex intersection of science and management, and a recognition of the interconnections among people, place, and fish that govern these tightly coupled socioecological and sociotechnical systems. The World Fisheries Congress (WFC) convenes every four years and provides a unique global forum to debate and discuss threats, issues, and opportunities facing fish populations and fisheries. The 2021 WFC meeting, hosted remotely in Adelaide, Australia, marked the 30th year since the first meeting was held in Athens, Greece, and provided an opportunity to reflect on progress made in the past 30 years and provide guidance for the future. We assembled a diverse team of individuals involved with the Adelaide WFC and reflected on the major challenges that faced fish and fisheries over the past 30 years, discussed progress toward overcoming those challenges, and then used themes that emerged during the Congress to identify issues and opportunities to improve sustainability in the world's fisheries for the next 30 years. Key future needs and opportunities identified include: rethinking fisheries management systems and modelling approaches, modernizing and integrating assessment and information systems, being responsive and flexible in addressing persistent and emerging threats to fish and fisheries, mainstreaming the human dimension of fisheries, rethinking governance, policy and compliance, and achieving equity and inclusion in fisheries. We also identified a number of cross-cutting themes including better understanding the role of fish as nutrition in a hungry world, adapting to climate change, embracing transdisciplinarity, respecting Indigenous knowledge systems, thinking ahead with foresight science, and working together across scales. By reflecting on the past and thinking about the future, we aim to provide guidance for achieving our mutual goal of sustaining vibrant fish populations and sustainable fisheries that benefit all. We hope that this prospective thinking can serve as a guide to (i) assess progress towards achieving this lofty goal and (ii) refine our path with input from new and emerging voices and approaches in fisheries science, management, and stewardship.

Reviews in Fish Biology and Fisheries↗

Quantifying the residence time and flushing characteristics of a shallow, back-barrier estuary: Application of hydrodynamic and particle tracking models

Estuarine residence time is a major driver of eutrophication and water quality. Barnegat Bay-Little Egg Harbor (BB-LEH), New Jersey, is a lagoonal back-barrier estuary that is subject to anthropogenic pressures including nutrient loading, eutrophication, and subsequent declines in water quality. A combination of hydrodynamic and particle tracking modeling was used to identify the mechanisms controlling flushing, residence time, and spatial variability of particle retention. The models demonstrated a pronounced northward subtidal flow from Little Egg Inlet in the south to Pt. Pleasant Canal in the north due to frictional effects in the inlets, leading to better flushing of the southern half of the estuary and particle retention in the northern estuary. Mean residence time for BB-LEH was 13 days but spatial variability was between ∼0 and 30 days depending on the initial particle location. Mean residence time with tidal forcing alone was 24 days (spatial variability between ∼0 and 50 days); the tides were relatively inefficient in flushing the northern end of the Bay. Scenarios with successive exclusion of physical processes from the models revealed that meteorological and remote offshore forcing were stronger drivers of exchange than riverine inflow. Investigations of water quality and eutrophication should take into account spatial variability in hydrodynamics and residence time in order to better quantify the roles of nutrient loading, production, and flushing.

Estuaries and Coasts↗

Field observations of wind waves in Upper Delaware Bay with living shorelines

Constructed oyster reefs (CORs) provide shore protections and habitats for fish and shellfish communities via wave energy attenuation. However, the processes and mechanism of CORs on wave attenuation remain unclear, thus limiting the effective assessment of CORs for shoreline protection. This paper presents results of a field investigation on wave characteristics and wave spectral variations along a shoreline with CORs in an estuary with a large tidal range as well as large wind waves and swell energy. Six pressure transducers were deployed from January 31 to April 2, 2018, in Gandy’s Beach, New Jersey, in upper Delaware Bay. CORs were constructed at the study site in 2016 as living shoreline structures after Hurricane Sandy. The data collected from the study site exhibits the wave variations and spectral characteristics over the span of 2 months, including four winter storms (i.e., nor’easters). The spatial variations of wave heights measured on both sides of CORs show a strong dependence on the ratio between the freeboard of CORs and the offshore wave heights. Due to the large tidal range (> 2 m), the crests of CORs remain submerged over 85% of the time. The submerged CORs only provide partial attenuation of wave energy. The wave environment in the estuary is complex, especially during nor’easters. For instance, winds with rapid changing fetches could lead to bi-modal wind seas. Due to the complex wave spectra, the bulk wave heights such as the significant wave heights cannot be adopted to adequately reveal the capacity of CORs to attenuate wave energy. Spectral analysis is conducted to investigate the spatial and temporal variations of wave energy in targeted frequency bins. The spectral analysis results reveal the energy transfer from the primary waves to the high harmonics after waves propagate over the submerged CORs. Moreover, it is found that swell energy originated from the Atlantic Ocean can penetrate CORs without any dampening even when CORs are emergent. This study could help resource managers for in-depth evaluation of living shoreline effectiveness and improvement of living shoreline structures such as CORs.

Delaware, New Jersey↗

Sediment budget estimates for a highly impacted embayment with extensive wetland loss

External sediment supply is an important control on wetland morphology and vulnerability to storms, sea-level rise, and land use change. Constraining sediment supply and net budgets is difficult due to multiple timescales of variability in hydrodynamic forcing and suspended-sediment concentrations, as well as the fundamental limitations of measurement and modeling technologies. We used two independent observational campaigns and one hydrodynamic modeling effort to estimate the sediment supply to Jamaica Bay, New York, USA, an urbanized embayment with a history of extensive wetland loss. We found that all three estimates indicate a net import to the system, ranging from 36 x 106 – 74 x 106 kg/y, with a mean estimate of 55,000 t/y +/- 31,000 t/y, which compares well with a prior estimate derived from radionuclide tracers. Net sediment import is controlled by flood-ebb asymmetry in bed shear stress, which results in higher suspended sediment concentrations on flood tide relative to ebb. This indicates a seaward source of sediment, likely offshore marine deposits and potentially sediment from the adjacent Hudson River-Estuary that is resuspended by waves in the coastal ocean. Despite the net sediment import, a simple sediment budget suggests that the rate of supply is not sufficient to maintain the present geomorphic planform of the system relative to sea-level rise. The convergent estimates from independent methods provide reasonable guidance as context for sediment-based restoration efforts.

New York↗

Genetic structure and diversity of the mustard hill coral Porites astreoides along the Florida Keys reef tract

Increases in local and global stressors have led to major declines in coral populations throughout the western Atlantic. While abundances of other species have declined, however, the relative abundance of the mustard hill coral, Porites astreoides , has increased. Porites astreoides is relatively resilient to some stressors, and because of its mixed reproductive strategies, its populations often recover quickly following disturbances. The ability for P. astreoides to continue as a potential “winner” in western Atlantic reefs relies on maintaining sufficient genetic variation within populations to support acclimatization and adaptation to current and future environmental change. Without high genetic diversity and gene flow within the population, it would have limited capacity for adaptation and the species’ competitive advantages could be short-lived. In this study, we determined the genetic relatedness of 37 P. astreoides colonies at four shallow reefs along the offshore Florida Keys Reef Tract (FKRT), a region particularly hard-hit by recent disturbances. Using previously designed microsatellite markers, we determined the genetic diversity and connectivity of individuals among and between sites. Our results suggest that the FKRT likely contains a single, well-mixed genetic population of P. astreoides , with high levels of gene flow and evidence for larval migration throughout the region. This suggests that regional populations of P. astreoides likely have a higher chance of maintaining resilience than many other western Atlantic species as they face current and future disturbances.

Florida↗

Geochemistry of pore waters from Shell Oil Company drill holes on the continental slope of the northern Gulf of Mexico

Pore waters were analyzed from 6 holes drilled from M.V. “Eureka” as a part of the Shell Oil Co. deeper offshore study. The holes were drilled in water depths of 600–3,000 ft. (approximately 180–550 m) and penetrated up to 1,000 ft. (300 m) of Pliocene-Recent clayey sediments. Salt and anhydrite caprock was encountered in one diapiric structure on the continental slope. Samples from holes drilled near diapiric structures showed systematic increases of pore-water salinity with depth, suggestive of salt diffusion from underlying salt plugs. Anomalous concentrations of K and Br indicate that at least one plug contains late-stage evaporite minerals. Salinities approaching halite saturation were observed. Samples from holes away from diapiric structures showed little change in pore-water chemistry, except for loss of SO 4 and other variations attributable to early-stage diagenetic reactions with enclosing sediments. Thus, increased salt concentrations in even shallow sediments from this part of the Gulf appear to provide an indicator of salt masses at depth.

Chemical Geology↗

Hydrocarbon-water interactions during brine migration: Evidence from hydrocarbon inclusions in calcite cements from Danish North Sea oil fields

Crude oils in primary and secondary fluid inclusions in calcite from fractures in seven offshore oil fields associated with diapiric salt structures in the Danish sector of the North Sea were analyzed by capillary column gas chromatography and compared with crude oils produced from the same reservoirs. Oils from fluid inclusions in all fields show evidence of biodegradation (decreased n - C 17 /pristane and n - C 18 /phytane ratios and loss of n-C 7 , 2-methyl hexane, and 3-methyl hexane relative to methyl cyclohexane) and water washing (absence of benzene and depletion of toluene). Some oils in inclusions are extremely enriched in C 6 and C 7 cyclic alkanes suggesting that these samples contain hydrocarbons exsolved from ascending, hotter formation waters. Compared to inclusion oils the produced oils are less biodegraded, but are water washed, indicating that both types of oil interacted with large volumes of formation water. The carbon isotopic composition of the calcite host of the fluid inclusions in the Dagmar and Skjold fields is as light as −16.5%. PDB and the sulfur isotopic composition of pyrite in and adjacent to the calcite veins in the Skjold field is as light as −39.6%. CDT, indicating that biodegradation of the oils was a source of some of the carbon in the calcite and sulfate reduction was the source of sulfur for the pyrite. The evidence for microbial degradation of petroleum is consistent with present-day reservoir temperatures (65°–96°C) but is not consistent with previous estimates of the temperatures of calcite vein filling (95°–130°C) which are much higher than the temperatures of known occurrences of biodegraded oil.

Geochimica et Cosmochimica Acta↗