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Detection of crystalline hematite mineralization on Mars by the Thermal Emission Spectrometer: evidence for near-surface water

The Thermal Emission Spectrometer (TES) instrument on the Mars Global Surveyor (MGS) mission has discovered a remarkable accumulation of crystalline hematite (α-Fe 2 O 3 ) that covers an area with very sharp boundaries approximately 350 by 350–750 km in size centered near 2°S latitude between 0° and 5°W longitude (Sinus Meridiani). Crystalline hematite is uniquely identified by the presence of fundamental vibrational absorption features centered near 300, 450, and >525 cm −1 and by the absence of silicate fundamentals in the 1000 cm −1 region. Spectral features resulting from atmospheric CO 2 , dust, and water ice were removed using a radiative transfer model. The spectral properties unique to Sinus Meridiani were emphasized by removing the average spectrum of the surrounding region. The depth and shape of the hematite fundamental bands show that the hematite is crystalline and relatively coarse grained (>5–10 μm). Diameters up to and greater than hundreds of micrometers are permitted within the instrumental noise and natural variability of hematite spectra. Hematite particles <5–10 μm in diameter (as either unpacked or hard-packed powders) fail to match the TES spectra. The spectrally derived areal abundance of hematite varies with particle size from ∼10% (>30 μm diameter) to 40–60% (10 μm diameter). The hematite in Sinus Meridiani is thus distinct from the fine-grained (diameter <5–10 μm), red, crystalline hematite considered, on the basis of visible, near-IR data, to be a minor spectral component in Martian bright regions like Olympus-Amazonis. Sinus Meridiani hematite is closely associated with a smooth, layered, friable surface that is interpreted to be sedimentary in origin. This material may be the uppermost surface in the region, indicating that it might be a late stage sedimentary unit or a layered portion of the heavily cratered plains units. We consider five possible mechanisms for the formation of coarse-grained, crystalline hematite. These processes fall into two classes depending on whether they require a significant amount of near-surface water: the first is chemical precipitation that includes origin by (1) precipitation from standing, oxygenated, Fe-rich water (oxide iron formations), (2) precipitation from Fe-rich hydrothermal fluids, (3) low-temperature dissolution and precipitation through mobile ground water leaching, and (4) formation of surface coatings, and the second is thermal oxidation of magnetite-rich lavas. Weathering and alteration processes, which produce nanophase and red hematite, are not consistent with the coarse, crystalline hematite observed in Sinus Meridiani. We prefer chemical precipitation models and favor precipitation from Fe-rich water on the basis of the probable association with sedimentary materials, large geographic size, distance from a regional heat source, and lack of evidence for extensive groundwater processes elsewhere on Mars. The TES results thus provide mineralogic evidence for probable large-scale water interactions. The Sinus Meridiani region may be an ideal candidate for future landed missions searching for biotic and prebiotic environments, and the physical characteristics of this site satisfy all of the engineering requirements for the missions currently planned.

Journal of Geophysical Research E: Planets↗

Structural evidence for northeastward movement on the Chocolate Mountains Thrust, southeasternmost California

The Late Cretaceous Chocolate Mountains thrust of southeastern California and southwestern Arizona places a block of Proterozoic and Mesozoic continental crust over the late Mesozoic continental margin oceanic sedimentary and volcanic rocks of the regionally distinctive Orocopia Schist. The Chocolate Mountains thrust is interpreted as a thrust (burial, subduction) fault rather than a low-angle normal (exhumation, unroofing, uplift) fault. An important parameter required to understand the tectonic significance of the Chocolate Mountains and related thrusts is their sense of movement. The Chocolate Mountains thrust zone contains sparse to locally abundant mesoscopic asymmetric folds. Fabric relations, supported by regional geologic evidence, indicate that these folds are an integral part of and coeval with the thrust zone. On a lower hemisphere equal-area plot representing the orientation and sense of asymmetry of 80 thrust zone folds from 36 localities, spread over an area 60 by 10 km, Z folds plot northwest of and S folds plot southeast of a northeast-southwest striking vertical plane of overall monoclinic symmetry. The only sense of movement consistent with the collective asymmetry of the thrust zone folds is top to the northeast. Asymmetric microstructures studied at several localities also indicate top to the northeast movement. Paleomagnetic data suggest that the original sense of thrusting, prior to Neogene vertical axis tectonic rotation related to the San Andreas fault system, was northward. The essential point is that movement of the upper plate of the Chocolate Mountains thrust evidently was continentward. Continentward thrusting suggests a tectonic scenario in which an insular or peninsular microcontinental fragment collided with mainland southern California. The suture predicted by this model is elusive; but the Chocolate Mountains thrust and underlying Orocopia Schist themselves may represent the suture, at the present level of exposure. Alternative tectonic models involving subduction of the Orocopia Schist eastward beneath continental southern California circumvent the suture problem but are presently not supported by any direct structural evidence.

Journal of Geophysical Research↗

Geospatial resources for the geologic community: The USGS National Map

Geospatial data are a key component of investigating, interpreting, and communicating the geological sciences. Locating geospatial data can be time-consuming, which detracts from time spent on a study because these data are not obviously placed in central locations or are served from many disparate databases. The National Map of the US Geological Survey is a publicly available resource for accessing the geospatial base map data needs of the geological community from a central location. The National Map data are available through a viewer and download platform providing access to eight primary data themes, plus the US Topo and scanned historical topographic maps. The eight themes are elevation, orthoimagery, hydrography, geographic names, boundaries, transportation, structures, and land cover, and they are being offered for download as predefined tiles in formats supported by leading geographic information system software. Data tiles are periodically refreshed to capture the most current content and are an efficient method for disseminating and receiving geospatial information. Elevation data, for example, are offered as a download from the National Map as 1&deg; &times; 1&deg; tiles for the 10- and 30- m products and as 15&prime; &times; 15&prime; tiles for the higher-resolution 3-m product. Vector data sets with smaller file sizes are offered at several tile sizes and formats. Partial tiles are not a download option&mdash;any prestaged data that intersect the requesting bounding box will be, in their entirety, part of the download order. While there are many options for accessing geospatial data via the Web, the National Map represents authoritative sources of data that are documented and can be referenced for citation and inclusion in scientific publications. Therefore, National Map products and services should be part of a geologist&rsquo;s first stop for geospatial information and data.

Journal of Geology↗

Diatoms in sediments of perennially ice-covered Lake Hoare, and implications for interpreting lake history in the McMurdo Dry Valleys of Antarctica

Diatom assemblages in surficial sediments, sediment cores, sediment traps, and inflowing streams of perennially ice-covered Lake Hore, South Victorialand, Antarctica were examined to determine the distribution of diatom taxa, and to ascertain if diatom species composition has changed over time. Lake Hoare is a closed-basin lake with an area of 1.8 km2, maximum depth of 34 m, and mean depth of 14 m, although lake level has been rising at a rate of 0.09 m yr-1 in recent decades. The lake has an unusual regime of sediment deposition: coarse grained sediments accumulate on the ice surface and are deposited episodically on the lake bottom. Benthic microbial mats are covered in situ by the coarse episodic deposits, and the new surfaces are recolonized. Ice cover prevents wind-induced mixing, creating the unique depositional environment in which sediment cores record the history of a particular site, rather than a lake=wide integration. Shallow-water (<1 m) diatom assemblages (Stauroneis anceps, Navicula molesta, Diadesmis contenta var. parallela, Navicula peraustralis) were distinct from mid-depth (4-16 m) assemblages (Diadesmis contenta, Luticola muticopsis fo. reducta, Stauroneis anceps, Diadesmis contenta var. parallela, Luticola murrayi) and deep-water (2-31 m) assemblages (Luticola murrayi, Luticola muticopsis fo. reducta, Navicula molesta. Analysis of a sediment core (30 cm long, from 11 m water depth) from Lake Hoare revealed two abrupt changes in diatom assemblages. The upper section of the sediment core contained the greatest biomass of benthic microbial mat, as well as the greatest total abundance and diversity of diatoms. Relative abundances of diatoms in this section are similar to the surficial samples from mid-depths. An intermediate zone contained less organic material and lower densities of diatoms. The bottom section of core contained the least amount of microbial mat and organic material, and the lowest density of diatoms. The dominant process influencing species composition and abundance of diatom assemblages in the benthic microbial mats is episodic deposition of coarse sediment from the ice surface.

Journal of Paleolimnology↗

A geostatistical approach to predicting sulfur content in the Pittsburgh coal bed

The US Geological Survey (USGS) is completing a national assessment of coal resources in the five top coal-producing regions in the US. Point-located data provide measurements on coal thickness and sulfur content. The sample data and their geologic interpretation represent the most regionally complete and up-to-date assessment of what is known about top-producing US coal beds. The sample data are analyzed using a combination of geologic and Geographic Information System (GIS) models to estimate tonnages and qualities of the coal beds. Traditionally, GIS practitioners use contouring to represent geographical patterns of "similar" data values. The tonnage and grade of coal resources are then assessed by using the contour lines as references for interpolation. An assessment taken to this point is only indicative of resource quantity and quality. Data users may benefit from a statistical approach that would allow them to better understand the uncertainty and limitations of the sample data. To develop a quantitative approach, geostatistics were applied to the data on coal sulfur content from samples taken in the Pittsburgh coal bed (located in the eastern US, in the southwestern part of the state of Pennsylvania, and in adjoining areas in the states of Ohio and West Virginia). Geostatistical methods that account for regional and local trends were applied to blocks 2.7 mi (4.3 km) on a side. The data and geostatistics support conclusions concerning the average sulfur content and its degree of reliability at regional- and economic-block scale over the large, contiguous part of the Pittsburgh outcrop, but not to a mine scale. To validate the method, a comparison was made with the sulfur contents in sample data taken from 53 coal mines located in the study area. The comparison showed a high degree of similarity between the sulfur content in the mine samples and the sulfur content represented by the geostatistically derived contours. Published by Elsevier Science B.V.

International Journal of Coal Geology↗

Mangrove forest distributions and dynamics (1975–2005) of the tsunami-affected region of Asia

Aim We aimed to estimate the present extent of tsunami-affected mangrove forests and determine the rates and causes of deforestation from 1975 to 2005. Location Our study region covers the tsunami-affected coastal areas of Indonesia, Malaysia, Thailand, Burma (Myanmar), Bangladesh, India and Sri Lanka in Asia. Methods We interpreted time-series Landsat data using a hybrid supervised and unsupervised classification approach. Landsat data were geometrically corrected to an accuracy of plus-or-minus half a pixel, an accuracy necessary for change analysis. Each image was normalized for solar irradiance by converting digital number values to the top-of-the atmosphere reflectance. Ground truth data and existing maps and data bases were used to select training samples and also for iterative labelling. We used a post-classification change detection approach. Results were validated with the help of local experts and/or high-resolution commercial satellite data. Results The region lost 12% of its mangrove forests from 1975 to 2005, to a present extent of c . 1,670,000 ha. Rates and causes of deforestation varied both spatially and temporally. Annual deforestation was highest in Burma ( c . 1%) and lowest in Sri Lanka (0.1%). In contrast, mangrove forests in India and Bangladesh remained unchanged or gained a small percentage. Net deforestation peaked at 137,000 ha during 1990–2000, increasing from 97,000 ha during 1975–90, and declining to 14,000 ha during 2000–05. The major causes of deforestation were agricultural expansion (81%), aquaculture (12%) and urban development (2%). Main conclusions We assessed and monitored mangrove forests in the tsunami-affected region of Asia using the historical archive of Landsat data. We also measured the rates of change and determined possible causes. The results of our study can be used to better understand the role of mangrove forests in saving lives and property from natural disasters such as the Indian Ocean tsunami, and to identify possible areas for conservation, restoration and rehabilitation.

Journal of Biogeography↗

Application of an updated atmospheric model to explore volcano infrasound propagation and detection in Alaska

Winds and temperature gradients greatly affect the long-range propagation of infrasound . The spatio-temporal variability of these parameters must therefore be accurately characterized to correctly interpret recorded infrasound at long distances, specifically to differentiate between source and propagation effects. Here we present the first results of an open source reanalysis model, termed Alaska Volcano Observatory Ground-to-Space (AVO-G2S), constructed to accurately characterize the atmosphere and model long-range infrasound propagation from volcanic eruptions in Alaska. We select a number of case studies to examine recent eruptions of Alaskan volcanoes whose ash emissions posed a threat to air traffic, including the two most recent eruptions of Pavlof Volcano and two typical explosions from Cleveland Volcano. Strong tropospheric ducting and low noise at the station during the 21 July 2015 explosion of Cleveland Volcano led to an automated detection of the explosion at an infrasound array 992 km away, whereas low signal-to-noise ratio for the 6 November 2014 Cleveland Volcano explosion helps explain the non-detection in real-time of a predicted strong stratospheric arrival. For the November 2014 Pavlof eruption, discrepancies between local seismic data and a distal infrasound array 460 km away cannot be solely explained by changes in atmospheric conditions, though some features of the complex propagation predictions follow the trends in long-range infrasound signals. The most recent eruption of Pavlof Volcano in March 2016 shows minimal changes in propagation conditions throughout the eruption and therefore indicates that the signals detected at long-range primarily reflect source processes. These results show how detailed examination of the acoustic propagation conditions provides insight into detection capability and eruption dynamics. Future work will implement AVO-G2S and high-resolution long-range infrasound propagation modeling in real-time for Alaskan volcanoes of interest.

Alaska↗

Evidence from lava flows for complex polarity transitions: The new composite Steens Mountain reversal record

Geomagnetic polarity transitions may be significantly more complex than are currently depicted in many sedimentary and lava-flow records. By splicing together paleomagnetic results from earlier studies at Steens Mountain with those from three newly studied sections of Oregon Plateau flood basalts at Catlow Peak and Poker Jim Ridge 70–90 km to the southeast and west, respectively, we provide support for this interpretation with the most detailed account of a magnetic field reversal yet observed in volcanic rocks. Forty-five new distinguishable transitional (T) directions together with 30 earlier ones reveal a much more complex and detailed record of the 16.7 Ma reversed (R)-to-normal (N) polarity transition that marks the end of Chron C5Cr. Compared to the earlier R-T-N-T-N reversal record, the new record can be described as R-T-N-T-N-T-R-T-N. The composite record confirms earlier features, adds new west and up directions and an entire large N-T-R-T segment to the path, and fills in directions on the path between earlier directional jumps. Persistent virtual geomagnetic pole (VGP) clusters and separate VGPs have a preference for previously described longitudinal bands from transition study compilations, which suggests the presence of features at the core–mantle boundary that influence the flow of core fluid and distribution of magnetic flux. Overall the record is consistent with the generalization that VGP paths vary greatly from reversal to reversal and depend on the location of the observer. Rates of secular variation confirm that the flows comprising these sections were erupted rapidly, with maximum rates estimated to be 85–120 m ka −1 at Catlow and 130–195 m ka −1 at Poker Jim South. Paleomagnetic poles from other studies are combined with 32 non-transitional poles found here to give a clockwise rotation of the Oregon Plateau of 11.4°± 5.6° with respect to the younger Columbia River Basalt Group flows to the north and 14.5°± 4.6° with respect to cratonic North America (95 per cent confidence interval).

Geophysical Journal International↗

Prolonged winter undernutrition and the interpretation of urinary allantoin:creatinine ratios in white-tailed deer

The urinary allantoin:creatinine (A:C) ratio (expressed in micromoles of allantoin to micromoles of creatinine) has shown potential as an index of recent winter energy intake in preliminary controlled studies of elk ( Cervus elaphus ) involving mild condition deterioration (up to 11% loss of body mass). To ensure reliable nutritional assessments of free-ranging cervids by measuring A:C ratios of urine in snow, it is essential to extend this work. We assessed the effect of moderate and severe winter nutritional restriction on urinary A:C ratios of captive white-tailed deer ( Odocoileus virginianus ) that lost up to 32% body mass and related these ratios to metabolizable energy intake (MEI), body-mass loss, and other reported nutritional indicators. Deer in the control group were fed a low-protein, low-energy diet ad libitum, whereas deer in the treatment group were fed restricted amounts of the same diet. MEI was below the winter maintenance requirement for all deer, but was lower ( P = 0.029) in treatment deer than in control deer. Percent body-mass loss differed between the two groups as the study progressed, and represented the full range of physiological tolerance (0-32% loss). Mean A:C ratios of control deer, which lost up to 17.4% body mass, showed a slight increasing ( P = 0.086) trend, whereas initially similar A:C ratios of severely restricted deer increased ( P = 0.0002) markedly by the eighth week (0.52 vs. 0.09 µmol:µmol). The urinary A:C ratio was not related ( P = 0.839) to recent (2 days prior to urine sampling) MEI, but there was a marginally significant relation ( r 2 = 0.42, P = 0.110) between the A:C ratio and cumulative percent mass loss. The urinary A:C ratio was directly related to urinary urea nitrogen:creatinine ( r 2 = 0.59, P < 0.0001) and 3-methylhistidine:creatinine ( r 2 = 0.43, P < 0.0001) ratios. This study confirms that elevated and increasing A:C ratios may be due either to increasing energy intake or to accelerated tissue catabolism and increased endogenous contributions to urinary allantoin excretion.

Canadian Journal of Zoology↗

Multiple plagioclase crystal populations identified by crystal size distribution and in situ chemical data: Implications for timescales of magma chamber processes associated with the 1915 eruption of Lassen Peak, CA

Products of the 1915 Lassen Peak eruption reveal evidence for a magma recharge–magma mixing event that may have catalyzed the eruption and from which four compositional members were identified: light dacite, black dacite, andesitic inclusion, and dark andesite. Crystal size distribution, textural, and in situ chemical (major and trace element and Sr isotope) data for plagioclase from these compositional products define three crystal populations that have distinct origins: phenocrysts (long axis > 0·5 mm) that typically have core An contents between 34 and 36 mol %, microphenocrysts (long axis between 0·1 and 0·5 mm) that have core An contents of 66–69, and microlites (long axis < 0·1 mm) with variable An core contents from 64 to 52. Phenocrysts are interpreted to form in an isolated dacitic magma chamber that experienced slow cooling. Based on textural, compositional, and isotopic data for the magma represented by the dacitic component, magma recharge was not an important process until just prior to the 1915 eruption. Average residence times for phenocrysts are in the range of centuries to millennia. Microphenocrysts formed in a hybrid layer that resulted from mixing between end-member reservoir dacite and recharge magma of basaltic andesite composition. High thermal contrast between the two end-member magmas led to relatively high degrees of undercooling, which resulted in faster crystal growth rates and acicular and swallowtail crystal habits. Some plagioclase phenocrysts from the dacitic chamber were incorporated into the hybrid layer and underwent dissolution–precipitation, seen in both crystal textures and rim compositions. Average microphenocryst residence times are of the order of months. Microlites may have formed in response to decompression and/or syn-eruptive degassing as magma ascended from the chamber through the volcanic conduit. Chemical distinctions in plagioclase microlite An contents reveal that melt of the dark andesite was more mafic than the melt of the other three compositions. We suggest that mixing of an intruding basaltic andesite and reservoir dacite before magma began ascending in the conduit allowed formation of a compositionally distinct microlite population. Melt in the other three products was more evolved because it had undergone differentiation during the months following initial mixing; as a consequence, melt and microlites among these three products have similar compositions. The results of this study highlight the integrated use of crystal size distribution, textural, and in situ chemical data in identifying distinct crystal populations and linking these populations to the thermal and chemical characteristics of complex magma bodies.

Journal of Petrology↗

Constraints on the composition of ore fluids and implications for mineralising events at the Cleo gold deposit, Eastern Goldfields Province, Western Australia

The Cleo gold deposit, 55 km south of Laverton in the Eastern Goldfields Province of Western Australia, is characterised by banded iron-formation (BIF)-hosted ore zones in the gently dipping Sunrise Shear Zone and high-grade vein-hosted ore in the Western Lodes. There is evidence that gold mineralisation in the Western Lodes (which occurred at ca 2655 Ma) post-dates the majority of displacement along the Sunrise Shear Zone, but it remains uncertain if the ore in both structures formed simultaneously or separately. Overall, the Pb, Nd, Sr, C. O and S isotopic compositions of ore-related minerals from both the Western Lodes and ore zones in the Sunrise Shear Zone are similar. Early low-salinity aqueous-carbonic fluids and late high-salinity fluids with similar characteristics are trapped in inclusions in quartz veins from both the Sunrise Shear Zone and the Western Lodes. The early CO2, CO2-H2O, and H2O- dominant inclusions are interpreted as being related to ore formation, and to have formed from a single low-salinity aqueous-carbonic fluid as a result of intermittent fluid immiscibility. Homogenisation temperatures indicate that these inclusions were trapped at approximately 280??C and at approximately 4 km depth, in the deeper epizonal range. Differences between the ore zones are detected in the trace-element composition of gold samples, with gold from the Sunrise Shear Zone enriched in Ni, Pb, Sn, Te and Zn, and depleted In As, Bi, Cd, Cu and Sb, relative to gold from the Western Lodes. Although there are differences in gold composition between the Sunrise Shear Zone and Western Lodes, and hence the metal content of ore fluids may have varied slightly between the different ore zones, no other systematic fluid or solute differences are detected between the ore zones. Given the fact that the ore fluids in each zone have very similar bulk properties, the considerable differences in gold grade, sulfide mineral abundance, and ore textures between the two ore zones most likely result from different gold-deposition mechanisms. The association of ore zones in the Sunrise Shear Zone with pyrite-replaced BIF suggests that wall-rock sulfidation was the most significant mechanism of gold precipitation, through the destabilisation of gold-bisulfide complexes. The Western Lodes, however, do not exhibit any host-rock preference and multistage veins commonly contain coarse-grained gold. Fluid-inclusion characteristics and breccia textures in veins in the Western Lodes suggest that rapid pressure changes, brought about by intermittent release of overpressured fluids and concomitant phase separation, are likely to have caused the destabilisation of gold-thiocomplexes, leading to formation of higher-grade gold ore zones.

Australian Journal of Earth Sciences↗

Mars Science Laboratory CheMin data from the Glen Torridon region and the significance of lake-groundwater interactions in interpreting mineralogy and sedimentary history

The Glen Torridon (GT) region is positioned in terrains with strong clay mineral signatures, as inferred from orbital spectroscopy. The GT campaign confirmed orbital distinctions with in situ measurements by the Mars Science Laboratory rover, Curiosity , and the CheMin X-ray diffraction instrument with of some of the highest clay mineral abundances to date. Additionally, GT is unique because of distinct phase identifications for the first time by CheMin, including: (i) Fe-carbonates, and (ii) a novel peak in the XRD patterns of some GT samples, with an interplanar spacing of at 9.2 Å. Fe-carbonates have been previously suggested from other instruments onboard, but this is the first definitive reporting by CheMin of multiple samples with Fe-carbonate. This new phase has never been observed in Gale crater with the CheMin instrument and may be a new mineral for Mars, but discrete identification still remains enigmatic because no single phase on Earth is able to account the mineralogical, geochemical, and sedimentological constraints in the GT region. Here, we modeled XRD profiles and propose an interstratified clay mineral, specifically greenalite-minnesotaite (G-M), as a reasonable candidate. The coexistence of Fe-carbonate and Fe-rich clay minerals in the GT samples, supports a conceptual model of a lacustrine groundwater mixing environment in the ancient Gale crater lake. Groundwater interaction with percolating lake waters in the sediments is common in terrestrial lacustrine settings, and the diffusion of two distinct water bodies within the subsurface can create a geochemical gradient and unique mineral front in the sediments. Ultimately, the proximity to this mixing zone controlled the secondary minerals preserved in the Jura, Knockfarril Hill, and Glasgow members of the Mt. Sharp group exposed in GT.

Journal of Geophysical Research E: Planets↗

Overview of the Spirit Mars Exploration Rover mission to Gusev Crater: Landing site to Backstay Rock in the Columbia Hills

Spirit landed on the floor of Gusev Crater and conducted initial operations on soil‐covered, rock‐strewn cratered plains underlain by olivine‐bearing basalts. Plains surface rocks are covered by wind‐blown dust and show evidence for surface enrichment of soluble species as vein and void‐filling materials and coatings. The surface enrichment is the result of a minor amount of transport and deposition by aqueous processes. Layered granular deposits were discovered in the Columbia Hills, with outcrops that tend to dip conformably with the topography. The granular rocks are interpreted to be volcanic ash and/or impact ejecta deposits that have been modified by aqueous fluids during and/or after emplacement. Soils consist of basaltic deposits that are weakly cohesive, relatively poorly sorted, and covered by a veneer of wind‐blown dust. The soils have been homogenized by wind transport over at least the several kilometer length scale traversed by the rover. Mobilization of soluble species has occurred within at least two soil deposits examined. The presence of monolayers of coarse sand on wind‐blown bedforms, together with even spacing of granule‐sized surface clasts, suggests that some of the soil surfaces encountered by Spirit have not been modified by wind for some time. On the other hand, dust deposits on the surface and rover deck have changed during the course of the mission. Detection of dust devils, monitoring of the dust opacity and lower boundary layer, and coordinated experiments with orbiters provided new insights into atmosphere‐surface dynamics.

Journal of Geophysical Research E: Planets↗

Paleomagnetic data bearing on style of Miocene deformation in the Lake Mead area, Southern Nevada

Paleomagnetic and structural data from intermediate to mafic composition lava flows and related dikes in all major blocks of the late Miocene Hamblin-Cleopatra Volcano, which was structurally dismembered during the development of the Lake Mead Fault System (LMFS), provide limits on the magnitude and sense of tilting and vertical axis rotation of crust during extension of this part of the Basin and Range province. Sinistral separation along the fault system dissected the volcano into three major blocks. The eastern, Cleopatra Lobe of the volcano is structurally the most intact section of the volcano. Normal and reverse polarity data from paleomagnetic sites collected along traverses in the Cleopatra Lobe yield an in situ grand mean of Declination (D) = 339??, Inclination (I) = +54??, ??95 = 3.1??, k = 27.2, N = 81 sites. The rocks of the central core of the volcano yield an in situ grand mean of D = 3??, I = + 59??, ??95 = 6.8??, k = 42.5, N = 11 sites (six normal, five reverse polarity). Sites collected within the western Hamblin Lobe of the volcano are exclusively of reverse polarity and yield an overall in situ mean of D = 168??, I = -58??, ??95 = 6.5??. k = 28.9, N = 18 sites. Interpretation of the paleomagnetic data in the context of the structural history of the volcano and surrounding area, considers the possibility of two different types of structural corrections. A stratigraphic tilt correction involves restoring flows to the horizontal using the present strike. This correction assumes no initial, possibly radial, dip of flows of the volcano and is considered invalid. A structural tilt correction to the data assumes that dikes of the radiating swarm associated with the volcano were originally vertical and results in block mean directions of D = 9??, I = +53??, ??95 = 3.1??, k = 27.2, and D = 58??, I = + 78??, ??95 = 6.8, k = 42.5, for the Cleopatra Lobe and the central intrusive core, respectively. The data from the Cleopatra Lobe are slightly discordant, in a clockwise sense, from expected middle- to late-Miocene field directions. The data from the volcano are not consistent with a proposed structural model of uniform, moderate magnitude, statistically significant, counter-clockwise vertical axis rotation of fault-bounded blocks during overall sinsitral displacement along the LMFS. We also analyzed dikes of the northernmost part of the Miocene Wilson Ridge hypabyssal igneous complex, strata of the Triassic Chinle Formation, and basalt flows of the Miocene West End Wash/Callville Mesa volcanic centers. Dikes in the Wilson Ridge pluton and the Triassic strata yield magnetizations with directions suggestive of statistically significant, clockwise, vertical-axis rotations consistent with local, large-magnitude shear of crustal fragments near some of the faults of the LMFS. Late Cenozoic deformation of the Hamblin-Cleopatra volcano area appears to have been non-uniform in scale and magnitude and no single structural model, involving strictly strike-slip faulting, can account for the observed paleomagnetic data. ?? 2001 Elsevier Science Ltd. All rights reserved.

Journal of Structural Geology↗

The 40Ar/39Ar thermochronology of the eastern Mojave Desert, California, and adjacent western Arizona with implications for the evolution of metamorphic core complexes

Mesozoic thickening and Cenozoic extension resulted in the juxtaposition of upper and middle crustal rocks in the eastern Mojave Desert, southeastern California and western Arizona. The application of 40 Ar/ 39 Ar thermochronology to rocks in this region provides information about the timing and nature of thrusting, plutonism, metamorphism, denudation, and detachment faulting. The 40 Ar/ 39 Ar ages of 175 to 125 Ma from the Clipper, Piute, Turtle, Mohave, Bill Williams, and Hualapai Mountains are interpreted to be the result of a middle Mesozoic thermal event(s) caused by crustal thickening. The 40 Ar/ 39 Ar data from the Clipper and Piute Mountains suggest that this thermal event was followed by a period of cooling at rates of 1°–5°C/m.y. Orogenesis culminated during the Late Cretaceous when rocks exposed in the Old Woman‐Piute, Chemehuevi, and Sacramento Mountains attained temperatures >500°C which reset the K–Ar systems of minerals from Proterozoic rocks. High‐grade metamorphism in the Old Woman Mountains area was caused by the intrusion of the Old Woman‐Piute batholith at 73±1 Ma. Cooling rates following batholith emplacement in the Old Woman Mountains were ∼100°C/m.y. between 73 and 70 Ma and 5°–10°C/m.y. from 70 to ∼30 Ma. Between 65 and 25 Ma the entire eastern Mojave Desert underwent a period of cooling at a rate of 2°–10°C/m.y. By 30 Ma, rocks exposed in the Old Woman‐Piute, Marble, Ship, Clipper, and Turtle Mountains were below ∼100°C. The 40 Ar/ 39 Ar ages from the Sacramento Mountains suggest that mylonitization caused by the onset of regional extension occurred at 23±1 Ma. When extension started in the Chemehuevi Mountains, rocks exposed in the southwestern and northeastern portions of footwall to the Chemehuevi detachment fault were at ∼180°C and ∼350°C, respectively. This suggests that the exposed part of the Chemehuevi detachment fault initiated at a dip of 5°–30° or as a series of higher‐angle faults that cut to a depth of 10–12 km and were later rotated to their present dip. Unroofing of the footwalls to detachment faults in the Sacramento and Chemehuevi Mountains resulted in average cooling rates of 10°–50°C/m.y. between 22 and 15 Ma.

California↗

Insights into glendonite formation from the upper Oligocene Sagavanirktok Formation, North Slope, Alaska

The type locality for the upper Oligocene Nuwok Member of the Sagavanirktok Formation (Carter Creek, North Slope, Alaska, USA) contains abundant occurrence of glendonite, a pseudomorph after the calcium carbonate mineral ikaite, which typically forms in the shallow subsurface of cold marine sediments. The region during the time of Nuwok Member deposition was located at a high latitude, similar to today, and the study site is characterized by sands and silty muds interpreted here to have been deposited in coastal and shelfal marine environments. Isotopic (Sr) and biostratigraphic (foraminifera) evidence presented here refine the depositional age of the outcrop to approximately 24 Ma. Glendonites occur in two basic forms: radial clusters, commonly centered around a single larger primary crystal ( approx. 10 cm; Type A) and larger single blades generally without accessory crystals (approx. 15–25 cm; Type B). Microscopic examination revealed a sequence of multiple types of replacive calcite that formed as a direct result of ikaite transformation: Type 1 rhombohedral crystals characterized by microporous and inclusion-rich cores and concentric zones, Type 2A, composed of clear calcite that overgrew and augmented Type 1 crystals, and inclusion-rich, microcrystalline Type 2B, which formed a matrix surrounding the rhombs and commonly dominates the outer rims of glendonite specimens. Type 3 calcite precipitated as fibrous, botryoidal epitaxial cement atop previous phases and is not ikaite-derived. These phases are distributed in similar ways in all examined specimens and are consistent with several previously described glendonite occurrences around the world, despite differing diagenetic and geologic histories. Stable isotope evidence (δ13C and δ18O) suggests sourcing of glendonite carbon from both organic and methanogenic sources. Glendonites of the Nuwok Member can therefore assist in the determination of a more comprehensive ikaite transformation model, improving our understanding of glendonite formation and the sedimentological and environmental context of their occurrence. Oligocene glendonites are uncommon globally; the well-preserved occurrence described here can allow future studies to better reconstruct Arctic environmental conditions and paleoclimates during this time.

Alaska↗

Use of geoelectrical methods in groundwater pollution surveys in a coastal environment

The pollution of coastal aquifers by old landfills can contaminate valuable and scarce water resources in the freshwater lens utilized seasonably by overcrowded communities. The pollutants will ultimately flow into the sea where they may also cause a coastal water pollution problem. We have detected pollution in the freshwater lens from a sanitary landfill near Provincetown, Cape Cod, using the geoelectrical resistivity method. This survey included Schlumberger geoelectrical depth soundings and a horizontal geoelectrical profile using the Wenner configuration. The geoelectrical survey was conducted at a site along Highway 6 where it passes the coastal town of Provincetown and a sanitary landfill that has been in operation since 1954. The depth soundings suggest the characteristic decrease in resistivity vs. depth from the high resistivity of the unsaturated zone to the low resistivity of the saltwater saturated zone. The freshwater lens is clearly identified by the change in slope of the steeply dipping curve of resistivity versus electrode spacing. Interpretations made using a multilayer program, Geomate, resulted in layer resistivities between 460 and 95 ohm?m for the freshwater lens. A comparison with well water resistivities suggests that a layer resistivity of 230 ohm?m or lower is indicative of pollution in the freshwater lens. The results of the geoelectrical depth soundings were confirmed in the Wenner horizontal profile. Both measurements suggest that the pollutants do not spread evenly as one would expect for a homogeneous and isotropic medium. Instead, a preferred channel for the flow of the pollutants is observed along a path from the landfill toward the shoreline. The depth to the saltwater/freshwater interface or, more specifically, to the low resistivity-high resistivity interface appears to be shallow where the freshwater lens is polluted. This was confirmed by pore water well samples that were highly mineralized. The equilibrium postulated by the Ghyben-Herzberg relation appears to be disturbed in the area of aquifer pollution. This rise in the conductivity boundary is caused by the highly mineralized bottom of the contaminant plume that submerges into the saltwater saturated zone. In the area of high freshwater pollution the groundwater can be subdivided into three layers that show a decrease in resistivity with depth. The formation factor, F, defined as the ratio of bulk aquifer resistivity to pore water resistivity, shows unusually high values between 10 and 12. These high values are unexpected for an unconsolidated sand. Pollution residues are suspected to clog the pores and thus to increase the resistivity. It is possible that iron-oxidizing bacteria and the precipitation of dissolved iron or organic pollutants are the cause of the high values of F. If proven correct, these interesting possibilities could lead to future new applications of the geoelectrical resistivity method in contaminant hydroloy.

Journal of Applied Geophysics↗

An axial view of a metamorphic core complex: Crustal structure of the Whipple and Chemehuevi Mountains, southeastern California

A 135‐km‐long, NW‐SE trending, seismic refraction/wide‐angle reflection profile provides a unique along‐strike view of the crustal structure of a belt of metamorphic core complexes in southeastern California: the Whipple, Chemehuevi, and Sacramento mountains metamorphic core complexes. Interpretation of the seismic data was done by two‐dimensional forward modeling of travel times and amplitudes. The final model consists of (1) a thin (< 1.5 km) veneer of upper plate and fractured lower plate rocks (velocities of 1.5–5.3 km s −1 ) overlying a fairly homogeneous basement with velocities of 6.0 km s −1 ; (2) a localized, high‐velocity (6.4 km s −1 ) body, situated directly beneath the Whipple Mountains; (3) a 6.3–6.4 km s −1 middle crust that is thickest beneath the core complexes; (4) a 6.65±0.15 km s −1 lower crust; (5) crustal thickness of 27 km with a deeper crustal root (3 km) beneath the Whipple Mountains metamorphic core complex; and (6) a P n velocity of 8.0±0.10 km s −1 . The crustal structure that underlies the belt of metamorphic core complexes provides new insights into the processes that control extension in the deep crust. Upper crustal velocities are higher beneath the Whipple Mountains (where velocities increase to 6.4 km s −1 at ∼5 km depth) than beneath the Chemehuevi and Sacramento mountains. In addition, midcrustal discontinuities rise 2–5 km beneath the Whipple complex compared to the other complexes. These observations support greater uplift and a slightly deeper midcrustal origin for the rocks now exposed in the core of the Whipple Mountains compared to rocks in the Chemehuevi and Sacramento mountains. Despite the enhanced uplift and extension in the Whipple Mountains, the crust is thicker here (30 km) than anywhere else along the Colorado River extensional corridor. This may be in part a relic of compressional and magmatic thickening during the Mesozoic. However, we suggest that inflation of the crust during Tertiary extension was the dominant mechanism. Both mantle‐derived magmatism and lateral ductile inflow in the crust are proposed.

Arizona, California↗