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At least 1,027 records · Page 57Linked to original sources

Plastic debris in 29 Great Lakes tributaries: Relations to watershed attributes and hydrology

Plastic debris is a growing contaminant of concern in freshwater environments, yet sources, transport, and fate remain unclear. This study characterized the quantity and morphology of floating micro- and macroplastics in 29 Great Lakes tributaries in six states under different land covers, wastewater effluent contributions, population densities, and hydrologic conditions. Tributaries were sampled three or four times each using a 333 μm mesh neuston net. Plastic particles were sorted by size, counted, and categorized as fibers/lines, pellets/beads, foams, films, and fragments. Plastics were found in all 107 samples, with a maximum concentration of 32 particles/m 3 and a median of 1.9 particles/m 3 . Ninety-eight percent of sampled plastic particles were less than 4.75 mm in diameter and therefore considered microplastics. Fragments, films, foams, and pellets/beads were positively correlated with urban-related watershed attributes and were found at greater concentrations during runoff-event conditions. Fibers, the most frequently detected particle type, were not associated with urban-related watershed attributes, wastewater effluent contribution, or hydrologic condition. Results from this study add to the body of information currently available on microplastics in different environmental compartments, including unique contributions to quantify their occurrence and variability in rivers with a wide variety of different land-use characteristics while highlighting differences between surface samples from rivers compared with lakes.

Environmental Science & Technology↗

Anthropogenic sources of arsenic and copper to sediments in a suburban lake, Northern Virginia

Mass balances of total arsenic and copper for a suburban lake in densely populated northern Virginia were calculated using data collected during 1998. Mass-balance terms were precipitation; stream inflow, including road runoff; stream outflow; and contributions from leaching of pressure-treated lumber. More mass of arsenic and copper was input to the lake than was output; the 1998 lake-retention rates were 70% for arsenic and 20% for copper. The arsenic mass balance compared well with a calculated annual mass accumulation in the top 1 cm of the lake sediments; however, the calculated contribution of copper to the lake was insufficient to account for the amount of copper in this zone. Leaching experiments were conducted on lumber treated with chromated copper arsenate (CCA) to quantify approximate amounts of arsenic and copper contributed by this source. Sources to lake sediments included leaching of CCA-treated lumber (arsenic, 50%; copper, 4%), streamwater (arsenic, 50%; copper, 90%), and atmospheric deposition (arsenic, 1%; copper, 3%). Results of this study suggest that CCA-treated lumber and road runoff could be significant nonpoint sources of arsenic and copper, respectively, in suburban catchments.

Virginia↗

Combined sewer overflows: an environmental source of hormones and wastewater micropollutants

Data were collected at a wastewater treatment plant (WWTP) in Burlington, Vermont, USA, (serving 30,000 people) to assess the relative contribution of CSO (combined sewer overflow) bypass flows and treated wastewater effluent to the load of steroid hormones and other wastewater micropollutants (WMPs) from a WWTP to a lake. Flow-weighted composite samples were collected over a 13 month period at this WWTP from CSO bypass flows or plant influent flows ( n = 28) and treated effluent discharges ( n = 22). Although CSO discharges represent 10% of the total annual water discharge (CSO plus treated plant effluent discharges) from the WWTP, CSO discharges contribute 40&ndash;90% of the annual load for hormones and WMPs with high (>90%) wastewater treatment removal efficiency. By contrast, compounds with low removal efficiencies (<90%) have less than 10% of annual load contributed by CSO discharges. Concentrations of estrogens, androgens, and WMPs generally are 10 times higher in CSO discharges compared to treated wastewater discharges. Compound concentrations in samples of CSO discharges generally decrease with increasing flow because of wastewater dilution by rainfall runoff. By contrast, concentrations of hormones and many WMPs in samples from treated discharges can increase with increasing flow due to decreasing removal efficiency.

Environmental Science & Technology↗

Catchment-scale variation in the nitrate concentrations of groundwater seeps in the Catskill Mountains, New York, U.S.A.

Forested headwater streams in the Catskill Mountains of New York show significant among-catchment variability in mean annual nitrate (NO3-) concentrations. Large contributions from deep groundwater with high NO3- concentrations have been invoked to explain high NO3- concentrations in stream water during the growing season. To determine whether variable contributions of groundwater could explain among-catchment differences in streamwater, we measured NO3- concentrations in 58 groundwater seeps distributed across six catchments known to have different annual average streamwater concentrations. Seeps were identified based on release from bedrock fractures and bedding planes and had consistently lower temperatures than adjacent streamwaters. Nitrate concentrations in seeps ranged from near detection limits (0.005 mg NO3--N/L) to 0.75 mg NO3--N/L. Within individual catchments, groundwater residence time does not seem to strongly affect NO3- concentrations because in three out of four catchments there were non-significant correlations between seep silica (SiO2) concentrations, a proxy for residence time, and seep NO3- concentrations. Across catchments, there was a significant but weak negative relationship between NO3- and SiO2 concentrations. The large range in NO3- concentrations of seeps across catchments suggests: 1) the principal process generating among-catchment differences in streamwater NO3- concentrations must influence water before it enters the groundwater flow system and 2) this process must act at large spatial scales because among-catchment variability is much greater than intra-catchment variability. Differences in the quantity of groundwater contribution to stream baseflow are not sufficient to account for differences in streamwater NO3- concentrations among catchments in the Catskill Mountains.

Water, Air, & Soil Pollution↗

Rapid fluid disruption: A source for self-potential anomalies on volcanoes

Self-potential (SP) anomalies observed above suspected magma reservoirs, dikes, etc., on various volcanoes (Kilauea, Hawaii; Mount Unzen, Japan; Piton de la Fournaise, Reunion Island, Miyake Jima, Japan) result from transient surface electric fields of tens of millivolts per kilometer and generally have a positive polarity. These SP anomalies are usually attributed to electrokinetic effects where properties controlling this process are poorly constrained. We propose an alternate explanation that contributions to electric fields of correct polarity should be expected from charge generation by fluid vaporization/disruption. As liquids are vaporized or removed as droplets by gas transport away from hot dike intrusions, both charge generation and local increase in electrical resistivity by removal of fluids should occur. We report laboratory observations of electric fields in hot rock samples generated by pulses of fluid (water) through the rock at atmospheric pressure. These indicate the relative amplitudes of rapid fluid disruption (RFD) potentials and electrokinetic potentials to be dramatically different and the signals are opposite in sign. Above vaporization temperatures, RFD effects of positive sign in the direction of gas flow dominate, whereas below these temperatures, effects of negative sign dominate. This suggests that the primary contribution to observed self-potential anomalies arises from gas-related charge transport processes at temperatures high enough to produce vigorous boiling and vapor transport. At lower temperatures, the primary contribution is from electrokinetic effects modulated perhaps by changing electrical resistivity and RFD effects from high-pressure but low-temperature CO2 and SO2 gas flow ripping water molecules from saturated crustal rocks. If charge generation is continuous, as could well occur above a newly emplaced dike, positive static potentials will be set up that could be sustained for many years, and the simplest method for identifying these hot, active regions would be to identify the SP anomalies they generate.

Hawai'i↗

Scale effects on headwater catchment runoff timing, flow sources, and groundwater‐streamflow relations

The effects of catchment size and landscape organization on runoff generation are poorly understood. Little research has integrated hillslope and riparian runoff investigation across catchments of different sizes to decipher first‐order controls on runoff generation. We investigated the role of catchment sizes on riparian and hillslope dynamics based on hydrometric and tracer data observed at five scales ranging from trenched hillslope sections (55–285 m 2 ) to a 280‐ha catchment at Maimai on the west coast of the South Island, New Zealand. The highly organized landscape is comprised of similar headwater catchments, regular geology, steep highly dissected topography, relatively consistent soil depths, and topographically controlled shallow through flow. We found a strong correlation between riparian zone groundwater levels and runoff for the headwaters, whereas the water tables in the valley bottom of the larger catchments were uncorrelated to runoff for 14 months of record. While there was no clear relationship between catchment size and new water contribution to runoff in the two storms analyzed in detail, lag times of tracer responses increased systematically with catchment size. The combination of hydrometric and tracer data allowed assessment of the runoff contributions from different parts of the landscape. Runoff was generated consistently in headwater riparian zones. This agreed also with the observed variations of tracer ( 18 O and silica) responses for the different catchments. During wetter antecedent conditions or during larger events (>30 mm under dry antecedent conditions) hillslope and valley bottom floodplains did contribute to event runoff directly. We propose that analysis of landscape‐scale organization and the distribution of dominant landscape features provide a structure for investigation of runoff production and solute transport, especially as catchment‐scale increases from headwaters to the mesoscale.

Water Resources Research↗

Increased groundwater to stream discharge from permafrost thawing in the Yukon River basin: Potential impacts on lateral export of carbon and nitrogen

Arctic and subarctic watersheds are undergoing climate warming, permafrost thawing, and thermokarst formation resulting in quantitative shifts in surface water - groundwater interaction at the basin scale. Groundwater currently comprises almost one fourth of Yukon River water discharged to the Bering Sea and contributes 5-10% of the dissolved organic carbon (DOC) and nitrogen (DON) and 35-45% of the dissolved inorganic carbon (DIC) and nitrogen (DIN) loads. Long-term strearnflow records (>30 yrs) of the Yukon River basin indicate a general upward trend in groundwater contribution to streamflow of 0.7-0.9%/yr and no pervasive change in annual flow. We propose that the increases in groundwater contributions were caused predominately by climate warming and permafrost thawing that enhances infiltration and supports deeper flowpaths. The increased groundwater fraction may result in decreased DOC and DON and increased DIC and DIN export when annual flow remains unchanged.

Geophysical Research Letters↗

Influence of perched groundwater on base flow

Analysis with a three‐dimensional variably saturated groundwater flow model provides a basic understanding of the interplay between streams and perched groundwater. A simplified, layered model of heterogeneity was used to explore these relationships. Base flow contribution from perched groundwater was evaluated with regard to varying hydrogeologic conditions, including the size and location of the fine‐sediment unit and the hydraulic conductivity of the fine‐sediment unit and surrounding coarser sediment. Simulated base flow was sustained by perched groundwater with a maximum monthly discharge in excess of 15 L/s (0.6 feet 3 /s) over the length of the 2000‐m stream reach. Generally, the rate of perched‐groundwater discharge to the stream was proportional to the hydraulic conductivity of sediment surrounding the stream, whereas the duration of discharge was proportional to the hydraulic conductivity of the fine‐sediment unit. Other aspects of the perched aquifer affected base flow, such as the depth of stream penetration and the size of the fine‐sediment unit. Greater stream penetration decreased the maximum base flow contribution but increased the duration of contribution. Perched groundwater provided water for riparian vegetation at the demand rate but reduced the duration of perched‐groundwater discharge nearly 75%.

Water Resources Research↗

Exploring changes in the spatial distribution of stream baseflow generation during a seasonal recession

Relating watershed structure to streamflow generation is a primary focus of hydrology. However, comparisons of longitudinal variability in stream discharge with adjacent valley structure have been rare, resulting in poor understanding of the distribution of the hydrologic mechanisms that cause variability in streamflow generation along valleys. This study explores detailed surveys of stream base flow across a gauged, 23 km 2 mountain watershed. Research objectives were (1) to relate spatial variability in base flow to fundamental elements of watershed structure, primarily topographic contributing area, and (2) to assess temporal changes in the spatial patterns of those relationships during a seasonal base flow recession. We analyzed spatiotemporal variability in base flow using (1) summer hydrographs at the study watershed outlet and 5 subwatershed outlets and (2) longitudinal series of discharge measurements every ~100 m along the streams of the 3 largest subwatersheds (1200 to 2600 m in valley length), repeated 2 to 3 times during base flow recession. Reaches within valley segments of 300 to 1200 m in length tended to demonstrate similar streamflow generation characteristics. Locations of transitions between these segments were consistent throughout the recession, and tended to be collocated with abrupt longitudinal transitions in valley slope or hillslope-riparian characteristics. Both within and among subwatersheds, correlation between the spatial distributions of streamflow and topographic contributing area decreased during the recession, suggesting a general decrease in the influence of topography on stream base flow contributions. As topographic controls on base flow evidently decreased, multiple aspects of subsurface structure were likely to have gained influence.

Water Resources Research↗

Three-dimensional modeling of fine sediment transport by waves and currents in a shallow estuary

A suspended sediment transport model is implemented in the unstructured‐grid SUNTANS model and applied to study fine‐grained sediment transport in South San Francisco Bay. The model enables calculation of suspension of bottom sediment based on combined forcing of tidal currents and wind waves. We show that accurate results can be obtained by employing two‐size classes which are representative of microflocs and macroflocs in the Bay. A key finding of the paper is that the critical calibration parameter is the ratio of the erosion of the microflocs to macroflocs from the bed. Different values of this erosion ratio are needed on the shallow shoals and deeper channels because of the different nature of the sediment dynamics in these regions. Application of a spatially variable erosion ratio and critical shear stress for erosion is shown to accurately reproduce observed suspended sediment concentration at four‐field sites located along a cross‐channel transect. The results reveal a stark contrast between the behavior of the suspended sediment concentration on the shoals and in the deep channel. Waves are shown to resuspend sediments on the shoals, although tidal and wind‐generated currents are needed to mix the thin wave‐driven suspensions into the water column. The contribution to the suspended sediment concentration in the channel by transport from the shoals is similar in magnitude to that due to local resuspension. However, the local contribution is in phase with strong bottom currents which resuspend the sediments, while the contribution from the shoals peaks during low‐water slack tide.

San Francisco Bay↗

A numerical study of wave-driven mean flows and setup dynamics at a coral reef-lagoon system

Two-dimensional mean wave-driven flow and setup dynamics were investigated at a reef-lagoon system at Ningaloo Reef, Western Australia, using the numerical wave-flow model, SWASH. Phase-resolved numerical simulations of the wave and flow fields, validated with highly detailed field observations (including >10 sensors through the energetic surf zone), were used to quantify the main mechanisms that govern the mean momentum balances and resulting mean current and setup patterns, with particular attention to the role of nonlinear wave shapes. Momentum balances from the phase-resolved model indicated that onshore flows near the reef crest were primarily driven by the wave force (dominated by radiation stress gradients) due to intense breaking, whereas the flow over the reef flat and inside the lagoon and channels was primarily driven by a pressure gradient. Wave setup inside the lagoon was primarily controlled by the wave force and bottom stress. The bottom stress reduced the setup on the reef flat and inside the lagoon. Excluding the bottom stress contribution in the setup balance resulted in an over prediction of the wave-setup inside the lagoon by up to 200–370%. The bottom stress was found to be caused by the combined presence of onshore directed wave-driven currents and (nonlinear) waves. Exclusion of the bottom stress contribution from nonlinear wave shapes led to an over prediction of the setup inside the lagoon by approximately 20–40%. The inclusion of the nonlinear wave shape contribution to the bottom stress term was found to be particularly relevant in reef regions that experience a net onshore mass flux over the reef crest.

Journal of Geophysical Research-Oceans↗

Groundwater as a nonpoint source of atrazine and deethylatrazine in a river during base flow conditions

Alluvial groundwater adjacent to the main stem river is the principal nonpoint source of atrazine and deethylatrazine in the Cedar River of Iowa after the river has been in base flow conditions for 5 days. Between two sites along a 116-km reach of the Cedar River, tributaries contributed about 25% of the increase in the atrazine and deethylatrazine load, whereas groundwater from the alluvial aquifer contributed at least 75% of the increase in load. Within the study area, tributaries aggregate almost all of the discharge from tile drains, and yet the tributaries still only contribute 25% of the increase in loads in the main stem river. At an unfamned study site adjacent to the Cedar River, the sources of atrazine and deethylatrazine in the alluvial groundwater are bank storage of river water and groundwater recharge from areas distant from the river. Atrazine and deethylatrazine associated with bank storage water will provide larger concentrations to the river during early base flow conditions. After the depletion of bank storage, stable and smaller concentrations of atrazine and deethylatrazine, originating from groundwater recharge, continue to be discharged from the alluvial aquifer to the river; thus these results indicate that alluvial aquifers are an important nonpoint source of atrazine and deethylatrazine in rivers during base flow.

Iowa↗

Suspended matter in the Colorado River, 1925–1935

The rugged topography of a great part of the Colorado River Basin is a significant factor in determining the quantity of water and suspended matter carried by the River. The mountainous regions of Colorado and Wyoming contribute a large part of the flow of the River, whereas the central part of the Basin, cut by deep gorges and canyons, contributes a large part of the suspended matter carried by the River. The discharge of the Colorado River as measured near Cisco, Utah, with a drainage‐area of 24,100 square miles is slightly greater than the discharge of the largest tributary, the Green River, measured near Greenriver, Utah, with a drainage‐area of 40,600 square miles. The Green, however, carries a considerably larger load of suspended matter. Two other tributaries, the San Juan and Little Colorado rivers, each with a drainage‐area of about 25,000 square miles, carry large loads of suspended matter in proportion to their discharge. For example, the Little Colorado River in the summer of 1931 contributed less than 10 per cent of the flow of the main river at Grand Canyon, but the Little Colorado carried about 10,000,000 tons of suspended matter during this period and the main river had about 25,000,000 tons for the same period.

Eos, Transactions, American Geophysical Union↗

Z chromosome divergence, polymorphism and relative effective population size in a genus of lekking birds

Sex chromosomes contribute disproportionately to species boundaries as they diverge faster than autosomes and often have reduced diversity. Their hemizygous nature contributes to faster divergence and reduced diversity, as do some types of selection. In birds, other factors (mating system and bottlenecks) can further decrease the effective population size of Z-linked loci and accelerate divergence (Fast-Z). We assessed Z-linked divergence and effective population sizes for two polygynous sage-grouse species and compared them to estimates from birds with various mating systems. We found lower diversity and higher F ST for Z-linked loci than for autosomes, as expected. The &pi; Z / &pi; A ratio was 0.38 in Centrocercus minimus, 0.48 in Centrocercus urophasianus and 0.59 in a diverged, parapatric population of C. urophasianus, a broad range given the mating system among these groups is presumably equivalent. The full data set had unequal males and females across groups, so we compared an equally balanced reduced set of C. minimus and individuals pooled from both C. urophasianus subgroups recovering similar estimates: 0.54 for C. urophasianus and 0.38 for C. minimus. We provide further evidence that N eZ / N eA in birds is often lower than expected under random mating or monogamy. The lower ratio in C. minimus could be a consequence of stronger selection or drift acting on Z loci during speciation, as this species differs strongly from C. urophasianus in sexually selected characters with minimal mitochondrial divergence. As C. minimus also exhibited lower genomic diversity, it is possible that a more severe demographic history may contribute to its lower ratio.

Heredity↗

Hydrological effects of forest transpiration loss in bark beetle-impacted watersheds

The recent climate-exacerbated mountain pine beetle infestation in the Rocky Mountains of North America has resulted in tree death that is unprecedented in recorded history. The spatial and temporal heterogeneity inherent in insect infestation creates a complex and often unpredictable watershed response, influencing the primary storage and flow components of the hydrologic cycle. Despite the increased vulnerability of forested ecosystems under changing climate 1 , watershed-scale implications of interception, ground evaporation, and transpiration changes remain relatively unknown, with conflicting reports of streamflow perturbations across regions. Here, contributions to streamflow are analysed through time and space to investigate the potential for increased groundwater inputs resulting from hydrologic change after infestation. Results demonstrate that fractional late-summer groundwater contributions from impacted watersheds are 30 &plusmn; 15% greater after infestation and when compared with a neighbouring watershed that experienced earlier and less-severe attack, albeit uncertainty propagations through time and space are considerable. Water budget analysis confirms that transpiration loss resulting from beetle kill can account for the relative increase in groundwater contributions to streams, often considered the sustainable flow fraction and critical to mountain water supplies and ecosystems.

Colorado↗

Climate-driven increase of natural wetland methane emissions offset by human-induced wetland reduction in China over the past three decades

Both anthropogenic activities and climate change can affect the biogeochemical processes of natural wetland methanogenesis. Quantifying possible impacts of changing climate and wetland area on wetland methane (CH 4 ) emissions in China is important for improving our knowledge on CH 4 budgets locally and globally. However, their respective and combined effects are uncertain. We incorporated changes in wetland area derived from remote sensing into a dynamic CH 4 model to quantify the human and climate change induced contributions to natural wetland CH 4 emissions in China over the past three decades. Here we found that human-induced wetland loss contributed 34.3% to the CH 4 emissions reduction (0.92 TgCH 4 ), and climate change contributed 20.4% to the CH 4 emissions increase (0.31 TgCH 4 ), suggesting that decreasing CH 4 emissions due to human-induced wetland reductions has offset the increasing climate-driven CH 4 emissions. With climate change only, temperature was a dominant controlling factor for wetland CH 4 emissions in the northeast (high latitude) and Qinghai-Tibet Plateau (high altitude) regions, whereas precipitation had a considerable influence in relative arid north China. The inevitable uncertainties caused by the asynchronous for different regions or periods due to inter-annual or seasonal variations among remote sensing images should be considered in the wetland CH 4 emissions estimation.

Scientific Reports↗

A comparison of speciated atmospheric mercury at an urban center and an upwind rural location

Gaseous elemental mercury (GEM), particulate mercury (PHg) and reactive gaseous mercury (RGM) were measured every other hour at a rural location in south central Wisconsin (Devil's Lake State Park, WI, USA) between April 2003 and March 2004, and at a predominantly downwind urban site in southeastern Wisconsin (Milwaukee, WI, USA) between June 2004 and May 2005. Annual averages of GEM, PHg, and RGM at the urban site were statistically higher than those measured at the rural site. Pollution roses of GEM and reactive mercury (RM; sum of PHg and RGM) at the rural and urban sites revealed the influences of point source emissions in surrounding counties that were consistent with the US EPA 1999 National Emission Inventory and the 2003-2005 US EPA Toxics Release Inventory. Source-receptor relationships at both sites were studied by quantifying the impacts of point sources on mercury concentrations. Time series of GEM, PHg, and RGM concentrations were sorted into two categories; time periods dominated by impacts from point sources, and time periods dominated by mercury from non-point sources. The analysis revealed average point source contributions to GEM, PHg, and RGM concentration measurements to be significant over the year long studies. At the rural site, contributions to annual average concentrations were: GEM (2%; 0.04 ng m-3); and, RM (48%; 5.7 pg m-3). At the urban site, contributions to annual average concentrations were: GEM (33%; 0.81 ng m-3); and, RM (64%; 13.8 pg m-3). ?? The Royal Society of Chemistry.

Journal of Environmental Monitoring↗

Regression models of discharge and mean velocity associated with near-median streamflow conditions in Texas: utility of the U.S. Geological Survey discharge measurement database

A database containing more than 16,300 discharge values and ancillary hydraulic attributes was assembled from summaries of discharge measurement records for 391 USGS streamflow-gauging stations (streamgauges) in Texas. Each discharge is between the 40th- and 60th-percentile daily mean streamflow as determined by period-of-record, streamgauge-specific, flow-duration curves. Each discharge therefore is assumed to represent a discharge measurement made for near-median streamflow conditions, and such conditions are conceptualized as representative of midrange to baseflow conditions in much of the state. The hydraulic attributes of each discharge measurement included concomitant cross-section flow area, water-surface top width, and reported mean velocity. Two regression equations are presented: (1) an expression for discharge and (2) an expression for mean velocity, both as functions of selected hydraulic attributes and watershed characteristics. Specifically, the discharge equation uses cross-sectional area, water-surface top width, contributing drainage area of the watershed, and mean annual precipitation of the location; the equation has an adjusted R-squared of approximately 0.95 and residual standard error of approximately 0.23 base-10 logarithm (cubic meters per second). The mean velocity equation uses discharge, water-surface top width, contributing drainage area, and mean annual precipitation; the equation has an adjusted R-squared of approximately 0.50 and residual standard error of approximately 0.087 third root (meters per second). Residual plots from both equations indicate that reliable estimates of discharge and mean velocity at ungauged stream sites are possible. Further, the relation between contributing drainage area and main-channel slope (a measure of whole-watershed slope) is depicted to aid analyst judgment of equation applicability for ungauged sites. Example applications and computations are provided and discussed within a real-world, discharge-measurement scenario, and an illustration of the development of a preliminary stage-discharge relation using the discharge equation is given.

Texas↗