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At least 1,027 records · Page 57Linked to original sources
USGS1989

Subsurface-water flow and solute transport: federal glossary of selected terms

The purpose of this report is to provide a glossary of selected terms for saturated and unsaturated flow and related processes involved in transport of contaminants in the subsurface. The glossary contains five tables. Table 1 is a list of parameters with associated symbols and units. Tables 2 to 5 are conversion charts. The original manuscript was prepared by Thomas J. Nicholson, U.S. Nuclear Regulatory Commission. It was subsequently examined by the Ground-Water Glossary Working Group and experts within and outside the Federal Government, whose recommendations were accommodated where appropriate in the glossary. It is hoped that the glossary will aid in the communications between soil scientists, hydrologists, and hydrogeologists. The terms defined in the glossary were selected after an extensive survey of glossaries and reports in the areas of (1) ground-water geology, hydraulics, and chemistry, (2) soil-water physics and chemistry, (3) contaminant transport, (4) unsaturated-zone hydrology, (5) chemistry and transport of solutes, and (6) ground-water quality. Some of the definitions have been modified for clarity from a variety of technical sources. Where more than one definition appears for the selected term, the first one was determined by the working group to be the most appropriate general definition, followed by other, more specialized, definitions. Some terms and definitions are not currently in use by all agencies; however, they are included in the glossary because they can be found in the literature. The reader is encouraged to consult with the original source cited for more explanatory comments. Additional regulatory definitions, which are underlined and are taken directly from the Code of Federal Regulations (CFR) and Federal laws (USC), were added following review by the various Federal agencies in May 1986. The definitions and conversion charts are from two principal sources provided herein. The first is the 11Glossary11 compiled by A. I. Johnson in the 1981 report by the American Society of Testing and Materials titled Permeability and Groundwater Contaminant Transport. The second is Manu a 1 40, 11Ground-water Management, 11 produced by the American Society of Civil Engineers in 1985.

Report↗
USGS2004

Ground-water flow direction, water quality, recharge sources, and age, Great Sand Dunes National Monument, south-central Colorado

Great Sand Dunes National Monument is located in south-central Colorado along the eastern edge of the San Luis Valley. The Great Sand Dunes National Monument contains the tallest sand dunes in North America; some rise up to750 feet. Important ecological features of the Great Sand Dunes National Monument are palustrine wetlands associated with interdunal ponds and depressions along the western edge of the dune field. The existence and natural maintenance of the dune field and the interdunal ponds are dependent on maintaining ground-water levels at historic elevations. To address these concerns, the U.S. Geological Survey conducted a study, in collaboration with the National Park Service, of ground-water flow direction, water quality, recharge sources, and age at the Great Sand Dunes National Monument. A shallow unconfined aquifer and a deeper confined aquifer are the two principal aquifers at the Great Sand Dunes National Monument. Ground water in the unconfined aquifer is recharged from Medano and Sand Creeks near the Sangre de Cristo Mountain front, flows underneath the main dune field, and discharges to Big and Little Spring Creeks. The percentage of calcium in ground water in the unconfined aquifer decreases and the percentage of sodium increases because of ionic exchange with clay minerals as the ground water flows underneath the dune field. It takes more than 60 years for the ground water to flow from Medano and Sand Creeks to Big and Little Spring Creeks. During this time, ground water in the upper part of the unconfined aquifer is recharged by numerous precipitation events. Evaporation of precipitation during recharge prior to reaching the water table causes enrichment in deuterium (2H) and oxygen-18 (18O) relative to waters that are not evaporated. This recharge from precipitation events causes the apparent ages determined using chlorofluorocarbons and tritium to become younger, because relatively young precipitation water is mixing with older waters derived from Medano and Sand Creeks. Major ion chemistry of water from sites completed in the confined aquifer is different than water from sites completed in the unconfined aquifer, but insufficient data exist to quantify if the two aquifers are hydrologically disconnected. Radiocarbon dating of ground water in the confined aquifer indicates it is about 30,000 years old (plus or minus 3,000 years). The peak of the last major ice advance (Wisconsin) during the ice age occurred about 20,000 years before present; ground water from the confined aquifer is much older than that. Water quality and water levels of the interdunal ponds are not affected by waters from the confined aquifer. Instead, the interdunal ponds are affected directly by fluctuations in the water table of the unconfined aquifer. Any lowering of the water table of the unconfined aquifer would result in an immediate decrease in water levels of the interdunal ponds. The water quality of the interdunal ponds probably results from several factors, including the water quality of the unconfined aquifer, evaporation of the pond water, and biologic activity within the ponds.

Colorado↗
USGS2004

Use of borehole radar methods and borehole geophysical logs to monitor a field-scale vegetable oil biostimulation pilot project at Fridley, Minnesota

Cross-hole and surface-to-borehole radar and conventional borehole geophysical logs were used to monitor subsurface injections of vegetable oil emulsion conducted as part of a field-scale biostimulation pilot project at the Anoka County Riverfront Park (ACP), located downgradient of the Naval Industrial Reserve Ordnance Plant (NIROP), in Fridley, Minnesota. The pilot project was undertaken to evaluate biostimulation using emulsified vegetable oil for treatment of ground water contaminated with chlorinated hydrocarbons. The objectives of the geophysical investigations were to delineate the distribution of vegetable oil injected at NIROP, and evaluate the utility of adding geophysical tracers to the vegetable oil emulsions. Geophysical data were acquired by the U.S Geological Survey in five site visits over 1.5 years. This paper presents (1) level-run radar traveltime and amplitude data; (2) radar cross-hole traveltime tomograms; (3) vertical-radar profile diffraction tomograms; and (4) borehole electromagnetic induction logs. Based on comparison of pre- and postinjection data sets, a conceptual model was developed to define the distribution of emulsified vegetable oil and the extent of ground water having altered chemistry resulting from injections and, possibly, enhanced microbial degradation of chlorinated hydrocarbons. Radar slowness (reciprocal velocity) anomalies indicate that the emplaced oil emulsion remained close to the injection wells, whereas attenuation anomalies indicate changes in ground-water chemistry downgradient of all three injections.

Minnesota↗
USGS2015

Hydrologic and geochemical dynamics of vadose zone recharge in a mantled karst aquifer: Results of monitoring drip waters in Mystery Cave, Minnesota

Caves provide direct access to flows through the vadose zone that recharge karst aquifers. Although many recent studies have documented the highly dynamic processes associated with vadose zone flows in karst settings, few have been conducted in mantled karst settings, such as that of southeastern Minnesota. Here we present some results of a long-term program of cave drip monitoring conducted within Mystery Cave, Minnesota. In this study, two perennial ceiling drip sites were monitored between 1997 and 2001. The sites were located about 90 m (300 ft) apart along the same cave passage approximately 18 m (60 ft) below the surface; 7 to 9 m (20 to 30 ft) of loess and 12 m (40 ft) of flat-lying carbonate bedrock strata overlie the cave. Records of drip rate, electrical conductivity, and water temperature were obtained at 15 minute intervals, and supplemented with periodic sampling for major ion chemistry and water stable isotopes. Patterns in flow and geochemistry emerged at each of the two drip sites that were repeated year after year. Although one site responded relatively quickly (within 2-7 hours) to surface recharge events while the other responded more slowly (within 2-5 days), thresholds of antecedent moisture needed to be overcome in order to produce a discharge response at both sites. The greatest amount of flow was observed at both sites during the spring snowmelt period. Rainfall events less than 10 mm (0.4 in) during the summer months generally did not produce a drip discharge response, yet rapid drip responses were observed following intense storm events after periods of prolonged rainfall. The chemical data from both sites indicate that reservoirs of vadose zone water with distinct chemical signatures mixed during recharge events, and drip chemistry returned to a baseline composition during low flow periods. A reservoir with elevated chloride and sulfate concentrations impacts the slow-response drip site with each recharge event, but does not similarly affect the fast-response drip site. Nitrate concentrations in drip waters were generally less than 4.0 mg/L as NO3- (or less than 1 mg/L as N). Nitrate was either stable or slightly increased with drip rate at the fast-response drip site; in contrast, nitrate concentrations decreased with drip rate at the slow-response drip site.

Conference Paper↗
USGS2006

Questa baseline and pre-mining ground-water quality investigation. 21. Hydrology and water balance of the Red River Basin, New Mexico, 1930-2004

A study of the hydrology of the Red River Basin of northern New Mexico, including development of a pre- mining water balance, contributes to a greater understanding of processes affecting the flow and chemistry of water in the Red River and its alluvial aquifer. Estimates of mean annual precipitation for the Red River Basin ranged from 22.32 to 25.19 inches. Estimates of evapotranspiration for the Red River Basin ranged from 15.02 to 22.45 inches or 63.23 to 94.49 percent of mean annual precipitation. Mean annual yield from the Red River Basin estimated using regression equations ranged from 45.26 to 51.57 cubic feet per second. Mean annual yield from the Red River Basin estimated by subtracting evapotranspiration from mean annual precipitation ranged from 55.58 to 93.15 cubic feet per second. In comparison, naturalized 1930-2004 mean annual streamflow at the Red River near Questa gage was 48.9 cubic feet per second. Although estimates developed using regression equations appear to be a good representation of yield from the Red River Basin as a whole, the methods that consider evapotranspiration may more accurately represent yield from smaller basins that have a substantial amount of sparsely vegetated scar area. Hydrograph separation using the HYSEP computer program indicated that subsurface flow for 1930-2004 ranged from 76 to 94 percent of streamflow for individual years with a mean of 87 percent of streamflow. By using a chloride mass-balance method, ground-water recharge was estimated to range from 7 to 17 percent of mean annual precipitation for water samples from wells in Capulin Canyon and the Hansen, Hottentot, La Bobita, and Straight Creek Basins and was 21 percent of mean annual precipitation for water samples from the Red River. Comparisons of mean annual basin yield and measured streamflow indicate that streamflow does not consistently increase as cumulative estimated mean annual basin yield increases. Comparisons of estimated mean annual yield and measured streamflow profiles indicates that, in general, the river is gaining ground water from the alluvium in the reach from the town of Red River to between Hottentot and Straight Creeks, and from Columbine Creek to near Thunder Bridge. The river is losing water to the alluvium from upstream of the mill area to Columbine Creek. Interpretations of ground- and surface-water interactions based on comparisons of mean annual basin yield and measured streamflow are supported further with water-level data from piezometers, wells, and the Red River.

New Mexico↗
USGS2001

Ground-water flow to Death Valley, as inferred from the chemistry and geohydrology of selected springs in Death Valley National Park, California and Nevada

Death Valley lies downgradient from adjacent valleys to the north, south, east, and west in California and Nevada, and is the site of substantial ground-water discharge. The sources of the discharging waters have been discussed by several investigators in the past and are of heightened concern because of the potential disposal of high-level radioactive waste at Yucca Mountain, Nevada, and because of ground-water withdrawals attendant to commercial mining in the northwestern Amargosa Valley region. This report describes high- and low-discharge springs in and along the Amargosa Range that were sampled to augment the level of understanding of the extent and distribution of westward ground-water flow through the range. The Black Mountains do not seem to be part of a significant path of ground-water flow from the Amargosa region. This is attributed to the complex lithology and geologic history of the Black Mountains structural block and to the presence of the intervening Furnace Creek fault zone. The only ground-water discharge associated with the Black Mountains where water chemistry reflects an external source or sources is Saratoga Spring, for which δ 2 H and δ 18 O data indicate recharge in the Spring Mountains to the east. The southern part of the Funeral Mountains transmits a large volume of water through faulted and fractured rocks of Cambrian age that lie at or along the distal part of the northeast -oriented Spotted Range-Mine Mountain structural zone. Waters discharging from springs in the Furnace Creek Ranch vicinity (Travertine and Nevares) both compositionally and isotopically resemble waters from the Ash Meadows spring group in the Amargosa Desert. The Ash Meadows springs and water in the Amargosa Valley alluvium likely are chemically representative of ground water entering the southern Funeral Mountains. Much less ground water flows through the central and northern Funeral Mountains than flows through the southern part, as indicated by the geologic setting and chemistry of Keane Wonder Spring. The northern one-half of the mountains comprises early-to-middle Proterozoic metamorphic rocks that are the core of the Funeral Mountains anticlinorium. The core is largely unfaulted, plunges to the northeast and southwest, and is truncated to some extent on the east by the shallow-dipping Boundary Canyon fault. This structural setting and the paucity of springs in the northern one-half of the Funeral Mountains indicate a long traveltime from the Amargosa region to the western margin of the northern and central parts of the mountains. The Grapevine Mountains include the highest elevations in the Amargosa Range. Substantial precipitation and recharge above about 2,000 meters are evinced by numerous small springs and seeps along the east and west margins. The local nature of the recharge is reflected in δ 2 H and δ 18 O values and in the spring chemistries that indicate control by Tertiary volcanic rocks. The highest spring discharges associated with the Grapevine Mountains are near the north end of the mountains in the Grapevine Ranch area. The springs in this area are similar chemically and isotopically, except for one or two order-of-magnitude differences in calcium, magnesium, and strontium concentrations and a 1.2 per mil difference in δ 13 C values. These differences can be attributed to differences in the distal parts of the respective flow paths. The springs also lie at the end of a northeast -oriented structural zone in the Walker Lane Belt, and their δ 2 H, δ 13 C, and δ 18 O values indicate a recharge area likely to the northeast, outside of the Grapevine Mountains.

California;Nevada↗
USGS2007

Bottom sediments and pore waters near a hydrothermal vent in Lake Baikal (Frolikha Bay)

We discuss the redox environments and the compositions of bottom sediments and sedimentary pore waters in the region of a hydrothermal vent in Frolikha Bay, Lake Baikal. According to our results, the submarine vent and its companion nearby spring on land originate from a common source. The most convincing evidence for their relation comes from the proximity of stable oxygen and hydrogen isotope compositions in pore waters and in the spring water. The isotope composition indicates a meteoric origin of pore waters, but their major- and minor-element chemistry bears imprint of deep water which may seep through permeable faulted crust. Although pore waters near the submarine vent have a specific enrichment in major and minor constituents, hydrothermal discharge at the Baikal bottom causes a minor impact on the lake water chemistry, unlike the case of freshwater geothermal lakes in the East-African Rift and North America. ?? 2007.

Russian Geology and Geophysics↗
USGS2006

Characterization of seepage in the exploratory studies facility, Yucca Mountain, Nevada

Following a 5-month period of above-average precipitation during the winter of 2004-2005, water was observed seeping into the South Ramp section of the Exploratory Studies Facility of the proposed repository for high-level radioactive waste at Yucca Mountain, Nevada. Samples of the seepage were collected and analyzed for major ions, trace metals, and delta deuterium and delta oxygen-18 values in an effort to characterize the water and assess the interaction of seepage with anthropogenic materials used in the construction of the proposed repository. As demonstrated by the changes in the chemistry of water dripping from a rock bolt, interaction of seepage with construction materials can alter solution chemistry and oxidation state.

Conference Paper↗
USGS2021

Hydrology and water quality of the Great Dismal Swamp, Virginia and North Carolina, and implications for hydrologic-management goals and strategies

The Great Dismal Swamp is a peat wetland in the Coastal Plain of southeastern Virginia and northeastern North Carolina. Timber harvesting and the construction of ditches to drain the swamp and facilitate the harvesting are collectively implicated in changes that altered the wetland forests, caused subsidence and decomposition of the peat, and increased the risk of fire. In response to these changes, managers have implemented strategies to control water levels and rewet the swamp using a network of 64 adjustable-height, water-control structures on the ditches. Rewetting the swamp is intended to re-establish the original wetland-forest types, reduce the risk of fire, reduce subsidence and decomposition of the peat, enhance peat accretion, and reduce the risk of fire. Knowledge of responses of the swamp to hydrologic controls, however, is critical to developing and implementing effective management goals and strategies. Because the 2008 South One fire reemphasized the need for this knowledge, the U.S. Geological Survey in cooperation with the U.S. Fish and Wildlife Service began studies in 2009 to identify critical hydrologic controls and responses to these controls. These studies identified water sources, topography, the two-layered hydraulic characteristics of the peat, the absence of peat in some areas, the ditch and road network, water-control structures on the ditches, the Dismal Swamp Canal and associated infrastructure, and wetland forests as the primary hydrologic controls. Precipitation is the only water source across much of the swamp. The eastward flow of streams and groundwater from the Isle of Wight Plain, across the Suffolk scarp, and into the swamp are additional water sources to the western part of the swamp. Vertical differences in the hydraulic characteristics of the peat reflect an upper peat having a high hydraulic conductivity and specific yield overlying a lower peat and sand having lower hydraulic conductivity and specific yield. The upper peat forms the main aquifer for the storage, flow, and release of water from the swamp. Maintaining water in the upper peat is critical to water availability to the wetland forests because of these properties. Groundwater flows from the swamp into the ditches and the Dismal Swamp Canal where it discharges into nearby streams. Discharge typically is to the closest ditch except where a spoil-pile road that impedes flow intervenes between the swamp and the ditch. When groundwater levels in a ditch are about 2 feet lower than levels in the other three ditches surrounding a part of the swamp, however, most groundwater typically discharges to the ditch having the lower level. This occurs even if a spoil-pile road intervenes between the swamp and the ditch having the lower level. Flow to a single ditch shifts watershed boundaries and groundwater divides toward the ditches having higher water levels and demonstrates how flow and discharge are controlled by ditch water levels. Consequently, managing water levels based on these and other hydrologic controls and responses is critical to achieving management objectives. The chemistry of water across the swamp shows the effects of the peat. Dissolved organic carbon concentrations in the groundwater are among the highest reported globally, ranging from 55 to 195 milligrams per liter. The pH of groundwater and ditch water is commonly less than 4.0 standard units because of organic acids. A relation between the pH and specific conductance of groundwater and ditch water reflects water sources, flow paths, and the chemical evolution, as waters from the different sources mix and flow along the paths.

North Carolina, Virginia↗
USGS2003

Hydrogeology and geochemistry of aquifers underlying the San Lorenzo and San Leandro areas of the East Bay Plain, Alameda County, California

The East Bay Plain, on the densely populated eastern shore of San Francisco Bay, contains an upper aquifer system to depths of 250 feet below land surface and an underlying lower aquifer system to depths of more than 650 feet. Injection and recovery of imported water has been proposed for deep aquifers at two sites within the lower aquifer system. Successful operation requires that the injected water be isolated from surface sources of poor-quality water during storage and recovery. Hydraulic, geochemical, and isotopic data were used to evaluate the isolation of deeper aquifers. Ground-water responses to tidal changes in the Bay suggest that thick clay layers present within these deposits effectively isolate the deeper aquifers in the northern part of the study area from overlying surficial deposits. These data also suggest that the areal extent of the shallow and deep aquifers beneath the Bay may be limited in the northern part of the study area. Despite its apparent hydraulic isolation, the lower aquifer system may be connected to the overlying upper aquifer system through the corroded and failed casings of abandoned wells. Water-level measurements in observation wells and downward flow measured in selected wells during nonpumped conditions suggest that water may flow through wells from the upper aquifer system into the lower aquifer system during nonpumped conditions. The chemistry of water from wells in the East Bay Plain ranges from fresh to saline; salinity is greater than seawater in shallow estuarine deposits near the Bay. Water from wells completed in the lower aquifer system has higher pH, higher sodium, chloride, and manganese concentrations, and lower calcium concentrations and alkalinity than does water from wells completed in the overlying upper aquifer system. Ground-water recharge temperatures derived from noble-gas data indicate that highly focused recharge processes from infiltration of winter streamflow and more diffuse recharge processes from infiltration of precipitation occur within the study area. However, recharge of imported water from leaking water-supply pipes, believed by previous investigators to be a large source of ground-water recharge, was not supported on the basis of oxygen-18 and deuterium data collected as part of this study. Based on tritium/helium-3 ages, most water in the upper aquifer system is relatively young and was recharged after 1952; however, water in the lower aquifer system is older and does not contain detectable tritium. Carbon-14 ages interpreted for water from wells in the lower aquifer system and underlying partly consolidated rocks range from 500 to more than 20,000 years before present. The greatest ages were in water from wells completed in the partly consolidated deposits that underlie the northern part of the study area. Ground water from wells in the lower aquifer system near the proposed Bayside injection/recovery site was recharged about 9,400 years before present and appears to be isolated from surface sources of recharge and ground-water contamination.

California↗
USGS2012

Electrical properties of granite with implications for the lower crust

The electrical properties of granite appear to be dominantly controlled by the amount of free water in the granite and by temperature. Minor contributions to the electrical properties are provided by hydrostatic and lithostatic pressure, structurally bound water, oxygen fugacity, and other parameters. The effect of sulfur fugacity may be important but is experimentally unconfirmed. In addition to changing the magnitude of electrical properties, the amount and chemistry of water in granite significantly changes the temperature dependence of the electrical properties. With increasing temperature, changes in water content retain large, but lessened, effects on electrical properties. Near room temperature, a monolayer of water will decrease the electrical resistivity by an order of magnitude. Several weight-percent water may decrease the electrical resistivity by as much as 9 orders of magnitude and decrease the thermal activation energy by a factor of 5. At elevated temperatures just below granitic melting, a few weight-percent water may still decrease the resistivity by as much as 3 orders of magnitude and the activation energy by a factor of 2. Above the melting temperature (650° to 1100°C depending upon water pressure), a few weight-percent water will decrease the resistivity by less than an order of magnitude and will barely change the activation energy. Remarkably, the few weight-percent water must be present as free water. Experiments with hydrated hornblende schist (with structural water) indicate an electrical resistivity very similar to that for dry granite. The implications of these results, together with the findings of deep magnetic sounding and magnetotelluric surveys, suggest much more free water than is commonly associated with the lower crust and possibly into the upper mantle.

Journal of Geophysical Research Solid Earth↗
USGS2015

Critical loads of atmospheric deposition to Adirondack lake watersheds: A guide for policymakers

Acid deposition is sometimes referred to as “acid rain,” although part of the acid load reaches the surface by means other than rainfall. In the eastern U.S., acid deposition consists of several forms of sulfur and nitrogen that largely originate as emissions to the atmosphere from sources such as electricity-generating facilities (coal, oil, and natural gas), diesel- and gasoline-burning vehicles, some agricultural activities, and smokestack industries. Acid deposition is known to cause deleterious effects to sensitive ecosystems of which the Adirondack region of New York State provides several well-known and well-studied examples. This largely forested region includes abundant lakes, streams, and wetlands and possesses several landscape features that result in high ecosystem sensitivity to acid deposition. These features include bedrock that weathers slowly, steep slopes, and thin, naturally acidic soils. An ecosystem is described as sensitive to, or affected by, acid deposition if prolonged exposure to acid deposition has resulted in detrimental ecosystem effects. Soils, streams, and lakes that are less sensitive are better able to buffer acid deposition. A principal reason that acidification is a concern for resource managers is because of the changes induced in native biota and their habitat on land and in water. As the chemistry of soils and surface waters in sensitive landscapes changes in response to prolonged exposure to acid deposition, organisms that cannot tolerate high acidity, such as sugar maple trees and many species of fish and aquatic insects, may be gradually eliminated from the ecosystem. Other biota such as red spruce may experience increased stress and reduced growth rates as a result of acidification, exposing these species to increased susceptibility to disease and other natural stressors and perhaps increased mortality. The ecological effects of acid deposition have been documented by extensive research that began in the U.S. in the 1970s and continues today. This report does not provide a detailed discussion of these ecological effects, but interested readers can refer to four publications that provide good summaries of current scientific knowledge of these effects, including extensive reference to previous research in the Adirondacks (Driscoll et al. 2001, Jenkins et al. 2007, Burns et al. 2011, Sullivan 2015).

New York↗
USGS2006

Coastal groundwater/surface-water interactions: a Great Lakes case study

Key similarities exist between marine and Great Lakes coastal environments. Water and nutrient fluxes across lakebeds in the Great Lakes are influenced by seiche and wind set-up and set-down, analogous to tidal influence in marine settings. Groundwater/surface-water interactions also commonly involve a saline-fresh water interface, although in the Great-Lakes cases, it is groundwater that is commonly saline and surface water that is fresh. Evapotranspiration also affects nearshore hydrology in both settings. Interactions between groundwater and surface water have recently been identified as an important component of ecological processes in the Great Lakes. Water withdrawals and the reversal of the groundwater/surface water seepage gradient are also common to many coastal areas around the Great Lakes. As compared to surface water, regional groundwater that discharges to western Lake Erie from Michigan is highly mineralized. Studies conducted by the U.S. Geological Survey at Erie State Game Area in southeastern Michigan, describe groundwater flow dynamics and chemistry, shallow lake-water chemistry, and fish and invertebrate communities. Results presented here provide an overview of recent progress of ongoing interdisciplinary studies of Great Lakes nearshore systems and describe a conceptual model that identifies relations among geologic, hydrologic, chemical, and biological processes in the coastal habitats of Lake Erie. This conceptual model is based on analysis of hydraulic head in piezometers at the study site and chemical analysis of deep and shallow coastal groundwater.

Book chapter↗
USGS2006

The influence of geology and land use on arsenic in stream sediments and ground waters in New England, USA

Population statistics for As concentrations in rocks, sediments and ground water differ by geology and land use features in the New England region, USA. Significant sources of As in the surficial environment include both natural weathering of rocks and anthropogenic sources such as arsenical pesticides that were commonly applied to apple, blueberry and potato crops during the first half of the 20th century in the region. The variation of As in bedrock ground water wells has a strong positive correlation with geologic features at the geologic province, lithology group, and bedrock map unit levels. The variation of As in bedrock ground water wells also has a positive correlation with elevated stream sediment and rock As chemistry. Elevated As concentrations in bedrock wells do not correlate with past agricultural areas that used arsenical pesticides on crops. Stream sediments, which integrate both natural and anthropogenic sources, have a strong positive correlation of As concentrations with rock chemistry, geologic provinces and ground water chemistry, and a weaker positive correlation with past agricultural land use. Although correlation is not sufficient to demonstrate cause-and-effect, the statistics favor rock-based As as the dominant regional source of the element in stream sediments and ground water in New England. The distribution of bedrock geology features at the geologic province, lithology group and map unit level closely correlate with areas of elevated As in ground water, stream sediments, and rocks. ?? 2006 Elsevier Ltd. All rights reserved.

Applied Geochemistry↗
USGS2007

Seasonal and interannual variability in the taxonomic composition and production dynamics of phytoplankton assemblages in Crater Lake, Oregon

Taxonomic composition and production dynamics of phytoplankton assemblages in Crater Lake, Oregon, were examined during time periods between 1984 and 2000. The objectives of the study were (1) to investigate spatial and temporal patterns in species composition, chlorophyll concentration, and primary productivity relative to seasonal patterns of water circulation; (2) to explore relationships between water column chemistry and the taxonomic composition of the phytoplankton; and (3) to determine effects of primary and secondary consumers on the phytoplankton assemblage. An analysis of 690 samples obtained on 50 sampling dates from 14 depths in the water column found a total of 163 phytoplankton taxa, 134 of which were identified to genus and 101 were identified to the species or variety level of classification. Dominant species by density or biovolume included Nitzschia gracilis, Stephanodiscus hantzschii, Ankistrodesmus spiralis, Mougeotia parvula, Dinobryon sertularia, Tribonema affine, Aphanocapsa delicatissima, Synechocystis sp., Gymnodinium inversum , and Peridinium inconspicuum . When the lake was thermally stratified in late summer, some of these species exhibited a stratified vertical distribution in the water column. A cluster analysis of these data also revealed a vertical stratification of the flora from the middle of the summer through the early fall. Multivariate test statistics indicated that there was a significant relationship between the species composition of the phytoplankton and a corresponding set of chemical variables measured for samples from the water column. In this case, concentrations of total phosphorus, ammonia, total Kjeldahl nitrogen, and alkalinity were associated with interannual changes in the flora; whereas pH and concentrations of dissolved oxygen, orthophosphate, nitrate, and silicon were more closely related to spatial variation and thermal stratification. The maximum chlorophyll concentration when the lake was thermally stratified in August and September was usually between depths of 100 m and 120 m. In comparison, the depth of maximum primary production ranged from 60 m to 80 m at this time of year. Regression analysis detected a weak negative relationship between chlorophyll concentration and Secchi disk depth, a measure of lake transparency. However, interannual changes in chlorophyll concentration and the species composition of the phytoplankton could not be explained by the removal of the septic field near Rim Village or by patterns of upwelling from the deep lake. An alternative trophic hypothesis proposes that the productivity of Crater Lake is controlled primarily by long-term patterns of climatic change that regulate the supply of allochthonous nutrients.

Crater Lake↗
USGS2005

Effect of sewage sludge on formation of acidic ground water at a reclaimed coal mine

Data on rock, ground water, vadose water, and vadose gas chemistry were collected for two years after sewage sludge was applied at a reclaimed surface coal mine in Pennsylvania to determine if surface-applied sludge is an effective barrier to oxygen influx, contributes metals and nutrients to ground water, and promotes the acidification of ground water. Acidity, sulfate, and metals concentrations were elevated in the ground water (6- to 21-m depth) from spoil relative to unmined rock because of active oxidation of pyrite and dissolution of aluminosilicate, carbonate, and Mn-Fe-oxide minerals in the spoil. Concentrations of acidity, sulfate, metals (Fe, Mn, Al, Cd, Cu, Cr, Ni, Zn), and nitrate, and abundances of iron-oxidizing bacteria were elevated in the ground water from sludge-treated spoil relative to untreated spoil having a similar mineral composition; however, gaseous and dissolved oxygen concentrations did not differ between the treatments. Abundances of iron-oxidizing bacteria in the ground water samples were positively correlated with concentrations of ammonia, nitrate, acidity, metals, and sulfate. Concentrations of metals in vadose water samples (<5-m depth) from sludge-treated spoil (pH 5.9) were not elevated relative to untreated spoil (pH 4.4). In contrast, concentrations of nitrate were elevated in vadose water samples from sludge-treated spoil, frequently exceeding 10 mg/L. Downgradient decreases in nitrate to less than 3 mg/L and increases in sulfate concentrations in underlying ground water could result from oxidation of pyrite by nitrate. Thus, sewage sludge added to pyritic spoil can increase the growth of iron-oxidizing bacteria, the oxidation of pyrite, and the acidification of ground water. Nevertheless, the overall effects on ground water chemistry from the sludge were small and probably short-lived relative to the effects from mining only.

Pennsylvania↗
USGS1999

Application of geologic map information to water quality issues in the southern part of the Chesapeake Bay watershed, Maryland and Virginia, eastern United States

Geologic map units contain much information about the mineralogy, chemistry, and physical attributes of the rocks mapped. This paper presents information from regional-scale geologic maps in Maryland and Virginia, which are in the southern part of the Chesapeake Bay watershed in the eastern United States. The geologic map information is discussed and analyzed in relation to water chemistry data from shallow wells and stream reaches in the area. Two environmental problems in the Chesapeake Bay watershed are used as test examples. The problems, high acidity and high nitrate concentrations in streams and rivers, tend to be mitigated by some rock and sediment types and not by others. Carbonate rocks (limestone, dolomite, and carbonate-cemented rocks) have the greatest capacity to neutralize acidic ground water and surface water in contact with them. Rocks and sediments having high carbon or sulfur contents (such as peat and black shale) potentially contribute the most toward denitrification of ground water and surface water in contact with them. Rocks and sediments that are composed mostly of quartz, feldspar, and light-colored clay (rocks such as granite and sandstone, sediments such as sand and gravel) tend not to alter the chemistry of waters that are in contact with them. The testing of relationships between regionally mapped geologic units and water chemistry is in a preliminary stage, and initial results are encouraging.Geologic map units contain much information about the mineralogy, chemistry, and physical attributes of the rocks mapped. This paper presents information from regional-scale geologic maps in Maryland and Virginia, which are in the southern part of the Chesapeake Bay watershed in the eastern United States. The geologic map information is discussed and analyzed in relation to water chemistry data from shallow wells and stream reaches in the area. Two environmental problems in the Chesapeake Bay watershed are used as test examples. The problems, high acidity and high nitrate concentrations in streams and rivers, tend to be mitigated by some rock and sediment types and not by others. Carbonate rocks (limestone, dolomite, and carbonate-cemented rocks) have the greatest capacity to neutralize acidic ground water and surface water in contact with them. Rocks and sediments having high carbon or sulfur contents (such as peat and black shale) potentially contribute the most toward denitrification of ground water and surface water in contact with them. Rocks and sediments that are composed mostly of quartz, feldspar, and light-colored clay (rocks such as granite and sandstone, sediments such as sand and gravel) tend not to alter the chemistry of waters that are in contact with them. The testing of relationships between regionally mapped geologic units and water chemistry is in a preliminary stage, and initial results are encouraging.

Journal of Geochemical Exploration↗