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Seasonal ice and hydrologic controls on dissolved organic carbon and nitrogen concentrations in a boreal-rich fen

[1] Boreal wetland carbon cycling is vulnerable to climate change in part because hydrology and the extent of frozen ground have strong influences on plant and microbial functions. We examined the response of dissolved organic carbon (DOC) and total dissolved nitrogen (TDN) across an experimental manipulation of water table position (both raised and lowered water table treatments) in a boreal-rich fen in interior Alaska. DOC and TDN responses to water table manipulation exhibited an interaction with seasonal ice dynamics. We observed consistently higher DOC and TDN concentrations in the lowered water table treatment (71.7 ± 6.5 and 3.0 ± 0.3 mg−L) than in both the control (55.6 ± 5.1 and 2.3 ± 0.2 mg−L) and raised (49.1 ± 4.3 and 1.9 ± 0.1 mg L−1, respectively) water table treatments. Across all plots, pore water DOC concentrations at 20 cm increased as the depth to water table increased (R2 = 0.43, p < 0.001). DOC concentrations also increased as the seasonal thaw depth increased, with solutes increasing most rapidly in the drained plot (R2 = 0.62, p < 0.001). About half of the TDN pool was composed of dissolved organic N (DON). Inorganic N and DON were both highly correlated with changes in DOC, and their respective constraints to mineralization are discussed. These results demonstrate that a declining water table position and dryer conditions affect thaw depth and peat temperatures, and interactions among these ecosystem properties will likely increase DOC and TDN loading and potential for export in these systems.

Alaska↗

Sulfur- and oxygen-isotopes in sediment-hosted stratiform barite deposits

Sulfur- and oxygen-isotope analyses have been obtained for sediment-hosted stratiform barite deposits in Alaska, Nevada, Mexico, and China to examine the environment of formation of this deposit type. The barite is contained in sedimentary sequences as old as Late Neoproterozoic and as young as Mississippian. If previously published data for other localities are considered, sulfur- and oxygen-isotope data are now available for deposits spanning a host-rock age range of Late Neoproterozoic to Triassic. On a ??34S versus ??18O diagram, many deposits show linear or concave-upward trends that project down toward the isotopic composition of seawater sulfate. The trends suggest that barite formed from seawater sulfate that had been isotopically modified to varying degrees. The ??34S versus ??18O patterns resemble patterns that have been observed in the modern oceans in pore water sulfate and water column sulfate in some anoxic basins. However, the closest isotopic analog is barite mineralization that occurs at fluid seeps on modern continental margins. Thus the data favor genetic models for the deposits in which barium was delivered by seafloor seeps over models in which barium was delivered by sedimentation of pelagic organisms. The isotopic variations within the deposits appear to reflect bacterial sulfate reduction operating at different rates and possibly with different electron donors, oxygen isotope exchange between reduction intermediates and H2O, and sulfate availability. Because they are isotopically heterogeneous, sediment-hosted stratiform barite deposits are of limited value in reconstructing the isotopic composition of ancient seawater sulfate.

Geochimica et Cosmochimica Acta↗

Geologic and Geochronologic Studies of the Early Proterozoic Kanektok Metamorphic Complex of Southwestern Alaska

The Kanektok complex of southwestern Alaska appears to be a rootless terrane of early Proterozoic sedimentary, volcanic, and intrusive rocks which were metamorphosed to amphibolite and granulite facies and later underwent a pervasive late Mesozoic thermal event accompanied by granitic plutonism and greenschist facies metamorphism of overlying sediments. The terrane is structurally complex and exhibits characteristics generally attributed to mantled gneiss domes. U-Th-Pb analyses of zircon and sphene from a core zone granitic orthogneiss indicate that the orthogneiss protolith crystallized about 2.05 b.y. ago and that the protolithic sedimentary, volcanic and granitic intrusive rocks of the core zone were metamorphosed to granulite and amphibolite facies about 1.77 b.y. ago. A Rb-Sr study of 13 whole-rock samples also suggests metamorphism of an early Proterozoic [Paleoproterozoic] protolith at 1.77 Ga, although the data are scattered and difficult to interpret. Seventy-seven conventional 40K/40Ar mineral ages were determined for 58 rocks distributed throughout the outcrop area of the complex. Analysis of the K-Ar data indicate that nearly all of these ages have been totally or partially reset by a pervasive late Mesozoic thermal event accompanied by granitic plutonism and greenschist facies metamorphism. Several biotites gave apparent K-Ar ages over 2 Ga. These ages appear to be controlled by excess radiogenic 40Ar produced by the degassing protolith during the 1.77 Ga metamorphism and incorporated by the biotites when they were at temperatures at which Ar could diffuse through the lattice. Five amphibolites yielded apparent Precambrian 40K/40Ar hornblende ages. There is no evidence that these hornblende ages have been increased by excess argon. The oldest 40K/40Ar hornblende age of 1.77 Ga is identical to the sphene 207Pb/206Pb orthogneiss age and to the Rb-Sr 'isochron' age for six of the 13 whole-rock samples. The younger hornblende ages are interpreted as having been partially reset during the late Mesozoic thermal event. 40Ar/39Ar incremental heating experiments suggest metamorphism occurred at least 1.2 b.y. ago but do not exhibit high temperature plateau ages significantly older than the 40Ar/39Ar total fusion ages of these samples. The age spectra are much more uniform than expected from a terrane with such a complex thermal history, perhaps caused by the small grain size of the samples which may possibly be less than the effective Ar diffusion radii of the analyzed hornblendes.

Open-File Report↗

Controls on methane released through ebullition in peatlands affected by permafrost degradation

Permafrost thaw in peat plateaus leads to the flooding of surface soils and the formation of collapse scar bogs, which have the potential to be large emitters of methane (CH 4 ) from surface peat as well as deeper, previously frozen, permafrost carbon (C). We used a network of bubble traps, permanently installed 20&thinsp;cm and 60&thinsp;cm beneath the moss surface, to examine controls on ebullition from three collapse bogs in interior Alaska. Overall, ebullition was dominated by episodic events that were associated with changes in atmospheric pressure, and ebullition was mainly a surface process regulated by both seasonal ice dynamics and plant phenology. The majority (>90%) of ebullition occurred in surface peat layers, with little bubble production in deeper peat. During periods of peak plant biomass, bubbles contained acetate-derived CH 4 dominated (>90%) by modern C fixed from the atmosphere following permafrost thaw. Post-senescence, the contribution of CH 4 derived from thawing permafrost C was more variable and accounted for up to 22% (on average 7%), in the most recently thawed site. Thus, the formation of thermokarst features resulting from permafrost thaw in peatlands stimulates ebullition and CH 4 release both by creating flooded surface conditions conducive to CH 4 production and bubbling as well as by exposing thawing permafrost C to mineralization.

Alaska↗

The Kanuti ophiolite, Alaska

The Kanuti ophiolite is a mafic-ultramafic thrust sheet of probable Jurassic age, formerly considered to be the upper part of the Yukon-Koyukuk ophiolite belt (Angayucham terrane). It is here called the Kanuti ophiolite after the Kanuti River region on the southeastern flank of the Yukon-Koyukuk Basin. The thrust sheet crops out discontinuously for a distance of more than 900 km along the northern and southeastern margins of the basin. It is probably correlative with similar ophiolite thrust sheets to the north in the western Brooks Range and to the south in the Ruby geanticline. Technically, the ophiolite is considered to be the Kanuti thrust panel of the Angayucham-Totzitna terrane. The Kanuti consistently overlies another extensive thrust sheet, consisting mostly of pillow basalt and radiolarian chert of Devonian to Jurassic age (Narvak thrust panel). This sheet is thrust over a third sheet consisting of probable Devonian phyllite and metagraywacke, which is in turn thrust over older metamorphic rocks (Slate Creek thrust panel). The Kanuti ophiolite is a partial ophiolite that consists of a lower residual mantle suite and an upper magmatic suite, but dikes, extrusives, and sediments are absent. The residual mantle suite is composed of harzburgite and dunite with refractory mineral compositions. The harzburgite is attributed to partial melting and extraction of basaltic magma; residual dunite is attributed to partial melting or to reaction of orthopyroxene out of harzburgite in contact with ascending melt diapirs. The magmatic suite consists of layered ultramafic and gabbroic rocks, containing minerals having limited iron enrichment. The absence of large volumes of magmatic rocks intermediate in composition between cumulus ultramafics and evolved gabbros favors periodic introduction of magma, rather than closed system fractional crystallization. The ultramafic rocks of both the residual mantle and magmatic suites are tectonites, which have undergone high-temperature deformation involving isoclinal folding on all scales and related syntectonic recrystallization. The olivine fabric is consistent with the glide system {0kl} [100], which has been produced experimentally at 800°–1190°C at 20 kbar. Olivine Z axes and subparallel isoclinal fold axes have consistent, northeast trends throughout the Kanuti region (>100 km NE-SW) and may be close to the original upper mantle flow direction, despite later low-angle thrust faulting. The order of crystallization in the cumulus ultramafic rocks of the magmatic suite is olivine, clinopyroxene, plagioclase, and orthopyroxene. The high Mg numbers of clinopyroxene (0.85–0.93) coexisting with olivine suggest that the cumulus ultramafic rocks crystallized at relatively high pressures (>10 kbar). The effects of parental magma composition cannot be evaluated, but the small difference in Mg numbers of coexisting olivine and clinopyroxene in the cumulus ultramafic rocks and in residual harzburgite suggests that regardless of absolute pressures, the pressure difference between the melting that produced the basalt magma and the initial fractional crystallization of the magma is small. Because of the limited range in rock types in the ophiolite, the tectonic environment cannot be interpreted unambiguously. However, the structural and petrological data are best reconciled with an origin in a volcanic arc tectonic setting.

Journal of Geophysical Research Solid Earth↗

High-alumina kaolinitic clay in the United States, exclusive of Alaska and Hawaii

The general distribution of high-alumina kaolinitic clay deposits in the United States (exclusive of Alaska and Hawaii) is shown on the accompanying map. The locations of mines, pits, and prospects are shown by appropriate symbols. Certain clay-bearing areas are shown by patterns that designate the geologic age of the deposits. The locations are numbered consecutively by states and are keyed to an index which lists the name of the deposit, county, and principal references. Only significant references on the size, quality, and geologic occurrence of deposits are listed. Some of the data for the map and index were compiled by John W. Hosterman and the late Leona Boardman.

Mineral Investigations Resource Map↗

Genesis of a zoned granite stock, Seward Peninsula, Alaska

A composite epizonal stock of biotite granite has intruded a diverse assemblage of metamorphic rocks in the Serpentine Hot Springs area of north-central Seward Peninsula, Alaska. The metamorphic rocks include amphibolite-facies orthogneiss and paragneiss, greenschist-facies fine-grained siliceous and graphitic metasediments, and a variety of carbonate rocks. Lithologic units within the metamorphic terrane trend generally north-northeast and dip moderately toward the southeast. Thrust faults locally juxtapose lithologic units in the metamorphic assemblage, and normal faults displace both the metamorphic rocks and some parts of the granite stock. The gneisses and graphitic metasediments are believed to be late Precambrian in age, but the carbonate rocks are in part Paleozoic. Dating by the potassium-argon method indicates that the granite stock is Late Cretaceous. The stock has sharp discordant contacts, beyond which is a well-developed thermal aureole with rocks of hornblende hornfels facies. The average mode of the granite is 29 percent plagioclase, 31 percent quartz, 36 percent K-feldspar, and 4 percent biotite. Accessory minerals include apatite, magnetite, sphene, allanite, and zircon. Late-stage or deuteric minerals include muscovite, fluorite, tourmaline, quartz, and albite. The stock is a zoned complex containing rocks with several textural facies that are present in four partly concentric zones. Zone 1 is a discontinuous border unit, containing fine- to coarse-grained biotite granite, that grades inward into zone 2. Zone 2 consists of porphyritic biotite granite with oriented phenocrysts of pinkish-gray microcline in a coarse-grained equigranular groundmass of plagioclase, quartz, and biotite. It is in sharp, concordant to discordant contact with rocks of zone 3. Zone 3 consists of seriate-textured biotite granite that has been intruded by bodies of porphyritic biotite granite containing phenocrysts of plagioclase, K-feldspar, quartz, and biotite in an aplitic groundmass. Flow structures, pegmatite and aplite segregations, and miarolitic cavities are common in the seriate-textured granite. Zone 4, which forms the central part of the complex, consists of fine- to medium-grained biotite granite and locally developed leucogranite. Small miarolitic cavities are common within it. Eight textural facies have been defined within the complex, and mineralogic, petrographic, modal, and chemical variations are broadly systematic within the facies sequence. Study of these variations shows that the gradational facies of zones l and 2 systematically shift toward more mafic compositions inward within the complex. Seriate-textured rocks of zone 3 are similar in composition to those of zone 2, but porphyritic rocks of zone 3 and rocks of zone 4 mark shifts to more felsic compositions. These late-crystallizing felsic rocks are products of an interior residual magma system. This system was enriched in water and certain trace elements including tin, lithium, niobium, lead, and zinc. The complex as a whole has higher concentrations of these elements than many other granites. The nature of this geochemical specialization is particularly well demonstrated by the trace-element composition of biotite. The crystallization history of the pluton was complex. The available data suggest that this history could have included: (1) chilling and metasomatic alteration adjacent to the contact, (2) in-situ crystallization in several marginal facies accompanied by some transfer of residual constituents toward interior parts of the pluton, (3) slight upward displacement of magma that was subjacent to the crystallized walls, accompanied by disequilibrium crystallization and local vapor saturation, (4) upward displacement of part of the residual water-rich interior magma, accompanied by rapid loss of a separated vapor phase, and (5) displacement of the margins of the pluton by normal faults, accompanied by loss of an exsolved vapor phase from th

Open-File Report↗

Geology and ore deposits of the central York Mountains, western Seward Peninsula, Alaska

In the central York Mountains, carbonate rocks of Lower and Middle Ordovician age and aggregating at least 8,000 feet thick are thrust northward over slate and argillaceous limestone of pre-Ordovician age which were intruded by gabbro in pre-Ordovician time. Normal faults of four distinct systems cut the thrust plates, and in Late Cretaceous time, stocks of biotite granite, abnormally rich in beryllium, tin, boron and certain other trace elements, pierced the thrust plates. In part following the intrusion of the granites, a strong set of normal faults developed striking N. 60°-85° E. through the central York Mountains and locally these faults cut the granites. Dikes of granite, rhyolite porphyry, and lamprophyre were injected into some of these faults, the lamprophyres being younger. Trace elements in the lamprophyres prove they are mafic rocks probably derived from the lama, and that they cannot be related genetically to granite. Shortly after the intrusion of lamprophyre dikes, ore deposits of tin, beryllium, and fluorite were formed from solutions probably derived from deeply-buried hot granite where the granite was ruptured by normal faults. Ore shoots were localized beneath thrust faults where the faults are intruded by dikes, and a major ore-bearing structure, the Rapid River fault, is mineralized for half its length for a distance of eight miles. The tin deposits contain cassiterite and stannite in topaz greisen with abundant sulfides of copper, lead, zinc, and iron, as well as wolframite. The beryllium deposits contain fluorite, chrysoberyl, diaspore, muscovite, and tourmaline, with trace to small amounts of euclase, bertrandite, helvite, phenikite(?), todorokite and hematite. Beryl occurs sparingly in late veins of quartz and fluorite. Chrysoberyl is the earliest and commonest beryllium mineral, followed by euclase and bertrandite, and then phenakite(?) and beryl. Helvite is restricted to banded skarns near granite, and which consist of magnetite and fluorite. Throughout the district, a strong zonation is displayed from tin deposits in greisen through transitional veins of sulfide minerals with fluorite and chrysoberyl to fluorite-beryllium deposits and thence to barren veins of silica and fluorite with trace amounts of beryllium. This zonal arrangement of deposits probably will be found elsewhere in the world where greisen tin deposits occur in carbonate rocks. The geochemical cycle of the trace elements Be, Sn, W, B, Li, Cu, Pb, Zn and Nb shows that these elements were enriched in the biotite granites and were strongly fractionated among the minerals of granites. Fran the granites, these rare elements moved outward into contact rocks and ore deposits. During the supergene cycle, clear geochemical anomalies were formed in stream sediments, soils and plants near ore deposits, and geochemical prospecting led to the discovery of the beryllium lodes. With the possible exception of zinc and niobium, the rare elements that are associated in the rocks and ores remain associated in the supergene processes. Fixation of zinc in clay soil and tundra plants may account for the relatively small amount of zinc in strew sediments. Datable Pleistocene events in the York Mountains begin with the Yarmouth Interglaciation when the York Terrace, a wide marine platform, was cut. In Illinoian time, the York Terrace was uplifted almost 400 feet, and during the Sangamon Interglaciation a second marine platform (Lost River Terrace) was cut and is not deformed. During Wisconsin time the widespread York Glaciation was followed by the more restricted Mint River Glaciation. Because uplift of the York Terrace extended into the Bering Strait, it is probable that prior to the uplift in Illinoian time the Bering Strait was a seaway and a barrier to land migration rather than a land bridge.

Alaska↗

Geology of the Alaska-Juneau lode system, Alaska

The Alaska-Juneau lode system for many years was one of the worlds leading gold-producing areas. Total production from the years 1893 to 1946 has amounted to about 94 million dollars, with principal values in contained gold but with some silver and lead values. The principal mine is the Alaska-Juneau mine, from which the lode system takes its name. The lode system is a part of a larger gold-bearing belt, generally referred to as the Juneau gold belt, along the western border of the Coast Range batholith. The rocks of the Alaska-Juneau lode system consist of a monoclinal sequence of steeply northeasterly dipping volcanic, state, and schist rocks, all of which have been metamorphosed by dynamic and thermal processes attendant with the intrusion of the Coast Range batholith. The rocks form a series of belts that trend northwest parallel to the Coast Range. In addition to the Coast Range batholith lying a mile to the east of the lode system, there are numerous smaller intrusives, all of which are sill-like in form and are thus conformable to the regional structure. The bedded rocks are Mesozoic in age; the Coast Range batholith is Upper Jurassic and Lower Cretaceous in age. Some of the smaller intrusives pre-date the batholith, others post-date it. All of the rocks are cut by steeply dipping faults. The Alaska-Juneau lode system is confined exclusively to the footwall portion of the Perseverance slate band. The slate band is composed of black slate and black phyllite with lesser amounts of thin-bedded quartzite. Intrusive into the slate band are many sill-like bodies of rocks generally referred to as meta-gabbro. The gold deposits of the lode system are found both within the slate rocks and the meta-gabbro rocks, and particularly in those places where meta-gabbro bodies interfinger with slate. Thus the ore bodies are found in and near the terminations of meta-gabbro bodies. The ore bodies are quartz stringer-lodes composed of a great number of quartz veins from 6 inches to 3 feet wide and extending along their strike and dip for several tens to hundreds of feet. In addition to quartz, the only other vein gangue mineral is ankerite. It occurs in small amounts along the borders of the quartz veins. Metallic vein minerals, in addition to native gold, are, in order of decreasing abundance, pyrrhotite, galena, sphalerite, and arsenopyrite. In the aggregate the metallic minerals comprise only 1 to 2 percent of the total amount of vein material. The wall rock, particularly the meta-gabbro, was profoundly altered by the vein-forming processes. The principal effects on the meta-gabbro were the addition of large amounts of soda, potash, titanium, carbon dioxide, and phosphorous, and the removal of considerable quantities of iron, magnesia, lime, and combined water. Silica also may have been decreased. The mineralogical changes involved in the alteration were the development of biotite and ankerite at the expense of original hornblende and feldspar, resulting in a brown-colored biotite- and ankerite-rich rock. The slates are relatively unaffected by the vein-forming processes. Because of their small size, relatively low grade, and discontinuity, no attempt has been made to mine any individual vein. The prevailing practice has been to mine large blocks of ground by a system of modified block-caving, followed by hand sorting to remove the barren country rock from the gold-bearing quartz prior to milling.

Open-File Report↗

Design and operations of the Hydrate 01 Stratigraphic test well, Alaska North Slope

The National Energy Technology Laboratory, the Japan Oil, Gas and Metals National Corporation, and the U.S. Geological Survey are leading an effort to conduct an extended gas hydrate production test in northern Alaska. The proposed production test required the drilling of an initial stratigraphic test well (STW) to confirm the geologic conditions of the proposed test site. This well was completed in December 2018 in cooperation with the Prudhoe Bay Unit Interest Owners. With the success of the STW, the project leadership group is developing plans to drill a geologic data well and a production test well. Drilling plans for the STW were advanced in late 2018. The Prudhoe Bay Unit Hydrate-01 well was spudded on 10-December-2018. Downhole data acquisition was completed on 25-December-2018 and the rig was released on 01-January-2019. The STW was drilled in two sections. The surface hole was drilled to a depth of 2248 ft (MD, measured depth) and cased, and the “production hole section” was drilled to a depth of 3558 ft (MD) and also cased. A thermally chilled mineral-oilbased mud was used to maintain drillhole stability and quality of the borehole acquired data. The primary borehole data were acquired using a suite of Schlumberger logging-while-drilling tools. To gather grain size and other data needed to inform the design of the production test well, sidewall pressure cores were collected using Halliburton’s CoreVault tool. In addition to confirming the geologic conditions at the test site, the Hydrate-01 well was designed to serve as a monitoring well during future field operations. Therefore, two sets of fiber optic cables, each including bundled Distributed Acoustic Sensors (DAS) and Distributed Temperature Sensors (DTS), were clamped to the outside of the well casing and cemented in place. In March 2019, the project team worked with SAExploration to acquire 3D DAS Vertical Seismic Profiling (VSP) data in the Hydrate-01 well, which was the largest 3D DAS-VSP ever conducted. Additionally, since the December 2018 completion of the STW, several borehole temperature surveys have been acquired with the DTS deployed in the Hydrate-01 well.

Alaska↗

Reconnaissance for radioactive deposits in the Fairbanks and Livengood Quadrangles, east-central Alaska, 1949

Several mines and prospects in the Fairbanks and Livengood quadrangles, east-central Alaska, were examined for the possible presence of radioactive materials in the summer of 1949. Also tested were pre-Cambrian and Paleozoic metamorphic and sedimentary rocks crossed by the Elliott Highway, which extends from Fox, near Fairbanks, northward about 70 miles to the town of Livengood. None of the lodes tested exhibited radioactivity in excess of 0.003 percent equivalent uranium, although nuggets consisting chiefly of native bismuth and containing as much as 0.1 percent equivalent uranium had been found previously in a placer on Fish Creek several miles below the reported bismuth-bearing lode on Melba Creek. The greatest radioactivity found in the rocks along the Elliott Highway was in an iron-stained schist of pre-Cambrian age and in carbonaceous shale of Middle Devonian or Carboniferous age. Respective samples of these rocks contain 0.003 and 0.004 percent equivalent uranium. A possible local bedrock source for a euxenite-polycrase mineral found in a placer concentrate containing about 0.04 percent equivalent uranium was sought in the watershed of Goodluck Creek, near Livengood. The bedrock source of this mineral could not be located; it is believed that the source could be outside of the Goodluck watershed, as drainage changes in the area during Quaternary time might well have introduced gravels from nearby areas.

Alaska↗

Chromite in the United States, exclusive of Alaska and Hawaii

The chromite deposits in the United States (exclusive of Alaska and Hawaii) are shown on the accompanying map. In compiling the map, the deposits were classified in five size categories according to the estimated total quantity of chromite present before mining. The map shows, by different symbols, deposits of chromite in ultramafic rocks, beach sands in which chromite is an important constituent, and lateritic iron ores in which chromium has been concentrated by weathering of peridotite in situ. Although geologically significant amounts of chromium are known to occur in some gabbros and sedimentary rocks other than beach sands and laterite, the data are too fragmentary to show on the map.

Mineral Investigations Resource Map↗

Iron in the United States, exclusive of Alaska and Hawaii

The iron-ore deposits in the United States (exclusive of Alaska and Hawaii) are shown on the accompanying map; many iron-bearing deposits that are of lesser or only potential value are also shown. Because these deposits range widely in extent, two general categories of symbols are used, each of which is subdivided as explained below. The first category is for deposits of such restricted extent that they can be represented by a "spot": the second is for deposits which, although not necessarily extremely large in terms of volume or tonnage, are either continuous (or essentially so) or clustered in reasonably well-defined districts of numerous small occurrences.

Mineral Investigations Resource Map↗

Fuel-reduction management alters plant composition, carbon and nitrogen pools, and soil thaw in Alaskan boreal forest

Increasing wildfire activity in Alaska's boreal forests has led to greater fuel-reduction management. Management has been implemented to reduce wildfire spread, but the ecological impacts of these practices are poorly known. We quantified the effects of hand-thinning and shearblading on above- and belowground stand characteristics, plant species composition, carbon (C) and nitrogen (N) pools, and soil thaw across 19 black spruce ( Picea mariana ) dominated sites in interior Alaska treated 2-12 years prior to sampling. The density of deciduous tree seedlings was significantly higher in shearbladed areas compared to unmanaged forest (6.4 vs. 0.1 stems m −2 ), and unmanaged stands exhibited the highest mean density of conifer seedlings and layers (1.4 stems m −2 ). Understory plant community composition was most similar between unmanaged and thinned stands. Shearblading resulted in a near complete loss of aboveground tree biomass C pools while thinning approximately halved the C pool size (1.2 kg C m −2 compared to 3.1 kg C m −2 in unmanaged forest). Significantly smaller soil organic layer (SOL) C and N pools were observed in shearbladed stands (3.2 kg C m −2 and 116.8 g N m −2 ) relative to thinned (6.0 kg C m −2 and 192.2 g N m −2 ) and unmanaged (5.9 kg C m −2 and 178.7 g N m −2 ) stands. No difference in C and N pool sizes in the uppermost 10 cm of mineral soil was observed among stand types. Total C stocks for measured pools was 2.6 kg C m −2 smaller in thinned stands and 5.8 kg C m −2 smaller in shearbladed stands when compared to unmanaged forest. Soil thaw depth averaged 13 cm deeper in thinned areas and 46 cm deeper in shearbladed areas relative to adjacent unmanaged stands, although variability was high across sites. Deeper soil thaw was linked to shallower SOL depth for unmanaged stands and both management types, however for any given SOL depth, thaw tended to be deeper in shearbladed areas compared to unmanaged forest. These findings indicate that fuel-reduction management alters plant community composition, C and N pools, and soil thaw depth, with consequences for ecosystem structure and function beyond those intended for fire management.

Alaska↗

Geochemical data of fumarolically altered rocks, Valley of Ten Thousand Smokes, Alaska

Samples from a fossil fumarole originating in the 1912 ash-flow tuffin the Valley of Ten Thousand Smokes have been analyzed to ascertain chemical changes resulting from high-temperature fumarolic alteration and subsequent cooling and weathering of the protolith. Samples of the underlying, dominantly leached, dacite-rich portion of the ash-flow tuff adjacent to the fumarolic conduit and samples of encrusted fallout from the shallow part of the fossil fumarole were interpreted using the isocon method of Grant (1986). The results show that, relative to unaltered l9l2 dacite, chosen as a standard composition for the protolith in this fossil fumarole, mass was conserved during the alteration reactions for most of the system, but mass gains of l4–2D% were determined for three samples in the leached ash-flow tuff Relative to unaltered dacite protolith, significant enrichments occurred in SO 3 , LOI (~H 2 O), Cl, F, Zn, Pb, Cu, Sn, Cr, Ni, As, Sb, Au, Br in various parts of the fossil fumarole. Some of these were during the high-temperature part of the alteration, and some were during cooling processes when acid alteration becomes prominent. The REEs indicate some depletion in highly altered samples relative to dacite protolith and differential mobility of Eu 2+ relative to trivalent REEs. This is manifested by positive Eu anomalies in REE patterns normalized against REE in the dacite protolith. Mineral phases introduced in the alteration assemblages include alunite reflecting high SO 3 , activity, hydrated aluminum hydroxy-fluoride (a ralstonite-like phase) and fluorite reflecting high F activity, smectite, magnetite, hematite, and goethite reflecting oxidation and hydration reactions. Opal and a portion of the α-cristobalite reflect SiO 2 , mobility; however, the abundance of α-cristobalite is formed from pumice leached during high-temperature vapor-phase processes and devitrification of the altered glass.

Open-File Report↗

Integration of microfacies analysis, inorganic geochemical data, and hyperspectral imaging to unravel mudstone depositional and diagenetic processes in two cores from the Triassic Shublik Formation, Northern Alaska

The Middle – Upper Triassic Shublik Formation is an organic-rich heterogeneous carbonate-siliciclastic-phosphatic unit that generated much of the oil in the Prudhoe Bay field and other hydrocarbon accumulations in northern Alaska. A large dataset, including total organic carbon (TOC), X-ray diffraction (XRD), X-ray fluorescence (XRF) and inductively coupled plasma – mass spectrometry (ICP-MS) measurements, has been built from core and outcrop samples of the Shublik, with a focus on the organic-rich intervals. In addition, two core intervals from the Shublik were analyzed using a hyperspectral imaging system in the visible, near-infrared and shortwave-infrared range. Integration of the hyperspectral results with core descriptions, microfacies interpretations, and analytical data is being used to decipher mudstone depositional and diagenetic processes. Petrographic analysis of Upper Triassic organic-rich intervals within the Shublik suggests that the main microfacies is a laminated bioclastic wackestone/packstone that was episodically disrupted by energetic events of variable intensity. These energetic events produced transitional and sparry calcite bioclastic packstone to grainstone intervals, depending on the depth of sediment column disturbance. By using hyperspectral imaging data from the Ikpikpuk core, individual distribution maps for minerals of interest have been generated and corroborate the microfacies interpretations. These maps also illustrate small-scale vertical changes in mineralogy. The laminated bioclastic wackestone/packstone intervals contain less calcite than the adjacent sparry bioclastic packstone to grainstone intervals. The calcite in these laminated intervals is more iron rich. This interpretation suggests that lower iron concentrations should be expected in the disrupted intervals than in nearby laminated intervals. Textural features are also enhanced in the hyperspectral images relative to visual description of the cores by combining the extraction of the average reflectance in the visible part of the electromagnetic spectrum and the depth of the main carbonate-related feature belonging to calcite. Examples noted in the enhanced imagery include low-angle features, calcite grain-size, and the size, shape and orientation of phosphatic nodules. This enhancement is being used to differentiate laminated from sparry bioclastic packstone to grainstone-rich intervals and provides a more comprehensive assessment of the microfacies than is practical by thin-section analysis.

Alaska↗

Soil nitrogen accretion along a floodplain terrace chronosequence in northwest Alaska: Influence of the nitrogen-fixing shrub Shepherdia canadensis

Nitrogen enters terrestrial ecosystems through multiple pathways during primary succession. We measured accumulation of total soil nitrogen and changes in inorganic nitrogen (N) pools across a 300-y sequence of river terraces in northwest Alaska and assessed the contribution of the nitrogen-fixing shrub Shepherdia canadensis . Our work compared 5 stages of floodplain succession, progressing from a sparsely vegetated silt cap to dense shrubby vegetation, balsam poplar-dominated ( Populus balsamifera ) and white spruce-dominated ( Picea glauca ) mixed forests, and old-growth white spruce forest. Total soil N (0–30 cm depth) increased throughout the age sequence, initially by 2.4 g N·m −2 ·y −1 during the first 120 y of terrace development, then by 1.6 g N·m −2 ·y −1 during the subsequent 2 centuries. Labile soil N, measured by anaerobic incubation, increased most rapidly during the first 85 y of terrace formation, then remained relatively constant during further terrace development. On recently formed terraces, Shepherdia shrubs enriched soil N pools several-fold compared to soil beneath Salix spp. shrubs or intercanopy sites. Total and labile soil N accretion was proportional to Shepherdia cover during the first century of terrace development, and mineral soil δ 15 N content indicated that newly formed river terraces receive substantial N through N-fixation. About half the 600 g total N·m −2 accumulated across the river terrace chronosequence occurred during the 120 y when S. canadensis was dominant. Sediment deposited by periodic flooding continued to add N to terrace soils after the decline in Shepherdia abundance and may have contributed 25% of the total N found in the floodplain terrace soils.

Alaska↗

Antimony in the United States, exclusive of Alaska and Hawaii

The principal sources of antimony in the United States (exclusive of Alaska and Hawaii) are shown on the accompanying map. The types of deposits are indicated by shape of symbols and the relative importance of the deposits is indicated by size of symbols. In the locality index the localities are listed by States and are keyed by numbers to the map. Localities are distinguished by name of mine, prospect, or geographic area, and their coordinates are given to the nearest minute of latitude and longitude. Geologic relations of each occurrence are characterized briefly. The text and map were compiled from published and unpublished information, and at least one reference is given for each locality if reports on it have been published.

Continental United States↗