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Stratigraphy and paleoenvironment of the phosphatic miocene strata of North Carolina

Foraminifera and Mollusca collected from the phosphatic Pungo River Formation and the overlying Yorktown Formation in eastern North Carolina were analyzed and interpreted for stratigraphic and environmental significance in order to determine optimum depositional sites for primary phosphorite. The Mollusca and benthonic foraminifera of the Pungo River Formation correlate with those of the Calvert Formation of Maryland, and the planktonic foraminifera in both of these formations correlate with the Globigerinatella insueta zone of Trinidad, postulated as late Aquitanian age. The paleoenvironment of the phosphorite deposition, interpreted primarily from the benthonic foraminifera, was of cool-temperate waters, ranging in depth from 100 to 200 m in the phosphatic beds to less than 70 m in the upper calcareous beds where phosphate is scarce. Phosphorite deposition occurred in an oceanic embayment located south of the Fort Monroe high in southern Virginia and north of a positive feature whose axis lies in the vicinity of New Bern, North Carolina . Cool-temperate waters in this area during Pungo River time indicate that circulation patterns of ocean currents and the resultant faunal provinces were not the same as those at present and later in the Miocene . In the Pungo River and its time equivalents of the Atlantic Coastal Plain, the presence of thick diatomaceous clay units, volcanic ash beds, shards, attapulgite clays, and other minerals probably derived from volcanic rocks, suggests a volcanic source somewhere off the coast during the Miocene . The Yorktown unconformably overlies the Pungo River Formation. The unconformity is marked by channels into the Pungo River, filled with phosphatic pebbles, vertebrate bones, and lower York-town molluscs and microfauna. The coarse-grained phosphatic material is derived from the underlying fine-grained primary phosphorite in the Pungo River and is abundant only in the lower part of the Yorktown Formation. Deposition of the lower part of the Yorktown occurred in waters about 100 m deep. The waters gradually became more shallow as deposition of the formation continued until depths of less than 15 m, and probable brackish conditions, were reached as the uppermost part of the formation was deposited. Temperature of the waters, cool-temperate during lower Yorktown deposition, became warm-temperate to subtropical in later Yorktown time. The faunal patterns suggest that circulation patterns reached their present state during late Yorktown time.

North Carolina↗

Boulder Creek batholith, Colorado part I: Allanite and its bearing upon age patterns

Allanite is abundant and commonly attains unusually large size as a late-replacement mineral in: (1) the comagnatic rocks of the Precambrian Boulder Creek batholith; (2) associated amphibolite xenoliths and related hybrid rocks; and (3) distinctly younger intrusions of Silver Plume Granite that cut the complex. Allanite porphyroblasts develop by replacement of biotite, probably in the presence of emanations from the rare earth-rich and thorium-rich Silver Plume Granite. The largest allanite crystals are made up of nearly isotropic (metamict) cores and birefringent (recrystallized) rims. Smaller crystals are made up exclusively of birefringent material. The maximum birefringence is shown to be that expectable in allanite of Late Cretaceous to early Tertiary age. As plotted on maps, the birefringence increases, and the thorium and uranium contents of the allanite decrease toward a Laramide stock. The variation in birefringence is, therefore, largely relatable to variations in the post-Laramide radiation dosage brought about by differences in the amounts of uranium and thorium lost during recrystallization. The recrystallized allanite is itself partly replaced by epidote which characteristically occurs as a border between allanite and biotite. Total rare-earth oxides for the eight samples of allanite analyzed range from 17.5 to 21.3 percent by weight. In 13 samples, thorium ranged from 0.50 to 1.14 percent by weight, and uranium from 54 to 158 parts pparts per million. Ranges in optical measurements for 20 samples using the spindle stage are: Nα = 1.719–1.759, Nβ = 1.731-1.774, N γ = 1.741–1.784, birefringence = 0.020–0.032, 2V X (calc.) 70°–84°. Ranges for unit-cell data obtained on 8 samples are: a = 8.948–8.985Å, b = 5.721-5.763Å, c = 10.184–10.240Å, β = 115°7.50′–115°25.89′ and volume = 473.02–478.43Å 3 . The average value for the ratio a:b:c = 1.561:1:1.778.

Colorado↗

Pb isotope geochemistry of stratabound Zn-Pb(-Ag-Au-Ba-F) deposits and occurrences in the Nome Complex, Seward Peninsula, Alaska: Metal sources and regional comparisons

A detailed study of the Pb isotope geochemistry of Zn-Pb(-Ag-Au-Ba-F) stratabound sulfide deposits within metasedimentary rocks of the Neoproterozoic to Mississippian(?) Nome Complex provides key information for understanding deposit genesis and crustal evolution. A total of 106 new analyses of galena (and other sulfi des) and metasedimentary rocks hosting the deposits shows that (1) Pb isotope signatures of the deposits are heterogeneous when considered as a group; (2) the stratabound Nelson deposit, and deformed veins at Quarry and Galena, are isotopically similar; (3) stratabound and locally stratiform lenses such as Wheeler North and Aurora Creek had different isotopic evolutions; and (4) the occurrence at Bluff and the postmetamorphic, undeformed Pb-Zn-Ag veins and replacements at Hannum, Independence, Foster, and Omilak show the highest values of 206 Pb/ 204 Pb in the region. Pb isotope data for the stratabound Zn-Pb deposits and occurrences do not lie along similar secondary or anomalous lead evolution lines, and there is no shared, two-stage lead line that would provide intersections with a primary or single-stage lead isotope growth curve. Lead isotopic characteristics of the Nelson stratabound deposit and the deformed veins at Quarry and Galena indicate that they largely shared metal and fluid sources. Quarry and Galena also display sufficient Pb isotopic contrast compared to Aurora Creek and Wheeler North to eliminate such veins as subsurface “feeders” for these stratabound deposits, if the deformed veins and deposits formed as closed isotopic systems (without a contribution from externally derived lead). The Pb isotope composition of galena from Aurora Creek formed by a multistage process. It is thus possible that the Aurora Creek deposit originally contained Pb isotope compositions that resembled those from Quarry and Galena. That early-formed Pb was probably remobilized and mixed with radiogenic lead contributed by Mesozoic hydrothermal fluids similar to those associated with the gold-quartz veins in the region. Values of 207 Pb/ 204 Pb and 206 Pb/ 204 Pb from each of the deposits and occurrences plot within the Pb isotope fields of the host metasedimentary rocks and Mesoproterozoic basement rocks of Seward Peninsula; Pb isotope compositions in the deposits thus reflect a local source control. The processes that generated the premetamorphic Zn-Pb(-Ag-Au-Ba-F) sulfide deposits in the Nome Complex differed from those that generated Zn-Pb-Ag deposits in the western Brooks Range, such as the giant Red Dog ore body. Taken as a group, the stratabound lenses and deformed veins in the Nome Complex did not form in a single, widespread, homogeneous hydrothermal system. The Brooks Range deposits, which consist of a range of host rock types and styles of mineralization distributed over a large area, have a high degree of regional Pb isotope homogeneity. The Wheeler North deposit is isotopically similar to Red Dog and related deposits and may have formed in a related hydrothermal system. A preliminary comparison of the Pb isotope compositions of sedimentary-exhalative (SEDEX)–type deposits within the Arctic Alaska–Chukotka terrane and deposits in crustal blocks of Laurussia shows: (1) noteworthy Pb isotopic overlap exists between some of Zn-Pb-Ag deposits in Ireland and the deposits in Arctic Alaska ; but (2) no exact isotopic match exists between any of the deposits in Arctic Alaska and any deposit in crustal blocks involved in the Paleozoic evolution of Laurussia.

Alaska↗

Physical properties, mineralogy, and geochemistry of Holocene varved sediments from Elk Lake, Minnesota

Elk Lake in northwestern Minnesota is situated close to a climatically sensitive ecotone, the forest-prairie border, that migrated back and forth over the drainage basin of the lake during the Holocene. The entire postglacial (Holocene) sediment record in the deepest part of Elk Lake is composed of annual layers (varves) that record the seasonal pulses of many sediment components, and, most important, provide high-resolution (seasonal) time calibration of rates and timing of environmental change. These varved sediments contain many allochthonous and autochthonous components that are sensitive to changing environmental conditions in the drainage basin and the lake. The mineral components of Elk Lake sediments consist mainly of authigenic calcium, magnesium, and manganese carbonate minerals (low-Mg calcite, high-Mg calcite, dolomite, and rhodochrosite), opaline silica (from diatoms), X-ray amorphous iron and manganese oxyhydroxides, and an iron phosphate mineral tentatively identified as rock-bridgeite [(Fe, Mn)Fe 4 (PO 4 ) 3 (OH) 5 ], plus minor contributions from fine-grained detrital quartz, feldspar, illite, and kaolinite. The most notable characteristic of the sediments in Elk Lake is that most of the components were formed in the lake. Q-mode factor analysis of sediment geochemistry reduced 23 observed compositional variables, expressed as percent or parts per million of elements, to three composite variables (factor loadings) whose “concentrations” are expressed on a scale of −1.0 to 1.0. Factor 1 expresses the composition of the inorganic clastic fraction based on concentrations of Mg, Na, Al, Cr, V, Y, Sc, Ni, Sr, Co, and Cu. Factor 2 expresses the similarities in variations of Fe, Mn, P, organic carbon, and Mo. Factor 3 loadings are a synthesis of concentrations of Mn, S, Ca, La, and Ba. Geochemical characteristics define three distinct chemical stages in the development of Elk lake: (1) a carbonate-, manganese-, iron-, sulfur-rich early-lake stage that lasted from 10,400 to 8200 varve yr; (2) a clastic- and diatom-rich mid-Holocene prairie-lake stage that lasted from 8200 to 4000 varve yr; and (3) a final iron-, manganese-, phosphate-, and organic-rich modern-lake stage that developed over the past 4000 yr. The chemical characteristics of the sediments deposited during these three lake phases can be represented by the average compositions of three groups of samples: (1) the average composition of sediments deposited over the past 2000 yr, representing the modern-lake stage; (2) the composition of a 50 varve sample centered on 5700 varve yr that represents the maximum clastic influx into the lake during the prairie period; and (3) the average composition of sediments deposited over the initial 2000 yr of the lake’s existence (10,400 to 8400 varve yr). The amplitudes of climatic oscillations, as reflected by changes in concentration of many climatically sensitive elements, were greatest during the prairie period, pronounced cycles having periodicities of several hundred years. The extremes of these oscillations occurred within several centuries or less, which suggests that significant changes in climate may occur abruptly and rapidly. Most notably, the end of the mid-Holocene prairie period, marked by a sudden decrease in the influx of detrital clastic material, occurred within a few decades.

Minnesota↗

Geochemistry of ground water

The science of geochemistry is the study of the chemical composition of and actual or possible chemical changes in the crust of the earth. The subdivision of geochemistry concerned with ground water includes study of the nature and amounts of dissolved mineral matter in ground waters, the chemical and geologic changes that influence the kinds and amounts of substances carried in solution, and the chemical relationships between dissolved mineral matter in waters and minerals that make up the rocks in which the waters occur. As . thus defined, the field of geochemistry of ground water is very large. Although much work has been done in geochemistry in general, and in some phases of the geochemistry of ground water, the field remains to a large extent unexplored.

Economic Geology↗

Geology and petrology of the Greenville quadrangle, Piscataquis and Somerset Counties, Maine

In the Greenville quadrangle, west-central Maine, slate, siltstone, and sandstone (calcareous and noncalcareous) of probable Silurian to Early Devonian age are intruded by a large mafic pluton and two granitic stocks of probable Early Devonian age. Ages of the sedimentary rocks are based upon tentative correlations with fossiliferous beds in adjacent quadrangles because the few fossils in the Greenville quadrangle are nondiagnostic; ages of the intrusive rocks are based upon radiometric age determinations. The sedimentary rocks are tightly folded about northeast-trending axes and have strong slaty cleavage. Widespread graded bedding is very useful in determining the tops of beds and thus the location of fold axes. The sedimentary rocks are in the chlorite zone of metamorphism except in the contact aureoles where the metamorphism ranges from the biotite zone, through the andalusiite-amphibole zone, to the sillimanite-cordierite zone adjacent to the intrusions; retrograde metamorphism is a minor local feature. The mafic rocks are part of the Moxie pluton, which extends southwest and northeast of the Greenville quadrangle for a total distance of about 45 miles. Troctolite and norite are the principal rock types; gabbro is less common. Plagioclase is the dominant mineral; it usually makes up 50-75 percent of the rock. Olivine and orthopyroxene are widespread, clinopyroxene is uncommon and biotite and hornblende are generally present in small amounts. The rocks can be separated into magnesium-rich and iron-rich varieties; magnesium-rich olivine and orthopyroxene are usually accompanied by plagioclase containing from 57 to 77 percent anorthite, and iron-rich olivine and orthopyroxene are associated with plagioclase containing about 50-62 percent anorithite. Compositional layering is rare, but flow structure is very common. Flow structure generally dips northward to eastward, whereas geophysical data indicate that the contacts of the pluton dip southeastward. The granitic stocks are discordant pipelike bodies that range from granodiorite to quartz monzonite in composition. Both the mafic and the felsic intrusions are undeformed and unmetamorphosed. Slate quarrying was once an important industry in the region, but in 1965 only one quarry was active at Monson just east of the report area. Slate is a potential source of raw material for lightweight concrete aggregate. There are several possible sites for stone quarries in the intrusive masses. Sand and gravel resources seem to be limited. Small amounts of sulfides that have low copper and nickel values are known at a few places in the mafic pluton.

Maine↗

Dynamic computer model for the metallogenesis and tectonics of the Circum-North Pacific

The digital files on this report consist of a dynamic computer model of the metallogenesis and tectonics of the Circum-North Pacific, and background articles, figures, and maps. The tectonic part of the dynamic computer model is derived from a major analysis of the tectonic evolution of the Circum-North Pacific which is also contained in directory tectevol. The dynamic computer model and associated materials on this CD-ROM are part of a project on the major mineral deposits, metallogenesis, and tectonics of the Russian Far East, Alaska, and the Canadian Cordillera. The project provides critical information on bedrock geology and geophysics, tectonics, major metalliferous mineral resources, metallogenic patterns, and crustal origin and evolution of mineralizing systems for this region. The major scientific goals and benefits of the project are to: (1) provide a comprehensive international data base on the mineral resources of the region that is the first, extensive knowledge available in English; (2) provide major new interpretations of the origin and crustal evolution of mineralizing systems and their host rocks, thereby enabling enhanced, broad-scale tectonic reconstructions and interpretations; and (3) promote trade and scientific and technical exchanges between North America and Eastern Asia.

Open-File Report↗

Tectonic and metallogenic model for northeast Asia

This document describes the digital files in this report that contains a tectonic and metallogenic model for Northeast Asia. The report also contains background materials. This tectonic and metallogenic model and other materials on this report are derived from (1) an extensive USGS Professional Paper, 1765, on the metallogenesis and tectonics of Northeast Asia that is available on the Internet at http://pubs.usgs.gov/pp/1765/; and (2) the Russian Far East parts of an extensive USGS Professional Paper, 1697, on the metallogenesis and tectonics of the Russian Far East, Alaska, and the Canadian Cordillera that is available on the Internet at http://pubs.usgs.gov/pp/pp1697/. The major purpose of the tectonic and metallogenic model is to provide, in movie format, a colorful summary of the complex geology, tectonics, and metallogenesis of the region. To accomplish this goal four steps were taken: (1) 13 time-stage diagrams, from the late Neoproterozoic (850 Ma) through the present (0 Ma), were adapted, generalized, and transformed into color static time-stage diagrams; (2) the 13 time-stage diagrams were placed in a computer morphing program to produce the model; (3) the model was examined and each diagram was successively adapted to preceding and subsequent diagrams to match the size and surface expression of major geologic units; and (4) the final version of the model was produced in successive iterations of steps 2 and 3. The tectonic and metallogenic model and associated materials in this report are derived from a project on the major mineral deposits, metallogenesis, and tectonics of the Northeast Asia and from a preceding project on the metallogenesis and tectonics of the Russian Far East, Alaska, and the Canadian Cordillera. Both projects provide critical information on bedrock geology and geophysics, tectonics, major metalliferous mineral resources, metallogenic patterns, and crustal origin and evolution of mineralizing systems for this region. The major scientific goals and benefits of the projects are to: (1) provide a comprehensive international data base on the mineral resources of the region that is the first extensive knowledge available in English; (2) provide major new interpretations of the origin and crustal evolution of mineralizing systems and their host rocks, thereby enabling enhanced, broad-scale tectonic reconstructions and interpretations; and (3) promote trade and scientific and technical exchanges between North America and eastern Asia.

Summit, Colorado↗

Appraisal of the water resources of Death Valley, California-Nevada

The hydrologic system in Death Valley is probably in a steady-state condition--that is, recharge and discharge are equal, and net changes in the quantity of ground water in storage are not occurring. Recharge to ground water in the valley is derived from interbasin underflow and from local precipitation. The two sources may be of the same magnitude. Ground water beneath the valley moves toward the lowest area, a 200-square-mile saltpan, much of which is underlain by rock salt and other saline minerals, probably to depths of hundreds of feet or even more than 1,000 feet. Some water discharges from the saltpan by evaportranspiration. Water beneath the valley floor, excluding the saltpan, typically contains between 3,000 and 5,000 milligrams per liter of dissolved solids. Water from most springs and seeps in the mountains contains a few hundred to several hundred milligrams per liter of dissolved solids. Water from large springs that probably discharge from interbasin flow systems typically contains between 500 and 1,000 milligrams per liter dissolved solids. Present sites of intensive use by man are supplied by springs, with the exception of the Stovepipe Wells Hotel area. Potential sources of supply for this area include (1) Emigrant Spring area, (2) Cottonwood Spring, and (3) northern Mesquite Flat. (Woodard-USGS)

California, Nevada↗

Ground-water quality and geochemistry in Carson and Eagle Valleys, western Nevada and eastern California

Aquifers in Carson and Eagle Valleys are an important source of water for human consumption and agriculture. Concentrations of major constituents in water from the principal aquifers on the west sides of Carson and Eagle Valleys appear to be a result of natural geochemical reactions with minerals derived primarily from plutonic rocks. In general, water from principal aquifers is acceptable for drinking when compared with current (1993) Nevada State drinking-water maximum contaminant level standards. Water was collected and analyzed for all inorganic constituents for which primary or secondary drinking-water standards have been established. About 3 percent of these sites had con- stituents that exceeded one or more primary or secondary drinking-water standards have been established. About 3 percent of these sites had con- stituents that exceeded one or more primary standards and water at about 10 percent of the sites had at least one constituent that surpassed a secondary standard. Arsenic exceeded the standard in water at less than 1 percent of the principal aquifer sites; nitrate surpassed its standard in water at 3 percent of 93 sites. Water from wells in the principal aquifer with high concentrations of nitrate was in areas where septic systems are used; these concentrations indicate that contamination may be entering the wells. Concentrations of naturally occurring radionuclides in water from the principal aquifers, exceed the proposed Federal standards for some constituents, but were not found t be above current (1993) State standards. The uranium concen- trations exceeded the proposed 20 micrograms per liter Federal standard at 10 percent of the sites. Of the sites analyzed for all of the inorganic constituents with primary standards plus uranium, 15 percent exceed one or more established standards. If the proposed 20 micrograms per liter standard for uranium is applied to the sampled sites, then 23 percent would exceed the standard for uranium or some other constituent with a primary drinking water standard. This represents a 50-percent increase in the frequency of exceedance. Almost all water sampled from the principal aquifers exceeds the 300 picocuries per liter proposed standard for radon. Ground-water sampling sites with the highest radon activities in water are most commonly located in the upland aquifers in the Sierra Nevada and in the principal aquifers beneath the west sides of Carson and Eagle Valleys.

Open-File Report↗

Table Mountain Shoshonite Porphyry Lava Flows and Their Vents, Golden, Colorado

During early Paleocene time shoshonite porphyry lava was extruded from several plugs about 5 km north of Golden, Colo., to form lava flows intercalated in the upper part of the Denver Formation. These flows now form the caps of North and South Table Mountains. Detailed field and petrographic studies provide insights into magma development, linkage between vents and flows, and the history of the lava flows. The magma was derived from a deep (mantle) source, was somewhat turbulent on its way up, paused on its way up in a shallow granite-hosted chamber, and near the surface followed the steep Golden fault and the thick, weak, steeply dipping Upper Cretaceous Pierre Shale. At the surface the lava flowed out of several plug and dike vents in a nonexplosive manner, four times during a span of about 1 m.y. Potassium-rich material acquired in the shallow chamber produced distinctive textures and mineral associations in the igneous rocks. Lava flows 1 (the lowest) and 2 are channel deposits derived from the southeastern group of intrusions, and flow 1 (a composite, multiple-tongued flow) lies about 50 m below the capping flows. Provisionally, the unit termed flow 1 is considered to include older, felty-textured flows that are distinguished from a blocky-textured unit, flow 1a. Flow 2, newly recognized in this study, lies immediately beneath the capping flows. Lava flows 3 and 4, more voluminous than the earlier ones, were derived from a plug vent 1?2 km farther north-northwest and flowed south-southeast across a broad alluvial plain. This plug is a composite body; the rim phase fed flow 3, and the core phase was the source of flow 4. During the time between the effusion of the four flows, the composition of the shoshonite porphyry magma changed subtly; the later flows contain more alkali, as shown by higher proportions of sanidine. On North Table Mountain, lava flows 3 and 4 form an elongate tumulus above a stream channel that carried water at the time of their eruption. On South Table Mountain, lava flow 3 forms a low, broad dome that forced flow 4 into channels now restricted to the west and northeast flanks of that mesa. Mesa-capping lava flows 3 and 4 are broken by many small normal faults and are warped into open synclines, probably in response to local stresses associated with the settling of piedmont deposits into the Denver Basin. Mid-Tertiary deposits are inferred to have covered the upper part of the Denver Formation and its lavas; these deposits could thus have been instrumental in changing the stream flow direction to the east before the onset of Neogene uplift and consequent canyon cutting across the flows. Other younger deposits may also have covered the area, to be linked to this consequent canyon cutting.

Scientific Investigations Report↗

Radioactivity at the Copper Creek copper lode prospect, Eagle district, east-central Alaska

Investigation of radioactivity anomalies at the Copper Creek copper lode prospect, Eagle district, east-central Alaska, during 1949 disclosed that the radioactivity is associated with copper mineralization in highly metamorphosed sedimentary rocks. These rocks are a roof pendant in the Mesozoic "Charley River" batholith. The radioactivity is probably all due to uranium associated with bornite and malachite.

Alaska↗

Unravelling the structural control of mississippi valley-type deposits and prospects in carbonate sequences of the Western Canada Sedimentary Basin

Re-examination of selected MVT outcrops and cores in the Interior Plains and Rocky Moun-tains of Alberta, corroborated with previous paragenetic, isotopic and structural data, suggests Laramide structural channelling of dolomitizing and mineralizing fluids into strained carbonate rocks. At Pine Point, extensional faults underlying the trends of MVT ore bodies and brittle faults overprinting the Great Slave Lake Shear Zone define apinnate fault geometry and appear to be kinematically linked. Chemical and isotopic characteristics of MVT parental fluids are consistent with seawater and brine convection within fault-confined verticalaquifers, strong water-basement rock interaction, metalleaching from the basement, and focused release of hydrothermal fluids within linear zones of strained carbonate caprocks. Zones of recurrent strain in the basement and a cap of carbonate strata constitute the critical criteria for MVTexploration target selection in the WCSB.

Bulletin of the Geological Survey of Canada↗

Water chemistry at Snowshoe Mountain, Colorado: mixed processes in a common bedrock

At Snowshoe Mountain the primary bedrock is quite homogeneous, but weathering processes vary as waters moves through the soils, vadose zone and phreatic zone of the subsurface. In the thin soil, physical degradation of tuff facilitates preferential dissolution of potassium ion from glass within the rock matrix, while other silicate minerals remain unaltered. In the vadose zone, in the upper few meters of fractured bedrock, dilute water infiltrates during spring snowmelt and summer storms, leading to preferential dissolution of augite exposed on fracture surfaces. Deeper yet, in the phreatic zone of the fractured bedrock, Pleistocene calcite fracture fillings dissolve, and dioctahedral and trioctahedral clays form as penetrative weathering alters feldspar and pyroxene. Alkalinity is generated and silica concentrations are buffered by mineral alteration reactions.

Colorado↗

A case of Te-rich low-sulfidation epithermal Au-Ag deposits in a calc-alkaline magmatic arc, NE China

Tellurium-bearing low-sulfidation epithermal Au-Ag deposits are significant producers of gold, silver, and potentially strategic elements if mineral processing methods are optimized for recovery. Although these deposits are generally related to alkaline magmatism, our study documents an unusual occurrence of Te-rich low-sulfidation epithermal systems in the North Heilongjiang Belt in northeast China that is spatially and temporally associated with calc-alkaline magmatism and tectonic extension in a continental arc‐setting. In the North Heilongjiang Belt, Te-bearing Au-Ag deposits are usually sited in dilatant zones, mostly along extensional NW structures or at their intersections with deep‐seated NE-striking faults such as the Nenjiang-Heihe and Jiayin-Mudanjiang lineaments. Of these deposits, Sandaowanzi is well‐known for its bonanza gold grades. These faults localized andesitic to rhyolitic volcano-plutonic centers that evolved from mantle‐derived mafic melts to intermediate compositions due to differentiation and crustal assimilation as documented by their mineralogy and Sr, Nd, and Pb isotope compositions. During assimilation of country rocks, fluids containing 3 He and other volatiles derived from mantle magmas displaced or mixed with external groundwater containing radiogenic 4 He derived from country rocks. In this belt, the bulk metal content of Au, Ag and Te was probably introduced by deep mantle‐derived mafic‐intermediate calc‐alkaline intrusions. However, our study does not exclude input of metals leached from underlying metasedimentary rocks and older Te‐bearing Au mineralization. The noble gas, hydrogen, oxygen and lead isotope compositions of fluid inclusions and ore minerals suggest that the deposits formed by mixing between magmatic fluids and convecting meteoric ground waters containing lead leached from surrounding country rocks. At deeper levels, isotopic evidence suggests that Au-Ag-Te (Bi) precipitated with pyrite, quartz, sericite, and carbonate minerals due to mixing with Te-rich fluids. At shallower levels, Au and Ag precipitated contemporaneously with base‐metal sulfides, hydrothermal quartz and sericite during episodic boiling as evidenced by silica morphology and mineral textures. The relatively uniform spacing of epithermal systems along NW- and NE-trending structures in the North Heilongjiang Belt was used to identify unexplored spaces within this mineral belt that are prospective for concealed low-sulfidation epithermal gold deposits. Although some of the Au-Ag deposits in this belt are enriched in Te, there is a lack of coeval alkaline igneous rocks that are commonly associated with Te-bearing gold deposits elsewhere in the world (e.g., Cripple Creek, Emperor, and Lihir Island).

North Heilongjiang Belt↗

Hydrothermal alteration mineralogy of SOH drill holes, Kilauea East Rift Zone geothermal area, Hawaii

Thirty-eight hydrothermal minerals were identified from 356 drill-core specimens that were obtained from three Scientific Observation Holes (SOH-1, SOH-2, and SOH-4) drilled along the lower East Rift Zone (ERZ) of Kilauea Volcano, Hawaii. The minerals formed during alteration of basaltic rocks and glass by hot, circulating, waters in aquifers consisting of variable mixtures of meteoric water and sea water. Several zeolites, hydrated calcium silicates, carbonates, clays, silicates, sulfates, sulfides, and other minerals were found filling open spaces of vesicles, fractures, and between breccia fragments of the recovered drill core; many specimens that originally consisted of glass are completely altered to some of these minerals, especially clays. Several hydrothermal minerals (erionite, mordenite, truscottite, smectite, chlorite-smectite, chalcedony, anhydrite, and hematite), occur in the SOH drill holes at higher measured temperatures than the same minerals are found in geothermal drill holes of Iceland or other geothermal areas, suggesting that temperatures within the ERZ geothermal system have increased since the minerals formed. Fluid-inclusion freezing data for quartz, anhydrite, and calcite from the three SOH holes show that composition of the inclusion fluids ranges from dilute meteoric water to highly modified sea water concentrated by boiling. Comparison of measured drill-hole temperatures with fluid-inclusion homogenization-temperature data indicates that only about 15% of the fluid inclusions could have formed under the present thermal conditions. The majority of fluid inclusions studied apparently formed during one or more temperature fluctuations associated with the emplacement of nearby dikes and their subsequent cooling. Bacteria-like particles at 1734.6 m depth in SOH-4 could be very significant because the particles occurred at much hotter temperatures (about 265°C) than the generally accepted 110°C limit for survival of bacteria. The presence of Cl in the particles suggests that they might have lived in a saline environment and did not result from contamination by the fresh water drilling fluids. We reccomend that future drilling and subsequent handling of drill hole specimens in the ERZ and elsewhere employ controls to minimize and(or) recognize bacterial contamination.

Open-File Report↗

Compositional and mineralogic constraints on the genesis of ophiolite hosted nickel mineralization in the Pevkos area, Limassol Forest, Cyprus

Mineralization composed dominantly of primary troilite, maucherite, pentlandite, and chalcopyrite, and secondary valleriite occurs in serpentinized transition zone rocks of the Limasol Forest segment of the Troodos ophiolite complex, Cyprus. Whole-rock and electron microprobe analyses of this mineralization gives ranges of Cu/(Cu+Ni)=0.16 to 0.47, Pt/(Pt+Pd)=0.66 to 0.51, Ni/Co=6.33 to 13.4, and chondrite normalized plots with low concentrations of Rh, Pt, and Pd, but relatively high Au. Estimated distribution coefficients of nickel and iron between olivine and ore range from 0.5 to 7.4. Most of these data are unlike values from magmatic sulfide deposits and indicate either a complete alteration of a preexisting magmatic sulfide concentration or, more likely, a nonmagmatic origin for this mineralization. ?? 1985 Springer-Verlag.

Mineralium Deposita↗

Carbonatites: A review

The carbonatites are essentially carbonate-silicate rock with a great variety of other minerals. In this review the writer stresses the field and geochemical relationships of the carbonatites and alkalic igneous rocks and concludes that carbonatites were deposited by carbonatic solutions having a wide range of temperature, pressure, and concentration and derived from alkalic magmas during the process of silicate crystallization. Brogger's concept of carbonate magma is evaluated in the light of more recent field and laboratory investigations, and the conclusion is reached that a carbonate magma in the normal sense is less likely to exist than carbonate-rich solutions which at elevated temperature and pressure can have a higher concentration of dissolved ingredients than normally believed for hydrothermal solutions. At many localities the carbonatites occur as veinlike or dikelike bodies or as cores in volcanic plugs of alkalic rocks. Recent investigations indicate that the carbonatites and related alkalic rocks represent a relatively unevaluated category of ore deposits that contain an impressive reserve of such rare commodities as niobium (columbium), titanium, zirconium, rare earths, barium, strontium, uranium, magnetite, phosphate, vermiculite, and agricultural lime.

GSA Bulletin↗