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USGS2019

Reactivity of As and U co-occurring in mine wastes in northeastern Arizona

The reactivity of co-occurring arsenic (As) and uranium (U) in mine wastes was investigated using batch reactors, microscopy, spectroscopy, and aqueous chemistry. Analyses of field samples collected in proximity to mine wastes in northeastern Arizona confirm the presence of As and U in soils and surrounding waters, as reported in a previous study from our research group. In this study, we measured As (<0.500 to 7.77 μg/L) and U (0.950 to 165 μg/L) in waters, as well as mine wastes (<20.0 to 40.0 mg/kg As and <60.0 to 110 mg/kg U) and background solids (<20.0 mg/kg As and <60.0 mg/kg U). Analysis with X-ray fluorescence (XRF) and electron microprobe show the co-occurrence of As and U with iron (Fe) and vanadium (V). These field conditions served as a foundation for additional laboratory experiments to assess the reactivity of metals in these mine wastes. Results from laboratory experiments indicate that labile and exchangeable As(V) was released to solution when solids were sequentially reacted with water and magnesium chloride (MgCl 2 ), while limited U was released to solution with the same reactants. The predominance of As(V) in mine waste solids was confirmed by X-ray absorption near edge (XANES) analysis. Both As and U were released to solution after reaction of solids in batch experiments with HCO 3 − . Both X-ray photoelectron spectroscopy (XPS) and XANES analysis determined the predominance of Fe(III) in the solids. Mössbauer spectroscopy detected the presence of nano-crystalline goethite, Fe(II) and Fe(III) in (phyllo)silicates, and an unidentified mineral with parameters consistent with arsenopyrite or jarosite in the mine waste solids. Our results suggest that As and U can be released under environmentally relevant conditions in mine waste, which is applicable to risk and exposure assessment.

Arizona↗

USGS2013

Water-level altitudes 2013 and water-level changes in the Chicot, Evangeline, and Jasper aquifers and compaction 1973--2012 in the Chicot and Evangeline aquifers, Houston-Galveston region, Texas

Most of the subsidence in the Houston-Galveston region, Texas, has occurred as a direct result of groundwater withdrawals for municipal supply, commercial and industrial use, and irrigation that depressured and dewatered the Chicot and Evangeline aquifers, thereby causing compaction mostly in the clay and silt layers of the aquifer sediments. This report, prepared by the U.S. Geological Survey in cooperation with the Harris-Galveston Subsidence District, City of Houston, Fort Bend Subsidence District, Lone Star Groundwater Conservation District, and Brazoria County Groundwater Conservation District, is one in an annual series of reports depicting water-level altitudes and water-level changes in the Chicot, Evangeline, and Jasper aquifers and measured compaction of subsurface sediments in the Chicot and Evangeline aquifers in the Houston-Galveston region. The report contains maps depicting approximate water-level altitudes for 2013 (represented by measurements made during December 2012-February 2013) for the Chicot, Evangeline, and Jasper aquifers; maps depicting 1-year (2012-13) water-level changes for each aquifer; maps depicting 5-year (2008--13) water-level changes for each aquifer; maps depicting long-term (1990-2013 and 1977-2013) water-level changes for the Chicot and Evangeline aquifers; a map depicting long-term (2000-13) water-level changes for the Jasper aquifer; a map depicting locations of borehole-extensometer sites; and graphs depicting measured compaction of subsurface sediments at the extensometers during 1973-2012. Tables listing the data used to construct each water-level map for each aquifer and the compaction graphs are included. In 2013, water-level-altitude contours for the Chicot aquifer ranged from 200 feet (ft) below North American Vertical Datum of 1988 (hereinafter, datum) in a small area in southwestern Harris County to 200 ft above datum in central to west-central Montgomery County. Water-level changes during 2012-13 in the Chicot aquifer ranged from a 58-ft decline to a 37-ft rise. Contoured 5-year and long-term changes in water levels in the Chicot aquifer ranged from a 30-ft decline to an 80-ft rise (2008-13), from a 120-ft decline to a 100-ft rise (1990-2013), and from an 80-ft decline to a 200-ft rise (1977-2013). In 2013, water-level-altitude contours for the Evangeline aquifer ranged from 300 ft below datum in south-central Montgomery County to 200 ft above datum in southeastern Grimes and northwestern Montgomery Counties. Water-level changes for 2012-13 in the Evangeline aquifer ranged from a 37-ft decline to a 68-ft rise. Contoured 5-year and long-term changes in water levels in the Evangeline aquifer ranged from an 80-ft decline to an 80-ft rise (2008-13), from a 220-ft decline to a 220-ft rise (1990-2013), and from a 360-ft decline to a 260-ft rise (1977-2013). In 2013, water-level-altitude contours for the Jasper aquifer ranged from 200 ft below datum in south-central Montgomery and north-central Harris Counties to 250 ft above datum in northwestern Montgomery County and extending into northeastern Grimes and south-central Walker Counties. Water-level changes for 2012-13 in the Jasper aquifer ranged from a 36-ft decline to an 87-ft rise. Contoured changes in water levels in the Jasper aquifer ranged from a 100-ft decline to 20-ft rise (2008-13) and from a 220-ft decline to no change (2000-13). Compaction of subsurface sediments (mostly in the clay and silt layers) of the Chicot and Evangeline aquifers was recorded continuously by 13 borehole extensometers at 11 sites that were either activated or installed between 1973 and 1980. For the period of record beginning in 1973 (or later depending on activation or installation date) and ending in December 2012, cumulative measured compaction by 12 of the 13 extensometers ranged from 0.100 ft at the Texas City-Moses Lake extensometer to 3.632 ft at the Addicks extensometer (data were used from only one of two extensometers at one site). The rate of compaction varies from site to site because of differences in groundwater withdrawals near each site and differences among sites in the clay-to-sand ratio in the subsurface sediments. Therefore, it is not possible to extrapolate or infer a rate of compaction for adjacent areas based on the rate of compaction measured at a nearby extensometer.

Texas↗

USGS2013

Groundwater withdrawals 1976, 1990, and 2000--10 and land-surface-elevation changes 2000--10 in Harris, Galveston, Fort Bend, Montgomery, and Brazoria Counties, Texas

The study area comprising Harris County and parts of Galveston, Fort Bend, Montgomery, and Brazoria Counties in southeastern Texas forms part of one of the largest areas of land-surface-elevation change in the United States. Land-surface-elevation change in the study area primarily is caused by the withdrawal of groundwater. Groundwater withdrawn from the Chicot and Evangeline aquifers has been the primary source of water for municipal supply, industrial and commercial use, and irrigation in the study area. Groundwater withdrawals cause compaction of clay and silt layers abundant in the aquifers, which has in turn resulted in the widespread, substantial land-surface-elevation changes in the region with increased flooding. To estimate land-surface-elevation changes, the U.S. Geological Survey (USGS), in cooperation with the Harris-Galveston Subsidence District (HGSD), documented land-surface-elevation changes in the study area that occurred during 2000–10 and 2005–10 based on elevation data measured by 11 USGS borehole-extensometer sites, a National Geodetic Survey Continuously Operating Reference Station, and Global Positioning System Port-A-Measure (PAM) sites operated by the HGSD and the Fort Bend Subsidence District. Groundwater withdrawals in the study area also were documented for 1976, 1990, and 2000–10. In 1976, about 428.9 million gallons per day (Mgal/d) were withdrawn from the aquifer system in Harris County, but by 2000, because of HGSD regulation, withdrawals had decreased to about 337.8 Mgal/d, or about a 21-percent reduction since 1976. By 2010, withdrawals had decreased to about 227.1 Mgal/d, or about a 47-percent reduction since 1976. Among the counties in the study area, the largest decrease in groundwater withdrawals has occurred in Galveston County since 1976. In 1976, about 27.4 Mgal/d were withdrawn from the aquifer system, and by 2000, withdrawals had decreased to about 4.12 Mgal/d, or about an 85-percent reduction since 1976. By 2010, withdrawals had decreased to about 0.626 Mgal/d, or about a 98-percent decrease since 1976. Since the mid-1970s, Fort Bend and Montgomery Counties have undergone extensive urban development and corresponding large increases in groundwater withdrawals. Total groundwater withdrawal for Fort Bend County in 1976 was about 16.0 Mgal/d, and by 2000, withdrawals had increased to about 86.5 Mgal/d, or about a 441-percent increase since 1976. By 2010, withdrawals in Fort Bend County had increased to about 99.8 Mgal/d, or about a 524-percent increase since 1976. Total groundwater withdrawal for Montgomery County in 1976 was about 7.84 Mgal/d, and by 2000, withdrawals had increased to about 43.6 Mgal/d, or about a 456-percent increase since 1976. By 2010, withdrawals in Montgomery County had increased to about 64.2 Mgal/d, or about a 719-percent increase since 1976. Total groundwater withdrawal in Brazoria County in 1976 was about 18.0 Mgal/d, and by 2000, withdrawals had increased to about 26.0 Mgal/d, or about a 44-percent increase. By 2010, withdrawals in Brazoria County had increased to about 24.7 Mgal/d, or about a 37-percent increase since 1976. Measured land-surface-elevation changes from December 31, 2000, to December 31, 2010, ranged from an elevation increase of 0.06 feet (ft), or an average increase in elevation of 0.006 ft per year, at the Seabrook borehole extensometer located near Seabrook, Tex., to an elevation decrease of 1.28 ft, or an average decrease in elevation of 0.128 ft per year, at a PAM station north of Jersey Village, Tex. (PAM 07). Measured land-surface-elevation changes from December 31, 2005, to December 31, 2010, ranged from an elevation increase of 0.07 ft, or an average increase in elevation of 0.014 ft per year, at PAM 09 in far northeastern Harris County to an elevation decrease of 0.51 ft, or an average decrease in elevation of 0.102 ft per year, at PAM 07.

Texas↗

USGS1987

Modes of development of slope canyons and their relation to channel and levee features on the Ebro sediment apron, off-shore northeastern Spain

Six submarine slope canyons in an area of the northwestern Mediterranean, offshore from the Ebro River and Delta, were surveyed with bathymetric swathmapping (SeaBeam) and mid-range side-looking sonar (SeaMARC I). All of the canyons have slightly winding paths with concave-upwards gradients that are relatively steep shallower than 1,200 m. Two major types of canyons are identified on the basis of their morphologic character at the base of the slope; Type-I canyons lead to an unchannelled base-of-slope deposit and Type-II canyons are continuous with channel-levee systems that cross the rise. Four Type-I canyons were surveyed in the area. Two of these are broad, U-shaped, steep (average gradients of 1:14), do not indent the shelf, and terminate downslope at debris-flow deposits. These two canyons, the most northern in the area, have rounded heads with extensive gullies separated by knife-edge ridges. Relief of the canyon walls is about equal on both sides of the canyons, although the right-hand walls (looking downslope) are generally steeper. The other two Type-I canyons in the area are similar in that they do not indent the shelf, but they are much smaller and shallower and coalesce before terminating in the base-of-slope region. The two Type-II canyons that feed leveed-channels are U-shaped with flatter floors, longer profiles and gentler gradients than Type-I canyons. They are closer to the Valencia Valley and have relatively small cross-sectional areas. We propose a four-stage evolutionary sequence to explain the development of the canyons observed in this section on the prograding Ebro margin. During the initial stage, slumping and erosion on the slope creates a network of small gullies. During the next stage, headward growth of one (or more) gully leads to a major indentation of the shelf. This is the critical factor for developing a channel that will incise the slope and provide a major conduit for moving sediment to the basin. Stage 3 is characterized by the development of a continuous channel accompanied by levee growth across the lobe. In the final stage, the channel-levee system becomes inactive either through destruction by mass wasting, infilling of the channel, or loss of the major sediment source. ?? 1987.

Marine and Petroleum Geology↗

USGS1968

Stratigraphy and structure of the tatum salt dome area, southeastern Mississippi and northeastern Washington Parish, Louisiana

In the 3000-square-mile area of southeastern Mississippi and northeastern Washington Parish , Louisiana , which has Tatum dome in its center, rocks of known Jurassic to Recent age are more than 20,000 feet thick. They are underlain by an unknown thickness of Louann Salt of Jurassic (?) age. The age, thickness, and nature of the sedimentary rocks between the salt and the basement, as well as the character of the basement, are unknown. The salt in the northern half of the area has moved upward to shallow depths as diapirs in overlying rocks. Outside of the area of shallow-piercement domes there are more deeply seated domes, ridges, and anticlines that may be the result of vertical movement of the salt . The Wiggins anticline in the south and, southwest of it, an area dipping more steeply to the southwest probably were not affected by salt movement. Structural maps of four horizons and isopach maps of rocks in the three intervals between them give information about the sedimentary and structural history of the region since the end of Early Cretaceous time. The horizons contoured mark either unconformities or the upper boundaries of zones of fairly uniform structural history. The top of the Lower Cretaceous rocks dips generally to the west. Upper Cretaceous rocks dip to the west-southwest and thicken to the northeast. Pre-Miocene Tertiary rocks dip to the southwest and thicken to the northwest. Miocene and later rocks dip and thicken to the south-southwest. The structure of the older formations is considerably more irregular than that of the younger ones; domes, ridges, and basins that were conspicuous in the Early Cretaceous became less pronounced as younger sediments progressively covered them. Of the eight shallow-piercement domes with which the author is familiar, three are known to have penetrated Oligocene rocks; two, middle Eocene; one, lower Eocene; one, Upper Cretaceous; and one, Lower Cretaceous. Some movement has taken place at Tatum dome since the sandy, gravelly Citronelle Formation was laid down.

Louisiana, Mississippi↗

USGS2001

Using multiple geochemical tracers to characterize the hydrogeology of the submarine spring off Crescent Beach, Florida

A spectacular submarine spring is located about 4 km east of Crescent Beach, FL, in the Atlantic Ocean. The single vent feature of Crescent Beach Spring provides a unique opportunity to examine onshore–offshore hydrogeologic processes, as well as point source submarine ground water discharge. The Floridan aquifer system in northeastern Florida consists of Tertiary interspersed limestone and dolomite strata. Impermeable beds confine the water-bearing zones under artesian pressure. Miocene and younger confining strata have been eroded away at the vent feature, enabling direct hydrologic communication of Eocene ground water with coastal bottom waters. The spring water had a salinity of 6.02, which was immediately diluted by ambient seawater during advection/mixing. The concentration of major solutes in spring water and onshore well waters confirm a generalized easterly flow direction of artesian ground water. Nutrient concentrations were generally low in the reducing vent samples, and the majority of the total nitrogen species existed as NH 3 . The submarine ground water tracers, Rn-222 (1174 dpm l −1 , dpm), methane (232 nM) and barium (294.5 nM) were all highly enriched in the spring water relative to ambient seawater. The concentrations of the reverse redox elements U, V and Mo were expectedly low in the submarine waters. The strontium isotope ratio of the vent water ( 87 Sr/ 86 Sr=0.70798) suggests that the spring water contain an integrated signature indicative of Floridan aquifer system ground water. Additional Sr isotopic ratios from a series of surficial and Lower Floridan well samples suggest dynamic ground water mixing, and do not provide clear evidence for a single hydrogeologic water source at the spring vent. In this karst-dominated aquifer, such energetic mixing at the vent feature is expected, and would be facilitated by conduit and fractured flow. Radium isotope activities were utilized to estimate flow-path trajectories and to provide information on potential travel times between an onshore well and the spring. Using either 223 Ra and 224 Ra or 228 Ra, and qualifying this approach with several key assumptions, estimates of water mass travel times from an upper Floridan well in Crescent Beach to the submarine vent feature (distance=4050 m) are in the order of ∼0.01–0.1 m min −1 .

Florida↗

USGS1915

Springs of California

In 1903 the United States Geological Survey began an investigation of the underground water of California, generally with financial cooperation on the part of the State. Since that year ten papers on the underground water of the State have been issued by the Survey, each representing an investigation that has been completed. The field work which is to serve as the basis for two additional papers has also been done and the reports are in preparation. Investigations have been begun in two other areas in the State and their results will eventually be assembled and published. Since a period soon after the inception of the California work those responsible for its conduct have realized the desirability of a special study of the springs, particularly those which yield mineral waters and which are utilized to a greater or less extent by citizens of the State and by tourists as recreation and health resorts. It did not become practicable to begin this work until the summer of 1908, when Mr. G. A. Waring, who had assisted in some of the earlier California studies and had investigated for the Survey certain areas in southern Oregon and Washington, was assigned to the task of collecting and assembling the necessary data. California, with an area of 158,000 square miles, is the second largest State in the Union. It exhibits wide geographic diversity, since it includes the lowest area in the United States Death Valley, 276 feet below sea level and the highest Mount Whitney, 14,501 feet above the sea; and accompanying this geographic diversity there is a corresponding range in scenic effects, climate, and vegetation. The records obtained at meteorological stations in the Salton Sink indicate a maximum temperature of 130° in the shade, the highest of record within the continental United States. It is probable that minimum temperatures on the higher peaks, like Mount Whitney and Mount Shasta, approach the minimum within our boundaries. Rainfall records in the most arid sections of the southern deserts of the State represent the extreme of aridity in the United States, with averages of less than 3 inches per annum and periods of 12 months or more with only traces of rain, whereas the precipitation in northwestern California is very heavy, an annual average of close to 100 inches being recorded at a few stations in Mendocino and Del Norte counties. The immensity of the area of the State has made the collection of the field data required for the report a task of considerable magnitude, though its diversity has added greatly to the interest of the work. In the original plan it was estimated that two years of field studies would prove sufficient. Mr. Waring succeeded in visiting the more important localities during this period, although some of his examinations were, of necessity, rather cursory. In midsummer, 1910, after the completion of the field work and the assembling of the greater portion of his data in manuscript form he was called by the Government of Brazil to take charge of general water supply investigations in the northeastern arid portion of that South American republic. The task of reviewing, editing, and supplementing in some respects, the results of his studies was thus unavoidably left to others. This task was rendered light by the systematic form in which Mr. Waring's material was left. It was a matter of regret to Mr. Waring, as it has been to those associated with him, that the financial limitations which controlled his work made it impracticable to procure the large number of new analyses which are particularly important in a paper of this type, in which waters of unusual chemical characteristics are discussed. Such analyses as are available have been assembled from all possible sources and combined with those which were prepared especially in connection with this investigation. The result, although it is in some respects unsatisfactory, furnishes a basis for a general view of the characteristics of the spring waters and serves to permit, their classification in a general way. Mr. Herman Stabler has reviewed the chemical data and rearranged and interpreted the available analyses. It is hoped that the report, setting forth as it does the results of impartial observations upon one of the important present and more important prospective resources of the State, will prove of value to its citizens as well as to its visitors, and that the assembled material will not be without interest to physicians, chemists, geologists, and teachers who may have especial need for the information contained in the volume.

California↗

USGS2017

Water quality, sources of nitrate, and chemical loadings in the Geronimo Creek and Plum Creek watersheds, south-central Texas, April 2015–March 2016

Located in south-central Texas, the Geronimo Creek and Plum Creek watersheds have long been characterized by elevated nitrate concentrations. From April 2015 through March 2016, an assessment was done by the U.S. Geological Survey, in cooperation with the Guadalupe-Blanco River Authority and the Texas State Soil and Water Conservation Board, to characterize nitrate concentrations and to document possible sources of elevated nitrate in these two watersheds. Water-quality samples were collected from stream, spring, and groundwater sites distributed across the two watersheds, along with precipitation samples and wastewater treatment plant (WWTP) effluent samples from the Plum Creek watershed, to characterize endmember concentrations and isotopic compositions from April 2015 through March 2016. Stream, spring, and groundwater samples from both watersheds were collected during four synoptic sampling events to characterize spatial and temporal variations in water quality and chemical loadings. Water-quality and -quantity data from the WWTPs and stream discharge data also were considered. Samples were analyzed for major ions, selected trace elements, nutrients, and stable isotopes of water and nitrate. The dominant land use in both watersheds is agriculture (cultivated crops, rangeland, and grassland and pasture). The upper part of the Plum Creek watershed is more highly urbanized and has five major WWTPs; numerous smaller permitted wastewater outfalls are concentrated in the upper and central parts of the Plum Creek watershed. The Geronimo Creek watershed, in contrast, has no WWTPs upstream from or near the sampling sites. Results indicate that water quality in the Geronimo Creek watershed, which was evaluated only during base-flow conditions, is dominated by groundwater, which discharges to the stream by numerous springs at various locations. Nitrate isotope values for most Geronimo Creek samples were similar, which indicates that they likely have a common source (or sources) of nitrate. Nitrate sources in the Geronimo Creek watershed include a predominance of nitrate from fertilizer applications, as well as a contribution from septic systems. Additional nitrate loading from these sources is ongoing. Chemical loadings of dissolved solids, chloride, and sulfate varied little among sampling events and were low at most sites because of low streamflow. In contrast to the Geronimo Creek watershed, nitrate sources in the Plum Creek watershed are dominated by effluent discharge from the major WWTPs in the upper and central parts of the watershed. Results indicate that discharge from these WWTPs accounts for the majority of base flow in the watershed. Nitrate concentrations in Plum Creek were dependent on flow conditions, with the highest concentrations measured at lower flows, when flow is dominated by WWTP effluent discharge. In addition to WWTP effluent discharge, the Plum Creek watershed, similar to the Geronimo Creek watershed, also is affected by historical and current loading of nitrate from fertilizer applications and from septic systems in the watershed. Chemical loadings of dissolved solids, chloride, sulfate, and nitrate in Plum Creek at lower flow conditions are highest at the upstream sites and decrease downstream as distance from the WWTPs increases, which is consistent with WWTP effluent as an important control on water quality. Under higher flow conditions, however, nitrate loads to Plum Creek increased by about a factor of three. These higher nitrate loads cannot be accounted for by WWTP effluent discharge from the five major WWTPs in the watershed. This additional loading indicates that nitrate is exported from the northeastern part of the watershed. In the lower part of the Plum Creek watershed, higher concentrations of dissolved solids, chloride, and sulfate occur, which might be affected by produced water associated with oil and gas exploration, or mixing with saline groundwater.

Texas↗

USGS2009

Palaeoseismology of the Vilariça segment of the Manteigas-Bragança fault in northeastern Portugal

The Manteigas-Bragança fault is a major, 250-km-long, NNE-striking, sinistral strike-slip structure in northern Portugal. This fault has no historical seismicity for large earthquakes, although it may have generated moderate (M5+) earthquakes in 1751 and 1858. Evidence of continued left horizontal displacement is shown by the presence of Cenozoic pull-apart basins as well as late Quaternary stream deflections. To investigate its recent slip history, a number of trenches were excavated at three sites along the Vilariça segment, north and south of the Douro River. At one site at Vale Meão winery, the occurrence of at least two and probably three events in the past 14.5 ka was determined, suggesting an average return period of about 5–7 ka. All three events appear to have occurred as a cluster in the interval between 14.5 and 11 ka, or shortly thereafter, suggesting a return period of less than 2 ka between events within the cluster. In the same area, a small offset rill suggests 2–2.5 m of slip in the most recent event and about 6.1 m after incision below a c . 16 ka alluvial fill event along the Douro River. At another site along the Vilariça River alluvial plain, NE of the Vale Meão site, several trenches were excavated in late Pleistocene and Holocene alluvium, and exposed the fault displacing channel deposits dated to between 18 and 23 ka. In a succession of closely spaced parallel cuts and trenches, the channel riser was traced into and across the fault to resolve c . 6.5 m of displacement after 18 ka and c . 9 m of slip after c . 23 ka. These observations yield a slip rate of 0.3–0.5 mm/a, which is consistent with earlier estimates. Combining the information on timing at Vale Meão winery and displacement at Vilariça argues for earthquakes in the M7+ range, with coseismic displacements of 2–3 m. This demonstrates that there are potential seismic sources in Portugal that are not associated with the 1755 Lisbon earthquake or the Tagus Valley, and, although rare, large events on the Vilariça fault could be quite destructive for the region. This work provides an analogue for the study of active faulting in intracontinental settings and supports the view that earthquakes within intracontinental settings tend to cluster in time. In addition, this study highlights the usefulness and application of multiple field, remote sensing and geochronological techniques for seismic hazard mitigation.

Manteigas - Braganca fault↗

USGS2017

Sequence stratigraphy, seismic stratigraphy, and seismic structures of the lower intermediate confining unit and most of the Floridan aquifer system, Broward County, Florida

Deep well injection and disposal of treated wastewater into the highly transmissive saline Boulder Zone in the lower part of the Floridan aquifer system began in 1971. The zone of injection is a highly transmissive hydrogeologic unit, the Boulder Zone, in the lower part of the Floridan aquifer system. Since the 1990s, however, treated wastewater injection into the Boulder Zone in southeastern Florida has been detected at three treated wastewater injection utilities in the brackish upper part of the Floridan aquifer system designated for potential use as drinking water. At a time when usage of the Boulder Zone for treated wastewater disposal is increasing and the utilization of the upper part of the Floridan aquifer system for drinking water is intensifying, there is an urgency to understand the nature of cross-formational fluid flow and identify possible fluid pathways from the lower to upper zones of the Floridan aquifer system. To better understand the hydrogeologic controls on groundwater movement through the Floridan aquifer system in southeastern Florida, the U.S. Geological Survey and the Broward County Environmental Planning and Community Resilience Division conducted a 3.5-year cooperative study from July 2012 to December 2015. The study characterizes the sequence stratigraphy, seismic stratigraphy, and seismic structures of the lower part of the intermediate confining unit aquifer and most of the Floridan aquifer system. Data obtained to meet the study objective include 80 miles of high-resolution, two-dimensional (2D), seismic-reflection profiles acquired from canals in eastern Broward County. These profiles have been used to characterize the sequence stratigraphy, seismic stratigraphy, and seismic structures in a 425-square-mile study area. Horizon mapping of the seismic-reflection profiles and additional data collection from well logs and cores or cuttings from 44 wells were focused on construction of three-dimensional (3D) visualizations of eight sequence stratigraphic cycles that compose the Eocene to Miocene Oldsmar, Avon Park, and Arcadia Formations. The mapping of these seismic-reflection and well data has produced a refined Cenozoic sequence stratigraphic, seismic stratigraphic, and hydrogeologic framework of southeastern Florida. The upward transition from the Oldsmar Formation to the Avon Park Formation and the Arcadia Formation embodies the evolution from (1) a tropical to subtropical, shallow-marine, carbonate platform, represented by the Oldsmar and Avon Park Formations, to (2) a broad, temperate, mixed carbonate-siliciclastic shallow marine shelf, represented by the lower part of the Arcadia Formation, and to (3) a temperate, distally steepened carbonate ramp represented by the upper part of the Arcadia Formation. In the study area, the depositional sequences and seismic sequences have a direct correlation with hydrogeologic units. The approximate upper boundary of four principal permeable units of the Floridan aquifer system (Upper Floridan aquifer, Avon Park permeable zone, uppermost major permeable zone of the Lower Floridan aquifer, and Boulder Zone) have sequence stratigraphic and seismic-reflection signatures that were identified on cross sections, mapped, or both, and therefore the sequence stratigraphy and seismic stratigraphy were used to guide the development of a refined spatial representation of these hydrogeologic units. In all cases, the permeability of the four permeable units is related to stratiform megaporosity generated by ancient dissolution of carbonate rock associated with subaerial exposure and unconformities at the upper surfaces of carbonate depositional cycles of several hierarchical scales ranging from high-frequency cycles to depositional sequences. Additionally, interparticle porosity also contributes substantially to the stratiform permeability in much of the Upper Floridan aquifer. Information from seismic stratigraphy allowed 3D geomodeling of hydrogeologic units—an approach never before applied to this area. Notably, the 3D geomodeling provided 3D visualizations and geocellular models of the depositional sequences, hydrostratigraphy, and structural features. The geocellular data could be used to update the hydrogeologic structure inherent to groundwater flow simulations that are designed to address the sustainability of the water resources of the Floridan aquifer system. Two kinds of pathways that could enable upward cross-formational flow of injected treated wastewater from the Boulder Zone have been identified in the 80 miles of high-resolution seismic data collected for this study: a near-vertical reverse fault and karst collapse structures. The single reverse fault, inferred to be of tectonic origin, is in extreme northeastern Broward County and has an offset of about 19 feet at the level of the Arcadia Formation. Most of the 17 karst collapse structures identified manifest as columniform, vertically stacked sagging seismic reflections that span early Eocene to Miocene age rocks equivalent to much of the Floridan aquifer system and the lower part of the overlying intermediate confining unit. In some cases, the seismic-sag structures extend upward into strata of Pliocene age. The seismic-sag structures are interpreted to have a semicircular shape in plan view on the basis of comparison to (1) other seismic-sag structures in southeastern Florida mapped with two 2D seismic cross lines or 3D data, (2) comparison to these structures located in other carbonate provinces, and (3) plausible extensional ring faults detected with multi-attribute analysis. The seismic-sag structures in the study area have heights as great as 2,500 vertical feet, though importantly, one spans about 7,800 feet. Both multi-attribute analysis and visual detection of offset of seismic reflections within the seismic-sag structures indicate faults and fractures are associated with many of the structures. Multi-attribute analysis highlighting chimney fluid pathways also indicates that the seismic-sag structures have a high probability for potential vertical cross-formational fluid flow along the faulted and fractured structures. A collapse of the seismic-sag structures within a deep burial setting evokes an origin related to hypogenic karst processes by ascending flow of subsurface fluids. In addition, paleo-epigenic karst related to major regional subaerial unconformities within the Florida Platform generated collapse structures (paleo-sinkholes) that are much smaller in scale than the cross-formational seismic-sag structures.

Florida↗

USGS1980

Ordovician and Silurian Phi Kappa and Trail Creek formations, Pioneer Mountains, central Idaho: Stratigraphic and structural revisions, and new data on graptolite faunas

Recent geologic mapping in the northern Pioneer Mountains combined with the identification of graptolites from 116 new collections indicate that the Ordovician and Silurian Phi Kappa and Trail Creek Formations occur in a series of thrust-bounded slices within a broad zone of imbricate thrust faulting. Though confirming a deformational style first reported in a 1963 study by Michael Churkin, our data suggest that the complexity and regional extent of the thrust zone were not previously recognized. Most previously published sections of the Phi Kappa and Trail Creek Formations were measured across unrecognized thrust faults and therefore include not only structural repetitions of graptolitic Ordovician and Silurian rocks but also other tectonically juxtaposed lithostratigraphic units of diverse ages as well. Because of this discovery, the need to reconsider the stratigraphic validity of these formations and their lithology, nomenclature, structural distribution, facies relations, and graptolite faunas has arisen. The Phi Kappa Formation in most thrust slices has internal stratigraphic continuity despite the intensity of deformation to which it was subjected. As revised herein, the Phi Kappa Formation is restricted to a structurally repeated succession of predominantly black, carbonaceous, graptolitic argillite and shale. Some limy, light-gray-weathering shale occurs in the middle part of the section, and fine-grained locally pebbly quartzite is present at the base. The basal quartzite is here named the Basin Gulch Quartzite Member of the Phi Kappa. The Phi Kappa redefined on a lithologic basis represents the span of Ordovician time from W. B. N. Berry's graptolite zones 2-4 through 15 and also includes approximately 17 m of lithologically identical shale of Early and Middle Silurian age at the top. The lower contact of the formation as revised is tectonic. The Phi Kappa is gradationally overlain by the Trail Creek Formation as restricted herein. Most of the coarser clastic rocks reported in previously measured sections of the Phi Kappa, as well as the sequence along Phi Kappa Creek from which the name originates, are excluded from the Phi Kappa as revised and are reassigned to two structural plates of Mississippian Copper Basin Formation; other strata now excluded from the formation are reassigned to the Trail Creek Formation and to an unnamed Silurian and Devonian unit. As redefined, the Phi Kappa Formation is only about 240 m thick, compared with the 3,860 m originally estimated, and it occupies only about 25 percent of the outcrop area previously mapped in 1930 by H. G. Westgate and C. P. Ross. Despite this drastic reduction in thickness and the exclusion of the rocks along Phi Kappa Creek, the name Phi Kappa is retained because of widely accepted prior usage to denote the Ordovician graptolitic shale facies of central Idaho, and because the Phi Kappa Formation as revised is present in thrust slices on Phi Kappa Mountain, at the head of Phi Kappa Creek. The lithic and faunal consistency of this unit throughout the area precludes the necessity for major facies telescoping along individual faults within the outcrop belt. However, tens of kilometers of tectonic shortening seems required to juxtapose the imbricated Phi Kappa shale facies with the Middle Ordovician part of the carbonate and quartzite shale sequence of east central Idaho. The shelf rocks are exposed in the Wildhorse structural window of the northeastern Pioneer Mountains, and attain a thickness of at least 1,500 m throughout the region north and east of the Pioneer Mountains. The Phi Kappa is in direct thrust contact on intensely deformed medium- to high-grade metamorphic equivalents of the same shelf sequence in the Pioneer window at the south end of the Phi Kappa-Trail Creek outcrop belt. Along East Pass, Big Lake, and Pine Creeks, north of the Pioneer Mountains, some rocks previously mapped as Ramshorn Slate are lithologically and faunally equivalent to the P

Idaho↗

USGS1991

Sedimentation and tectonics of the Sylhet trough, Bangladesh

The Sylhet trough, a sub-basin of the Bengal Basin in northeastern Bangladesh, contains a thick fill (12 to 16 km) of late Mesozoic and Cenozoic strata that record its tectonic evolution. Stratigraphic, sedimentologic, and petrographic data collected from outcrops, cores, well logs, and seismic lines are here used to reconstruct the history of this trough. The Sylhet trough occupied a slope/basinal setting on a passive continental margin from late Mesozoic through Eocene time. Subsidence may have increased slightly in Oligocene time when the trough was located in the distal part of a foreland basin paired to the Indo-Burman ranges. Oligocene fluvial-deltaic strata (Barail Formation) were derived from incipient uplifts in the eastern Himalayas. Subsidence increased markedly in the Miocene epoch in response to western encroachment of the Indo-Burman ranges. Miocene to earliest Pliocene sediments of the Surma Group were deposited in a large, mud-rich delta system that may have drained a significant proportion of the eastern Himalayas. Subsidence rates in the Sylhet trough increased dramatically (3-8 times) from Miocene to Pliocene-Pleistocene time when the fluvial Tipam Sandstone and Dupi Tila Formation were deposited. This dramatic subsidence change is attributed to south-directed overthrusting of the Shillong Plateau on the Dauki fault for the following reasons. (1) Pliocene and Pleistocene strata thin markedly away from the Shillong Plateau, consistent with a crustal load emplaced on the northern basin margin. (2) The Shillong Plateau is draped by Mesozoic to Miocene rocks, but Pliocene and younger strata are not represented, suggesting that the massif was an uplifted block at this time. (3) South-directed overthrusting of the Shillong Plateau is consistent with gravity data and with recent seismotectonic observations. Sandstone in the Tioam has a marked increase in sedimentary lithic fragments compared to older rocks, reflecting uplift and erosion of the sedimentary cover of the Shillong Plateau. If the Dauki fault has a dip similar to that of other Himalayan overthrusts, then a few tens of kilometers of horizontal tectonic transport would be required to carry the Shillong Plateau to its present elevation. Uplift of the Shillong Plateau probably generated a major (∼300 km) westward shift in the course of the Brahmaputra River.

Geological Society of America Bulletin↗

USGS2019

Water-quality and geochemical variability in the Little Arkansas River and Equus aquifer, south-central Kansas, 2001–16

The city of Wichita’s water supply currently (2019) comes from two primary sources: Cheney Reservoir and the Equus Beds aquifer. The Equus Beds aquifer storage and recovery project was developed to help the city of Wichita meet increasing future water demands. Source water for artificial recharge comes from the Little Arkansas River during above-base-flow conditions, is treated using National Primary Drinking Water Regulations as a guideline, and is injected into the Equus Beds aquifer through recharge wells or surface spreading basins for later use. The Equus Beds aquifer storage and recovery project currently (2019) consists of two coexisting phases. Phase I began in 2007 and captures Little Arkansas River water and indirect streambank diversion well water for aquifer recharge using 4 wells and 2 recharge basins. Phase II began in 2013 and currently (2019) includes a surface-water treatment facility, a river intake facility, eight recharge injection wells, and a third recharge basin. The U.S. Geological Survey, in cooperation with the City of Wichita, completed this study to summarize water-quality and geochemical variability of the Equus Beds aquifer. Data in this report can be used to establish baseline conditions before implementing artificial aquifer recharge further, document groundwater quality, evaluate changing conditions, identify environmental factors affecting groundwater, provide science-based information for decision making, and help meet regulatory monitoring requirements. Physicochemical properties were measured and water-quality data were collected from 2 Little Arkansas River surface-water sites and 63 Equus Beds aquifer groundwater sites, including 38 areal assessment index wells (IWs) during 2001 through 2016. Data collection included discrete samples and additional continuous measurements at selected sites. Discretely collected samples were analyzed for physicochemical properties, dissolved solids, primary ions, nutrients (nitrogen and phosphorus species), organic carbon, indicator bacteria, trace elements, arsenic species, organic compounds, and radioactivity. This report focuses discussion on aquifer water quality. Federal drinking-water criteria were used to evaluate aquifer water quality. Primary drinking-water criteria are those that are enforceable for public drinking water. Secondary criteria are those that can cause aesthetics or tastes that are unpleasant. Continuously collected data at a subset of sites included streamflow, groundwater levels, water temperature, specific conductance, pH, oxidation-reduction potential (ORP), dissolved oxygen, turbidity, nitrate plus nitrite, and fluorescent dissolved organic matter. Continuous measurement of physicochemical properties in near-real time allowed characterization of Little Arkansas River surface water and Equus Beds aquifer groundwater during conditions and time scales that would not have been possible otherwise and served as a complement to discrete water-quality sampling. During 2001 through 2016, less than 1 percent of chloride and nitrate plus nitrite, 7 percent of dissolved iron, 48 percent of dissolved manganese, 12 percent of dissolved arsenic, and 39 percent of atrazine detections in surface-water samples exceeded their respective Federal primary or secondary drinking-water criteria. None of the surface-water samples collected exceeded the Federal sulfate criterion, and every sample had detections of total coliform bacteria during the study. Constituents of concern in the Equus Beds aquifer exceeded their respective Federal criteria throughout the study period and included chloride, sulfate, nitrate plus nitrite, Escherichia coli ( E. coli ), total coliforms, and dissolved iron and arsenic species. About 5 percent of shallow (less than 80 feet) and 7 percent of deep (greater than 80 feet) IW chloride sample concentrations exceeded the secondary Federal criterion of 250 milligrams per liter (mg/L). Chloride tended to exceed its criterion in shallow and deep wells along the Arkansas River and near Burrton, Kansas, an area with past oil and gas activities. Chloride concentrations near Burrton were larger in the deep parts of the aquifer. About 18 percent of shallow and 13 percent of deep IW sulfate sample concentrations exceeded the secondary Federal criterion of 250 mg/L. Mean sulfate concentrations tended to exceed the criterion in the central part of the study area. Shallow IW mean nitrate plus nitrite (hereafter referred to as “nitrate”) was substantially larger than mean deep IW nitrate. Geochemical conditions in the deeper aquifer reduced forms of nitrogen to species such as ammonia. About 15 percent of shallow and less than 1 percent of deep IW nitrate sample concentrations exceeded the Federal criterion of 10 mg/L. Mean shallow IW nitrate concentrations exceeded the criterion in the northeastern and southeastern parts of the study area; on average, deep IW nitrate concentrations did not exceed the criterion. E. coli and fecal coliform bacteria detections were usually at or near the detection limit. E. coli was detected in 3 percent of shallow and deep IWs, and fecal coliform bacteria were detected in 8 percent of shallow and 6 percent of deep IWs. Total coliforms were detected in 24 percent of shallow and 12 percent of deep IWs. E. coli coliphage was detected in two shallow IW samples (1 percent of samples) at the detection limit and was not detected in deep IW samples. Dissolved iron was detected in 51 percent of shallow and 62 percent of deep IW samples. Dissolved iron concentrations exceeded the secondary Federal criterion of 0.3 mg/L in 38 percent of shallow and 46 percent of deep IW samples. Mean dissolved iron concentrations were largest mostly in the central and northwest part of the study area corresponding to an area of the aquifer where aquifer material is more clay-rich. The distribution of large dissolved iron concentrations was similar to that of large sulfate concentrations. About 55 percent of shallow and 92 percent of deep IW dissolved manganese samples exceeded the secondary Federal criterion of 0.05 mg/L. Almost all samples from the central and northern parts of the study area had mean dissolved manganese concentrations that exceeded the Federal criterion in the shallow part of the aquifer. Mean dissolved manganese concentrations in the shallow part of the aquifer were substantially large (greater than 1,000 micrograms per liter [μg/L]) in wells near the Little Arkansas River and in the central part of the study area because of chemically reducing conditions in the aquifer that likely related to larger percentages of clay in the aquifer material. Concentrations of dissolved arsenic species generally were larger in the deep parts of the aquifer. Arsenite was the dominant form of arsenic on average in shallow (52 percent) and deep (55 percent) IWs. About 12 percent of shallow and 34 percent of deep IW dissolved arsenic sample concentrations exceeded the Federal primary drinking criterion of 10 μg/L. Shallow IW dissolved arsenic concentrations were larger near the Little Arkansas River and the center of the study area; large shallow IW dissolved arsenic concentrations (10–50 μg/L) in the center of the study area correspond to areas that have had the most water-level recovery since the historical low in 1993. Mean ORP in shallow IWs generally decreased with increasing water-level depths and were inversely related to mean dissolved arsenic concentrations because of more reducing conditions (smaller ORP) at larger depths below the land surface. Larger dissolved arsenic concentrations in the shallow parts of the aquifer were associated with decreases in water levels and a subsequent decrease in ORP and thus more reducing conditions. Atrazine was detected in about 58 percent of shallow and 28 percent of deep IWs and did not exceed the primary Federal criterion of 3 μg/L in any groundwater samples. Atrazine concentrations in shallow IWs generally were largest in the northwest part of the study area near the North Branch Kisiwa Creek, and atrazine concentrations in deep IWs generally were largest most often in the southern part of the study area. Gross α radioactivity concentrations exceeded the primary Federal criterion of 15 picocuries per liter in 4 percent of shallow IW samples. Gross α and gross β radioactivity concentrations generally were larger in the southern third of the aquifer. Most groundwater-sample-simulated minerals saturation indices (SIs) were consistently negative (undersaturated). Minerals that had SI values that were consistently or typically positive (oversaturated) included iron oxide, hydroxide, and quartz-group minerals. Several SI values for arsenic- and manganese-bearing minerals were consistently negative. Some manganese-bearing mineral SI values ranged from undersaturated to oversaturated in shallow and deep IWs during the study. Several carbonate minerals in shallow and deep IWs varied across their equilibrium state. Calcite SI values were larger more often in the deep parts of the aquifer and did not show a clear distributional pattern. Mean and median calcite SI values for shallow and deep IWs were negative (undersaturated) indicating the potential for calcite dissolution if calcite is present for a substantial part of the study period. However, some individual calcite SI values in this study indicated saturation and subsequent calcite precipitation may occur in the study area, potentially resulting in formation of calcite mineral deposits that may reduce efficiency of injection wells. SI values with respect to iron hydroxide varied across their equilibrium states. Mean and median SI values with respect to iron hydroxide were undersaturated in shallow and deep IWs; however, some samples had positive SI values indicating there is potential for iron hydroxide precipitation, possibly caused by leaching and oxidation of iron-containing minerals, like pyrite, in the aquifer material.

Kansas↗

USGS1985

The Dunbar Gneiss-granitoid dome: Implications for early Proterozoic tectonic evolution of northern Wisconsin

The Dunbar dome in northeastern Wisconsin is a critical structural feature in the early Proterozoic Penokean orogen. It provides exposures of gneisses (Dunbar Gneiss) that structurally underlie the voluminous metavolcanic rocks of northeastern Wisconsin, and exposures of abundant granitoid rocks ranging from tonalite to granite. The granitoid rocks cut both the gneisses in the core and the supracrustal (cover) metavolcanic rocks and were emplaced essentially along the core-cover boundary. The Dunbar Gneiss is calc-alkaline and was derived from volcanic and intrusive rocks of intermediate composition. The various intrusive rocks have calcic, calc-alkaline, and alkali to alkali-calcic compositions, and they progress with time to more SiO 2 and K 2 -rich compositions. U-Pb zircon ages indicate that accumulation of the layered rocks in the core and cover, deformation and metamorphism, and intrusion of the granitoid rocks spanned a relatively short time, ∼1865–1835 Ma. We interpret the dome as being a large-scale, fold-interference structure resulting from polydeformation modified by diapirism. Northeast-oriented folds (F 3 ) and a related mylonitic foliation (S 3 ), nearly confined to the dome, are superposed on northwest-oriented folds (F 2 ) that developed during regional deformation. In the core-cover boundary, these structures are obliterated by a zone of intense deformation—a mylonitic foliation and a steeply plunging stretching lineation—as much as 500 m wide, which we interpret as resulting from diapirism. Metamorphic zoning is concentric: amphibolite facies in inner parts of the mantle and greenschist facies in the outer part of the mantle. The Wisconsin magmatic terrane, as represented by the rocks in the Dunbar dome, differs from the epicratonic, early Proterozoic sedimentary-volcanic sequence (Marquette Range Supergroup) in Michigan, to the north, in stratigraphy, structure, and volume and composition of igneous rocks. Whereas the basalts in northern Michigan are compositionally similar to continental rift basalts, the volcanic rocks in the Dunbar dome have over-all island-arc compositional affinities. The over-all calc-alkaline compositions of the intrusive rocks are similar to those in magmatic arcs formed at convergent plate-margin settings. Accordingly, we interpret the Wisconsin magmatic terrane as an oceanic-arc complex that was sutured to the North American continent during development of the Penokean orogen. Similar interpretations based on broad regional observations have been proposed previously.

Michigan, Wisconsin↗

USGS2017

Groundwater quality for 75 domestic wells in Lycoming County, Pennsylvania, 2014

Groundwater is a major source of drinking water in Lycoming County and adjacent counties in north-central and northeastern Pennsylvania, which are largely forested and rural and are currently undergoing development for hydrocarbon gases. Water-quality data are needed for assessing the natural characteristics of the groundwater resource and the potential effects from energy and mineral extraction, timber harvesting, agriculture, sewage and septic systems, and other human influences. This report, prepared in cooperation with Lycoming County, presents analytical data for groundwater samples from 75 domestic wells sampled throughout Lycoming County in June, July, and August 2014. The samples were collected using existing pumps and plumbing prior to any treatment and analyzed for physical and chemical characteristics, including nutrients, major ions, metals and trace elements, volatile organic compounds, gross-alpha particle and gross beta-particle activity, uranium, and dissolved gases, including methane and radon-222. Results indicate groundwater quality generally met most drinking-water standards, but that some samples exceeded primary or secondary maximum contaminant levels (MCLs) for arsenic, iron, manganese, total dissolved solids (TDS), chloride, pH, bacteria, or radon-222. Arsenic concentrations were higher than the MCL of 10 micrograms per liter (µg/L) in 9 of the 75 (12 percent) well-water samples, with concentrations as high as 23.6 μg/L; arsenic concentrations were higher than the health advisory level (HAL) of 2 μg/L in 23 samples (31 percent). Total iron concentrations exceeded the secondary maximum contaminant level (SMCL) of 300 μg/L in 20 of the 75 samples. Total manganese concentrations exceeded the SMCL of 50 μg/L in 20 samples and the HAL of 300 μg/L in 2 of those samples. Three samples had chloride concentrations that exceeded the SMCL of 250 milligrams per liter (mg/L); two of those samples exceeded the SMCL of 500 mg/L for TDS. The pH ranged from 5.3 to 9.15 and did not meet the SMCL range of 6.5 to 8.5 in 22 samples, with 17 samples having a pH less than 6.5 and 8 samples having pH greater than 8.5. Generally, the samples that had elevated TDS, chloride, or arsenic concentrations had high pH. Total coliform bacteria were detected in 39 of 75 samples (52 percent), with Escherichia coli detected in 10 of those 39 samples. Radon-222 activities ranged from non-detect to 7,420 picocuries per liter (pCi/L), with a median of 863 pCi/L, and exceeded the proposed drinking-water standard of 300 pCi/L in 50 (67 percent) of the 75 samples; radon-222 activities were higher than the alternative proposed standard of 4,000 pCi/L in 3 samples. Water from 15 of 75 (20 percent) wells had concentrations of methane greater than the reporting level of 0.01 mg/L; detectable methane concentrations ranged from 0.04 to 16.8 mg/L. Two samples had methane concentrations (13.1 and 16.8 mg/L) exceeding the action level of 7 mg/L. Low levels of ethane (up to 0.12 mg/L) were present in the five samples with the highest methane concentrations (near or above 1 mg/L) that were analyzed for hydrocarbon compounds and isotopic composition. The isotopic composition of methane in four of these groundwater samples, from the Catskill and Lock Haven Formations and the Hamilton Group, have sample carbon isotopic ratio delta values (carbon-13/carbon-12) ranging from –42.36 to –36.08 parts per thousand (‰) and hydrogen isotopic ratio delta values (deuterium/protium) ranging from –212.0 to –188.4 ‰, which are consistent with the isotopic compositions reported for mud-gas logging samples from these geologic units and a thermogenic source of the methane. However, the isotopic composition and ratios of methane to ethane in a fifth sample indicate the methane in that sample may be of microbial origin that subsequently underwent oxidation. The fifth sample had the highest concentration of methane, 16.8 mg/L, with an carbon isotopic ratio delta values of -50.59 ‰ and a hydrogen isotopic ratio delta values of -209.7 ‰. The six well-water samples with the highest methane concentrations also had among the highest pH values (8.25 to 9.15) and elevated concentrations of sodium, lithium, boron, fluoride, arsenic, and bromide. Relatively elevated concentrations of some other constituents, such as barium, strontium, and chloride, commonly were present in, but not limited to, those well-water samples with elevated methane. Three of the six groundwater samples with the highest methane concentrations had chloride/bromide ratios that indicate mixing with a small amount of brine (0.02 percent or less) similar in composition to those reported at undetermined depth below the freshwater aquifer and for gas and oil well brines in Pennsylvania. The sample with the highest methane concentration and most other samples with low methane concentrations (less than about 1 mg/L) have chloride/bromide ratios that indicate predominantly anthropogenic sources of chloride, such as road-deicing salt, septic systems, and (or) animal waste. Brines that are naturally present may originate from deeper parts of the aquifer system, while anthropogenic sources are more likely to affect shallow groundwater because they occur on or near the land-surface. The spatial distribution of groundwater compositions generally indicate that (1) uplands along the western border of Lycoming County usually have dilute, slightly acidic oxygenated, calcium-bicarbonate type waters; (2) intermediate altitudes or areas of carbonate bedrock usually have water of near neutral pH, with highest amounts of hardness (calcium and magnesium); (3) stream valleys, low elevations where groundwater may be discharging, and deep wells in uplands usually have water with pH values greater than 8 and highest arsenic, sodium, lithium, bromide concentrations. Geochemical modeling indicated that for samples with elevated pH, sodium, lithium, bromide, and alkalinity, the water chemistry could have resulted by dissolution of calcite (calcium carbonate) combined with cation-exchange and mixing with a small amount of brine. Through cation-exchange reactions between water and bedrock, which are equivalent to processes in a water softener, calcium ions released by calcite dissolution are exchanged for sodium ions on clay minerals. Thus, the assessment of groundwater quality in Lycoming County indicates groundwater is generally of good quality, but various parts of Lycoming County can have groundwater with low to moderate concentrations of methane and other constituents that appear in naturally present brine and produced waters from gas and oil wells at high concentrations."

Pennsylvania↗

USGS1956

Floods of August 1955 in the Northeastern States

The floods of August 1955 were an unprecedented disaster in a arge area of the northeastern United States. They rank among the most destructive in the country's his ory. Augmented by the antecedent hurricane sto m of August 11-15, the rainfall of August 17-20 accompanying hurricane Diane reached maximum val es of 17 to 19 inches in south-central Massachusett • Record-breaking floods resulted within a broad re ion extending from southeastern Pennsylvania to east rn Massachusetts. The floods were outstanding in four categories: The large geogra hie area covered by floods of such magnitude; the ex ensive damage and loss .of life ranking with the grea est recorded in this country; the degree to which prio records were exceeded; and the distribution which as such that the greatest floods occurred predominate! on the smaller streams. Property damage has been stimated to be about half a billion dollars and was most~y concentrated in the heavily industrialized valleys f New England. A death toll of 179 persons was attr"buted to the floods. Peak discharges exceeded previ usly established maxima by 2. 2 and 2. 3 times respec ively, on Blackstone River at Woonsocket, R. I. , and Q inebaug River at Putnam, Conn.; 4. 1 times on Nau atuck River near Thomaston, Conn. ; and 4. 5 times on 1 ush Kill at Shoemakers, Pa. A unit runoff of 2, 300 c 1 hie feet per second per square mile occurred from ~· 50 square miles on Powdermill Brook near Westfiel , Mass. Although the floods were generally greate t on the smaller streams, Connecticut River at Hart ord reached the third highest stage since settlement an Delaware River between Port Jervis and Trenton exce ded the previous historic flood of 1903. This adv ce report has been prepared to supply preliminary · formation needed for immediate planning. It has been r leased pending preparation of a more comprehensive r port covering a three-month period of floods within an area from Massachusetts to North Carolina. In luded herein, for the region from Massachuset s to Pennsylvania, are general descriptions of the fEods, peak discharges for the present and previous rec rd floods at gaging stations, peak discharges at m y miscellaneous sites in the areas of greatest floo ing, and detailed stage and discharge data at 51 selecte gaging stations.

Circular↗

USGS2015

Water-quality trends in the Scituate reservoir drainage area, Rhode Island, 1983-2012

The Scituate Reservoir is the primary source of drinking water for more than 60 percent of the population of Rhode Island. Water-quality and streamflow data collected at 37 surface-water monitoring stations in the Scituate Reservoir drainage area, Rhode Island, from October 2001 through September 2012, water years (WYs) 2002-12, were analyzed to determine water-quality conditions and constituent loads in the drainage area. Trends in water quality, including physical properties and concentrations of constituents, were investigated for the same period and for a longer period from October 1982 through September 2012 (WYs 1983-2012). Water samples were collected and analyzed by the Providence Water Supply Board, the agency that manages the Scituate Reservoir. Streamflow data were collected by the U.S. Geological Survey. Median values and other summary statistics for pH, color, turbidity, alkalinity, chloride, nitrite, nitrate, total coliform bacteria, Escherichia coli ( E. coli ), and orthophosphate were calculated for WYs 2003-12 for all 37 monitoring stations. Instantaneous loads and yields (loads per unit area) of total coliform bacteria and E. coli , chloride, nitrite, nitrate, and orthophosphate were calculated for all sampling dates during WYs 2003-12 for 23 monitoring stations with streamflow data. Values of physical properties and concentrations of constituents were compared with State and Federal water-quality standards and guidelines and were related to streamflow, land-use characteristics, varying classes of timber operations, and impervious surface areas. Tributaries in the Scituate Reservoir drainage area for WYs 2003-12 were slightly acidic (median pH of all stations equal to 6.1) and contained low median concentrations of chloride (22 milligrams per liter [mg/L]), nitrate (0.01 mg/L as nitrogen), nitrite (0.001 mg/L as nitrogen), and orthophosphate (0.02 milligrams per liter as phosphorus [mg/L as P]). Turbidity and alkalinity values also were low with medians of 0.57 nephelometric turbidity units and 5.1 mg/L as calcium carbonate, respectively. Total coliform bacteria and E. coli were detected in most samples from all stations, but median concentrations were generally low-43 colony-forming units per 100 milliliters (mL) and 15 colony-forming units per 100 milliliters, respectively. Median values of several physical properties and median concentrations of several constituents correlated positively with the percentages of developed land and negatively with the percentages of forest cover in the drainage areas above the monitoring stations. Median concentrations of chloride correlated positively with the percentages of impervious land use in the subbasins of monitoring stations, likely reflecting the effects of deicing compounds applied to roadways during winter maintenance. Median concentrations of alkalinity also correlated positively with the percentage of impervious land use, which may be related to the deterioration of fabricated structures containing calcium carbonate. Median values of color correlated positively with the percentage of wetland area in the subbasins of monitoring stations, reflecting the natural sources of color in tributaries. Streamflows were negatively correlated with turbidity and concentrations of total coliform bacteria and E. coli, possibly reflecting seasonal patterns in which relatively high values of these properties and constituents occur during warmer low-flow conditions late in the water year. Similar seasonal patterns were observed for pH, alkalinity, and color. Negative correlations between concentrations of chloride and streamflow also were significant, indicating that deicing salts from roadways and other impervious surfaces that lack direct connection to the tributaries are likely infiltrating to the groundwater and discharging to some of the tributaries late in the water year. While salt-laden runoff directly enters some of the tributaries at roadway crossings, most of the roadway runoff infiltrates into the adjacent berms throughout the drainage area. Statistically significant correlations were not identified between various degrees of tree-canopy reduction caused by timber operations in the subbasins and median values or concentrations of water-quality properties. Loads and yields of chloride, nitrate, nitrite, orthophosphate, and bacteria varied at monitoring stations in the Scituate Reservoir drainage area in WYs 2003-12. Loads generally were greater at stations in the Barden Reservoir and the Regulating Reservoir Subbasins that have larger drainage areas than in subbasins with smaller drainage areas. Subbasin yields of fecal-indicator bacteria and orthophosphate generally were largest in the Westconnaug Reservoir Subbasin, and subbasin yields for chloride, nitrate, and nitrite were largest in the Moswansicut Reservoir Subbasin in the northeastern part of the drainage area. Upward trends in pH were identified for nearly half of the monitoring stations for WYs 1983-2012 and may reflect regional reductions in acid precipitation. Many upward trends in alkalinity also were identified for both the WYs 1983-2012 and for WYs 2003-12 periods and are likely related to the natural weathering of structures containing concrete or, in some cases, the application of lime or fertilizers on agriculture lands. Significant trends in chloride concentrations at most stations during WYs 1983-2012 were upward; however, results for WYs 2003-12 substantiate few significant upward trends and, in a few cases, downward trends were identified in several tributary drainage areas.

Rhode Island↗

USGS2020

Reconstruction of an early Permian, sublacustrine magmatic-hydrothermal system: Mount Carlton epithermal Au-Ag-Cu deposit, northeastern Australia

The Mt. Carlton Au-Ag-Cu deposit, northern Bowen basin, northeastern Australia, is an uncommon example of a sublacustrine hydrothermal system containing economic high-sulfidation epithermal mineralization. The deposit formed in the early Permian and comprises vein- and hydrothermal breccia-hosted Au-Cu mineralization within a massive rhyodacite porphyry (V2 open pit) and stratabound Ag-barite mineralization within volcano-lacustrine sedimentary rocks (A39 open pit). These orebodies are all associated with extensive advanced argillic alteration of the volcanic host rocks. Stable isotope data for disseminated alunite ( δ 34 S = 6.3–29.2‰; δ 18 OSO 4 = –0.1 to 9.8‰; δ 18 O OH = –15.3 to –3.4‰; δ D = –102 to –79‰) and pyrite ( δ 34 S = –8.8 to –2.7‰), and void-filling anhydrite ( δ 34 S = 17.2–19.2‰; δ 18 O SO4 = 1.8–5.7‰), suggest that early advanced argillic alteration formed within a magmatic-hydrothermal system. The ascending magmatic vapor ( δ 34 S ΣS ≈ –1.3‰) was absorbed by meteoric water (~50–60% meteoric component), producing an acidic (pH ≈ 1) condensate that formed a silicic → quartz-alunite → quartz-dickite-kaolinite zoned alteration halo with increasing distance from feeder structures. The oxygen and hydrogen isotope compositions of alunite-forming fluids at Mt. Carlton are lighter than those documented at similar deposits elsewhere, probably due to the high paleolatitude (~S60°) of northeastern Australia in the early Permian. Veins of coarse-grained, banded plumose alunite ( δ 34 S = 0.4– 7.0‰; δ 18 O SO4 = 2.3–6.0‰; δ 18 O OH = –10.3 to –2.9‰; δ D = –106 to –93‰) formed within feeder structures during the final stages of advanced argillic alteration. Epithermal mineralization was deposited subsequently, initially as fracture- and fissure-filling, Au-Cu–rich assemblages within feeder structures at depth. As the mineralizing fluids discharged into lakes, they produced syngenetic Ag-barite ore. Isotope data for ore-related sulfides and sulfosalts ( δ 34 S = –15.0 to –3.0‰) and barite ( δ 34 S = 22.3–23.8‰; δ 18 O SO4 = –0.2 to 1.3‰), and microthermometric data for primary fluid inclusions in barite (Th = 116°– 233°C; 0.0–1.7 wt % NaCl), are consistent with metal deposition at temperatures of ~200 ± 40°C (for Au-Cu mineralization in V2 pit) and ~150 ± 30°C (Ag mineralization in A39 pit) from a low-salinity, sulfur- and metal-rich magmatic-hydrothermal liquid that mixed with vapor-heated meteoric water. The mineralizing fluids initially had a high-sulfidation state, producing enargite-dominated ore with associated silicification of the early-altered wall rock. With time, the fluids evolved to an intermediate-sulfidation state, depositing sphalerite- and tennantite-dominated ore mineral assemblages. Void-filling massive dickite ( δ 18 O = –1.1 to 2.1‰; δ D = –121 to –103‰) with pyrite was deposited from an increasingly diluted magmatic-hydrothermal liquid (≥70% meteoric component) exsolved from a progressively degassed magma. Gypsum ( δ 34 S = 11.4–19.2‰; δ 18 O SO4 = 0.5–3.4‰) occurs in veins within postmineralization faults and fracture networks, likely derived from early anhydrite that was dissolved by circulating meteoric water during extensional deformation. This process may explain the apparent scarcity of hypogene anhydrite in lithocaps elsewhere. While the Mt. Carlton system is similar to those that form subaerial high-sulfidation epithermal deposits, it also shares several key characteristics with magmatic-hydrothermal systems that form base and precious metal mineralization in shallow-submarine volcanic arc and back-arc settings. The lacustrine paleosurface features documented at Mt. Carlton may be useful as exploration indicators for concealed epithermal mineralization in similar extensional terranes elsewhere.

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