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USGS2016

The Chuar Petroleum System, Arizona and Utah

The Neoproterozoic Chuar Group consists of marine mudstone, sandstone and dolomitic strata divided into the Galeros and Kwagunt Formations, and is exposed only in the eastern Grand Canyon, Arizona. Research by the U.S. Geological Survey (USGS) in the late 1980s identified strata within the group to be possible petroleum source rocks, and in particular the Walcott Member of the Kwagunt Formation. Industry interest in a Chuar oil play led to several exploratory wells drilled in the 1990s in southern Utah and northern Arizona to test the overlying Cambrian Tapeats Sandstone reservoir, and confirm the existence of the Chuar in subcrop. USGS geochemical analyses of Tapeats oil shows in two wells have been tentatively correlated to Chuar bitumen extracts. Distribution of the Chuar in the subsurface is poorly constrained with only five well penetrations, but recently published gravity/aeromagnetic interpretations provide further insight into the Chuar subcrop distribution. The Chuar petroleum system was reexamined as part of the USGS Paradox Basin resource assessment in 2011. A map was constructed to delineate the Chuar petroleum system that encompasses the projected Chuar source rock distribution and all oil shows in the Tapeats Sandstone, assuming that the Chuar is the most likely source for such oil shows. Two hypothetical plays were recognized but not assessed: (1) a conventional play with a Chuar source and Tapeats reservoir, and (2) an unconventional play with a Chuar source and reservoir. The conventional play has been discouraging because most surface structures have been tested by drilling with minimal petroleum shows, and there is some evidence that petroleum may have been flushed by CO2 from Tertiary volcanism. The unconventional play is untested and remains promising even though the subcrop distribution of source facies within the Chuar Group is largely unknown.

Book chapter↗

USGS2015

Land use structures fish assemblages in reservoirs of the Tennessee River

Inputs of nutrients, sediments and detritus from catchments can promote selected components of reservoir fish assemblages, while hindering others. However, investigations linking these catchment subsidies to fish assemblages have generally focussed on one or a handful of species. Considering this paucity of community-level awareness, we sought to explore the association between land use and fish assemblage composition in reservoirs. To this end, we compared fish assemblages in reservoirs of two sub-basins of the Tennessee River representing differing intensities of agricultural development, and hypothesised that fish assemblage structure indicated by species percentage composition would differ among reservoirs in the two sub-basins. Using multivariate statistical analysis, we documented inter-basin differences in land use, reservoir productivity and fish assemblages, but no differences in reservoir morphometry or water regime. Basins were separated along a gradient of forested and non-forested catchment land cover, which was directly related to total nitrogen, total phosphorous and chlorophyll- a concentrations. Considering the extensive body of knowledge linking land use to aquatic systems, it is reasonable to postulate a hierarchical model in which productivity has direct links to terrestrial inputs, and fish assemblages have direct links to both land use and productivity. We observed a shift from an invertivore-based fish assemblage in forested catchments to a detritivore-based fish assemblage in agricultural catchments that may be a widespread pattern among reservoirs and other aquatic ecosystems.

Tennessee River↗

USGS2020

Research is needed to inform environmental management of hydrothermally inactive and extinct polymetallic sulfide (PMS) deposits

Polymetallic sulfide (PMS) deposits produced at hydrothermal vents in the deep sea are of potential interest to miners. Hydrothermally active sulfide ecosystems are valued for the extraordinary chemosynthetic communities that they support. Many countries, including Canada, Portugal, and the United States, protect vent ecosystems in their Exclusive Economic Zones. When hydrothermal activity ceases temporarily (dormancy) or permanently (extinction), the habitat and associated ecosystem change dramatically. Until recently, so-called “inactive sulfide” habitats, either dormant or extinct, received little attention from biologists. However, the need for environmental management of deep-sea mining places new imperatives for building scientific understanding of the structure and function of inactive PMS deposits. This paper calls for actions of the scientific community and the emergent seabed mining industry to i) undertake fundamental ecological descriptions and study of ecosystem functions and services associated with hydrothermally inactive PMS deposits, ii) evaluate potential environmental risks to ecosystems of inactive PMS deposits through research, and iii) identify environmental management needs that may enable mining of inactive PMS deposits. Mining of some extinct PMS deposits may have reduced environmental risk compared to other seabed mining activities, but this must be validated through scientific research on a case-by-case basis.

Marine Policy↗

USGS2017

Food-web dynamics and isotopic niches in deep-sea communities residing in a submarine canyon and on the adjacent open slopes

Examination of food webs and trophic niches provide insights into organisms' functional ecology, yet few studies have examined trophodynamics within submarine canyons, where the interaction of canyon morphology and oceanography influences habitat provision and food deposition. Using stable isotope analysis and Bayesian ellipses, we documented deep-sea food-web structure and trophic niches in Baltimore Canyon and the adjacent open slopes in the US Mid-Atlantic Region. Results revealed isotopically diverse feeding groups, comprising approximately 5 trophic levels. Regression analysis indicated that consumer isotope data are structured by habitat (canyon vs. slope), feeding group, and depth. Benthic feeders were enriched in 13 C and 15 N relative to suspension feeders, consistent with consuming older, more refractory organic matter. In contrast, canyon suspension feeders had the largest and more distinct isotopic niche, indicating they consume an isotopically discrete food source, possibly fresher organic material. The wider isotopic niche observed for canyon consumers indicated the presence of feeding specialists and generalists. High dispersion in δ 13 C values for canyon consumers suggests that the isotopic composition of particulate organic matter changes, which is linked to depositional dynamics, resulting in discrete zones of organic matter accumulation or resuspension. Heterogeneity in habitat and food availability likely enhances trophic diversity in canyons. Given their abundance in the world's oceans, our results from Baltimore Canyon suggest that submarine canyons may represent important havens for trophic diversity.

Baltimore Canyon↗

USGS1996

Gravity field over the Sea of Galilee: Evidence for a composite basin along a transform fault

The Sea of Galilee (Lake Kinneret) is located at the northern portion of the Kinneret-Bet Shean basin, in the northern Dead Sea transform. Three hundred kilometers of continuous marine gravity data were collected in the lake and integrated with land gravity data to a distance of more than 20 km around the lake. Analyses of the gravity data resulted in a free-air anomaly map, a variable density Bouguer anomaly map, and a horizontal first derivative map of the Bouguer anomaly. These maps, together with gravity models of profiles across the lake and the area south of it, were used to infer the geometry of the basins in this region and the main faults of the transform system. The Sea of Galilee can be divided into two units. The southern half is a pull-apart that extends to the Kinarot Valley, south of the lake, whereas the northern half was formed by rotational opening and transverse normal faults. The deepest part of the basinal area is located well south of the deepest bathymetric depression. This implies that the northeastern part of the lake, where the bathymetry is the deepest, is a young feature that is actively subsiding now. The pull-apart basin is almost symmetrical in the southern part of the lake and in the Kinarot Valley south of the lake. This suggests that the basin here is bounded by strike-slip faults on both sides. The eastern boundary fault extends to the northern part of the lake, while the western fault does not cross the northern part. The main factor controlling the structural complexity of this area is the interaction of the Dead Sea transform with a subperpendicular fault system and rotated blocks.

Sea of Galilee↗

USGS1997

The wind-forced response on a buoyant coastal current: Observations of the western Gulf of Maine plume

The Freshwater plume in the western Gulf of Maine is being studied as part of an interdisciplinary investigation of the physical transport of a toxic alga. A field program was conducted in the springs of 1993 and 1994 to map the spatial and temporal patterns of salinity, currents and algal toxicity. The observations suggest that the plume's cross-shore structure varies markedly as a function of fluctuations in alongshore wind forcing. Consistent with Ekman drift dynamics, upwelling favorable winds spread the plume offshore, at times widening it to over 50 km in offshore extent, while downwelling favorable winds narrow the plume width to as little as 10 km. Using a simple slab model, we find qualitative agreement between the observed variations of plume width and those predicted by Ekman theory for short time scales of integration. Near surface current meters show significant correlations between cross-shore currents and alongshore wind stress, consistent with Ekman theory. Estimates of the terms in the alongshore momentum equation calculated from moored current meter arrays also indicate a dominant Ekman balance within the plume. A significant correlation between alongshore currents and winds suggests that interfacial drag may be important, although inclusion of a Raleigh drag term does not significantly improve the alongshore momentum balance.

Gulf of Maine↗

USGS2011

Geologic map of the eastern half of the Vail 30' x 60' quadrangle, Eagle, Summit, and Grand Counties, Colorado

Recent mapping and geochronologic studies for the eastern half of the Vail 1:100,000-scale quadrangle have significantly improved our understanding of (1) Paleoproterozoic history of the basement rocks of the Gore Range and Williams Fork Mountains (western margin of the Front Range), (2) the Late Paleozoic history of the Gore fault system, (3) Laramide contractional tectonism, including deformation along the Gore fault and Williams Range thrust, (4) Oligocene and younger extensional history of the Blue River half graben (The northern extent of the Rio Grande rift), and (5) late Neogene and Quaternary surficial history. The recently active Gilman mining district, a major producer of zinc and lead, is in the southwestern corner of the map area. Marine sediments and mafic to felsic volcanic rocks deposited between about 1,740 and 1,780 m.y. were generally metamorphosed to amphibolite grade and intruded and deformed by mostly calc-alkalic granitic rocks during an orogenic episode that lasted about 110 m.y. The distribution of well-studied Upper Cambrian to thick Upper Cretaceous platform sediments is now greatly improved, which allows a better definition of the late Paleozoic uplift, erosion, and flanking sedimentation of the ancestral Front Range. Detailed mapping has also better defined the geometry of Late Cretaceous to early Tertiary Laramide deformation along both the Gore fault system and Williams Range thrust, as well as increased understanding of the details of mostly Neogene extension along the Blue River normal fault system (the western margin of the Blue River half graben). Scarps along the latter fault system indicate movement may be as young as Holocene. Detailed mapping of surficial deposits has defined and described (1) six ages of terrace alluvium, (2) three general ages of landslides, (3) glacial and periglacial deposits, and (4) fan, pediment, talus, and debris-flow deposits. The map is intended as a database for a variety of land-use and scientific purposes, including (1) assessment of geologically stable building sites, (2) planning for road and highway construction, (3) assessment of groundwater resources, (4) assessment of mineral resources, (5) determining geologic-hazard potential (flooding, landslide, rockfall, and seismic risk), (6) evaluating the structure of the northern Rio Grande rift in the Blue River valley, (7) improvement in understanding of the sedimentary section, which spans the period from the Cambrian to the Holocene, and (8) new insights into the geologic history of the Proterozoic basement rocks, including a number of new radiometric dates.

Scientific Investigations Map↗

USGS1986

The Munson-Nygren slide: A major lower-slope slide off Georges Bank

The Munson-Nygren slide is a large compound slide located between Munson and Nygren Canyons below 1900 m depth on the Continental Slope off Georges Bank. Its structural and morphological features are recognized in high-resolution seismic-reflection profiles. The slide comprises an axial trough which has a relief as great as 325 m and a width of 6–10 km. The trough is flanked by displaced and disrupted strata for a total lateral extent of approximately 20 km and a downslope extent of at least 35 km. The slide is unrelated genetically to the adjacent canyons and may postdate Munson Canyon. There is evidence of plastic deformation at the base of the section subjected to sliding. Certain features of the slide complex resemble those seen in landforms on the Laurentian Rise and attributed by Emery et al. ∗ to the 1929 Grand Banks earthquake. The Munson-Nygren slide may have been triggered by a large earthquake in late Pleistocene time or later. Destructional landforms associated with the slide are similar to those widely present along the lower slope off Georges Bank.

Georges Bank↗

USGS1999

Subsurface gas offshore of northern California and its link to submarine geomorphology

The northern California continental margin contains evidence of abundant subsurface gas and numerous seafloor features that suggest a causative link between gas expulsion and geomorphology. Analyses of seismic reflection, sidescan sonar, and high-resolution multibeam bathymetric data show that the occurrence of subbottom gas and the migration processes beneath the shelf differ from those beneath the slope. Subsurface gas, inferred from enhanced reflectors and other geophysical indicators, is spatially variable and related more to total depth and stratigraphy than to underlying structure, with the exception of one band of gas that follows the regional structural trend. Shallow depressions on the seafloor (pockmarks) are used to infer expulsion sites. The largest zone of acoustically impenetrable subsurface gas occurs between water depths of 100 m and 300 m, where expulsion features are rare. The upper slope (water depths 400-600 m) has a high concentration of pockmarks (diameter 10-20 m), in contrast to a near-absence of pockmarks at water depths shallower than 400 m. Of nearly 4000 pockmarks observed on sidescan sonar records, more than 95% are located in water depths deeper than 400 m. Bottom simulating reflectors (BSRs) on some seismic reflection profiles indicate the possible presence of gas hydrate. We find that gas and pore-fluid migration in the offshore Eel River Basin is: (1) correlated to surface morphology; (2) a contributor to seabed roughness; (3) a significant mode of sediment redistribution on the upper slope; and (4) potentially a factor in large slope failures.

Marine Geology↗

USGS2016

Sources, distributions and dynamics of dissolved organic matter in the Canada and Makarov Basins

A comprehensive survey of dissolved organic carbon (DOC) and chromophoric dissolved organic matter (CDOM) was conducted in the Canada and Makarov Basins and adjacent seas during 2010–2012 to investigate the dynamics of dissolved organic matter (DOM) in the Arctic Ocean. Sources and distributions of DOM in polar surface waters were very heterogeneous and closely linked to hydrological conditions. Canada Basin surface waters had relatively low DOC concentrations (69 ± 6 μmol L −1 ), CDOM absorption ( a 325 : 0.32 ± 0.07 m −1 ) and CDOM-derived lignin phenols (3 ± 0.4 nmol L −1 ), and high spectral slope values ( S 275–295 : 31.7 ± 2.3 μm −1 ), indicating minor terrigenous inputs and evidence of photochemical alteration in the Beaufort Gyre. By contrast, surface waters of the Makarov Basin had elevated DOC (108 ± 9 μmol L −1 ) and lignin phenol concentrations (15 ± 3 nmol L −1 ), high a 325 values (1.36 ± 0.18 m −1 ), and low S 275–295 values (22.8 ± 0.8 μm −1 ), indicating pronounced Siberian river inputs associated with the Transpolar Drift and minor photochemical alteration. Observations near the Mendeleev Plain suggested limited interactions of the Transpolar Drift with Canada Basin waters, a scenario favoring export of Arctic DOM to the North Atlantic. The influence of sea-ice melt on DOM was region-dependent, resulting in an increase (Beaufort Sea), a decrease (Bering-Chukchi Seas), and negligible change (deep basins) in surface DOC concentrations and a 325 values. Halocline structures differed between basins, but the Canada Basin upper halocline and Makarov Basin halocline were comparable in their average DOC (65–70 μmol L −1 ) and lignin phenol concentrations (3–4 nmol L −1 ) and S 275–295 values (22.9–23.7 μm −1 ). Deep-water DOC concentrations decreased by 6–8 μmol L −1 with increasing depth, water mass age, nutrient concentrations, and apparent oxygen utilization. Maximal estimates of DOC degradation rates (0.036–0.039 μmol L −1 yr −1 ) in the deep Arctic were lower than those in other ocean basins, possibly due to low water temperatures. DOC concentrations in bottom waters (>2500 m; 46 ± 2 μmol L −1 ) of the Canada and Makarov Basins were slightly lower than those reported for deep waters of the Eurasian Basin and Nordic Seas. Elevated a 325 values (by 10–20%) were observed near the seafloor, indicating biological activity in Arctic basin sediments.

Frontiers in Marine Science↗

USGS1970

The structure and origin of the large submarine canyons of the Bering Sea

Three exceptionally large and long submarine canyons — Bering, Pribilof, and Zhemchug — incise the continental slope underlying the southeastern Bering Sea. Bering Canyon, the world's longest known slope valley, is approximately 400 km long and has a volume of 4,300 km 3 . The volume of Pribilof Canyon is 1,300 km 3 and that of Zhemchug is 8,500 km 3 ; Zhemchug Canyon may well be the world's largest slope valley; most other large submarine canyons have volumes less than 500 km 3 . Pribilof and Zhemchug canyons are further distinguished by the headward bifurcation of their slope axes to form elongated trough-shaped basins behind the regionally projected position of the shelf edge. These troughs are superimposed over structural depressions formed by down-faulted basement rocks of Mesozoic and older ages. Prior to canyon cutting these depressions were filled with as much as 2,600 m of shallow-water diatomaceous, tuffaceous, and detrital sediments largely of Tertiary age. Deposition of these sediments took place concurrently with general margin subsidence of at least 2,000 m. The data and conclusions presented in this paper stress that the location, trend, and shape of the enormous submarine canyons cutting the Bering margin are structurally determined. However, axial cutting and headward erosion within the relatively unconsolidated Tertiary strata and the older, lithified basement rock is thought to have been caused by basinward-sliding masses of sediment; these unstable sediment bodies accumulated on the upper continental slope and outer shelf, probably near the mouths of major Alaskan rivers. Bering Canyon was periodically cut and filled by axial sedimentation during Late Tertiary and Quaternary time. Pribilof and Zhemchug canyons, however, are thought to have been excavated entirely during the Pleistocene. It is presumed that, during one or more periods of glacially lowered sea level, the Kuskokwim and Yukon rivers emptied into or near the heads of Pribilof and Zhemchug canyons. The enormous size and unusual shape of Zhemchug Canyon resulted from the breaching of the seaward wall of an outer-shelf basement depression and the subsequent removal of nearly 4,500 km 3 of Tertiary deposits filling it.

Alaska↗

USGS2001

Juxtaposition of Neoproterozoic units along the Baruda - Tulu Dimtu shear-belt in the East African Orogen of western Ethiopia

Amalgamation of East and West Gondwanaland during the Neoproterozoic East African Orogen is recorded by several shear-belts or 'suture zones', some of which are associated with ultramafic and mafic complexes that have been interpreted as ophiolite fragments. The Baruda shear-belt is a major structure of this type that belongs to the N-S trending Barka - Tulu Dimtu zone. The significance of this zone has been studied within a transect in western Ethiopia which covers a variety of metasedimentary and metavolcanic sequences, ultramafic rocks and synkinematic intrusive complexes. All rocks participated in the regional D1 event as reflected in a penetrative steep foliation in supracrustal rocks and marginal parts of the intrusions. Highly strained rocks contain a stretching lineation that plunge to the east. The several-km thick Baruda shear-belt, comprising mylonitic supracrustal and plutonic rocks including mafic-ultramafic mega-lenses, is the most prominent expression of this event. Shear-sense indicators demonstrate top-to-the-west shear. Subsequent D2 deformation is recorded in 2-300 m wide, N-S striking, subvertical shear-zones with subhorizontal stretching lineation relatable to sinistral transcurrent movements. Our data indicate that rock units on either side of the Baruda shear-belt are related, rather than being exotic to each other as implied in suture zone models, since there is no major lithologic or metamorphic difference, geochemical data on metavolcanic rocks and pre-tectonic intrusions suggest a paleotectonic link, and style and extent of deformation is similar across the shear-belt. A tentative model for the transect suggests an arc and back-arc setting which experienced later continental collision and tectonic shortening. The initial setting was that of a shallow marine platform characterised by carbonates and sandstones, which covered extensive areas prior to break-up of a pre-existing supercontinent. Continental convergence is first recorded in high-K calc-alkaline volcanism characterised by pyroclastic deposits of andesitic composition, at an active continental margin at about 800 Ma. Subaerial arc volcanism was temporally and spatially overlapping with limited arc rifting, represented by submarine basalts compositionally transitional between enriched MORB and calc-alkaline magmas, and associated dyke swarms in the older carbonate-sandstone platform sequence. It is suggested that the large, mafic-ultramafic, bodies relate to this event and were originally formed as intrusions along one or more propagating rift axis within the arc complex. The regional Baruda shear-belt formed in response to contractional D1 deformation, and its location may have been largely controlled by competence contrasts between the array of rift-related intrusions and the marble-dominated lithologies. Associated shortening of the arc and back-arc region led to crustal thickening and emplacement of synkinematic, composite, batholiths at about 570-550 Ma. These are composed of moderately peraluminous granite and coeval, intermediate to mafic intrusions of shoshonitic affinity. D2 sinistral movements succeeded the contractional deformation. ?? 2001 Elsevier Science B.V.

Precambrian Research↗

USGS2006

February 2003 marine atmospheric conditions and the bora over the northern Adriatic

A winter oceanographic field experiment provided an opportunity to examine the atmospheric marine conditions over the northern Adriatic. Mean February winds are from a northeasterly direction over most of the Adriatic and a more northerly direction along the western coast. Wind speeds are fastest in jets over the NE coast during bora events and weakest in the mid-northwestern Adriatic. Diurnal air temperature cycles are smallest on the NE coast and largest in the midwestern Adriatic. The maximum sea-air difference is +10??C on the eastern coast and near zero on the midwestern Adriatic. Boras are northeasterly (from) wind events that sweep off Croatia and Slovenia, bringing slightly colder and drier air over the northern Adriatic. The main bora season is December to March. Winter 2002-2003 was normal for bora events. Synoptic-scale temporal variations are correlated over the northern Adriatic. Fastest Bora winds and highest wind stress over the northern Adriatic is concentrated in four topographically controlled jets. The strongest is the Senj Jet, while the Trieste Jet extends across the entire northern Adriatic. Between each two jets is a weak wind zone. The greatest mean net heat loss is in bora jets in the NE Adriatic, where it was -438 W m-2 and is weakest in the midwestern northern Adriatic, where it was near zero. Wind stress is concentrated over the NE half of Adriatic in four bora jets, while wind stress is weak in the NW Adriatic. There is significant variation in wind stress mean and standard deviation structure over the northern Adriatic with each bora event. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research C: Oceans↗

USGS2016

Evaluation of a floating fish guidance structure at a hydrodynamically complex river junction in the Sacramento-San Joaquin River Delta, California, USA

Survival of out-migrating juvenile Chinook salmon ( Oncorhynchus tshawytscha ) in the Sacramento–San Joaquin River delta, California, USA, varies by migration route. Survival of salmonids that enter the interior and southern Delta can be as low as half that of salmonids that remain in the main-stem Sacramento River. Reducing entrainment into the higher-mortality routes, such as Georgiana Slough, should increase overall survival. In spring 2014, a floating fish-guidance structure (FFGS) designed to reduce entrainment into Georgiana Slough was deployed just upstream of the Georgiana Slough divergence. We used acoustic telemetry to evaluate the effect of the FFGS on Chinook entrainment to Georgiana Slough. At intermediate discharge (200–400 m 3 s –1 ), entrainment into Georgiana Slough was five percentage points lower when the FFGS was in the on state (19.1% on; 23.9% off). At higher discharge (>400 m 3 s –1 ), entrainment was higher when the FFGS was in the on state (19.3% on; 9.7% off), and at lower discharge (0–200 m 3 s –1 ) entrainment was lower when the FFGS was in the on state (43.7% on; 47.3% off). We found that discharge, cross-stream fish position, time of day, and proportion of flow remaining in the Sacramento River contributed to the probability of being entrained to Georgiana Slough.

California↗

USGS2011

Evidence and implications of recent and projected climate change in Alaska's forest ecosystems

The structure and function of Alaska's forests have changed significantly in response to a changing climate, including alterations in species composition and climate feedbacks (e.g., carbon, radiation budgets) that have important regional societal consequences and human feedbacks to forest ecosystems. In this paper we present the first comprehensive synthesis of climate-change impacts on all forested ecosystems of Alaska, highlighting changes in the most critical biophysical factors of each region. We developed a conceptual framework describing climate drivers, biophysical factors and types of change to illustrate how the biophysical and social subsystems of Alaskan forests interact and respond directly and indirectly to a changing climate. We then identify the regional and global implications to the climate system and associated socio-economic impacts, as presented in the current literature. Projections of temperature and precipitation suggest wildfire will continue to be the dominant biophysical factor in the Interior-boreal forest, leading to shifts from conifer- to deciduous-dominated forests. Based on existing research, projected increases in temperature in the Southcentral- and Kenai-boreal forests will likely increase the frequency and severity of insect outbreaks and associated wildfires, and increase the probability of establishment by invasive plant species. In the Coastal-temperate forest region snow and ice is regarded as the dominant biophysical factor. With continued warming, hydrologic changes related to more rapidly melting glaciers and rising elevation of the winter snowline will alter discharge in many rivers, which will have important consequences for terrestrial and marine ecosystem productivity. These climate-related changes will affect plant species distribution and wildlife habitat, which have regional societal consequences, and trace-gas emissions and radiation budgets, which are globally important. Our conceptual framework facilitates assessment of current and future consequences of a changing climate, emphasizes regional differences in biophysical factors, and points to linkages that may exist but that currently lack supporting research. The framework also serves as a visual tool for resource managers and policy makers to develop regional and global management strategies and to inform policies related to climate mitigation and adaptation.

Alaska↗

USGS1985

Kinetic and thermodynamic factors controlling the distribution of SO32- and Na+ in calcites and selected aragonites

Significant amounts of SO 4 2− , Na + , and OH − are incorporated in marine biogenic calcites. Biogenic high Mg-calcites average about 1 mole percent SO 4 2− . Aragonites and most biogenic low Mg-calcites contain significant amounts of Na + , but very low concentrations of SO 4 2− . The SO 4 2− content of non-biogenic calcites and aragonites investigated was below 100 ppm. The presence of Na + and SO 4 2− increases the unit cell size of calcites. The solid-solutions show a solubility minimum at about 0.5 mole percent SO 4 2− beyond which the solubility rapidly increases. The solubility product of calcites containing 3 mole percent SO 4 2− is the same as that of aragonite. Na + appears to have very little effect on the solubility product of calcites. The amounts of Na + and SO 4 2− incorporated in calcites vary as a function of the rate of crystal growth. The variation of the distribution coefficient ( D "> D ) of SO 4 2− in calcite at 25.0°C and 0.50 molal NaCl is described by the equation D = k 0 + k 1 R "> D = k 0 + k 1 R where k 0 "> k 0 and k 1 "> k 1 are constants equal to 6.16 × 10 −6 "> 6.16 × 10 −6 and 3.941 × 10 −6 "> 3.941 × 10 −6 , respectively, and R "> R is the rate of crystal growth of calcite in mg·min −1 ·g −1 of seed. The data on Na + are consistent with the hypothesis that a significant amount of Na + occupies interstitial positions in the calcite structure. The distribution of Na + follows a Freundlich isotherm and not the Berthelot-Nernst distribution law. The numerical value of the Na + distribution coefficient in calcite is probably dependent on the number of defects in the calcite structure. The Na + contents of calcites are not very accurate indicators of environmental salinities.

Geochimica et Cosmochimica Acta↗

USGS2016

Observations of pockmark flow structure in Belfast Bay, Maine, Part 2: evidence for cavity flow

Pockmark flow circulation patterns were investigated through current measurements along the rim and center of two pockmarks in Belfast Bay, Maine. Observed time-varying current profiles have a complex vertical and directional structure that rotates significantly with depth and is strongly dependent on the phase of the tide. Observations of the vertical profiles of horizontal velocities in relation to relative geometric parameters of the pockmark are consistent with circulation patterns described qualitatively by cavity flow models (Ashcroft and Zhang 2005 ). The time-mean behavior of the shear layer is typically used to characterize cavity flow, and was estimated using vorticity thickness to quantify the growth rate of the shear layer horizontally across the pockmark. Estimated positive vorticity thickness spreading rates are consistent with cavity flow predictions, and occur at largely different rates between the two pockmarks. Previously modeled flow (Brothers et al. 2011 ) and laboratory measurements (Pau et al. 2014 ) over pockmarks of similar geometry to those examined herein are also qualitatively consistent with cavity flow circulation, suggesting that cavity flow may be a good first-order flow model for pockmarks in general.

Maine↗

USGS1993

Hydrothermal palygorskite and ferromanganese mineralization at a central California margin fracture zone

Ferromanganese oxyhydroxide crusts and nodules associated with palygorskite were recovered from the Santa Lucia Escarpment where the Morro Fracture Zone intersects the central California continental margin. Palygorskite was found in pure, high-Mg, low-Al, boxwork-textured veins, and disseminated in poorly consolidated palygorskite-rich mudstone. The purity of the palygorskite boxwork blades and the boxwork structure suggest formation by direct precipitation rather than by diagenetic or detrital processes. Interaction of hydrothermal fluids with oceanic basalt and/or deeper ultramafic rocks produced a Mg-Si enriched fluid supersaturated with respect to palygorskite that precipitated directly from the fluid at or near the seafloor. The close association of Fe-Mn crusts and nodules with both the palygorskite-rich mudstone and boxwork-vein palygorskite suggests a genetic link between the three types of mineralization. Mixed origin hydrothermal-hydrogenetic Fe-Mn crusts, with up to 50% hydrothermal input, formed contemporaneously with and subsequent to palygorskite formation. Fe-Mn nodules collected in the same dredge are of combined hydrogenetic and diagenetic origin and appear to be unrelated to hydrothermal mineralization that produced the crusts and palygorskite. The thickness of the Fe-Mn crusts and rare diatom fragments within the mudstone suggest an age of formation between 13 and 5 Ma.

Marine Geology↗