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Origin of the high Pd/Pt ratio of the J-M Reef, Stillwater Complex Montana USA

The J-M Reef of the Stillwater Complex exhibits a high and consistent Pd/Pt ratio (~3.8). This ratio results from the equilibration of an immiscible sulfide liquid with a relatively high Pd/Pt silicate melt rather than an unusually Pd- and Pt-enriched parental melt. Numerical modeling suggests that the original silicate melt contained typical mantle-derived concentrations of Pd and Pt (~10–20 ppb Pd/Pt ~1). The partitioning of Pt and Pd between sulfide liquid and silicate melt alone cannot explain the consistently high Pd/Pt ratio across variable melt-to-sulfide mass ratios (R factors). Instead Pt-depletion caused by the early fractionation of Pt-alloy from S-undersaturated silicate magma likely established the high Pd/Pt signature. High Pd/Pt ratios can form through batch equilibration of sulfide liquid with silicate melt if partition coefficients are extremely high (>10⁶). Alternatively Pd enrichment may result from sulfide upgrading within the resident footwall mush under smaller partition coefficients (10⁴–10⁶) in this model the instantaneous R factors remain low (R ≈ 100–700). This limits the impact of Pt and Pd partitioning on sulfide composition and helps explain the Pd-enriched character of the J-M Reef.

Montana

Long-term trends in microseismicity during operational shut-ins at the Coso Geothermal Field, California

Pausing injection and production can lead to induced seismicity in a variety of settings, with some of the largest events occurring during these so-called shut-ins. In geothermal fields, shut-ins are periodically conducted for maintenance on wells and surface infrastructure, thereby offering recurring means of estimating stress changes in the subsurface that lead to increased seismicity rates. Here, we examine daily production and microseismicity data from the Coso Geothermal Field (CGF) in California between 1996 and 2010 to investigate the repetitive trends of operational shut-in microseismicity. Using 24 local seismic stations, we first analyze spatial and temporal trends of over 60,000 earthquakes with magnitudes between -0.4 to 3.8. We find that the northern region exhibits no significant seismicity changes during shut-ins, whereas the rest of the field experiences induced seismicity during almost every shut-in with an increasing intensity towards the southern and eastern portions of the field, highlighting local differences in stress within the CGF. Additionally, we cluster the seismicity using waveform cross-correlation, revealing several earthquake clusters primarily occurring during shut-in periods. These observations suggest that certain fracture and fault sections respond quicker to changes in pore pressure and poroelastic stresses within the geothermal system, possibly highlighting main fluid pathways.

California

Estimation of the accessible and useful resource base for electric-grade enhanced geothermal systems (EGS) resources of the Great Basin, USA

Scientists with the U.S. Geological Survey (USGS) recently completed a provisional assessment of the electric-grade geothermal resources associated with the low-permeability geologic formations of the Great Basin, USA, where resources are assumed to be accessible using enhanced geothermal systems (EGS) technologies (i.e., the engineering of sufficient permeability to facilitate efficient heat extraction). This assessment required estimation of the accessible resource base (electric-grade heat [>90ºC] at depths where drilling and stimulation are deemed achievable using current technology) and useful resource (heat that can be extracted from the accessible region). Electric-grade heat can be estimated from existing temperature models. The accessible resource base can be estimated as the electric-grade heat that exists at depths shallower than 6 km based on the limitations of current drilling and stimulation technologies, along with evidence for sustained natural fracture conductivity at depth. The useful part of the accessible heat can be estimated as the product of three efficiencies and factors: the heat extraction efficiency, the viable geology factor, and the reservoir spacing efficiency. The accessible and useful parts of the resource can be estimated in units of heat, or in units of electric power using an electrical conversion efficiency, which is a function of resource temperature. We also estimate the ranges for each of the efficiencies and describe the motivations behind the choice of best estimates used for the recent assessment. An analytic solution is provided for the useful resource above any depth (in units of electric power), where efficiency estimation assumes nearly steady heat extraction rates that cool reservoirs to 90ºC over 30 years of power generation.

Great Basin

Cnidarian–algal partnerships structure bacterial communities during strobilation in Cassiopea xamachana

Cnidarian–algal (Symbiodiniaceae) symbioses rely on complex interactions among the cnidarian host, algal symbionts, and associated bacterial communities. In the upside-down jellyfish Cassiopea xamachana , the polyp-to-medusa transition (strobilation) requires the establishment of symbiosis with Symbiodiniaceae algal partners, yet bacterial community dynamics during this developmental process remain unknown. Here, we experimentally induced symbiosis in aposymbiotic polyps using four algal treatments: xenic Symbiodinium microadriaticum (native symbiont), xenic Breviolum minutum , antibiotic-treated B. minutum , and a photosynthetically impaired B. minutum mutant. We combined 16S rRNA gene sequencing with measurements of photosynthetic efficiency, asexual budding, and algal surface N-glycan profiles to characterize holobiont assembly during symbiosis onset and strobilation. Algal treatment structured bacterial communities in both algal cultures and polyp tissues. Our analyses identified a set of amplicon sequence variants that consistently distinguished strobilating polyps from non-strobilating aposymbiotic and mutant polyps, in addition to potential bacterial biomarkers associated with successful metamorphosis. Strobilation was associated with the enrichment of bacterial communities putatively involved in sulfur and nitrogen cycling, whereas non-strobilating aposymbiotic and mutant polyps were characterized by opportunistic bacteria and increased community variability. Together, these results reveal coordinated changes in algal physiology, surface glycan profiles, and bacterial community structure associated with successful strobilation in C. xamachana and support a model in which tripartite host–alga–bacteria interactions influence cnidarian life stage transitions.

ISME Communications

Using visualization science to inform the design of environmental decision-support tools—A case study of the U.S. Geological Survey Waterwatch

Environmental decision-support tools are increasingly being used to serve both expert and non-expert audiences. Many existing tools are primarily expert-focused, and redesigning them can be challenging because experts and non-experts interact with tools differently, existing users may be resistant to changes, and there is little guidance on how to prioritize redesign efforts and demonstrate their efficacy. In this report, we present a case study of a user-centered redesign of an established environmental decision-support tool—the U.S. Geological Survey WaterWatch. WaterWatch supports flood, drought, and other water resource management decisions through the display of water levels at gages across the United States. Using a participatory process, we identified a functional change (replacing the existing rainbow colormap), created an alternative design, and tested the alternative’s usability through two general public surveys. The results showed that replacing the rainbow colormap with a more intuitive diverging colormap improves usability, regardless of the audience’s subjective preference for the rainbow color scheme. In addition, we demonstrated the importance of using legends to improve the audience’s understanding of the map symbols. This study demonstrates how user-centered design approaches can be used to inform the design of high-profile products and tools.

Scientific Investigations Report

Archean to Mesozoic–Cenozoic seismic crustal structure: Implications for geological and biological evolution

We use >4500 measurements of crustal structure to investigate the seismic structure of continental crust, Archean to Mesozoic–Cenozoic. The mean crustal thickness of continents, including their margins, is 36.5 km. We find that Archean, Paleoproterozoic, and Mesoproterozoic crust have similar mean crustal thickness (41 km), seismic velocities, Vp/Vs ratio, and density. Crusts of these ages span 3 Ga, from 4.0 to 1.0 Ga, and their similarity of physical properties (thickness, density, and seismic velocities) suggests that the process of crustal formation may have been similar during this time period, which covers 66% of Earth's history. Neoproterozoic crustal properties differ significantly from Mesoproterozoic and older crusts. The mean thickness of Neoproterozoic crust is 32 km, some 9 km thinner than the mean thickness of Archean, Paleoproterozoic, and Mesoproterozoic crust. A lithospheric root with a thickness of 150–200 km underlies Archean, Paleoproterozoic, and Mesoproterozoic crusts, and this root resists lithospheric rifting and crustal extension and thinning. Based on these observations, particularly the lithospheric thickness, we conclude that Archean, Paleoproterozoic, and Mesoproterozoic lithosphere are unique and together form the stable cratonic nuclei, defined as the thick (150–250 km), long-lived cores of continents. Higher mantle temperatures during the Archean, Paleoproterozoic, and Mesoproterozoic may have played a key role in the formation of the thick lithospheric roots. The second key finding is that the similarities of mean seismic properties indicate that the process of crustal formation operating in the Archean continued during the Paleoproterozoic and Mesoproterozoic. The thin (mean value < 135 km) lithospheric root beneath Neoproterozoic and younger crust may be related to the steady decrease in mantle temperature through time. Neoproterozoic and Paleozoic crust have similar physical properties, and these eras are characterized by pronounced biodiversification, including the renowned Garden of Ediacara, the Cambrian Explosion, and the Great Ordovician Biodiversification. Mesozoic–Cenozoic crust is the most diverse and reflects the current tectonic and magmatic processes of crustal formation.

Book chapter

Detrital zircons and the magmatic history of Viti Levu, Fiji

We integrate the existing detrital zircon data from multiple modern river sediment samples on Viti Levu, Fiji, with the most current available geological and topographic mapping of the respective river drainage basins to compare detrital populations with potential bedrock sources. The temporal and spatial variations in zircon geochemistry supplement what is known from igneous rocks and confirm the petrological differences between plutonic and volcanic rocks from the Eocene to early Oligocene (Yavuna age, >30 Ma), middle Oligocene to middle Miocene (Wainimala age, 30–12.5 Ma), late Miocene (Colo age, 12.5–6.5 Ma) and latest Miocene (Namosi age, 6.5–5 Ma). The >30 Ma Yavuna-age zircons are restricted to areas that drain the previously mapped Yavuna Group. The 30–12.5 Ma zircons are found across central Viti Levu from west to east, and the 30–15 Ma zircons have distinctively low U/Yb and high Dy/Yb ratios. They are the best radiometric evidence of widespread early to middle Miocene arc magmatism in Fiji that was relatively U-poor. Peak deconvolution of the Colo age zircons from individual basins suggests the following ages for undated or poorly dated plutons from central Viti Levu. The large Mavuvu pluton is probably composed of multiple intrusions in the 12–10 Ma range, the Waiqa pluton is probably ca 10 Ma, and the Noikoro pluton is probably ca 9 Ma. There are zircons from unknown plutonic or volcanic sources between 8 and 7 Ma in western Viti Levu that have distinct Eu/Eu* ratios. We attribute the highest U/Yb ratios in some Colo age zircons to crustal anatexis. Namosi-age zircons are abundant in the Medrausucu Group and can be found scattered across Viti Levu.

Viti Levu

As above, so below? A framework for integrating long-term water quantity trends reveals divergent patterns in groundwater and low streamflow across the United States

Climate, land-use, and disturbance drive long-term global trends in groundwater levels and streamflow. At large scales, these trends are typically considered separately, despite the well-established concept that groundwater and surface water comprise a single resource. Joint trend assessment at national scales is challenging because it requires pairing and aggregating data from spatially disparate streamflow and groundwater monitoring sites for which no established framework exists. Here, we evaluate alternative approaches for integrating groundwater and streamflow data to enable joint trend analysis—a critical step toward understanding how water-budget components respond concurrently and interactively to environmental drivers. Mann–Kendall trends were computed for individual groundwater (annual mean depth) and streamflow (annual low of 7 d averages) sites across the U.S over 21- (2000–2020), 31- (1990–2020), and 41-year (1980–2020) periods. Regional Kendall trends were calculated using five spatially contiguous and noncontiguous regional classifications for aggregation based on subsurface (e.g. aquifer, geology) and surface (e.g. watershed, landscape) characteristics. Site-level results revealed contrasting trends, with tendencies toward increasing low flows (wetting) and increasing groundwater depths (drying). Agreement between streamflow and groundwater trends increased with regional aggregation and longer timeframes, though persistent skew toward streamflow wetting and groundwater drying remained. Results varied by region and trend period, with notable consistencies: unified drying in the West/Southwest and wetting in the Upper Midwest. Directional mismatches in long-term trends were prominent in the High Plains and Mississippi Alluvial Plain, whereas near-term mismatches were most evident in the Northwest. Aggregation by hydrologic landscape regions (HLR) yielded the greatest agreement between groundwater and streamflow trends. These findings indicate that coupled responses may represent combined influences of climate, relief, and geology, as captured by HLR, more strongly than geography or geology alone. Integrated water availability assessments may benefit from a multi-characteristic classification framework to treat groundwater and surface water as a unified resource.

Environmental Research: Water

Field evidence and indicators of rockfall fragmentation and implications for mobility

Rockfall fragmentation can play an important role in hazard studies and the design of protective measures. However, the current lack of modeling tools that incorporate rock fragmentation mechanics is a limitation to enhancing studies and design. This research investigates the fragmentation patterns of rockfalls and analyzes the resulting distribution of fragment sizes within corresponding rockfall deposits. We focus on small rock fragments, which provide insights into the dynamics of the rockfall event and can be used as input for numerical modeling. We analyzed multiple rockfall events from locations worldwide, each exhibiting different degrees of fragmentation. Using image analysis techniques, we mapped all visible blocks, determined their volumes, and measured the distances they travelled from the initial point of impact. A key finding is the identification of three indicators of fragmentation. First, in cases where fragmentation was largely absent, we observed a trend of increasing block size with distance from the impact point or source area, which aligns with previously published findings. However, for energetic rockfall events characterized by intense fragmentation, we observed that small fragments exhibited longer travel distances compared to larger fragments. This distinction allowed us to differentiate blocks primarily resulting from the disaggregation process from those primarily resulting from dynamic fragmentation, with implications for rockfall mobility. Second, although the size distribution of rockfall deposits exhibits a power-law scaling for volumes larger than a minimum size threshold corresponding to a rollover of the distribution, in some case studies a deviation from power-law scaling is observed, indicating a process of larger block comminution due to fragmentation. Third, we found that rockfalls with fragmentation experience reduced mobility, indicated by higher reach angles, and higher lateral dispersion showing a wider distribution of trajectories. We interpret these findings as being directly related to the energy-consuming nature of fragmentation, which prevents farther deposition of fragmented rock blocks.

Albacete province, Lombardy and Aosta Valley, Yose

Hydrogeologic framework and conceptual groundwater-flow model of the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, 1998–2022

This study was conducted by the U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, to update the hydrogeologic framework and conceptual flow model for the panhandle and northwest parts of the High Plains (Ogallala) aquifer in Oklahoma, which together compose the Ogallala aquifer focus area. The study included the construction of a potentiometric surface, and available geologic and hydrologic data were used to evaluate saturated thickness of the aquifer. The water budget for the updated conceptual groundwater-​flow model was based on estimated inflows and outflows for the 1998–2022 study period. Saturated thickness of the Ogallala aquifer averaged 127 and 116 feet for the panhandle and northwest parts, respectively. Groundwater withdrawals from the Ogallala aquifer for 1998–2022 averaged 422,054 and 39,645 acre-feet per year (acre-ft/yr) for the panhandle and northwest parts, respectively. Recharge, the primary inflow, was estimated at 0.63 inch per year for the 1998–2022 study period, with the panhandle part of the Ogallala aquifer receiving 175,068 acre-ft/yr and the northwest part of the Ogallala aquifer receiving 49,376 acre-ft/yr. Additional inflows included irrigation return flows, estimated at 8,111 and 642 acre-ft/yr for the panhandle and northwest parts, respectively, of the Ogallala aquifer. Net lateral groundwater flows, considered to be aquifer outflows, were estimated to account for 31,908 acre-ft/yr for the Ogallala aquifer focus area. Streambed seepage, which was an outflow of 5,535 acre-ft/yr, was only present in the northwest part of the Ogallala aquifer. Vertical leakage and saturated-zone evapotranspiration were considered negligible outflows. These findings provide a revised conceptual groundwater-flow model water budget for the Ogallala aquifer focus area in Oklahoma.

Colorado, Kansas, Oklahoma, Texas

Climate-driven sulfate export in alpine watersheds may stimulate methylmercury production

Climate change is increasing sulfate export and changing wetland extent in mountain regions. These changes may increase microbially mediated production of the neurotoxic substance methylmercury due to enhanced sulfate metabolism in mountain environments. Here, we assess methylmercury concentrations and formation rates across high-elevation wetlands in the Colorado Rocky Mountains. We also investigate sulfate controls on methylmercury production within subalpine peatlands by amending soils with sulfate to mimic increased stream export of sulfate from the alpine zone and measuring methylmercury formation rates for different sulfate treatments. We found that subalpine peatlands have statistically significant higher methylmercury concentrations and formation rates compared to alpine, mineral-soil wetlands. Methylmercury production in subalpine peatlands also increased significantly ( p < 0.05) following sulfate additions; the highest rates occurred in sediments with intermediate extractable sulfate concentrations (∼0.60–1.4 mg sulfate g −1 dry soil). Our study is the first to identify soil sulfate-related thresholds for methylmercury production and sulfate-limitation of methylmercury production in subalpine peatlands. These findings highlight important linkages between climate-driven mineral weathering and mercury cycling in mountain regions globally.

Colorado

A great tsunami earthquake component of the 1957 Aleutian Islands earthquake

The great 1957 Aleutian Islands earthquake ruptured ∼1200 km of the plate boundary along the Aleutian subduction zone and produced a destructive tsunami across Hawaiʻi. Early seismic and tsunami analyses indicated that large megathrust fault slip was concentrated in the western Aleutian Islands, but tsunami waves generated by slip in the west cannot explain the large observed runup in Hawaiʻi far to the southeast. Recently mapped 1957 geologic deposits on eastern Aleutian Islands suggest occurrence of very large nearby slip. Jointly modeling tsunami runup along the eastern Aleutian and Hawaiian Islands together with tide gauge recordings across the Pacific resolves 12-26 m shallow slip along 600 km of the eastern Aleutian Islands in addition to modest, deeper western slip inferred from seismic records. The eastern near-trench slip results in an M W 8.3-8.6 tsunami earthquake component of the M W 8.6-8.8 rupture, comparable in size to the adjacent 1946 Aleutian tsunami earthquake to the east. The reexamination of the 1957 rupture confirms the tsunami hazards posed by the eastern Aleutian subduction zone to Hawaiʻi and lays the groundwork for investigation of large prehistoric earthquakes through modeling tsunami runup inferred from stratigraphic observations to constrain their rupture processes.

Alaska

Upper Triassic igneous rocks of the southern Kenai Peninsula, Alaska – Prelude to Early Jurassic subduction along the western Wrangellia composite terrane margin

New U–Pb zircon geochronology identifies a latest Triassic (ca 214–201 Ma) igneous suite of tuff, hypabyssal dikes, and a pluton on the southern Kenai Peninsula, Alaska. The igneous suite was emplaced within Upper Triassic sedimentary rocks along the southern margin of Western Wrangellia, the western-most fragment of the Wrangellia composite terrane. The igneous rocks range from mafic (50.6% SiO 2 ) to felsic (78.3% SiO 2 ), characteristically have less than 1.55% K 2 O, and generally have low trace element abundances. The tonalitic and trondhjemitic magmas were largely sourced in mafic-rich lower crust and incompletely assimilated quartz and other mineral xenocrysts are common. Fractionation involving plagioclase and amphibole is indicated for some magmas and composite intrusions and igneous xenoliths indicate magma mixing was possible. Paleozoic and Precambrian inherited zircons and initial 87 Sr/ 86 Sr (0.704103–0.705609) and 143 Nd/ 144 Nd (0.512396–0.512777) ratios indicate that the Western Wrangellia crustal sources are heterogeneous and contain sialic components. The latest Triassic magmatism reflects processes that preceded Early Jurassic subduction along the Wrangellia composite terrane and Pacific Ocean plate boundary. These processes involved heating and melting of mantle lithosphere and lower crust as mantle instabilities accompanied the breaking of the plate boundary linkages. The Late Triassic transition to subduction along the Wrangellia composite terrane margin coincided with the transition to subduction cessation in the Late Triassic arcs of the western Intermontane terranes of Canada. The shift to subduction along the outboard Wrangellia composite terrane margin marks the beginning of the Pacific Ocean–Cordillera plate interactions that came to dominate the tectonic evolution of the northern Cordillera from the Early Jurassic to today.

Alaska

Altitude of the potentiometric surface and depth to water in the Mississippi River Valley alluvial aquifer, spring 2024

Potentiometric-surface and depth-to-water maps for spring 2024 were created for the Mississippi River Valley alluvial aquifer using groundwater-altitude data from 1,151 wells completed in the Mississippi River Valley alluvial aquifer and from the altitude of the top of the water surface in area rivers from 160 U.S. Geological Survey and U.S. Army Corps of Engineers streamgages. The potentiometric-surface and depth-to-water maps for 2024 were created to support investigations to characterize the Mississippi River Valley alluvial aquifer as part of the U.S. Geological Survey Water Availability and Use Science Program. Sufficient data were available to map the potentiometric surface and depth to water of the Mississippi River Valley alluvial aquifer for spring 2024 for about 83 percent of the aquifer area. The potentiometric contours ranged from 0 to 330 feet (ft) above the North American Vertical Datum of 1988. The regional direction of the groundwater gradient was generally to the south-southwest, except in areas of groundwater-altitude depressions, where the groundwater gradient direction was into the depression, and near rivers, where the groundwater gradient direction was either from the aquifer to the river or from the river into the aquifer. Groundwater depressions in the potentiometric-surface map are in the lower one-half of the Cache region and in most of the Grand Prairie and Delta regions. Depth to water by well in the Mississippi River Valley alluvial aquifer in spring 2024 ranged from 0.27 ft above land surface to 145.65 ft below land surface.

Arkansas, Illinois, Kentucky, Louisiana, Mississip

Fish beta diversity associated with hydrologic and anthropogenic disturbance gradients in contrasting stream flow regimes

Understanding the role of hydrologic variation in structuring aquatic communities is crucial for successful conservation and sustainable management of native freshwater biodiversity. Partitioning beta diversity into the additive components of spatial turnover and nestedness can provide insight into the forces driving variability in fish assemblages across stream flow regimes. We examined stream fish beta diversity across hydrologic and anthropogenic disturbance gradients using long-term (1916–2016) site occurrence records ( n = 17,375) encompassing 252 species. We assessed total beta diversity (Sørensen dissimilarity), spatial turnover, and nestedness of fish assemblages in contrasting stream flow regimes across a gradient of decreasing flow stability: groundwater stable ( n = 77), groundwater ( n = 67), groundwater flashy ( n = 175), perennial runoff ( n = 141), runoff flashy ( n = 255), and intermittent ( n = 63) streams. Differences in total beta diversity among the stream flow regimes were driven predominantly (>86 %) by spatial turnover (i.e. species replacement) as opposed to nestedness (i.e. species loss or gain). Total fish beta diversity and spatial turnover were highest in streams with intermediate flow stability (groundwater flashy), while more flow-stable streams (groundwater stable and groundwater) had lower turnover and higher nestedness. Species turnover was also strongly associated with seasonal variation in hydrology across all flow regimes, but these relationships were most evident for assemblages in intermittent streams. Distance-based statistical comparisons showed significant correlations between beta diversity and anthropogenic disturbance variables, including dam density, dam storage volume and water withdrawals in catchments of groundwater stable streams, while hydrologic variables were more strongly correlated with beta diversity in streams with runoff-dominated and flashy flow regimes. The high spatial turnover of species implies that fish conservation actions would benefit from watershed-focused approaches targeting multiple streams with wide spatial distribution, as opposed to simply focusing on preserving sites with the greatest number of species.

Science of the Total Envionrment

Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems

Beyond optimality: Dryland ecosystems infrequently use water efficiently for carbon gain

Optimality theory assumes plants maximize carbon gain per unit water lost and is often implemented to scale leaf-level carbon gain and water use to regional and global scales. Optimality theory is often mathematically represented by assuming plant water-use efficiency (WUE) scales with VPD k , where k = ½ represents expected optimal behavior. It is unclear, however, if this relationship holds in arid and semi-arid ecosystems that are strongly impacted by soil and atmospheric moisture status. We used data from seven flux tower sites along an aridity gradient in New Mexico to answer: how does the relationship between WUE and VPD compare to expectations based on optimality theory? To address this question, we integrated the Dynamic Evapotranspiration Partitioning Approach for Rapid Timescales with a stochastic antecedent model to estimate ecosystem-level WUE (GPP/T) and the net sensitivity of WUE to VPD, or k Dynamic , which we compare to the theoretical optimal sensitivity of k = ½. Our results show that optimality theory is not always appropriate, and k Dynamic often deviates from ½, especially at some of the more arid sites or during periods of low soil moisture. At less arid, higher elevation sites, k Dynamic is most consistent with optimality theory at moderate VPD levels, but not at high VPD. In general, the sensitivity of WUE to VPD is highly variable such that k Dynamic exhibits notable daily and seasonal variability, suggesting highly dynamic stomatal behavior. These results emphasize that representing plant water-use strategies as dynamic in time and space is critical to improving large-scale estimates of plant water use.

New Mexico

Deformation by pressure solution and grain boundary sliding in a retrograde shear zone in southern New England, USA

Alleghanian phyllonites in a shear zone in southern New England were formed by the retrogression and hydration of a high-grade Acadian pelitic schist. The retrogression was locally incomplete, resulting in both heterogeneous mineralogy and mineral compositions, and in many arrested reaction textures. These features, documented by backscattered electron and element map imaging, and by 40 Ar/ 39 Ar dating, provide a record of the processes active as the schist was converted to a phyllonite. On the margins of the shear zone relic biotite and garnet grains survive but are partially replaced by chlorite. Relic high-grade muscovite flakes containing up to 35 % paragonite (pg) also persist but are entrained in swarms of pg-poor muscovite flakes producing folia with an anastomosing network of muscovite grains of variable composition. Single crystals of pg-rich muscovite are truncated by muscovite in successively younger cross-cutting folia that contain decreasing pg contents, falling to <5% pg in the youngest folia. In the core of the shear zone all high-grade minerals are destroyed, but recrystallization continues with earlier greenschist facies folia replaced by lower grade and pg-poorer muscovite in younger folia. Muscovite grains in truncated folia are commonly kinked and selective recrystallization of muscovite in kink bands to pg-poor-compositions demonstrates that strain energy helped drive recrystallization. The boundaries of these new pg-poor muscovite folia are sharp, and truncations indicate that grain boundary sliding (GBS) involved dissolution. GBS also enabled folding by flexural slip along muscovite grain boundaries. Fold amplitudes increased as chlorite dissolved from fold limbs precipitated in fold hinges producing crescent-shaped saddle-reef-like structures. Together these observations of truncation and replacement by dissolution and precipitation demonstrate that pressure solution and GBS facilitated both the formation of the phyllonitic shear zone and slip along it.

Connecticut