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Determination of per- and polyfluoroalkyl substances in water by direct injection of matrix-modified centrifuge supernatant and liquid chromatography/tandem mass spectrometry with isotope dilution

A direct-injection liquid chromatography/tandem mass spectrometry method was developed to determine 34 per- and polyfluoroalkyl substances (PFAS), including selected branched isomers, in centrifuge supernatant of matrix-modified (amended with approximately 50 percent methanol) water samples. The method has been validated in reagent water, surface water, groundwater, and wastewater effluent. Other water types (for example, drinking water, untreated wastewater, and landfill leachate) have been analyzed by the method but not systematically validated. Recovery of isotope-dilution standards, added to each sample, may be used to assess method performance in nonvalidated matrices on a sample-by-sample basis. Using this method, PFAS concentrations were determined in the range of 2–2,000 nanograms per liter in water samples. This range can be extended by diluting concentrated samples. At circumneutral pH, most compounds are present in the environment in their ionized form, and data are reported as such (for example, perfluorooctanoic acid is referred to as “perfluorooctanoate” [PFOA], perfluorooctane sulfonic acid is referred to as “perfluorooctane sulfonate” [PFOS]). Sample preparation procedures were designed without the use of filtration and with minimum sample handling steps to mitigate procedural losses of target compounds due to sorption to surfaces. Further, isotope-dilution quantification allowed for the correction of bias that may result from procedural losses, matrix-induced signal suppression or enhancement, and other factors. Validation experiments to characterize bias and variability, method detection level, and holding time were done in four distinct water matrices—reagent water, surface water, treated wastewater effluent, and groundwater—at multiple concentration levels. Mean PFAS recoveries met data quality objectives of bias and variability studies in all four validation matrices except for two compounds with low and variable recovery in the reagent water matrix only. Isotope-dilution standards, treated as surrogate compounds, were analyzed in more than 1,500 customer-submitted environmental samples with aggregate recovery of 102.5±6.5 percent (mean±standard deviation). Maximum holding times for all target compounds in the four validation matrices were 28 days for refrigerated samples and 90 days for frozen samples.

Techniques and Methods

Impact of land subsidence on housing sale values: Evidence from the San Joaquin Valley, California

This study assesses the impact of land subsidence on housing sale values in the San Joaquin Valley, California. The study utilizes home sale transactions and vertical land-surface displacement data from Interferometric Synthetic Aperture Radar techniques. Using fine-scale fixed effects, matching, as well as a repeat-sales approach, our results indicate that land subsidence resulted in a 2.4% to 5.8% reduction in housing sale values, with the largest reductions occurring in areas where substantial subsidence occurred. Such findings may have implications for groundwater management and can potentially help inform policy design to help mitigate the causes and impacts of land subsidence.

California

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 5 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 5, the subject of this scientific investigations map, has an area of 211 km 2 and has water depths that range from 23 meters (m) on the Stellwagen Bank crest to 105 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates on the crest and western flank of the south-central part of Stellwagen Bank and in Stellwagen Basin to the west. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 729 stations were analyzed, including 620 sediment samples. The geologic substrate maps of quadrangle 5 show the distribution of 20 substrates that represent a wide range of textures, such as mobile and rippled sand, immobile sand, sand that partially veneers gravel, boulder ridges, and mud. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 5. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and to support seabed management in the region.

Massachusetts

Use of a numerical groundwater-flow model and projected climate scenarios to simulate the effects of future climate conditions on base flow for reach 1 of the Washita River alluvial aquifer and Foss Reservoir storage, western Oklahoma

To better understand the relation between climate variability and future groundwater resources in reach 1 of the Washita River alluvial aquifer and Foss Reservoir in western Oklahoma, the U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used a previously published numerical groundwater-flow model and climate-model data to investigate changes in base flow and reservoir storage by evaluating three scenarios. The three projected climate scenarios were (1) a central-tendency scenario, (2) a warmer/drier scenario, and (3) a less-warm/wetter scenario. To estimate future base flow and groundwater availability in western Oklahoma, specifically in reach 1 of the Washita River alluvial aquifer, downscaled climate-model data from 231 Coupled Model Intercomparison Project phase 5 (CMIP5) projections coupled with a previously published numerical groundwater-flow model were used to compare the effects of different climate scenarios on the aquifer. Changes in base flow and groundwater-level elevations during a 30-year baseline scenario (1985–2014) and the three 30-year projected climate scenarios (2050–79) under central-tendency, warmer/drier, and less-warm/wetter climatic conditions were assessed by using the calibrated model. In the simulations, the amount of base flow and reservoir storage declined in the central-tendency and warmer/drier scenarios compared to the amount of base flow and reservoir storage under historical climatic conditions (baseline scenario). Mean annual change in reservoir storage decreased from the baseline scenario the most in the warmer/drier scenario, followed by the central-tendency scenario, but increased in the less-warm/wetter scenario compared to the baseline scenario. At the end of the simulation period (2079), the largest magnitude differences in groundwater-level elevations in all three projected climate scenarios relative to the baseline scenario occurred upstream from Foss Reservoir. Results from incorporating downscaled climate projections into localized numerical groundwater-flow models can highlight potential future changes in and implications for groundwater resources and availability.

Oklahoma

The U.S. Geological Survey, the U.S. Department of Defense, and the U.S. Intelligence Community—100 years of mapping and remote sensing collaboration, 1879–1979

Introduction The U.S. Geological Survey (USGS)—a Federal civilian agency—and U.S. military and intelligence agencies collaborate on mapping and remote sensing and have since the establishment of the USGS. The organizations exchange data and information and share technology to further their respective missions in service to the American people. Often referred to as examples of “good government” or “whole of government,” the collaboration avoids costly duplication and maximizes time and effort for the government sectors. Collaboration between these sectors started with the original mapping of the United States and evolved to include remote sensing after the advent of aerial photography and satellite imagery.

Circular

Early Miocene volcanic rocks and associated tectonics, Lava Hills and southern Bristol Mountains, California

Volcanic rocks of latest Oligocene to early Miocene age form an east-west belt across part of the central eastern Mojave Desert from the Whipple Mountains on the east to the Rosamond Hills on the west. We term this the central belt because it is separated from northern and southern belts by swaths with no volcanic rocks. Limited geochronologic data indicate that much of the belt is latest Oligocene and early Miocene in age, about 24 to 19 Ma, a finding that is consistent with these rocks being overlain by the 18.8 Ma Peach Spring Tuff in many places. We describe Miocene geology in a central area of the belt, in the Lava Hills, southern Bristol Mountains, and southern Old Dad Mountains. Sedimentary basins formed coeval with early andesite to rhyolite volcanism, progressing from fluvial and lacustrine tuffaceous sandstone to volcanic lavas, tuffs, and breccias, indicating that early basins formed proximal to volcanic edifices. Higher strata are fluvial and lacustrine with lavas punctuating the sequence. Although basins may partly have been formed within topographic lows bounded by volcanic domes, plateaus, and stratovolcanoes, consistent stratigraphic sections over wide areas indicate that tectonic basin evolution affected broad areas. The volcanic section is capped by local basalt flows and the regional Peach Spring Tuff. Limited data on normal faults support interpretations of early extensional basin development caused by northeast-southwest oriented stretching. Later extension caused stratal rotations, tilting early deposits down to the southwest. This tilted and subsequently beveled basin architecture was overlain by the youngest volcanic deposits, primarily rhyolite and basalt. The Peach Spring Tuff, 18.8 Ma, lies within this upper unit. Similar stratigraphic and structural relations are exposed in the nearby Marble Mountains and Van Winkle Mountain sections, reinforcing that a broad area underwent similar volcanism and tectonism. In our study area the upper unit is only very gently tilted except near dextral strike-slip faults of the eastern California shear zone. These late Miocene to Recent faults are represented as four main fault zones spaced about 5 km apart, representing distributed shear north of the Bristol Lake basin.

California

Biodegradation of chlorinated ethenes at a karst site in middle Tennessee

This report presents results of field and laboratory investigations examining the biodegradation of chlorinated ethenes in a karst aquifer contaminated with trichloroethylene (TCE). The study site, located in Middle Tennessee, was selected because of the presence of TCE degradation byproducts in the karst aquifer and available site hydrologic and chlorinated-ethene information. Additional chemical, biological, and hydrologic data were gathered to evaluate whether the occurrence of TCE degradation byproducts in the karst aquifer was the result of biodegradation within the aquifer or simply transport into the aquifer. Geochemical analysis established that sulfate-reducing conditions, essential for reductive dechlorination of chlorinated solvents, existed in parts of the contaminated karst aquifer. Other areas of the aquifer fluctuated between anaerobic and aerobic conditions and contained compounds associated with cometabolism, such as ethane, methane, ammonia, and dissolved oxygen. A large, diverse bacteria population inhabits the contaminated aquifer. Bacteria known to biodegrade TCE and other chlorinated solvents, such as sulfate-reducers, methanotrophs, and ammonia-oxidizers, were identified from karst-aquifer water using the RNA-hybridization technique. Results from microcosms using raw karst-aquifer water found that aerobic cometabolism and anaerobic reductive-dechlorination degradation processes were possible when appropriate conditions were established in the microcosms. These chemical and biological results provide circumstantial evidence that several biodegradation processes are active in the aquifer. Additional site hydrologic information was developed to determine if appropriate conditions persist long enough in the karst aquifer for these biodegradation processes to be significant. Continuous monitoring devices placed in four wells during the spring of 1998 indicated that pH, specific conductance, dissolved oxygen, and oxidation-reduction potentials changed very little in areas isolated from active ground-water flow paths. These stable areas in the karst aquifer had geochemical conditions and bacteria conducive to reductive dechlorination of chlorinated ethenes. Other areas of the karst aquifer were associated with active ground-water flow paths and fluctuated between anaerobic and aerobic conditions in response to rain events. Associated with this dynamic environment were bacteria and geochemical conditions conducive to cometabolism. In summary, multiple lines of evidence developed from chemical, biological, and hydrologic data demonstrate that a variety of biodegradation processes are active in this karst aquifer.

Tennessee

Ground-motion characterization for the 2025 U.S. National Seismic Hazard Model for Puerto Rico and the U.S. Virgin Islands

We develop the ground-motion characterization (GMC) for the 2025 U.S. National Seismic Hazard Model for Puerto Rico and the U.S. Virgin Islands (NSHM-PRVI) for earthquakes in active crustal, subduction interface, and subduction intraslab regimes. Using ground-motion models (GMMs) from the Next-Generation Attenuation (NGA)-West2 and NGA-Subduction projects, the GMC is parameterized by scaled-backbone models for median ground motions and by independent logic trees of aleatory variability. We introduce several novel GMC features into the U.S. NSHM: (1) use of regional ground-motion data for modeling median ground motions; (2) development of scaled-backbone models for median ground motions; and (3) development of independent logic trees of aleatory variability from variance components of GMMs and computed from multiple ground-motion datasets, and incorporating regional ground-motion data effects on variability. We compute probabilistic seismic hazard curves and maps to evaluate the contributions from the GMC components and for comparison with the 2003 GMC. Contributions of the GMC to epistemic uncertainty in seismic hazard are evaluated through spatial variations in epistemic uncertainty in hazard maps, comparisons between mean hazard curves and fractiles, as well as investigations of the contributions of logic-tree branches to hazard maps and curves. Comparisons between seismic hazard from the 2025 and 2003 GMCs allow examination of the changes in hazard curves and mapped values with 2% and 10% probabilities of exceedance in 50 years. The 2025 GMC exhibits modest changes in median predictions, relative to the 2003 GMC; overall, values of aleatory variability are higher, except at long periods ( ), resulting in changes to probabilistic ground motions at low probabilities of exceedance (<10% probability of exceedance in 50 years). Changes in hazard at 2% and 10% probabilities of exceedance in 50 years are also relatively modest (within 20%) at most sites, with the impacts from the 2025 GMC exhibiting minor reductions and increases at 0.2 and 1.0 s periods, respectively, relative to the 2003 GMC.

Puerto Rico, U.S. Virgin Islands

Technique for estimating magnitude and frequency of peak flows in Maryland

A convenient and reliable technique for estimating flood magnitudes is required for effective flood-plain management and for the efficient design of bridges, culverts, embankments, and flood-protection structures. Methods are presented for estimating peak-flow magnitudes of selected frequencies, ranging from 2 to 500 years, for all nontidal drainage basins in Maryland. The methods were developed by generalized least-squares regression techniques using data from 219 gaged basins in and near Maryland. The State is divided into five hydrologic regions: the Appalachian Plateaus and Allegheny Ridges region, the Blue Ridge and Great Valley region, the Piedmont region, the Western Coastal Plain region, and the Eastern Coastal Plain region. These regions correspond to the physiographic provinces of the State, with the exceptions that (1) the Coastal Plain Province is divided into two hydrologic regions, and (2) there is no distinct hydrologic region corresponding to the Valley and Ridge Province as it is divided into its constituent Allegheny Ridges and Great Valley subdivisions. Sets of equations for calculating peak discharges based on physical basin characteristics are provided for each of the regions. Based on the peak-flow equations, methods for estimating peak flows are presented for ungaged and gaged streams in Maryland. The methods and equations are supported by generalized least-squares analysis of basin and flood-frequency characteristics data from 219 drainage basins in and near Maryland. estimates for each of the five regions are calculated using combinations of the fol-lowing basin characteristics: drainage area, forest cover, basin relief, carbonate rock coverage, storage, and runoff-curve number. Drainage area contributes to the estimate in all five study regions. Carbonate rock coverage is used only in the Blue Ridge and Great Valley region. Storage and runoff-curve number are used solely in the Eastern Coastal Plain region. All other basin characteristics are used in two or more regions. Standard errors of estimate for the regression equations range from 19 to 31 percent in the Appalachian Plateaus and Allegheny Ridges region, 34 to 47 percent in the Blue Ridge and Great Valley region, 33 to 48 percent in the Piedmont region, 45 to 64 percent in the Western Coastal Plain region, and 36 to 42 percent in the Eastern Coastal Plain region.

Maryland

James Buttle review: The characteristics of baseflow resilience across diverse ecohydrological terrains

The dynamic storage of aquifers is the portion of groundwater that can potentially drain to any given point along a stream to create baseflow. Baseflow typically occurs year-round in perennial streams, though the characteristics and stability of dynamic storage are often most important to instream processes during extended dry periods (without precipitation and snowmelt) when runoff and quickflows are minimised. The term ‘baseflow resilience’ is defined for this review as the tendency of baseflow in streams to maintain a consistent volume and water quality year to year while under stress from climate variability and extremes, along with anthropogenic stressors such as water withdrawals, land use change, and water quality degradation. ‘Baseflow resilience’ has, in part, a user-defined meaning spanning water supply and water quality variables of primary interest. Watershed characteristics that directly impact resilience can often produce non-intuitive feedbacks that enhance some attributes of baseflow while simultaneously impairing others. For example, permeable stream corridor geology creates strong stream-groundwater hydrologic connectivity, yet fast groundwater drainage via preferential high-permeability flowpaths can lead to streamflow not being sustained during extended dry periods. Also, shallow groundwater sources are generally more immediately vulnerable to extreme events, warming, salinization, transpiration, and precipitation drought, compared to deeper groundwater. Yet baseflow drought in streams influenced by deeper groundwater can lag precipitation drought by years, and contaminant legacies may propagate through deep groundwater flowpaths to receiving waters for decades to centuries. Finally, irrigation withdrawals can intercept groundwater that would have drained to streams, and the application of irrigation may leach contaminants from the soil zone by unnaturally raising water tables, yet irrigation return flows can sustain baseflow and groundwater-dependent habitats in semiarid areas. This review covers the concept of hydrologic resilience in the context of stream baseflow processes and summarises the common hydrogeological controls on, and multiscale stressors of, dynamic groundwater storage. Further, we present several quantitative metrics to assess a range of water supply to water quality baseflow characteristics using both broadly available and boutique data types, a subset of which are demonstrated using data from the Delaware River Basin, USA.

Delaware River Basin

Utilizing hydrophones to detect streambed mobilization in the Wild and Scenic reach of the Rio Chama

This paper describes a study that deployed underwater acoustic sensors (hydrophones) to detect streambed mobilization in the Wild and Scenic reach of the Rio Chama, New Mexico. Fine sediment accumulation in the gravel‑cobble bed affects brown trout spawning habitat, and understanding incipient motion thresholds is essential for planning effective environmental flushing flows released from El Vado Dam. Two hydrophone stations were operated during 2021–2022, capturing audio data during a high‑flow pulse in late 2021. Acoustic processing techniques, including spectral analysis and threshold‑based impact detection, were used to identify sediment‑generated noise associated with coarse sediment transport. Results indicate detectable sediment mobilization during the high‑flow pulse, demonstrating hydrophones’ potential as a passive monitoring tool for environmental flow planning and sediment‑management decision support.

Conference Paper

Petrogenesis and mineralization potential of the Bradley Peak komatiitic basalts, Wyoming Province

The ca. 2.72 Ga Bradley Peak greenstone terrane in the Wyoming Province contains spinifex- and cumulate-textured komatiitic volcanic rocks that may host Ni-Cu-PGE sulfide mineralization. New whole rock geochemistry classifies these rocks as Al-undepleted komatiitic basalts derived from a parental melt with ~17 wt. % MgO. Isotopic data (Sm-Nd, Re-Os) and REE profiles suggest a plume source and possible assimilation of juvenile footwall volcanic rocks. Calculated sulfur concentrations at sulfide saturation and low-detection PGE geochemistry indicate these magmas did not saturate a sulfide liquid resulting in sulfide mineralization. Although the Bradley Peak komatiitic basalt flows are unlikely to host magmatic sulfide mineralization, they are likely the source of Au for regional orogenic gold deposits.

Wyoming

Quantitative mineral resource assessment of lithium pegmatite deposits in the northern Appalachian orogen, USA

Lithium demand is projected to increase more than 48 times by 2040 due to electric vehicle production and other energy storage needs. Most lithium production is outside of the USA, thereby increasing supply chain vulnerability. The combined end use importance and heightened supply risk of lithium make this lightest metallic element a critical commodity to the USA. To mitigate this supply risk, the US Geological Survey is actively assessing lithium deposits in the USA. Herein, we detail an assessment for lithium-mineralized pegmatites in the US northern Appalachian Mountains. Permissive tracts were generated by cross-referencing tectonic and geologic maps and mineral occurrence data with mappable criteria derived from generalized and region-specific lithium pegmatite ore deposit models; tracts were then ranked as having high, medium, or low permissibility. Available geophysical and geochemical data were found to be of minimal utility for this deposit type at the scale of the assessment. The number of undiscovered deposits were estimated and integrated into probabilistic simulations, which included an expanded and updated global grade and tonnage model of pegmatite-hosted lithium ore. The estimated total amount of undiscovered resources for the northern Appalachian Orogen has a median value of 1,410,000 metric tons of Li 2 O when considering moderate correlation across sub-regions. At a confidence level of 90%, a resource of at least 90,000 metric tons of Li 2 O remains undiscovered, and at a 10% confidence level, a resource of as much as 7,380,000 metric tons Li 2 O remains undiscovered. After applying an up-to-date economic filter to convert median contained lithium to recoverable material, a correlated total of 900,000 metric tons of Li 2 O may be economically extractable, equating to enough Li 2 O to provide the current annual US lithium supply deficit (presently obtained through net imports) for 127 years at 2025 rates of apparent consumption. This period of provision will inevitably shorten with projected increasing consumption rates, emphasizing that further research could be completed to better delineate regions of high lithium resource potential and support exploration and domestic production.

Connecticut, Delaware, Maine, Massachusetts, New H

Seabed maps showing topography, ruggedness, backscatter intensity, sediment mobility, and the distribution of geologic substrates in quadrangle 2 of the Stellwagen Bank National Marine Sanctuary region offshore of Boston, Massachusetts

The U.S. Geological Survey, in cooperation with the National Marine Sanctuary Program of the National Oceanic and Atmospheric Administration, has conducted seabed mapping and related research in the Stellwagen Bank National Marine Sanctuary (SBNMS) region since 1993. The area being mapped using geophysical and geological data includes the SBNMS and the surrounding region, which totals approximately 3,700 square kilometers (km 2 ) and is subdivided into 18 quadrangles. The seabed is a glaciated terrain that is topographically and texturally diverse. Quadrangle 2, the subject of this scientific investigations map, has a mapped area of 209 km 2 and has water depths that range from about 19 meters (m) on the Stellwagen Bank crest to about 68 m in the Stellwagen Basin. Seven map types, each at a scale of 1:25,000, depict seabed topography, ruggedness, backscatter intensity, distribution of geologic substrates, sediment mobility, distribution of fine- and coarse-grained sand, and substrate mud content. These maps show the distribution of geologic substrates across the southwestern part of Stellwagen Bank, in Stellwagen Basin to the west and southwest of the bank, and in Little Stellwagen Basin and the western part of Race Point Channel to the south of the bank. Interpretations of multibeam sonar bathymetric and seabed backscatter imagery, photographs, video imagery, and grain-size analyses were used to create the geology-based maps. Data from 733 stations were analyzed, including 656 sediment samples. The geologic substrate maps of quadrangle 2 show the distribution of 19 geologic substrates that represent a wide range of textures, such as rippled and immobile sand, immobile muddy sand and sandy mud, sand that partially veneers gravel, and a boulder ridge. Mapped substrates are characterized by sediment grain-size composition, surface morphology, substrate layering, the mobility or immobility of substrate surfaces, and water depth range. This scientific investigations map portrays the major geological elements (substrates, topographic features, and processes) of environments in quadrangle 2. It is intended to provide a foundation for research into present and past sediment transport processes in a complex terrain, provide insights into the ecological requirements of invertebrate and vertebrate species that utilize the various substrates, and support seabed management in the region.

Massachusetts

Estimating groundwater level records using MOVE.1 and computing monthly percentiles from estimated groundwater records in Massachusetts

The U.S. Geological Survey, in cooperation with the Massachusetts Department of Environmental Protection, performed record extensions on groundwater levels at select wells using the Maintenance of Variance Extension type 1 (MOVE.1) method. The groundwater levels estimated from these record extensions were used to compute monthly percentiles to improve future determinations of a groundwater index. In Massachusetts, 27 of 29 short-record study wells with continuous groundwater levels between 0.8 and 8.1 years were suitable for record extensions; 37 long-record index wells were used to extend the groundwater level records at the study wells. The index well selected to pair with a study well was chosen based on Pearson correlation coefficient values; cross-correlation between the two wells; geologic and topographic similarity; and smallest distance spanning the wells. Each study well and its corresponding index well have 1 or more years of concurrent, overlapping data; a Pearson correlation coefficient that exceeded a threshold value of 0.8; and a similar aquifer type and hydrologic characteristics. Of the 29 study wells, 2 showed poor correlations with all index wells and were not considered for record extensions. Performance metrics used to assess the accuracy of the MOVE.1 models indicated that most models provided reasonable estimates of groundwater levels. Root mean square error values ranged from 0.097 to 2.292 feet, with a median of 0.536 foot. Nash-Sutcliffe efficiency coefficient values ranged from 0.623 to 0.996, with a median value of 0.759. Generally, study wells in close geographical proximity to their index well resulted in stronger model performance. The average length of groundwater level records was extended by 14.1 years to a new average of 18.1 years. The estimated groundwater level records from the MOVE.1 models resulted in an increase in the range of highest and lowest groundwater levels at 23 of 27 wells. The increase in range of groundwater levels was between 0.08 to 7.95 feet. Monthly percentiles for State drought indices were computed from the estimated MOVE.1 records and observed records through December 31, 2021. Percentiles computed from estimated records show an average groundwater level about 1.0 foot lower than observed data at the 2d percentile and 0.1 foot lower at the 30th percentile.

Massachusetts

Water, ice, meteorological, and speed measurements at South Cascade Glacier, Washington, 1999 balance year

Winter snow accumulation and summer snow, firn, and ice melt were measured at South Cascade Glacier, Washington, to determine the winter and net balances for the 1999 balance year. The 1999 winter snow balance, averaged over the glacier, was 3.59 meters, and the net balance was 1.02 meters. Since the winter balance record began in 1959, only three winters have had a higher winter balance. Since the net balance record began in 1953, only 2 years have had a greater positive net balance than 1999. Runoff was measured from the glacier and an adjacent non-glacierized basin. Air temperature, precipitation, and humidity were measured nearby, and ice speed was measured. This report makes these data available to the glaciological and climatological community.

Washington

Investigation of land cover within wetland complexes at Dixie Meadows, Churchill County, Nevada, from October 2015 to January 2022

The U.S. Geological Survey investigated land cover at subannual time steps within six wetland areas in Dixie Valley, Churchill County, Nevada, from October 2015 to January 2022. As requested by the U.S. Fish and Wildlife Service, we used aerial photography and satellite remote sensing data to map surface water and other land cover types within the wetland complexes. We identified five land cover classes using the green normalized difference vegetation index (gNDVI) and its inverse relationship to the normalized difference water index (NDWI) within three U.S. Department of Agriculture National Agriculture Imagery Program aerial images (acquired in 2015, 2017, and 2019) and 110 European Space Agency Sentinel-2 satellite images (acquired 2015–2022). The relative wetness of soil conditions within each land cover class is estimated by comparison to previously published observations of relative conductivity measured by 79 field-based sensors within the wetlands from 2019 to 2021. We mapped the areal coverage of the five land cover classes for approximately 385 acres (1,559,000 square meters [m²]) comprising six individual wetland complexes as well as a larger 1,298- acre (5,254,000-m 2 ) area of interest inclusive of the wetland complexes and adjacent landscape. Land cover of open water (Class 5) primarily within ponds at one of the wetland complexes comprised 8,333 m 2 , on average, of the wetland complexes. Land cover of mixed shallow surface water, saturated soil, and vegetation (Class 4) comprised 111,723 m 2 on average of the wetland complexes. Land cover of dense green vegetation canopy cover (Class 3) that often (46 percent of observations) had underlying surface water or saturated soil conditions comprised 592,522 m 2 on average of the wetland complexes. The remaining areas of the wetland complexes not mapped as these three land cover types (Classes 2 and 1) had sparse vegetation or bare soil cover and commonly (greater than or equal to 67 percent of observations) had dry soil conditions. The investigation of land cover detailed in this report could inform future efforts to map land cover more precisely via higher resolution remote sensing or ground-based surveying or could be incorporated with other environmental monitoring data to characterize habitat and hydrology of the wetland complexes at Dixie Meadows.

Nevada

Technique for estimating magnitude and frequency of floods in Kentucky

This report presents flood magnitude and frequency relations applicable to unregulated streams in Kentucky. The relations are based on flood data at 117 gaging stations in Kentucky and 14 in adjacent states having 10 or more years of record not significantly affected by man-made changes. Equations that relate flood magnitude and frequency to contributing drainage area in 16 geographic areas may be used to estimate magnitude of future floods with recurrence intervals of as much as 100 years on gaged and ungaged streams having drainage areas of 10 to 4,300 square miles (25 .9 to 11,100 square kilometers) . Estimating equations are also presented in graphical form for the convenience of the user. Additional graphs are presented to estimate flood magnitude for selected recurrence intervals along the Cumberland, Kentucky, and Ohio Rivers.

Kentucky