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At least 1,009 records · Page 56Linked to original sources

Proxy of monsoon seasonality in carbon isotopes from paleosols of the southern Chinese Loess Plateau

Soil organic matter (SOM) and soil carbonate (SC) are common constituents in soils and are directly related to plant growth. SOM accumulates gradually from the decomposition of plant material over time, whereas SC formation is biased to dry-season soil-dissolved CO 2 that derives from plant respiration during a drying phase of the growing season. In some mixed C 3 -C 4 environments, the peak of C 3 and C 4 plant metabolism differs seasonally, and the carbon source that contributes to the SOM and SC can be different. Consequently, δ 13 SOM values reflect an annual average of the floral biomass, but δ 13 SC values reflect a seasonal aspect of the plant community. The relationship between δ 13 C SC and δ 13 C SOM is mainly controlled by how different the seasonal conditions are. Our results suggest that the relationship is a seasonal proxy that can be used to differentiate the seasonality effects of Indian, East Asian, and Siberian monsoons on the Chinese Loess Plateau during the last interglacial-glacial cycle.

Geology↗

Comment [on 'Are Proterozoic cap carbonates and isotopic excursions a record of gas hydrate destabilization following Earth’s coldest intervals?, Kennedy et al., Geology 29(5), 442-446]

We welcome the evidence noted by Kennedy et al. (2001) for strong methane excursions associated with the cessation of glacial episodes. They identify the carbon in cap carbonates overlying glacial sediments as probably being of biogenic origin and as likely having had a biogenic methane source. These authors suggest that the methane was released from gas hydrate, which we agree is likely. However, we suggest a different mechanism for that release, rather than their suggested warming event. We propose that a dominantly pressure-related mechanism would be more plausible for releasing sufficient methane from the huge gas hydrate reservoir to modify the global greenhouse and drive global warming in a geological instant.

Geology↗

Evolution of Devonian carbonate-shelf margin, Nevada

The north-trending, 550-km-long Nevada segment of the Devonian carbonate-shelf margin, which fringed western North America, evidences the complex interaction of paleotectonics, eustasy, biotic changes, and bolide impact-related influences. Margin reconstruction is complicated by mid-Paleozoic to Paleogene compressional tectonics and younger extensional and strike-slip faulting. Reports published during the past three decades identify 12 important events that influenced development of shelf-margin settings; in chronological order, these are: (1) Early Devonian inheritance of Silurian stable shelf inargin, (2) formation of Early to early Middle 'Devonian shelf-margin basins, (3) propradation of later Middle Devonian shelf margin, (4) late Middle Devonian Taghanic ondap and continuing long-term Frasnian transgression, (5) initiation of latest Middle Devonian to early Frasnian proto-Antler orogenic forebulge, (6) mid-Frasnian Alamo Impact, (7) accelerated development of proto-Antler forebulge and backbulge Pilot basin, (8) global late Frasnian sentichatovae sea-level rise, (9) end-Frasnian sea-level fluctuations and ensuing mass extinction, (10) long-term Famennian regression and continept-wide erosion, (11) late Famennian emergence: of Ahtler orogenic highlands, and (12) end-Devonian eustatic sea-level fall. Although of considerable value for understanding facies relationships and geometries, existing standard carbonate platform-margin models developed for passive settings else-where do not adequately describe the diverse depositional and, structural settings along the Nevada Devonian platform margin. Recent structural and geochemical studies suggest that the Early to Middle Devonian-shelf-margin basins may have been fault-bound and controlled by inherited Precambrian structure. Subsequently, the migrating latest Middle to Late Devonian Antler orogenic forebulge exerted a dominant control on shelf-margin position, morphology, and sedimentation.

Nevada↗

Responses of invasive silver and bighead carp to a carbon dioxide barrier in outdoor ponds

Resource managers need for effective methods to prevent the movement of silver ( Hypophthalmichthys molitrix ) and bighead carp ( H. nobilis ) from the Mississippi River basin into the Laurentian Great Lakes. In this study, we evaluated dissolved carbon dioxide (CO 2 ) as a barrier and deterrent to silver (278 ± 30.5 mm) and bighead (212 ± 7.7 mm) carp movement in continuous-flow outdoor ponds. As a barrier, CO 2 significantly reduced upstream movement but was not 100% effective at blocking fish passage. As a deterrent, we observed a significant shift away from areas of high CO 2 relative to normal movement before and after injection. Carbon dioxide concentrations varied across the pond during injection and reached maximum concentrations of 74.5±1.9 mg/L CO 2 ; 29 532 – 41 393 µatm at the site of injection during three independent trials. We conclude that CO 2 altered silver and bighead carp movement in outdoor ponds and recommend further research to determine barrier effectiveness during field applications.

Canadian Journal of Fisheries and Aquatic Sciences↗

Lethal and sublethal responses of native mussels (Unionidae: Lampsilis siliquoidea and Lampsilis higginsii) to elevated carbon dioxide

Levels of carbon dioxide (CO 2 ) that have been proposed for aquatic invasive species control (24 000 – 96 000 μatm partial pressure of CO 2 ( P CO 2 ); 1 atm = 101.325 kPa) were tested on two juvenile mussels, the fatmucket ( Lampsilis siliquoidea ) and the US federally endangered Higgins’ eye ( Lampsilis higginsii ). A suite of responses (survival, growth, behavior, and gene expression) were measured after 28 days of exposure to CO 2 and 14 days postexposure. The 28-day LC 20 (concentration lethal to 20% of organisms) was lower for L. higginsii (31 800 μatm P CO 2 , 95% confidence interval (CI) 15 000 – 42 800 μatm) than for L. siliquoidea (58 200 μatm P CO 2 , 95% CI 45 200 – 68 100 μatm). Treatment-related reductions occurred in all measures of growth and condition. Expression of chitin synthase, key for shell formation, was downregulated at 28 days of exposure. Carbon dioxide caused narcotization and movement to the substrate surface of mussels, behaviors that could increase mortality by predation and displacement. We conclude that survival and growth of juvenile mussels could be reduced by continuous exposure to elevated CO 2 , but recovery may be possible with shorter-duration exposure.

Canadian Journal of Fisheries and Aquatic Sciences↗

The role of soil drainage class in carbon dioxide exchange and decomposition in boreal black spruce (Picea mariana) forest stands

Black spruce (Picea mariana (Mill.) B.S.P.) forest stands range from well drained to poorly drained, typically contain large amounts of soil organic carbon (SOC), and are often underlain by permafrost. To better understand the role of soil drainage class in carbon dioxide (CO2) exchange and decomposition, we measured soil respiration and net CO2 fluxes, litter decomposition and litterfall rates, and SOC stocks above permafrost in three Alaska black spruce forest stands characterized as well drained (WD), moderately drained (MD), and poorly drained (PD). Soil respiration and net CO2 fluxes were not significantly different among sites, although the relation between soil respiration rate and temperature varied with site (Qw: WD > MD > PD). Annual estimated soil respiration, litter decomposition, and groundcover photosynthesis were greatest at PD. These results suggest that soil temperature and moisture conditions in shallow organic horizon soils at PD were more favorable for decomposition compared with the better drained sites. SOC stocks, however, increase from WD to MD to PD such that surface decomposition and C storage are diametric. Greater groundcover vegetation productivity, protection of deep SOC by permafrost and anoxic conditions, and differences in fire return interval and (or) severity at PD counteract the relatively high near-surface decomposition rates, resulting in high net C accumulation.

Canadian Journal of Forest Research↗

Effect of timber harvest on soil carbon storage at Blodgett Experimental Forest, California

Four plots from a mixed conifer forest were similarly cleared, burned, and replanted at various times over 17 years; a plot logged 79 years before sampling was used as a control. The plots had similar slope (2 to 15%, midslope position), aspect (south to southeast), and soil type (Holland series: mesic Haploxeralf; a Gray Brown Luvisol in the Canadian classification system). Twenty sites at each plot were sampled volumetrically by horizon to 20 cm below the organic–mineral soil boundary. Samples were analyzed for bulk density, organic C, and total N. There was an initial loss (15%) of organic C from the soil within 1 to 7 years, likely the result of oxidation (burning and decomposition) and erosion. For 17 years of forest regrowth, the soil continued to lose C (another 15%), probably owing to decomposition of slash material and possibly erosion, despite the slight accumulation of new litter and roots. After 80 years of regrowth, rates of carbon accumulation exceeded rates of loss, but carbon storage had declined and was not likely to recover to preharvest levels. Timber harvest and site preparation dramatically altered soil C and N distribution, in which C/N ratios after site preparation were initially high throughout the upper 20 cm. Subsequently, C/N ratios became lower with depth and with recovery age. Although stocks of C and N varied considerably among the plots and did not change consistently as a function of recovery age, the C/N ratios did vary systematically with recovery age. We hypothesize that the amount of C ultimately stored in the soil at steady state depends largely on N reserves and potentials, which appear to vary with erosion, intensity of burning, and site treatment.

California↗

Models for the deposition of Mesozoic-Cenozoic fine-grained organic-carbon-rich sediment in the deep sea

The widespread occurrence of organic-carbon-rich strata (‘black shales’) in certain portions of Jurassic, Cretaceous and Cenozoic sequences has been well-documented from Deep Sea Drilling Project sites in the Atlantic and Pacific Oceans and from sequences, now exposed on land, originally deposited in the Tethyan ocean. These ancient black shales usually have been explained by analogy with examples of modern deep-sea sediments in which organic matter locally is preserved by (1) increasing the supply of organic matter, (2) increasing the rate of sedimentation, and/or (3) decreasing the oxygen content of the bottom water. However, detailed examination of many black shales reveals characteristics that cannot be explained by simple local models, including: their approximate coincidence in time globally; their occurrence in a variety of different environments, including open oxygenated oceans, restricted basins, deep and shallow water; their interbedding with organic-carbonpoor strata which often dominate a so-called black shale sequence; their deposition by pelagic, hemipelagic, turbiditic and other processes; and the variations in type and amount of organic matter that occur even within the same sequence. A more complex model for the origin of black shales therefore appears most appropriate, in which the cyclic preservation of organic matter depends on the interplay of the three main variables, namely supply of organic matter, sedimentation rate, and deep-water oxygenation, each of which varies independently to some extent. The variation and relative importance of these parameters in individual basins and widespread black shale deposition in general are linked globally and temporally by changes in global sea-level, climate and related changes in oceanic circulation. An important and often overlooked factor for the supply of organic matter to deep-basin sediments is the frequency and magnitude of redepositional processes. The interplay of these variables is discussed in relation to the middle Cretaceous and Cenozoic organic-carbon-rich strata, in particular, which show marked differences in the relative importance of the different variables.

Geological Society of London Special Publications↗

Biostratigraphy and chronostratigraphy of the Cambrian-Ordovician great American carbonate bank

The carbonate strata of the great American carbonate bank (GACB) have been subdivided and correlated with ever-increasing precision and accuracy during the past half century through use of the dominant organisms that evolved on the Laurentian platform through the Cambrian and the Ordovician. Trilobites and conodonts remain the primary groups used for this purpose, although brachiopods, both calcareous and phosphatic, and graptolites are very important in certain facies and intervals. A series of charts show the chronostratigraphic units (series and stages) currently in use for deposits of the GACB and the biostratigraphic units (zones, subzones, and biomeres) whose boundaries delineate them. Older and, in some cases obsolete, stages and faunal units are included in the figures to allow users to relate information from previous publications and/or industry databases to modern units. This chapter also provides a brief discussion on the use of biostratigraphy in the recognition and interregional correlation of supersequence boundaries within the Sauk and Tippecanoe megasequences, and the varied perspectives on the nature of biostratigraphic units and their defining taxa during the past half century. Also included are a concise update on the biomere concept, and an explanation of the biostratigraphic consequences of a profound change in the dynamics of extinction and replacement that occurred on the GACB in the Early Ordovician when the factors responsible for platformwide biomere-type extinctions faded and ultimately disappeared. A final section addresses recent and pending refinements in the genus and species taxonomy of biostratigraphically significant fossil groups, the potential they hold for greatly improved correlation, and the obstacles to be overcome for that potential to be realized.

AAPG Memoir↗

Origin of gasoline-range hydrocarbons and their migration by solution in carbon dioxide in Norton basin, Alaska.

Carbon dioxide from a submarine seep in Norton Sound, Alaska, carries a minor component of gas- and gasoline-range hydrocarbons. The molecular and isotopic compositions of the hydrocarbon gases and the presence of gasoline-range hydrocarbons indicate that these molecules are derived from thermal alteration of marine and/or nonmarine organic matter buried within Norton basin. In the gasoline-range hydrocarbons, individual cyclic and branched-chain molecules are much more abundant than straight-chain hydrocarbons. This distribution suggests that the hydrocarbon mixture is an immature, petroleumlike condensate of lower temperature origin than normal crude oil. The submarine seep provides a natural example in support of a carbon dioxide solution transport mechanism thought to be operative in the migration of hydrocarbons in certain reservoirs.

Alaska↗

Citronelle Dome: A giant opportunity for multizone carbon storage and enhanced oil recovery in the Mississippi Interior Salt Basin of Alabama

The Citronelle Dome is a giant, salt-cored anticline in the eastern Mississippi Interior Salt Basin of southern Alabama that is located near several large-scale, stationary, carbon-emitting sources in the greater Mobile area. The dome forms an elliptical, four-way structural closure containing opportunities for CO2-enhanced oil recovery (CO2-EOR) and large-capacity saline reservoir CO2 sequestration. The Citronelle oil field, located on the crest of the dome, has produced more than 169 million bbl of 42-46?? API gravity oil from sandstone bodies in the Lower Cretaceous Rodessa Formation. The top seal for the oil accumulation is a thick succession of shale and anhydrite, and the reservoir is underfilled such that oil-water contacts are typically elevated 30-60 m (100-200 ft) above the structural spill point. Approximately 31-34% of the original oil in place has been recovered by primary and secondary methods, and CO2-EOR has the potential to increase reserves by up to 20%. Structural contour maps of the dome demonstrate that the area of structural closure increases upward in section. Sandstone units providing prospective carbon sinks include the Massive and Pilot sands of the lower Tuscaloosa Group, as well as several sandstone units in the upper Tuscaloosa Group and the Eutaw Formation. Many of these sandstone units are characterized by high porosity and permeability with low heterogeneity. The Tuscaloosa-Eutaw interval is capped by up to 610 m (2000 ft) of chalk and marine shale that are proven reservoir seals in nearby oil fields. Therefore, the Citronelle Dome can be considered a major geologic sink where CO2 can be safely stored while realizing the economic benefits associated with CO2-EOR. Copyright ?? 2008. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Environmental Geosciences↗

Inter-annual variability of area-scaled gaseous carbon emissions from wetland soils in the Liaohe Delta, China

Global management of wetlands to suppress greenhouse gas (GHG) emissions, facilitate carbon (C) sequestration, and reduce atmospheric CO 2 concentrations while simultaneously promoting agricultural gains is paramount. However, studies that relate variability in CO 2 and CH 4 emissions at large spatial scales are limited. We investigated three-year emissions of soil CO 2 and CH 4 from the primary wetland types of the Liaohe Delta, China, by focusing on a total wetland area of 3287 km 2 . One percent is Suaeda salsa , 24% is Phragmites australis , and 75% is rice. While S . salsa wetlands are under somewhat natural tidal influence, P . australis and rice are managed hydrologically for paper and food, respectively. Total C emissions from CO 2 and CH 4 from these wetland soils were 2.9 Tg C/year, ranging from 2.5 to 3.3 Tg C/year depending on the year assessed. Primary emissions were from CO 2 (~98%). Photosynthetic uptake of CO 2 would mitigate most of the soil CO 2 emissions, but CH 4 emissions would persist. Overall, CH 4 fluxes were high when soil temperatures were >18°C and pore water salinity <18 PSU. CH 4 emissions from rice habitat alone in the Liaohe Delta represent 0.2% of CH 4 carbon emissions globally from rice. With such a large area and interannual sensitivity in soil GHG fluxes, management practices in the Delta and similar wetlands around the world have the potential not only to influence local C budgeting, but also to influence global biogeochemical cycling.

Liaohe Delta↗

The anaesthesia of fish by high carbon-dioxide concentrations

A practical and economical method for anaesthetizing adult salmon and steelhead trout in the fish trucks used in the Grand Coulee fish salvage program is described. The method consists in generating a predetermined carbon-dioxide concentration in the 1000-gallon tanks of the trucks through the successive addition of predissolved sodium bicarbonate and dilute sulphuric acid in proper quantities. Carbon-dioxide anaesthesia effectively solved the acute problem of species segregation in the fish salvage program and, with minor modifications, could be used with equal success in certain hatchery operations necessitating the handling of large fish.

Transactions of the American Fisheries Society↗

Scientific communications: Re-Os sulfide (bornite, chalcopyrite, and pyrite) systematics of the carbonate-hosted copper deposits at ruby creek, southern brooks range, Alaska

New Re-Os data for chalcopyrite, bornite, and pyrite from the carbonate-hosted Cu deposit at Ruby Creek (Bornite), Alaska, show extremely high Re abundances (hundreds of ppb, low ppm) and contain essentially no common Os. The Re-Os data provide the first absolute ages of ore formation for the carbonate-hosted Ruby Creek Cu-(Co) deposit and demonstrate that the Re-Os systematics of pyrite, chalcopyrite, and bornite are unaffected by greenschist metamorphism. The Re-Os data show that the main phase of Cu mineralization pre dominantly occurred at 384 ?? 4.2 Ma, with an earlier phase possibly at ???400 Ma. The Re-Os data are consistent with the observed paragenetic sequence and coincide with zircon U-Pb ages from igneous rocks within the Ambler metallogenic belt, some of which are spatially and genetically associated with regional volcanogenic massive sulfide deposits. The latter may suggest a temporal link between regional magmatism and hydrothermal mineralization in the Ambler district. The utility of bornite and chalcopyrite, in addition to pyrite, contributes to a new understanding of Re-Os geochronology and permits a refinement of the genetic model for the Ruby Creek deposit. ?? 2009 Society of Economices Geologists, Inc.

Economic Geology↗

Effect of sulfate and carbonate minerals on particle-size distributions in arid soils

Arid soils pose unique problems during measurement and interpretation of particle-size distributions (PSDs) because they often contain high concentrations of water-soluble salts. This study investigates the effects of sulfate and carbonate minerals on grain-size analysis by comparing analyses in water, in which the minerals dissolve, and isopropanol (IPA), in which they do not. The presence of gypsum, in particular, substantially affects particle-size analysis once the concentration of gypsum in the sample exceeds the mineral’s solubility threshold. For smaller concentrations particle-size results are unaffected. This is because at concentrations above the solubility threshold fine particles cement together or bind to coarser particles or aggregates already present in the sample, or soluble mineral coatings enlarge grains. Formation of discrete crystallites exacerbates the problem. When soluble minerals are dissolved the original, insoluble grains will become partly or entirely liberated. Thus, removing soluble minerals will result in an increase in measured fine particles. Distortion of particle-size analysis is larger for sulfate minerals than for carbonate minerals because of the much higher solubility in water of the former. When possible, arid soils should be analyzed using a liquid in which the mineral grains do not dissolve, such as IPA, because the results will more accurately reflect the PSD under most arid soil field conditions. This is especially important when interpreting soil and environmental processes affected by particle size.

Soil Science Society of America Journal↗

Preliminary report on the stratigraphy and structure of part of the Carbon Creek and Ketik anticlines

U. S. Geological Survey Party No. 4 mapped the stratigraphy and structure of parts of the Carbon Creek and Ketik anticlines during the summer of 1950. The area, which lies in quadrangles I-19 and I-20 is shown in figure 1. Large-scale maps, compiled from plane-table surveys, give a more detailed picture of two parts of the area, the west plunge of the Carbon Creek anticline (fig. 2) and a segment near the middle of the Ketik anticline (fig. 3).

Alaska↗

A seasonal and spatial comparison of metals, and stable carbon and nitrogen isotopes, in Chincoteague Bay and the marsh deposits of Assateague Island and the adjacent vicinity, Maryland and Virginia

After Hurricane Sandy, scientists from the U.S. Geological Survey, St. Petersburg Coastal and Marine Science Center conducted a seasonal collection of estuarine, marsh, and sandy overwash surface sediments from Chincoteague Bay, Tom’s Cove, and the surrounding Assateague Island and Delmarva Peninsula in March–April and October 2014. Surplus surface sediment was analyzed for metals, percent carbon and nitrogen, δ 13 C, and δ 15 N as part of a complementary U.S. Geological Survey Coastal and Marine Geology Program Sea-level and Storm Impacts on Estuarine Environments and Shorelines project study. The geochemical subsample analyzed for metals and stable isotopes at each site may be used for comparison with past data sets, to create a modern baseline of the natural distribution of the area, to understand seasonal variability as it relates to the health of the local environment, and to assess marsh-to-bay interactions. The use of metals, stable carbon, and stable nitrogen isotopes allows for a more cohesive snapshot of factors influencing the environment and could aid in tracking environmental change. This report serves as an archive for chemical data derived from the surface sediment. Data are available for a seasonal comparison between the March–April 2014 and October 2014 sampling trips. Downloadable data are available as Microsoft Excel spreadsheets. These additional files include formal Federal Geographic Data Committee metadata ( data downloads ).

Maryland, Virginia↗

Seasonal changes in concentrations of dissolved pesticides and organic carbon in the Sacramento-San Joaquin delta, California, 1994-1996

The Sacramento-San Joaquin Delta (Delta) of California is an ecologically rich and hydrologically complex region that receives runoff from nearly one-quarter of the state. Water-quality studies of surface water in the region have found dissolved pesticides in winter storm runoff at concentrations toxic to some aquatic invertebrates. However, scientists have little information on pesticide concentrations in the Delta on a seasonal timescale or the importance of pesticide contributions from within-Delta sources. Consequently, the U.S. Geological Survey conducted a study from 1994 to 1996 during which water samples were collected seasonally from 31 sites located within the Delta and on major tributaries to the Delta. Water samples were analyzed for 20 current-use pesticides and dissolved organic carbon. During the study, 11 current-use pesticides were detected; maximum concentrations ranging from 17 ng/L (for trifluralin) to 1,160 ng/L (for metolachlor). The highest concentrations of five pesticides (carbaryl, carbofuran, metolachlor, molinate, and simazine) were greater than 900 ng/L. The greatest number of pesticides was detected in the summer of 1994, whereas the least number were detected in the winter of 1994. The herbicides metolachlor and simazine were the most frequently detected pesticides and were detected in five of the six sampling seasons. The herbicides molinate and EPTC were detected only during the three summer sampling seasons. A comparison of pesticides detected during the spring and summer of 1995 showed some seasonal variability. Comparison of the three summer seasons sampled showed that a larger number of pesticides were detected, and with generally higher maximum concentrations, in 1994 than in 1995 or 1996. Dissolved organic carbon (DOC) concentrations ranged, over the course of the study, from 1.4 mg/L to 10.4 mg/L, and had a median concentration of 3.8 mg/L. On a seasonal basis, the lowest maximum DOC concentrations occurred during the summer and winter of 1994. The highest median DOC concentration on a seasonal basis occurred in the spring of 1995. This previously unreported data is being published now to provide historical information on pesticide concentrations in the Delta to water managers and the scientific community.

Data Series↗