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Geologic framework and petroleum potential of the Atlantic Coastal Plain and continental shelf, with a section on stratigraphy

The Atlantic Coastal Plain and Continental Shelf of North America is represented by a belt of Mesozoic and Cenozoic rocks, 150 to 300 miles wide and 2,400 miles long, extending from southern Florida to the Grand Banks of Newfoundland. This belt of Mesozoic and Cenozoic rocks encompasses an area of about 400,000 to 450,000 square miles, more than three-fourths of which is covered by the Atlantic Ocean. The volume of Mesozoic and Cenozoic rocks beneath the Atlantic Coastal Plain and Continental Shelf exceeds 450,000 cubic miles, perhaps by a considerable amount. More than one-half of this is seaward far enough to contain marine source rocks in sufficient proportion to attract exploration for oil. A larger fraction, perhaps three-quarters of the volume, may be of interest in exploration for gas. The Coastal Plain consists of land between the crystalline piedmont of the Appalachian System and mean low-tide from southern Florida to the tip of Long Island plus a few small offshore islands and the Cape Cod Peninsula. This is an area of more than 100,000 square miles. The Continental Shelf extends from mean law-tide to the break marking the beginning of the continental rise, which is somewhat less than 600 feet in depth at most places. It is a gently sloping platform, about 350,000 square miles in area, that widens from less than 3 miles off southern Florida to about 285 miles off Newfoundland. The Blake Plateau occupies an area of about 70,000 square miles between the 500 and 5,000-foot bottom contours from the Cape Hatteras vicinity to the northernmost bank of the Bahamas. It has a gentle slope with only minor irregularities and scattered patches of Recent sediments. Both gravity and magnetic anomalies along the Atlantic Coast reflect primarily compositional differences at considerable depths in the earth's crust, but are related to some extent to the structure and composition of the Coastal Plain sedimentary rocks and shallow basement. Four alternating belts of predominantly positive and predominantly negative Bouguer gravity anomalies extend diagonally across the region from southwest to northeast. These correspond roughly with the continental rise and slope, the Continental Shelf and Coastal Plain, the Appalachian Mountain System front, and the Piedmont Plateau-Blue Ridge-Appalachian Basin region.

Atlantic Coastal Plain↗

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas↗

Arctic Alaska’s Lower Cretaceous (Hauterivian and Barremian) mudstone succession—Linking lithofacies, texture, and geochemistry to marine processes

We present new images and descriptions of the lithofacies and organic facies of the pebble shale unit and lower part of the Hue Shale (Lower Cretaceous) of Arctic Alaska at a high magnification that illustrates their textural characteristics. Our aims were to describe and determine the distribution of facies in these petroleum source rocks and to identify the processes that formed them. We sampled at high-resolution and applied new petrographic techniques combined with scanning electron microscopy and geochemical analyses to samples collected from three widely spaced sections—located in exposures along the Canning River and continuous core from the Mikkelsen Bay State 1 and Orion 1 wells. Results from these three locations indicate that this succession consists primarily of clay-rich mudstones that are variously silt- or sand-bearing and clay-dominated mudstones that exhibit mainly relict, 2–5 millimeter thick bedding and common but variable microbioturbation, rare macrobioturbation, and common fabrics of pelleted clay and silt. These mudstones contain rare, poorly sorted, silt-rich basal laminae that are often discontinuous and have wavy, sharp bases and crude upward fining. In addition, mud-supported, outsized clasts (dropstones) of fine sand to pebble size are present throughout the succession as isolated clasts or in clusters. We interpret these textures and much of this succession to result from intermittent deposition by suspension settling from melting seasonal sea ice—sometimes sediment-laden—and associated primary productivity. Overall, this mudstone succession fines and deepens upward from the pebble shale unit into the Hue Shale. In the Hue Shale of the Orion well, however, different processes intermittently deposited thin, discrete intervals of coarser sediment that probably represent deposition from density currents. Also in the Hue Shale of the Orion well, several thicker sandstone and silt-dominated mudstone units with discordant, scoured bases and cut and fill structures represent erosion during higher energy events such as major storms. Other lithofacies within the succession are graded tuffs/bentonites and tuffaceous/bentonitic mudstones from episodic volcanic ash falls; these are abundant in the Hue Shale, and very rare in the pebble shale unit of the two wells. Organic-carbon rich strata associated with volcanic ash intervals of the pebble shale unit and Hue Shale in the Mikkelsen 1 well have some of the best petroleum source rock potential determined for this succession. Authigenic pyrite and carbonate-cement-dominated mudstone are also present in both units of all three sections. The carbonate-cemented units indicate breaks in sedimentation and are common in the Hue Shale and in sections of the pebble shale unit interpreted to be more distal, such as along the Canning River. Our results document the variation in facies and textures of the Hauterivian and Barremian Lower Cretaceous mudstone succession of Arctic Alaska. Comparison of these characteristics to the products of modern processes on the North Slope of Alaska, in the Beaufort Sea, and elsewhere suggest that this succession formed primarily from depositional processes related to seasonal sea ice with intermittent fluvial-sourced sediment deposited by density currents and episodic erosion and reworking by storms and other currents.

Alaska↗

Sediment thickness in the southern Canada Basin

Multichannel seismic reflection data are used, in conjunction with deep crustal seismic refraction data, to estimate the thickness of sediments in the southern Canada Basin of the Arctic Ocean north of Alaska. The sediments are interpreted to be of Hauterivian (mid-Early Cretaceous) to Holocene age. Comparison of the seismic reflection character of seismic reflections in the study area with that in other basins indicates that a base-of-sediment—top of oceanic layer 2 reflection is not present above the depth at which the water-bottom multiple obscures all deeper arrivals, which is in conflict with the conclusions drawn from aeromagnetic, refraction, and other reflection studies. Seismic velocity structure, determined from the reflection data, indicates that the reflections above the multiple are from sedimentary strata. In the absence of seismic reflection evidence for the top of layer 2 above the multiple, we estimate total sediment thickness by using the layer 3 refractions and subtracting an average assumed layer 2 thickness from the top of layer 3. Assuming that an average thickness of oceanic layer 2 (1.4 km) overlies layer 3 in the southern Canada Basin, sediment thickness in the study area is estimated to range between 6.5 km where water depth is 3.8 km to greater than 11 km where the water depth is 2 km. This is nearly double that of any previous estimates and should have a significant effect on calculations such as the age of Canada Basin, regional heat flow, and long-term sedimentation rates.

Marine Geology↗

Geology of parts of the Johnny Gulch quadrangle, Montana

An area of about 35 square miles, situated about 30 miles southeast of Helena, Montana, was mapped during the summer of 1952 at a scale of l:24, 000. The area includes a part of the eastern foothills of the Elkhorn Mountains, and is underlain by sedimentary mad volcanic rocks of Cretaceous age that were intruded during late Cretaceous or early Tertiary time by several types of igneous rocks. The oldest rocks in the map area are the nonmarine sandstone, shale, and limestone of the Kootenai formation. These are overlain disconformably by the black shale siltstone, sandstone, and siliceous mudstone of the Colorado group that is subdivided into three map units; a lower black shale unit composed of black shale and silty shale with a basal clean sandstone, all of probable marine origin; a middle siliceous unit composed of sandstone, siltstone, and siliceous mudstone of both marine and nonmarine origin; and an upper black unit composed of black shale of marine origin. Conformably above the Colorado group are crystal lithic turfs of the Slim Sam formation; in places theme grade into and in other places are unconformably overlain by the Elkhorn Mountains volcanics composed of crystal tuff, breccia, flows, and bedded tuff of andesitic composition. The rocks of the Elkhorn Mountains volcanics and older formations have been intruded by diorite porphyry and related rocks and by hornblende quartz monzonite. The diorite porphyry and related rocks include hornblende diorite porphyry, hornblende augite diorite porphyry, augite diorite porphyry, and basalt. Resting with marked unconformity upon older rocks are volcanic sedimentary rocks of early Tertiary age that are locally overlain by thin rhyolite flows. Late Tertiary and Quaternary fans overlie the rhyolite flows. Alluvium, talus, and other mantle are present in small amounts in many parts of the area. The sedimentary rocks of the area mapped form a part of the east flank of a major anticline. A major north-south syncline to the north of map area is believed to have been deflected to the east of the area because of the rigidity of large irregular plutons of diorite porphyry. The location of the plutons may have been controlled by the initiation of the major syncline, by a postulated pre-intrusive fault, or by both. Most of the small-scale structural features are related to the emplacement of the plutons. During emplacement the intruded sediments yielded either by faulting or by folding; the deeper rocks failed by faulting and the shallower rocks failed by folding. The area contains deposits of gold, silver, copper, lead, and zinc, none of which are currently being mined; and a deposit of magnetite which is being mined for use in cement.

Open-File Report↗

Structure and sediment distribution in the western Bering Sea

Eleven seismic reflection profiles across Shirshov Ridge and the adjacent deep-water sedimentary basins (Komandorsky and Aleutian Basins) are presented to illustrate the sediment distribution in the western Bering Sea. A prominent seismic reflecting horizon, Reflector P (Middle—Late Miocene in age), is observed throughout both the Aleutian and Komandorsky Basins at an approximate subbottom depth of 1 km. This reflector is also present, in places, on the flanks and along the crest of Shirshov Ridge. The thickness of sediments beneath Reflector P is significantly different within the two abyssal basins. In the Aleutian Basin, the total subbottom depth to acoustic basement (basalt?) is about 4 km, while in the Komandorsky Basin the depth is about 2 km. Shirshov Ridge, a Cenozoic volcanic feature that separates the Aleutian and Komandorsky Basins, is an asymmetric bathymetric ridge characterized by thick sediments along its eastern flank and steep scarps on its western side. The southern portion of the ridge has more structural relief that includes several deep, sediment-filled basins along its summit. Velocity data from sonobuoy measurements indicate that acoustic basement in the Komandorsky Basin has an average compressional wave velocity of 5.90 km/sec. This value is considerably larger than the velocities measured for acoustic basement in the northwestern Aleutian Basin (about 5.00 km/sec) and in the central Aleutian Basin (5.40–5.57 km/sec). In the northwestern Aleutian Basin, the low-velocity acoustic basement may be volcaniclastic sediments or other indurated sediments that are overlying true basaltic basement. A refracting horizon with similar velocities (4.6–5.0 km/sec) as acoustic basement dips steeply beneath the Siberian continental margin, reaching a maximum subbottom depth of about 8 km. The thick welt of sediment at the base of the Siberian margin may be the result of sediment loading or tectonic depression prior to Late Cenozoic time.

Alaska↗

Methane seeps on the U.S. Atlantic margin: An updated inventory and interpretative framework

Since the discovery of >570 methane flares on the northern U.S. Atlantic margin between Cape Hatteras and Georges Bank in the last decade, the acquisition of thousands of kilometers of additional water column imaging data has provided greater coverage at water depths between the outer continental shelf and the lower continental slope. The additional high-resolution data reveal >1400 gas flares, but the removal of probable duplicates from the combined database of new flares and those recognized in 2014 yields ∼1139 unique sites. Most of these sites occur in clusters of 5 or more seeps, leaving about 275 unique locations (including 47 clusters) for seepage along the margin. As a function of depth, seep distribution is heavily skewed toward the upper continental slope at water depths shallower than 400 m on the southern New England margin and ∼ 550 m in the Mid-Atlantic Bight, with additional seeps clustered at ∼1100 m and just deeper than ∼1400 m in both sectors. Despite little ongoing tectonic deformation or active faulting on this passive margin, a variety of processes driven from below the seafloor (e.g., migration of fluids along faults or through permeable strata, seepage above diapirs or other pre-existing structures) and from above (e.g., erosion, sapping, unroofing) contribute to the development of seeps in different settings along the margin. In addition, the prevalence of seeps on promontories overlooking shelf-breaking canyons may be directly related to the three-dimensional nature of the hydrate stability zone in these locations. As a function of depth, the parts of the slope at the contemporary landward limit of gas hydrate stability are devoid of seeps, and the upper slope zones with the most concentrated seepage were not within the gas hydrate stability zone even during the Last Glacial Maximum. Thus, if the large number of upper slope seeps is at least partially sourced in gas hydrate degradation, the gas emitted at these seeps must have migrated there from greater depths on the continental slope.

Marine Geology↗

Gimme shelter: The importance of crevices to some fish species inhabiting a deeper-water rocky outcrop in Southern California

Federal law governing fisheries management recognizes the role habitat plays in structuring fish assemblages and achieving sustainable fisheries. However, in most instances it is not known which aspects of habitat are important to the lives of fish species. In 2004, we examined the importance of sheltering sites (crevices) to fishes living along low ledges in deeper waters off Anacapa Island, southern California. We found that patterns of fish-habitat relationships varied among the eight most abundant species. Three species, bocaccio (Sebastes paucispinis), vermilion (S. miniatus), and flag (S. rubrivinctus) rockfishes, had densities one to three orders of magnitude greater in the deep crevice habitat compared to low relief rock or shallow crevice habitats. Density and mean size of the two most abundant fishes, halfbanded (S. semicinctus) and squarespot (S. hopkinsi) rockfishes, generally increased as complexity of rock habitat increased. Not all species had the highest densities in deep crevice habitat. Greenspotted rockfish (S. chlorostictus) and blackeye goby (Rhinogobiops nicholsii) showed no significant difference in density among rock habitats. Pink seaperch (Zalembius rosaceus) were absent in the deep crevice habitat and abundant only in low relief rock habitats. Our study implies that it is not sufficient to distinguish only between soft and hard bottom types when using habitat to guide fisheries management strategies. Finer-scale investigations of fish-habitat relationships, paired with habitat mapping and groundtruthing, aid in the design and positioning of Marine Park Areas (MPAs) and are necessary to facilitate understanding of how a particular MPA may contribute to fisheries management.

California Cooperative Oceanic Fisheries Investiga↗

Upper Cretaceous subsurface stratigraphy and structure of coastal Georgia and South Carolina

Upper Cretaceous subsurface stratigraphy and structure of coastal Georgia and South Carolina is based on the study of 24 wells along two transects, one extending across the seaward-dipping sedimentary basin termed the 'Southeast Georgia Embayment' northeastward to the crest of the Cape Fear Arch, and the other alined east-west, parallel to the basin axis and including the COST GE-l well on the Outer Continental Shelf. A new biostratigraphic analysis, using calcareous nannofossils, of the Fripp Island, S.C., well and reinterpretations of the Clubhouse Crossroads corehole 1, South Carolina, and other wells in South Carolina, Georgia, and northernmost Florida have made possible the comparison and reevaluation of stratigraphic interpretations of the region made by G. S. Gohn and others in 1978 and 1980 and by P. M. Brown and others in 1979. The present study indicates that within the Upper Cretaceous section the stratigraphic units formerly assigned a Cenomanian (Eaglefordian and Woodbinian) age are Coniacian (Austinian) and Turonian (Eaglefordian) in age. A previously described hiatus encompassing Coniacian and Turonian time is not present. More likely, a hiatus is probably present in the upper Turonian, and major gaps in the record are present within the Cenomanian and between the Upper Cretaceous and the pre-Cretaceous basement. After an erosional episode in Cenomanian time that affected the section beneath eastern Georgia and South Carolina, Upper Cretaceous marine clastic and carbonate rocks were deposited on a regionally subsiding margin that extended to the present Blake Escarpment. In contrast, during Cenozoic time, especially in the Eocene, subsidence and sedimentation rates were uneven across the margin. A thick progradational sequence of carbonate rocks accumulated in the Southeast Georgia Embayment and also built the present Continental Shelf, whereas farther offshore a much thinner layer of sediments was deposited on the Blake Plateau. There is no general agreement on the exact placement of the Cenomanian-Turonian boundary in Europe or the United States Western Interior, and the widespread Sciponoceras gracile ammonite zone represents an interval of equivocal age between accepted Cenomanian and Turonian strata. The extinction of the foraminifer genus Rotalipora took place within the Sciporwceras gracile zone; it is used here to identify the Cenomanian-Turonian boundary. Pollen zone IV (Complexiopollis-Atlantopollis assemblage zone) is an important and widespread biostratigraphic unit characterized by a distinctive spore and pollen flora. It is consistently associated with lower Turonian calcareous nannofossils on the Atlantic continental margin; these nannofossil assemblages are also present in pollen zone IV, in strata that encompass the Sciponoceras gracile zone and the lower part of the Mytiloides labiatus zone in the Gulf Coastal Plain at Dallas, Tex.

Professional Paper↗

Examination of core samples from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Effects of retrieval and preservation

Collecting and preserving undamaged core samples containing gas hydrates from depth is difficult because of the pressure and temperature changes encountered upon retrieval. Hydrate-bearing core samples were collected at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well in February 2007. Coring was performed while using a custom oil-based drilling mud, and the cores were retrieved by a wireline. The samples were characterized and subsampled at the surface under ambient winter arctic conditions. Samples thought to be hydrate bearing were preserved either by immersion in liquid nitrogen (LN), or by storage under methane pressure at ambient arctic conditions, and later depressurized and immersed in LN. Eleven core samples from hydrate-bearing zones were scanned using x-ray computed tomography to examine core structure and homogeneity. Features observed include radial fractures, spalling-type fractures, and reduced density near the periphery. These features were induced during sample collection, handling, and preservation. Isotopic analysis of the methane from hydrate in an initially LN-preserved core and a pressure-preserved core indicate that secondary hydrate formation occurred throughout the pressurized core, whereas none occurred in the LN-preserved core, however no hydrate was found near the periphery of the LN-preserved core. To replicate some aspects of the preservation methods, natural and laboratory-made saturated porous media samples were frozen in a variety of ways, with radial fractures observed in some LN-frozen sands, and needle-like ice crystals forming in slowly frozen clay-rich sediments. Suggestions for hydrate-bearing core preservation are presented.

Alaska↗

Lithium contents and isotopic compositions of ferromanganese deposits from the global ocean

To test the feasibility of using lithium isotopes in marine ferromanganese deposits as an indicator of paleoceanographic conditions and seawater composition, we analyzed samples from a variety of tectonic environments in the global ocean. Hydrogenetic, hydrothermal, mixed hydrogenetic–hydrothermal, and hydrogenetic–diagenetic samples were subjected to a two-step leaching and dissolution procedure to extract first the loosely bound Li and then the more tightly bound Li in the Mn oxide and Fe oxyhydroxide. Total leachable Li contents vary from <1 ppm in hydrogenetic crusts to 1422 ppm (up to 1188 ppm measured here) in hydrothermal deposits. Hydrated Li ions in seawater and hydrothermal fluids are preferentially sorbed on the negatively charged surface of MnO 2 by coulombic force. Hence, the abundant Li in hydrothermal deposits is mainly associated with the dominant phase, MnO 2 . The surface of amorphous FeOOH holds a slightly positive charge and attracts little Li, as demonstrated by data for hydrothermal Fe oxyhydroxide. Loosely sorbed Li in both hydrogenetic crusts and hydrothermal deposits exhibit Li isotopic compositions that resemble that of modern seawater. We infer that the hydrothermally derived Li scavenged onto the surface of MnO 2 freely exchanged with ambient seawater, thereby losing its original isotopic signature. Li in the tightly bound sites is always isotopically lighter than that in the loosely bound fraction, suggesting that the isotopic fractionation occurred during formation of chemical bonds in the oxide and oxyhydroxide structures. Sr isotopes also show evidence of re-equilibration with seawater after deposition. Because of their mobility, Li and Sr in the ferromanganese crusts do not faithfully record secular variations in the isotopic compositions of seawater. However, Li content can be a useful proxy for the hydrothermal history of ocean basins. Based on the Li concentrations of the globally distributed hydrogenetic and hydrothermal samples, we estimate a scavenging flux of Li that is insignificant compared to the hydrothermal flux and river input to the ocean.

Deep-Sea Research Part II: Topical Studies in Ocea↗

Demography of the Pacific walrus (Odobenus rosmarus divergens) in a changing Arctic

The Pacific walrus ( Odobenus rosmarus divergens ) is a candidate to be listed as an endangered species under United States law, in part, because of climate change‐related concerns. While the population was known to be declining in the 1980s and 1990s, its recent status has not been determined. We developed Bayesian models of walrus population dynamics to assess the population by synthesizing information on population sizes, age structures, reproductive rates, and harvests for 1974–2015. Candidate models allowed for temporal variation in some or all vital rates, as well as density dependence or density independence in reproduction and calf survival. All selected models indicated that the population underwent a multidecade decline, which began moderating in the 1990s, and that annual reproductive rate and natural calf survival rates rose over time in a density‐dependent manner. However, selected models were equivocal regarding whether the natural juvenile survival rate was constant or decreasing over time. Depending on whether juvenile survival decreased after 1998, the population growth rate either increased during 1999–2015 or stabilized at a lesser level of decline than seen in the 1980s. The probability that the population was still declining in 2015 ranged from 45% to 87%.

Marine Mammal Science↗

Infrared survey of the Pisgah Crater area, San Bernardino County, California - a geologic interpretation

The infrared survey of the Pisgah Crater Area, San Bernardino County, California was primarily undertaken to establish parameters by which rock types, structures, and textures peculiar to this locale could be recognized or differentiated. A secondary purpose was to provide an adequate evaluation and calibration of airborne and ground-based instruments used in the survey. Pisgah Crater and its vicinity was chosen as one of the fundamental test sites for the NASA remote sensing program because of its relatively fresh basaltic flows and pyroclastics. Its typical exposure of basalt also made it a possible lunar analogue. A fundamental test site for the purpose of the program is defined as a readily accessible area for which the topography, geology, hydrology, soils, vegetation and other features are relatively well known. All remote sensor instrument teams, i.e. infrared, radar, microwave, and photography, were obligated to use the fundamental test sites for instrument evaluation and to establish terrain identification procedures. Pisgah Crater, nearby Sunshine Cone, and their associated lava flows are in the southern Mojave Desert about 40 miles east-southeast of Barstow, California. (See fig. 1.) U. S. Highway 66 skirts .the northern part of the area and provides access via asphalt-paved and dirt roads to the Crater and to the perimeters of the flows. Pisgah Crater, which is a pumiceous cone, is owned and occasionally quarried by the Atchison, Topeka and Santa Fe Railroad. The remaining part of the area to the south is within the boundary of the Marine Corps Base, Twentynine Palms, California and is currently being used as a gunnery, and bombing range. The proximate area to east, west, and north of Pisgah Crater is public domain. Originally, an area totaling 10 square miles was outlined for detailed study. (See plate 1.) This included an 8 mile long strip extending south- east from and including Pisgah Crater to Lavic Dry Lake, and a 2 mile strip aligned to include a portion of the Sunshine lava flow and the dry lake. Additional aerial infrared imagery of the Sunshine and Pisgah flows along the Pisgah fault proved so interesting and informative that this area is included in the discussion. Infrared surveys were flown February ii through 13, 1965 and August 5 and 9, 1966. The initial survey was flown by the NASA personnel aboard the NASA 926 Convair 240 aircraft. Because of technical problems with the infrared scanners (4.5-5.5 and 8-14 micron bands) and with certain ground instruments, most of the imagery and ground temperature data obtained during the initial survey period was of little value. However, excellent infrared imagery in the 8-14 micron (?) region of the spectrum was acquired by the Geological Survey during the August 1966 survey. The scanner was mounted in a Beech D-18 aircraft provided by the Survey's Water Resources Division. Likewise, more reliable ground data was obtained at this time owing to improved instrumentation and technique. Ground data were taken by Geological Survey personnel including W. A. Fischer, J. D. Friedman, W. R. Hemphill, D. L. Daniels, G. R. Boynton, Po W. Philbin and the author. C. R. Fross operated the infrared scanner during the August, 1966 survey and R. M. Turner was-responsible for photo processing of the infrared imagery. Their assistance is gratefully acknowledged.

Open-File Report↗

Geology of the central and northern parts of the Western Cascade Range in Oregon

This report pt·esents a description of the stratigraphy, structure, and petrology of the volcanic rocks of the central and northern parts of the Western Cascade Range of Oregon. The study is a part of a long-range cooperative program between the U.S. Geological Survey and the Oregon State Department of Geology and Mineral Industries to prepare a geologic map of Oregon. The map area, about 7,500 square miles, lies in the densely forested western slope of the Cascade Range. It is bounded approximately by lat 43° N. and lat 45°30' N. on the south and north, the crest of the range on the east, and long 123° W. and the edge of the Willamette Valley on the west. The geology, which was mapped by reconnaissance methods, is chiefly based on examination of rock exposures along roads. The Cascade Range in Oregon comprises two physiographic divisions: the Western Cascade Range, which includes a wide, deeply dissected belt of volcanic formations making up the western slope of the range, and the High Cascade Range, which includes chiefly younger cones and lava flows forming the nearly undissected crest of the range. The volcanic rocks of the Western Cascade Range are deformed and partially altered flows and pyroclastic rocks that range in age from late Eocene t·o lute Miocene, as determined chiefly from fossil plants from more than 50 localities. These volcanic rocks overlie or interfinger westward with marine sedimentary rocks, and in the southwestern part of the map area they overlie pre-Tertiary plutonic and metamorphic rocks of the Klamath Mountains.

Oregon↗

Habitat characteristics affecting fish assemblages on a Hawaiian coral reef

Habitat characteristics of a reef were examined as potential influences on fish assemblage structure, using underwater visual census to estimate numbers and biomass of all fishes visible on 42 benthic transects and making quantitative measurements of 13 variables of the corresponding physical habitat and sessile biota. Fish assemblages in the diverse set of benthic habitats were grouped by detrended correspondence analysis, and associated with six major habitat types. Statistical differences were shown between a number of these habitat types for various ensemble variables of the fish assemblages. Overall, both for complete assemblages and for component major trophic and mobility guilds, these variables tended to have higher values where reef substratum was more structurally or topographically complex, and closer to reef edges. When study sites were separately divided into five depth strata, the deeper strata tended to have statistically higher values of ensemble variables for the fish assemblages. Patterns with depth varied among the various trophic and mobility guilds. Multiple linear regression models indicated that for the complete assemblages and for most trophic and mobility guilds, a large part of the variability for most ensemble variables was explained by measures of holes in the substratum, with important contributions from measured substratum rugosity and depth. A strong linear relationship found by regression of mean fish length on mean volume of holes in the reef surface emphasized the importance of shelter for fish assemblages. Results of this study may have practical applications in designing reserve areas as well as theoretical value in helping to explain the organization of reef fish assemblages.

Journal of Experimental Marine Biology and Ecology↗

Geologic map of the Vail East quadrangle, Eagle County, Colorado

New 1:24,000-scale geologic mapping along the Interstate-70 urban corridor in western Colorado, in support of the State/USGS Cooperative Geologic Mapping Project, is contributing to a more complete understanding of the stratigraphy, structure, tectonic evolution, and hazard potential of this rapidly developing region. The 1:24,000-scale Vail East quadrangle straddles the Gore fault system, the western structural boundary of the Gore Range. The Gore fault system is a contractional structure that has been recurrently active since at least the early Paleozoic and marks the approximate eastern boundary of the Central Colorado trough, a thick late Paleozoic depocenter into which thousands of meters of clastic sediment were deposited from several uplifts, including the ancestral Front Range. The Gore fault was active during both the late Paleozoic and Upper Cretaceous-lower Tertiary (Laramide) deformations. In addition, numerous north-northwest faults that cut the crystalline rocks of the Gore Range were active during at least 5 periods, the last of which was related to Neogene uplift of the Gore Range and formation of the northern Rio Grande rift. Early Proterozoic crystalline rocks underlie the high Gore Range, north and east of the Gore fault system. These rocks consist predominantly of migmatitic biotite gneiss intruded by mostly granitic rocks of the 1.667-1.750 Ma Cross Creek batholith, part of the 1,667-1,750 Ma Routt Plutonic Suite (Tweto, 1987). Southwest of the Gore fault, a mostly gently south-dipping sequence of Pennsylvanian Mimturn Formation, as thick as 1,900 m, and the Permian and Pennsylvanian Maroon Formation (only the basal several hundred meters are exposed in the quadrangle)were shed from the ancestral Front Range and overlie a thin sequence of Devonian and Cambrian rocks. The Minturn Formation is a sequence of interlayered pink, maroon, and gray conglomerate, sandstone, shale, and marine limestone. The Maroon Formation is mostly reddish conglomerate and sandstone. Glacial till of both the middle Pleistocene Bull Lake and late Pleistocene Pinedale glaciations are well exposed along parts of the Gore Creek valley and its tributaries, although human development has profoundly altered the outcrop patterns along the Gore Creek valley bottom. Landslides, some of which are currently active, are also mapped.

Miscellaneous Field Studies Map↗

Seismic and tsunami hazard in Puerto Rico and the Virgin Islands

Executive Summary Puerto Rico and the Virgin Islands are located at an active plate boundary between the North American plate and the northeast corner of the Caribbean plate. The region was subject in historical times to large magnitude earthquakes and devastating tsunamis. A major downward tilt of the sea floor north of Puerto Rico and the Virgin Islands, large submarine rockslides, and an unusually large negative gravity anomaly are also indicative of a tectonically active region. Scientists have so far failed to explain the deformation of this region in a coherent and predictable picture, such as in California, and this has hampered their ability to assess seismic and tsunami hazards in the region. The NE corner of the Caribbean is unique among the seismically-active regions of the United States in that it is mostly covered by water. This fact presents an additional challenge for seismic and tsunami hazard assessment and mitigation. The workshop, convened in San Juan on March 23-24, 1999, was "historic" in that it brought together for the first time a broad spectrum of scientists, engineers, and public and private sector officials who deal with such diverse questions as tectonic models, probabilistic assessment of seismic hazard, prediction of tsunami runup, strong ground motion, building codes, stability of man-made structures, and the public’s preparedness for natural disasters. It was an opportunity for all the participants to find out how their own activity fit into the broad picture of science and how it aids society in hazard assessment and mitigation. In addition, the workshop was offered as a continuing education course at the Colegio de Ingenieros y Agrimensores de Puerto Rico, which assured a rapid dissemination of the results to the local community. A news conference which took place during the workshop alerted the public to the efforts of the USGS, other Federal agencies, the Commonwealth of Puerto Rico, universities and the private sector. During the first day of the workshop, participants from universities, federal institutions, and consulting firms in Puerto Rico, the Virgin Islands, the continental U.S., Dominican Republic, and Europe reviewed the present state of knowledge including a review and discussion of present plate models, recent GPS and seismic reflection data, seismicity, paleoseismology, and tsunamis. The state of earthquake/tsunami studies in Puerto Rico was presented by several faculty members from the University of Puerto Rico at Mayaguez. A preliminary seismic hazard map was presented by the USGS and previous hazard maps and economic loss assessments were considered. During the second day, the participants divided into working groups and prepared specific recommendations for future activities in the region along the six following topics below. Highlights of these recommended activities are: Marine geology and geophysics – Acquire deep-penetration seismic reflection and refraction data, deploy temporary ocean bottom seismometer arrays to record earthquakes, collect high-resolution multibeam bathymetry and side scan sonar data of the region, and in particular, the near shore region, and conduct focussed high-resolution seismic studies around faults. Determine slip rates of specific offshore faults. Assemble a GIS database for available marine geological and geophysical data. Paleoseismology and active faults - Field reconnaissance aimed at identifying Quaternary faults and determining their paleoseismic chronology and slip rates, as well as identifying and dating paleoliquefaction features from large earthquakes. Quaternary mapping of marine terraces, fluvial terraces and basins, beach ridges, etc., to establish framework for understanding neotectonic deformation of the island. Interpretation of aerial photography to identify possible Quaternary faults. Earthquake seismology – Determine an empirical seismic attenuation function using observations from local seismic networks and recently-installed broad-band stations. Evaluate existing earthquake catalogs from local networks and regional stations, complete the catalogs. Transcribe the pre-1991 network data from 9-track tape onto more stable archival media. Calibrate instruments of local networks. Use GPS measurement to constrain deformation rates used in seismic-hazard maps. Engineering – Prepare liquefaction susceptibility maps for the urban areas. Update and improve databases for types of site conditions. Collect site effect observations and near-surface geophysical measurements for future local (urban-area) hazard maps. Expand the number of instruments in the strong motion program. Develop fragility curves for Puerto Rico construction types and details, and carry out laboratory testing on selected types of mass-produced construction. Consider tsunami design in shoreline construction projects. Tsunami hazard - Extract tsunami observations from archives and develop a Caribbean historical tsunami database. Analyze prehistoric tsunami deposits. Collect accurate, up-to-date, near-shore topography and bathymetry for accurate inundation models. Prepare tsunami flooding and evacuation maps. Establish a Caribbean Tsunami Warning System for Puerto Rico and the Virgin Islands. Evaluate local, regional, national, and global seismic networks and equipment, and their role in a tsunami warning system. Societal concerns – Prepare warning messages, protocols, and evacuation routes for earthquake, tsunami, and landslide hazards for Puerto Rico and the U.S. Virgin Islands. Advocate enforcement of existing building codes. Prepare non-technical hazard assessment maps for political and educational uses. Raise the awareness of potentially affected populations by presentations at elementary schools, by the production of a tsunami video, and by distribution of earthquake preparedness manuals in newspaper supplements. Promote partnerships at state and federal level for long-term earthquake and tsunami hazard mitigation. This partnership should also include the private sector such as the insurance industry, telecommunication companies, and the engineering community. The following reports of the various working groups are the cumulative recommendations of the community of scientists, engineers, and public officials, who participated in the workshop. The list of participants and the workshop’s agenda are given in the appendix. Marine and Geology and Geophysics Working Group Paleoseismology and Active Faults Working Group Joint Working Group for Earthquake Seismology and Engineering Tsunami Working Group Societal Concerns Working Group

Puerto Rico and the Virgin Islands↗

Mapping, exploration, and characterization of the California continental margin and associated features from the California-Oregon border to Ensenada, Mexico

Priority Geographic Area: Both within and outside US Exclusive Economic Zone (EEZ). California continental margin. This area includes and continues south of the geographic area captured in the Watt et al. white paper. Description of Priority Area: The California continental margin, from the narrow shelf to abyssal depths, contains diverse seafloor features that influence benthic community types, biological connectivity, and is associated with significant seafloor geohazards. These complex features include marginal basins, depositional slopes, submarine canyons, ridges, and seamounts, and seep environments as a result of fluid seeps along active faults. Water column characteristics are variable, with steep gradients in current velocities, which influence sediment transport, from depositional fans (slow flow, muddy) to submarine canyons and seamounts (high currents, rocky, rugged terrain). These features and associated environments can influence the distribution of deep-sea habitats, including coral and sponge communities. South of the region described in the Watt et al. and Demopoulos et al. white papers, plentiful seeps occur from northern California down to the southern California Borderland. However, the underlying foundational geology associated with these seeps varies along the margin, changing with contrasting tectonic settings, from convergent tectonics to regions dominated by strike-slip faulting (Barry et al. 1996; Paull et al. 2008; Bernardo and Smith 2010; Maloney et al. 2015). For seeps located off southern California, the relationship to strike-slip fault systems may influence the distribution of seep fluid expulsion sites and associated seep habitats (Maloney et al. 2015; Grupe et al. 2015; Conrad et al., 2017), where transpression plays a key role in formation and localization of fluid seeps. Further exploration is required in order to understand these connections. Several submarine canyons intersect the shelf within this region, serving as important channels of energy and transport of sediment from shelf to slope depths. Canyons are typically associated with high currents, turbidity flows, steep and rugged terrain, and high food availability, all of which structures canyon communities and supports hotspots of biodiversity. Specific canyons along the California margin that have been well studied include Scripps and La Jolla Canyons off San Diego, and Monterey Canyon off Monterey, but many more remain relatively unexplored. Commercially important species of fish and invertebrates have been found associated with canyons, as well as deep-sea corals and sponges (e.g., Barry et al. 1996). However, in contrast to their Atlantic counterparts (e.g., through ACUMEN and ASPIRE campaigns) there has been a dearth of exploration and characterization of canyons along the California margin. A number of questions remain regarding canyon and slope wall stability and associated geohazards, plus, how the canyons connect and influence the broader regional biogeography of benthic communities is unknown. Due to their topography, seamounts along the California margin are characterized by steep slopes, large areas of rocky substrate, and high currents. Hydrological complexity is associated with seamounts given they impinge different watermasses, depending on depth range. This heterogeneity yields complex and diverse benthic communities, including commercially important fishes (e.g., Tracey et al., 2012). The geology of Davidson, Pioneer, San Juan, and Rodriquez Seamounts has received considerable study (e.g., Davis et al., 2010) but other seamounts are less known, including how they are biologically and ecologically connected. For example, research comparing the benthic communities associated with Rodriguez and San Juan Seamounts, located outside of the Channel Islands National Marine Sanctuary and within the proposed Chumash Heritage National Marine Sanctuary, to communities found within the sanctuary is critical for managing and protecting resources within the sanctuary and modifying sanctuary boundaries. Exploration would yield the data needed to delineate and characterize essential fish habitats, and deep-sea coral and sponge communities, thus directly connecting the utility of exploration and discovery to decision making. The southern California Borderland is a geomorphologically heterogeneous area created by a complex network of faults, containing deep basins separated by shallow ridges and islands. Persistent fault-related deformation has created complex features, such as exposure of scarps and uplift rocks/ridges, seeps, erosional terraces, hydrate mounds, and mud volcanoes that provide support for thriving benthic communities. That said, significant oxygen minimum zones and low aragonite saturation states persist within several of the basin environments, influencing energy flow, community ecology, and calcification. For example, the combined effects of hypoxia and acidification pose serious threats to marine organisms and biological resources along the California margin. Mapping and exploration of the extensive faults and fault scarps can help constrain historical earthquake activity. But many questions remain regarding how the underlying geology and geological processes have shaped the biological communities.

California↗